JPWO2021192749A5 - - Google Patents

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JPWO2021192749A5
JPWO2021192749A5 JP2022509411A JP2022509411A JPWO2021192749A5 JP WO2021192749 A5 JPWO2021192749 A5 JP WO2021192749A5 JP 2022509411 A JP2022509411 A JP 2022509411A JP 2022509411 A JP2022509411 A JP 2022509411A JP WO2021192749 A5 JPWO2021192749 A5 JP WO2021192749A5
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Japan
Prior art keywords
water
liquid ink
based liquid
base material
ink
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JP2022509411A
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Japanese (ja)
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JP7197054B2 (en
JPWO2021192749A1 (en
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Priority claimed from PCT/JP2021/006029 external-priority patent/WO2021192749A1/en
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Publication of JPWO2021192749A5 publication Critical patent/JPWO2021192749A5/ja
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Description

尚、いずれの評価項目においてもC以上が実用レベルである。
上記結果より水性リキッドインキの固形分中の酸価が本発明の下限値を下回った場合、密着性、耐水性、インキ転移性、ラミネート適正は優れるものの、基材から脱離しないことが分かった。また、水性リキッドインキ中の固形分中の酸価が本発明の上限値を上回った場合、基材からの脱離性は同等以上ではあるものの、密着性、耐水性、インキ転移性、ラミネート適正が実用レベルに達しないことが分かった。
本発明の実施形態を有する水性リキッドインキを用いた実施例ではいずれの評価結果も実用レベル以上である。
以上より、本発明の水性リキッドを使用することで、従来の水性リキッドインキと同等程度の物性を有した上で、設定した脱離条件において容易に脱離するインキ塗膜をプラスチック基材上に形成することができる。
なお、実施例4~6,10~12,16~18,22~24は、それぞれ参考例1~3,4~6,7~9,10~12とする。
In addition, C or more in any evaluation item is a practical level.
From the above results, it was found that when the acid value in the solid content of the water-based liquid ink is below the lower limit of the present invention, the adhesiveness, water resistance, ink transfer property, and lamination suitability are excellent, but the ink does not detach from the substrate. . In addition, when the acid value in the solid content of the water-based liquid ink exceeds the upper limit of the present invention, the releasability from the substrate is equivalent or higher, but adhesion, water resistance, ink transfer, lamination suitability was found to be inadequate for practical use.
In the examples using the water-based liquid ink having the embodiment of the present invention, all the evaluation results are above the practical level.
From the above, by using the water-based liquid of the present invention, it is possible to form an ink coating on a plastic substrate that has physical properties equivalent to those of conventional water-based liquid inks and is easily detached under set detachment conditions. can be formed.
Examples 4 to 6, 10 to 12, 16 to 18, and 22 to 24 are referred to as Reference Examples 1 to 3, 4 to 6, 7 to 9, and 10 to 12, respectively.

Claims (11)

基材Aに対して温水又はアルカリ溶液脱離性インキ塗膜を形成するための水性リキッドインキであって、当該水性リキッドインキの固形分中の酸価が3~150mgKOH/gであり、酸性添加物及び水性媒体を含有し、前記酸性添加物が有機酸であることを特徴とする水性リキッドインキ。 A water-based liquid ink for forming a hot water or alkaline solution releasable ink coating on the base material A, wherein the acid value in the solid content of the water-based liquid ink is 3 to 150 mgKOH/g, and the water-based liquid ink is acidic. An aqueous liquid ink comprising an additive and an aqueous medium, wherein said acidic additive is an organic acid . 更に着色剤を含有する請求項に記載の水性リキッドインキ。 The water-based liquid ink according to Claim 1 , further comprising a colorant. 前記酸性添加物の酸価が3~900mgKOH/gである請求項1又は2に記載の水性リキッドインキ。 3. The aqueous liquid ink according to claim 1 , wherein the acid additive has an acid value of 3 to 900 mgKOH/g. 前記有機酸の炭素原子数が3~20である請求項1~3のいずれか一項に記載の水性リキッドインキ。 The water-based liquid ink according to any one of claims 1 to 3, wherein the organic acid has 3 to 20 carbon atoms. 前記有機酸の炭素原子数が6~18である請求項1~3のいずれか一項に記載の水性リキッドインキ。 The water-based liquid ink according to any one of claims 1 to 3, wherein the organic acid has 6 to 18 carbon atoms. 前記酸性添加物が酸性基を有する樹脂である請求項1~3のいずれか一項に記載の水性リキッドインキ。 The aqueous liquid ink according to any one of claims 1 to 3 , wherein the acidic additive is a resin having an acidic group. 前記酸性基を有する樹脂の酸価が3~300mgKOH/gである請求項に記載の水性リキッドインキ。 7. The water-based liquid ink according to claim 6 , wherein the resin having an acidic group has an acid value of 3 to 300 mgKOH/g. 請求項1~のいずれか一項に記載の水性リキッドインキを基材Aに直接又は他の層を介して印刷してなる印刷物。 A printed matter obtained by printing the water-based liquid ink according to any one of claims 1 to 7 on a substrate A directly or via another layer. 請求項8に記載の印刷物と、基材Bとインキ塗膜を内側に配置する形で積層した積層体。 A laminate obtained by laminating the printed matter according to claim 8 , the base material B, and the ink coating film on the inside. 請求項8に記載の印刷物に対して、温水又はアルカリ溶液処理によりインキ塗膜を基材Aから脱離して得られるリサイクル基材Aの製造方法。 A method for producing a recycled base material A obtained by removing the ink coating film from the base material A by treating the printed matter according to claim 8 with warm water or an alkaline solution. 請求項8に記載の印刷物と、基材Bとインキ塗膜を内側に配置する形で積層した積層体に対して、温水又はアルカリ溶液処理によりインキ塗膜とともに接着剤層及び基材Bを脱離して得られるリサイクル基材Aの製造方法。 A laminate obtained by laminating the printed matter according to claim 8, the substrate B and the ink coating film on the inside is treated with hot water or an alkaline solution to remove the adhesive layer and the substrate B together with the ink coating film. A method for producing a recycled base material A obtained separately.
JP2022509411A 2020-03-24 2021-02-18 Removable water-based ink and its desorption method Active JP7197054B2 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
JP2020052634 2020-03-24
JP2020052634 2020-03-24
PCT/JP2021/006029 WO2021192749A1 (en) 2020-03-24 2021-02-18 Detachable aqueous ink and method for detaching same

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JPWO2021192749A1 JPWO2021192749A1 (en) 2021-09-30
JPWO2021192749A5 true JPWO2021192749A5 (en) 2022-07-29
JP7197054B2 JP7197054B2 (en) 2022-12-27

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JP (1) JP7197054B2 (en)
CN (1) CN115003764B (en)
TW (1) TW202136434A (en)
WO (1) WO2021192749A1 (en)

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WO2022137914A1 (en) * 2020-12-24 2022-06-30 Dic株式会社 Organic solvent-based composition for forming detachable coating
JP7358720B1 (en) 2022-06-10 2023-10-11 東洋インキScホールディングス株式会社 Manufacturing method of recovered base material
JP7284903B1 (en) 2022-07-01 2023-06-01 東洋インキScホールディングス株式会社 Laminate separation and collection method
JP7234487B1 (en) 2022-07-01 2023-03-08 東洋インキScホールディングス株式会社 Laminate separation and collection method
JP7284904B1 (en) 2022-07-01 2023-06-01 東洋インキScホールディングス株式会社 Laminate separation and collection method
JP7168814B1 (en) 2022-07-01 2022-11-09 東洋インキScホールディングス株式会社 Laminate separation and collection method

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JP2989735B2 (en) * 1992-09-14 1999-12-13 早川ゴム株式会社 Printed thermoplastic resin product and method of printing thermoplastic resin product
JPH0834868A (en) * 1994-05-18 1996-02-06 Hayakawa Rubber Co Ltd Thermoplastic resin product having print on top of another thereon and method of printing on top of another on thermoplastic product
JP3909434B2 (en) * 2002-07-04 2007-04-25 サカタインクス株式会社 Aqueous pigment type ink jet ink composition
JP5773185B2 (en) * 2011-03-24 2015-09-02 セイコーエプソン株式会社 Ink jet recording ink, ink set, method for producing recorded matter, deinking method
JP5900070B2 (en) * 2012-03-21 2016-04-06 コニカミノルタ株式会社 Ink jet ink and ink jet recording method
JP6388131B2 (en) * 2015-12-21 2018-09-12 東洋インキScホールディングス株式会社 Water-based primer composition and printed matter
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JP6676410B2 (en) * 2016-02-26 2020-04-08 サカタインクス株式会社 Aqueous pigment type ink composition for inkjet
JP6742878B2 (en) * 2016-09-30 2020-08-19 大日本印刷株式会社 Container and manufacturing method thereof
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JP6638802B1 (en) * 2018-12-06 2020-01-29 東洋インキScホールディングス株式会社 Organic solvent-based printing inks, printed matter and laminates

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