JPWO2021175784A5 - - Google Patents
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- JPWO2021175784A5 JPWO2021175784A5 JP2022552744A JP2022552744A JPWO2021175784A5 JP WO2021175784 A5 JPWO2021175784 A5 JP WO2021175784A5 JP 2022552744 A JP2022552744 A JP 2022552744A JP 2022552744 A JP2022552744 A JP 2022552744A JP WO2021175784 A5 JPWO2021175784 A5 JP WO2021175784A5
- Authority
- JP
- Japan
- Prior art keywords
- condensate
- stripper
- vapor
- shift
- purge
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
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- 238000000034 method Methods 0.000 claims description 24
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims description 14
- 238000010926 purge Methods 0.000 claims description 13
- 230000015572 biosynthetic process Effects 0.000 claims description 8
- 238000002407 reforming Methods 0.000 claims description 8
- 238000003786 synthesis reaction Methods 0.000 claims description 8
- 229910021529 ammonia Inorganic materials 0.000 claims description 7
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 6
- 150000001412 amines Chemical class 0.000 claims description 5
- 239000004215 Carbon black (E152) Substances 0.000 claims description 4
- 229930195733 hydrocarbon Natural products 0.000 claims description 4
- 150000002430 hydrocarbons Chemical class 0.000 claims description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 4
- 239000006227 byproduct Substances 0.000 claims description 2
- 238000001816 cooling Methods 0.000 claims description 2
- 239000000446 fuel Substances 0.000 claims description 2
- 239000012535 impurity Substances 0.000 claims description 2
- 238000004519 manufacturing process Methods 0.000 claims description 2
- 238000011144 upstream manufacturing Methods 0.000 claims description 2
- 238000005406 washing Methods 0.000 claims description 2
Description
パージ凝縮物の量は、改質およびシフトセクションにおいて形成されるアミンおよびアンモニアの全部または一部を除去するように調節される。部分的に除去する場合、残留するアミンおよびアンモニアは、許容可能なレベルのアミンおよびアンモニアを、凝縮物蒸気ストリッパーからのストリッパー蒸気を介して改質セクションに入れることによって除去することができる。
なお、本願は、特許請求の範囲に記載の発明に関するものであるが、他の態様として以下も包含し得る。
1.合成ガスを製造するための方法であって、以下のステップ:
a)改質セクションにおいて炭化水素供給材料を改質し、それによってCH4、CO、CO2、H2およびH2Oと、アンモニアを含む不純物とを含む合成ガスを得るステップ;b)前記合成ガスを、1または複数のシフトステップを連続して含むシフトセクションにおいて、シフト合成ガスにシフトさせるステップ;
c)前記シフト合成ガスから、前記シフト合成ガスの冷却および任意選択的に洗浄から生じるプロセス凝縮物を分離するステップ;
d)前記プロセス凝縮物の一部を凝縮物蒸気ストリッパーに通すステップであって、前記合成ガスのシフトの間に形成されたアンモニア、メタノールおよびアミンを含む溶存シフト副生成物を蒸気を用いてプロセス凝縮物からストリッピングし、ストリッパー蒸気流をもたらすステップ、
e)プロセス凝縮物蒸気ストリッパーからの前記ストリッパー蒸気流を、前記炭化水素供給材料に、および/または前記改質セクションの下流かつ最後のシフトステップの上流で前記合成ガスに添加するステップ、
を含み、前記プロセス凝縮物の残部がパージされる、前記方法。
2.前記凝縮物蒸気ストリッパーが中圧ストリッパーである、上記1に記載の方法。
3.パージがパージ凝縮物蒸気ストリッパーに通される、上記1または2に記載の方法。
4.前記パージ凝縮物蒸気ストリッパーが低圧ストリッパーである、上記1~3のいずれか1つに記載の方法。
5.パージ凝縮物蒸気ストリッパーからの蒸気は凝縮され、非凝縮性ガスは燃料として使用される、上記3または4に記載の方法。
6.ステップ(d)からのストリッピングされた凝縮物が水処理に通される、上記1~5のいずれか1つに記載の方法。
7.パージ凝縮物蒸気ストリッパーからのストリッピングされたパージ凝縮物が水処理に通される、上記3~6のいずれか1つに記載の方法。
The amount of purge condensate is adjusted to remove all or a portion of the amine and ammonia formed in the reforming and shift sections. For partial removal, residual amine and ammonia can be removed by passing acceptable levels of amine and ammonia into the reforming section via stripper steam from a condensate steam stripper.
Note that this application relates to the invention described in the claims, but may also include the following as other aspects.
1. A method for producing synthesis gas, comprising the following steps:
a) reforming the hydrocarbon feed in a reforming section, thereby obtaining a synthesis gas comprising CH4, CO, CO2, H2 and H2O and impurities including ammonia; b) converting said synthesis gas into one or more in a shift section including a plurality of consecutive shift steps, shifting to shift syngas;
c) separating from said shifted syngas process condensate resulting from cooling and optionally washing of said shifted syngas;
d) passing a portion of the process condensate through a condensate steam stripper, the process comprising using steam to process dissolved shift byproducts including ammonia, methanol and amines formed during the syngas shift; stripping the condensate and providing a stripper vapor stream;
e) adding the stripper vapor stream from a process condensate vapor stripper to the hydrocarbon feed and/or to the synthesis gas downstream of the reforming section and upstream of the last shift step;
wherein the remainder of the process condensate is purged.
2. 2. The method of claim 1, wherein the condensate vapor stripper is a medium pressure stripper.
3. 3. A method according to claim 1 or 2, wherein the purge is passed through a purge condensate vapor stripper.
4. 4. A method according to any one of claims 1 to 3, wherein the purge condensate vapor stripper is a low pressure stripper.
5. 5. A method according to claim 3 or 4, wherein the vapor from the purge condensate vapor stripper is condensed and the non-condensable gas is used as fuel.
6. 6. A method according to any one of 1 to 5 above, wherein the stripped condensate from step (d) is passed through a water treatment.
7. A method according to any one of claims 3 to 6, wherein the stripped purge condensate from the purge condensate vapor stripper is passed to a water treatment.
Claims (7)
a)改質セクションにおいて炭化水素供給材料を改質し、それによってCH4、CO、CO2、H2およびH2Oと、アンモニアを含む不純物とを含む合成ガスを得るステップ;b)前記合成ガスを、1または複数のシフトステップを連続して含むシフトセクションにおいて、シフト合成ガスにシフトさせるステップ;
c)前記シフト合成ガスから、前記シフト合成ガスの冷却および任意選択的に洗浄から生じるプロセス凝縮物を分離するステップ;
d)前記プロセス凝縮物の一部を凝縮物蒸気ストリッパーに通すステップであって、前記合成ガスのシフトの間に形成されたアンモニア、メタノールおよびアミンを含む溶存シフト副生成物を蒸気を用いてプロセス凝縮物からストリッピングし、ストリッパー蒸気流をもたらすステップ、
e)プロセス凝縮物蒸気ストリッパーからの前記ストリッパー蒸気流を、前記炭化水素供給材料に、および/または前記改質セクションの下流かつ最後のシフトステップの上流で前記合成ガスに添加するステップ、
を含み、前記プロセス凝縮物の残部がパージされる、前記方法。 A method for producing synthesis gas, comprising the following steps:
a) reforming the hydrocarbon feed in a reforming section, thereby obtaining a synthesis gas comprising CH4, CO, CO2, H2 and H2O and impurities including ammonia; b) converting said synthesis gas into one or more in a shift section including a plurality of consecutive shift steps, shifting to shift syngas;
c) separating from said shifted syngas process condensate resulting from cooling and optionally washing of said shifted syngas;
d) passing a portion of the process condensate through a condensate steam stripper, the process comprising using steam to process dissolved shift byproducts including ammonia, methanol and amines formed during the syngas shift; stripping the condensate and providing a stripper vapor stream;
e) adding the stripper vapor stream from a process condensate vapor stripper to the hydrocarbon feed and/or to the synthesis gas downstream of the reforming section and upstream of the last shift step;
wherein the remainder of the process condensate is purged.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DKPA202000270 | 2020-03-03 | ||
DKPA202000270 | 2020-03-03 | ||
PCT/EP2021/055050 WO2021175784A1 (en) | 2020-03-03 | 2021-03-01 | Process for the production of synthesis gas |
Publications (2)
Publication Number | Publication Date |
---|---|
JP2023516364A JP2023516364A (en) | 2023-04-19 |
JPWO2021175784A5 true JPWO2021175784A5 (en) | 2024-03-27 |
Family
ID=74853642
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2022552744A Pending JP2023516364A (en) | 2020-03-03 | 2021-03-01 | Method for producing synthesis gas |
Country Status (15)
Country | Link |
---|---|
US (1) | US20230121402A1 (en) |
EP (1) | EP4114793B1 (en) |
JP (1) | JP2023516364A (en) |
KR (1) | KR20220148845A (en) |
CN (1) | CN115175870A (en) |
AR (2) | AR121498A1 (en) |
AU (1) | AU2021231509A1 (en) |
BR (1) | BR112022014978A2 (en) |
CA (1) | CA3165158A1 (en) |
CL (1) | CL2022002348A1 (en) |
DK (1) | DK4114793T3 (en) |
FI (1) | FI4114793T3 (en) |
IL (1) | IL295651A (en) |
MX (1) | MX2022010246A (en) |
WO (1) | WO2021175784A1 (en) |
Family Cites Families (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4681603A (en) * | 1986-02-13 | 1987-07-21 | Kinetics Technology International Corporation | Feed gas saturation system for steam reforming plants |
AU2010275804B2 (en) * | 2009-07-21 | 2014-02-06 | Linde Aktiengesellschaft | Process for cleaning a process condensate |
FR2999555B1 (en) * | 2012-12-13 | 2015-01-30 | Air Liquide | PROCESS FOR HYDROGEN PRODUCTION BY HYDROCARBON REFORMING USING STEAM, ASSOCIATED WITH CARBON DIOXIDE CAPTURE AND STEAM PRODUCTION |
DK3592703T3 (en) * | 2017-03-07 | 2023-09-11 | Topsoe As | UREA PROCESS WITH CONTROLLED EXCESS OF CO2 AND/OR NH3 |
-
2021
- 2021-03-01 CN CN202180018490.6A patent/CN115175870A/en active Pending
- 2021-03-01 JP JP2022552744A patent/JP2023516364A/en active Pending
- 2021-03-01 WO PCT/EP2021/055050 patent/WO2021175784A1/en active Application Filing
- 2021-03-01 CA CA3165158A patent/CA3165158A1/en active Pending
- 2021-03-01 IL IL295651A patent/IL295651A/en unknown
- 2021-03-01 US US17/800,997 patent/US20230121402A1/en active Pending
- 2021-03-01 FI FIEP21709384.8T patent/FI4114793T3/en active
- 2021-03-01 MX MX2022010246A patent/MX2022010246A/en unknown
- 2021-03-01 DK DK21709384.8T patent/DK4114793T3/en active
- 2021-03-01 EP EP21709384.8A patent/EP4114793B1/en active Active
- 2021-03-01 AU AU2021231509A patent/AU2021231509A1/en active Pending
- 2021-03-01 BR BR112022014978A patent/BR112022014978A2/en unknown
- 2021-03-01 KR KR1020227032731A patent/KR20220148845A/en unknown
- 2021-03-02 AR ARP210100549A patent/AR121498A1/en unknown
- 2021-03-02 AR ARP210100548A patent/AR121497A1/en unknown
-
2022
- 2022-08-26 CL CL2022002348A patent/CL2022002348A1/en unknown
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