KR0119766B1 - Vaporizing and concentration drying apparatus and method - Google Patents

Vaporizing and concentration drying apparatus and method

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Publication number
KR0119766B1
KR0119766B1 KR1019940026474A KR19940026474A KR0119766B1 KR 0119766 B1 KR0119766 B1 KR 0119766B1 KR 1019940026474 A KR1019940026474 A KR 1019940026474A KR 19940026474 A KR19940026474 A KR 19940026474A KR 0119766 B1 KR0119766 B1 KR 0119766B1
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South Korea
Prior art keywords
steam
evaporation
chamber
heat
heat exchange
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KR1019940026474A
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Korean (ko)
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KR950014827A (en
Inventor
신호근
이대성
박용희
Original Assignee
신호근
이대성
박용희
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Priority to KR1019940026474A priority Critical patent/KR0119766B1/en
Application filed by 신호근, 이대성, 박용희 filed Critical 신호근
Priority to PCT/KR1994/000167 priority patent/WO1995014640A1/en
Priority to JP7514966A priority patent/JPH09507036A/en
Priority to RU96113053A priority patent/RU2145573C1/en
Priority to AU11218/95A priority patent/AU690172B2/en
Priority to BR9408150A priority patent/BR9408150A/en
Priority to EP95902312A priority patent/EP0730561A1/en
Priority to CA002177161A priority patent/CA2177161C/en
Priority to CN94194698A priority patent/CN1097559C/en
Priority to US08/344,984 priority patent/US5548906A/en
Publication of KR950014827A publication Critical patent/KR950014827A/en
Application granted granted Critical
Publication of KR0119766B1 publication Critical patent/KR0119766B1/en

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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D1/00Evaporating
    • B01D1/28Evaporating with vapour compression
    • B01D1/284Special features relating to the compressed vapour
    • B01D1/2846The compressed vapour is not directed to the same apparatus from which the vapour was taken off
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/02Treatment of water, waste water, or sewage by heating
    • C02F1/04Treatment of water, waste water, or sewage by heating by distillation or evaporation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D1/00Evaporating
    • B01D1/0011Heating features
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D3/00Distillation or related exchange processes in which liquids are contacted with gaseous media, e.g. stripping
    • B01D3/02Distillation or related exchange processes in which liquids are contacted with gaseous media, e.g. stripping in boilers or stills
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D5/00Condensation of vapours; Recovering volatile solvents by condensation
    • B01D5/0057Condensation of vapours; Recovering volatile solvents by condensation in combination with other processes
    • B01D5/006Condensation of vapours; Recovering volatile solvents by condensation in combination with other processes with evaporation or distillation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D5/00Condensation of vapours; Recovering volatile solvents by condensation
    • B01D5/0057Condensation of vapours; Recovering volatile solvents by condensation in combination with other processes
    • B01D5/0075Condensation of vapours; Recovering volatile solvents by condensation in combination with other processes with heat exchanging
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D5/00Condensation of vapours; Recovering volatile solvents by condensation
    • B01D5/0078Condensation of vapours; Recovering volatile solvents by condensation characterised by auxiliary systems or arrangements
    • B01D5/009Collecting, removing and/or treatment of the condensate
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D5/00Condensation of vapours; Recovering volatile solvents by condensation
    • B01D5/0078Condensation of vapours; Recovering volatile solvents by condensation characterised by auxiliary systems or arrangements
    • B01D5/0096Cleaning
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/02Treatment of water, waste water, or sewage by heating
    • C02F1/04Treatment of water, waste water, or sewage by heating by distillation or evaporation
    • C02F1/048Purification of waste water by evaporation
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F11/00Treatment of sludge; Devices therefor
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W10/00Technologies for wastewater treatment
    • Y02W10/40Valorisation of by-products of wastewater, sewage or sludge processing

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Hydrology & Water Resources (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Organic Chemistry (AREA)
  • Vaporization, Distillation, Condensation, Sublimation, And Cold Traps (AREA)
  • Heat Treatment Of Water, Waste Water Or Sewage (AREA)
  • Drying Of Solid Materials (AREA)
  • Treatment Of Sludge (AREA)

Abstract

The latent heat of vaporization obtained by liquefying the heat of vaporization of vapor discharged from the vacuum evaporation or pressure evaporation process is reused for the sake of evaporation energy-saving. The offensive odor and vapor impurities in condensate water are removed by oxidization burning or carbonization at high temperature to give clean distilled water. The high temperature heating energy of water vapor is adsorbed as vapor preheating energy by the heat-exchanger system and reused to produce the high temperature vapor.

Description

증기정화(蒸氣淨化)능력을 가진 증발(蒸發) 및 증발농축건조(蒸發濃縮乾燥)장치와 방법Evaporation and Evaporative Concentration Drying Apparatus and Method with Steam Purification Capability

제1도는 본 발명의 양호한 실시예의 부분단면된 구성도.1 is a partial cross-sectional view of a preferred embodiment of the present invention.

제2도는 본 발명의 가열증기 열교환 회수장치의 부분 확대사시도.2 is a partially enlarged perspective view of the heat vapor heat exchange recovery apparatus of the present invention.

제3도는 본 발명의 가열증기 열교환 회수장치내의 열교환 변화를 나타내는 부분 단면도.3 is a partial cross-sectional view showing the heat exchange change in the heated steam heat exchange recovery apparatus of the present invention.

제4도는 본 발명의 교반날개 및 스팀열교환 패널의 부분 확대사시도.4 is a partially enlarged perspective view of the stirring blade and the steam heat exchange panel of the present invention.

제5도는 본 발명의 패널형 스팀챔버의 부분 확대정면도.5 is a partially enlarged front view of the panel type steam chamber of the present invention.

* 도면의 주요부분에 대한 부호의 설명* Explanation of symbols for main parts of the drawings

1 : 증발대상물 저장탱크 10 : 교반형 증발 및 증발농축건조기1: evaporation object storage tank 10: stirring evaporation and evaporation concentration dryer

11 : 함몰부 11s : 스크류11: depression 11s: screw

12 : 교반날개 13 : 패널형 스팀챔버12: stirring blade 13: panel type steam chamber

14 : 스팀챔버 15(a),15(b) : 투입구14: steam chamber 15 (a), 15 (b): inlet

16 : 연결관 17 : 오버플로방지용 챔버16: connector 17: overflow prevention chamber

18 : U형트랩 20 : 증기압축터빈18: U type trap 20: Steam compression turbine

21 : 예열공기 공급 조절밸브 30 : 증기압축펌프21: preheating air supply control valve 30: steam compression pump

40 : 보조보일러 41 : 버너40: auxiliary boiler 41: burner

42 : 코일형 증기가열튜브 43 : 증기가열챔버42: coil type steam heating tube 43: steam heating chamber

50 : 응축수저장탱크 51 : 레귤레이터50: condensate storage tank 51: regulator

52 : 드레인 밸브 60 : 가열증기 열교환 회수장치52: drain valve 60: heated steam heat exchange recovery unit

R : 코일형 튜브 R1-R10 : 관로R: Coiled Tube R1-R10: Pipeline

본 발명은 감압증발(減壓蒸發) 또는 가압증발(加壓蒸發)과정에서 발생하는 수증기의 기화열(氣化熱)을 액화시켜 기화열이 가지고 있는 잠열(latent heat)(물의 경우에 539kcal/ℓ)을 재생(再生)사용함으로써 에너지를 절약하고 수증기에 함유되어 함께 동반증발(同伴蒸發)하여 응축수(凝縮水)의 수질을 악화시키는 악취 및 B.O.D., C.O.D. 등의 증발기체(수증기 불순물)들을 고온에서 산화연소시키거나 탄화시켜 제거함으로써 획기적으로 깨끗한 수질(水質)의 응축수를 제공할 수 있는 증기정화(蒸氣淨化) 능력을 가진 증발(蒸發) 및 증발농축건조(蒸發濃縮乾燥)장치와 방법에 관한 것이다.The present invention is to liquefy the vaporization heat of water vapor generated in the process of reduced pressure evaporation or pressure evaporation (latent heat) of the vaporization heat (539 kcal / l in the case of water) Odor and BOD, COD which save energy by regenerating oil and it is contained in water vapor and together evaporates together to deteriorate the water quality of condensed water. Evaporation and evaporation drying drying with steam purification ability to provide clean water condensed water by oxidizing or carbonizing and removing evaporation gas (water vapor impurity) at high temperature. (Iii) The apparatus and method.

종래의 증발장치들은 증발에 필요한 열량, 즉, 비등점까지의 열량(100kcal)과 기화열량(잠열) 539kcal/ℓ을 투입하는 외에 응축과정에서 필요한 냉각수가 추가로 투입되어야만 한다. 이런 과정을 거쳐 증발, 기화, 응축된 증류수의 경우 증발대상물이 갖고 있는 냄새성분의 악취와 B.O.D., C.O.D. 등의 오염물질중 일부가 수증기와 함께 동반증발하여 수증기에 함유되어 있다가 액화되기 때문에 증류수의 수질이 허용기준치를 벗어나게 되고, 결국 이러한 기준미달인 증류수의 수질개선을 위해 2차 처리가 불가피하게 된다.Conventional evaporators require an additional amount of cooling water required in the condensation process, in addition to the amount of heat required for evaporation, that is, the amount of heat to boiling point (100 kcal) and the heat of vaporization (latent heat) 539 kcal / l. In the case of distilled water evaporated, vaporized, and condensed through this process, the odor of the odor component of the evaporation object and the B.O.D., C.O.D. Some of the contaminants such as water are vaporized together with the water vapor to be contained in the water vapor and then liquefied. Therefore, the water quality of the distilled water is out of the allowable standard value, and the secondary treatment is inevitably necessary to improve the water quality of the distilled water that falls below the standard. .

다시한번 바꾸어 말하면 지금까지의 증발장치 및 방법들은 증발시의 기화열에 포함되어 있는 잠열(539kcal/ℓ)을 재사용하지 못하고, 오히려 많은 경비를 들여 냉각응축과정의 콘덴서 시스템(condenser system)을 통하여 내버리는 결과를 초래하였다.In other words, until now, the evaporation apparatus and methods so far cannot reuse the latent heat (539 kcal / l) contained in the evaporation heat during evaporation, but rather, it is thrown out through the condenser system of the cooling condensation process at a high cost. Resulted.

더욱이 수증기에 함유되어 증발하였다가 함께 액화되어 증류수의 수질을 떨어뜨리는 각종 냄새성분의 악취와 B.O.D., C.O.D. 등의 불순물들을 제거하지 못하기 때문에 증류수의 수질을 양호하게 하기 위해서는 또다른 2차 정수처리과정을 거쳐야 하며, 이것의 처리방법이 복잡할 뿐만 아니라 과다한 처리비용이 요구되는 단점이 있다.Furthermore, the odors of various odors and the B.O.D., C.O.D. In order to improve the quality of the distilled water because it is not able to remove impurities such as such, it is required to go through another secondary water treatment process, there is a disadvantage that the treatment method is complicated and excessive treatment cost is required.

또한 감압증발법(減壓蒸發法)을 이용하여 수증기를 증발시킨다 할지라도 증발을 위한 열량을 진공도에 따라 감압된 만큼 절약시킬 수 있지만, 역시 액화(液化)된 응축수에는 많은 악취와 증발한 만큼의 B.O.D., C.O.D. 등이 함유되어 있기 때문에 탈취(脫臭)와 정수(淨水)를 위해서 상기 방법만을 이용할때 역시 2차 처리과정이 요구되고 있다.In addition, even if the vaporized water vapor is evaporated using the reduced pressure evaporation method, the amount of heat for evaporation can be saved as much as the reduced pressure depending on the degree of vacuum. BOD, COD Since such a method is used, a secondary treatment is also required when only the above method is used for deodorization and purification.

그러나 증기정화(蒸氣淨化) 능력을 가진 증발 및 농축건조장치와 방법에 관한 본 발명의 증발기(蒸發機) 또는 증발농축건조기(蒸發濃縮乾燥機)는 이와같은 단점을 극복하고 개선하여 양질(良質)의 증류수를 제공함은 물론 증발에너지를 최소화하여 에너지를 절약케 하는데 그 목적이 있으며, 오염된 폐수의 증류수화 정수(蒸溜水化 淨水)처리 및 각종 환경오염 슬러지의 농축 및 건조처리에 이용될 수 있다.However, the evaporator or evaporative condenser of the present invention regarding the evaporation and concentration drying apparatus and method having the steam purification ability overcomes these disadvantages and improves the quality thereof. Its purpose is to save energy by minimizing evaporation energy as well as providing distilled water.It can be used for the distillation water purification treatment of contaminated wastewater and the concentration and drying treatment of various environmental polluted sludge. have.

또한, 폐수에 함유된 B.O.D., C.O.D. 등의 불순물 및 악취제거를 위해 고온으로 가열된 고온증기를 본 발명의 가열증기 열교환 회수장치에 의해서 필요한 만큼 회수하여 증기가열 연료비용을 획기적으로 절감시킬 수도 있다.In addition, B.O.D., C.O.D. In order to remove impurities such as impurities and odors, hot steam heated to a high temperature may be recovered as needed by the heated steam heat exchange recovery apparatus of the present invention, thereby significantly reducing the steam heating fuel cost.

상기한 본 발명을 더 구체적으로 살펴보면 종래의 증발기화(蒸發氣化)방법 및 기술로는 1ℓ 물을 증발시키는데 요구되는 열량이 0℃의 대기압을 기준으로 할때 비등점 100℃까지의 도달을 위해 100kcal, 그리고 증발에 필요한 기화열량 539kcal 도합 639kcal가 필요하게 되며 기를 사용할 경우 약 10Torr(750mmHg)의 진공도일때 35℃에서 물이 비등하므로 35kcal+570kcal=605kcal의 열량이 필요하게 된다.(증기압이 0.1kg/cm2·A일때, 잠열은 약 570kcal가 된다.)Looking at the present invention in more detail in the conventional evaporation method and technology 100kcal for reaching the boiling point 100 ℃ when the amount of heat required to evaporate 1L water based on the atmospheric pressure of 0 ℃ In addition, the total amount of vaporization heat required for evaporation is 539kcal and 639kcal is required. When using a gas, water is boiled at 35 ° C. at a vacuum degree of about 10 Torr (750 mmHg). In cm2 · A, the latent heat is about 570 kcal.)

그러나 이와같은 종래의 감압증발 또는 가열증발 또는 가열증발장치 및 기술로는 기화(氣化)수증기를 다시 응축, 액화시키기 위해 응축기(condenser)를 사용함으로써 많은 양의 열교환용 냉각수가 필요하게 됨은 물론 수증기가 갖고 있는 잠열(539kcal)을 재사용하지 못하고 그대로 버려온 셈이다.However, such a conventional reduced pressure evaporation or heating evaporation or heating evaporation apparatus and technology requires a large amount of cooling water for heat exchange by using a condenser to condense and liquefy vaporized water vapor. Was unable to reuse his latent heat (539kcal).

결론적으로 종래의 감압증발 또는 가열증발장치 및 기술로는 1ℓ의 물을 증발시키기 위해 639kcal의 열량에너지를 필요로 하는 외에 응축기(condenser)의 냉각수 공급, 순환에 따른 에너지가 추가로 투입되어야 하고, 이 과정에서 기화열량 539kcal는 많은 경비를 들여 내어버리는 결과가 되는 셈이다. 이 뿐만 아니라 종래 기술의 감압 또는 가열증발장치에서 증발된 기체에는 증발물질이 갖고 있는 악취 와 B.O.D., C.O.D. 등의 물질들이 동반 증발하여 섞이게 되는데 이같은 수증기 불순물 및 악취를 제거하기 위하여 다시 특정한 방법의 폐수처리 과정을 거쳐야만 방류할 수 있게 되는 비경제적 단점들이 있다.In conclusion, the conventional reduced-pressure evaporation or heating evaporation apparatus and technology require 639 kcal of calorie energy to evaporate 1 liter of water, and additional energy from cooling water supply and circulation of the condenser must be added. In the process, 539 kcal of vaporization is a result of spending a lot of money. In addition, the gas evaporated in the decompression or heat evaporation system of the prior art includes the odor and the B.O.D., C.O.D. These substances are mixed together by evaporation, and there is an uneconomical disadvantage in that they can be discharged only after a specific method of wastewater treatment in order to remove such water vapor impurities and odors.

그러나 본 발명 기술 및 방법을 사용할 경우 전술한 종래 기술 및 방법들의 단점들을 극복, 개선할 수 있기 때문에 증발(蒸發), 기화(氣化), 응축(凝縮), 액화(液化)에 따르는 공정 및 장치비용을 획기적으로 줄일 수 있을 뿐만 아니라 기화열을 재생사용하므로써 종래 기술에 비해 에너지를 2-10배 이상까지 절약할 수 있고, 수증기에 함유된 악취나 불순물 역시 별도의 폐수처리 장치없이 기화열 재생과정에서 동시에 산화, 연소 또는 탄화시켜 제거하여 응축수의 수질을 높여주는 간단하면서도 탁월한 성능을 발휘하는 증기정화(蒸氣淨化)능력을 가진 증발(蒸發) 및 증발농축건조(蒸發濃縮乾燥)장치와 방법을 제공함에 있는 것이다.However, when using the present technology and method can overcome and improve the above-mentioned disadvantages of the prior art and method, the process and apparatus according to evaporation, vaporization, condensation, liquefaction Not only can it drastically reduce the cost, but it also saves energy by 2-10 times more than the conventional technology by regenerating the heat of vaporization, and the odor or impurities contained in the water vapor can also be recovered at the same time without the separate wastewater treatment device. Evaporation and Evaporative Concentration Drying Apparatus and Method with Simple and Excellent Performance of Steam Purification by Oxidation, Combustion or Carbonization to Improve Condensate Water Quality will be.

이하에서 이를 첨부도면에 의해 상세히 설명하면 다음과 같다.Hereinafter, described in detail by the accompanying drawings as follows.

먼저 본 발명의 장치를 설명하면 도면 제1도에 도시되어 있는 것처럼 코일형 튜브(R)가 내설되고 상부에 증발 대상물 투입구(15a)를 구비하여 응축수 폐열회수(凝縮水廢熱回收) 기능을 위해 이중으로 형성된 증발대상물(蒸發對象物) 저장탱크(1) 및 물, 예컨데 폐수를 저장할 수 있는 교반형 증발 및 증발농축건조기(10)의 상부는 상황에 따라 사용가능한 증발물 투입구(15b)를 구비하고 하부가 원형단면을 가지며 일측에 함몰부(11)를 형성, 찌꺼기배출용 스크류(11s)를 내설하고, 제4도 및 제5도에 도시되어 있는 것처럼 다수의 판상 반원형태의 패널형 스팀챔버(13)들이 일정한 간격으로 수직으로 내설되고 패널형 스팀챔버(13)와 챔버(13)사이를 회전하면서 교반할 수 있는 다수의 교반날개(12)들이 상기 증발 및 증발농축건조기(10)의 길이에 따라 중앙을 관통하도록 장치된 축(S)에 부착되어 정,역회전하면서 교반기능을 수행하며 이 챔버(13)는 상기 교반형 증발 및 증발농축건조기(10)에 이중으로 형성된 스팀챔버(14)와 연통되어 있으며, 상기 증발농축건조기(10)의 상부 일측에는 연결관(16)으로 오버플로방지용 챔버(17)와 연결되며, 이 챔버(17)하부에는 U형 트랩(18)을 두어 상기 교반형 증발 및 증발농축건조기(10)내부와 연결된다. 상기 패널형 스팀챔버(13)는 상기 교반날개(12)가 원할하게 작동하기 위하여 상광하협으로 형성된다.First, the apparatus of the present invention will be described as shown in Figure 1, the coiled tube (R) is built-in and the evaporation object inlet (15a) is provided at the top for the condensate waste heat recovery function The upper portion of the evaporation object storage tank (1) and the agitated evaporation and evaporation concentration dryer (10) capable of storing water, for example, wastewater, are provided with an evaporant inlet (15b) which can be used according to circumstances. The lower part has a circular cross section and forms a depression 11 on one side, and there is a screw discharged screw 11s, and as shown in FIG. 4 and FIG. 13 are built vertically at regular intervals and a plurality of stirring blades 12 capable of stirring while rotating between the panel-type steam chamber 13 and the chamber 13 to the length of the evaporation and evaporation dryer 10. Penetrating the middle along It is attached to the shaft (S) equipped with a rocker performs a stirring function while rotating forward and reverse, the chamber 13 is in communication with the steam chamber 14 formed in the agitated evaporation and evaporation condenser dryer (10) The upper one side of the evaporation condenser 10 is connected to the overflow preventing chamber 17 by a connecting tube 16, and a lower U-shaped trap 18 is provided below the chamber 17 to evaporate and evaporate the stirred type. It is connected to the inside of the concentrated dryer (10). The panel-type steam chamber 13 is formed of a subsoil in order to operate the stirring blade 12 smoothly.

그리고 상기 오버플로방지용 챔버(17) 상부로 연결된 관로(R1)상에 예열공기 공급 조절밸브(21)를 갖고 증기압축터빈(20)과 연결되고, 이 증기압축터빈(20) 말단으로부터 연결된 관로(R2)는 증기압축펌프(30)와 연결되며 이로부터의 관로(R3)는 도면 제1도 내지 제3도에 도시되어 있는 것처럼 내부에 증발스팀관로(R9)가 내설된 가열증기(加熱蒸氣) 열교환 회수(熱交換 回收)장치(60)에 연결되며, 상기 회수장치(60)의 양측에 부설된 관로(R4, R6)는 내부로 화력을 갖게 한 보조보일러(40) 및 교반형 증발 및 증발농축건조기(10)에 각각 연결된다. 또한 관로(R4)는 화력이 보조보일러 내부로 향하는 버너(41)의 화구 전방에서 코일형 증기가열튜브(42)와 연결되어 그 중심축의 증기가열챔버(43)를 지나 관로(R5)로 인출되어 가열된 증기열의 재사용을 위해 다시 가열증기 열교환 회수장치(60)에 연결되며, 초기 가동시에 가열증기를 상기 열교환 회수장치(60)로 배출하기 위해 상기 보조보일러(40) 상부에 관로(R10)가 인출되어 관로(R3)와 연결된다.And connected to the steam compression turbine 20 having a preheated air supply control valve 21 on the pipeline (R 1 ) connected to the overflow prevention chamber 17, the pipeline connected from the end of the steam compression turbine (20) (R 2 ) is connected to the steam compression pump 30 and the pipeline (R 3 ) therefrom is a heated steam in which the evaporation steam pipe (R 9 ) is built, as shown in FIGS. 1 to 3. (熱蒸氣) connected to the heat exchange recovery device 60, the pipelines (R 4 , R 6 ) attached to both sides of the recovery device 60, the auxiliary boiler 40 having a thermal power therein And agitated evaporation and evaporative concentration dryers 10, respectively. In addition, the conduit (R 4 ) is connected to the coil-type steam heating tube 42 in front of the burner of the burner 41, the thermal power is directed to the inside of the auxiliary boiler, passing through the steam heating chamber 43 of the central axis to the conduit (R 5 ) It is connected to the heated steam heat exchange recovery device 60 for reuse of the extracted and heated steam heat, and a pipe line on the upper portion of the auxiliary boiler 40 to discharge the heated steam to the heat exchange recovery device 60 during initial operation. R 10 ) is drawn out and connected to the conduit R 3 .

한편, 상기 교반형 증발 및 증발농축건조기(10)의 스팀챔버(14) 하부로는 압력조절 레귤레이터(51)와 드레인밸브(52)를 갖는 관로(R7)가 인출되어 증발대상물 저장탱크(1)로 연결되고, 상기 저장탱크(1)내의 코일형 튜브(R)를 통과하며 폐열을 빼앗긴 응축수가 응축수저장(凝縮水 貯藏)탱크(50)에 모여진다.Meanwhile, a conduit R 7 having a pressure regulating regulator 51 and a drain valve 52 is drawn out below the steam chamber 14 of the stirred evaporation and evaporation concentration dryer 10 to store the evaporation object storage tank 1. The condensed water is collected in the condensed water storage tank 50 through the coiled tube R in the storage tank 1 and the waste heat is deprived.

상기와 같은 장치로 된 본 발명의 실시방법을 살펴보면 오염된 폐수등의 증발대상물이 투입구(15a)를 통해 응축수 폐열회수 기능을 가진 증발대상물 저장탱크(1)로 투입되어 관로(R8)을 지나 교반형 증발 및 증발농축건조기(10)내에서 증발되고, 이 증발된 증기는 오버플로방지용 챔버(17)를 거쳐 관로(R1)를 지나, 수증기에 포함된 기화(氣化)불순물의 성질에 따라 산화연소촉진용 공기공급 목적의 예열공기 공급 조절밸브(21)로 적정량의 예열공기를 혼합시킨 상태에서 증기압축터빈(20)으로 진입되고(증발대상물의 성질에 따라 예열공기 공급없이 고온에서 탄화시킬 수도 있음), 교반형 증발 및 증발농축건조기(10)는 증기압축터빈(20)과 증기압축펌프(30)의 작용으로 진공상태를 초래하여 증발농축건조기의 내부온도를 약 60℃, 진공도를 약 300-400mmHg가 되도록 하며, 증기압축펌프(30)로 가압하여 증기압이 더욱 높아진 상태에서 관로(R3)를 거쳐 가열증기 열교환 회수장치(60)의 증발스팀관로(R9)를 통과하여, 관로(R4)로 배출된다. 관로(R4)를 통해 배출된 수증기는 보조보일러(40)내의 증기가열튜브(42)와 증기가열챔버(43)를 통과할 때 증기가열수단에 의해 600℃∼800℃의 고온증기로 되면서 증기내의 악취 및 B.O.D., C.O.D. 등의 불순물들이 산화연소되거나 탄화된 증기상태로 관로(R5)를 거쳐, 관로(R3)를 통해 유입된 60℃∼100℃의 증기와 열교환하기 위해 가열증기 열교환 회수장치(60)로 보내어져서, 증기가열수단에 의해 고온화된 증기는, 증발기(10)에서 증발되어 아직 탄화되지 아니한 60℃∼100℃의 증기가 통과하는 증발스팀관로(R9) 주위로 격판에 의해 유도되며 지그재그형식의 역방향으로 진행하여 도면 제2도에 도시되어 있는 가열증기 열교환 회수장치(60)내에서 열교환이 이루어진다. 이때 열교환 회수장치(60)내에 일정한 간격으로 격판을 부재하여 열교환 시간을 연장시켜 효율적인 열교환이 이루어지게 할 수 있다.Looking at the embodiment of the present invention with the device as described above, the evaporation object such as contaminated waste water is introduced into the evaporation object storage tank (1) having the condensate waste heat recovery function through the inlet (15a) to pass through the pipeline (R 8 ) Evaporated in the stirred evaporation and evaporation condenser 10, the evaporated vapor is passed through the overflow prevention chamber 17, passing through the pipeline (R 1 ) to the nature of the vaporized impurities contained in the water vapor Therefore, the preheating air supply control valve 21 for the purpose of supplying air for oxidation combustion is entered into the steam compression turbine 20 in a state in which an appropriate amount of preheating air is mixed (carbonization at high temperature without supplying preheating air depending on the properties of the evaporation object). Agitation type evaporation and evaporation concentration dryer (10) causes a vacuum state by the action of the steam compression turbine (20) and the steam compression pump (30) to raise the internal temperature of the evaporation concentration dryer to about 60 ℃, the degree of vacuum Even about 300-400mmHg When the pressure of the steam compression pump 30 is increased, the steam pressure is further increased, and then, through the pipe line R 3 , the evaporation steam pipe line R 9 of the heated steam heat exchange recovery device 60, and the pipe line R 4 . To be discharged. The steam discharged through the conduit R 4 passes through the steam heating tube 42 and the steam heating chamber 43 in the auxiliary boiler 40 and becomes steam at a high temperature of 600 ° C. to 800 ° C. by the steam heating means. in odor and BOD, COD impurities such as oxidation or combustion by the carbonized vapor state through a pipe (R 5), the pipeline (R 3) a heat recovery steam heat exchanger to heat exchange with steam of 60 ℃ ~100 ℃ introduced through the The steam, which has been sent to the apparatus 60 and heated by the steam heating means, is evaporated in the evaporator 10 and passed to the diaphragm around the evaporation steam pipe line R 9 through which steam of 60 ° C. to 100 ° C., which has not yet been carbonized, passes. The heat exchange is conducted in the heated steam heat exchange recovery device 60 shown in FIG. At this time, the diaphragm may be absent at regular intervals in the heat exchange recovery device 60 to extend the heat exchange time, thereby making efficient heat exchange.

그러나 최초 가동시에는 보조보일러(40)내의 물을 가열수단에 의해 가열시켜 고온화된 증기가 관로(R10)와 관로(R3)을 거쳐 상기 열교환 회수장치(60)내의 증발스팀관로(R9)를 통과하며, 증기가열튜브(42) 및 증기가열챔버(43)내에서 고온가열수단에 의해 고온화되며 불순물들이 산화연소 또는 탄화된 상태로 다시 열교환 회수장치(60)내를 역방향으로 진행하여, 증발기(10)내의 패널형 스팀챔버(13) 및 스팀챔버(14)로 보내져 증발대상물과 열교환시켜 60℃∼100℃의 증기로 만들 수 있다. 이러한 열교환작용으로 60℃∼100℃의 증기는 450℃∼600℃인 고온증기로 관로(R4)에 의해 배출되어지며, 관로(R6)로는 열교환 회수장치(60)내에서 열교환으로 온도가 낮아진 150℃∼200℃의 증기로 증발기(10)를 향하여 배출된다.(도면의 제3도 참조) 상기 관로(R4)로 배출된 450℃∼600℃의 예열증기는 상기에서 설명된 것과 같이 보조보일러(40)내에서 가열수단에 의해 고온으로 가열되면서 코일형 증기가열튜브(42) 및 증기가열챔버(43)안으로 진입하여 600℃∼800℃의 고온 증기화(蒸氣化)하여 연소 또는 탄화된 상태에서 관로(R5)를 거쳐, 증발기(10)로부터 증발되어 스팀관로(R9)내에서 유동하는 60℃∼100℃의 증기와 역방향으로 진행하며 가열증기 열교환 회수장치(60)내에서 열교환이 이루어진다. 이때 가열수단에 의해서 600℃∼800℃의 고온증기를 얻기 위해 투입된 가열에너지는 열교환 회수장치(60)내에서 열교환되어(도면 제3도 참조) 증발기(10)에서 증발한 60℃∼100℃의 증기를 450℃∼600℃의 고온증기로 예열하여 재사용함으로써 회수할 뿐만 아니라 가열수단의 가열에너지를 절약시키는 효과를 발생시킨다. 그리고 상기 관로(R6)로 배출된 150℃∼200℃의 불순물이 연소 또는 탄화된 증기는 증발농축건조기(10)의 패널형 스팀챔버(13) 및 스팀챔버(14)로 보내어져 증발농축기내의 증발대상물과 열교환되어 액화되는 과정에서 기화열을 빼앗기고, 이 액화된 고온의 응축수(약 80℃∼120℃)는 압력조절용 레귤레이터(51) 및 드레인밸브(52)를 거쳐 관로(R7)를 통해 증발대상물 저장탱크(1)내의 코일형 튜브(R)에서 제2차로 폐열이 회수되어 응축수저장탱크(50)에 모이게 된다. 이때 응축수저장탱크(50)내의 응축수는 필터링하여 탄화된 수증기 불순물들을 제거하여 양질(良質)의 증류수로 만들 수도 있다.However, in the initial operation, the water in the auxiliary boiler 40 is heated by a heating means so that the vaporized temperature passes through the pipe line R 10 and the pipe line R 3 and the evaporation steam pipe line R 9 in the heat exchange recovery device 60. ) Is heated by the high temperature heating means in the steam heating tube 42 and the steam heating chamber 43, and the impurities proceed in the heat exchange recovery apparatus 60 in the reverse direction again in the state of oxidizing combustion or carbonization. It is sent to the panel-type steam chamber 13 and the steam chamber 14 in the evaporator 10 can be heat-exchanged with the evaporation object to make a vapor of 60 ℃ to 100 ℃. The heat exchange with steam of 60 ℃ ~100 ℃ becomes action is set to the 450 ℃ ~600 ℃ temperature steam discharged by the pipeline (R 4), a pipe (R 6) roneun temperature by heat exchange in the heat recovery device (60) The lowered steam is discharged toward the evaporator 10 (see FIG. 3 of the drawing). The preheated steam of 450 ° C to 600 ° C discharged to the pipe line R 4 is as described above. While heating to a high temperature by the heating means in the auxiliary boiler 40, it enters into the coil-type steam heating tube 42 and the steam heating chamber 43, and burns or carbonizes at a high temperature of 600 ° C to 800 ° C. through the pipeline (R 5) in the state, is evaporated from the evaporator 10, steam pipe (R 9) proceeds to the opposite direction of the steam 60 ℃ ~100 ℃ flowing in, and in the heating steam heat recovery device (60) Heat exchange takes place. At this time, the heating energy inputted by the heating means to obtain high temperature steam of 600 ° C to 800 ° C is heat exchanged in the heat exchange recovery device 60 (see FIG. 3). The steam is preheated with hot steam at 450 ° C. to 600 ° C. and reused to recover steam, thereby generating the effect of saving heating energy of the heating means. In addition, 150 ° C. to 200 ° C. of impurities discharged into the conduit R 6 are burned or carbonized, and the vapor is sent to the panel-type steam chamber 13 and the steam chamber 14 of the evaporation concentrator 10, and the The heat of vaporization and the evaporation heat is removed in the process of liquefaction, the liquefied high temperature condensate (about 80 ℃ ~ 120 ℃) is evaporated through the pipeline (R 7 ) through the pressure regulating regulator 51 and the drain valve 52 Waste heat is recovered from the coiled tube (R) in the object storage tank (1) and collected in the condensate storage tank (50). At this time, the condensed water in the condensate storage tank 50 may be filtered to remove carbonized water vapor impurities to obtain high quality distilled water.

이상과 같은 본 발명은 감압상태에서 적용되었지만 필요에 따라서 대기압 이상의 고압으로 증발시켜 가압된 상태에서 적용될 수도 있다.Although the present invention as described above has been applied under reduced pressure, it may be applied in a pressurized state by evaporating to a high pressure above atmospheric pressure as necessary.

상기와 같은 구성과 방법으로 되는 본 발명의 작용효과를 살펴보면 다음과 같다.Looking at the effects of the present invention made of the configuration and method as described above are as follows.

증발물 저장탱크(1)내의 증발대상물은 코일형 튜브(R)내의 액화된 고온의 응축수로부터 폐열을 회수하여 증기압축터빈(20) 및 증기압축펌프(30)의 감압작용에 의해 자연스럽게 관로(R8)를 통해 교반형 증발 및 증발농축건조기(10)안으로 흡인되고, 교반형 증발 및 증발농축건조기(10)내의 교반날개(12)에 의해 처리대상물이 고른 분포로 혼합되고 최종 슬러지는 함몰부(11)로 이동되어 압출스크류(11s)에 의해 증발농축건조기(10)밖으로 토출되며, 상기 증발 및 증발농축건조기(10)내의 증발 대상물이 패널형 스팀챔버(13) 및 스팀챔버(14)내의 150℃∼200℃인 고온증기로부터 기화열을 회수하여 연결관(16)을 거쳐, 기화기에 액체의 넘침을 방지하기 위해 하부에 U형 트랩(18)이 인출되어 있는 오버플로방지용 챔버(17) 그리고 관로(R1)를 통해 증기압축터빈(20)으로 진입하게 되는데, 이때 증기압축터빈(20)으로 진입하는 증발기체는 필요한 경우에 증기압축터빈(20)의 진입구 직전에 위치한 예열공기 공급 조절밸브(21)에 의해 일정량의 예열공기와 혼합하여 진입하게 된다.The evaporation object in the evaporation storage tank 1 recovers waste heat from the liquefied high-temperature condensate in the coiled tube (R) and naturally flows through the decompression action of the steam compression turbine (20) and the steam compression pump (30). 8 ) is drawn into the stirring evaporation and evaporation dryer 10, the treatment object is mixed in an even distribution by the stirring blades 12 in the stirring evaporation and evaporation concentration dryer 10 and the final sludge ( 11) is discharged out of the evaporation concentration dryer 10 by the extrusion screw (11s), the evaporation object in the evaporation and evaporation concentration dryer 10 is 150 in the panel-type steam chamber 13 and the steam chamber 14 The overflow prevention chamber 17 and the pipe line in which the U-shaped trap 18 is drawn out at the lower part to recover the heat of vaporization from the high temperature steam at which the temperature is between 200 ° C. and 200 ° C., and to prevent the liquid from overflowing into the vaporizer. (R 1) a binary vapor compression turbine 20 through the In this case, the evaporation gas entering the steam compression turbine 20 is mixed with a predetermined amount of preheating air by a preheating air supply control valve 21 positioned immediately before the entrance of the steam compression turbine 20 when necessary. .

이렇게 진입한 증발기체는 증기압축터빈(20)을 거쳐 증기압축펌프(30)에 의해 압축되어 증기압을 높이게 되는데, 이때 교반형 증발 및 증발농축건조기(10)내에 투입된 증발대상물은 증기압축터빈(20)과 증기압축펌프(30)의 작용으로 약 300mmHg-400mmHg의 진공도에 도달한 교반형 증발 및 증발농축건조기(10)내의 감압환경때문에 약 60℃의 증발온도를 유지하면서 증발하게 된다. 기체 혼합물에 대해서도 성립하는 이상기체의 법칙에 관한 하기의 초보적인 수식(E-1)으로부터 알 수 있듯이 상기 증발된 증기가 높은 증기압 상태에서 고온 액화가 발생하도록 증기압축터빈(20) 및 증기압축펌프(30)에 의해 증기압을 높일 수 있다. 상기 증기압축수단으로 사용된 증기압축터빈(20)에 대신하여 진공부스터, 진공분자펌프 및 기타 적정한 방법의 증기압축수단이 이용될 수도 있다.The evaporated gas thus entered is compressed by the steam compression pump 30 through the steam compression turbine 20 to increase the vapor pressure. At this time, the evaporation object introduced into the stirring type evaporation and evaporation concentration dryer 10 is a vapor compression turbine 20. And evaporation while maintaining the evaporation temperature of about 60 ℃ due to the reduced pressure environment in the agitation type evaporation and evaporation dryer 10 reaching a vacuum degree of about 300mmHg-400mmHg by the action of the steam compression pump 30). As can be seen from the following Equation (E-1) regarding the law of an ideal gas that holds for a gas mixture, the vapor compression turbine 20 and the vapor compression pump are used to generate high temperature liquefaction under the high vapor pressure. By 30, the vapor pressure can be increased. Instead of the steam compression turbine 20 used as the steam compression means, a vacuum booster, a vacuum molecular pump and other suitable steam compression means may be used.

PV=nt RT … … (E-1)PV = nt RT… … (E-1)

(여기서, P는 기체성분의 압력, V는 부피, T는 기체성분의 절대온도, R은 기체상수, nt는 부피 V속에 들어있는 기체몰수의 합이다.)Where P is the gas component pressure, V is the volume, T is the absolute temperature of the gas component, R is the gas constant, and nt is the sum of the moles of gas in the volume V.

따라서 이들 증발기체는 증기압축터빈(20)과 증기압축펌프(30)에 의해 증기압이 더욱 높아진 상태로 가열증기 열교환 회수장치(60)내의 증발스팀관로(R9)를 통과하면서 열교환이 이루어진 후 증기가열챔버(43)로 투입되어 가열수단에 의해 600℃∼800℃의 고온으로 가열되어 연소 또는 탄화된 상태에서 가열증기 열교환회수장치(60)로 보내어져 내부에 60℃∼100℃의 증기가 유동하고 있는 증발스팀관로(R9) 주위에서 열교환시간 연장을 위한 격판에 기인하여 서로 역방향의 지그재그형식으로 유동하면서 열교환이 이루어진다.(도면 제2도 참도) 이 결과로 450℃∼600℃의 온도로 예열된 증발기체는 관로(R4)를 통해, 600℃∼800℃의 고온을 유지하기 위해 증기가열수단에 부착된 증기가열튜브(42) 및 증기가열챔버(43)로 보내어지고, 가열 에너지를 빼앗겨 150℃∼200℃로 온도가 낮아진 증발기체는 관로(R6)을 통해 유동하여 교반형 증발 및 증발농축건조기(10)내의 패널형 스팀챔버(13) 및 스팀쳄버(14)로 유입되고, 그곳에서 증발대상물과 열교환하여 약 80℃∼120℃의 온도로 액화된다. 이것은 상기 수식(E-1)에 의해서도 알 수 있듯이 증기압에 비례하는 온도에서 증기의 액화가 발생하기 때문에 증기압이 높은 수증기는 증기압에 비례하는 고온에서 액화되는 것에 기인한다.Therefore, these evaporation gas is passed through the evaporation steam pipe line (R 9 ) in the heated steam heat exchange recovery device 60 in a state in which the vapor pressure is further increased by the steam compression turbine 20 and the steam compression pump 30, Injected into the heating chamber 43 and heated to a high temperature of 600 ℃ ~ 800 ℃ by the heating means and sent to the heated steam heat exchange recovery device 60 in a combustion or carbonized state, the steam of 60 ℃ ~ 100 ℃ flow inside Due to the diaphragm for extending the heat exchange time around the evaporation steam pipe (R9), heat exchange takes place in a zigzag fashion in the opposite direction to each other (see FIG. 2). As a result, at a temperature of 450 ° C to 600 ° C. The preheated evaporator gas is sent to the steam heating tube 42 and the steam heating chamber 43 attached to the steam heating means to maintain a high temperature of 600 ° C. to 800 ° C. through the conduit R 4 . Take away 150 ℃ -20 The evaporation gas having a temperature lowered to 0 ° C. flows through the conduit R6 and flows into the panel-type steam chamber 13 and the steam chamber 14 in the stirring-type evaporation and evaporation dryer 10, where the evaporation object and It heat-exchanges and liquefies to the temperature of about 80 degreeC-120 degreeC. This is due to the liquefaction of the steam at a temperature proportional to the vapor pressure, as can be seen by the above formula (E-1), because the vapor of the high vapor pressure is liquefied at a high temperature proportional to the vapor pressure.

상기의 고온으로 액화된 물은 압력조절용 레귤레이터(51) 및 드레인밸브(52)를 거쳐 관로(R7)를 통해 코일형 튜브(R)로 보내어져 증발대상물 저장탱크(1)내의 증발대상물과 2차 열교환되어 폐열을 빼앗긴 후 응축수저장탱크(50)에 모이게 된다. 한편, 증발 및 증발농축건조기(10)에서 기화열을 회수하여 증발한 60℃∼100℃의 증발 수증기가 오버플로방지용 챔버(17)를 거쳐 가열증기 열교환 회수장치(60)로 보내진다.The water liquefied at a high temperature is sent to the coiled tube (R) through the pipe line (R 7 ) through the pressure regulating regulator (51) and the drain valve (52) and the evaporation object in the evaporation object storage tank (1) and 2 After the heat exchange to take the waste heat is collected in the condensate storage tank (50). On the other hand, 60 ° C to 100 ° C evaporated water vapor that is recovered by evaporation and evaporation heat from the evaporation and condensation dryer 10 is sent to the heated steam heat exchange recovery device 60 through the overflow prevention chamber 17.

또한, 증발기체와 함께 증발하여 수증기와 혼합된 수증기의 악취나 B.O.D., C.O.D. 등의 불순물들은 증기압축터빈(20)의 진입구 직전에 장치된 예열공기 공급 조절밸브(21)의 개,폐조절에 의해 공급된 일정량의 예열공기와 혼합되어 산화를 용이하게 한 상태에서 증기가열 수단인 코일형 증기가열튜브(42)와 증기가열챔버(43)를 통과하면서 600℃∼800℃의 고온환경에 의해 산화·연소되어 제거되거나 증기에 포함된 기화(氣化)상태의 불순물 성질에 따라 예열공기 혼합없이 증기가열 챔버(43)의 고온환경(600℃∼800℃)만으로 탄화시켜 응축수의 고질적인 악취와 B.O.D., C.O.D. 등의 불순물들을 제거할 수 있게 되며, 600℃∼800℃의 고온환경을 만들어 주기 위해 가열수단에 의해 투입된 가열에너지는 가열증기 열교환 회수장치(60)에 의해 회수되어 재사용함으로써 예열된 만큼 가열에너지를 절약할 수 있는 장점을 가지게 된다. 또한 본 발명의 도면에는 도시하지 않았으나 증발물 저장탱크(1), 증발 및 증발농축건조기(10)나 보조보일러(40)등을 단열처리하여 에너지 효율을 더욱 높일 수 있다.In addition, the odor of water vapor mixed with water vapor by evaporation with evaporation gas, or B.O.D., C.O.D. Impurities such as steam heating means are mixed with a predetermined amount of preheated air supplied by opening and closing control of the preheated air supply control valve 21 installed immediately before the entrance of the steam compression turbine 20 to facilitate oxidation. Depending on the impurity properties of the vaporized state contained in the vapor, removed or oxidized and burned by a high temperature environment of 600 ° C to 800 ° C while passing through the in-coil type steam heating tube 42 and the steam heating chamber 43 Carbonization only in the high temperature environment (600 ℃ ~ 800 ℃) of steam heating chamber 43 without mixing preheating air It is possible to remove impurities such as, and the heating energy introduced by the heating means to create a high temperature environment of 600 ℃ ~ 800 ℃ is recovered by the heated steam heat exchange recovery device 60 to reuse the heating energy as preheated You have the advantage of saving. In addition, although not shown in the drawings of the present invention, the heat treatment of the evaporation storage tank 1, the evaporation and evaporation concentration dryer 10, the auxiliary boiler 40, etc. can further increase the energy efficiency.

본 발명의 장치 및 방법을 이용한 실시예의 결과는 하기의 표 1에 나타나 있으며, 이것은 증발대상물로서 분뇨를 사용하여 620℃로 고온 가열 산화연소 또는 탄화시켜 얻은 결과치이다. 하기 결과치로부터 알 수 있듯이 본 발명을 이용한 증발대상물은 획기적으로 정화(淨化)처리될 수 있음을 보여준다.The results of the examples using the apparatus and method of the present invention are shown in Table 1 below, which is the result obtained by high-temperature heating and oxidizing combustion or carbonization at 620 ° C. using manure as an evaporation object. As can be seen from the following results, the evaporation object using the present invention can be remarkably purified.

상술한 바와 같이 본 발명은 특히 시스템 구성을 위한 장치 및 설비운용 비용이 재래식에 비해 현저히 저렴한 가격으로 공급될 수 있는 경제적 장점과 높은 성능을 확보할 수 있기 때문에 양질의 증류수를 싼값으로 생산할 수 있음은 물론 유독성 폐수나 환경오염 폐수의 증발건조, 각종 폐(廢)슬러지(sludge)의 증발, 농축건조 및 종말처리를 위해 폭넓게 사용될 수 있는 특장점이 있다. 또한 폐수내의 B.O.D., C.O.D. 등의 불순물 및 악취의 제거를 위해 고온으로 가열하는 가열수단에서 요구되는 많은 연료비용은 가열증기 열교환 회수장치(60)에 의해 증기예열 에너지로 재사용할 수 있기 때문에 증기 가열 연료비용을 절감시킬 수 있는 장점이 있다.As described above, the present invention can produce high-quality distilled water at a low price, because it can secure economic advantages and high performance, which can be supplied at a significantly lower price than a conventional device and equipment operation cost. Of course, there are features that can be widely used for the evaporative drying of toxic wastewater or environmental pollution wastewater, the evaporation of various waste sludges, the concentrated drying and the end treatment. In addition, B.O.D., C.O.D. Many fuel costs required by heating means for heating to a high temperature for the removal of impurities such as odors and the like can be reused as steam preheating energy by the heating steam heat exchange recovery device 60, thereby reducing the steam heating fuel cost. There is an advantage.

이상과 같이 작용되는 증기 정화(蒸氣 淨化) 능력을 가진 증발(蒸發) 및 증발농축건조(蒸發濃縮乾燥)장치와 방법은 필요한 경우 감압 또는 가압상태의 다양한 증발장치와 가열수단과 열교환 수단들을 동원하여 적정한 설계변경으로 대응 적용시킬 수 있는 것으로 본 발명의 요지에 속한 것이며, 동일분야의 통상의 기술자들이 명확하게 이해할 수 있다고 사료된다.The evaporation and evaporation concentration drying apparatus and method having the above-described vapor purification ability can be mobilized by using various evaporators, heating means and heat exchange means under reduced pressure or pressure, if necessary. Applicable to appropriate design changes to belong to the gist of the present invention, it is believed that those skilled in the art can clearly understand.

Claims (3)

응축수 폐열 회수를 위해 상부에 증발 대상물 투입구(15a)를 갖고, 일단이 응축수 저장탱크(50)와 연결되어 있는 코일형 튜브(R)가 내설되어 이중으로 형성되어 있는 증발물 저장탱크(1) ; 열교환에 의해 기화열을 회수하기 위해 상부에 투입구(15b)를 갖고 하부가 원형단면으로 형성되며 일측에 함몰부(11)를 형성하여 찌꺼기 배출용 스크류(11s)를 내설하고, 스팀챔버(14)와 연통되어 있는 다수의 판상 반원형태의 패널형 스팀챔버(13)들이 일정한 간격으로 수직으로 내설되고, 상기 패널형 스팀챔버(13)와 챔버(13)사이를 회전하면서 교반할 수 있는 다수의 교반날개(12)들이 길이에 따라 중앙을 관통하도록 장치된 축(S)에 부착되어 정,역회전하면서 교반기능을 수행하며, 하부의 패널형 스팀챔버(13)는 압력조절 레귤레이터(51) 및 드레인밸브(52)가 부설되어 있는 관로(R7)에 의해 상기 코일형 튜브(R)와 연결되며, 상부 일측에는 연결관(16)이 인출되어 하부에 U형 트랩(18)이 인출된 오버플로방지용 챔버(17)와 연통되어 있으며, 측면 상부에는 상기 증발대상물 저장탱크(1) 하부로부터 증발대상물을 흡인하기 위해 관로(R8)가 인출되어 있는 교반형 증발 및 증발농축건조기(10) ; 보조보일러(40)내의 가열수단에 의해 가열된 증기열을 회수하기 위해 다수의 증발 스팀관로(R9)가 수평으로 내설되고 열교환 능력을 향상시키기 위해 다수의 격판들이 일정한 간격으로 수직으로 부설되어 있으며, 일단에는 관로(R3)가 상기 증발농축건조기(10)와 연결하기 위해 인출되어 있으며, 타단에는 일측에 버너(41)가 부착되어 있는 보조보일러(40)내의 코일형 증기가열튜브(42) 및 증기가열챔버(43)와 연결하기 위해 관로(R4)가 인출되어 있고, 하부 일측에는 상기 증발농축건조기(10)내의 패널형 스팀챔버(13) 및 스팀챔버(14)와 연결하기 위해 관로(R6)가 인출되어 있으며 다른 하부 일측에는 보조보일러(40)내의 코일형 증기가열튜브(42) 및 증기가열챔버(43)와 연결하기 위해 관로(R5)가 인출되어 있는 가열증기 열교환 회수장치(60)와, 초기 가동시에 가열증기를 상기 열교환 회수장치(60)로 배출하기 위해 관로(R10)가 인출되어 관로(R3)와 연결되어 있으며 측면에 버너(41)가 부착되고 코일형 증기가 열튜브(42)와 증기가열챔버(43)가 내설되어 있으며, 가열증기 열교환 회수장치(60)에 의해 예열된 증기가 유입되는 관로(R4)가 인출되어 있고 가열수단에 의해 증기를 고온 가열하여 연소 또는 탄화된 상태로 배출되기 위해 관로(R5)가 인출되어 있는 보조보일러(40) ; 및 상기 증발농축건조기(10)와 연결하기 위해 가열증기 열교환 회수장치(60)로부터 인출된 관로(R3)와 상기 증발농축건조기(10) 상부로부터 인출된 연결관(16) 사이에는 오버플로방지용 챔버(17), 관로(R1), 예열공기 공급 조절밸브(21), 상기 증발농축건조기(10)에서 증발한 증기를 압축하여 증기압을 높여주기 위한 증기압축터빈(20) 및 관로(R2)에 의해 연결된 증기압축펌프(30)가 부재되어 있는 것을 특징으로 하는 증기 정화능력을 가진 증발 및 증발농축건조장치.An evaporation storage tank (1) having an evaporation object inlet (15a) at the top for recovering condensate waste heat and having a coil-shaped tube (R) connected at one end thereof to the condensate storage tank (50); In order to recover the heat of vaporization by heat exchange, the upper part has an inlet 15b, the lower part is formed in a circular cross section, and the recess 11 is formed on one side to impart a waste discharge screw 11s, and the steam chamber 14 and A plurality of plate-shaped semicircular panel-type steam chambers 13 communicated vertically at regular intervals, and a plurality of stirring vanes capable of stirring while rotating between the panel-type steam chambers 13 and the chambers 13. (12) are attached to the shaft (S) is installed to penetrate the center along the length and performs the stirring function while rotating forward and reverse, the lower panel type steam chamber 13 is the pressure regulating regulator 51 and the drain valve (52) is connected to the coiled tube (R) by a pipe line (R 7 ), the upper side is connected to the tube 16 is drawn out to prevent the overflow of the U-shaped trap 18 is drawn out at the bottom It is in communication with the chamber 17, the upper portion of the side An agitated evaporation and evaporation concentration dryer 10 in which a pipe line R 8 is drawn out to suck an evaporation object from the lower part of the object storage tank 1; In order to recover the heat of steam heated by the heating means in the sub-boiler 40, a plurality of evaporative steam pipe (R 9 ) is horizontally installed and a plurality of diaphragms are vertically laid at regular intervals to improve heat exchange capacity. At one end, a pipe (R 3 ) is drawn out to connect with the evaporative concentration dryer (10), and at the other end, a coil type steam heating tube (42) in the auxiliary boiler (40) having a burner (41) attached to one side. And a pipe line R 4 is drawn out to connect with the steam heating chamber 43, and a lower part of the pipe line R 4 is connected to the panel-type steam chamber 13 and the steam chamber 14 in the evaporative concentration dryer 10. (R 6 ) is drawn out and heat steam heat exchange recovery with the pipe (R 5 ) drawn out to connect to the coil-type steam heating tube 42 and the steam heating chamber 43 in the auxiliary boiler 40 on the other lower side At the time of initial operation with apparatus 60 In order to discharge the heated steam to the heat exchange recovery device 60, a pipe line R 10 is drawn out and connected to the pipe line R 3 , and a burner 41 is attached to the side, and the coil-type steam is connected to the heat tube 42. The steam heating chamber 43 is internally installed, and the pipeline R 4 through which the steam preheated by the heated steam heat exchange recovery device 60 is drawn out, and the steam is heated or heated by a heating means to burn or carbonize it. An auxiliary boiler 40 in which a conduit R 5 is drawn out to be discharged to the furnace; And between the pipe line R 3 drawn from the heated steam heat exchange recovery device 60 and the connection pipe 16 drawn from the top of the evaporation concentration dryer 10 to connect with the evaporation concentration dryer 10. Chamber 17, conduit (R 1 ), preheating air supply control valve 21, steam compression turbine 20 and the conduit (R 2 ) for increasing the vapor pressure by compressing the vapor evaporated in the evaporative condensation dryer (10) Evaporation and evaporation and drying apparatus having a steam purification capability, characterized in that the absence of a steam compression pump (30) connected by. 제1항에 있어서, 상기 증발농축건조기(10)내에서 길이를 따라 중앙을 관통하는 축(S)상에 부설되어 있는 교반날개(12)가 원할하게 작동하기 위하여 상광하협으로 형성되어 있는 패널형 스팀챔버(13)로 구성되는 것을 특징으로 하는 증기 정화능력을 가진 증발 및 증발농축건조장치.The panel type according to claim 1, wherein the stirring blades 12 placed on the shaft S passing through the center along the length in the evaporation dryer 10 are formed in the upper and lower straits to smoothly operate. Evaporation and evaporation concentrated drying apparatus having a steam purification capability, characterized in that consisting of a steam chamber (13). 초기 가동시에 가열수단에 의해 보조보일러(40)내의 물을 가열하여 생산된 증기를 관로(R10)와 관로(R3)를 통해 상기 열교환 회수장치(60)내의 증발스팀관로(R9)를 거쳐 증기가열튜브(42) 및 증기가열챔버(43)내에서 고온가열수단에 의해 산화연소 또는 탄화되어, 다시 열교환 회수장치(60)내를 역방향으로 진행하여 상기 증발농축건조기(10)내의 패널형 스팀챔버(13) 및 스팀챔버(14)로 투입하여 증발대상물과 열교환이 이루어지고, 압력조절 레귤레이터(51) 및 드레인밸브(52)가 부재되어 있는 관로(R7)에 통해 증발대상물 저장탱크(1)에 내설되어 있는 코일형 튜브(R)로 보내어 폐열이 회수되는 단계 ; 증기압축터빈(20)과 증기압축펌프(30)에 의해 교반형 증발 및 증발농축건조기(10)의 내부를 감압 또는 가압함으로써 증발대상물 저장탱크(1)안에 증발 대상물이 관로(R8)를 통해 흡인되어, 관로(R6)를 통해 패널형 스팀챔버(13) 및 스팀챔버(14)내로 유입된 150℃∼200℃의 탄화된 증기와 열교환하여 60℃∼100℃의 증기로 연결관(16)을 통해 배출되고, 상기 증발농축건조기(10)에 내설된 교반날개(12)의 정.역회전에 의해 처리 대상물이 고르게 혼합되고 최종 슬러지는 압출스크류(11s)에 의해 상기 증발농축건조기(10)밖으로 토출하기 위해 함몰부(11)로 슬러지를 이동시키는 단계 ; 상기 증발농축건조기(10) 상부에 인출되어 있는 연결관(16)으로 배출된 60℃∼100℃의 증기중에 함유된 액체등의 오버플로된 것은 오버플로방지용 챔버(17)를 거쳐 하부의 U형 트랩(18)을 통해 다시 증발농축건조기(10)내로 유입되고, 상기 연결관(16)에 연통되어 있는 관로(R1)를 통해 유동하는 60℃∼100℃의 증기는 예열공기 공기 조절밸브(21)를 통해 예열공기와 혼합되어(증발대상물의 성질에 따라 예열공기를 혼합시키지 않을 수도 있음), 증기압축터빈(20), 관로(R2), 증기압축펌프(30) 및 관로(R3)을 통해 가열증기 열교환 회수장치(60)내의 다수의 증발스팀관로(R9)내로 유입되는 단계 ; 상기 증발스팀관로(R9)로 유입된 60℃∼100℃의 증기는 보조보일러(40)에 내설되어 있는 버너(41), 코일형 증기가열튜브(42) 및 증기가열챔버(43)에 의해 고온가열되어 관로(R5)를 통해 상기 열교환 회수장치(60)내부로 유입되어, 일정한 간격으로 수직으로 배열되어 있는 다수의 격판에 의해 유도되어 지그재그식으로 유동하는 600℃∼800℃의 고온증기와 서로 역방향으로 유동하며 열교환이 이루어져서, 600℃∼800℃의 증기는 150∼200℃로 하강하여 관로(R5)를 통해 배출되어 증발 및 증발농축건조기(10)내의 패널형 스팀쳄버(13) 및 스팀챔버(14)내로 유입되고, 60℃∼100℃의 증기는 450℃∼600℃로 예열되어 관로(R4)를 통해 보조보일러(40)에 내설되어 있는 코일형 증기가열튜브(42) 및 증기가열챔버(43)내로 유입되는 단계; 및 상기 열교환 회수장치(60)에 의해 450℃~600℃로 예열된 증기는 관로(R4)를 통해 보조보일러(40)에 내설되어 있는 코일형 증기가열튜브(42) 및 증기가열챔버(43)를 거치면서 버너(41)에 의해 재가열되어 악취 및 B.O.D., C.O.D. 등의 불순물들이 산화연소 또는 탄화되어 제거된 600℃∼800℃의 고온증기로 관로(R5)를 통해 가열증기 열교환 회수장치(60)내로 유입되어 증발 스팀관로(R9)내의 60℃∼100℃의 증기와 역방향으로 유동하며 열교환되어 150℃∼200℃로 하강하여 관로(R6)를 통해 배출되어 증발농축건조기(10)내의 패널형 스팀챔버(13) 및 스팀챔버(14)내로 유입되어 다시 상기 증발농축건조기(10)내의 증발대상물과 열교환하여 액화하는 과정에서 잠열(539kcal/ℓ)을 증발에너지로 빼앗기어 80℃∼120℃로 액화된 물은 압력조절용 레귤레이터(51)와 드레인밸브(52)를 거쳐 증발대상물 저장탱크(1)내의 코일형 튜브(R)를 지나면서 증발대상물과 2차로 열교환되어 폐열을 빼앗긴 상태에서 응축수 저장탱크(50)에 저장시키는 단계를 특징으로 하는 증기 정화능력을 가진 증발 및 증발농축건조방법.Evaporation steam pipe (R 9 ) in the heat exchange recovery device (60) through the pipe (R 10 ) and pipe (R 3 ) produced steam by heating the water in the auxiliary boiler 40 by the heating means at the initial operation. Oxidative combustion or carbonization in the steam heating tube 42 and the steam heating chamber 43 by means of a high temperature heating means is carried out again in the heat exchange recovery apparatus 60 to reverse the panel in the evaporative concentration dryer 10. The evaporation object storage tank is introduced into the type steam chamber 13 and the steam chamber 14 by heat exchange with the evaporation object, and is provided through a pipe line R 7 having no pressure regulating regulator 51 and a drain valve 52. Sending to the coil-shaped tube (R) built in (1) to recover the waste heat; By evaporating or depressurizing the inside of the stirring type evaporation and evaporation concentration dryer 10 by the vapor compression turbine 20 and the vapor compression pump 30, the evaporation object is stored in the evaporation object storage tank 1 through a conduit R 8 . Aspirated, heat exchanged with the carbonized steam of 150 ° C. to 200 ° C. introduced into the panel-type steam chamber 13 and the steam chamber 14 through the conduit R 6 , and the connection pipe 16 to the steam of 60 ° C. to 100 ° C. The discharged through the), the object to be treated is uniformly mixed by the forward and reverse rotation of the stirring blade 12 in the evaporation concentration dryer 10 and the final sludge is the evaporation concentration dryer (10s) by the extrusion screw (11s). Moving the sludge to the depression 11 to discharge it outward; The overflowed liquid, such as a liquid contained in the vapor at 60 ° C. to 100 ° C. discharged to the connection pipe 16 drawn out on the evaporation condenser 10, is U-shaped at the bottom through the overflow prevention chamber 17. The steam of 60 ° C. to 100 ° C. flowing into the evaporation dryer 10 again through the trap 18 and flowing through the pipe line R1 connected to the connecting pipe 16 is preheated air air control valve 21. ) Is mixed with preheated air (may not mix preheated air depending on the nature of the evaporation object), steam compression turbine 20, pipeline (R 2 ), steam compression pump (30) and pipeline (R 3 ) Flowing through the plurality of evaporation steam pipes (R9) in the heated steam heat exchange recovery device (60) through; The steam of 60 ° C. to 100 ° C. introduced into the evaporation steam pipe line R 9 is provided by the burner 41, the coil type steam heating tube 42, and the steam heating chamber 43 which are installed in the auxiliary boiler 40. High temperature heating is introduced into the heat exchange recovery device 60 through the pipe line (R 5 ), 600 ℃ ~ 800 ℃ high temperature steam flowing in a zigzag flow guided by a plurality of diaphragms arranged vertically at regular intervals And the heat exchange is performed in a reverse direction to each other, the steam of 600 ℃ ~ 800 ℃ is lowered to 150 ~ 200 ℃ discharged through the pipe line (R 5 ) to evaporate and evaporation concentrated dryer 10 in the panel-type steam chamber (13) And a coil type steam heating tube 42 which is introduced into the steam chamber 14 and the steam having a temperature of 60 ° C. to 100 ° C. is preheated to 450 ° C. to 600 ° C. and installed in the auxiliary boiler 40 through a conduit R 4 . And flowing into the steam heating chamber 43; And the steam preheated to 450 ℃ ~ 600 ℃ by the heat exchange recovery device 60 is the coil-type steam heating tube 42 and the steam heating chamber 43 which is installed in the auxiliary boiler 40 through the conduit (R 4 ). Heat steam heat exchange recovery unit through the pipe line (R 5 ) to a high temperature steam of 600 ℃ ~ 800 ℃ is reheated by the burner 41 and the odor and impurities such as BOD, COD are removed by oxidative combustion or carbonization 60) flows in the reverse direction with the steam of 60 ℃ ~ 100 ℃ in the evaporation steam pipe (R 9 ) and heat exchanged and descended to 150 ℃ ~ 200 ℃ discharged through the pipe (R 6 ) evaporation condensation dryer (10) The latent heat (539 kcal / l) is taken into the evaporation energy in the process of liquefying heat by entering into the panel-type steam chamber 13 and the steam chamber 14 in the panel-type heat exchanger 10 again. The water liquefied at 120 ° C regulates the pressure regulating regulator (51) and the drain valve (52). Evaporation with the steam purification capability, characterized in that the second heat exchange with the evaporation object while passing through the coiled tube (R) in the evaporation object storage tank (1) and storing the waste heat in the condensate storage tank (50) And evaporative concentration drying method.
KR1019940026474A 1993-11-23 1994-10-17 Vaporizing and concentration drying apparatus and method KR0119766B1 (en)

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KR1019940026474A KR0119766B1 (en) 1993-11-23 1994-10-17 Vaporizing and concentration drying apparatus and method
JP7514966A JPH09507036A (en) 1993-11-23 1994-11-17 Evaporative concentrating and drying apparatus and method having vapor purification capability
RU96113053A RU2145573C1 (en) 1993-11-23 1994-11-17 Method and apparatus for vaporization and concentration drying
AU11218/95A AU690172B2 (en) 1993-11-23 1994-11-17 Vaporizing and concentration drying apparatus and method
PCT/KR1994/000167 WO1995014640A1 (en) 1993-11-23 1994-11-17 Vaporizing and concentration drying apparatus and method
BR9408150A BR9408150A (en) 1993-11-23 1994-11-17 Apparatus and process of vaporization and drying by concentration
EP95902312A EP0730561A1 (en) 1993-11-23 1994-11-17 Vaporizing and concentration drying apparatus and method
CA002177161A CA2177161C (en) 1993-11-23 1994-11-17 Vaporizing and concentration drying apparatus and method
CN94194698A CN1097559C (en) 1993-11-23 1994-11-17 Vaporizing and concentration drying apparatus and method
US08/344,984 US5548906A (en) 1994-10-17 1994-11-25 Vaporizing and concentration drying apparatus and method

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KR93-25019 1993-11-23
KR1019940026474A KR0119766B1 (en) 1993-11-23 1994-10-17 Vaporizing and concentration drying apparatus and method

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CN105819528A (en) * 2014-10-24 2016-08-03 吴昊 Paper mill wastewater distillation and heat recovery system for recycling papermaking additives
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CN109734249A (en) * 2019-02-22 2019-05-10 江苏和顺环保有限公司 A kind of heavy-metal waste water treatment device
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CN110465107B (en) * 2019-08-07 2023-12-22 浙江宣达环境科技股份有限公司 Concentrating device and method for sulfuric acid process titanium white liquid
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