JPWO2019240138A1 - Heat-resistant oil-based confectionery and its manufacturing method - Google Patents

Heat-resistant oil-based confectionery and its manufacturing method Download PDF

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JPWO2019240138A1
JPWO2019240138A1 JP2020525594A JP2020525594A JPWO2019240138A1 JP WO2019240138 A1 JPWO2019240138 A1 JP WO2019240138A1 JP 2020525594 A JP2020525594 A JP 2020525594A JP 2020525594 A JP2020525594 A JP 2020525594A JP WO2019240138 A1 JPWO2019240138 A1 JP WO2019240138A1
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優介 前田
優介 前田
宣幸 北岡
宣幸 北岡
侑香 臼杵
侑香 臼杵
豊 ▲くわ▼野
豊 ▲くわ▼野
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Meiji Co Ltd
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    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23GCOCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
    • A23G1/00Cocoa; Cocoa products, e.g. chocolate; Substitutes therefor
    • A23G1/30Cocoa products, e.g. chocolate; Substitutes therefor
    • A23G1/32Cocoa products, e.g. chocolate; Substitutes therefor characterised by the composition containing organic or inorganic compounds
    • A23G1/40Cocoa products, e.g. chocolate; Substitutes therefor characterised by the composition containing organic or inorganic compounds characterised by the carbohydrates used, e.g. polysaccharides

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Abstract

本発明は、耐熱性を有する油性菓子の製造方法であって、室温で固体の糖質であって、加熱により融液状となっている糖質を、油性菓子の全重量に対して0.5重量%以上〜50重量%未満となるように油性菓子生地と混合して混合生地を得る工程を含む、方法、を提供する。The present invention is a method for producing a heat-resistant oil-based confectionery, in which a sugar that is solid at room temperature and becomes a melt-liquid by heating is 0.5 with respect to the total weight of the oil-based confectionery. Provided is a method, which comprises a step of mixing with an oil-based confectionery dough to obtain a mixed dough so as to be from% by weight to less than 50% by weight.

Description

本発明は、耐熱性を有する油性菓子及びその製造方法等に関する。 The present invention relates to a heat-resistant oil-based confectionery and a method for producing the same.

油性菓子の代表的なものであるチョコレートは、味や香りが良いだけでなく、特有の滑らかな口どけを有する嗜好性の高い食品である。チョコレートの滑らかな口どけは、配合されている油脂、一般的にはココアバターの物性に依存している。ココアバターは人の体温付近で急激に融解する性質を有する。そのため、チョコレートを手指でつまむと付着したり、夏季等の高温条件下ではパッケージ内でチョコレートが融けて変形したりする。 Chocolate, which is a typical oil-based confectionery, is a highly palatable food that not only has a good taste and aroma, but also has a peculiar smooth melting in the mouth. The smooth melting of chocolate depends on the physical properties of the fats and oils it contains, generally cocoa butter. Cocoa butter has the property of rapidly melting near human body temperature. Therefore, if you pinch the chocolate with your fingers, it will adhere, or under high temperature conditions such as summer, the chocolate will melt and deform in the package.

チョコレートの耐熱性を向上させる課題に対して、解決手段がこれまでに多数提案されている。例えば、室温で液状のグリセリンを添加する技術(特許文献1:特表昭61−502938)、水に溶解したソルビトールを添加する技術(特許文献2:特開昭59−156246)、高融点油脂を添加して耐熱化する技術(特許文献3:特開2015−173614)、チョコレート生地を焼成することによって表面をビスケット様の硬い組織とする技術(特許文献4:特開2004−254639)等が挙げられる。 Many solutions have been proposed to solve the problem of improving the heat resistance of chocolate. For example, a technique for adding glycerin liquid at room temperature (Patent Document 1: Japanese Patent Application Laid-Open No. 61-502938), a technique for adding sorbitol dissolved in water (Patent Document 2: Japanese Patent Application Laid-Open No. 59-156246), and high melting point fats and oils. Examples thereof include a technique of adding heat to heat (Patent Document 3: Japanese Patent Application Laid-Open No. 2015-173614) and a technique of baking a chocolate dough to form a biscuits-like hard structure (Patent Document 4: Japanese Patent Application Laid-Open No. 2004-254639). Be done.

特表昭61−502938号公報Special Table No. 61-502938 特開昭59−156246号公報JP-A-59-156246 特開2015−173614号公報Japanese Unexamined Patent Publication No. 2015-173614 特開2004−254639号公報Japanese Unexamined Patent Publication No. 2004-254639

従来の技術のうち、液状の糖類をチョコレートに添加する技術は、糖類を溶解するための水分が含まれていることから、添加されたチョコレート生地の粘度が急激に上昇する。そのため、後に行われるチョコレート生地を成形する工程において成形が困難となる。また、得られたチョコレート製品中の水分含量が高くなることから、チョコレート製品に含まれる粉乳等の成分の品質が経時的に劣化し、良好な風味の維持が困難であった。液状の糖類としてグリセリンを使用した場合、混合や成形が困難であるだけでなく、得られたチョコレートは口どけが悪くぼそぼそした食感となった。 Among the conventional techniques, the technique of adding liquid saccharides to chocolate contains water for dissolving the saccharides, so that the viscosity of the added chocolate dough rapidly increases. Therefore, molding becomes difficult in the subsequent step of molding the chocolate dough. In addition, since the water content in the obtained chocolate product is high, the quality of components such as milk powder contained in the chocolate product deteriorates with time, and it is difficult to maintain a good flavor. When glycerin was used as a liquid sugar, not only was it difficult to mix and mold, but the resulting chocolate had a poor mouthfeel and a sloppy texture.

また、高融点油脂をチョコレートに添加することにより得られる耐熱性チョコレートは、一般的なココアバターを配合したチョコレートと比較すると、口どけが悪く感じられてしまう。 In addition, the heat-resistant chocolate obtained by adding the high-melting point fat and oil to the chocolate feels worse in the mouth than the chocolate containing general cocoa butter.

チョコレート生地を焼成することにより得られる耐熱性チョコレートは、表面がビスケット様に硬くなるため、口どけが通常のチョコレートとは異なるものとなる。 The heat-resistant chocolate obtained by baking the chocolate dough has a surface that becomes hard like a biscuit, so that the melting in the mouth is different from that of ordinary chocolate.

本発明は上記課題に鑑みてなされたものであり、良好な風味、食感、口どけを有する耐熱性油性菓子とその製造方法を提供することを目的とする。特に、チョコレートに特有の良好な風味、食感、口どけを有する耐熱性チョコレートとその製造法を提供することを目的とする。 The present invention has been made in view of the above problems, and an object of the present invention is to provide a heat-resistant oil-based confectionery having a good flavor, texture, and melting in the mouth, and a method for producing the same. In particular, it is an object of the present invention to provide a heat-resistant chocolate having a good flavor, texture, and melting in the mouth peculiar to chocolate and a method for producing the same.

本発明は更に、良好な風味、食感、口どけを有する耐熱性油性菓子を製造する方法において、製造工程におけるエージングに要する時間を低減することを目的とする。 Another object of the present invention is to reduce the time required for aging in the manufacturing process in a method for producing a heat-resistant oil-based confectionery having a good flavor, texture, and melting in the mouth.

本発明者らは鋭意検討の結果、油性菓子生地に配合する糖質の一部を融液の状態として用いることにより、意外にも融液状の糖質は油性菓子生地と均一に混合することが可能であり、得られる油性菓子の耐熱性が向上することを見出した。 As a result of diligent studies, the present inventors have unexpectedly been able to uniformly mix the melted liquid sugar with the oil-based confectionery dough by using a part of the sugar to be blended in the oil-based confectionery dough as a melted state. It has been found that it is possible and the heat resistance of the obtained oil-based confectionery is improved.

また、本発明者らは、このような耐熱性油性菓子の製造方法では、混合生地をエージングする工程が耐熱性付与の観点で重要になることを見出した。特に、融液状の糖質と油性菓子生地を穏やかに撹拌した後、25℃程度の比較的低い温度帯でエージングすると、耐熱性を有する状態となるまでに20日間ものエージングが必要となる場合がある。また、このような状況において、融液状の糖質の添加量を増加することにより、油性菓子の耐熱性を得るために必要なエージング時間が短縮される傾向がある。しかしながら、融液状の糖質の添加量が増加すると油性菓子生地と混合した後の生地の粘度が増加するため、型へ充填するための充填装置が限定されてしまう。また、添加量が過剰である場合は、相転移が発生して、油脂が連続層の口どけがよい油性菓子が得られなくなる。 Further, the present inventors have found that in such a method for producing a heat-resistant oil-based confectionery, the step of aging the mixed dough is important from the viewpoint of imparting heat resistance. In particular, if the melt-liquid sugar and the oil-based confectionery dough are gently agitated and then aged in a relatively low temperature range of about 25 ° C., aging for as long as 20 days may be required until the dough becomes heat-resistant. is there. Further, in such a situation, by increasing the amount of the melted liquid sugar added, the aging time required to obtain the heat resistance of the oil-based confectionery tends to be shortened. However, when the amount of the melted liquid sugar added increases, the viscosity of the dough after mixing with the oil-based confectionery dough increases, which limits the filling device for filling the mold. On the other hand, if the amount added is excessive, a phase transition occurs, and an oil-based confectionery having a continuous layer of fats and oils that melts in the mouth cannot be obtained.

更に、本発明者らは、油性菓子生地に対して、融液状の糖質と、前記糖質と同種の糖質の結晶粉末(以下、種結晶ともいう)を配合するか、あるいは油性菓子生地と融液状の糖質を混合して油性菓子を製造する工程において、せん断作用を与えながら混合する混合工程を加えることにより、得られる油性菓子の耐熱性が向上するだけでなく、エージング時間を短縮できることを見出した。 Further, the present inventors mix a melted liquid sugar and a crystal powder of a sugar of the same type as the sugar (hereinafter, also referred to as seed crystal) with the oil-based confectionery dough, or the oil-based confectionery dough. In the process of producing an oil-based confectionery by mixing and melted liquid sugar, by adding a mixing step of mixing while giving a shearing action, not only the heat resistance of the obtained oil-based confectionery is improved, but also the aging time is shortened. I found out what I could do.

本発明はこれらの知見に基づくものであり、以下に記載の事項をその特徴とするものである。 The present invention is based on these findings, and is characterized by the following items.

[1]耐熱性を有する油性菓子の製造方法であって、
室温で固体の糖質であって、加熱により融液状となっている糖質を、油性菓子の全重量に対して0.5重量%以上〜50重量%未満となるように油性菓子生地と混合して混合生地を得る工程を含む、方法。
[2]融液状の糖質が、溶媒の不在下で、糖質のみを加熱することで調製される、[1]に記載の方法。
[3]更に、混合生地を得る工程の後に、混合生地を成形及びエージングする工程を含む、[1]又は[2]に記載の方法。
[4]エージングを24℃以上で行う、[3]に記載の方法。
[5]融液状の糖質と混合する時の油性菓子生地の温度が30℃〜65℃である、[1]〜[4]のいずれか一つに記載の方法。
[6]油性菓子生地と混合する時の融液状の糖質の温度が60℃以上200℃未満である、[1]〜[5]のいずれか一つに記載の方法。
[7]融液状の糖質が、キシリトール、ソルビトール、フルクトース、エリスリトールのいずれか1種、又は前記糖質を2種以上組み合わせたものである、[1]〜[7]のいずれか一つに記載の方法。
[8]融液状の糖質と混合する前の油性菓子生地に含まれる油分が40重量%以下である、[1]〜[7]のいずれか一つに記載の方法。
[9]融液状の糖質が、油性菓子の全重量に対して2重量%〜20重量%となるように油性菓子生地と混合される、[1]〜[8]のいずれかに記載の方法。
[10]油性菓子生地に融液状の糖質の種結晶が配合されている、[1]〜[8]のいずれか一つに記載の方法。
[11]融液状の糖質が、油性菓子の全重量に対して0.5重量%〜20重量%となるように油性菓子生地と混合される、[10]に記載の方法。
[12]混合生地を得る工程において、混合生地が、せん断作用を与えながら融液状の糖質と油性菓子生地とを混合することにより得られる、[1]〜[8]のいずれか一つに記載の方法。
[13]融液状の糖質が、油性菓子の全重量に対して1重量%〜20重量%となるように油性菓子生地と混合される、[12]に記載の方法。
[14]融液状の糖質を混合する前の油性菓子生地に含まれる油分が40重量%以下である、[12]又は[13]に記載の方法。
[15][1]〜[14]のいずれか一つに記載の方法により得られる、油性菓子。
[16]室温で固体の糖質であって、加熱により融液状となっている糖質を油性菓子生地に添加することにより、油性菓子の耐熱性を向上させる方法。
[17]融液状の糖質を添加する前の油性菓子生地が流動状態にある、[16]に記載の方法。
[18]室温で固体の糖質であって、加熱により融液状となっている糖質を有効成分として含む、油性菓子に対する耐熱性付与剤。
[19]更に、当該融液状の糖質の種結晶を有効成分として含む、[18]に記載の耐熱性付与剤。
[1] A method for producing a heat-resistant oil-based confectionery.
A sugar that is solid at room temperature and is melted by heating is mixed with the oil-based confectionery dough so as to be 0.5% by weight or more and less than 50% by weight based on the total weight of the oil-based confectionery. A method comprising the step of obtaining a mixed dough.
[2] The method according to [1], wherein the melt-liquid sugar is prepared by heating only the sugar in the absence of a solvent.
[3] The method according to [1] or [2], further comprising a step of forming and aging the mixed dough after the step of obtaining the mixed dough.
[4] The method according to [3], wherein the aging is performed at 24 ° C. or higher.
[5] The method according to any one of [1] to [4], wherein the temperature of the oil-based confectionery dough when mixed with the melted liquid sugar is 30 ° C. to 65 ° C.
[6] The method according to any one of [1] to [5], wherein the temperature of the melted liquid sugar when mixed with the oil-based confectionery dough is 60 ° C. or higher and lower than 200 ° C.
[7] The melted liquid sugar is any one of xylitol, sorbitol, fructose, and erythritol, or a combination of two or more of the above sugars, in any one of [1] to [7]. The method described.
[8] The method according to any one of [1] to [7], wherein the oil content in the oil-based confectionery dough before being mixed with the melted liquid sugar is 40% by weight or less.
[9] The method according to any one of [1] to [8], wherein the melt-liquid sugar is mixed with the oil-based confectionery dough so as to be 2% by weight to 20% by weight based on the total weight of the oil-based confectionery. Method.
[10] The method according to any one of [1] to [8], wherein a melt-liquid sugar seed crystal is blended in an oil-based confectionery dough.
[11] The method according to [10], wherein the melted liquid sugar is mixed with the oil-based confectionery dough so as to be 0.5% by weight to 20% by weight based on the total weight of the oil-based confectionery.
[12] In the step of obtaining the mixed dough, the mixed dough is obtained by mixing the melt-liquid sugar and the oil-based confectionery dough while giving a shearing action, to any one of [1] to [8]. The method described.
[13] The method according to [12], wherein the melted liquid sugar is mixed with the oil-based confectionery dough so as to be 1% by weight to 20% by weight based on the total weight of the oil-based confectionery.
[14] The method according to [12] or [13], wherein the oil content in the oil-based confectionery dough before mixing the melted liquid sugar is 40% by weight or less.
[15] An oil-based confectionery obtained by the method according to any one of [1] to [14].
[16] A method for improving the heat resistance of an oil-based confectionery by adding a sugar that is a solid sugar at room temperature and becomes a melt-liquid by heating to an oil-based confectionery dough.
[17] The method according to [16], wherein the oil-based confectionery dough before the addition of the melted liquid sugar is in a fluid state.
[18] A heat-resistant imparting agent for oil-based confectionery, which contains a sugar that is solid at room temperature and becomes a melt-liquid by heating as an active ingredient.
[19] The heat resistance imparting agent according to [18], further comprising a seed crystal of the melted liquid sugar as an active ingredient.

本発明の方法によれば、耐熱性を有しながら、食感、風味、口どけがよい油性菓子が提供される。本発明の方法にしたがって融液状の糖質を配合して得られる耐熱性油性菓子は、同じ糖質を融液ではなく結晶糖質として配合された油性菓子に対して格別に高い耐熱性を有している。更に、本発明の耐熱性油性菓子は、高温で静置されても形状が変化しない一方で、口中では従来のチョコレートと変わらない口どけ、食感、風味を有している。 According to the method of the present invention, an oil-based confectionery having heat resistance and having a good texture, flavor, and melting in the mouth is provided. The heat-resistant oil-based confectionery obtained by blending a melt-liquid sugar according to the method of the present invention has exceptionally high heat resistance to an oil-based confectionery in which the same sugar is blended as a crystalline sugar instead of a melt. doing. Further, the heat-resistant oil-based confectionery of the present invention does not change its shape even when left to stand at a high temperature, but has the same mouthfeel, texture and flavor as conventional chocolate in the mouth.

融液状の糖質とその種結晶を配合して油性菓子を得る方法によれば、種結晶を配合しない油性菓子の製造方法と比較して、耐熱性が得られるまでに必要なエージング時間を短縮することが可能になる。この方法にしたがって得られる耐熱性油性菓子は、エージング時間が短縮されているにもかかわらず、高温で静置されても形状が変化しない一方で、口中では従来のチョコレートと変わらない食感、風味、口どけを有している。 According to the method of obtaining an oil-based confectionery by blending a melt-liquid sugar and its seed crystals, the aging time required for obtaining heat resistance is shortened as compared with the method of producing an oil-based confectionery that does not contain seed crystals. It becomes possible to do. Although the heat-resistant oil-based confectionery obtained by this method has a shortened aging time, its shape does not change even when it is left to stand at a high temperature, but it has the same texture and flavor as conventional chocolate in the mouth. , Has a mouthfeel.

油性菓子生地に融液状の糖質を配合して耐熱性油性菓子を製造する方法においてせん断作用を与えながら混合する混合工程を含む方法は、前記混合工程を含まない製造方法と比較すると、耐熱性が得られるまでに必要なエージング時間が大幅に短縮される。この方法にしたがって得られる耐熱性油性菓子は、エージング時間が短縮されているにもかかわらず、高温で静置されても形状が変化しない一方で、口中では従来のチョコレートと変わらない食感、風味、口どけを有している。 In the method for producing a heat-resistant oil-based confectionery by blending a melt-liquid sugar with an oil-based confectionery dough, the method including a mixing step of mixing while giving a shearing action is heat-resistant as compared with the production method not including the mixing step. The aging time required to obtain the above is greatly reduced. Although the heat-resistant oil-based confectionery obtained by this method has a shortened aging time, its shape does not change even when it is left to stand at a high temperature, but it has the same texture and flavor as conventional chocolate in the mouth. , Has a mouthfeel.

第一の実施形態において、本発明は、耐熱性を有する油性菓子の製造方法であって、室温で固体の糖質であって、加熱により融液状となっている糖質を、油性菓子の全重量に対して0.5重量%以上〜50重量%未満となるように油性菓子生地と混合して混合生地を得る工程を含む、方法、を提供する。 In the first embodiment, the present invention is a method for producing a heat-resistant oil-based confectionery, in which a sugar that is solid at room temperature and becomes a melt-liquid by heating is used as a whole of the oil-based confectionery. Provided is a method comprising a step of obtaining a mixed dough by mixing with an oil-based confectionery dough so as to be 0.5% by weight or more and less than 50% by weight based on the weight.

本明細書では以降、重量、温度等の数値範囲について、それらの下限値や上限値を「以上」、「超」、「以下」「未満」の表現により規定する場合だけでなく、これらの表現を使用せずに各数値範囲を「2重量%〜20重量%」、「30℃〜65℃」のように規定する場合もある。後者の場合、下限値と上限値の両方がその数値範囲に含まれることを意図している。 Hereinafter, in the present specification, not only the case where the lower limit value and the upper limit value of the numerical range such as weight and temperature are defined by the expressions of "greater than or equal to", "greater than", "less than or equal to" and "less than", but also these expressions In some cases, each numerical range is specified as "2% by weight to 20% by weight" and "30 ° C. to 65 ° C." without using. In the latter case, both the lower and upper limits are intended to be included in the numerical range.

(油性菓子)
本発明において「油性菓子」とは、油性原料によってその物性特性が支配されている菓子をいう。油性菓子として、具体的にはチョコレートやナッツクリーム、好ましくはチョコレートが挙げられる。「チョコレート」とは、規格上のチョコレートに限定されるものではなく、日本国公正取引委員会が認定したルールである「チョコレート類の表示に関する公正競争規約」に定めるチョコレート、準チョコレートを含むものとする。
(Oil confectionery)
In the present invention, the "oil-based confectionery" refers to a confectionery whose physical characteristics are controlled by an oil-based raw material. Specific examples of the oil-based confectionery include chocolate, nut cream, and preferably chocolate. "Chocolate" is not limited to standard chocolate, but includes chocolate and quasi-chocolate stipulated in the "Fair Competition Code for Labeling Chocolates", which is a rule approved by the Japan Fair Trade Commission.

本発明の方法により得られる油性菓子(以下、本発明の油性菓子という)の水分含量は特に限定されないが、油性菓子中に3重量%未満、好ましくは油性菓子中に2重量%未満、より好ましくは1.5重量%以下である。 The water content of the oil-based confectionery obtained by the method of the present invention (hereinafter referred to as the oil-based confectionery of the present invention) is not particularly limited, but is less than 3% by weight in the oil-based confectionery, preferably less than 2% by weight in the oil-based confectionery, more preferably. Is 1.5% by weight or less.

本発明の油性菓子は、「耐熱性」を有する。本発明において、「耐熱性」とは、油性菓子が一定温度(例えば30℃、35℃、又は45℃)で一定時間(例えば1時間)静置された後に、軽く指で押しても変形しにくい性質をいう。本発明の油性菓子は、前記静置後に、指でつまみあげても指に付着せず、容易に持ち上げることができる。 The oil-based confectionery of the present invention has "heat resistance". In the present invention, "heat resistance" means that an oil-based confectionery is not easily deformed even if it is lightly pressed with a finger after being allowed to stand at a constant temperature (for example, 30 ° C., 35 ° C., or 45 ° C.) for a certain period of time (for example, 1 hour). Refers to the nature. The oil-based confectionery of the present invention does not adhere to the fingers even if it is picked up with a finger after the standing, and can be easily lifted.

本発明の油性菓子の耐熱性は、以下に示す「硬度」により評価することもできる。本発明において、「硬度」とは、以下の条件により測定された数値をいう(単位:gf)。なお、硬度測定用サンプルは、一辺が約15mmの略立方体形状に成形された油性菓子を一定温度(30℃〜45℃)の恒温機に1時間静置した後、取り出した直後のものを用いる。
測定機器:FUDOHレオメーターRTC−3010D−CW
プランジャー:直径15mmの円筒状のプランジャー(プラスチック素材)
プランジャーの進入速度:2cm/分
プランジャーの進入深度:3mm
The heat resistance of the oil-based confectionery of the present invention can also be evaluated by the "hardness" shown below. In the present invention, "hardness" means a numerical value measured under the following conditions (unit: gf). As the sample for hardness measurement, an oil-based confectionery formed into a substantially cubic shape having a side of about 15 mm is allowed to stand in a thermostat at a constant temperature (30 ° C. to 45 ° C.) for 1 hour, and then immediately taken out. ..
Measuring equipment: FUDOH rheometer RTC-3010D-CW
Plunger: Cylindrical plunger with a diameter of 15 mm (plastic material)
Plunger approach speed: 2 cm / min Plunger approach depth: 3 mm

本発明の油性菓子の「硬度」は、35℃で1時間静置した後に、少なくとも100gf以上であることが好ましく、より好ましくは、45℃で1時間静置した後に、少なくとも100gf以上である。ただし、本発明の油性菓子に低融点油脂が配合された場合は、30℃で1時間静置した後に、少なくとも100gf以上であることが好ましい。なお、本発明において「低融点油脂」とは、基準油脂分析試験法による20℃におけるSFC測定値が42%〜45%である市販油脂のことをいう。 The "hardness" of the oil-based confectionery of the present invention is preferably at least 100 gf or more after being allowed to stand at 35 ° C. for 1 hour, and more preferably at least 100 gf or more after being allowed to stand at 45 ° C. for 1 hour. However, when the oil-based confectionery of the present invention contains a low melting point fat and oil, it is preferably at least 100 gf or more after being allowed to stand at 30 ° C. for 1 hour. In the present invention, the "low melting point fat and oil" refers to a commercially available fat and oil having an SFC measurement value of 42% to 45% at 20 ° C. by a standard fat and oil analysis test method.

本発明の油性菓子は、製造工程において「融液状」の糖質が配合されることを特徴とする。本発明の油性菓子は、メカニズムの詳細は不明であるが、同じ糖質を「融液」ではなく「結晶」とした点のみ異なる従来の油性菓子よりも、少なくとも5℃以上高い耐熱性を有している。特に、製造工程において糖質としてキシリトール融液を油性菓子中に2重量%〜10重量%配合された油性菓子は、45℃で1時間以上静置された後においても変形しないという著しく高い耐熱性を有している。本発明の油性菓子は、高温で静置されても形状が変化しない一方で、口中では従来のチョコレートと変わらない口どけ、食感、甘味などの風味を有している。 The oil-based confectionery of the present invention is characterized in that a "melted liquid" sugar is blended in the manufacturing process. Although the details of the mechanism are unknown, the oil-based confectionery of the present invention has a heat resistance that is at least 5 ° C. higher than that of the conventional oil-based confectionery, which differs only in that the same sugar is made into "crystals" instead of "melts". doing. In particular, an oil-based confectionery containing 2% by weight to 10% by weight of xylitol melt as a sugar in the manufacturing process has extremely high heat resistance that it does not deform even after being allowed to stand at 45 ° C. for 1 hour or more. have. The oil-based confectionery of the present invention does not change its shape even when it is allowed to stand at a high temperature, but has a flavor such as melting, texture, and sweetness that is the same as that of conventional chocolate in the mouth.

(融液状の糖質)
本発明の油性菓子に配合される「融液状」の糖質とは、固体状の糖質を、水分を添加せずに加熱して融解することによって得られる糖質をいう。本発明の効果を奏する限り、水以外の溶媒やその他の成分を加熱時に添加してもよいが、溶媒の不在下で、糖質のみを加熱することが好ましい。加熱温度は糖質の融点以上であればよい。しかしながら、融液の温度が高い方が結晶を完全に融解することができ、かつ、製造途中での結晶析出を防ぐことができるため、加熱温度は高い方が好ましい。融液状の糖質は、融液状態を維持している限り、配合される前に冷却されていてもよい。加熱して融液状となった糖質を冷却することにより、糖質の粘性が上がり、油性菓子と混合分散しやすくなるという利点もある。
(Fluid sugar)
The "melted liquid" sugar contained in the oil-based confectionery of the present invention refers to a sugar obtained by heating and melting a solid sugar without adding water. As long as the effect of the present invention is exhibited, a solvent other than water and other components may be added at the time of heating, but it is preferable to heat only the sugar in the absence of the solvent. The heating temperature may be equal to or higher than the melting point of the sugar. However, it is preferable that the heating temperature is high because the higher the temperature of the melt, the more the crystals can be completely melted and the crystal precipitation during the production can be prevented. The melted liquid sugar may be cooled before being blended as long as the melted state is maintained. By cooling the sugar that has become melted and liquid by heating, the viscosity of the sugar is increased, and there is an advantage that it is easy to mix and disperse with the oil-based confectionery.

本発明において「固体状の糖質」とは、室温で固体の炭素数4以上の糖質、好ましくは常温常圧下(より具体的には20℃〜25℃、1気圧。実施例では単に「室温」ともいう)において固体である糖質をいう。また、「固体状の糖質」は、ガラス転移点が低く、油性菓子と混合できる温度帯で液状アモルファスとなる糖質が好ましい。より好ましくは、キシリトール、ソルビトール、フルクトース、エリスリトールのいずれか1種又は前記糖質を2種以上組み合わせた糖質である。さらにより好ましくは、キシリトール又はソルビトールのいずれか1種である。前記した「糖質を2種以上組み合わせた糖質」としては、キシリトール及びソルビトールの混合物が好ましい。 In the present invention, the "solid sugar" is a solid sugar having 4 or more carbon atoms at room temperature, preferably under normal temperature and pressure (more specifically, 20 ° C to 25 ° C, 1 atm. A sugar that is solid at room temperature). Further, the "solid sugar" is preferably a sugar having a low glass transition point and becoming liquid amorphous in a temperature range where it can be mixed with oil-based confectionery. More preferably, it is a sugar obtained by any one of xylitol, sorbitol, fructose and erythritol, or a combination of two or more of the above sugars. Even more preferably, it is either xylitol or sorbitol. As the above-mentioned "sugar in which two or more kinds of sugars are combined", a mixture of xylitol and sorbitol is preferable.

油性菓子に対して糖質を配合する場合、一般的には粉末の原料が用いられる。油性菓子に水分を追加することは、物性(特に流動性)に大きな影響を与えるため好ましくない。そのため、通常は油性菓子に融液状の糖質を配合することはない。従来技術(特許文献1)において、チョコレートの油脂成分を不動化するために、液状ポリオール、具体的にはグリセリン、水素添加コーンシラップ、ソルビトール70%水溶液が用いられている。しかしながら、液状ポリオールを油性菓子(チョコレート)に添加した場合、添加されたチョコレート生地は粘度が上昇するため、混合やその後の成形が著しく困難となる。 When sugar is added to oil-based confectionery, powdered raw materials are generally used. Adding water to oil-based confectionery is not preferable because it has a great effect on physical properties (particularly fluidity). Therefore, normally, oil-based confectionery is not mixed with melted liquid sugar. In the prior art (Patent Document 1), a liquid polyol, specifically glycerin, hydrogenated corn syrup, or a 70% aqueous solution of sorbitol is used to immobilize the fat and oil component of chocolate. However, when the liquid polyol is added to the oil-based confectionery (chocolate), the added chocolate dough has an increased viscosity, which makes mixing and subsequent molding extremely difficult.

本発明の油性菓子において、融液状の糖質は、油性菓子の全重量に対して0.5重量%以上〜50重量%未満となるように油性菓子生地と混合される。融液状の糖質の配合量は、1重量%〜20重量%であることが好ましく、2重量%〜10重量%がより好ましく、更により好ましくは2重量%〜5重量%である。0.5重量%よりも融液状の糖質が少ない場合は、耐熱性の効果が十分に得られにくい。また、50重量%よりも融液状の糖質が多い場合は、融液状の糖質を油性菓子の他原料と混合する工程で、著しく粘度が上昇するために混練作業を連続して行うことが困難となるか、もしくは、前記した混合工程において相転移が起こって、油脂が連続層の口どけがよい油性菓子が得られなくなる。そもそも、融液状の糖質が50重量%超添加された場合に得られる最終製品は油性菓子と呼べないものとなる。 In the oil-based confectionery of the present invention, the melt-liquid sugar is mixed with the oil-based confectionery dough so as to be 0.5% by weight or more and less than 50% by weight with respect to the total weight of the oil-based confectionery. The blending amount of the melted liquid sugar is preferably 1% by weight to 20% by weight, more preferably 2% by weight to 10% by weight, still more preferably 2% by weight to 5% by weight. When the amount of melted sugar is less than 0.5% by weight, it is difficult to sufficiently obtain the effect of heat resistance. When the amount of melted liquid sugar is more than 50% by weight, the kneading operation may be continuously performed in the step of mixing the melted liquid sugar with other raw materials of oil-based confectionery because the viscosity increases remarkably. It becomes difficult, or a phase transition occurs in the above-mentioned mixing step, and it becomes impossible to obtain an oil-based confectionery having a continuous layer of fats and oils that melts in the mouth. In the first place, the final product obtained when more than 50% by weight of the melted liquid sugar is added cannot be called an oil-based confectionery.

本発明の油性菓子には、本発明の効果を損なわない範囲において、カカオ豆由来原料(カカオマス、ココアパウダー、ココアバター、カカオ豆原料由来抽出物、等)、融液状の糖質以外の糖質、生乳由来原料(全脂粉乳、脱脂粉乳、等)、油脂、乳化剤、香料等を配合することができる。油性菓子に耐熱性を付与する観点からは、融液状の糖質に加え、それ以外の糖質を配合することが好ましい。 The oil-based confectionery of the present invention contains raw materials derived from cocoa beans (cocoa mass, cocoa powder, cocoa butter, extracts derived from cocoa bean raw materials, etc.) and sugars other than melted sugars, as long as the effects of the present invention are not impaired. , Raw milk-derived raw materials (whole fat powder milk, defatted milk powder, etc.), fats and oils, emulsifiers, flavors, etc. can be blended. From the viewpoint of imparting heat resistance to oil-based confectionery, it is preferable to add other sugars in addition to the melted liquid sugar.

本発明の油性菓子には、油性菓子の全重量に対して28重量%〜50重量%の油分を含有することが好ましい。油分の含量は30重量%〜40重量%であることがより好ましく、32重量%〜37重量%であることが特に好ましい。 The oil-based confectionery of the present invention preferably contains 28% by weight to 50% by weight of oil based on the total weight of the oil-based confectionery. The oil content is more preferably 30% by weight to 40% by weight, and particularly preferably 32% by weight to 37% by weight.

本発明の油性菓子には、油性菓子の全重量に対して25重量%〜45重量%の糖質を含有することが好ましい。 The oil-based confectionery of the present invention preferably contains 25% by weight to 45% by weight of sugar based on the total weight of the oil-based confectionery.

(融液状の糖質を調製する工程)
本発明における「融液状の糖質を調製する工程」は、通常、固体状の糖質を、水分を添加せずに加熱して融解する工程である。融解するための加熱温度、加熱時間、加熱手段は、用いる糖質の融点等に応じて当業者が適宜選択できる。例えば、キシリトールを用いる場合、結晶キシリトールを結晶融解装置に投入して、110℃で結晶が融解するまで撹拌することによって、融液状のキシリトールを調製することができる。また、ソルビトールを用いる場合、結晶ソルビトールを120℃にて同様に操作することにより融液状のソルビトールを調製することができる。
(Step of preparing melted liquid sugar)
The "step of preparing a melt-liquid sugar" in the present invention is usually a step of heating and melting a solid sugar without adding water. The heating temperature, heating time, and heating means for melting can be appropriately selected by those skilled in the art according to the melting point of the sugar to be used and the like. For example, when xylitol is used, a melted liquid xylitol can be prepared by putting crystalline xylitol into a crystal melting device and stirring it at 110 ° C. until the crystals are melted. When sorbitol is used, a melt-liquid sorbitol can be prepared by similarly operating crystalline sorbitol at 120 ° C.

本調製工程により得られた融液状の糖質は、後の混合工程に用いるまでの間、融液状態を維持できる条件(例えば、用いる融液状の糖質の融点以上)で保存されることが好ましい。 The melted liquid sugar obtained in this preparation step may be stored under conditions that can maintain the melted state (for example, at least the melting point of the melted liquid sugar used) until it is used in a subsequent mixing step. preferable.

(油性菓子生地と融液状の糖質とを混合する工程)
本混合工程では、前記した調製工程によって得られた「融液状の糖質」と、流動状態の「油性菓子生地」とを混合して混合生地を調製する。本混合工程において、融液状の糖質は親水性であるにも関わらず、油系である油性菓子生地と均一に混合することが可能である。ここで、「油性菓子生地」とは、本発明の「油性菓子」を構成する原料のうち、「融液状の糖質」を含まずに構成され、油性原料によってその物性特性が支配されているものをいう。「油性菓子生地」は、融液状の糖質を除いた油性菓子の原料が、焙炒、摩砕、混合、微細化、精練、調温等の工程によって予め均一な状態に調製されたものが好ましい。なお、本明細書の全体において、単に「油性菓子生地」と記載した場合は、融液状の糖質が含まれないものを示す。また、融液状の糖質と油性菓子生地を混合した後(及び、更に必要に応じて油脂結晶安定化剤を添加した後)に得られるものを「混合生地」という。
(Process of mixing oil-based confectionery dough and melted liquid sugar)
In this mixing step, the "melted liquid sugar" obtained in the above-mentioned preparation step and the "oil-based confectionery dough" in a fluid state are mixed to prepare a mixed dough. In this mixing step, although the melt-liquid sugar is hydrophilic, it can be uniformly mixed with the oil-based confectionery dough. Here, the "oil-based confectionery dough" is composed of the raw materials constituting the "oil-based confectionery" of the present invention without containing "fused liquid sugar", and its physical characteristics are controlled by the oil-based confectionery. Say something. "Oil-based confectionery dough" is made by preparing the raw materials for oil-based confectionery excluding melted and liquid sugars into a uniform state in advance by processes such as roasting, grinding, mixing, miniaturization, refining, and temperature control. preferable. In addition, in the whole of this specification, when it simply describes as "oil-based confectionery dough", it means that it does not contain melted liquid sugar. Further, what is obtained after mixing the melted liquid sugar and the oil-based confectionery dough (and after adding the fat crystal stabilizer if necessary) is referred to as "mixed dough".

「油性菓子生地」には、従来から一般的に用いられている原料を適宜使用することができる。例えば、カカオマス、ココアバター、その他の植物油脂、粉糖、全脂粉乳、脱脂粉乳、乳化剤、色素、香料等が挙げられる。 As the "oil-based confectionery dough", raw materials generally used conventionally can be appropriately used. For example, cocoa mass, cocoa butter, other vegetable oils and fats, powdered sugar, whole fat powdered milk, skim milk powder, emulsifiers, pigments, flavors and the like can be mentioned.

本混合工程において、油性菓子生地は、融液状の糖質と混合する際に流動状態とする。前記流動状態の油性菓子生地は、油性原料の性質に依存するが、流動状態を維持し、延いては油性菓子に耐熱性を付与するために30℃〜65℃、好ましくは45℃〜60℃、より好ましくは50℃〜60℃とする。前記温度帯よりも低い温度の油性菓子生地を用いると、融液状の糖質が分散しにくくなるため、耐熱性を有する油性菓子が得られにくくなる。前記温度帯よりも高い温度の油性菓子生地を用いた場合、耐熱性を有する油性菓子が得られても、融液状の糖質と混合した後の工程で冷却するための時間やエネルギーが多く必要となったり、好ましい風味が得られにくくなったりする。 In this mixing step, the oil-based confectionery dough is brought into a fluid state when mixed with the melted liquid sugar. The oil-based confectionery dough in a fluid state depends on the properties of the oil-based raw material, but in order to maintain the fluid state and further impart heat resistance to the oil-based confectionery, 30 ° C. to 65 ° C., preferably 45 ° C. to 60 ° C. , More preferably 50 ° C to 60 ° C. When an oil-based confectionery dough having a temperature lower than the above temperature range is used, it becomes difficult to disperse the melted liquid sugar, so that it becomes difficult to obtain a heat-resistant oil-based confectionery. When an oil-based confectionery dough having a temperature higher than the above temperature range is used, even if a heat-resistant oil-based confectionery is obtained, a large amount of time and energy is required for cooling in the process after mixing with the melt-liquid sugar. Or it becomes difficult to obtain a favorable flavor.

融液状の糖質は、本混合工程において融液状態であるだけでなく、混合する時点で流動状態の油性菓子生地との混合が可能な温度となるように調整することが好ましい。融液状の糖質の原料がソルビトール又はキシリトールである場合、前記温度として60℃以上200℃未満が好ましく、60℃〜150℃がより好ましく、特に好ましくは90℃〜145℃である。例えば、キシリトールの融点は92℃〜97℃くらいであるが、融液を融点以下に冷却すると「過冷却」状態となる。「過冷却」状態である60℃未満のキシリトールは、直ちに固体にはならないものの、過冷却状態において刺激を与えると、白濁して結晶化が一気に進行する。また、60℃未満の融液を油性菓子生地に添加すると、分散せず、結晶状態の大きな粒が散在した状態となり(つまり、チョコレートとしてざらつきを感じる)、混合生地の粘度が高くなり、本発明の効果の一つである成形困難の緩和が実現されないことになる。 It is preferable to adjust the melt-liquid sugar so that the temperature is not only in the melt state in the main mixing step but also at the time of mixing so that it can be mixed with the oil-based confectionery dough in the fluid state. When the raw material of the melt-liquid sugar is sorbitol or xylitol, the temperature is preferably 60 ° C. or higher and lower than 200 ° C., more preferably 60 ° C. to 150 ° C., and particularly preferably 90 ° C. to 145 ° C. For example, the melting point of xylitol is about 92 ° C. to 97 ° C., but when the melt is cooled below the melting point, it becomes a “supercooled” state. Xylitol below 60 ° C. in the "supercooled" state does not immediately become a solid, but when stimulated in the supercooled state, it becomes cloudy and crystallization proceeds at once. Further, when a melt of less than 60 ° C. is added to the oil-based confectionery dough, it does not disperse and large grains in a crystalline state are scattered (that is, it feels grainy as chocolate), and the viscosity of the mixed dough becomes high. It will not be possible to alleviate the molding difficulty, which is one of the effects of.

本発明の耐熱性油性菓子の生産性を向上するためには、本混合工程において、融液状の糖質が流動状態の油性菓子生地に対して均一に分散して混合されることが好ましい。融液状の糖質と油性菓子生地を均一に混合するために、油性菓子生地の粘度を少なくとも25,000cps以上、好ましくは40,000cps以上、より好ましくは50,000cps以上とすることが好ましい(粘度測定条件は40℃、B型粘度計、ローターNo.6、ローター回転数4r.p.m.)。油性菓子生地の粘度が前記範囲に満たない場合は、公知の手段で調整することが好ましい。例えば、油性菓子生地の温度又は水分条件の調整、乳化剤の添加、等が挙げられる。 In order to improve the productivity of the heat-resistant oil-based confectionery of the present invention, it is preferable that the melt-liquid sugar is uniformly dispersed and mixed with the oil-based confectionery dough in a fluid state in the present mixing step. In order to uniformly mix the melted sugar and the oil-based confectionery dough, the viscosity of the oil-based confectionery dough is preferably at least 25,000 cps or more, preferably 40,000 cps or more, and more preferably 50,000 cps or more (viscosity). The measurement conditions are 40 ° C., B-type viscometer, rotor No. 6, rotor rotation speed 4 rpm.). When the viscosity of the oil-based confectionery dough is less than the above range, it is preferable to adjust it by a known means. For example, adjustment of temperature or moisture conditions of oil-based confectionery dough, addition of emulsifier, and the like can be mentioned.

本混合工程において、油性菓子生地に含まれる油分が40重量%を超える場合は、融液状の糖質を均一に分散させて混合することが困難となる。この場合、油性菓子生地に対して降伏値を上げる乳化剤を配合することにより、均一な混合が可能となる。別の手段として、第一工程として油性菓子生地中の油分を40重量%以下(好ましくは35重量%以下)となるように選抜して調製した原料と、融液状の糖質とを均一に混合した後、第二工程として、第一工程で添加しなかったその他の原料を追加して混合することによって、均一に混合することが可能となる。 In this mixing step, if the oil content in the oil-based confectionery dough exceeds 40% by weight, it becomes difficult to uniformly disperse and mix the melted liquid sugar. In this case, by adding an emulsifier that raises the yield value to the oil-based confectionery dough, uniform mixing becomes possible. As another means, as a first step, a raw material selected and prepared so that the oil content in the oil-based confectionery dough is 40% by weight or less (preferably 35% by weight or less) and a melted liquid sugar are uniformly mixed. After that, as the second step, other raw materials not added in the first step are added and mixed, so that the mixture can be uniformly mixed.

本混合工程において、油性菓子生地と融液状の糖質を混合する装置は、一般的な混合装置であれば特に限定されない。 In this mixing step, the apparatus for mixing the oil-based confectionery dough and the melted liquid sugar is not particularly limited as long as it is a general mixing apparatus.

本混合工程において、融液状の糖質と油性菓子生地を混合した後、油性菓子の油脂の結晶系を安定化するためのシード剤を添加することができる。シード剤は、前記混合生地を35℃未満となるまで徐冷した後に添加することが好ましい。 In this mixing step, after mixing the melt-liquid sugar and the oil-based confectionery dough, a seeding agent for stabilizing the crystal system of the fat and oil of the oil-based confectionery can be added. The seeding agent is preferably added after the mixed dough is slowly cooled to less than 35 ° C.

通常、本混合工程において融液状の糖質と油性菓子生地を含有する混合生地(結晶系を安定化させるシード剤を含有する場合も含む)の粘度は、混合前の油性菓子生地の粘度よりも上昇する。しかしながら、本発明においては、融液状の糖質を用いることにより、従来よりも混合工程や成形工程における作業効率が大幅に改善される。なお、混合生地の粘度は、油性菓子生地の組成等や融液状の糖質の配合量等に応じて異なるが、例えば40,000cps以上、好ましくは50,000cps以上である(粘度測定条件は40℃、B型粘度計、ローターNo.6、ローター回転数4r.p.m.)。 Usually, the viscosity of the mixed dough containing the melted sugar and the oil-based confectionery dough in this mixing step (including the case where the seed agent for stabilizing the crystal system is contained) is higher than the viscosity of the oil-based confectionery dough before mixing. To rise. However, in the present invention, by using the melted liquid sugar, the work efficiency in the mixing step and the molding step is significantly improved as compared with the conventional case. The viscosity of the mixed dough varies depending on the composition of the oil-based confectionery dough, the blending amount of the melted liquid sugar, and the like, but is, for example, 40,000 cps or more, preferably 50,000 cps or more (viscosity measurement condition is 40). ° C., B-type viscometer, rotor No. 6, rotor rotation speed 4 rpm).

(混合生地を成形及びエージングする工程)
本成形・エージング工程は、前記混合工程によって得られた混合生地を成形及びエージングする工程である。本工程成形・エージングは、混合生地を成形する工程を含む。前記成形工程の手段は特に限定されず、従来から用いられている装置を用いることができる。例えば、モールド成形機、すりこみ成形機、バー成形機、押出し成形機、エンローバー、シート成形機等が挙げられる。
(Process of molding and aging mixed dough)
The main molding / aging step is a step of molding and aging the mixed dough obtained by the mixing step. This process molding / aging includes a step of molding a mixed dough. The means of the molding step is not particularly limited, and a conventionally used device can be used. For example, a molding machine, a rubbing molding machine, a bar molding machine, an extrusion molding machine, an enrober, a sheet molding machine and the like can be mentioned.

本成形・エージング工程で、混合生地は、所定の温度のもとで一定期間静置することによりエージングされる。エージングのメカニズムの詳細は不明であるが、所定の期間静置されることで融液状の糖質が結晶化して糖骨格を形成すると推定される。そのため、融液状の糖質の自由度を確保できるように、油性菓子に含まれる油分が液状となる温度条件でエージングされることが好ましい。本成形・エージング工程におけるエージング中の温度条件は、油性菓子に耐熱性を付与する観点から、低くとも24℃以上(例えば24℃〜45℃)であり、好ましくは28℃以上(例えば28℃〜35℃)である。エージングの時間は、油性菓子の組成や製造工程によって適宜調整されるが、1日以上であることが好ましい。 In the main molding / aging step, the mixed dough is aged by allowing it to stand at a predetermined temperature for a certain period of time. The details of the aging mechanism are unknown, but it is presumed that the melt-liquid sugar crystallizes to form a sugar skeleton after being allowed to stand for a predetermined period of time. Therefore, it is preferable that the oil contained in the oil-based confectionery is aged under a temperature condition in which it becomes liquid so that the degree of freedom of the melted and liquid sugar can be ensured. The temperature condition during aging in the main molding / aging step is at least 24 ° C. or higher (for example, 24 ° C. to 45 ° C.), preferably 28 ° C. or higher (for example, 28 ° C. to 28 ° C.) from the viewpoint of imparting heat resistance to the oil-based confectionery. 35 ° C.). The aging time is appropriately adjusted depending on the composition of the oil-based confectionery and the manufacturing process, but is preferably 1 day or more.

なお、エージング中の油性菓子は、成形後に脱型された状態であってもよいし、成形用の型に充填された状態であってもよい。例えば、油性菓子を成形用の型に充填した後、冷却固化工程及び脱型工程を実施せず、型に充填された状態でエージングすることができる。 The oil-based confectionery being aged may be in a state of being demolded after molding, or may be in a state of being filled in a molding mold. For example, after filling an oil-based confectionery into a molding mold, aging can be performed in a state of being filled in the mold without performing a cooling solidification step and a mold removal step.

(種結晶の配合によるエージング時間の短縮)
別の実施形態において、混合生地を得る工程は、エージング時間短縮の観点から、室温で固体の糖質であって、加熱により融液状となっている糖質と、その種結晶が配合された油性菓子生地とが混合されてもよい。メカニズムの詳細は不明であるが、融液状の糖質の種結晶を配合して得られる油性菓子は、同じ糖質について「結晶糖質」のみが配合された油性菓子よりも、少なくとも5℃以上高い耐熱性を有している。特に、製造工程において、糖質としてキシリトール融液を0.9重量%〜5重量%、種結晶としてキシリトール結晶粉末を0.8重量%〜2重量%配合された油性菓子は、45℃で1時間以上静置された後においても変形しないという著しく高い耐熱性を有している。本発明の油性菓子は、高温で静置されても形状が変化しない一方で、口中では従来のチョコレートと変わらない口どけ、食感、風味を有している。
(Reduction of aging time by blending seed crystals)
In another embodiment, from the viewpoint of shortening the aging time, the step of obtaining the mixed dough is an oily substance in which a sugar that is solid at room temperature and becomes a melted liquid by heating and a seed crystal thereof are blended. It may be mixed with confectionery dough. Although the details of the mechanism are unknown, the oil-based confectionery obtained by blending the seed crystals of the melted liquid sugar is at least 5 ° C or higher than the oil-based confectionery containing only "crystal sugar" for the same sugar. It has high heat resistance. In particular, in the manufacturing process, an oil-based confectionery containing 0.9% by weight to 5% by weight of xylitol melt as a sugar and 0.8% by weight to 2% by weight of xylitol crystal powder as a seed crystal is 1 at 45 ° C. It has extremely high heat resistance that it does not deform even after being left to stand for more than an hour. The oil-based confectionery of the present invention does not change its shape even when left to stand at a high temperature, but has the same mouthfeel, texture and flavor as conventional chocolate in the mouth.

混合生地を得る工程において種結晶が油性菓子生地に配合される場合、融液状の糖質の配合量は、油性菓子の全重量に対して0.5重量%〜20重量%であることが好ましく、0.5重量%〜10重量%がより好ましく、更により好ましくは0.9重量%〜5重量%である。0.5重量%よりも融液状の糖質が少ない場合は、耐熱性の効果が十分に得られにくい。また、50重量%よりも融液状の糖質が多い場合は、融液状の糖質を油性菓子の他原料と混合する工程で、著しく粘度が上昇するために混練作業を連続して行うことが困難となるか、もしくは、前記した混合工程において相転移が起こって、油脂が連続層の口どけがよい油性菓子が得られなくなる。そもそも、融液状の糖質が50重量%超添加された場合に得られる最終製品は油性菓子と呼べないものとなる。 When the seed crystals are blended in the oil-based confectionery dough in the step of obtaining the mixed dough, the blending amount of the melted liquid sugar is preferably 0.5% by weight to 20% by weight with respect to the total weight of the oil-based confectionery. , 0.5% by weight to 10% by weight, and even more preferably 0.9% by weight to 5% by weight. When the amount of melted sugar is less than 0.5% by weight, it is difficult to sufficiently obtain the effect of heat resistance. When the amount of melted liquid sugar is more than 50% by weight, the kneading operation may be continuously performed in the step of mixing the melted liquid sugar with other raw materials of oil-based confectionery because the viscosity increases remarkably. It becomes difficult, or a phase transition occurs in the above-mentioned mixing step, and it becomes impossible to obtain an oil-based confectionery having a continuous layer of fats and oils that melts in the mouth. In the first place, the final product obtained when more than 50% by weight of the melted liquid sugar is added cannot be called an oil-based confectionery.

(種結晶)
本明細書において、「種結晶」とは、「融液状の糖質」と同じ糖質を含有する結晶をいう。例えば、融液状の糖質がキシリトールである場合、油性菓子に配合される種結晶としてもキシリトールが使用されることになる。本発明の油性菓子に配合される「種結晶」は、原料として配合する時に粉末状態であることが好ましい。粉末状の種結晶が本発明の油性菓子に配合されることにより、製造工程において耐熱性が発現するまでに必要なエージング時間が短縮される。
(Seed crystal)
As used herein, the term "seed crystal" refers to a crystal containing the same sugar as the "fused liquid sugar". For example, when the melted sugar is xylitol, xylitol is also used as a seed crystal to be blended in oil-based confectionery. The "seed crystal" blended in the oil-based confectionery of the present invention is preferably in a powder state when blended as a raw material. By blending the powdered seed crystals into the oil-based confectionery of the present invention, the aging time required for heat resistance to be exhibited in the manufacturing process is shortened.

前記種結晶の配合量は、本発明の効果を損なわない限り限定されない。例えば、糖融液の糖質の添加量との比較で過剰に種結晶が油性菓子に配合されている場合、融液状の糖質は添加からすぐに結晶化し、それにより混合生地を増粘するため、型への充填を困難にする。反対に、糖融液の糖質の添加量との比較で種結晶が少ない場合、融液状の糖質の結晶化が遅延するため、所望とするエージング期間での耐熱性が得られないことがある。このような観点から、種結晶の配合量は、油性菓子生地全重量に対して0.1重量%〜10重量%、好ましくは0.3重量%〜5重量%、より好ましくは0.5重量%〜2重量%である。 The blending amount of the seed crystal is not limited as long as the effect of the present invention is not impaired. For example, when the seed crystals are excessively blended in the oil-based confectionery in comparison with the amount of sugar added to the sugar melt, the melted sugar crystallizes immediately after the addition, thereby thickening the mixed dough. Therefore, it becomes difficult to fill the mold. On the contrary, when the number of seed crystals is small compared to the amount of sugar added to the sugar melt, the crystallization of the melted sugar is delayed, so that heat resistance during the desired aging period may not be obtained. is there. From this point of view, the blending amount of the seed crystal is 0.1% by weight to 10% by weight, preferably 0.3% by weight to 5% by weight, more preferably 0.5% by weight, based on the total weight of the oil-based confectionery dough. % To 2% by weight.

(融液状の糖質とその種結晶が配合された油性菓子生地とを混合する工程)
本混合工程では、前記した調製工程によって得られた「融液状の糖質」と、流動状態の「種結晶が配合された油性菓子生地」とを混合して混合生地を調製する。本混合工程において、融液状の糖質は親水性であるにも関わらず、油系である油性菓子生地と均一に混合することが可能である。ここで、「油性菓子生地」とは、本発明の「油性菓子」を構成する原料のうち、「融液状の糖質」を含まずに構成され、油性原料によってその物性特性が支配されているものをいう。「種結晶が配合された油性菓子生地」は、融液状の糖質を除いた油性菓子の原料であって、種結晶を含む原料が、焙炒、摩砕、混合、微細化、精練、調温等の工程によって予め均一な状態に調製されたものが好ましい。なお、混合生地を得る工程において種結晶が油性菓子生地に配合される態様に関して、単に「油性菓子生地」と記載した場合は、融液状の糖質及びその種結晶が含まれないものを示す。また、融液状の糖質とその種結晶が配合された油性菓子生地を混合した後(及び、更に必要に応じて油脂結晶安定化剤を添加した後)に得られるものを「混合生地」という。
(Step of mixing melted liquid sugar and oil-based confectionery dough containing seed crystals)
In this mixing step, the "melted liquid sugar" obtained in the above-mentioned preparation step and the "oil-based confectionery dough containing seed crystals" in a fluid state are mixed to prepare a mixed dough. In this mixing step, although the melt-liquid sugar is hydrophilic, it can be uniformly mixed with the oil-based confectionery dough. Here, the "oil-based confectionery dough" is composed of the raw materials constituting the "oil-based confectionery" of the present invention without containing "fused liquid sugar", and its physical characteristics are controlled by the oil-based confectionery. Say something. "Oil-based confectionery dough containing seed crystals" is a raw material for oil-based confectionery excluding melted sugar, and the raw material containing seed crystals is roasted, ground, mixed, refined, refined, and prepared. Those prepared in a uniform state in advance by a process such as temperature are preferable. Regarding the mode in which the seed crystals are blended into the oil-based confectionery dough in the step of obtaining the mixed dough, when the term "oil-based confectionery dough" is simply described, it means that the melted sugar and the seed crystals thereof are not contained. Further, what is obtained after mixing the oil-based confectionery dough containing the melted liquid sugar and its seed crystals (and after adding the fat crystal stabilizer if necessary) is called "mixed dough". ..

本混合工程における諸条件等は、特に断らない限り、上述した種結晶が配合されない場合のものと同様である。 Unless otherwise specified, the conditions and the like in this mixing step are the same as those in the case where the above-mentioned seed crystals are not blended.

本混合工程において、融液状の糖質をその種結晶が配合された流動状態の油性菓子生地に対して均一に分散して混合することは、耐熱性油性菓子を確実に得るために重要である。 In this mixing step, it is important to uniformly disperse and mix the melted liquid sugar in the fluid confectionery dough containing the seed crystals in order to surely obtain a heat-resistant oil-based confectionery. ..

前記混合工程によって得られた混合生地は、種結晶が配合されない場合と同様に成形及びエージングされる。本成形・エージング工程における諸条件等は、特に断らない限り、上述した種結晶が配合されない場合のものと同様である。しかしながら、種結晶を配合することで得られる効果は、比較的低い温度帯でエージングする場合において顕著であることから、この場合はエージング温度が24℃以上28℃未満であることが好ましい。 The mixed dough obtained by the mixing step is molded and aged in the same manner as when the seed crystals are not blended. Unless otherwise specified, the conditions and the like in the main molding / aging step are the same as those in the case where the above-mentioned seed crystals are not blended. However, the effect obtained by blending the seed crystal is remarkable in the case of aging in a relatively low temperature range, and in this case, the aging temperature is preferably 24 ° C. or higher and lower than 28 ° C.

エージングの時間は、油性菓子の組成や製造工程によって適宜調整されるが、1日以上であることが好ましい。種結晶を配合する方法によれば、油性菓子生地に種結晶を配合することにより、油性菓子が耐熱性を得るまでに必要なエージング時間を短縮することができる。例えば、製造工程において糖質として油性菓子中に融液状の糖質を0.9重量%〜5重量%、及び種結晶を0.8重量%〜2重量%配合された油性菓子は、35℃以上で耐熱性を有する状態になるまでに必要なエージング時間(エージング温度:25℃)が、同条件でエージングされた種結晶を配合されていない油性菓子と比較すると、5日〜9日間短縮することができる。 The aging time is appropriately adjusted depending on the composition of the oil-based confectionery and the manufacturing process, but is preferably 1 day or more. According to the method of blending the seed crystals, by blending the seed crystals with the oil-based confectionery dough, the aging time required for the oil-based confectionery to obtain heat resistance can be shortened. For example, in the manufacturing process, an oil-based confectionery containing 0.9% by weight to 5% by weight of a melted liquid sugar and 0.8% by weight to 2% by weight of seed crystals as sugars in the oil-based confectionery has a temperature of 35 ° C. As described above, the aging time (aging temperature: 25 ° C.) required to reach the state of having heat resistance is shortened by 5 to 9 days as compared with the oil-based confectionery not containing the seed crystal aged under the same conditions. be able to.

(せん断作用によるエージング時間の短縮)
更に別の実施形態において、混合生地を得る工程は、エージング時間短縮の観点から、室温で固体の糖質であって、加熱により融液状となっている糖質を、油性菓子の全重量に対して1重量%〜50重量%未満となるように油性菓子生地に添加し、せん断作用を与えながら混合されてもよい。メカニズムの詳細は不明であるが、せん断作用を与えながら混合することで得られる油性菓子は、同じ糖質について「結晶糖質」のみで配合された油性菓子よりも、少なくとも5℃以上高い耐熱性を有している。特に、糖質としてキシリトール融液を油性菓子中に2重量%〜10重量%配合された油性菓子は、45℃で1時間以上静置された後においても変形しないという著しく高い耐熱性を有している。本発明の油性菓子は、高温で静置されても形状が変化しない一方で、口中では従来のチョコレートと変わらない口どけ、食感、風味を有している。
(Reduction of aging time due to shearing action)
In yet another embodiment, in the step of obtaining the mixed dough, from the viewpoint of shortening the aging time, the sugar which is a solid sugar at room temperature and becomes a melted liquid by heating is added to the total weight of the oil-based confectionery. It may be added to the oil-based confectionery dough so as to be less than 1% by weight to less than 50% by weight, and mixed while giving a shearing action. Although the details of the mechanism are unknown, the oil-based confectionery obtained by mixing while applying a shearing action has a heat resistance at least 5 ° C. higher than that of the oil-based confectionery containing only "crystalline sugar" for the same sugar. have. In particular, an oil-based confectionery containing 2% by weight to 10% by weight of a xylitol melt as a sugar has extremely high heat resistance that it does not deform even after being allowed to stand at 45 ° C. for 1 hour or more. ing. The oil-based confectionery of the present invention does not change its shape even when left to stand at a high temperature, but has the same mouthfeel, texture and flavor as conventional chocolate in the mouth.

せん断作用を与えながら混合する場合、融液状の糖質は、油性菓子の全重量に対して1重量%〜20重量%であることが好ましく、2重量%〜10重量%がより好ましく、更により好ましくは2重量%〜5重量%である。1重量%よりも融液状の糖質が少ない場合は、耐熱性の効果が十分に得られにくい。また、50重量%よりも融液状の糖質が多い場合は、融液状の糖質を油性菓子の他原料と混合する工程で、著しく粘度が上昇するために混練作業を連続して行うことが困難となるか、もしくは、前記した混合工程において相転移が起こって、油脂が連続層の口どけがよい油性菓子が得られなくなる。そもそも、融液状の糖質が50重量%超添加された場合に得られる最終製品は油性菓子と呼べないものとなる。 When mixing while giving a shearing action, the melted liquid sugar is preferably 1% by weight to 20% by weight, more preferably 2% by weight to 10% by weight, still more, based on the total weight of the oil-based confectionery. It is preferably 2% by weight to 5% by weight. When the amount of melted sugar is less than 1% by weight, it is difficult to obtain a sufficient heat resistance effect. When the amount of melted liquid sugar is more than 50% by weight, the kneading operation may be continuously performed in the step of mixing the melted liquid sugar with other raw materials of oil-based confectionery because the viscosity increases remarkably. It becomes difficult, or a phase transition occurs in the above-mentioned mixing step, and it becomes impossible to obtain an oil-based confectionery having a continuous layer of fats and oils that melts in the mouth. In the first place, the final product obtained when more than 50% by weight of the melted liquid sugar is added cannot be called an oil-based confectionery.

(油性菓子生地と融液状の糖質とをせん断作用を与えながら混合する工程)
本混合工程における諸条件等は、特に断らない限り、上述した種結晶が配合されない場合のものと同様である。
(The process of mixing oil-based confectionery dough and melt-liquid sugar while applying shearing action)
Unless otherwise specified, the conditions and the like in this mixing step are the same as those in the case where the above-mentioned seed crystals are not blended.

本混合工程において、融液状の糖質をその種結晶が配合された流動状態の油性菓子生地に対して均一に分散して混合することは、耐熱性油性菓子を確実に得るために重要である。 In this mixing step, it is important to uniformly disperse and mix the melted liquid sugar in the fluid confectionery dough containing the seed crystals in order to surely obtain a heat-resistant oil-based confectionery. ..

本混合工程において、混合装置は、せん断作用を与えながら混合することが可能であれば、特に限定されない。例えば、菓子分野で汎用されているタイプのホモジナイザー、ミキサー(ケンミックス(登録商標)、モンドミックス(登録商標)、等)、スクリューニーダー、エクストルーダー、ハイシアミキサー、等を用いることができる。 In this mixing step, the mixing device is not particularly limited as long as it can be mixed while applying a shearing action. For example, a homogenizer, a mixer (Kenmix (registered trademark), Mondomix (registered trademark), etc.), a screw kneader, an extruder, a high shear mixer, etc., which are widely used in the confectionery field, can be used.

本混合工程における「せん断作用を与えながら混合する」ための混合条件(混合機の回転速度、回転羽根の形状、等)は、油性菓子生地や融液状の糖質の組成、全体量、温度等に応じて適宜選択することが可能である。実施態様が以下に限定されるものではないが、具体例を示す。ホモジナイザーとして、ヒスコトロンNS−57S8(株式会社マイクロテック・ニチオン製、シャフト形式:NS−20)を用いる場合、回転数1,000rmp〜11,000rpmで30秒間〜1分間混合することが好ましい。ミキサーとして、ケンミックスKMM770(デロンギ・ジャパン株式会社製、撹拌子:ホイッパー)を用いる場合、回転数430rpm〜450rpmで4分〜10分間混合することが好ましく、モンドミックス(モンドミックス社製)を用いる場合、回転数265rpm〜300rpmでポンプ送液量40kg/hにより混合することが好ましい。スクリューニーダーとして、二軸ニーダーを用いる場合、ジャケット温水温度設定60℃にて30分〜60分混合することが好ましい。 The mixing conditions for "mixing while giving shearing action" in this mixing step (rotation speed of the mixer, shape of rotating blades, etc.) are the composition, total amount, temperature, etc. of oil-based confectionery dough and melt-liquid sugar. It is possible to select as appropriate according to the above. The embodiment is not limited to the following, but a specific example is shown. When Hiscotron NS-57S8 (manufactured by Microtech Nithion Co., Ltd., shaft type: NS-20) is used as the homogenizer, it is preferable to mix at a rotation speed of 1,000 rpm to 11,000 rpm for 30 seconds to 1 minute. When Kenmix KMM770 (manufactured by Delonghi Japan Co., Ltd., stirrer: whipper) is used as a mixer, it is preferable to mix at a rotation speed of 430 rpm to 450 rpm for 4 to 10 minutes, and Mondomix (manufactured by Mondomix) is used. In this case, it is preferable to mix at a rotation speed of 265 rpm to 300 rpm with a pump liquid feed rate of 40 kg / h. When a biaxial kneader is used as the screw kneader, it is preferable to mix at a jacket hot water temperature setting of 60 ° C. for 30 to 60 minutes.

本混合工程により、得られる混合生地が、混合後の成形作業(特に充填作業)が可能な性状を維持したままで、融液状の糖質が油性菓子生地に均一に分散された状態になることが好ましい。メカニズムの詳細は不明であるが、本混合工程において高いせん断力で融液状の糖質と油性菓子生地とを混合することにより、混合中に融液状の糖質の結晶化が促進されると推定される。その結果、油性菓子に耐熱性を付与する糖骨格が形成されるまでに必要な時間が、穏やかに撹拌した後に静置状態でエージングした場合に必要な時間よりも短縮されると考えられる。 By this mixing step, the obtained mixed dough is in a state where the melt-liquid sugar is uniformly dispersed in the oil-based confectionery dough while maintaining the property that the molding work (particularly the filling work) after mixing is possible. Is preferable. Although the details of the mechanism are unknown, it is presumed that the crystallization of the melt-liquid sugar is promoted during the mixing by mixing the melt-liquid sugar and the oil-based confectionery dough with a high shearing force in this mixing step. Will be done. As a result, it is considered that the time required for the sugar skeleton that imparts heat resistance to the oil-based confectionery is formed is shorter than the time required for aging in a stationary state after gentle stirring.

エージングの時間は、油性菓子の組成や製造工程によって適宜調整されるが、1日以上であることが好ましい。油性菓子生地又は混合生地を、せん断作用を与えながら混合することにより、油性菓子が耐熱性を得るまでに必要なエージング時間を短縮することができる。例えば、製造工程において糖質として油性菓子中に融液状の糖質を2重量%〜5重量%配合された油性菓子は、35℃以上で耐熱性を有する状態になるまでに必要なエージング時間(エージング温度:25℃)が、同条件でエージングされた融液状の糖質が配合された油性菓子と比較すると、9日〜13日間短縮することができる。 The aging time is appropriately adjusted depending on the composition of the oil-based confectionery and the manufacturing process, but is preferably 1 day or more. By mixing the oil-based confectionery dough or the mixed dough while giving a shearing action, the aging time required for the oil-based confectionery to obtain heat resistance can be shortened. For example, in an oil-based confectionery in which 2% by weight to 5% by weight of a melt-liquid sugar is blended as a sugar in the oil-based confectionery in the manufacturing process, the aging time required for the oil-based confectionery to become heat-resistant at 35 ° C. or higher ( The aging temperature (aging temperature: 25 ° C.) can be shortened by 9 to 13 days as compared with the oil-based confectionery containing the melt-liquid sugar aged under the same conditions.

第二の実施形態において、本発明は、上記耐熱性を有する油性菓子の製造方法により得られる、油性菓子、を提供する。油性菓子等の定義は上述したとおりである。 In the second embodiment, the present invention provides an oil-based confectionery obtained by the above-mentioned method for producing an oil-based confectionery having heat resistance. The definitions of oil-based confectionery and the like are as described above.

第三の実施形態において、本発明は、室温で固体の糖質であって、加熱により融液状となっている糖質を油性菓子生地に添加することにより、油性菓子の耐熱性を向上させる方法、を提供する。糖質、油性菓子等の定義は上述したとおりである。 In a third embodiment, the present invention is a method for improving the heat resistance of an oil-based confectionery by adding a sugar that is a solid sugar at room temperature and becomes a melt-liquid by heating to an oil-based confectionery dough. ,I will provide a. The definitions of sugar, oil-based confectionery, etc. are as described above.

(油性菓子の耐熱性を向上させる方法)
製造工程において糖質として油性菓子中に融液状の糖質を1重量%〜20重量%配合された油性菓子は、融液状の糖質が配合されていない油性菓子が30℃で1時間静置された場合は静置前の形状を維持できないのに対して、30℃をはるかに超える35℃以上でも形状を維持し、なおかつ持ち上げることができる程度の硬さを有する程度まで耐熱性を向上させることができる。融液状の糖質を添加する前の油性菓子生地は流動状態にあることが好ましい。流動状態に必要な温度等については上述したとおりである。
(How to improve the heat resistance of oil-based confectionery)
In the manufacturing process, oil-based confectionery containing 1% by weight to 20% by weight of melt-liquid sugar as sugar is left to stand at 30 ° C. for 1 hour for oil-based confectionery that does not contain melt-liquid sugar. When this is done, the shape before standing cannot be maintained, but the shape is maintained even at 35 ° C or higher, which far exceeds 30 ° C, and the heat resistance is improved to the extent that it has a hardness sufficient to be lifted. be able to. It is preferable that the oil-based confectionery dough before adding the melted liquid sugar is in a fluid state. The temperature and the like required for the flow state are as described above.

第四の実施形態において、本発明は、室温で固体の糖質であって、加熱により融液状となっている糖質を有効成分として含む、油性菓子に対する耐熱性付与剤、を提供する。室温で固体の糖質であって、加熱により融液状となっている糖質については上述したとおりである。耐熱性付与剤には、本発明の効果を損なわない範囲において、カカオ豆由来原料(カカオマス、ココアパウダー、ココアバター、カカオ豆原料由来抽出物、等)、融液状の糖質以外の糖質、生乳由来原料(全脂粉乳、脱脂粉乳、等)、油脂、乳化剤、香料等を配合してもよい。 In a fourth embodiment, the present invention provides a heat resistance imparting agent for oil-based confectionery, which contains a sugar which is a solid sugar at room temperature and becomes a melt-liquid by heating as an active ingredient. The sugars that are solid at room temperature and become melted by heating are as described above. Heat resistance imparting agents include raw materials derived from cocoa beans (cocoa mass, cocoa powder, cocoa butter, extracts derived from cocoa bean raw materials, etc.), sugars other than melted sugars, as long as the effects of the present invention are not impaired. Raw milk-derived raw materials (whole fat powder milk, skim milk powder, etc.), fats and oils, emulsifiers, flavors and the like may be blended.

別の実施形態において、耐熱性付与剤は更に、融液状の糖質の種結晶を有効成分として含んでもよい。 In another embodiment, the heat resistance imparting agent may further contain a melted liquid sugar seed crystal as an active ingredient.

本発明を以下の例によって詳細に説明するが、本発明はこれらに限定されるものではない。 The present invention will be described in detail by the following examples, but the present invention is not limited thereto.

[耐熱性の評価方法]
以下の例において、エージングされた後の油性菓子を35℃(一部の実施例では30℃、45℃)環境下で1時間静置した後、指でかるく押して、変形の程度を確認することにより耐熱性を評価した。以下に示した評価結果がCを「耐熱性を有する」、評価結果がBを「高い耐熱性を有する」、評価結果Aを「著しく高い耐熱性を有する」とした。
評価:A … 外観の形状が静置前後で変化しない。指でつまんだ時に油性菓子が指に付着しない。複数回触れても変形しにくい。
評価:B … 外観の形状が静置前後でほぼ維持されている。指でつまんだ時に油性菓子が指に付着しない。複数回触れると、やや変形することがある。
評価:C … 外観の形状が静置前後でほぼ維持されている。バット上に置いた際に衝撃を与えても形状は保っている。指でつまんで持ち上げることが可能であるが、指に油性菓子が付着する。複数回触れると、やや変形することがある。
評価:D … 静置前の形状が保たれていない(崩れている)。指でつまむことができない。
[Evaluation method of heat resistance]
In the following example, the aged oil-based confectionery is allowed to stand in an environment of 35 ° C. (30 ° C., 45 ° C. in some examples) for 1 hour, and then lightly pressed with a finger to check the degree of deformation. The heat resistance was evaluated by. The evaluation results shown below set C as "having heat resistance", the evaluation result B as "having high heat resistance", and the evaluation result A as "having extremely high heat resistance".
Evaluation: A ... The shape of the appearance does not change before and after standing. Oily confectionery does not adhere to fingers when pinched with fingers. Hard to deform even if touched multiple times.
Evaluation: B ... The shape of the appearance is almost maintained before and after standing. Oily confectionery does not adhere to fingers when pinched with fingers. If you touch it multiple times, it may be slightly deformed.
Evaluation: C ... The shape of the appearance is almost maintained before and after standing. The shape is maintained even if it is impacted when placed on the bat. It is possible to pinch and lift with fingers, but oily confectionery adheres to the fingers. If you touch it multiple times, it may be slightly deformed.
Evaluation: D ... The shape before standing is not maintained (collapsed). I can't pinch with my fingers.

[硬度の測定方法]
以下の例において、硬度の測定は以下に示す条件で実施した。なお、硬度測定用サンプルは、一辺が約15mmの略立方体形状に成形された油性菓子を一定温度(30℃、35℃、又は45℃)の恒温機に1時間静置した後、取り出した直後のものを用いた。
測定機器:FUDOHレオメーターRTC−3010D−CW
プランジャー:直径15mmの円筒状のプランジャー(プラスチック素材)
プランジャーの進入速度:2cm/分
プランジャーの進入深度:3mm 上記の条件において、硬度が100gf以上である場合「耐熱性を有する」とした。
[Hardness measurement method]
In the following example, the hardness was measured under the conditions shown below. The hardness measurement sample was prepared by allowing an oil-based confectionery molded into a substantially cubic shape having a side of about 15 mm in a constant temperature (30 ° C., 35 ° C., or 45 ° C.) incubator for 1 hour, and then immediately taking it out. Was used.
Measuring equipment: FUDOH rheometer RTC-3010D-CW
Plunger: Cylindrical plunger with a diameter of 15 mm (plastic material)
Plunger approach speed: 2 cm / minute Plunger approach depth: 3 mm Under the above conditions, when the hardness is 100 gf or more, it is considered to have "heat resistance".

[粘度の測定方法]
以下の例において、油性菓子生地、又は成形前の混合生地の粘度の測定は、B型粘度計を用い、40℃で、ローターNo.6を用いて、回転速度が4rpmの条件で実施した。
[Viscosity measurement method]
In the following example, the viscosity of the oil-based confectionery dough or the mixed dough before molding was measured using a B-type viscometer at 40 ° C. 6 was used under the condition that the rotation speed was 4 rpm.

[実施例1−1]ソルビトール融液を配合した耐熱性油性菓子
(1)ソルビトール結晶粉末を120℃まで加熱して、ソルビトールを融解させたソルビトール融液を調製した。
(2)カカオマス20重量部、ココアバター17.5重量部、全粉乳20重量部、乳化剤(レシチン)0.5重量部、香料0.1重量部、砂糖42重量部を常法により混合、粉砕及びコンチングして油性菓子生地1を調製した。流動状態(50℃)である前記油性菓子生地1を95重量部に対して、前記(1)で調製したソルビトール融液を90℃まで冷却した後に5重量部となるように添加して、おだやかに混合した。前記混合時の生地に含まれる油分は33重量%であった。ソルビトール融液が添加された混合生地97重量部を35℃まで徐冷し、シード剤(不二製油株式会社製、商品名:チョコシードB)3重量部を添加し、更に混合した。
(3)前記(2)でシード剤を混合して得られた混合生地をモールドに充填した後、冷却固化させ、モールドから外して油性菓子を得た。得られた油性菓子を、25℃で20日間エージングした。
[Example 1-1] Heat-resistant oily confectionery containing a sorbitol melt (1) A sorbitol melt was prepared by heating sorbitol crystal powder to 120 ° C. to melt sorbitol.
(2) 20 parts by weight of cocoa mass, 17.5 parts by weight of cocoa butter, 20 parts by weight of whole milk powder, 0.5 parts by weight of emulsifier (lecithin), 0.1 parts by weight of flavor, and 42 parts by weight of sugar are mixed and crushed by a conventional method. And conching to prepare an oil-based confectionery dough 1. The oil-based confectionery dough 1 in a fluid state (50 ° C.) is added to 95 parts by weight of the sorbitol melt prepared in (1) above to 90 ° C. and then added to 5 parts by weight to make it mild. Mixed in. The oil content in the dough at the time of mixing was 33% by weight. 97 parts by weight of the mixed dough to which the sorbitol melt was added was slowly cooled to 35 ° C., 3 parts by weight of a seed agent (manufactured by Fuji Oil Co., Ltd., trade name: chocolate seed B) was added, and the mixture was further mixed.
(3) The mixed dough obtained by mixing the seed agent in (2) above was filled in a mold, then cooled and solidified, and removed from the mold to obtain an oil-based confectionery. The obtained oil-based confectionery was aged at 25 ° C. for 20 days.

前記(3)で調製された油性菓子について、35℃における耐熱性を評価したところ、35℃における高い耐熱性(評価:B)を有するだけでなく、風味、食感、口どけのいずれも従来のチョコレートと同様に良好であった。風味の中でも甘味については、同一の糖質を用いて従来の製法で製造される油性菓子と同程度であった。 When the heat resistance of the oil-based confectionery prepared in (3) above was evaluated at 35 ° C., not only did it have high heat resistance at 35 ° C. (evaluation: B), but also the flavor, texture, and melting in the mouth were all conventional. It was as good as the chocolate. Among the flavors, the sweetness was about the same as that of oil-based confectionery produced by the conventional manufacturing method using the same sugar.

[実施例1−2]ソルビトール融液を配合した耐熱性油性菓子
実施例1−1(2)において、油性菓子生地1を90重量部に対して、ソルビトール融液を10重量部となるように添加混合する以外は、実施例1−1と同様の手順で油性菓子を調製した。得られた油性菓子を25℃で20日間エージングした後、同様に耐熱性を評価したところ、35℃における高い耐熱性(評価:B)を有するだけでなく、風味、食感、口どけのいずれも従来のチョコレートと同様に良好であった。風味の中でも甘味については、同一の糖質を用いて従来の製法で製造される油性菓子と同程度であった。
[Example 1-2] Heat-resistant oil-based confectionery containing sorbitol melt In Example 1-1 (2), the oil-based confectionery dough 1 is 90 parts by weight and the sorbitol melt is 10 parts by weight. An oil-based confectionery was prepared in the same procedure as in Example 1-1 except for addition and mixing. After aging the obtained oil-based confectionery at 25 ° C. for 20 days, the heat resistance was evaluated in the same manner. As a result, not only the obtained oil-based confectionery had high heat resistance at 35 ° C. (evaluation: B), but also any of flavor, texture, and melting in the mouth. Was as good as conventional chocolate. Among the flavors, the sweetness was about the same as that of oil-based confectionery produced by the conventional manufacturing method using the same sugar.

[実施例1−3]ソルビトール融液を配合した耐熱性油性菓子
実施例1−1(2)において、油性菓子生地1を80重量部に対して、ソルビトール融液を20重量部となるように添加混合する以外は、実施例1−1と同様の手順で油性菓子を調製した。ただし、油性菓子のエージングは25℃で15日間とした。エージングした後、同様に耐熱性を評価したところ、35℃における高い耐熱性(評価:B)を有するだけでなく、風味、食感、口どけのいずれも従来のチョコレートと同様に良好であった。風味の中でも甘味については、同一の糖質を用いて従来の製法で製造される油性菓子と同程度であった。
[Example 1-3] Heat-resistant oil-based confectionery containing sorbitol melt In Example 1-1 (2), the oil-based confectionery dough 1 is 80 parts by weight and the sorbitol melt is 20 parts by weight. An oil-based confectionery was prepared in the same procedure as in Example 1-1 except for addition and mixing. However, the aging of the oil-based confectionery was set at 25 ° C. for 15 days. When the heat resistance was evaluated in the same manner after aging, not only was it highly heat resistant at 35 ° C. (evaluation: B), but also the flavor, texture, and melting in the mouth were all as good as those of conventional chocolate. .. Among the flavors, the sweetness was about the same as that of oil-based confectionery produced by the conventional manufacturing method using the same sugar.

[実施例1−4]ソルビトール融液を配合した耐熱性油性菓子
実施例1−1(2)において、油性菓子生地1を95重量部に対して、ソルビトール融液を5重量部添加する際に、更にココアバターを添加混合することにより、混合生地中の油分を35重量%となるように調整する以外は、実施例1−1と同様の手順で油性菓子を調製した。得られた油性菓子を25℃で20日間エージングした後、同様に耐熱性を評価したところ、35℃における高い耐熱性(評価:B)を有するだけでなく、風味、食感、口どけのいずれも従来のチョコレートと同様に良好であった。風味の中でも甘味については、同一の糖質を用いて従来の製法で製造される油性菓子と同程度であった。
[Example 1-4] Heat-resistant oil-based confectionery containing sorbitol melt In Example 1-1 (2), when adding 5 parts by weight of sorbitol melt to 95 parts by weight of oil-based confectionery dough 1. An oil-based confectionery was prepared in the same procedure as in Example 1-1, except that the oil content in the mixed dough was adjusted to 35% by weight by further adding and mixing cocoa butter. After aging the obtained oil-based confectionery at 25 ° C. for 20 days, the heat resistance was evaluated in the same manner. As a result, not only the obtained oil-based confectionery had high heat resistance at 35 ° C. (evaluation: B), but also any of flavor, texture, and melting in the mouth. Was as good as conventional chocolate. Among the flavors, the sweetness was about the same as that of oil-based confectionery produced by the conventional manufacturing method using the same sugar.

[比較例1−1]
実施例1−1(2)で調製した油性菓子生地1を50重量部に対して、実施例1−1(1)で調製したソルビトール融液50重量部を90℃まで冷却した後に添加して、おだやかに混合した。混合された生地は、乳化状態がW/O型からO/W型へ変化したため、実施例1−1と同様の手順で油性菓子を成形することができなかった。
[Comparative Example 1-1]
To 50 parts by weight of the oil-based confectionery dough 1 prepared in Example 1-1 (2), 50 parts by weight of the sorbitol melt prepared in Example 1-1 (1) was added after cooling to 90 ° C. , Gently mixed. Since the emulsified state of the mixed dough changed from W / O type to O / W type, it was not possible to mold oil-based confectionery by the same procedure as in Example 1-1.

[比較例1−2]
実施例1−1(2)で調製した油性菓子生地1を用いて、ソルビトール融液を配合せずに、実施例1−1(3)と同様の手順で油性菓子を調製した。得られた油性菓子を、35℃で1時間静置したところ、静置前の形状が保たれていなかった。(評価:D)。
[Comparative Example 1-2]
Using the oil-based confectionery dough 1 prepared in Example 1-1 (2), an oil-based confectionery was prepared in the same procedure as in Example 1-1 (3) without blending the sorbitol melt. When the obtained oil-based confectionery was allowed to stand at 35 ° C. for 1 hour, the shape before standing was not maintained. (Evaluation: D).

[比較例1−3]
実施例1−1(2)で調製した油性菓子生地1を95重量部に対して、実施例1−1(1)で使用したソルビトール粉末5重量部を添加して、おだやかに混合した後、実施例1−1(3)と同様の手順で油性菓子を調製した。得られた油性菓子を、35℃で1時間静置したところ、静置前の形状が保たれていなかった。(評価:D)。
[Comparative Example 1-3]
After adding 5 parts by weight of the sorbitol powder used in Example 1-1 (1) to 95 parts by weight of the oil-based confectionery dough 1 prepared in Example 1-1 (2) and mixing gently. An oil-based confectionery was prepared in the same procedure as in Example 1-1 (3). When the obtained oil-based confectionery was allowed to stand at 35 ° C. for 1 hour, the shape before standing was not maintained. (Evaluation: D).

実施例1−1〜4、及び比較例1−1〜3の結果を表1に示した。5重量%〜20重量%のソルビトール融液を配合して調製された油性菓子は、35℃で1時間静置された後でも変形しない高い耐熱性を有していた。また、得られた耐熱性油性菓子は、いずれも食感、風味、口どけが従来のチョコレートと同様によいものであった。風味の中でも甘味については、同一の糖質を用いて従来の製法で製造される油性菓子と同程度であった。 The results of Examples 1-1 to 4 and Comparative Examples 1-1 to 3 are shown in Table 1. The oil-based confectionery prepared by blending 5% by weight to 20% by weight of the sorbitol melt had high heat resistance that did not deform even after being allowed to stand at 35 ° C. for 1 hour. In addition, all of the obtained heat-resistant oil-based confectioneries had good texture, flavor, and melting in the mouth as well as conventional chocolate. Among the flavors, the sweetness was about the same as that of oil-based confectionery produced by the conventional manufacturing method using the same sugar.

Figure 2019240138
Figure 2019240138

[実施例2−1]キシリトール融液を配合した耐熱性油性菓子
(1)キシリトール結晶粉末を110℃まで加熱して、キシリトールを融解させたキシリトール融液を調製した。
(2)実施例1−1と同様にして油性菓子生地1を調製した。流動状態(60℃)である前記油性菓子生地1を95重量部に対して、前記(1)で調製したキシリトール融液を90℃まで冷却した後、5重量部となるように添加して、おだやかに混合した。前記混合時の生地に含まれる油分は33重量%であった。キシリトール融液が添加された混合生地97重量部を35℃まで徐冷し、シード剤(不二製油株式会社製、商品名:チョコシードB)3重量部を添加し、更に混合した。
(3)前記(2)でシード剤を混合して得られた混合生地をモールドに充填した後、冷却固化させ、モールドから外した。得られた油性菓子を、25℃で14日間エージングした。
[Example 2-1] Heat-resistant oil-based confectionery containing a xylitol melt (1) A xylitol crystal powder was heated to 110 ° C. to prepare a xylitol melt in which xylitol was melted.
(2) Oil-based confectionery dough 1 was prepared in the same manner as in Example 1-1. The xylitol melt prepared in (1) above was cooled to 90 ° C. with respect to 95 parts by weight of the oil-based confectionery dough 1 in a flowing state (60 ° C.), and then added to 5 parts by weight. Gently mixed. The oil content in the dough at the time of mixing was 33% by weight. 97 parts by weight of the mixed dough to which the xylitol melt was added was slowly cooled to 35 ° C., 3 parts by weight of a seed agent (manufactured by Fuji Oil Co., Ltd., trade name: chocolate seed B) was added, and the mixture was further mixed.
(3) The mixed dough obtained by mixing the seed agent in (2) above was filled in a mold, then cooled and solidified, and removed from the mold. The obtained oil-based confectionery was aged at 25 ° C. for 14 days.

前記(3)で調製された油性菓子について、35℃における耐熱性を評価したところ、35℃における著しく高い耐熱性(評価:A)を有するだけでなく、風味、食感、口どけのいずれも従来のチョコレートと同様に良好であった。風味の中でも甘味については、同一の糖質を用いて従来の製法で製造される油性菓子と同程度であった。 When the heat resistance of the oil-based confectionery prepared in (3) above was evaluated at 35 ° C., it not only had extremely high heat resistance at 35 ° C. (evaluation: A), but also had a flavor, texture, and melting in the mouth. It was as good as conventional chocolate. Among the flavors, the sweetness was about the same as that of oil-based confectionery produced by the conventional manufacturing method using the same sugar.

[実施例2−2]キシリトール融液を配合した耐熱性油性菓子
実施例2−1(2)において、油性菓子生地1を90重量部に対して、キシリトール融液を10重量部となるように添加混合する以外は、実施例2−1と同様の手順で油性菓子を調製した。ただし、キシリトール融液と油性菓子生地を均一に混合することは可能だったが、一般的な充填機を用いた型への充填作業を行うことは困難であった。なお、油性菓子のエージングは25℃で1日間とした。エージングした後、同様に耐熱性を評価したところ、35℃における著しく高い耐熱性(評価:A)を有するだけでなく、風味、食感、口どけのいずれも従来のチョコレートと同様に良好であった。風味の中でも甘味については、同一の糖質を用いて従来の製法で製造される油性菓子と同程度であった。
[Example 2-2] Heat-resistant oil-based confectionery containing xylitol melt In Example 2-1 (2), the oil-based confectionery dough 1 is 90 parts by weight and the xylitol melt is 10 parts by weight. An oil-based confectionery was prepared in the same procedure as in Example 2-1 except for addition and mixing. However, although it was possible to uniformly mix the xylitol melt and the oil-based confectionery dough, it was difficult to fill the mold using a general filling machine. The aging of the oil-based confectionery was set at 25 ° C. for one day. After aging, the heat resistance was evaluated in the same manner. As a result, not only the heat resistance at 35 ° C. was remarkably high (evaluation: A), but also the flavor, texture, and melting in the mouth were all as good as those of the conventional chocolate. It was. Among the flavors, the sweetness was about the same as that of oil-based confectionery produced by the conventional manufacturing method using the same sugar.

[実施例2−3]キシリトール融液を配合した耐熱性油性菓子
実施例2−1(2)において、油性菓子生地1を95重量部に対して、キシリトール融液を5重量部添加する際に、更にココアバターを添加混合することにより、混合生地中の油分を35重量%とする以外は、実施例2−1と同様の手順で油性菓子を調製した。ただし、油性菓子のエージングは25℃で14日間とした。成型前の混合生地の粘度を測定したところ、142,500cpsであった。エージングした後、同様に耐熱性を評価したところ、45℃における著しく高い耐熱性(評価:A)を有するだけでなく、風味、食感、口どけのいずれも従来のチョコレートと同様に良好であった。風味の中でも甘味については、同一の糖質を用いて従来の製法で製造される油性菓子と同程度であった。
[Example 2-3] Heat-resistant oil-based confectionery containing xylitol melt In Example 2-1 (2), when adding 5 parts by weight of xylitol melt to 95 parts by weight of oil-based confectionery dough 1. An oil-based confectionery was prepared in the same procedure as in Example 2-1 except that the oil content in the mixed dough was 35% by weight by further adding and mixing cocoa butter. However, the aging of the oil-based confectionery was set at 25 ° C. for 14 days. The viscosity of the mixed dough before molding was measured and found to be 142,500 cps. After aging, the heat resistance was evaluated in the same manner. As a result, not only the heat resistance at 45 ° C. was remarkably high (evaluation: A), but also the flavor, texture, and melting in the mouth were all as good as those of the conventional chocolate. It was. Among the flavors, the sweetness was about the same as that of oil-based confectionery produced by the conventional manufacturing method using the same sugar.

[比較例2−1]
実施例2−1(2)で調製した油性菓子生地1を95重量部に対して、実施例2−1(1)で使用したキシリトール結晶粉末5重量部を添加して、おだやかに混合した後、実施例2−1(3)と同様の手順で油性菓子を調製した。得られた油性菓子を35℃で1時間静置したところ、静置前の形状が保たれていなかった。(耐熱性評価:D)。
[Comparative Example 2-1]
After adding 5 parts by weight of the xylitol crystal powder used in Example 2-1 (1) to 95 parts by weight of the oil-based confectionery dough 1 prepared in Example 2-1 (2) and gently mixing. , An oil-based confectionery was prepared in the same procedure as in Example 2-1 (3). When the obtained oil-based confectionery was allowed to stand at 35 ° C. for 1 hour, the shape before standing was not maintained. (Heat resistance evaluation: D).

実施例2−1〜3、及び比較例2−1の結果を表2に示した。5重量%〜10重量%のキシリトール融液を配合して調製された油性菓子は、35℃で1時間静置された後でも変形しない高い耐熱性を有していた。特に、キシリトール融液が5重量%添加された油性菓子(実施例2−3)は、45℃で1時間静置された後でも変形しない著しく優れた耐熱性を有していた。また、得られた耐熱性を有する油性菓子は、いずれも食感、風味、口どけが従来のチョコレートと同様によいものであった。風味の中でも甘味については、同一の糖質を用いて従来の製法で製造される油性菓子と同程度であった。 The results of Examples 2-1 to 3 and Comparative Example 2-1 are shown in Table 2. The oil-based confectionery prepared by blending 5% by weight to 10% by weight of xylitol melt had high heat resistance that did not deform even after being allowed to stand at 35 ° C. for 1 hour. In particular, the oil-based confectionery (Example 2-3) to which 5% by weight of the xylitol melt was added had extremely excellent heat resistance that did not deform even after being allowed to stand at 45 ° C. for 1 hour. In addition, the obtained heat-resistant oil-based confectionery had a good texture, flavor, and melting in the mouth as well as conventional chocolate. Among the flavors, the sweetness was about the same as that of oil-based confectionery produced by the conventional manufacturing method using the same sugar.

Figure 2019240138
Figure 2019240138

[実施例3−1]キシリトール融液配合による低融点油脂配合油性菓子の耐熱化
(1)キシリトール結晶粉末を130℃まで加熱して、キシリトールを融解させたキシリトール融液を調製した。
(2)実施例1−1と同様にして油性菓子生地1を調製した。流動状態(60℃)である前記油性菓子生地1を95重量部に対して、前記(1)で調製したキシリトール融液を90℃まで冷却した後、5重量部となるように添加して、おだやかに混合した。更に、低融点油脂(基準油脂分析試験法による20℃におけるSFC測定値が42%〜45%である市販油脂)を添加することにより、前記混合時の生地に含まれる油分が50重量%となるように調整した。キシリトール融液及び低融点油脂が添加された混合生地97重量部を35℃まで徐冷し、シード剤(不二製油株式会社製、商品名:チョコシードB)3重量部を添加し、更に混合した。
(3)前記(2)でシード剤を混合して得られた混合生地をモールドに充填した後、冷却固化させ、モールドから外した。得られた油性菓子を、25℃で7日間エージングした。
[Example 3-1] Heat resistance of oil-based confectionery containing low melting point oil and fat by blending xylitol melt (1) The xylitol crystal powder was heated to 130 ° C. to prepare a xylitol melt in which xylitol was melted.
(2) Oil-based confectionery dough 1 was prepared in the same manner as in Example 1-1. The xylitol melt prepared in (1) above was cooled to 90 ° C. with respect to 95 parts by weight of the oil-based confectionery dough 1 in a flowing state (60 ° C.), and then added to 5 parts by weight. Gently mixed. Further, by adding a low melting point fat and oil (commercially available fat and oil having an SFC measurement value of 42% to 45% at 20 ° C. by the standard fat and oil analysis test method), the oil content in the dough at the time of mixing becomes 50% by weight. Adjusted to. 97 parts by weight of the mixed dough to which the xylitol melt and the low melting point fat were added was slowly cooled to 35 ° C., 3 parts by weight of a seed agent (manufactured by Fuji Oil Co., Ltd., trade name: chocolate seed B) was added, and further mixed. did.
(3) The mixed dough obtained by mixing the seed agent in (2) above was filled in a mold, then cooled and solidified, and removed from the mold. The obtained oil-based confectionery was aged at 25 ° C. for 7 days.

前記(3)で調製された油性菓子について、30℃における耐熱性を評価したところ、30℃における高い耐熱性(評価:B)を有するだけでなく、風味、食感、口どけのいずれも従来のチョコレートと同様に良好であった。風味の中でも甘味については、同一の糖質を用いて従来の製法で製造される油性菓子と同程度であった。 When the heat resistance of the oil-based confectionery prepared in (3) above was evaluated at 30 ° C., not only did it have high heat resistance at 30 ° C. (evaluation: B), but also the flavor, texture, and melting in the mouth were all conventional. It was as good as the chocolate. Among the flavors, the sweetness was about the same as that of oil-based confectionery produced by the conventional manufacturing method using the same sugar.

[比較例3−1]
実施例1−1(2)で調製した油性菓子生地1を用いて、キシリトール融液を配合せずに、実施例3−1(2)で用いたものと同じ低融点油脂を添加することにより油分が50重量%である油性菓子を調製した。得られた油性菓子は、30℃で1時間静置すると、形状を全く維持できずに融解した状態であった(耐熱性評価:D)。
[Comparative Example 3-1]
By using the oil-based confectionery dough 1 prepared in Example 1-1 (2) and adding the same low melting point fat and oil as used in Example 3-1 (2) without blending the xylitol melt. An oil-based confectionery having an oil content of 50% by weight was prepared. When the obtained oil-based confectionery was allowed to stand at 30 ° C. for 1 hour, the shape could not be maintained at all and it was in a melted state (heat resistance evaluation: D).

実施例3−1及び比較例3−1の結果を表3に示した。低融点油脂が添加された油性菓子は、一般的なチョコレートよりも更に低温で融解しやすく調整されている。そのため、口中でさっと融ける独特の食感を有する一方で、指でつまんで持ち上げるときにチョコレートが付着する。5重量%のキシリトール融液を添加して調製された低融点油脂配合油性菓子は、30℃で1時間静置された後でも変形しない高い耐熱性を有していた。また、得られた油性菓子は、いずれも食感、風味、口どけがキシリトール融液を配合されていない低融点油脂配合油性菓子と同様によいものであった。風味の中でも甘味については、同一の糖質を用いて従来の製法で製造される油性菓子と同程度であった。 The results of Example 3-1 and Comparative Example 3-1 are shown in Table 3. Oil-based confectionery to which low-melting point fats and oils are added is adjusted to be easier to melt at a lower temperature than general chocolate. Therefore, while it has a unique texture that melts quickly in the mouth, chocolate adheres when it is picked up with fingers and lifted. The low melting point fat-containing oil-based confectionery prepared by adding 5% by weight of xylitol melt had high heat resistance that did not deform even after being allowed to stand at 30 ° C. for 1 hour. In addition, the obtained oil-based confectionery was as good as the low-melting-point oil-based confectionery containing no xylitol melt in terms of texture, flavor, and melting in the mouth. Among the flavors, the sweetness was about the same as that of oil-based confectionery produced by the conventional manufacturing method using the same sugar.

Figure 2019240138
Figure 2019240138

[実施例4]キシリトール融液を配合した耐熱性油性菓子
(1)キシリトール結晶粉末を130℃まで加熱して、キシリトールを融解させたキシリトール融液を調製した。
(2)ココアバター32重量部、全粉乳30.4重量部、乳化剤(レシチン)0.5重量部、香料0.1重量部、砂糖37重量部を常法により混合、粉砕及びコンチングしてホワイトチョコレート生地-を調製した。流動状態(60℃)である前記ホワイトチョコレート生地を99重量部に対して、前記(1)で調製したキシリトール融液を90℃となるまで冷却した後、1重量部となるように添加して、おだやかに混合した。前記混合時の生地に含まれる油分は40重量%であった。キシリトール融液が添加された混合生地97重量部を35℃まで徐冷し、シード剤(不二製油株式会社製、商品名:チョコシードB)3重量部を添加し、更に混合した。
(3)前記(2)でシード剤を混合して得られた混合生地をモールドに充填した後、冷却固化させ、モールドから外した。得られた油性菓子を、25℃で5日間エージングした。
[Example 4] Heat-resistant oil-based confectionery containing a xylitol melt (1) A xylitol crystal powder was heated to 130 ° C. to prepare a xylitol melt in which xylitol was melted.
(2) 32 parts by weight of cocoa butter, 30.4 parts by weight of whole milk powder, 0.5 parts by weight of emulsifier (lecithin), 0.1 parts by weight of flavor and 37 parts by weight of sugar are mixed, crushed and conched by a conventional method to make white. Chocolate dough-prepared. The white chocolate dough in a flowing state (60 ° C.) is cooled to 90 parts by weight with respect to 99 parts by weight of the xylitol melt prepared in (1), and then added to 1 part by weight. , Gently mixed. The oil content in the dough at the time of mixing was 40% by weight. 97 parts by weight of the mixed dough to which the xylitol melt was added was slowly cooled to 35 ° C., 3 parts by weight of a seed agent (manufactured by Fuji Oil Co., Ltd., trade name: chocolate seed B) was added, and the mixture was further mixed.
(3) The mixed dough obtained by mixing the seed agent in (2) above was filled in a mold, then cooled and solidified, and removed from the mold. The obtained oil-based confectionery was aged at 25 ° C. for 5 days.

前記(3)で調製された油性菓子について、35℃における耐熱性を評価したところ、35℃における高い耐熱性(評価:B)を有するだけでなく、風味、食感、口どけのいずれも従来のチョコレートと同様に良好であった。風味の中でも甘味については、同一の糖質を用いて従来の製法で製造される油性菓子と同程度であった。 When the heat resistance of the oil-based confectionery prepared in (3) above was evaluated at 35 ° C., not only did it have high heat resistance at 35 ° C. (evaluation: B), but also the flavor, texture, and melting in the mouth were all conventional. It was as good as the chocolate. Among the flavors, the sweetness was about the same as that of oil-based confectionery produced by the conventional manufacturing method using the same sugar.

[実施例5]フルクトース融液を配合した耐熱性油性菓子
(1)フルクトース結晶粉末を110℃まで加熱して、フルクトースを融解させたフルクトース融液を調製した。
(2)実施例1−1と同様にして油性菓子生地1を調製した。流動状態(60℃)である前記油性菓子生地1を95重量部に対して、前記(1)で調製したフルクトース融液を90℃となるまで冷却した後、5重量部となるように添加して、おだやかに混合した。前記混合時の生地に含まれる油分は33重量%であった。フルクトース融液が添加された混合生地97重量部を35℃まで徐冷し、シード剤(不二製油株式会社製、商品名:チョコシードB)3重量部を添加し、更に混合した。
(3)前記(2)でシード剤を混合して得られた混合生地をモールドに充填した後、冷却固化させ、モールドから外した。得られた油性菓子を、25℃で20日間エージングした。
[Example 5] Heat-resistant oil-based confectionery containing a fructose melt (1) A fructose crystal powder was heated to 110 ° C. to prepare a fructose melt in which fructose was melted.
(2) Oil-based confectionery dough 1 was prepared in the same manner as in Example 1-1. The fructose melt prepared in (1) above was cooled to 90 ° C. with respect to 95 parts by weight of the oil-based confectionery dough 1 in a flowing state (60 ° C.), and then added to 5 parts by weight. And mixed gently. The oil content in the dough at the time of mixing was 33% by weight. 97 parts by weight of the mixed dough to which the fructose melt was added was slowly cooled to 35 ° C., 3 parts by weight of a seed agent (manufactured by Fuji Oil Co., Ltd., trade name: chocolate seed B) was added, and the mixture was further mixed.
(3) The mixed dough obtained by mixing the seed agent in (2) above was filled in a mold, then cooled and solidified, and removed from the mold. The obtained oil-based confectionery was aged at 25 ° C. for 20 days.

前記(3)で調製された油性菓子について、35℃における耐熱性を評価したところ、35℃における高い耐熱性(評価:B)を有するだけでなく、風味、食感、口どけのいずれも従来のチョコレートと同様に良好であった。風味の中でも甘味については、同一の糖質を用いて従来の製法で製造される油性菓子と同程度であった。 When the heat resistance of the oil-based confectionery prepared in (3) above was evaluated at 35 ° C., not only did it have high heat resistance at 35 ° C. (evaluation: B), but also the flavor, texture, and melting in the mouth were all conventional. It was as good as the chocolate. Among the flavors, the sweetness was about the same as that of oil-based confectionery produced by the conventional manufacturing method using the same sugar.

[実施例6]エリスリトール融液を配合した耐熱性油性菓子
(1)エリスリトール結晶粉末を130℃まで加熱して、エリスリトールを融解させたエリスリトール融液を調製した。
(2)実施例1−1と同様にして油性菓子生地1を調製した。流動状態(60℃)である前記油性菓子生地1を95重量部に対して、前記(1)で調製したエリスリトール融液を90℃となるまで冷却した後、5重量部となるように添加して、おだやかに混合した。前記混合時の生地に含まれる油分は33重量%であった。エリスリトール融液が添加された混合生地97重量部を35℃まで徐冷し、シード剤(不二製油株式会社製、商品名:チョコシードB)3重量部を添加し、更に混合した。
(3)前記(2)でシード剤を混合して得られた混合生地をモールドに充填した後、冷却固化させ、モールドから外した。得られた油性菓子を、25℃で20日間エージングした。
[Example 6] Heat-resistant oil-based confectionery containing an erythritol melt (1) An erythritol crystal powder was heated to 130 ° C. to prepare an erythritol melt in which erythritol was melted.
(2) Oil-based confectionery dough 1 was prepared in the same manner as in Example 1-1. The oil-based confectionery dough 1 in a fluid state (60 ° C.) was cooled to 90 parts by weight with respect to 95 parts by weight of the erythritol melt prepared in (1), and then added to 5 parts by weight. And mixed gently. The oil content in the dough at the time of mixing was 33% by weight. 97 parts by weight of the mixed dough to which the erythritol melt was added was slowly cooled to 35 ° C., 3 parts by weight of a seed agent (manufactured by Fuji Oil Co., Ltd., trade name: chocolate seed B) was added, and the mixture was further mixed.
(3) The mixed dough obtained by mixing the seed agent in (2) above was filled in a mold, then cooled and solidified, and removed from the mold. The obtained oil-based confectionery was aged at 25 ° C. for 20 days.

前記(3)で調製された油性菓子について、35℃における耐熱性を評価したところ、35℃における高い耐熱性(評価:B)を有するだけでなく、風味、食感、口どけのいずれも従来のチョコレートと同様に良好であった。風味の中でも甘味については、同一の糖質を用いて従来の製法で製造される油性菓子と同程度であった。 When the heat resistance of the oil-based confectionery prepared in (3) above was evaluated at 35 ° C., not only did it have high heat resistance at 35 ° C. (evaluation: B), but also the flavor, texture, and melting in the mouth were all conventional. It was as good as the chocolate. Among the flavors, the sweetness was about the same as that of oil-based confectionery produced by the conventional manufacturing method using the same sugar.

[実施例7]
(1)ソルビトール結晶粉末を120℃まで加熱して、ソルビトールを融解させたソルビトール融液を調製した。キシリトール結晶粉末を110℃まで加熱して、キシリトールを融解させたキシリトール融液を調製した。
(2)実施例1−1と同様にして油性菓子生地1を調製した。流動状態(60℃)である前記油性菓子生地1を80重量部に対して、前記(1)で調製したソルビトール融液10重量部及びキシリトール融液10重量部を90℃となるまで冷却した後に添加して、おだやかに混合した。ソルビトール融液及びキシリトール融液が添加された混合生地97重量部を35℃まで徐冷し、シード剤(不二製油株式会社製、商品名:チョコシードB)3重量部を添加し、更に混合した。
(3)前記(2)でシード剤を混合して得られた混合生地をモールドに充填した後、冷却固化させ、モールドから外した。得られた油性菓子を、25℃で15日間エージングした。
[Example 7]
(1) The sorbitol crystal powder was heated to 120 ° C. to prepare a sorbitol melt in which sorbitol was melted. The xylitol crystal powder was heated to 110 ° C. to prepare a xylitol melt in which xylitol was melted.
(2) Oil-based confectionery dough 1 was prepared in the same manner as in Example 1-1. After cooling 10 parts by weight of the sorbitol melt and 10 parts by weight of the xylitol melt prepared in (1) above to 80 parts by weight of the oily confectionery dough 1 in a flowing state (60 ° C.) until the temperature reaches 90 ° C. It was added and mixed gently. 97 parts by weight of the mixed dough to which the sorbitol melt and the xylitol melt were added was slowly cooled to 35 ° C., 3 parts by weight of a seed agent (manufactured by Fuji Oil Co., Ltd., trade name: chocolate seed B) was added, and further mixed. did.
(3) The mixed dough obtained by mixing the seed agent in (2) above was filled in a mold, then cooled and solidified, and removed from the mold. The obtained oil-based confectionery was aged at 25 ° C. for 15 days.

前記(3)で調製された油性菓子について、35℃における耐熱性を評価したところ、35℃における高い耐熱性(評価:B)を有するだけでなく、風味、食感、口どけのいずれも従来のチョコレートと同様に良好であった。風味の中でも甘味については、同一の糖質を用いて従来の製法で製造される油性菓子と同程度であった。 When the heat resistance of the oil-based confectionery prepared in (3) above was evaluated at 35 ° C., not only did it have high heat resistance at 35 ° C. (evaluation: B), but also the flavor, texture, and melting in the mouth were all conventional. It was as good as the chocolate. Among the flavors, the sweetness was about the same as that of oil-based confectionery produced by the conventional manufacturing method using the same sugar.

実施例4〜7の結果を表4に示した。フルクトース融液(実施例5)、エリスリトール融液(実施例5)、又は、ソルビトール融液及びキシリトール融液(実施例7)を配合して調製された油性菓子は、35℃で1時間静置された後でも変形しない耐熱性を有していた。また、得られた耐熱性を有する油性菓子は、いずれも食感、風味、口どけが従来のチョコレートと同様によいものであった。風味の中でも甘味については、同一の糖質を用いて従来の製法で製造される油性菓子と同程度であった。また、カカオマスを含有しないホワイトチョコレートである油性菓子(実施例4)に対しても、融液状の糖質を添加することにより、35℃で1時間静置された後でも変形しない高い耐熱性を付与することが可能であった。 The results of Examples 4 to 7 are shown in Table 4. An oil-based confectionery prepared by blending a fructose melt (Example 5), an erythritol melt (Example 5), or a sorbitol melt and a xylitol melt (Example 7) is allowed to stand at 35 ° C. for 1 hour. It had heat resistance that did not deform even after it was squeezed. In addition, the obtained heat-resistant oil-based confectionery had a good texture, flavor, and melting in the mouth as well as conventional chocolate. Among the flavors, the sweetness was about the same as that of oil-based confectionery produced by the conventional manufacturing method using the same sugar. In addition, even for oil-based confectionery (Example 4), which is white chocolate containing no cocoa mass, by adding a melted liquid sugar, high heat resistance that does not deform even after being allowed to stand at 35 ° C. for 1 hour can be achieved. It was possible to grant.

Figure 2019240138
Figure 2019240138

[参考例1]
特許文献1(特表昭61−502938号)に対応する公告公報(特公平2−31934)に記載された実施例1にしたがって、チョコレート混合物200gに対して2gのグリセリンを加えてヘラでかきまぜたところ、グリセリンを添加した直後に固くなり、混合を継続することが不可能であった。
[Reference example 1]
According to Example 1 described in Gazette (Japanese Patent Publication No. 2-31934) corresponding to Patent Document 1 (Japanese Patent Publication No. 61-502938), 2 g of glycerin was added to 200 g of the chocolate mixture and stirred with a spatula. However, it became hard immediately after the addition of glycerin, and it was impossible to continue the mixing.

[実施例8]エージング温度の検討(1)
(1)キシリトール結晶粉末を130℃まで加熱して、キシリトールを融解させたキシリトール融液を調製した。
(2)実施例1−1と同様にして油性菓子生地1を調製した。流動状態(46℃)である前記油性菓子生地1を97重量部に対して、前記(1)で調製したキシリトール融液を140℃に調整した後、3重量部となるように添加して、100ml容プラカップ内で軽く混合した後、ホモジナイザー(商品名:ヒスコトロンNS−57S、株式会社マイクロテック・ニチオン製、シャフト形式:NS−20、回転数:1000rpm)を用いて、プラカップの内容物が全体的にシャフトの撹拌部に触れるようにプラカップを動かしながら30秒間撹拌混合した。キシリトール融液が添加された混合生地97重量部を35℃まで徐冷し、シード剤(不二製油株式会社製、商品名:チョコシードB)3重量部を添加し、更に混合した。
(3)前記(2)でシード剤を添加して得られた混合生地をモールドに充填した後、冷蔵庫で20分間静置して冷却固化し、モールドから外した。得られた油性菓子を、13℃〜30℃で0日〜5日間エージングした。
[Example 8] Examination of aging temperature (1)
(1) The xylitol crystal powder was heated to 130 ° C. to prepare a xylitol melt in which xylitol was melted.
(2) Oil-based confectionery dough 1 was prepared in the same manner as in Example 1-1. The xylitol melt prepared in (1) above was adjusted to 140 ° C. with respect to 97 parts by weight of the oil-based confectionery dough 1 in a flowing state (46 ° C.), and then added to 3 parts by weight. After lightly mixing in a 100 ml plastic cup, the entire contents of the plastic cup are made using a homogenizer (trade name: Hiscotron NS-57S, manufactured by Microtech Nithione Co., Ltd., shaft type: NS-20, rotation speed: 1000 rpm). The mixture was stirred and mixed for 30 seconds while moving the plastic cup so as to touch the stirring part of the shaft. 97 parts by weight of the mixed dough to which the xylitol melt was added was slowly cooled to 35 ° C., 3 parts by weight of a seed agent (manufactured by Fuji Oil Co., Ltd., trade name: chocolate seed B) was added, and the mixture was further mixed.
(3) The mixed dough obtained by adding the seeding agent in (2) above was filled in a mold, then allowed to stand in a refrigerator for 20 minutes to cool and solidify, and then removed from the mold. The obtained oil-based confectionery was aged at 13 ° C. to 30 ° C. for 0 to 5 days.

前記(3)で調製された油性菓子について、45℃における耐熱性を評価した。結果を表5に示した。キシリトール融液を配合して調製された油性菓子を、25℃以上(25℃〜30℃)でエージングすることにより得られた油性菓子(試験区8−3〜8−6)は、45℃で1時間静置された後でも変形しない耐熱性を有していた(評価:A〜C)。また、得られた耐熱性を有する油性菓子は、いずれも食感、風味、口どけが従来のチョコレートと同様によいものであった。風味の中でも甘味については、同一の糖質を用いて従来の製法で製造される油性菓子と同程度であった。尚、結果は示さないが、特許文献2(特開昭59−156246号公報)との比較実験として、下記のキシリトール溶液を水分1.5%の糖溶液に置き換えてエージングの効果を確認したところ、5日目までD評価であった。 The heat resistance of the oil-based confectionery prepared in (3) above at 45 ° C. was evaluated. The results are shown in Table 5. The oil-based confectionery (test group 8-3 to 8-6) obtained by aging the oil-based confectionery prepared by blending the xylitol melt at 25 ° C. or higher (25 ° C. to 30 ° C.) is at 45 ° C. It had heat resistance that did not deform even after being allowed to stand for 1 hour (evaluation: A to C). In addition, the obtained heat-resistant oil-based confectionery had a good texture, flavor, and melting in the mouth as well as conventional chocolate. Among the flavors, the sweetness was about the same as that of oil-based confectionery produced by the conventional manufacturing method using the same sugar. Although the results are not shown, the effect of aging was confirmed by replacing the following xylitol solution with a sugar solution having a water content of 1.5% as a comparative experiment with Patent Document 2 (Japanese Patent Laid-Open No. 59-156246). It was rated D until the 5th day.

Figure 2019240138
Figure 2019240138

[実施例9]エージング温度の検討(2)
(1)キシリトール結晶粉末を130℃まで加熱して、キシリトールを融解させたキシリトール融液を調製した。
(2)実施例4と同様にして油性菓子生地4(ホワイトチョコレート生地)を調製した。流動状態(46℃)である前記油性菓子生地4を97重量部に対して、前記(1)で調製したキシリトール融液を140℃に調整した後、3重量部となるように添加して、100ml容プラカップ内で軽く混合した後、ホモジナイザー(商品名:ヒスコトロンNS−57S、株式会社マイクロテック・ニチオン製、シャフト形式:NS−20、回転数:1000rpm)を用いて、プラカップの内容物が全体的にシャフトの撹拌部に触れるようにプラカップを動かしながら10秒間撹拌混合した。キシリトール融液が添加された混合生地97重量部を35℃まで徐冷し、シード剤(不二製油株式会社製、商品名:チョコシードB)3重量部を添加し、更に混合した。
(3)前記(2)でシード剤を添加して得られた混合生地をモールドに充填した後、冷蔵庫で20分間静置して冷却固化し、モールドから外した。得られた油性菓子を、13℃〜30℃で0日〜5日間エージングした。
[Example 9] Examination of aging temperature (2)
(1) The xylitol crystal powder was heated to 130 ° C. to prepare a xylitol melt in which xylitol was melted.
(2) An oil-based confectionery dough 4 (white chocolate dough) was prepared in the same manner as in Example 4. The xylitol melt prepared in (1) above was adjusted to 140 ° C. with respect to 97 parts by weight of the oily confectionery dough 4 in a fluid state (46 ° C.), and then added to 3 parts by weight. After lightly mixing in a 100 ml plastic cup, the entire contents of the plastic cup are made using a homogenizer (trade name: Hiscotron NS-57S, manufactured by Microtech Nithione Co., Ltd., shaft type: NS-20, rotation speed: 1000 rpm). The mixture was stirred and mixed for 10 seconds while moving the plastic cup so as to touch the stirring part of the shaft. 97 parts by weight of the mixed dough to which the xylitol melt was added was slowly cooled to 35 ° C., 3 parts by weight of a seed agent (manufactured by Fuji Oil Co., Ltd., trade name: chocolate seed B) was added, and the mixture was further mixed.
(3) The mixed dough obtained by adding the seeding agent in (2) above was filled in a mold, then allowed to stand in a refrigerator for 20 minutes to cool and solidify, and then removed from the mold. The obtained oil-based confectionery was aged at 13 ° C. to 30 ° C. for 0 to 5 days.

前記(3)で調製された油性菓子について、45℃における耐熱性を評価した。結果を表6に示した。キシリトール融液を配合して調製された油性菓子を、28℃以上(28℃〜30℃)でエージングすることにより得られた油性菓子(試験区9−3〜9−5)は、45℃で1時間静置された後でも変形しない耐熱性を有していた(評価:A〜C)。また、得られた耐熱性を有する油性菓子は、いずれも食感、風味、口どけが従来のチョコレートと同様によいものであった。風味の中でも甘味については、同一の糖質を用いて従来の製法で製造される油性菓子と同程度であった。 The heat resistance of the oil-based confectionery prepared in (3) above at 45 ° C. was evaluated. The results are shown in Table 6. The oil-based confectionery (test group 9-3 to 9-5) obtained by aging the oil-based confectionery prepared by blending the xylitol melt at 28 ° C. or higher (28 ° C. to 30 ° C.) was prepared at 45 ° C. It had heat resistance that did not deform even after being allowed to stand for 1 hour (evaluation: A to C). In addition, the obtained heat-resistant oil-based confectionery had a good texture, flavor, and melting in the mouth as well as conventional chocolate. Among the flavors, the sweetness was about the same as that of oil-based confectionery produced by the conventional manufacturing method using the same sugar.

Figure 2019240138
Figure 2019240138

[実施例10]油性菓子生地の温度と、融液状の糖質の温度の影響
(1)キシリトール結晶粉末を130℃まで加熱して、キシリトールを融解させたキシリトール融液を調製した。
(2)実施例1−1と同様にして油性菓子生地1を調製した。流動状態(温度は表7を参照)である前記油性菓子生地1を95重量部に対して、前記(1)で調製したキシリトール融液を特定温度(温度は表7を参照)に調整した後、5重量部となるように添加して、軽く混合した。ただし、試験区10−5については、油性菓子生地1を98重量部に対して、キシリトール融液を2重量部として同様に混合した。キシリトール融液が添加された混合生地97重量部を35℃まで徐冷し、シード剤(不二製油株式会社製、商品名:チョコシードB)3重量部を添加し、更に混合した。
(3)前記(2)でシード剤を添加して得られた混合生地をモールドに充填した後、冷却固化し、モールドから外した。得られた油性菓子を、室温(24℃)で14日間エージングした。
[Example 10] Effect of temperature of oily confectionery dough and temperature of melted sugar (1) Xylitol crystal powder was heated to 130 ° C. to prepare a xylitol melt in which xylitol was melted.
(2) Oil-based confectionery dough 1 was prepared in the same manner as in Example 1-1. After adjusting the xylitol melt prepared in (1) to a specific temperature (see Table 7 for the temperature) with respect to 95 parts by weight of the oil-based confectionery dough 1 in a flowing state (see Table 7 for the temperature). 5 parts by weight were added and mixed lightly. However, in the test group 10-5, the oil-based confectionery dough 1 was mixed in the same manner with 98 parts by weight and the xylitol melt as 2 parts by weight. 97 parts by weight of the mixed dough to which the xylitol melt was added was slowly cooled to 35 ° C., 3 parts by weight of a seed agent (manufactured by Fuji Oil Co., Ltd., trade name: chocolate seed B) was added, and the mixture was further mixed.
(3) The mixed dough obtained by adding the seeding agent in (2) above was filled in a mold, then cooled and solidified, and removed from the mold. The obtained oil-based confectionery was aged at room temperature (24 ° C.) for 14 days.

前記(3)で調製された油性菓子について、45℃における耐熱性を評価した。結果を表7に示した。混合前の油性菓子生地の温度を40℃以上(45℃〜54℃)として、かつ、融液状の糖質(キシリトール融液)を60℃以上200℃未満(60℃〜145℃)に調整して混合し、室温(24℃)でエージングすることにより、得られる油性菓子(試験区10−1、10−6〜10−8)は45℃における耐熱性(評価:C〜B)を有していた。特に、油性菓子生地と融液状の糖質を混合した生地の温度が50℃を超える場合(試験区10−6〜10−8)については、得られる油性菓子は優れた高い耐熱性(評価:B)を有していた。 The heat resistance of the oil-based confectionery prepared in (3) above at 45 ° C. was evaluated. The results are shown in Table 7. The temperature of the oil-based confectionery dough before mixing is adjusted to 40 ° C. or higher (45 ° C. to 54 ° C.), and the melted sugar (xylitol melt) is adjusted to 60 ° C. or higher and lower than 200 ° C. (60 ° C. to 145 ° C.). The oil-based confectionery (Test Group 10-1, 10-6 to 10-8) obtained by mixing and aging at room temperature (24 ° C.) has heat resistance (evaluation: C to B) at 45 ° C. Was there. In particular, when the temperature of the dough in which the oil-based confectionery dough and the melted liquid sugar are mixed exceeds 50 ° C. (test group 10-6 to 10-8), the obtained oil-based confectionery has excellent high heat resistance (evaluation:: B) had.

Figure 2019240138
Figure 2019240138

[実施例11]エージング温度の検討
(1)キシリトール結晶粉末を130℃まで加熱して、キシリトールを融解させたキシリトール融液を調製した。
(2)実施例1−1と同様にして油性菓子生地1を調製した。流動状態(温度は表8を参照)である前記油性菓子生地1を100重量部〜97重量部に対して、前記(1)で調製したキシリトール融液を140℃に調整した後、0重量部〜3重量部となるように添加して、100ml容プラカップ内で軽く混合した後、ホモジナイザー(商品名:ヒスコトロンNS−57S、株式会社マイクロテック・ニチオン製、シャフト形式:NS−20、回転数:1000rpm)を用いて、プラカップの内容物が全体的にシャフトの撹拌部に触れるようにプラカップを動かしながら30秒間撹拌混合した。キシリトール融液が添加された混合生地97重量部を35℃まで徐冷し、シード剤(不二製油株式会社製、商品名:チョコシードB)3重量部を添加し、更に混合した。
(3)前記(2)でシード剤を混合して得られた混合生地をモールドに充填した後、冷却固化し、モールドから外した。得られた油性菓子を、25℃又は28℃で0日〜3日間エージングした。
[Example 11] Examination of aging temperature (1) A xylitol melt was prepared by heating xylitol crystal powder to 130 ° C. to melt xylitol.
(2) Oil-based confectionery dough 1 was prepared in the same manner as in Example 1-1. After adjusting the xylitol melt prepared in (1) to 140 ° C. with respect to 100 parts by weight to 97 parts by weight of the oily confectionery dough 1 in a flowing state (see Table 8 for the temperature), 0 parts by weight. Add to ~ 3 parts by weight, mix lightly in a 100 ml plastic cup, and then homogenizer (trade name: Hiscotron NS-57S, manufactured by Microtech Nithion Co., Ltd., shaft type: NS-20, rotation speed: Using 1000 rpm), the mixture was stirred and mixed for 30 seconds while moving the plastic cup so that the contents of the plastic cup touched the stirring part of the shaft as a whole. 97 parts by weight of the mixed dough to which the xylitol melt was added was slowly cooled to 35 ° C., 3 parts by weight of a seed agent (manufactured by Fuji Oil Co., Ltd., trade name: chocolate seed B) was added, and the mixture was further mixed.
(3) The mixed dough obtained by mixing the seed agent in (2) above was filled in a mold, then cooled and solidified, and removed from the mold. The obtained oil-based confectionery was aged at 25 ° C. or 28 ° C. for 0 to 3 days.

前記(3)で調製された油性菓子について、45℃における耐熱性を評価した。結果を表8に示した。混合生地中に融液状の糖質(キシリトール融液)を0重量%〜1重量%配合した試験区においては、25℃〜28℃で3日間エージングした後に耐熱性を有する油性菓子を得ることができなかった(指でつかめる状態ではなかった)。融液状の糖質を2重量%以上配合した試験区においては、25℃及び28℃のいずれのエージング温度においても、耐熱性を有する油性菓子を得ることができた(評価:C〜A)。エージング温度が25℃よりも28℃の方が、より高い耐熱性を有する油性菓子を得ることができた(評価:B〜A)。得られた耐熱性を有する油性菓子は、いずれも食感、風味、口どけが従来のチョコレートと同様によいものであった。風味の中でも甘味については、同一の糖質を用いて従来の製法で製造される油性菓子と同程度であった。 The heat resistance of the oil-based confectionery prepared in (3) above at 45 ° C. was evaluated. The results are shown in Table 8. In the test group in which 0% by weight to 1% by weight of a melted liquid sugar (xylitol melt) was blended in the mixed dough, a heat-resistant oily confectionery could be obtained after aging at 25 ° C. to 28 ° C. for 3 days. I couldn't (I wasn't in a state where I could grab it with my fingers). In the test group containing 2% by weight or more of the melted liquid sugar, an oil-based confectionery having heat resistance could be obtained at both aging temperatures of 25 ° C. and 28 ° C. (evaluation: CA). An oil-based confectionery having higher heat resistance could be obtained when the aging temperature was 28 ° C. than 25 ° C. (evaluation: B to A). All of the obtained heat-resistant oil-based confectioneries had good texture, flavor, and melting in the mouth as well as conventional chocolate. Among the flavors, the sweetness was about the same as that of oil-based confectionery produced by the conventional manufacturing method using the same sugar.

Figure 2019240138
Figure 2019240138

[実施例12]耐熱性を有する油性菓子の硬度(1)
(1)キシリトール結晶粉末を130℃まで加熱して、キシリトールを融解させたキシリトール融液を調製した。
(2)実施例1−1と同様にして油性菓子生地1を調製した。流動状態(40℃)である前記油性菓子生地1を98又は97重量部に対して、前記(1)で調製したキシリトール融液を140℃に調整した後、2又は3重量部となるように添加して、100ml容プラカップ内で軽く混合した後、ホモジナイザー(商品名:ヒスコトロンNS−57S、株式会社マイクロテック・ニチオン製、シャフト形式:NS−20、回転数:1000rpm)を用いて、プラカップの内容物が全体的にシャフトの撹拌部に触れるようにプラカップを動かしながら30秒間撹拌混合した。キシリトール融液が添加された混合生地97重量部を35℃まで徐冷し、シード剤(不二製油株式会社製、商品名:チョコシードB)3重量部を添加し、更に混合した。
(3)前記(2)でシード剤を混合して得られた混合生地をモールドに充填した後、冷却固化し、モールドから外した。得られた油性菓子を、28℃で0日〜4日間エージングした。
[Example 12] Hardness of heat-resistant oil-based confectionery (1)
(1) The xylitol crystal powder was heated to 130 ° C. to prepare a xylitol melt in which xylitol was melted.
(2) Oil-based confectionery dough 1 was prepared in the same manner as in Example 1-1. The amount of the oil-based confectionery dough 1 in a flowing state (40 ° C.) is adjusted to 98 or 97 parts by weight, and the amount of the xylitol melt prepared in (1) is adjusted to 140 ° C., so that the amount is 2 or 3 parts by weight. After adding and lightly mixing in a 100 ml plastic cup, a homogenizer (trade name: Hiscotron NS-57S, manufactured by Microtech Nithione Co., Ltd., shaft type: NS-20, rotation speed: 1000 rpm) is used to prepare the plastic cup. The mixture was stirred and mixed for 30 seconds while moving the plastic cup so that the contents touched the stirring part of the shaft as a whole. 97 parts by weight of the mixed dough to which the xylitol melt was added was slowly cooled to 35 ° C., 3 parts by weight of a seed agent (manufactured by Fuji Oil Co., Ltd., trade name: chocolate seed B) was added, and the mixture was further mixed.
(3) The mixed dough obtained by mixing the seed agent in (2) above was filled in a mold, then cooled and solidified, and removed from the mold. The obtained oil-based confectionery was aged at 28 ° C. for 0 to 4 days.

前記(3)で調製された油性菓子について、40℃及び45℃における耐熱性を評価した。結果を表9に示した。全ての試験区において、高い耐熱性を有する油性菓子が得られた。融液状の糖質の配合量が3重量%である油性菓子は、同配合量が2重量%の油性菓子よりも高い硬度を有していた。同じ条件で製造された油性菓子について、45℃で1時間静置された後に測定した硬度は、40℃で1時間静置された油性菓子の硬度よりも高い値を示す傾向がみられた。いずれの試験区においても、28℃でのエージング2日目〜3日目に急激に硬度が上昇した。高い耐熱性を有する油性菓子(評価:B〜A)は、硬度が100gf以上を示した。得られた耐熱性を有する油性菓子は、いずれも食感、風味、口どけが従来のチョコレートと同様によいものであった。風味の中でも甘味については、同一の糖質を用いて従来の製法で製造される油性菓子と同程度であった。 The heat resistance of the oil-based confectionery prepared in (3) above was evaluated at 40 ° C. and 45 ° C. The results are shown in Table 9. Oil-based confectionery having high heat resistance was obtained in all the test plots. The oil-based confectionery containing 3% by weight of the melted liquid sugar had a higher hardness than the oil-based confectionery containing 2% by weight. For oil-based confectionery produced under the same conditions, the hardness measured after being allowed to stand at 45 ° C. for 1 hour tended to be higher than the hardness of the oil-based confectionery that was allowed to stand at 40 ° C. for 1 hour. In each of the test plots, the hardness increased sharply on the 2nd to 3rd days of aging at 28 ° C. The oil-based confectionery having high heat resistance (evaluation: B to A) showed a hardness of 100 gf or more. All of the obtained heat-resistant oil-based confectioneries had good texture, flavor, and melting in the mouth as well as conventional chocolate. Among the flavors, the sweetness was about the same as that of oil-based confectionery produced by the conventional manufacturing method using the same sugar.

Figure 2019240138
Figure 2019240138

[実施例13]耐熱性を有する油性菓子の硬度(2)
(1)キシリトール結晶粉末を130℃まで加熱して、キシリトールを融解させたキシリトール融液を調製した。
(2)実施例1−1と同様にして油性菓子生地1を調製した。流動状態(温度は表10を参照)である前記油性菓子生地1を95又は97重量部に対して、前記(1)で調製したキシリトール融液を140℃に調整した後、5又は3重量部となるように添加して、軽く混合した後、ミキサー(商品名:ケンミックスKMM770、デロンギ・ジャパン株式会社、撹拌子:ホイッパー)を用いて撹拌混合した(混合条件は表10を参照)。キシリトール融液が添加された混合生地97重量部を35℃まで徐冷し、シード剤(不二製油株式会社製、商品名:チョコシードB)3重量部を添加し、更に混合した。
(3)前記(2)でシード剤を混合して得られた混合生地をモールドに充填した後、冷却固化し、モールドから外した。得られた油性菓子を、室温(26℃〜28℃)でエージングした(エージング時間は表10を参照)。
[Example 13] Hardness of heat-resistant oil-based confectionery (2)
(1) The xylitol crystal powder was heated to 130 ° C. to prepare a xylitol melt in which xylitol was melted.
(2) Oil-based confectionery dough 1 was prepared in the same manner as in Example 1-1. After adjusting the xylitol melt prepared in (1) to 140 ° C. with respect to 95 or 97 parts by weight of the oily confectionery dough 1 in a flowing state (see Table 10 for the temperature), 5 or 3 parts by weight. After adding and mixing lightly, the mixture was stirred and mixed using a mixer (trade name: Kenmix KMM770, Delonghi Japan Co., Ltd., stirrer: whipper) (see Table 10 for mixing conditions). 97 parts by weight of the mixed dough to which the xylitol melt was added was slowly cooled to 35 ° C., 3 parts by weight of a seed agent (manufactured by Fuji Oil Co., Ltd., trade name: chocolate seed B) was added, and the mixture was further mixed.
(3) The mixed dough obtained by mixing the seed agent in (2) above was filled in a mold, then cooled and solidified, and removed from the mold. The obtained oil-based confectionery was aged at room temperature (26 ° C. to 28 ° C.) (see Table 10 for the aging time).

前記(3)で調製された油性菓子について、45℃における耐熱性を評価した。結果を表10に示した。 The heat resistance of the oil-based confectionery prepared in (3) above at 45 ° C. was evaluated. The results are shown in Table 10.

温度が30℃である油性菓子生地97重量部に対して140℃に調整された融液状の糖質(キシリトール融液)を3重量部配合して室温(26℃〜28℃)で4日間エージングされた油性菓子は、耐熱性を有していた(45℃における評価:C、硬度:207gf、40℃における硬度:143gf)。
また、油性菓子生地95重量部に対して90℃に調整された融液状の糖質(キシリトール融液)を5重量部配合して室温(26℃〜28℃)で3日〜9日間エージングされた油性菓子は、高い耐熱性を有していた(45℃における耐熱性評価:B〜A、45℃における硬度:400gf〜677gf、40℃における硬度:293gf〜567gf)。得られた耐熱性を有する油性菓子は、いずれも食感、風味、口どけが従来のチョコレートと同様によいものであった。風味の中でも甘味については、同一の糖質を用いて従来の製法で製造される油性菓子と同程度であった。
97 parts by weight of oil-based confectionery dough having a temperature of 30 ° C. was mixed with 3 parts by weight of a melt-liquid sugar (xylitol melt) adjusted to 140 ° C. and aged at room temperature (26 ° C. to 28 ° C.) for 4 days. The oil-based confectionery produced had heat resistance (evaluation at 45 ° C.: C, hardness: 207 gf, hardness at 40 ° C.: 143 gf).
Further, 5 parts by weight of a melt-liquid sugar (xylitol melt) adjusted to 90 ° C. was added to 95 parts by weight of the oil-based confectionery dough, and the dough was aged at room temperature (26 ° C. to 28 ° C.) for 3 to 9 days. The oil-based confectionery had high heat resistance (heat resistance evaluation at 45 ° C.: B to A, hardness at 45 ° C.: 400 gf to 677 gf, hardness at 40 ° C.: 293 gf to 567 gf). All of the obtained heat-resistant oil-based confectioneries had good texture, flavor, and melting in the mouth as well as conventional chocolate. Among the flavors, the sweetness was about the same as that of oil-based confectionery produced by the conventional manufacturing method using the same sugar.

Figure 2019240138
Figure 2019240138

[実施例14]耐熱性を有する油性菓子の硬度(3)
(1)キシリトール結晶粉末を130℃まで加熱して、キシリトールを融解させたキシリトール融液を調製した。
(2)実施例1−1と同様にして油性菓子生地1を調製した。流動状態(31℃)である前記油性菓子生地1を95重量部又は97重量部に対して、前記(1)で調製したキシリトール融液を140℃に調整した後、5重量部又は3重量部となるように添加して、軽く混合した後、ミキサー(商品名:ケンミックスKMM770、デロンギ・ジャパン株式会社、撹拌子:ホイッパー)を用いて10分間撹拌混合した。キシリトール融液が添加された混合生地97重量部を35℃まで徐冷し、シード剤(不二製油株式会社製、商品名:チョコシードB)3重量部を添加し、更に混合した。
(3)試験区14−1、14−2:前記(2)でシード剤を混合して得られた混合生地をモールドに充填した後、冷蔵庫で30分冷却固化し、モールドから外し、室温(26℃〜28℃)で5日間エージングした。更に、45℃で2時間、4時間又は24時間静置してエージングした。
試験区14−3:前記(2)でシード剤を混合して得られた混合生地をモールドに充填した後、冷却固化及び脱型は行わず、モールドに充填したまま45℃で24時間静置することによりエージングした。
試験区14−4:前記(2)でシード剤を混合して得られた混合生地をモールドに充填した後、冷蔵庫で30分冷却固化し、モールドから外した後、45℃で2時間、4時間又は24時間静置することによりエージングした。
[Example 14] Hardness of heat-resistant oil-based confectionery (3)
(1) The xylitol crystal powder was heated to 130 ° C. to prepare a xylitol melt in which xylitol was melted.
(2) Oil-based confectionery dough 1 was prepared in the same manner as in Example 1-1. After adjusting the xylitol melt prepared in (1) to 140 ° C. with respect to 95 parts by weight or 97 parts by weight of the oily confectionery dough 1 in a flowing state (31 ° C.), 5 parts by weight or 3 parts by weight. After adding and mixing lightly, the mixture was stirred and mixed for 10 minutes using a mixer (trade name: Kenmix KMM770, Delongi Japan Co., Ltd., stirrer: whipper). 97 parts by weight of the mixed dough to which the xylitol melt was added was slowly cooled to 35 ° C., 3 parts by weight of a seed agent (manufactured by Fuji Oil Co., Ltd., trade name: chocolate seed B) was added, and the mixture was further mixed.
(3) Test groups 14-1, 14-2: The mixed dough obtained by mixing the seed agent in (2) above is filled in a mold, cooled and solidified in a refrigerator for 30 minutes, removed from the mold, and at room temperature (3). Aged at 26 ° C-28 ° C) for 5 days. Further, it was allowed to stand at 45 ° C. for 2 hours, 4 hours or 24 hours for aging.
Test group 14-3: After the mixed dough obtained by mixing the seed agent in (2) above is filled in a mold, it is not cooled and solidified or demolded, and is allowed to stand at 45 ° C. for 24 hours while being filled in the mold. Aged by doing.
Test group 14-4: The mixed dough obtained by mixing the seed agent in (2) above was filled in a mold, cooled and solidified in a refrigerator for 30 minutes, removed from the mold, and then at 45 ° C. for 2 hours, 4 Aged by standing for hours or 24 hours.

前記(3)で調製された油性菓子について、耐熱性を評価した。結果を表11に示した。
試験区14−1、14−2:室温でエージングした後のサンプルについて耐熱性を評価した。硬度測定には、室温で5日間エージングした後に45℃で2時間、4時間、24時間エージングしたサンプルを用いた。なお、本試験区では、硬度測定前に45℃で1時間静置する操作は実施せず、エージング直後のサンプルの硬度を測定した。
試験区14−3:エージング後の油性菓子は、指で押しても変形しない程度に固化していた(耐熱性評価:A)。ただし、エージング後のサンプルを30分間冷蔵庫で冷却した後、モールドから外そうとしたところ、外すことができなかったため、硬度測定は実施できなかった。
試験区14−4:45℃でエージングした直後のサンプルを耐熱性評価及び硬度測定に供した。硬度測定は、試験区14−1〜2と同様に、エージング直後に実施した。
The heat resistance of the oil-based confectionery prepared in (3) above was evaluated. The results are shown in Table 11.
Test groups 14-1, 14-2: The heat resistance of the sample after aging at room temperature was evaluated. For the hardness measurement, a sample that had been aged at room temperature for 5 days and then aged at 45 ° C. for 2 hours, 4 hours, and 24 hours was used. In this test group, the hardness of the sample immediately after aging was measured without performing the operation of allowing the sample to stand at 45 ° C. for 1 hour before measuring the hardness.
Test group 14-3: The oil-based confectionery after aging was solidified to the extent that it was not deformed even when pressed with a finger (heat resistance evaluation: A). However, when the sample after aging was cooled in a refrigerator for 30 minutes and then tried to be removed from the mold, the hardness could not be measured because it could not be removed.
Test group 14-4: The sample immediately after aging at 45 ° C. was subjected to heat resistance evaluation and hardness measurement. Hardness measurement was carried out immediately after aging in the same manner as in Test Group 14-1 to 2.

本実施例の全ての試験区において、高い耐熱性を有する油性菓子が得られた。いずれの試験区の油性菓子においても、融液状の糖質と混合後に45℃で静置された時間が長くなるほど硬度が上昇した。45℃で24時間静置した後の油性菓子の硬度は、測定上限の2000gfを超える値を示し、いずれも指で押した時に硬く感じられた。得られた耐熱性を有する油性菓子は、いずれも食感、風味、口どけが従来のチョコレートと同様によいものであった。風味の中でも甘味については、同一の糖質を用いて従来の製法で製造される油性菓子と同程度であった。試験区14−3においては、混合生地を冷却固化させずに、モールドに充填されたまま45℃でエージングすることにより、著しく高い耐熱性を有する油性菓子を得ることができた。 Oil-based confectionery having high heat resistance was obtained in all the test plots of this example. The hardness of the oil-based confectionery in each test group increased as the time of standing at 45 ° C. after mixing with the melt-liquid sugar increased. The hardness of the oil-based confectionery after standing at 45 ° C. for 24 hours showed a value exceeding the measurement upper limit of 2000 gf, and all of them felt hard when pressed with a finger. All of the obtained heat-resistant oil-based confectioneries had good texture, flavor, and melting in the mouth as well as conventional chocolate. Among the flavors, the sweetness was about the same as that of oil-based confectionery produced by the conventional manufacturing method using the same sugar. In Test Group 14-3, an oil-based confectionery having extremely high heat resistance could be obtained by aging the mixed dough at 45 ° C. while being filled in the mold without cooling and solidifying.

Figure 2019240138
Figure 2019240138

[実施例15]耐熱性を有する油性菓子の硬度(4)
(1)キシリトール結晶粉末を130℃まで加熱して、キシリトールを融解させたキシリトール融液を調製した。
(2)実施例1−1と同様にして油性菓子生地1を調製した。流動状態(31℃)である前記油性菓子生地1を95重量部又は97重量部に対して、前記(1)で調製したキシリトール融液を140℃に調整した後、5重量部又は3重量部となるように添加して、軽く混合した後、ミキサー(商品名:ケンミックスKMM770、デロンギ・ジャパン株式会社、撹拌子:ホイッパー)を用いて10分間撹拌混合した。キシリトール融液が添加された混合生地97重量部を35℃まで徐冷し、シード剤(不二製油株式会社製、商品名:チョコシードB)3重量部を添加し、更に混合した。
(3)試験区15−1、15−2:前記(2)でシード剤を混合して得られた混合生地をモールドに充填した後、冷蔵庫で20分冷却固化し、モールドから外し、室温(26℃〜28℃)で6日間エージングした。その後更に35℃で1時間又は24時間静置してエージングした。
試験区15−3:前記(2)でシード剤を混合して得られた混合生地をモールドに充填した後、冷却固化及び脱型は行わず、モールドに充填したまま35℃で24時間静置することによりエージングした。
試験区15−4:前記(2)でシード剤を混合して得られた混合生地をモールドに充填した後、冷蔵庫で30分冷却固化し、モールドから外し、35℃で24時間静置することによりエージングした。
[Example 15] Hardness of heat-resistant oil-based confectionery (4)
(1) The xylitol crystal powder was heated to 130 ° C. to prepare a xylitol melt in which xylitol was melted.
(2) Oil-based confectionery dough 1 was prepared in the same manner as in Example 1-1. After adjusting the xylitol melt prepared in (1) to 140 ° C. with respect to 95 parts by weight or 97 parts by weight of the oily confectionery dough 1 in a flowing state (31 ° C.), 5 parts by weight or 3 parts by weight. After adding and mixing lightly, the mixture was stirred and mixed for 10 minutes using a mixer (trade name: Kenmix KMM770, Delongi Japan Co., Ltd., stirrer: whipper). 97 parts by weight of the mixed dough to which the xylitol melt was added was slowly cooled to 35 ° C., 3 parts by weight of a seed agent (manufactured by Fuji Oil Co., Ltd., trade name: chocolate seed B) was added, and the mixture was further mixed.
(3) Test groups 15-1, 15-2: The mixed dough obtained by mixing the seed agent in (2) above is filled in a mold, cooled and solidified in a refrigerator for 20 minutes, removed from the mold, and at room temperature (3). Aged at 26 ° C-28 ° C) for 6 days. After that, it was allowed to stand at 35 ° C. for 1 hour or 24 hours for aging.
Test group 15-3: After the mixed dough obtained by mixing the seed agent in (2) above is filled in a mold, it is not cooled and solidified or demolded, and is allowed to stand at 35 ° C. for 24 hours while being filled in the mold. Aged by doing.
Test group 15-4: The mixed dough obtained by mixing the seed agent in (2) above is filled in a mold, cooled and solidified in a refrigerator for 30 minutes, removed from the mold, and allowed to stand at 35 ° C. for 24 hours. Aged by.

前記(3)で調製された油性菓子について、耐熱性を評価した。
試験区15−1、15−2:室温でエージングした後のサンプルについて耐熱性を評価した。硬度測定には、室温でのエージング後に35℃で1時間又は24時間静置したサンプルを用いた。前記に加えて、前記35℃24時間静置したサンプルを更に常温(26℃〜28℃)で72時間静置した後の硬度も測定した。なお、硬度測定は、サンプルを45℃で1時間静置した後に実施した。
試験区15−3:エージング後の油性菓子は、指で押しても変形しない程度に固化していた(耐熱性評価:A)。エージング後に、30分間冷蔵庫で冷却した後、モールドから外して、更に常温(26℃〜28℃)で72時間静置したサンプルを、45℃で1時間静置した後、硬度を測定した。
試験区15−4:35℃で24時間エージングした後のサンプルの耐熱性を評価した。硬度測定には、前記サンプルに加えて、35℃24時間静置した後に更に常温(26℃〜28℃)で72時間静置したサンプルの硬度も測定した。なお、硬度測定には、45℃で1時間静置した後のサンプルを用いた。
The heat resistance of the oil-based confectionery prepared in (3) above was evaluated.
Test groups 15-1, 15-2: The heat resistance of the sample after aging at room temperature was evaluated. For the hardness measurement, a sample left at 35 ° C. for 1 hour or 24 hours after aging at room temperature was used. In addition to the above, the hardness of the sample that had been allowed to stand at 35 ° C. for 24 hours was also measured after being further allowed to stand at room temperature (26 ° C. to 28 ° C.) for 72 hours. The hardness was measured after the sample was allowed to stand at 45 ° C. for 1 hour.
Test group 15-3: The oil-based confectionery after aging was solidified to the extent that it was not deformed even when pressed with a finger (heat resistance evaluation: A). After aging, the sample was cooled in a refrigerator for 30 minutes, removed from the mold, and further allowed to stand at room temperature (26 ° C. to 28 ° C.) for 72 hours, and then allowed to stand at 45 ° C. for 1 hour, and then the hardness was measured.
Test group 15-4: The heat resistance of the sample after aging at 35 ° C. for 24 hours was evaluated. In the hardness measurement, in addition to the sample, the hardness of the sample which was allowed to stand at 35 ° C. for 24 hours and then allowed to stand at room temperature (26 ° C. to 28 ° C.) for 72 hours was also measured. For the hardness measurement, a sample after standing at 45 ° C. for 1 hour was used.

本実施例の全ての試験区において、高い耐熱性を有する油性菓子が得られた。試験区15−1及び15−2によると、融液状の糖質と混合後に35℃で静置された時間が長くなるほど硬度が上昇した。ただし、実施例14の45℃で静置された油性菓子よりも硬度は低かった。得られた耐熱性を有する油性菓子は、いずれも食感、風味、口どけが従来のチョコレートと同様によいものであった。風味の中でも甘味については、同一の糖質を用いて従来の製法で製造される油性菓子と同程度であった。試験区15−3においては、混合生地を冷却固化させずに、モールドに充填されたまま35℃でエージングすることにより、著しく高い耐熱性を有する油性菓子を得ることができた。モールド充填後35℃エージング品は、冷却固化して型から外す際に、形崩れ等の発生もなく、その後常温で3日間保存した後にブルーム等の明らかな外観不良も発生しなかった。 Oil-based confectionery having high heat resistance was obtained in all the test plots of this example. According to Test Groups 15-1 and 15-2, the hardness increased as the time of standing at 35 ° C. after mixing with the melted sugar increased. However, the hardness was lower than that of the oil-based confectionery left at 45 ° C. in Example 14. All of the obtained heat-resistant oil-based confectioneries had good texture, flavor, and melting in the mouth as well as conventional chocolate. Among the flavors, the sweetness was about the same as that of oil-based confectionery produced by the conventional manufacturing method using the same sugar. In Test Group 15-3, an oil-based confectionery having extremely high heat resistance could be obtained by aging the mixed dough at 35 ° C. while being filled in the mold without cooling and solidifying. The 35 ° C. aged product after filling with the mold did not lose its shape when it was cooled and solidified and removed from the mold, and after storage at room temperature for 3 days, no obvious deterioration in appearance such as bloom occurred.

Figure 2019240138
Figure 2019240138

[実施例16]ソルビトール融液及びソルビトール種結晶を配合した耐熱性油性菓子
(1)ソルビトール結晶粉末を120℃まで加熱して、ソルビトールを融解させたソルビトール融液を調製した。
(2)カカオマス20重量部、ココアバター17.5重量部、全粉乳20重量部、乳化剤(レシチン)0.5重量部、香料0.1重量部、砂糖41重量部、上記ソルビトール結晶粉末1重量部を種結晶として常法により混合、粉砕及びコンチングして油性菓子生地を調製した。流動状態(50℃)である前記油性菓子生地を99重量部に対して、前記(1)で調製したソルビトール融液を90℃まで冷却した後に1重量部となるように添加して、おだやかに混合した。更にココアバターを添加混合して、前記混合生地中に含まれる油分を35重量%となるように調整した。油分を調整した後の混合生地97重量部を35℃まで徐冷し、シード剤(不二製油株式会社製、商品名:チョコシードB)3重量部を添加し、更に混合した。
(3)前記(2)でシード剤を混合して得られた混合生地をモールドに充填した後、冷却固化させ、モールドから外して油性菓子を得た。得られた油性菓子を、25℃で10日間エージングした。
[Example 16] Heat-resistant oily confectionery containing a sorbitol melt and sorbitol seed crystals (1) A sorbitol melt was prepared by heating sorbitol crystal powder to 120 ° C. to melt sorbitol.
(2) 20 parts by weight of cocoa mass, 17.5 parts by weight of cocoa butter, 20 parts by weight of whole milk powder, 0.5 parts by weight of emulsifier (lecithin), 0.1 parts by weight of fragrance, 41 parts by weight of sugar, 1 weight of the above sorbitol crystal powder. An oily confectionery dough was prepared by mixing, crushing and conching the portions as seed crystals by a conventional method. The oil-based confectionery dough in a fluid state (50 ° C.) is added to 99 parts by weight by adding the sorbitol melt prepared in (1) to 90 parts by weight so as to be 1 part by weight. Mixed. Further, cocoa butter was added and mixed to adjust the oil content in the mixed dough to 35% by weight. After adjusting the oil content, 97 parts by weight of the mixed dough was slowly cooled to 35 ° C., 3 parts by weight of a seed agent (manufactured by Fuji Oil Co., Ltd., trade name: chocolate seed B) was added, and the mixture was further mixed.
(3) The mixed dough obtained by mixing the seed agent in (2) above was filled in a mold, then cooled and solidified, and removed from the mold to obtain an oil-based confectionery. The obtained oil-based confectionery was aged at 25 ° C. for 10 days.

前記(3)で調製された油性菓子について耐熱性を評価したところ、35℃における高い耐熱性(評価:B)を有するだけでなく、風味、食感、口どけのいずれも従来のチョコレートと同様に良好であった。風味の中でも甘味については、同一の糖質を用いて従来の製法で製造される油性菓子と同程度であった。 When the heat resistance of the oil-based confectionery prepared in (3) was evaluated, it not only has high heat resistance at 35 ° C. (evaluation: B), but also has the same flavor, texture, and melting in the mouth as conventional chocolate. Was good. Among the flavors, the sweetness was about the same as that of oil-based confectionery produced by the conventional manufacturing method using the same sugar.

[参考例2−1]
(1)ソルビトール結晶粉末を120℃まで加熱して、ソルビトールを融解させたソルビトール融液を調製した。
(2)実施例16(2)に記載した油性菓子生地配合において、ソルビトール結晶粉末(種結晶)を含まない油性菓子生地を同様の手順で調製した。流動状態(50℃)である前記油性菓子生地を95重量部に対して、前記(1)で調製したソルビトール融液を90℃まで冷却した後に5重量部となるように添加して、おだやかに混合した。前記混合時の生地に含まれる油分は33重量%であった。ソルビトール融液を混合した後の混合生地97重量部を35℃まで徐冷し、シード剤(不二製油株式会社製、商品名:チョコシードB)3重量部を添加し、更に混合した。
(3)前記(2)でシード剤を混合して得られた混合生地をモールドに充填した後、冷却固化させ、モールドから外して油性菓子を得た。得られた油性菓子を、25℃でエージングした。
[Reference Example 2-1]
(1) The sorbitol crystal powder was heated to 120 ° C. to prepare a sorbitol melt in which sorbitol was melted.
(2) In the oil-based confectionery dough formulation described in Example 16 (2), an oil-based confectionery dough containing no sorbitol crystal powder (seed crystal) was prepared by the same procedure. The oil-based confectionery dough in a fluid state (50 ° C.) is added to 95 parts by weight by adding the sorbitol melt prepared in (1) to 90 parts by weight so as to be 5 parts by weight. Mixed. The oil content in the dough at the time of mixing was 33% by weight. After mixing the sorbitol melt, 97 parts by weight of the mixed dough was slowly cooled to 35 ° C., 3 parts by weight of a seed agent (manufactured by Fuji Oil Co., Ltd., trade name: chocolate seed B) was added, and the mixture was further mixed.
(3) The mixed dough obtained by mixing the seed agent in (2) above was filled in a mold, then cooled and solidified, and removed from the mold to obtain an oil-based confectionery. The obtained oil-based confectionery was aged at 25 ° C.

前記(3)において、35℃における高い耐熱性(評価:B)を有する油性菓子を得るまでに必要なエージング時間は20日間であった。ただし、得られた油性菓子は、風味、食感、口どけのいずれも従来のチョコレートと同様に良好であった。風味の中でも甘味については、同一の糖質を用いて従来の製法で製造される油性菓子と同程度であった。 In (3) above, the aging time required to obtain an oil-based confectionery having high heat resistance (evaluation: B) at 35 ° C. was 20 days. However, the obtained oil-based confectionery was as good in flavor, texture, and melting as conventional chocolate. Among the flavors, the sweetness was about the same as that of oil-based confectionery produced by the conventional manufacturing method using the same sugar.

[参考例2−2]
参考例2−1(2)において、油性菓子生地を90重量部に対して、ソルビトール融液を10重量部となるように添加混合する以外は、参考例2−1と同様の手順で油性菓子を調製した。工程(3)において、35℃における高い耐熱性(評価:B)を有する油性菓子を得るまでに必要なエージング時間は20日間であった。ただし、得られた油性菓子は、風味、食感、口どけのいずれも従来のチョコレートと同様に良好であった。風味の中でも甘味については、同一の糖質を用いて従来の製法で製造される油性菓子と同程度であった。
[Reference Example 2-2]
In Reference Example 2-1 (2), the procedure is the same as that of Reference Example 2-1 except that the oil-based confectionery dough is added and mixed in an amount of 10 parts by weight based on 90 parts by weight of the sorbitol melt. Was prepared. In step (3), the aging time required to obtain an oil-based confectionery having high heat resistance (evaluation: B) at 35 ° C. was 20 days. However, the obtained oil-based confectionery was as good in flavor, texture, and melting as conventional chocolate. Among the flavors, the sweetness was about the same as that of oil-based confectionery produced by the conventional manufacturing method using the same sugar.

[参考例2−3]
参考例2−1(2)において、油性菓子生地を80重量部に対して、ソルビトール融液を20重量部となるように添加混合する以外は、参考例2−1と同様の手順で油性菓子を調製した。工程(3)において、35℃における高い耐熱性(評価:B)を有する油性菓子を得るまでに必要なエージング時間は15日間であった。ただし、得られた油性菓子は、風味、食感、口どけのいずれも従来のチョコレートと同様に良好であった。風味の中でも甘味については、同一の糖質を用いて従来の製法で製造される油性菓子と同程度であった。
[Reference Example 2-3]
In Reference Example 2-1 (2), the procedure is the same as that of Reference Example 2-1 except that the oil-based confectionery dough is added and mixed in an amount of 20 parts by weight with respect to 80 parts by weight of the sorbitol melt. Was prepared. In step (3), the aging time required to obtain an oil-based confectionery having high heat resistance (evaluation: B) at 35 ° C. was 15 days. However, the obtained oil-based confectionery was as good in flavor, texture, and melting as conventional chocolate. Among the flavors, the sweetness was about the same as that of oil-based confectionery produced by the conventional manufacturing method using the same sugar.

[比較例4−1]
参考例2−1(2)で調製した油性菓子生地を50重量部に対して、実施例16の(1)で調製したソルビトール融液50重量部を90℃まで冷却した後に添加して、おだやかに混合した。混合された生地は、乳化状態がW/O型からO/W型へ変化したため、実施例16と同様の手順で油性菓子を成形することができなかった。
[Comparative Example 4-1]
The oil-based confectionery dough prepared in Reference Example 2-1 (2) was added to 50 parts by weight after cooling to 90 ° C. to 50 parts by weight of the sorbitol melt prepared in Example 16 (1). Mixed in. Since the emulsified state of the mixed dough changed from the W / O type to the O / W type, it was not possible to mold the oil-based confectionery by the same procedure as in Example 16.

[比較例4−2]
参考例2−1(2)で調製した油性菓子生地を用いて、ソルビトール融液を配合せずに、実施例16と同様の手順で油性菓子を調製した。得られた油性菓子を、35℃で1時間静置したところ、静置前の形状が保たれていなかった。(評価:D)。
[Comparative Example 4-2]
Using the oil-based confectionery dough prepared in Reference Example 2-1 (2), an oil-based confectionery was prepared in the same procedure as in Example 16 without blending the sorbitol melt. When the obtained oil-based confectionery was allowed to stand at 35 ° C. for 1 hour, the shape before standing was not maintained. (Evaluation: D).

[比較例4−3]
参考例2−1(2)で調製した油性菓子生地を95重量部に対して、実施例16の(1)で使用したソルビトール粉末5重量部を添加して、おだやかに混合した後、実施例16と同様の手順で油性菓子を調製した。得られた油性菓子を、35℃で1時間静置したところ、静置前の形状が保たれていなかった。(評価:D)。
[Comparative Example 4-3]
To 95 parts by weight of the oil-based confectionery dough prepared in Reference Example 2-1 (2), 5 parts by weight of the sorbitol powder used in (1) of Example 16 was added and mixed gently, and then Examples. An oily confectionery was prepared in the same procedure as in 16. When the obtained oil-based confectionery was allowed to stand at 35 ° C. for 1 hour, the shape before standing was not maintained. (Evaluation: D).

実施例16、参考例2−1〜3、比較例4−1〜3の結果を表13に示した。融液状の糖質を配合しない油性菓子生地を用いて得られた油性菓子(比較例4−2、4−3)は、35℃における高い耐熱性を有していなかった。種結晶を含まない油性菓子生地を用いて、5重量%〜20重量%のソルビトール融液を配合して調製された油性菓子(参考例2−1〜3、比較例4−1)は、35℃で1時間静置された後でも変形しない高い耐熱性(評価:B)を有していたが、耐熱性を発現するまでに必要なエージング時間(エージング温度:25℃)は15日〜20日間であった。一方、実施例16では、油性菓子生地に対して融液状の糖質に加えて種結晶を配合することにより、高い耐熱性(評価:B)を発現するまでに必要なエージング時間は、エージング温度が同じ25℃であるにも関わらず、5日以上短い10日間となった。また、油性菓子生地に対する融液状の糖質の配合量が5重量%〜20重量%よりも低い配合量であっても、種結晶が配合された油性菓子生地を用いることにより、同程度の高い耐熱性(評価:B)を有する油性菓子を得ることができた(実施例16:種結晶1重量%含有する油性菓子生地99重量部に対して1重量部の融液状の糖質を配合)。 The results of Example 16, Reference Examples 2-1 to 3, and Comparative Examples 4-1 to 3 are shown in Table 13. The oil-based confectionery (Comparative Examples 4-2 and 4-3) obtained by using the oil-based confectionery dough not containing the melted liquid sugar did not have high heat resistance at 35 ° C. The oil-based confectionery (Reference Examples 2-1 to 3 and Comparative Example 4-1) prepared by blending 5% by weight to 20% by weight of a sorbitol melt using an oil-based confectionery dough containing no seed crystals is 35. It had high heat resistance (evaluation: B) that did not deform even after being allowed to stand at ° C for 1 hour, but the aging time (aging temperature: 25 ° C) required to develop heat resistance was 15 days to 20 ° C. It was a day. On the other hand, in Example 16, the aging time required to develop high heat resistance (evaluation: B) by blending seed crystals in addition to the melt-liquid sugar to the oil-based confectionery dough is the aging temperature. Although the temperature was the same at 25 ° C, it was 10 days, which was shorter than 5 days. Further, even if the blending amount of the melted liquid sugar in the oil-based confectionery dough is lower than 5% by weight to 20% by weight, it is as high as that by using the oil-based confectionery dough containing the seed crystals. An oil-based confectionery having heat resistance (evaluation: B) could be obtained (Example 16: 1 part by weight of melted liquid sugar was mixed with 99 parts by weight of the oil-based confectionery dough containing 1% by weight of seed crystals). ..

Figure 2019240138
Figure 2019240138

[実施例17]キシリトール融液及びキシリトール種結晶を配合した耐熱性油性菓子
(1)キシリトール結晶粉末を130℃まで加熱して、キシリトールを融解させたキシリトール融液を調製した。
(2)カカオマス20重量部、ココアバター17.5重量部、全粉乳20重量部、乳化剤(レシチン)0.5重量部、香料0.1重量部、砂糖41重量部、キシリトール結晶粉末(種結晶)1重量部を常法により混合、粉砕及びコンチングして油性菓子生地を調製した。流動状態(60℃)である前記油性菓子生地3を99重量部に対して、前記(1)で調製したキシリトール融液を90℃まで冷却した後、1重量部となるように添加しておだやかに混合した。更にココアバターを添加混合して、前記混合生地中に含まれている油分が35重量%となるように調整した。キシリトール融液を混合した後の混合生地97重量部を35℃まで徐冷し、シード剤(不二製油株式会社製、商品名:チョコシードB)3重量部を添加し、更に混合した。
(3)前記(2)でシード剤を混合して得られた混合生地をモールドに充填した後、冷却固化させ、モールドから外した。得られた油性菓子を、25℃で5日間エージングした。
[Example 17] Heat-resistant oily confectionery containing a xylitol melt and xylitol seed crystals (1) A xylitol crystal powder was heated to 130 ° C. to prepare a xylitol melt in which xylitol was melted.
(2) 20 parts by weight of cocoa mass, 17.5 parts by weight of cocoa butter, 20 parts by weight of whole milk powder, 0.5 parts by weight of emulsifier (lecithin), 0.1 parts by weight of fragrance, 41 parts by weight of sugar, xylitol crystal powder (seed crystal) ) 1 part by weight was mixed, crushed and conched by a conventional method to prepare an oily confectionery dough. The oil-based confectionery dough 3 in a flowing state (60 ° C.) is cooled to 90 parts by weight with respect to 99 parts by weight, and then the xylitol melt prepared in (1) is added to 1 part by weight. Mixed in. Further, cocoa butter was added and mixed to adjust the oil content in the mixed dough to 35% by weight. After mixing the xylitol melt, 97 parts by weight of the mixed dough was slowly cooled to 35 ° C., 3 parts by weight of a seed agent (manufactured by Fuji Oil Co., Ltd., trade name: chocolate seed B) was added, and the mixture was further mixed.
(3) The mixed dough obtained by mixing the seed agent in (2) above was filled in a mold, then cooled and solidified, and removed from the mold. The obtained oil-based confectionery was aged at 25 ° C. for 5 days.

前記(3)で調製された油性菓子について耐熱性を評価したところ、45℃における高い耐熱性(評価:B)を有するだけでなく、風味、食感、口どけのいずれも従来のチョコレートと同様に良好であった。風味の中でも甘味については、同一の糖質を用いて従来の製法で製造される油性菓子と同程度であった。 When the heat resistance of the oil-based confectionery prepared in (3) was evaluated, it not only has high heat resistance at 45 ° C. (evaluation: B), but also has the same flavor, texture, and melting in the mouth as conventional chocolate. Was good. Among the flavors, the sweetness was about the same as that of oil-based confectionery produced by the conventional manufacturing method using the same sugar.

[参考例3−1]
(1)キシリトール結晶粉末を110℃まで加熱して、キシリトールを融解させたキシリトール融液を調製した。
(2)実施例17(2)に記載した油性菓子生地配合において、キシリトール結晶粉末(種結晶)を含まない油性菓子生地を同様の手順で調製した。流動状態(60℃)である前記油性菓子生地を95重量部に対して、前記(1)で調製したキシリトール融液を90℃まで冷却した後、5重量部となるように添加して、おだやかに混合した。前記混合時の生地に含まれる油分は33重量%であった。キシリトール融液を混合した後の混合生地97重量部を35℃まで徐冷し、シード剤(不二製油株式会社製、商品名:チョコシードB)3重量部を添加し、更に混合した。
(3)前記(2)でシード剤を混合して得られた混合生地をモールドに充填した後、冷却固化させ、モールドから外した。得られた油性菓子を、25℃でエージングした。
[Reference Example 3-1]
(1) The xylitol crystal powder was heated to 110 ° C. to prepare a xylitol melt in which xylitol was melted.
(2) In the oil-based confectionery dough formulation described in Example 17 (2), an oil-based confectionery dough containing no xylitol crystal powder (seed crystal) was prepared by the same procedure. The oily confectionery dough in a flowing state (60 ° C.) is added to 95 parts by weight of the xylitol melt prepared in (1) above to 90 ° C., and then added to 5 parts by weight to make it mild. Mixed in. The oil content in the dough at the time of mixing was 33% by weight. After mixing the xylitol melt, 97 parts by weight of the mixed dough was slowly cooled to 35 ° C., 3 parts by weight of a seed agent (manufactured by Fuji Oil Co., Ltd., trade name: chocolate seed B) was added, and the mixture was further mixed.
(3) The mixed dough obtained by mixing the seed agent in (2) above was filled in a mold, then cooled and solidified, and removed from the mold. The obtained oil-based confectionery was aged at 25 ° C.

前記(3)において、35℃における耐熱性(評価:A)を有する油性菓子を得るまでに必要なエージング時間は14日間であった。ただし、得られた油性菓子は、風味、食感、口どけのいずれも従来のチョコレートと同様に良好であった。風味の中でも甘味については、同一の糖質を用いて従来の製法で製造される油性菓子と同程度であった。 In (3) above, the aging time required to obtain an oil-based confectionery having heat resistance (evaluation: A) at 35 ° C. was 14 days. However, the obtained oil-based confectionery was as good in flavor, texture, and melting as conventional chocolate. Among the flavors, the sweetness was about the same as that of oil-based confectionery produced by the conventional manufacturing method using the same sugar.

[比較例5−1]
参考例3−1(2)で調製した油性菓子生地を95重量部に対して、参考例3−1(1)で使用したキシリトール結晶粉末5重量部を添加して、おだやかに混合した後、参考例3−1(3)と同様の手順で油性菓子を調製した。得られた油性菓子を35℃で1時間静置したところ、静置前の形状が保たれていなかった。(評価:D)。
[Comparative Example 5-1]
After adding 5 parts by weight of the xylitol crystal powder used in Reference Example 3-1 (1) to 95 parts by weight of the oil-based confectionery dough prepared in Reference Example 3-1 (2) and mixing gently. An oil-based confectionery was prepared in the same procedure as in Reference Example 3-1 (3). When the obtained oil-based confectionery was allowed to stand at 35 ° C. for 1 hour, the shape before standing was not maintained. (Evaluation: D).

[参考例3−2]
参考3−1(2)において、油性菓子生地を90重量部に対して、キシリトール融液を10重量部となるように添加混合する以外は、参考例3−1と同様の手順で油性菓子を調製した。工程(3)において、35℃における著しく高い耐熱性(評価:A)を有する油性菓子を得るまでに必要なエージング時間は1日間であった。得られた油性菓子は、風味、食感、口どけのいずれも従来のチョコレートと同様に良好であった。風味の中でも甘味については、同一の糖質を用いて従来の製法で製造される油性菓子と同程度であった。ただし、工程(2)において、キシリトール融液と油性菓子生地を均一に混合することは可能だったが、一般的な充填機を用いた型への充填作業を行うことは困難であった。
[Reference Example 3-2]
In Reference 3-1 (2), the oil-based confectionery is prepared in the same procedure as in Reference Example 3-1 except that the oil-based confectionery dough is added and mixed in an amount of 10 parts by weight based on 90 parts by weight of the xylitol melt. Prepared. In the step (3), the aging time required to obtain an oil-based confectionery having extremely high heat resistance (evaluation: A) at 35 ° C. was one day. The obtained oil-based confectionery was as good in flavor, texture, and melting as conventional chocolate. Among the flavors, the sweetness was about the same as that of oil-based confectionery produced by the conventional manufacturing method using the same sugar. However, in the step (2), although it was possible to uniformly mix the xylitol melt and the oil-based confectionery dough, it was difficult to perform the filling operation into the mold using a general filling machine.

実施例17、参考例3−1、比較例5−1、参考例3−2の結果を表14に示した。融液状の糖質を配合しない油性菓子生地を用いて得られた油性菓子(比較例5−1)は、35℃における高い耐熱性を有していなかった。種結晶を含まない油性菓子生地にキシリトール融液を配合して調製された油性菓子(参考例3−1)は、35℃で1時間静置された後でも変形しない著しく高い耐熱性(評価:A)を有していたが、耐熱性を発現するまでに必要なエージング時間(エージング温度:25℃)は14日間であった。一方、実施例17は、油性菓子生地に対して融液状の糖質に加えて種結晶を配合することにより、同じ25℃でエージングしたにもかかわらず、耐熱性(評価:B)を発現するまでに必要なエージング時間は5日間であり、種結晶を含まない場合よりも9日間短縮することができた。なお、キシリトール融液を10重量%配合した油性菓子(参考例3−2)は、25℃で1日間エージングすることにより35℃における著しく高い耐熱性(評価:A)を有していたが、一般的な充填機を用いた充填作業を行うことは困難であった。実施例17においては、充填作業は何ら問題なく進めることが可能であった。 The results of Example 17, Reference Example 3-1 and Comparative Example 5-1 and Reference Example 3-2 are shown in Table 14. The oil-based confectionery (Comparative Example 5-1) obtained by using the oil-based confectionery dough not containing the melted liquid sugar did not have high heat resistance at 35 ° C. The oil-based confectionery (Reference Example 3-1) prepared by blending a xylitol melt with an oil-based confectionery dough that does not contain seed crystals has extremely high heat resistance that does not deform even after being allowed to stand at 35 ° C. for 1 hour (evaluation: Although it had A), the aging time (aging temperature: 25 ° C.) required for developing heat resistance was 14 days. On the other hand, in Example 17, heat resistance (evaluation: B) was exhibited in spite of aging at the same 25 ° C. by blending seed crystals in addition to the melt-liquid sugar to the oil-based confectionery dough. The aging time required was 5 days, which was 9 days shorter than that without the seed crystal. The oil-based confectionery containing 10% by weight of xylitol melt (Reference Example 3-2) had extremely high heat resistance (evaluation: A) at 35 ° C. by aging at 25 ° C. for 1 day. It was difficult to perform filling work using a general filling machine. In Example 17, the filling work could proceed without any problem.

Figure 2019240138
Figure 2019240138

[参考例4]油性菓子生地の温度と、融液状の糖質の温度の影響
(1)キシリトール結晶粉末を130℃まで加熱して、キシリトールを融解させたキシリトール融液を調製した。
(2)カカオマス20重量部、ココアバター17.5重量部、全粉乳20重量部、乳化剤(レシチン)0.5重量部、香料0.1重量部、砂糖42重量部を常法により混合、粉砕及びコンチングして油性菓子生地を調製した。流動状態(温度は表15を参照)である前記油性菓子生地を95重量部に対して、前記(1)で調製したキシリトール融液を特定温度(温度は表15を参照)に調整した後、5重量部となるように添加して、手早く混合した。ただし、試験区7−5については、油性菓子生地を98重量部に対して、キシリトール融液を2重量部として同様に混合した。前記キシリトール融液混合生地97重量部を35℃まで徐冷し、シード剤(不二製油株式会社製、商品名:チョコシードB)3重量部を添加し、更に混合した。
(3)前記(2)でシード剤を添加して得られた混合生地をモールドに充填した後、冷却固化し、モールドから外した。得られた油性菓子を、室温(24℃)で14日間エージングした。
[Reference Example 4] Effect of temperature of oily confectionery dough and temperature of melted sugar (1) Xylitol crystal powder was heated to 130 ° C. to prepare a xylitol melt in which xylitol was melted.
(2) 20 parts by weight of cocoa mass, 17.5 parts by weight of cocoa butter, 20 parts by weight of whole milk powder, 0.5 parts by weight of emulsifier (lecithin), 0.1 parts by weight of flavor, and 42 parts by weight of sugar are mixed and crushed by a conventional method. And conching to prepare an oily confectionery dough. After adjusting the oil-based confectionery dough in a flowing state (see Table 15 for temperature) to a specific temperature (see Table 15 for temperature) with respect to 95 parts by weight of the xylitol melt prepared in (1) above. It was added in an amount of 5 parts by weight and mixed quickly. However, in Test Group 7-5, the oil-based confectionery dough was mixed in the same manner with 98 parts by weight and the xylitol melt as 2 parts by weight. 97 parts by weight of the xylitol melt mixed dough was slowly cooled to 35 ° C., 3 parts by weight of a seed agent (manufactured by Fuji Oil Co., Ltd., trade name: chocolate seed B) was added, and the mixture was further mixed.
(3) The mixed dough obtained by adding the seeding agent in (2) above was filled in a mold, then cooled and solidified, and removed from the mold. The obtained oil-based confectionery was aged at room temperature (24 ° C.) for 14 days.

前記(3)で調製された油性菓子について、45℃における耐熱性を評価した。結果を表15に示した。混合前の油性菓子生地の温度を40℃以上(45℃〜54℃)として、かつ、融液状の糖質(キシリトール融液)を60℃以上200℃未満(60℃〜145℃)に調整して混合し、室温(24℃)でエージングすることにより、得られる油性菓子(試験区7−1、7−5〜7−8)は45℃における耐熱性(評価:C〜B)を有していた。特に、油性菓子生地と融液状の糖質を混合した生地の温度が50℃を超える場合(試験区7−6〜7−8)については、得られる油性菓子は高い耐熱性(評価:B)を有していた。 The heat resistance of the oil-based confectionery prepared in (3) above at 45 ° C. was evaluated. The results are shown in Table 15. The temperature of the oil-based confectionery dough before mixing is adjusted to 40 ° C. or higher (45 ° C. to 54 ° C.), and the melted sugar (xylitol melt) is adjusted to 60 ° C. or higher and lower than 200 ° C. (60 ° C. to 145 ° C.). The oil-based confectionery (Test Group 7-1, 7-5-7-8) obtained by mixing and aging at room temperature (24 ° C.) has heat resistance (evaluation: C to B) at 45 ° C. Was there. In particular, when the temperature of the dough in which the oil-based confectionery dough and the melted liquid sugar are mixed exceeds 50 ° C. (test group 7-6 to 7-8), the obtained oil-based confectionery has high heat resistance (evaluation: B). Had.

Figure 2019240138
Figure 2019240138

[実施例18]キシリトール融液を配合した耐熱性油性菓子(1)
(1)キシリトール結晶粉末を130℃まで加熱して、キシリトールを融解させたキシリトール融液を調製した。
(2)カカオマス20重量部、ココアバター17.5重量部、全粉乳20重量部、乳化剤(レシチン)0.5重量部、香料0.1重量部、砂糖42重量部を常法により混合、粉砕及びコンチングして油性菓子生地1を調製した。流動状態(31℃〜37℃)である前記油性菓子生地1を95重量部に対して、前記(1)で調製したキシリトール融液を65℃〜140℃に調整した後に5重量部となるように添加して、ゴムべらで軽く撹拌して混合した。続いて、ホモジナイザー(商品名:ヒスコトロンNS−57S、株式会社マイクロテック・ニチオン製、シャフト形式:NS−20)又はミキサー(商品名:ケンミックスKMM770、デロンギ・ジャパン株式会社製、撹拌子:ホイッパー)を用いて、30秒〜10分間せん断混合した。各試験区における油性菓子生地とキシリトール融液の温度、混合条件を表16に示した。前記混合時の生地に含まれる油分は34重量%であった。キシリトール融液が添加された混合生地97重量部を35℃まで徐冷し、シード剤(不二製油株式会社製、商品名:チョコシードB)3重量部を添加し、更に混合した。
(3)前記(2)でシード剤を混合して得られた混合生地をモールドに充填した後、冷却固化し、モールドから外した。得られた油性菓子を、24℃〜28℃で1日〜9日間エージングした。
[Example 18] Heat-resistant oil-based confectionery containing a xylitol melt (1)
(1) The xylitol crystal powder was heated to 130 ° C. to prepare a xylitol melt in which xylitol was melted.
(2) 20 parts by weight of cocoa mass, 17.5 parts by weight of cocoa butter, 20 parts by weight of whole milk powder, 0.5 parts by weight of emulsifier (lecithin), 0.1 parts by weight of flavor, and 42 parts by weight of sugar are mixed and crushed by a conventional method. And conching to prepare an oil-based confectionery dough 1. The amount of the oil-based confectionery dough 1 in a flowing state (31 ° C. to 37 ° C.) is adjusted to 95 parts by weight, and the amount of the xylitol melt prepared in the above (1) is adjusted to 65 ° C. to 140 ° C. to 5 parts by weight. Was added to the mixture, and the mixture was mixed by gently stirring with a rubber spatula. Subsequently, a homogenizer (trade name: Hiscotron NS-57S, manufactured by Microtech Nithione Co., Ltd., shaft type: NS-20) or a mixer (trade name: Kenmix KMM770, manufactured by Delonghi Japan Co., Ltd., stirrer: whipper) Was shear-mixed for 30 seconds to 10 minutes. Table 16 shows the temperatures and mixing conditions of the oil-based confectionery dough and the xylitol melt in each test group. The oil content in the dough at the time of mixing was 34% by weight. 97 parts by weight of the mixed dough to which the xylitol melt was added was slowly cooled to 35 ° C., 3 parts by weight of a seed agent (manufactured by Fuji Oil Co., Ltd., trade name: chocolate seed B) was added, and the mixture was further mixed.
(3) The mixed dough obtained by mixing the seed agent in (2) above was filled in a mold, then cooled and solidified, and removed from the mold. The obtained oil-based confectionery was aged at 24 ° C. to 28 ° C. for 1 to 9 days.

前記(3)で調製された油性菓子について、45℃における耐熱性を評価した。キシリトール融液を油性菓子全重量中に5重量%配合された油性菓子は、実施例18の全試験区の油性菓子は、9日以下のエージング時間によって45℃における耐熱性(評価:A〜C)を有するだけでなく、風味、食感、口どけのいずれも従来のチョコレートと同様に良好であった。風味の中でも甘味については、同一の糖質を用いて従来の製法で製造される油性菓子と同程度であった。 The heat resistance of the oil-based confectionery prepared in (3) above at 45 ° C. was evaluated. The oil-based confectionery containing 5% by weight of the xylitol melt in the total weight of the oil-based confectionery was heat-resistant at 45 ° C. for the oil-based confectionery in all the test groups of Example 18 with an aging time of 9 days or less (evaluation: A to C). ), But also the flavor, texture, and melting in the mouth were all as good as those of conventional chocolate. Among the flavors, the sweetness was about the same as that of oil-based confectionery produced by the conventional manufacturing method using the same sugar.

実施例18−4、18−5、18−10、18−11で得られた油性菓子の硬度を測定した。ただし、硬度測定前の静置温度と静置時間は、以下のとおりとした。
実施例18−4:35℃で1時間静置
実施例18−5:45℃で2時間静置
実施例18−10、18−11:45℃で1時間静置
結果を表16に示した。いずれの実施例についても、硬度は100gf以上であった。
The hardness of the oil-based confectionery obtained in Examples 18-4, 18-5, 18-10, 18-11 was measured. However, the standing temperature and standing time before hardness measurement were as follows.
Example 18-4: Standing at 35 ° C for 1 hour Example 18-5: Standing at 45 ° C for 2 hours Example 18-10, Standing at 18-11: 45 ° C for 1 hour The results are shown in Table 16. .. In each of the examples, the hardness was 100 gf or more.

[比較例6]キシリトール融液を配合していない耐熱性油性菓子
比較例6−1
実施例18において、キシリトール融液を添加せず、油性菓子生地1をホモジナイザーで10,000rpmで15秒せん断混合した後、実施例18と同様の手順で油性菓子を調整した。エージングは室温(24℃)で15日間行ったが、35℃における耐熱性を有する油性菓子は得られなかった(評価:D)。
[参考例5]キシリトール融液を配合していない耐熱性油性菓子
参考例5−1〜5−4
実施例18の(2)において、せん断混合を行わず、ゴムべらで軽く撹拌することにより混合する以外は、実施例18と同様の手順で油性菓子を調製した。ただし、油性菓子のエージングは24℃〜25℃で実施した。各試験区の油性菓子生地とキシリトール融液の温度は、表16に示した。
[Comparative Example 6] Heat-resistant oil-based confectionery that does not contain xylitol melt
Comparative Example 6-1 :
In Example 18, the oil-based confectionery dough 1 was shear-mixed with a homogenizer at 10,000 rpm for 15 seconds without adding the xylitol melt, and then the oil-based confectionery was prepared in the same procedure as in Example 18. Aging was carried out at room temperature (24 ° C.) for 15 days, but no oil-based confectionery having heat resistance at 35 ° C. was obtained (evaluation: D).
[Reference Example 5] Heat-resistant oil-based confectionery that does not contain xylitol melt
Reference example 5-1 to 5-4 :
In Example 18 (2), an oil-based confectionery was prepared in the same procedure as in Example 18 except that shear mixing was not performed and the mixture was mixed by gently stirring with a rubber spatula. However, the aging of the oil-based confectionery was carried out at 24 ° C. to 25 ° C. The temperatures of the oil-based confectionery dough and the xylitol melt in each test group are shown in Table 16.

実施例18−1〜11及び比較例6−1、参考例5−1〜4の結果を表16に示した。参考例5−1〜4が示すように、せん断混合工程を含まない製造方法により耐熱性チョコレートを得るためにはエージング時間として14日間必要であった。一方、実施例18−1〜11が示すように、せん断混合工程を実施することにより、45℃における耐熱性を有する油性菓子を得るために必要なエージング時間は1日〜9日間となった。すなわち、せん断混合を行うことにより、耐熱性チョコレートを得るまでに必要なエージング時間は5日〜13日間短縮された。 The results of Examples 18-1 to 11, Comparative Example 6-1 and Reference Examples 5-1 to 4 are shown in Table 16. As shown in Reference Examples 5-1 to 4, 14 days was required as the aging time in order to obtain heat-resistant chocolate by the production method not including the shear mixing step. On the other hand, as shown in Examples 18-1 to 11, the aging time required to obtain an oil-based confectionery having heat resistance at 45 ° C. was 1 to 9 days by carrying out the shear mixing step. That is, by performing shear mixing, the aging time required to obtain heat-resistant chocolate was shortened by 5 to 13 days.

Figure 2019240138
Figure 2019240138

[実施例19]キシリトール融液を配合した耐熱性油性菓子(2)
(1)キシリトール結晶粉末を130℃まで加熱して、キシリトールを融解させたキシリトール融液を調製した。
(2)カカオマス20重量部、ココアバター17.5重量部、全粉乳20重量部、乳化剤(レシチン)0.5重量部、香料0.1重量部、砂糖42重量部を常法により混合、粉砕及びコンチングして油性菓子生地1を調製した。流動状態(31℃〜44℃)である前記油性菓子生地1を97重量部に対して、前記(1)で調製したキシリトール融液を140℃に調整した後に3重量部となるように添加して、ゴムべらで軽く撹拌して混合した。続いて、ホモジナイザー(商品名:ヒスコトロンNS−57S、株式会社マイクロテック・ニチオン製、シャフト形式:NS−20)又はミキサー(商品名:ケンミックスKMM770、デロンギ・ジャパン株式会社製、撹拌子:ホイッパー)を用いて、30秒〜10分間せん断混合した。各試験区における油性菓子生地とキシリトール融液の温度、混合条件を表17に示した。前記混合時の生地に含まれる油分は34重量%であった。キシリトール融液が添加された混合生地97重量部を35℃まで徐冷し、シード剤(不二製油株式会社製、商品名:チョコシードB)3重量部を添加し、更に混合した。
(3)実施例19−1〜19−6、19−11:前記(2)でシード剤を混合して得られた混合生地をモールドに充填した後、冷却固化し、モールドから外した。得られた油性菓子を、25℃〜45℃で1時間〜5日間エージングした。
実施例19−7、19−10:前記(2)でシード剤を混合して得られた混合生地をモールドに充填した後、冷却固化せずに、モールドに入れた状態で35℃(実施例19−10)又は45℃(実施例19−1)で1日間エージングした。
実施例19−8、19−9:前記(2)でシード剤を混合して得られた混合生地をモールドに充填した後、冷却固化し、モールドから外した。実施例19−8では、得られた油性菓子を45℃で2時間エージングした。実施例19−9では、得られた油性菓子を35℃で1時間エージングした。
[Example 19] Heat-resistant oil-based confectionery containing a xylitol melt (2)
(1) The xylitol crystal powder was heated to 130 ° C. to prepare a xylitol melt in which xylitol was melted.
(2) 20 parts by weight of cocoa mass, 17.5 parts by weight of cocoa butter, 20 parts by weight of whole milk powder, 0.5 parts by weight of emulsifier (lecithin), 0.1 parts by weight of flavor, and 42 parts by weight of sugar are mixed and crushed by a conventional method. And conching to prepare an oil-based confectionery dough 1. The oil-based confectionery dough 1 in a flowing state (31 ° C. to 44 ° C.) was added to 97 parts by weight of the xylitol melt prepared in (1) above so as to be 3 parts by weight after adjusting to 140 ° C. Then, the mixture was mixed by gently stirring with a rubber spatula. Subsequently, a homogenizer (trade name: Hiscotron NS-57S, manufactured by Microtech Nithione Co., Ltd., shaft type: NS-20) or a mixer (trade name: Kenmix KMM770, manufactured by Delonghi Japan Co., Ltd., stirrer: whipper) Was shear-mixed for 30 seconds to 10 minutes. Table 17 shows the temperatures and mixing conditions of the oil-based confectionery dough and the xylitol melt in each test group. The oil content in the dough at the time of mixing was 34% by weight. 97 parts by weight of the mixed dough to which the xylitol melt was added was slowly cooled to 35 ° C., 3 parts by weight of a seed agent (manufactured by Fuji Oil Co., Ltd., trade name: chocolate seed B) was added, and the mixture was further mixed.
(3) Examples 19-1 to 19-6, 19-11: The mixed dough obtained by mixing the seed agent in (2) above was filled in a mold, then cooled and solidified, and removed from the mold. The obtained oil-based confectionery was aged at 25 ° C. to 45 ° C. for 1 hour to 5 days.
Examples 19-7, 19-10: The mixed dough obtained by mixing the seed agent in (2) above is filled in a mold, and then placed in a mold without cooling and solidifying at 35 ° C. (Example). It was aged at 19-10) or 45 ° C. (Example 19-1) for 1 day.
Examples 19-8 and 19-9: The mixed dough obtained by mixing the seed agent in (2) above was filled in a mold, then cooled and solidified, and removed from the mold. In Examples 19-8, the obtained oil-based confectionery was aged at 45 ° C. for 2 hours. In Examples 19-9, the obtained oil-based confectionery was aged at 35 ° C. for 1 hour.

前記(3)のエージング後の油性菓子について、45℃における耐熱性を評価した。実施例19により得られた油性菓子は、45℃における耐熱性(評価:A〜C)を有するだけでなく、風味、食感、口どけのいずれも従来のチョコレートと同様に良好であった。風味の中でも甘味については、同一の糖質を用いて従来の製法で製造される油性菓子と同程度であった。実施例19においては、耐熱性が得られるまでに必要なエージング時間は1時間〜5日間であり、前記した参考例5−1〜5−4における14日間よりも9日以上短縮された。 The heat resistance of the aged oil-based confectionery (3) at 45 ° C. was evaluated. The oil-based confectionery obtained in Example 19 not only had heat resistance at 45 ° C. (evaluation: A to C), but also had good flavor, texture, and melting in the mouth as well as conventional chocolate. Among the flavors, the sweetness was about the same as that of oil-based confectionery produced by the conventional manufacturing method using the same sugar. In Example 19, the aging time required to obtain heat resistance was 1 hour to 5 days, which was shorter than the 14 days in Reference Examples 5-1 to 5-4 described above by 9 days or more.

Figure 2019240138
Figure 2019240138

実施例19−3〜19−6、19−8、19−9、19−11で得られた油性菓子の硬度を測定した。ただし、硬度測定前の静置温度と静置時間は、以下のとおりとした。
実施例19−3〜19−5、19−11:45℃で1時間静置
実施例19−6:45℃で2時間静置
実施例19−8、19−9:エージング直後に硬度測定
結果を表17に示した。いずれの実施例についても、硬度は100gf以上であった。
The hardness of the oil-based confectionery obtained in Examples 19-3 to 19-6, 19-8, 19-9, 19-11 was measured. However, the standing temperature and standing time before hardness measurement were as follows.
Examples 19-3 to 19-5, 19-11: Standing at 45 ° C. for 1 hour Example 19-6: Standing at 45 ° C. for 2 hours Examples 19-8, 19-9: Hardness measurement results immediately after aging Is shown in Table 17. In each of the examples, the hardness was 100 gf or more.

[実施例20]キシリトール融液を配合した耐熱性油性菓子(3)
(1)キシリトール結晶粉末を130℃まで加熱して、キシリトールを融解させたキシリトール融液を調製した。
(2)カカオマス20重量部、ココアバター17.5重量部、全粉乳20重量部、乳化剤(レシチン)0.5重量部、香料0.1重量部、砂糖42重量部を常法により混合、粉砕及びコンチングして油性菓子生地1を調製した。流動状態(35℃)である前記油性菓子生地1を97重量部に対して、前記(1)で調製したキシリトール融液を140℃に調整した後に3重量部となるように添加した。続いて、ミキサー(商品名:モンドミックス、株式会社モンドミックス・ジャパン社製)を用いて、ポンプ送液量40kg/hとして、表18に示した回転数によりせん断混合した。前記混合時の生地に含まれる油分は34重量%であった。キシリトール融液が添加された混合生地97重量部を35℃まで徐冷し、シード剤(不二製油株式会社製、商品名:チョコシードB)3重量部を添加し、更に混合した。
(3)前記(2)でシード剤を混合して得られた混合生地をモールドに充填した後、冷却固化し、モールドから外した後、油性菓子を得た。
[Example 20] Heat-resistant oil-based confectionery containing a xylitol melt (3)
(1) The xylitol crystal powder was heated to 130 ° C. to prepare a xylitol melt in which xylitol was melted.
(2) 20 parts by weight of cocoa mass, 17.5 parts by weight of cocoa butter, 20 parts by weight of whole milk powder, 0.5 parts by weight of emulsifier (lecithin), 0.1 parts by weight of flavor, and 42 parts by weight of sugar are mixed and crushed by a conventional method. And conching to prepare an oil-based confectionery dough 1. The oil-based confectionery dough 1 in a flowing state (35 ° C.) was added to 97 parts by weight so that the xylitol melt prepared in (1) above was adjusted to 140 ° C. and then increased to 3 parts by weight. Subsequently, using a mixer (trade name: Mondomix, manufactured by Mondomix Japan Co., Ltd.), shear mixing was performed at a pump liquid feed rate of 40 kg / h at the rotation speeds shown in Table 18. The oil content in the dough at the time of mixing was 34% by weight. 97 parts by weight of the mixed dough to which the xylitol melt was added was slowly cooled to 35 ° C., 3 parts by weight of a seed agent (manufactured by Fuji Oil Co., Ltd., trade name: chocolate seed B) was added, and the mixture was further mixed.
(3) The mixed dough obtained by mixing the seed agent in (2) above was filled in a mold, then cooled and solidified, removed from the mold, and then an oil-based confectionery was obtained.

前記(3)で調製された油性菓子を45℃で1時間静置した後、耐熱性を評価した。実施例20により得られた油性菓子は、耐熱性(評価:B〜C)を有するだけでなく、風味、食感、口どけのいずれも従来のチョコレートと同様に良好であった。風味の中でも甘味については、同一の糖質を用いて従来の製法で製造される油性菓子と同程度であった。実施例20においては、耐熱性が得られるまでに必要なエージング時間は実質的に1時間であり、前記した参考例5−1〜5−4における14日間よりも大幅に短縮された。 The oil-based confectionery prepared in (3) above was allowed to stand at 45 ° C. for 1 hour, and then the heat resistance was evaluated. The oil-based confectionery obtained in Example 20 not only had heat resistance (evaluation: BC), but also had good flavor, texture, and melting in the mouth as well as conventional chocolate. Among the flavors, the sweetness was about the same as that of oil-based confectionery produced by the conventional manufacturing method using the same sugar. In Example 20, the aging time required to obtain heat resistance was substantially 1 hour, which was significantly shorter than the 14 days in Reference Examples 5-1 to 5-4 described above.

Figure 2019240138
Figure 2019240138

Claims (19)

耐熱性を有する油性菓子の製造方法であって、
室温で固体の糖質であって、加熱により融液状となっている糖質を、油性菓子の全重量に対して0.5重量%以上〜50重量%未満となるように油性菓子生地と混合して混合生地を得る工程を含む、方法。
A method for producing heat-resistant oil-based confectionery.
A sugar that is solid at room temperature and is melted by heating is mixed with the oil-based confectionery dough so as to be 0.5% by weight or more and less than 50% by weight based on the total weight of the oil-based confectionery. A method comprising the step of obtaining a mixed dough.
融液状の糖質が、溶媒の不在下で、糖質のみを加熱することで調製される、請求項1に記載の方法。 The method according to claim 1, wherein the melt-liquid sugar is prepared by heating only the sugar in the absence of a solvent. 更に、混合生地を得る工程の後に、混合生地を成形及びエージングする工程を含む、請求項1又は2に記載の方法。 The method according to claim 1 or 2, further comprising a step of forming and aging the mixed dough after the step of obtaining the mixed dough. エージングを24℃以上で行う、請求項3に記載の方法。 The method according to claim 3, wherein the aging is performed at 24 ° C. or higher. 融液状の糖質と混合する時の油性菓子生地の温度が30℃〜65℃である、請求項1〜4のいずれか一項に記載の方法。 The method according to any one of claims 1 to 4, wherein the temperature of the oil-based confectionery dough when mixed with the melted liquid sugar is 30 ° C. to 65 ° C. 油性菓子生地と混合する時の融液状の糖質の温度が60℃以上200℃未満である、請求項1〜5のいずれか一項に記載の方法。 The method according to any one of claims 1 to 5, wherein the temperature of the melted liquid sugar when mixed with the oil-based confectionery dough is 60 ° C. or higher and lower than 200 ° C. 融液状の糖質が、キシリトール、ソルビトール、フルクトース、エリスリトールのいずれか1種、又は前記糖質を2種以上組み合わせたものである、請求項1〜6のいずれか一項に記載の方法。 The method according to any one of claims 1 to 6, wherein the melt-liquid sugar is any one of xylitol, sorbitol, fructose, and erythritol, or a combination of two or more of the sugars. 融液状の糖質と混合する前の油性菓子生地に含まれる油分が40重量%以下である、請求項1〜7のいずれか一項に記載の方法。 The method according to any one of claims 1 to 7, wherein the oil content in the oil-based confectionery dough before being mixed with the melted liquid sugar is 40% by weight or less. 融液状の糖質が、油性菓子の全重量に対して2重量%〜20重量%となるように油性菓子生地と混合される、請求項1〜8のいずれか一項に記載の方法。 The method according to any one of claims 1 to 8, wherein the melt-liquid sugar is mixed with the oil-based confectionery dough so as to be 2% by weight to 20% by weight based on the total weight of the oil-based confectionery. 油性菓子生地に融液状の糖質の種結晶が配合されている、請求項1〜8のいずれか一項に記載の方法。 The method according to any one of claims 1 to 8, wherein the oil-based confectionery dough contains a melt-liquid sugar seed crystal. 融液状の糖質が、油性菓子の全重量に対して0.5重量%〜20重量%となるように油性菓子生地と混合される、請求項10に記載の方法。 The method according to claim 10, wherein the melt-liquid sugar is mixed with the oil-based confectionery dough so as to be 0.5% by weight to 20% by weight based on the total weight of the oil-based confectionery. 混合生地を得る工程において、混合生地が、せん断作用を与えながら融液状の糖質と油性菓子生地とを混合することにより得られる、請求項1〜8のいずれか一項に記載の方法。 The method according to any one of claims 1 to 8, wherein in the step of obtaining the mixed dough, the mixed dough is obtained by mixing the melted sugar and the oily confectionery dough while giving a shearing action. 融液状の糖質が、油性菓子の全重量に対して1重量%〜20重量%となるように油性菓子生地と混合される、請求項12に記載の方法。 The method according to claim 12, wherein the melt-liquid sugar is mixed with the oil-based confectionery dough so as to be 1% by weight to 20% by weight based on the total weight of the oil-based confectionery. 融液状の糖質を混合する前の油性菓子生地に含まれる油分が40重量%以下である、請求項12又は13に記載の方法。 The method according to claim 12 or 13, wherein the oil content in the oil-based confectionery dough before mixing the melted liquid sugar is 40% by weight or less. 請求項1〜14のいずれか一項に記載の方法により得られる、油性菓子。 An oil-based confectionery obtained by the method according to any one of claims 1 to 14. 室温で固体の糖質であって、加熱により融液状となっている糖質を油性菓子生地に添加することにより、油性菓子の耐熱性を向上させる方法。 A method of improving the heat resistance of an oil-based confectionery by adding a sugar that is solid at room temperature and becomes a melt-liquid by heating to the oil-based confectionery dough. 融液状の糖質を添加する前の油性菓子生地が流動状態にある、請求項16に記載の方法。 The method according to claim 16, wherein the oil-based confectionery dough before the addition of the melted liquid sugar is in a fluid state. 室温で固体の糖質であって、加熱により融液状となっている糖質を有効成分として含む、油性菓子に対する耐熱性付与剤。 A heat-resistant imparting agent for oil-based confectionery, which contains a sugar that is solid at room temperature and becomes a melted liquid by heating as an active ingredient. 更に、当該融液状の糖質の種結晶を有効成分として含む、請求項18に記載の耐熱性付与剤。 The heat resistance imparting agent according to claim 18, further comprising a seed crystal of the melted liquid sugar as an active ingredient.
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JPH02276537A (en) * 1989-04-15 1990-11-13 Lotte Co Ltd Heat-resistant chocolate and preparation thereof
JP2010178662A (en) * 2009-02-05 2010-08-19 Nagaoka Koryo Kk Heat-resistant chocolate
JP2011015680A (en) * 2009-07-09 2011-01-27 Kraft Foods Research & Development Inc Process for producing confectionery product
WO2014052312A1 (en) * 2012-09-28 2014-04-03 Mars, Incorporated Heat resistant chocolate

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JPH02276537A (en) * 1989-04-15 1990-11-13 Lotte Co Ltd Heat-resistant chocolate and preparation thereof
JP2010178662A (en) * 2009-02-05 2010-08-19 Nagaoka Koryo Kk Heat-resistant chocolate
JP2011015680A (en) * 2009-07-09 2011-01-27 Kraft Foods Research & Development Inc Process for producing confectionery product
WO2014052312A1 (en) * 2012-09-28 2014-04-03 Mars, Incorporated Heat resistant chocolate

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Publication number Priority date Publication date Assignee Title
CN113875868A (en) * 2021-08-31 2022-01-04 北京辛迪焙瑞食品有限公司 Preparation method of wine-filled chocolate with mellow bouquet

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