KR0119287B1 - Manufacturing method of positive electrode material for lithium secondary battery - Google Patents
Manufacturing method of positive electrode material for lithium secondary batteryInfo
- Publication number
- KR0119287B1 KR0119287B1 KR1019940032656A KR19940032656A KR0119287B1 KR 0119287 B1 KR0119287 B1 KR 0119287B1 KR 1019940032656 A KR1019940032656 A KR 1019940032656A KR 19940032656 A KR19940032656 A KR 19940032656A KR 0119287 B1 KR0119287 B1 KR 0119287B1
- Authority
- KR
- South Korea
- Prior art keywords
- acid
- sol
- lithium secondary
- secondary battery
- lico
- Prior art date
Links
- 229910052744 lithium Inorganic materials 0.000 title claims abstract description 11
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 title claims abstract description 10
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 9
- 239000007774 positive electrode material Substances 0.000 title claims description 4
- 150000001875 compounds Chemical class 0.000 claims abstract description 23
- 238000003980 solgel method Methods 0.000 claims abstract description 18
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims abstract description 15
- 238000000034 method Methods 0.000 claims abstract description 11
- 150000007524 organic acids Chemical class 0.000 claims abstract description 11
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 claims abstract description 9
- BJEPYKJPYRNKOW-REOHCLBHSA-N (S)-malic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O BJEPYKJPYRNKOW-REOHCLBHSA-N 0.000 claims abstract description 5
- KRKNYBCHXYNGOX-UHFFFAOYSA-K Citrate Chemical compound [O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O KRKNYBCHXYNGOX-UHFFFAOYSA-K 0.000 claims abstract description 5
- BJEPYKJPYRNKOW-UHFFFAOYSA-N alpha-hydroxysuccinic acid Natural products OC(=O)C(O)CC(O)=O BJEPYKJPYRNKOW-UHFFFAOYSA-N 0.000 claims abstract description 5
- 239000001630 malic acid Substances 0.000 claims abstract description 5
- 235000011090 malic acid Nutrition 0.000 claims abstract description 5
- 239000000463 material Substances 0.000 claims abstract description 4
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 claims abstract description 3
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 claims abstract description 3
- 239000002253 acid Substances 0.000 claims abstract description 3
- 235000006408 oxalic acid Nutrition 0.000 claims abstract description 3
- 239000011975 tartaric acid Substances 0.000 claims abstract description 3
- 235000002906 tartaric acid Nutrition 0.000 claims abstract description 3
- 229910013733 LiCo Inorganic materials 0.000 claims description 17
- 229910012851 LiCoO 2 Inorganic materials 0.000 claims description 15
- 125000002524 organometallic group Chemical group 0.000 claims description 4
- 239000002243 precursor Substances 0.000 claims description 3
- 239000002904 solvent Substances 0.000 claims description 3
- 150000004696 coordination complex Chemical class 0.000 claims description 2
- 239000011368 organic material Substances 0.000 claims description 2
- 239000010406 cathode material Substances 0.000 claims 4
- 238000002360 preparation method Methods 0.000 claims 1
- 230000004913 activation Effects 0.000 abstract 2
- 229910032387 LiCoO2 Inorganic materials 0.000 abstract 1
- 238000003836 solid-state method Methods 0.000 description 6
- 238000002441 X-ray diffraction Methods 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- OIFBSDVPJOWBCH-UHFFFAOYSA-N Diethyl carbonate Chemical compound CCOC(=O)OCC OIFBSDVPJOWBCH-UHFFFAOYSA-N 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 238000000975 co-precipitation Methods 0.000 description 2
- 150000002500 ions Chemical class 0.000 description 2
- 239000007791 liquid phase Substances 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- RUOJZAUFBMNUDX-UHFFFAOYSA-N propylene carbonate Chemical compound CC1COC(=O)O1 RUOJZAUFBMNUDX-UHFFFAOYSA-N 0.000 description 2
- KDYFGRWQOYBRFD-UHFFFAOYSA-L succinate(2-) Chemical compound [O-]C(=O)CCC([O-])=O KDYFGRWQOYBRFD-UHFFFAOYSA-L 0.000 description 2
- KDYFGRWQOYBRFD-UHFFFAOYSA-N succinic acid Chemical compound OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 2
- 238000003786 synthesis reaction Methods 0.000 description 2
- 229910013075 LiBF Inorganic materials 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 239000006182 cathode active material Substances 0.000 description 1
- 150000001860 citric acid derivatives Chemical class 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 239000012153 distilled water Substances 0.000 description 1
- 239000003792 electrolyte Substances 0.000 description 1
- 238000009830 intercalation Methods 0.000 description 1
- 230000002687 intercalation Effects 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000010532 solid phase synthesis reaction Methods 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 239000001384 succinic acid Substances 0.000 description 1
- 238000001308 synthesis method Methods 0.000 description 1
- 230000002194 synthesizing effect Effects 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G51/00—Compounds of cobalt
- C01G51/40—Complex oxides containing cobalt and at least one other metal element
- C01G51/42—Complex oxides containing cobalt and at least one other metal element containing alkali metals, e.g. LiCoO2
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G51/00—Compounds of cobalt
- C01G51/80—Compounds containing cobalt, with or without oxygen or hydrogen, and containing one or more other elements
- C01G51/82—Compounds containing cobalt, with or without oxygen or hydrogen, and containing two or more other elements
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/052—Li-accumulators
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
- H01M4/52—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron
- H01M4/525—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron of mixed oxides or hydroxides containing iron, cobalt or nickel for inserting or intercalating light metals, e.g. LiNiO2, LiCoO2 or LiCoOxFy
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Battery Electrode And Active Subsutance (AREA)
- Inorganic Compounds Of Heavy Metals (AREA)
Abstract
Description
제1도는 LiCoO2화합물의 구조를 나타낸 도면.1 is a diagram showing the structure of a LiCoO 2 compound.
제2도는 우기산을 이용한 졸-겔법에 의해 LiCoO2와 LiCoyNi1-yO2을 제조하는 방법에 관한 도식.2 is a schematic of a method for producing LiCoO 2 and LiCo y Ni 1-y O 2 by a sol-gel method using an organic acid.
제3도는 유기산을 이용한 졸-겔법과 고온고상법에 의해 제조한LiCoyNi1-yO2(y=0.3)의 X-선 회절분석피크 비교도.3 is a comparison of X-ray diffraction peaks of LiCo y Ni 1-y O 2 (y = 0.3) prepared by a sol-gel method using an organic acid and a high temperature solid state method.
제4도는 유기산을 이용한 졸-겔법에 의해 제조한 LiCoO2와 LiCoyNi1-yO2(0y1) 화합물의 I101/I3비교도.4 is a comparison of I 101 / I 3 between LiCoO 2 and LiCo y Ni 1-y O 2 (0y1) compounds prepared by a sol-gel method using an organic acid.
제5도는 유기산을 이용한 졸-겔법에 의해 제조한 LiCoyNi1-yO2(y=0.3) 화합물의 1차 충반전 곡선.5 is a primary charge and inversion curve of the LiCo y Ni 1-y O 2 (y = 0.3) compound prepared by the sol-gel method using an organic acid.
본 발명은 리튬 이차전지의 개선에 관계된 것으로, 특히 양극 활성물질인 LiCoO2와 LiCoyNi1-yO2화합물의 개선에 관한 것이다.The present invention relates to the improvement of a lithium secondary battery, and more particularly, to the improvement of LiCoO 2 and LiCo y Ni 1-y O 2 compounds which are positive electrode active materials.
LiCoO2와 LiCoyNi1-yO2화합물의 이상적인 구조는 제1도에 나타낸 것과 같이 Li이 온과 Co(또는 Ni)이온이 완벽한 질서화 배열을 하고 있는 것이다. 그러나 Li층에 Co(또는 Ni)이온이 들어가게 되면 이차원적구조가 삼차원적 구조로 바뀌어 전극특성을 떨어뜨리게 되며, 이는 X-선 회절분석 패턴에서 (003) 피크의 상대 세기가 감소하는 것으로 부터 쉽게 확인할 수 있다.The ideal structure of LiCoO 2 and LiCo y Ni 1-y O 2 compounds is that Li and Co (or Ni) ions are in perfect ordered arrangement as shown in FIG. However, when the Co (or Ni) ion enters the Li layer, the two-dimensional structure is changed to a three-dimensional structure, which degrades the electrode characteristics, which is easy from the decrease of the relative intensity of the (003) peak in the X-ray diffraction pattern. You can check it.
상기 LiCoO2와 LiCoyNi1-yO2같은금속 산화물을 합성하는 방법에는 고온 고상법과 액상에 의한 방법이 있다.The method of synthesizing a metal oxide such as LiCoO 2 and LiCo y Ni 1-y O 2 includes a high temperature solid state method and a liquid phase method.
액상에 의한 합성법에는 공침법과 졸-겔(Sol-Gel)법이 있는데, 공침법의 경우 합성하고자하는 화합물이 공침되는 pH영역이 있어야 가능하지만, 졸-겔법은 출발물질이 모두 용해되는 용해되는 용매와 이를 겔화시켜줄 수 있는 첨가제(예를들면, 구연산(citric acid), 호박산(succnic acid), 사과산(malic acid), 수산(oxalic acid), 주석산(tartaric acid)등과 같은 유기산)만 있으면 가능하고 미세한 분말을 얻을 수 있으므로 초미세 분말재료의 합성에 많이 이용되고 있다.There are coprecipitation method and sol-gel method in the liquid phase synthesis method. In the case of the coprecipitation method, it is possible to have a pH range in which the compound to be synthesized is coprecipitated, but the sol-gel method dissolves all of the starting materials. All you need is a solvent and an additive that can gel it (for example, citric acid, succnic acid, malic acid, malic acid, oxalic acid, tartaric acid, etc.). Since fine powders can be obtained, they are widely used for the synthesis of ultrafine powder materials.
이러한 졸-겔법을 이용하여 리튬 이차전지의 양극 활성물질인 LiCoO2와 LiCoyNi1-yO2화합물을 합성하면 기존의 고온 고상법에 의해 합성한 것보다 이차원적 구조가 잘 발달되고, 입자크기도 작은 화합물을 합성할 수 있어서 전극 특성이 개선된다.Synthesis of LiCoO 2 and LiCo y Ni 1-y O 2 compounds, which are positive electrode active materials of lithium secondary batteries, using the sol-gel method results in better two-dimensional structures than those synthesized by conventional high-temperature solid-state methods. Smaller compounds can be synthesized to improve electrode properties.
따라서, 본 발명은 유기산을 이용한 졸-겔법에 의해서 리튬이차전지의 양극활성물질인 LiCoO2와 LiCoyNi1-yO2(0y1)화합물을 제조하는 새로운 방법을 제안한다.Accordingly, the present invention proposes a new method for preparing LiCoO 2 and LiCo y Ni 1-y O 2 (0y1) compounds which are cathode active materials of a lithium secondary battery by a sol-gel method using an organic acid.
구연산과 호박산(succinic acid)을 이용한 졸-겔법에 의해서 LiCoO2와 LiCoyNi1-yO2(0y1)를 제조하는 과정은 아래와 같다.The process for preparing LiCoO 2 and LiCo y Ni 1-y O 2 (0y1) by sol-gel method using citric acid and succinic acid is as follows.
LiCoO2는 LiCO3, Co(NO3)2·6H2O, C6H8O7(또는 C4H6O4)을 1:1:2의 몰비로 섞고, LICoyNi1-yO2(0y1)의 경우에는 Li2CO3, Co(NO3)2·6H2O, Ni(NO3)2· 6H2O, C6H8O7(또는 C4H6O4)을 1:y:(1-y):3의 몰비로 섞은 후 증류수에 녹여 용액을 만든다.LiCoO 2 is a mixture of LiCO 3 , Co (NO 3 ) 2 · 6H 2 O, C 6 H 8 O 7 (or C 4 H 6 O 4 ) in a molar ratio of 1: 1: 2, LICo y Ni 1-y O In the case of 2 (0y1), Li 2 CO 3 , Co (NO 3 ) 2 · 6H 2 O, Ni (NO 3 ) 2 , 6H 2 O, C 6 H 8 O 7 (or C 4 H 6 O 4 ) Mix in a molar ratio of 1: y: (1-y): 3 and dissolve in distilled water to form a solution.
이용액을 aq. NH4OH를 사용하여 pH3~4로 조절하면 구연산염 졸(citrate sol)(또는 호박산염 졸(succinate sol))이 된다.AQ. PH using NH 4 OH Adjusting to 3-4 results in a citrate sol (or succinate sol).
이 구연산염 졸(또는 호박산염 졸)을 진공하(10~20mmHg)에서 80~95℃의 온도로 18~20시간 가열하면 용매가 증발되어 구연산염 졸은 겔화를 거쳐 고체상의 유기금속착물이 된다.When this citrate sol (or succinate sol) is heated under vacuum (10-20 mmHg) to a temperature of 80-95 ° C. for 18-20 hours, the solvent is evaporated, and the citrate sol is gelled to form a solid organic metal complex.
이 유기금속착물을 300~350℃에서 3~4시간 가열하여 유기물을 분해하여 LiCoO2와 LiCoyNi1-yO2을(0y1) 화합물의 전구물질(precursor)을 얻는다.The organometallic complex is heated at 300 to 350 ° C. for 3 to 4 hours to decompose the organic material to obtain precursors of the compounds LiCoO 2 and LiCo y Ni 1-y O 2 (0y1).
이 전구물질을 600~650℃에서 6시간 하소한 후 840~860℃에서 20시간 어닐링하여 LiCoO2와 LiCoyNi1-yO2을(0y1) 화합물을 얻는다.This precursor was calcined at 600-650 ° C. for 6 hours and then annealed at 840-860 ° C. for 20 hours to obtain LiCoO 2 and LiCo y Ni 1-y O 2 (0y1).
제2도에서는 상기 제조방법을 도식화하여 놓았다.In FIG. 2, the manufacturing method is illustrated.
제3도에는 상기 졸-겔법에 의해서 합성한 화합물들과 고온 고상법에 의해서 합성한LiCoyNi1-yO20(y=0.3) 화합물의 X-선 회절분석 패턴을 비교하여 나타내었다.3 shows the X-ray diffraction patterns of the compounds synthesized by the sol-gel method and the LiCo y Ni 1-y O 2 0 (y = 0.3) compound synthesized by the high temperature solid state method.
상기 도면에서 보듯이 졸-겔법에 의해서 합성한 화합물의 (003) 피크의 상대 세기가 고온 고상법으로 합성한 화합물의 (003) 피크의 상대 세기가 고온 고상법으로 합성한 화합물의 (003)피크의 상대 세기보다큼을 알 수가 있는데, 이는 상기한 바와 같이 졸-겔법에 의해 합성한 화합물이 고온 고상법으로 합성한 혼합물보다 층상구조가 잘 발달되었음을 의미하며, 제4도에 유기산을 이용한 졸-겔법과 고온 고상법에 의해 제조한 LiCoO2와 LiCoyNi1-yO2(0y1) 화합물들의 I101/I003비를 비교 요약해 놓았다.As shown in the drawings, the relative intensity of the (003) peak of the compound synthesized by the sol-gel method is the peak of the compound synthesized by the high temperature solid state method. It can be seen that the relative strength of is greater than that, which means that the compound synthesized by the sol-gel method is better developed than the mixture synthesized by the high temperature solid state method as described above, and the sol-gel method using the organic acid in FIG. The I 101 / I 003 ratios of LiCoO 2 and LiCo y Ni 1-y O 2 (0y1) compounds prepared by the high temperature solid phase method are summarized.
상기한 바와 같이 졸-겔법에 의해 합성한 화합물에 대해서 전극 특성을 알아보기 위해서 양극은 상기 화합물, 음극은 Li 금속을 전해질은 PC(propylene carbonate)+DEC(diethyl carbonate)에 LiBF6를 1M녹인 용액을 사용하여 Cell을 구성하고, 전류밀도 200μA/cm2의 전류를 흘려주면서 충방전 특성을 측정하였다.As described above, in order to examine the electrode characteristics of the compound synthesized by the sol-gel method, a solution in which 1 M of LiBF 6 was dissolved in PC (propylene carbonate) + DEC (diethyl carbonate) in the anode was the compound, the cathode was Li metal, and the electrolyte was Cells were constructed using the same, and charging / discharging characteristics were measured while flowing a current having a current density of 200 μA / cm 2 .
제5도는 상기 졸-겔법에 의해서 합성한 LiCoyNi1-yO2(y=0.3) 화합물의 1차 충방전 곡선을 나타내었다.5 shows the primary charge and discharge curves of the LiCo y Ni 1-y O 2 (y = 0.3) compound synthesized by the sol-gel method.
제5도에서는 보듯이 상기 화합물은 3.5V 이상의 고전압을 유지하고 있으며, 첨가량(intercalation rate)의 차도 적고 전압의 평탄성도 우수함을 알수 있다.As shown in FIG. 5, the compound maintains a high voltage of 3.5V or more, and there is little difference in intercalation rate and excellent voltage flatness.
Claims (6)
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| KR1019940032656A KR0119287B1 (en) | 1994-12-03 | 1994-12-03 | Manufacturing method of positive electrode material for lithium secondary battery |
| JP7315695A JPH08264184A (en) | 1994-12-03 | 1995-12-04 | Method for manufacturing electrode material for lithium secondary battery |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| KR1019940032656A KR0119287B1 (en) | 1994-12-03 | 1994-12-03 | Manufacturing method of positive electrode material for lithium secondary battery |
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| Publication Number | Publication Date |
|---|---|
| KR960027035A KR960027035A (en) | 1996-07-22 |
| KR0119287B1 true KR0119287B1 (en) | 1997-10-04 |
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| KR1019940032656A KR0119287B1 (en) | 1994-12-03 | 1994-12-03 | Manufacturing method of positive electrode material for lithium secondary battery |
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| Country | Link |
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| JP (1) | JPH08264184A (en) |
| KR (1) | KR0119287B1 (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR100448272B1 (en) * | 2002-02-25 | 2004-09-10 | 한국지질자원연구원 | Method for recycling of spent lithium ion battery |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5914094A (en) * | 1995-12-19 | 1999-06-22 | Samsung Display Devices Co., Ltd. | Process for preparing cathode active material by a sol-gel method |
| KR100393194B1 (en) * | 1996-12-05 | 2003-11-01 | 삼성에스디아이 주식회사 | A process for preparing LixMn2O4 Powder used for cathode of lithium secondary battery |
| WO1998029914A1 (en) * | 1996-12-25 | 1998-07-09 | Mitsubishi Denki Kabushiki Kaisha | Anode active material, method for manufacturing the same, and lithium ion secondary cell using the same |
| US6383235B1 (en) | 1997-09-26 | 2002-05-07 | Mitsubishi Denki Kabushiki Kaisha | Cathode materials, process for the preparation thereof and secondary lithium ion battery using the cathode materials |
| KR100388633B1 (en) * | 2000-09-04 | 2003-06-25 | 윤원섭 | Cathode Active Material Using Sol-gel Method, Preparing Method Thereof and The Composite Cathode Using the Same |
| JP2006016257A (en) * | 2004-07-01 | 2006-01-19 | Ministry Of National Defense Chung Shan Inst Of Science & Technology | Method for producing lithium cobalt oxide powder |
| JP4979319B2 (en) * | 2005-09-29 | 2012-07-18 | Ａｇｃセイミケミカル株式会社 | Method for producing lithium-containing composite oxide |
| JP6485232B2 (en) * | 2014-11-27 | 2019-03-20 | 日立金属株式会社 | Method for producing positive electrode active material |
-
1994
- 1994-12-03 KR KR1019940032656A patent/KR0119287B1/en not_active IP Right Cessation
-
1995
- 1995-12-04 JP JP7315695A patent/JPH08264184A/en not_active Withdrawn
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR100448272B1 (en) * | 2002-02-25 | 2004-09-10 | 한국지질자원연구원 | Method for recycling of spent lithium ion battery |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH08264184A (en) | 1996-10-11 |
| KR960027035A (en) | 1996-07-22 |
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