JPWO2019130664A1 - Sheet-like external preparation - Google Patents
Sheet-like external preparation Download PDFInfo
- Publication number
- JPWO2019130664A1 JPWO2019130664A1 JP2019562740A JP2019562740A JPWO2019130664A1 JP WO2019130664 A1 JPWO2019130664 A1 JP WO2019130664A1 JP 2019562740 A JP2019562740 A JP 2019562740A JP 2019562740 A JP2019562740 A JP 2019562740A JP WO2019130664 A1 JPWO2019130664 A1 JP WO2019130664A1
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- Japan
- Prior art keywords
- external preparation
- oil
- sheet
- based external
- coating film
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/89—Polysiloxanes
- A61K8/891—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
- A61Q1/02—Preparations containing skin colorants, e.g. pigments
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Cosmetics (AREA)
Abstract
被覆フィルムと油性外用剤層との間に隙間を設けなくても油性外用剤が被覆フィルムに付着しにくく、しかも、油性外用剤の指取れにも優れたシート状外用剤を提供する。本発明のシート状外用剤は、基材シートと、基材シートの表面の少なくとも一部に形成された油性外用剤層と、油性外用剤層の表面を保護するように積層された被覆フィルムとを有するシート状外用剤であって、油性外用剤層を構成する油性外用剤が、（Ａ）シリコーン油を５〜６０質量％、及び（Ｂ）粉末成分を３〜４５質量％含み、かつ、油性外用剤の硬度が３５〜１７０ｇｆである。Provided is a sheet-like external preparation that does not easily adhere to the coating film even if a gap is not provided between the coating film and the oil-based external preparation layer, and is also excellent in picking up the oil-based external preparation. The sheet-like external preparation of the present invention includes a base sheet, an oil-based external preparation layer formed on at least a part of the surface of the base sheet, and a coating film laminated so as to protect the surface of the oil-based external preparation layer. The oil-based external preparation which constitutes the oil-based external preparation layer contains 5 to 60% by mass of (A) silicone oil and 3 to 45% by mass of (B) powder component, and is a sheet-like external preparation. The hardness of the oil-based external preparation is 35 to 170 gf.
Description
本発明は、油性外用剤を基材シートに塗着させて被覆フィルムで保護したシート状外用剤に関する。本発明のシート状外用剤は、皮膚の角質層、毛髪、爪などの、ケラチンを主成分とする様々な部位に適用可能な油性外用剤を収容するのに適しており、油性外用剤が被覆フィルム側に付着しにくく、油性外用剤の指取れにも優れている。 The present invention relates to a sheet-like external preparation in which an oil-based external preparation is applied to a base sheet and protected by a coating film. The sheet-like external preparation of the present invention is suitable for accommodating an oil-based external preparation applicable to various parts containing keratin as a main component, such as the stratum corneum, hair, and nails of the skin, and is coated with the oil-based external preparation. It does not easily adhere to the film side and is excellent for removing oil-based external preparations.
近年、ファッション誌やインターネットなどを通じて化粧や美容に対する意識が１０代を中心に低年齢層にまで普及しており、子供でも気軽に購入できる低価格帯の化粧品に対する需要が高まっている。なかでも、一回で使い切るような小型で薄型のものは、バリエーション豊富に揃えても嵩張らず、携帯性に優れるため、友達同士で交換したりプレゼントしあったりする新たなコミュニケーションツールとしての可能性も秘めている。また、各種発表会やイベントなどでは普段とは異なる大胆なメイクにチャレンジする機会も増えており、イメージ通りのメイクを完成するには様々な色彩の化粧料を幅広く揃えることが求められる。このため、カラーバリエーションに富み、使い切りタイプで安価に入手できるメーキャップ化粧料は、低年齢層のみならず大人にとっても魅力的である。 In recent years, awareness of makeup and beauty has spread to younger age groups, mainly teenagers, through fashion magazines and the Internet, and demand for low-priced cosmetics that even children can easily purchase is increasing. Among them, the small and thin ones that can be used up at one time are not bulky even if they are available in a wide variety, and they are excellent in portability, so they have the potential as a new communication tool for exchanging and presenting with friends. Is also hidden. In addition, at various presentations and events, there are increasing opportunities to challenge bold makeup that is different from usual, and it is necessary to prepare a wide range of cosmetics of various colors in order to complete makeup as imagined. For this reason, makeup cosmetics, which are rich in color variations and can be obtained at low cost as a single-use type, are attractive not only to younger age groups but also to adults.
また、メーキャップ用途以外の外用剤、例えば皮膚、毛髪、爪のケア、クレンジング、虫除けなどの用途を有する外用剤についても、小型かつ薄型であれば、嵩張らず、携帯性に優れるため、外出時や旅行時などに特に便利である。さらに、一回で使い切るタイプのものは、開封後直ちに使用してしまうため衛生面にも優れている。
このように、ユーザー層や用途を問わず、様々な外用剤を小型かつ薄型の形態で安価に提供することが求められている。In addition, external preparations other than those used for makeup, such as those for skin, hair, nail care, cleansing, and insect repellent, are not bulky and have excellent portability if they are small and thin, so they can be used when going out. It is especially convenient when traveling. Furthermore, the type that is used up once is also excellent in hygiene because it is used immediately after opening.
As described above, it is required to provide various external preparations in a compact and thin form at low cost regardless of the user group and application.
このような外用剤として、シート状の基材に外用剤を塗着させてフィルムで被覆した、いわゆる「シート状外用剤」が多数提案されている。
例えば特許文献１には、基材シートの表面の一部に化粧料（外用剤）層を設けた化粧料シートと、化粧料層表面が露出するように開口部が設けられた保護シートと、透明フィルム層とが積層された化粧料試供品の製造方法が記載されている。特許文献１によれば、薄手でコンパクトなファンデーション、アイシャドー等の化粧料試供品を低コストで提供できるとされている。As such an external preparation, many so-called "sheet-shaped external preparations" in which a sheet-shaped base material is coated with the external preparation and coated with a film have been proposed.
For example, Patent Document 1 describes a cosmetic sheet in which a cosmetic (external agent) layer is provided on a part of the surface of the base material sheet, and a protective sheet in which an opening is provided so that the surface of the cosmetic layer is exposed. A method for producing a cosmetic sample in which a transparent film layer is laminated is described. According to Patent Document 1, it is possible to provide a thin and compact foundation, eye shadow, and other cosmetic samples at low cost.
また、特許文献２には、シート状基材、化粧料、被覆シートから構成される積層体を複数重ねることにより、ファンデーション、アイシャドー、口紅等の複数の化粧料の組合せを同時に提供でき、しかも、各化粧料が協働して所定の文字・図形を表すことにより訴求性を高めたとされる化粧品が記載されている。 Further, in Patent Document 2, by stacking a plurality of laminates composed of a sheet-like base material, a cosmetic, and a coating sheet, a combination of a plurality of cosmetics such as foundation, eye shadow, and lipstick can be provided at the same time. , Cosmetics that are said to have enhanced appeal by collaborating with each other to represent predetermined characters and figures are described.
ところが、シート状外用剤に収容する外用剤として、油剤成分を多く含む油性外用剤を用いると、外用剤を被覆していたフィルム（又はシート）側に外用剤が付着してしまい、実際に使用できる外用剤の量が減少したり、被覆フィルムに付着した外用剤が手指や周囲の物を汚してしまったりすることがある。また、保管の際に、外用剤に含まれる油分が経時的に分離して滲み出し、シート状外用剤の品質、外観、使用性が損なわれるという問題もある。そのため、油性外用剤は種々の適用部位に幅広く用いることができるという利点を有するものの、それをシート状の形態で提供するには多くの課題があった。 However, if an oil-based external preparation containing a large amount of oil component is used as the external preparation to be contained in the sheet-shaped external preparation, the external preparation adheres to the film (or sheet) side covering the external preparation and is actually used. The amount of external preparation that can be produced may decrease, or the external preparation that adheres to the coating film may stain the fingers and surrounding objects. In addition, there is also a problem that the oil contained in the external preparation is separated and exuded with time during storage, and the quality, appearance, and usability of the sheet-like external preparation are impaired. Therefore, although the oil-based external preparation has an advantage that it can be widely used in various application sites, there are many problems in providing it in the form of a sheet.
そこで、このような問題を回避するために、上記特許文献２には、シート状基材と被覆フィルムとの間に保護枠シートを配置して、化粧料と被覆フィルムとが直接接触しないように隙間を設けることが提案されている。同様に、油性外用剤と被覆フィルムとの間に隙間を設ける構成は、特許文献３及び４等の多数の文献にも提案されている。さらに、特許文献１においても、保護シートにより化粧料層と透明フィルム層との直接接触を妨げている態様が図示されている。
しかし、シート状基材と被覆フィルムとの間に保護枠シートのようなスペーサー部材を配置する構成とすると、シート状外用剤全体の厚みが増し、嵩張って取り扱い性が損なわれるほか、部材が増え構造も複雑になるため製造コストが割高になるといった問題がある。Therefore, in order to avoid such a problem, in Patent Document 2, a protective frame sheet is arranged between the sheet-like base material and the coating film so that the cosmetic and the coating film do not come into direct contact with each other. It has been proposed to provide a gap. Similarly, a configuration in which a gap is provided between the oil-based external preparation and the coating film has been proposed in many documents such as Patent Documents 3 and 4. Further, Patent Document 1 also illustrates a mode in which a protective sheet prevents direct contact between the cosmetic layer and the transparent film layer.
However, if a spacer member such as a protective frame sheet is arranged between the sheet-like base material and the coating film, the thickness of the entire sheet-like external preparation is increased, which makes the member bulky and impairs handleability. There is a problem that the manufacturing cost becomes high because the structure increases and the structure becomes complicated.
一方、被覆フィルムに対する油性外用剤の付着を抑制する他の方策としては、収容する油性外用剤の粘度を高くして、油性外用剤層そのものを硬くしてしまうことも考えられる。しかし、油性外用剤層が硬くなると、それに応じて油性外用剤の指取れが悪くなり、皮膚等に適用する際の延びが損なわれることとなり、例えば油性外用剤がメーキャップ用途の場合には十分な発色が得られなくなるといった問題がある。 On the other hand, as another measure for suppressing the adhesion of the oil-based external preparation to the coating film, it is conceivable to increase the viscosity of the contained oil-based external preparation to harden the oil-based external preparation layer itself. However, when the oil-based external preparation layer becomes hard, the oil-based external preparation becomes difficult to remove from the fingers, and the spreadability when applied to the skin or the like is impaired. For example, when the oil-based external preparation is used for makeup, it is sufficient. There is a problem that color development cannot be obtained.
本発明は、マルチ使用に対応可能な油性外用剤を収容したシート状外用剤であって、被覆フィルムと油性外用剤層との間に隙間を設けなくても油性外用剤が被覆フィルムに付着しにくく、しかも、油性外用剤の指取れに優れたシート状外用剤を提供することを目的とする。 The present invention is a sheet-like external preparation containing an oil-based external preparation that can be used in multiple ways, and the oil-based external preparation adheres to the coating film without providing a gap between the coating film and the oil-based external preparation layer. It is an object of the present invention to provide a sheet-like external preparation that is difficult to remove and has excellent finger removal of the oil-based external preparation.
本発明者は、前記の課題を解決すべく鋭意研究を重ねた結果、シート状外用剤に収容する油性外用剤を特定の組成とすることにより、被覆フィルムに付着しにくいにも拘わらず、指取れにも優れたシート状外用剤が得られることを見出し、本発明を完成するに至った。 As a result of intensive research to solve the above-mentioned problems, the present inventor has made the oil-based external preparation contained in the sheet-like external preparation a specific composition, and although it is difficult to adhere to the coating film, the finger We have found that a sheet-like external preparation that is also excellent in removal can be obtained, and have completed the present invention.
すなわち、本発明は、
基材シートと、
基材シートの表面の少なくとも一部に形成された油性外用剤層と、
油性外用剤層の表面を保護するように積層された被覆フィルムと
を有するシート状化粧料であって、
油性外用剤層を構成する油性外用剤が、
（Ａ）シリコーン油を５〜６０質量％、及び
（Ｂ）粉末成分を３〜４５質量％、
含み、かつ、油性外用剤の硬度が３５〜１７０ｇｆである、シート状外用剤を提供するものである。That is, the present invention
Base sheet and
An oil-based external preparation layer formed on at least a part of the surface of the base sheet,
A sheet-like cosmetic having a coating film laminated so as to protect the surface of the oil-based external preparation layer.
The oil-based external preparation that constitutes the oil-based external preparation layer is
(A) Silicone oil 5 to 60% by mass, (B) Powder component 3 to 45% by mass,
Provided is a sheet-like external preparation containing 35 to 170 gf and having a hardness of an oil-based external preparation.
本発明に係るシート状外用剤は、油性外用剤の組成及び硬度を限定したことにより、被覆フィルムに対する油性外用剤の付着を抑制できる一方で、油性外用剤の指取れにも優れている。また、油性外用剤自体が被覆フィルムに付着しにくい特性を有するため、付着を避けるために油性外用剤層と被覆フィルムとの間に隙間を設ける必要がない。このため、油性外用剤層と被覆フィルムとが直接接触した単純かつ薄い構造とすることができる。 The sheet-shaped external preparation according to the present invention can suppress the adhesion of the oil-based external preparation to the coating film by limiting the composition and hardness of the oil-based external preparation, and is also excellent in picking up the oil-based external preparation. Further, since the oil-based external preparation itself has a property of being difficult to adhere to the coating film, it is not necessary to provide a gap between the oil-based external preparation layer and the coating film in order to avoid adhesion. Therefore, a simple and thin structure can be obtained in which the oil-based external preparation layer and the coating film are in direct contact with each other.
本発明に係るシート状外用剤は、上記のように単純かつ薄い構造を有するため、比較的安価で製造・提供できる。このため、複数枚を重ねて収容しても、嵩張らず、持ち運びに優れ、幅広い需要者層が気軽に購入・使用できる。また、広告宣伝のための試供品として雑誌やチラシに添付するにも適している。
さらに、本発明に係るシート状外用剤は指取れが良いため、油性外用剤が色材を含む場合には肌等に適用した際の発色が優れている。また、油性外用剤が香料を含む場合には、香りの持続性にも優れた効果を示す。Since the sheet-shaped external preparation according to the present invention has a simple and thin structure as described above, it can be manufactured and provided at a relatively low cost. For this reason, even if a plurality of sheets are stacked and stored, they are not bulky, are excellent in portability, and can be easily purchased and used by a wide range of consumers. It is also suitable for attaching to magazines and leaflets as a free sample for advertising.
Further, since the sheet-shaped external preparation according to the present invention has good finger removal, when the oil-based external preparation contains a coloring material, the color development when applied to the skin or the like is excellent. In addition, when the oil-based external preparation contains a fragrance, it also has an excellent effect on the durability of the scent.
本発明のシート状外用剤は、基材シートと、基材シートの表面の少なくとも一部に形成された油性外用剤層と、油性外用剤層の表面を保護するように積層された被覆フィルムとを有する。以下、本発明について詳述する。 The sheet-like external preparation of the present invention includes a base sheet, an oil-based external preparation layer formed on at least a part of the surface of the base sheet, and a coating film laminated so as to protect the surface of the oil-based external preparation layer. Has. Hereinafter, the present invention will be described in detail.
＜基材シート＞
基材シートは、その表面の一部又は全面に油性外用剤を塗着することにより、油性外用剤層を形成するための台紙である。
本発明において使用される基材シートの材質は特に限定されるものではなく、紙、樹脂製シート、金属製シート等を使用することができるが、油性外用剤に含まれる油剤の浸透を回避するために、油性外用剤層を形成する面がＰＥＴ（ポリエチレンテレフタレート）樹脂等のポリエステルからなることが好ましい。例えば、紙基材を用いる場合には、少なくともその油性外用剤層を形成する面がＰＥＴ樹脂フィルム等でコーティング又はラミネートされていることが好ましい。<Base sheet>
The base material sheet is a mount for forming an oil-based external preparation layer by applying an oil-based external preparation on a part or the entire surface thereof.
The material of the base sheet used in the present invention is not particularly limited, and paper, a resin sheet, a metal sheet, or the like can be used, but the penetration of the oil agent contained in the oil-based external preparation is avoided. Therefore, it is preferable that the surface forming the oil-based external preparation layer is made of polyester such as PET (polyethylene terephthalate) resin. For example, when a paper base material is used, it is preferable that at least the surface forming the oil-based external preparation layer is coated or laminated with a PET resin film or the like.
基材シートの外形や寸法は特に限定されるものではない。例えば、縦横の一辺が２〜５ｃｍ、厚さ１００μｍ〜５００μｍの四辺形等であれば、嵩張らず、携帯性にも優れたシート状外用剤を提供できるので好ましい。
基材シートは、油性外用剤層の滑りや脱落を避けるために、油性外用剤層が形成される面が粗面化処理されていてもよい。The outer shape and dimensions of the base sheet are not particularly limited. For example, a quadrilateral having a length and width of 2 to 5 cm and a thickness of 100 μm to 500 μm is preferable because it can provide a sheet-like external preparation that is not bulky and has excellent portability.
In the base sheet, the surface on which the oil-based external preparation layer is formed may be roughened in order to prevent the oil-based external preparation layer from slipping or falling off.
＜油性外用剤層＞
油性外用剤層は、基材シートの表面の一部又は全面に油性外用剤を塗着させ、乾燥させることによって形成された、油性外用剤からなる固形の薄膜である。
油性外用剤の塗着には、公知の塗着方法を用いることができる。特に好ましくは、スクリーン印刷である。
油性外用剤層の厚みは、１０〜２００μｍであることが好ましく、４０〜１４０μｍであることがさらに好ましい。油性外用剤層の厚みがこの範囲であれば、被覆フィルムに対する油性外用剤の付着を抑えつつ、指取れのよい十分な量を供給できる。<Oil-based external preparation layer>
The oil-based external preparation layer is a solid thin film made of an oil-based external preparation, which is formed by applying the oil-based external preparation to a part or the entire surface of the base sheet and drying it.
A known coating method can be used for coating the oil-based external preparation. Screen printing is particularly preferable.
The thickness of the oil-based external preparation layer is preferably 10 to 200 μm, more preferably 40 to 140 μm. When the thickness of the oil-based external preparation layer is within this range, it is possible to supply a sufficient amount with good finger removal while suppressing adhesion of the oil-based external preparation to the coating film.
＜油性外用剤＞
油性外用剤層を構成する油性外用剤は、（Ａ）シリコーン油と（Ｂ）粉末成分を必須に含有し、なおかつ、２５℃における硬度が特定の数値範囲を有する。本発明において油性外用剤とは、油剤成分を多く含む組成物であって、皮膚の角質層、毛髪、爪などの、ケラチンを主成分とする様々な部位に適用可能なものである。その用途は特に限定されるものではなく、メーキャップ、クレンジング等の化粧品や、虫除けやニキビケア等の様々な有効成分を配合した医薬品、医薬部外品、薬用化粧品などを含む。また、使用態様も特に限定されず、適用部位に単に塗布するものから、塗布後に洗い落とす、拭き取るものなど、あらゆる態様を含む。<Oil-based external preparation>
The oil-based external preparation that constitutes the oil-based external preparation layer essentially contains (A) silicone oil and (B) powder component, and has a hardness at 25 ° C. having a specific numerical range. In the present invention, the oil-based external preparation is a composition containing a large amount of an oil preparation component, and is applicable to various parts containing keratin as a main component, such as the stratum corneum of the skin, hair, and nails. Its use is not particularly limited, and includes cosmetics such as make-up and cleansing, pharmaceuticals containing various active ingredients such as insect repellent and acne care, quasi-drugs, and medicated cosmetics. Further, the mode of use is not particularly limited, and includes all modes such as those simply applied to the application site, those that are washed off after application, and those that are wiped off.
（Ａ）シリコーン油
本発明に用いられる（Ａ）シリコーン油は、化粧料に通常使用されるシリコーン油であって、１種又は２種以上を任意に選択して用いることができる。
好ましいシリコーン油としては、ジメチコン、トリメチルペンタフェニルトリシロキサン、ジフェニルシロキシフェニルトリメチコン、ジフェニルジメチコン、（パーフルオロオクチルエチル／ジフェニルジメチコン）コポリマー、シクロペンタシロキサン等が挙げられる。
シリコーン油の市販品としては、例えば、ジメチコンであるＫＦ−９６Ａ−６ｃｓ、ＫＦ−９６−１００ｃｓ、ＫＦ−９６−３００ｃｓ、ＫＦ−９６−１０００ｃｓ、ＫＦ−９６−５０００ｃｓ（以上、信越化学工業社）、トリメチルペンタフェニルトリシロキサンであるメチルフェニルシリコーンＰＨ−１５５５（東レ・ダウコーニング社）、ジフェニルシロキシフェニルトリメチコンであるシリコーンＫＦ５６（信越化学工業社）、ジフェニルジメチコンであるシリコーンＫＦ５４、シリコーンＫＦ−５４ＨＶ（以上、信越化学工業社）、（パーフルオロオクチルエチル／ジフェニルジメチコン）コポリマーであるＦＭＰＳ（モメンティブ・パフォーマンス・マテリアルズ・ジャパン合同会社）、シクロペンタシロキサンであるエキセコールＤ−５（信越化学工業社）を挙げることができる。(A) Silicone oil The (A) silicone oil used in the present invention is a silicone oil usually used for cosmetics, and one type or two or more types can be arbitrarily selected and used.
Preferred silicone oils include dimethicone, trimethylpentaphenyltrisiloxane, diphenylsiloxyphenyltrimethicone, diphenyldimethicone, (perfluorooctylethyl / diphenyldimethicone) copolymers, cyclopentasiloxane and the like.
Examples of commercially available silicone oil products include dimethicone KF-96A-6cs, KF-96-100cs, KF-96-300cs, KF-96-1000cs, and KF-96-5000cs (Shin-Etsu Chemical Co., Ltd.). , Trimethylpentaphenyltrisiloxane PH-1555 (Toray Dowcorning), Diphenylsiloxyphenyltrimethicone Silicone KF56 (Shin-Etsu Chemical Co., Ltd.), Diphenyldimethicone Silicone KF54, Silicone KF-54HV ( (Shin-Etsu Chemical Co., Ltd.), FMPS (Momentive Performance Materials Japan LLC), which is a (perfluorooctylethyl / diphenyldimethicone) copolymer, and Execol D-5 (Shin-Etsu Chemical Co., Ltd.), which is a cyclopentasiloxane. Can be mentioned.
（Ａ）シリコーン油の配合量は、油性外用剤全体に対して、５〜６０質量％であり、より好ましくは１０〜６０質量％、さらに好ましくは１０〜３０質量％である。５質量％未満では、被覆フィルムへの油性外用剤の付着を抑制できなくなったり、十分な指取れや発色が得られなくなる傾向がある。一方、６０質量％を超えて配合すると、保管時に滲みを生じる場合がある。 The blending amount of the silicone oil (A) is 5 to 60% by mass, more preferably 10 to 60% by mass, and further preferably 10 to 30% by mass with respect to the entire oil-based external preparation. If it is less than 5% by mass, the adhesion of the oil-based external preparation to the coating film cannot be suppressed, and sufficient finger removal and color development tend to be impossible. On the other hand, if it is blended in an amount exceeding 60% by mass, bleeding may occur during storage.
（Ｂ）粉末成分
本発明に用いられる（Ｂ）粉末成分は、化粧品、医薬品、医薬部外品に使用可能なものであれば特に制限されない。そのような粉末成分としては、例えば、二酸化チタン、酸化亜鉛、酸化鉄、酸化クロム等の無機顔料；酸化チタン被覆マイカ、酸化チタン被覆ホウケイ酸ガラス等のパール剤；球状シリカ、球状ポリエチレン、ポリアミド球状樹脂粉末（ナイロン球状粉末）、架橋型ポリ（メタ）クリル酸メチル球状樹脂粉末等の球状粉末；タルク、マイカ、カオリン、セリサイト、炭酸カルシウム、炭酸マグネシウム等の体質顔料；ジメチコンクロスポリマー、（ジメチコン／ビニルジメチコン）クロスポリマー、ポリメチルシルセスキオキサン等の高分子シリコーン系粉末などが挙げられる。(B) Powder component The (B) powder component used in the present invention is not particularly limited as long as it can be used in cosmetics, pharmaceuticals, and quasi-drugs. Examples of such powder components include inorganic pigments such as titanium dioxide, zinc oxide, iron oxide, and chromium oxide; pearlizing agents such as titanium oxide-coated mica and titanium oxide-coated borosilicate glass; spherical silica, spherical polyethylene, and polyamide spheres. Spherical powders such as resin powder (nylon spherical powder), crosslinked poly (meth) methyl crylate spherical resin powder; extender pigments such as talc, mica, kaolin, cericite, calcium carbonate, magnesium carbonate; dimethicone crosspolymer, (dimethicone) / Vinyl dimethicone) Cross-polymer, high molecular weight silicone powder such as polymethylsilsesquioxane, etc. can be mentioned.
（Ｂ）粉末成分の配合量は、油性外用剤全体に対して、３〜４５質量％であり、より好ましくは４〜４０質量％である。３質量％未満では、被覆フィルムへの油性外用剤の付着を抑えるのが難しくなる傾向がある。また、驚くべきことに、油性外用剤が香料を含む場合に（Ｂ）粉末成分を３質量％以上配合すると、香りがより長時間にわたって持続するという予想外の効果が確認されている。一方、（Ｂ）粉末成分を４５質量％を超えて配合すると、粉末が多すぎて油性外用剤の利点であるマルチ使用に対応できなくなり、特にリップに適用した場合などに使用感触が著しく損なわれる。 The blending amount of the powder component (B) is 3 to 45% by mass, more preferably 4 to 40% by mass, based on the total amount of the oil-based external preparation. If it is less than 3% by mass, it tends to be difficult to suppress the adhesion of the oil-based external preparation to the coating film. Surprisingly, when the oil-based external preparation contains a fragrance, it has been confirmed that when the powder component (B) is blended in an amount of 3% by mass or more, the fragrance lasts for a longer period of time, which is an unexpected effect. On the other hand, if the powder component (B) is blended in an amount of more than 45% by mass, the amount of powder is too large to support multi-use, which is an advantage of oil-based external preparations, and the feeling of use is significantly impaired especially when applied to lips. ..
硬度
油性外用剤の２５℃における硬度は、３５〜１７０ｇｆ（０．３４〜１．６７Ｎ）であり、より好ましくは４０〜１５０ｇｆである。油性外用剤の硬度が３５ｇｆ未満であると、被覆フィルムへの油性外用剤の付着や滲みを抑えるのが難しくなる傾向がある。一方、油性外用剤の硬度が１７０ｇｆを超えると、硬度が高すぎて指取れが悪くなり、滑らかに塗布できず、皮膚等へのつきも悪くなって十分な発色が得られない傾向がある。
なお、本発明における硬度とは、油性外用剤を加熱溶解し、１０ｍｌの軟膏壺に充填して固化した後に、２５℃においてレオテック社製レオメーター（感圧軸１φ、針入速度２ｃｍ／ｍｉｎ、針入度１０ｍｍ）で測定した値である。Hardness The hardness of the oil-based external preparation at 25 ° C. is 35 to 170 gf (0.34 to 1.67 N), more preferably 40 to 150 gf. If the hardness of the oil-based external preparation is less than 35 gf, it tends to be difficult to suppress the adhesion and bleeding of the oil-based external preparation to the coating film. On the other hand, when the hardness of the oil-based external preparation exceeds 170 gf, the hardness is too high and the finger removal becomes difficult, the application cannot be performed smoothly, and the adhesion to the skin or the like is also deteriorated, so that sufficient color development tends not to be obtained.
The hardness in the present invention is defined as a rheometer manufactured by Leotech Co., Ltd. (pressure sensitive shaft 1φ, needle insertion speed 2 cm / min,) at 25 ° C. after the oil-based external preparation is heated and dissolved, filled in a 10 ml ointment jar and solidified. It is a value measured with a needle insertion degree of 10 mm).
油性外用剤には、固形又は半固形の外用剤に通常配合される他の成分を、本発明の効果を阻害しない範囲で任意に配合できる。このような成分としては、例えば、上記（Ａ）シリコーン油以外の油分、色材、増粘剤、セラミド類、ビタミン類、紫外線吸収剤、キレート剤、殺菌剤、防腐剤、アミノ酸、各種薬剤、香料、エタノール等の低級アルコール類などを挙げることができる。 In the oil-based external preparation, other components usually blended in the solid or semi-solid external preparation can be arbitrarily blended as long as the effects of the present invention are not impaired. Examples of such components include oils other than the above-mentioned (A) silicone oil, coloring materials, thickeners, ceramides, vitamins, ultraviolet absorbers, chelating agents, bactericides, preservatives, amino acids, various agents, and the like. Examples thereof include fragrances and lower alcohols such as ethanol.
例えば、（Ａ）シリコーン油以外の油分として、油性外用剤の硬度調節のために固形油分を配合することが好ましい。固形油分としては、通常化粧料に用いられる油分のうち、常温で固体〜半固体状を呈する油分であって、融点が５０℃程度以上のもの、さらに好ましくは融点が５０〜９０℃のものを用いることができる。例えばモクロウ、硬化ヒマシ油等の固体油脂；カルナウバロウ、ミツロウ、キャンデリラロウ、ホホバロウ等のロウ類：ポリエチレンワックス、パラフィンワックス、セレシン、マイクロクリスタリンワックス等の炭化水素系ワックス類；ベヘニルアルコール、セタノール、バチルアルコール等の高級アルコール；シリコンワックス等が挙げられる。特に、被覆フィルムへの付着防止や滲み防止に優れることから、マイクロクリスタリンワックス、ポリエチレンワックス等の炭化水素系ワックス類が好ましい。 For example, as an oil component other than (A) silicone oil, it is preferable to add a solid oil component in order to adjust the hardness of the oil-based external preparation. As the solid oil, among the oils usually used for cosmetics, those which are solid to semi-solid at room temperature and have a melting point of about 50 ° C. or higher, more preferably 50 to 90 ° C. Can be used. For example, solid fats and oils such as mokuro and hardened castor oil; waxes such as carnauba wax, honey wax, candelilla wax and jojoba wax: hydrocarbon waxes such as polyethylene wax, paraffin wax, ceresin and microcrystalin wax; behenyl alcohol, cetanol and bacil alcohol. Higher alcohols such as, silicon wax and the like. In particular, hydrocarbon waxes such as microcrystalline wax and polyethylene wax are preferable because they are excellent in preventing adhesion to the coating film and preventing bleeding.
固形油分を配合する場合、その配合量は、油性外用剤全体に対して、３０質量％以下、より好ましくは５〜３０質量％であり、さらに好ましくは５〜２０質量％である。３０質量％を超えて配合すると油性外用剤が硬くなりすぎて指取れが悪くなり、皮膚や唇に適用する際に十分な発色が得られない傾向がある。 When the solid oil content is blended, the blending amount thereof is 30% by mass or less, more preferably 5 to 30% by mass, and further preferably 5 to 20% by mass with respect to the entire oil-based external preparation. If it is blended in an amount of more than 30% by mass, the oil-based external preparation becomes too hard and the finger removal becomes difficult, and there is a tendency that sufficient color development cannot be obtained when applied to the skin or lips.
固形油分以外の油分としては、オリーブ油、アボカド油、ツバキ油、マカデミアナッツ油、月見草油、ホホバ油、ナタネ油、卵黄油、ゴマ油、ヒマシ油、サフラワー油、綿実油、大豆油、茶実油、コメヌカ油、胚芽油等の液体油脂類；スクワラン、流動パラフィン等の炭化水素油；イソステアリン酸イソセチル、２−エチルヘキサン酸セチル、２−ヘプチルウンデシルパルミテート、アジピン酸ジイソブチル、セバシン酸２−ヘキシルデシル、イソプロピルミリステート、２−オクチルドデシルオレエート、リンゴ酸ジイソステアリル、ジ−２−エチルヘキサン酸エチレングリコール、トリ−２−ヘプチルウンデカン酸グリセライド、トリ−２−エチルヘキサン酸グリセリル、グリセリルジイソステアレート、グリセリルトリイソステアレート、ジイソステアリン酸グリセリル、トリオクタン酸グリセリン、トリイソパルミチン酸グリセリン、トリ−２−エチルヘキサン酸トリメチロールプロパン、テトラ−２−エチルヘキサン酸ペンタエリスリトール等のエステル油類；ジメチルポリシロキサン、メチルフェニルポリシロキサン（ジフェニルシロキシフェニルトリメチコン）等の鎖状シリコーン油；オクタメチルシクロテトラシロキサン、デカメチルシクロペンタシロキサン等の環状シリコーン油；トリグリセリン、フッ素変性油等が挙げられる。 Oils other than solid oil include olive oil, avocado oil, camellia oil, macadamia nut oil, evening primrose oil, jojoba oil, rapeseed oil, egg yolk oil, sesame oil, sunflower oil, cherry oil, cottonseed oil, soybean oil, teaseed oil, and rice bran. Liquid oils and fats such as oils and germ oils; hydrocarbon oils such as squalane and liquid paraffin; isocetyl isostearate, cetyl 2-ethylhexanate, 2-heptylundecyl palmitate, diisobutyl adipate, 2-hexyldecyl sebacate, Isopropyl myristate, 2-octyldodecyloleate, diisostearyl malate, ethylene glycol di-2-ethylhexanoate, glyceride tri-2-heptylundecanoate, glyceryl tri-2-ethylhexanoate, glyceryl diisostearate , Glyceryl triisostearate, glyceryl diisostearate, glycerin trioctanoate, glycerin triisopalmitate, trimethylpropane tri-2-ethylhexanoate, pentaerythritol tetra-2-ethylhexanoate and other ester oils; dimethylpolysiloxane , Methylphenylpolysiloxane (diphenylsiloxyphenyltrimethicone) and other chain silicone oils; octamethylcyclotetrasiloxane, decamethylcyclopentasiloxane and other cyclic silicone oils; triglycerin, fluorine-modified oil and the like.
また、色材としては、上記（Ｂ）粉末成分に該当しない色材であって、有機化合物を主体とする顔料が好ましい。例えば、ジルコニウム、バリウム又はアルミニウムレーキ等の有機顔料（例えば、赤色２０１号、赤色２０２号、赤色２０４号、赤色２０５号、赤色２２０号、赤色２２６号、赤色２２８号、赤色４０５号、橙色２０３号、橙色２０４号、黄色２０５号、黄色４０１号、及び青色４０４号などの有機顔料、赤色３号、赤色１０４号、赤色１０６号、赤色２２７号、赤色２３０号、赤色４０１号、赤色５０５号、橙色２０５号、黄色４号、黄色５号、黄色２０２号、黄色２０３号、緑色３号及び青色１号等）；天然色素（例えば、クロロフィル、β−カロチン等）等が挙げられる。 Further, as the coloring material, a pigment that does not correspond to the powder component (B) and is mainly composed of an organic compound is preferable. For example, organic pigments such as zirconium, barium or aluminum lake (eg, red 201, red 202, red 204, red 205, red 220, red 226, red 228, red 405, orange 203). , Orange No. 204, Yellow No. 205, Yellow No. 401, and Blue No. 404, Red No. 3, Red No. 104, Red No. 106, Red No. 227, Red No. 230, Red No. 401, Red No. 505, Orange No. 205, Yellow No. 4, Yellow No. 5, Yellow No. 202, Yellow No. 203, Green No. 3 and Blue No. 1 etc.); Natural pigments (for example, chlorophyll, β-carotene, etc.) and the like can be mentioned.
薬剤としては、例えば、ビタミンＡ油、レチノール、パルミチン酸レチノール、塩酸ピリドキシン、ニコチン酸ベンジル、ニコチン酸アミド、ニコチン酸ｄｌ−α−トコフェロール、アスコルビン酸リン酸マグネシウム、ビタミンＤ２、ｄｌ−α−トコフェロール、パントテン酸、ビオチン等のビタミン類；アズレン、グリチルリチン等の抗炎症剤；アルブチン、４−メトキシサリチル酸、トラネキサム酸、エチルビタミンＣ、アスコルビン酸リン酸マグネシウム等の美白剤、エストラジオール等のホルモン類；酸化亜鉛、タンニン酸等の収斂剤；Ｌ−メントール、カンフル等の清涼剤；その他塩化リゾチーム、塩酸ピリドキシン、イオウ等を配合することができる。さらに多様な薬効を示す各種抽出物を配合することができる。すなわちドクダミエキス、オウバクエキス、カンゾウエキス、シャクヤクエキス、ボタンピエキス、ヘチマエキス、ユキノシタエキス、ユーカリエキス、チョウジエキス、マロニエエキス、ヤグルマギクエキス、海藻エキス、タイムエキス等を挙げることができる。 Examples of the drug include vitamin A oil, retinol, retinol palmitate, pyridoxin hydrochloride, benzyl nicotinate, nicotinamide, dl-α-tocopherol nicotinate, magnesium ascorbate phosphate, vitamin D2, dl-α-tocopherol, etc. Vitamins such as pantothenic acid and biotin; Anti-inflammatory agents such as azulene and glycyrrhizin; Whitening agents such as arbutin, 4-methoxysalicylic acid, tranexamic acid, ethyl vitamin C, magnesium ascorbate, hormones such as estradiol; Zinc oxide , Astringents such as tannic acid; refreshing agents such as L-menthol and camphor; other lysozyme chloride, pyridoxin hydrochloride, sulfur and the like can be blended. Furthermore, various extracts showing various medicinal effects can be blended. That is, Dokudami extract, Oubaku extract, Kanzo extract, Shakuyaku extract, Buttonpi extract, Hechima extract, Yukinoshita extract, Eucalyptus extract, Chouji extract, Maronie extract, Yagurumagiku extract, Seaweed extract, Thyme extract and the like can be mentioned.
なお本発明においては、油性外用剤に、オルガノゲル化剤として知られるデキストリン脂肪酸エステルを配合すべきでない。デキストリン脂肪酸エステルを配合すると、適度な硬度の油性外用剤層を形成することができなくなり、被覆フィルムへの付着を十分に抑えられなくなる傾向がある。デキストリン脂肪酸エステルとしては、例えばレオパールシリーズ（千葉製粉（株））などが挙げられる。 In the present invention, the oil-based external preparation should not be mixed with a dextrin fatty acid ester known as an organogelling agent. When the dextrin fatty acid ester is blended, it becomes impossible to form an oil-based external preparation layer having an appropriate hardness, and there is a tendency that adhesion to the coating film cannot be sufficiently suppressed. Examples of the dextrin fatty acid ester include the Leopard series (Chiba Flour Milling Co., Ltd.).
＜被覆フィルム＞
被覆フィルムは、基材シート上に形成された油性外用剤層を保護するために積層されるフィルムである。
本発明において使用される被覆フィルムの材質は特に限定されるものではなく、ポリエステルフィルム、ポリエチレンフィルム、ポリプロピレンフィルム、ポリカーボネートフィルムを用いることができる。なかでも、油性外用剤中の油分の浸透回避に優れることから、ポリエステルフィルムが好ましく、特にＰＥＴ樹脂フィルムが好ましい。
被覆フィルムの外形や寸法は、基材シート上に形成された油性外用剤層を完全に覆うことができれば特に限定されず、例えば、基材シートと同じ形状及び寸法とすることができる。<Coating film>
The coating film is a film laminated to protect the oil-based external preparation layer formed on the base sheet.
The material of the coating film used in the present invention is not particularly limited, and a polyester film, a polyethylene film, a polypropylene film, and a polycarbonate film can be used. Among them, a polyester film is preferable, and a PET resin film is particularly preferable, because it is excellent in avoiding permeation of oil in an oil-based external preparation.
The outer shape and dimensions of the coating film are not particularly limited as long as they can completely cover the oil-based external preparation layer formed on the base sheet, and can be, for example, the same shape and dimensions as the base sheet.
＜シート状外用剤の製法＞
各原料を溶解混合して油性外用剤を調製し、得られた油性外用剤をスクリーン印刷等の公知の方法に従って基材シート上の一部又は全面に塗着し、乾燥させて、油性外用剤層を形成する。
次いで、基材シート上の油性外用剤層を覆うように被覆フィルムを積層する。ここで、被覆フィルムのズレや脱落を防止するために、被覆フィルムと基材シートとを、油性外用剤層よりも外側の周縁部において感圧接着剤等により剥離自在に接着してもよい。<Manufacturing method of sheet-like external preparation>
Each raw material is dissolved and mixed to prepare an oil-based external preparation, and the obtained oil-based external preparation is applied to a part or the entire surface of a base sheet according to a known method such as screen printing, dried, and the oil-based external preparation is dried. Form a layer.
Next, the coating film is laminated so as to cover the oil-based external preparation layer on the base sheet. Here, in order to prevent the coating film from slipping or falling off, the coating film and the base material sheet may be detachably bonded to each other at the peripheral edge portion outside the oil-based external preparation layer with a pressure-sensitive adhesive or the like.
以下に具体例を挙げて本発明を更に詳細に説明するが、本発明は以下の実施例に限定されるものではない。また、以下の実施例等における配合量は特に断らない限り質量％を示す。 The present invention will be described in more detail with reference to specific examples below, but the present invention is not limited to the following examples. In addition, the blending amount in the following examples and the like shows mass% unless otherwise specified.
（実施例１〜１３及び比較例１〜１４）
厚み１３５〜３５０μｍのＰＥＴ樹脂フィルムからなる基材シート上に、下記の表１に掲げた組成を有する油性外用剤（化粧料）を１つのシート状外用剤当たり８〜２０ｍｇとなるように略正方形状にスクリーン印刷により塗着した。これを室温で乾燥させて、厚さ４０〜１３５μｍの油性外用剤層を形成した。次いで、油性外用剤層を覆うようにＰＥＴ樹脂製の被覆フィルムを被せ、裁断して縦２７ｍｍ×横２７ｍｍのシート状外用剤を作成した。
得られた各シート状外用剤について、以下の項目を評価した。(Examples 1 to 13 and Comparative Examples 1 to 14)
On a base sheet made of a PET resin film having a thickness of 135 to 350 μm, an oil-based external preparation (cosmetics) having the composition shown in Table 1 below is substantially square so as to be 8 to 20 mg per sheet-like external preparation. It was coated by screen printing. This was dried at room temperature to form an oil-based external preparation layer having a thickness of 40 to 135 μm. Next, a coating film made of PET resin was covered so as to cover the oil-based external preparation layer, and the film was cut to prepare a sheet-shaped external preparation having a length of 27 mm and a width of 27 mm.
The following items were evaluated for each of the obtained sheet-like external preparations.
＜油性外用剤の硬度＞
各シート状外用剤の作成に使用した油性外用剤の硬度を調べるために、油性外用剤を加熱溶解して１０ｍｌの軟膏壺にそれぞれ充填し、２５℃でそのまま１日間静置して固化させた後に、２５℃における硬度をレオテック社製レオメーター（感圧軸１φ、針入速度２ｃｍ／ｍｉｎ、針入度１０ｍｍ）で測定した。<Hardness of oil-based external preparation>
In order to examine the hardness of the oil-based external preparation used to prepare each sheet-shaped external preparation, the oil-based external preparation was heated and dissolved, filled in 10 ml ointment jars, and allowed to stand at 25 ° C. for 1 day to solidify. Later, the hardness at 25 ° C. was measured with a rheometer manufactured by Leotech (pressure sensitive shaft 1φ, needle insertion speed 2 cm / min, needle insertion degree 10 mm).
＜被覆フィルムに対する油性外用剤の付着率＞
各シート状外用剤を縦置きに配置して、２５℃で７日間保管した。次いで、シート状外用剤の一辺に指を当てて被覆フィルムを捲り、被覆フィルムを基材シートから完全に剥がした。被覆フィルムに付着した油性外用剤の量（付着率）について、以下の基準に従って評価した。各油性外用剤について６枚のシート状外用剤を評価し、６枚中最も評価の悪いものを評価結果とした。評価Ａ〜Ｂを合格と判断した。<Adhesion rate of oil-based external preparation to coating film>
Each sheet-like external preparation was placed vertically and stored at 25 ° C. for 7 days. Next, a finger was placed on one side of the sheet-like external preparation to roll the coating film, and the coating film was completely peeled off from the base sheet. The amount (adhesion rate) of the oil-based external preparation adhering to the coating film was evaluated according to the following criteria. Six sheet-shaped external preparations were evaluated for each oil-based external preparation, and the one with the worst evaluation among the six sheets was used as the evaluation result. Evaluations A to B were judged to be acceptable.
評価基準
Ａ：被覆フィルムに付着した油性外用剤の重さが油性外用剤全量の１０％未満
Ｂ：被覆フィルムに付着した油性外用剤の重さが油性外用剤全量の１０％以上３０％未満
Ｃ：被覆フィルムに付着した油性外用剤の重さが油性外用剤全量の３０％以上４５％未満
Ｄ：被覆フィルムに付着した油性外用剤の重さが油性外用剤全量の４５％以上７０％未満
Ｅ：被覆フィルムに付着した油性外用剤の重さが油性外用剤全量の７０％以上Evaluation Criteria A: The weight of the oil-based external preparation attached to the coating film is less than 10% of the total amount of the oil-based external preparation B: The weight of the oil-based external preparation attached to the coating film is 10% or more and less than 30% of the total amount of the oil-based external preparation C : The weight of the oil-based external preparation attached to the coating film is 30% or more and less than 45% of the total amount of the oil-based external preparation D: The weight of the oil-based external preparation attached to the coating film is 45% or more and less than 70% of the total amount of the oil-based external preparation E : The weight of the oil-based external preparation attached to the coating film is 70% or more of the total amount of the oil-based external preparation.
＜指取りのし易さ、発色の良さ＞
各シート状外用剤について、専門パネル１０名による実使用試験を行った。具体的には、専門パネルに、基材シートから油性外用剤を実際に指で取り、唇に適用してもらった。指取れ及び発色の良さについて、下記の基準に従って判定してもらった。評価Ａ〜Ｂを合格と判断した。
判定基準
Ａ：専門パネル９〜１０名が、指取れ及び発色が良いと認めた。
Ｂ：専門パネル７〜８名が、指取れ及び発色が良いと認めた。
Ｃ：専門パネル５〜６名が、指取れ及び発色が良いと認めた。
Ｄ：専門パネル３〜４名が、指取れ及び発色が良いと認めた。
Ｅ：専門パネル２名以下が、指取れ及び発色が良いと認めた。<Easy to pick up fingers, good color development>
For each sheet-like external preparation, an actual use test was conducted by 10 specialized panels. Specifically, we asked a specialized panel to actually take an oil-based external preparation from the base sheet with a finger and apply it to the lips. We asked them to judge the goodness of finger removal and color development according to the following criteria. Evaluations A to B were judged to be acceptable.
Judgment Criteria A: 9 to 10 specialized panels recognized that finger removal and color development were good.
B: 7 to 8 specialized panels admitted that finger removal and color development were good.
C: 5 to 6 specialist panels admitted that finger removal and color development were good.
D: Specialized panels 3-4 people admitted that finger removal and color development were good.
E: Two or less specialized panels admitted that finger removal and color development were good.
各実施例・比較例に使用した油性外用剤の組成、及び、評価結果を下記の表１及び表２に併せて示す。 The composition of the oil-based external preparation used in each Example / Comparative Example and the evaluation results are also shown in Tables 1 and 2 below.
＊２ 赤色２０１号（５０％）、赤色２０２号（２５％）、黄色５号（２５％）の混合物
* 2 A mixture of Red No. 201 (50%), Red No. 202 (25%), and Yellow No. 5 (25%).
表１に示されるとおり、シート状外用剤に収容する油性外用剤として、シリコーン油を５〜６０質量％、粉末成分を３〜４５質量％含有し、硬度が３５〜１７０ｇｆの範囲を満たす油性外用剤を用いた場合には、被覆フィルムに付着しにくいにも拘わらず、指取れや発色に優れたシート状外用剤が得られた（実施例１〜１３）。 As shown in Table 1, as an oil-based external preparation to be contained in a sheet-like external preparation, an oil-based external preparation containing 5 to 60% by mass of silicone oil and 3 to 45% by mass of a powder component and having a hardness in the range of 35 to 170 gf. When the agent was used, a sheet-like external preparation having excellent finger removal and color development was obtained even though it was difficult to adhere to the coating film (Examples 1 to 13).
一方、表２に示されるとおり、油性外用剤がシリコーン油を含有しない又はシリコーン油の配合量が５質量％に満たない場合には、被覆フィルムへの付着を抑えられないか、指取れ及び発色が不十分であった（比較例１〜９）。また、粉末成分の配合量が４５質量％を超える場合には（比較例１０）、油性外用剤が粉状であり、基材シートに塗着後に固まらないため、油性外用剤層を形成できなかった。さらに、油性外用剤の硬度が３５ｇｆ未満であると（比較例１１〜１３）、被覆フィルムへの付着率が高くなり、油性外用剤の硬度が１７０ｇｆを超えると（比較例１４）、指取れや発色が劣る傾向が認められた。 On the other hand, as shown in Table 2, when the oil-based external preparation does not contain silicone oil or the blending amount of silicone oil is less than 5% by mass, adhesion to the coating film cannot be suppressed, finger removal and color development occur. Was insufficient (Comparative Examples 1 to 9). When the blending amount of the powder component exceeds 45% by mass (Comparative Example 10), the oil-based external preparation is in the form of powder and does not harden after being applied to the base sheet, so that the oil-based external preparation layer cannot be formed. It was. Further, when the hardness of the oil-based external preparation is less than 35 gf (Comparative Examples 11 to 13), the adhesion rate to the coating film is high, and when the hardness of the oil-based external preparation exceeds 170 gf (Comparative Example 14), the finger can be removed. A tendency for poor color development was observed.
（実施例１４〜２４）
下記の表３に掲げた組成を有する油性外用剤（化粧料）を用いて、上記実施例１等と同様に、シート状外用剤を作成し、評価した。
各実施例に使用した油性外用剤の組成、及び、評価結果を下記の表３に併せて示す。(Examples 14 to 24)
Using the oil-based external preparation (cosmetics) having the composition shown in Table 3 below, a sheet-like external preparation was prepared and evaluated in the same manner as in Example 1 and the like.
The composition of the oil-based external preparation used in each example and the evaluation results are also shown in Table 3 below.
＊３ ＫＦ−９６−１００ｃｓ（信越化学工業社）
＊４ ＫＦ−９６−３００ｃｓ（信越化学工業社）
＊５ ＫＦ−９６−１０００ｃｓ（信越化学工業社）
＊６ ＫＦ−９６−５０００ｃｓ（信越化学工業社）
＊７ メチルフェニルシリコーンＰＨ−１５５５（東レ・ダウコーニング社）
＊８ シリコーンＫＦ５６（信越化学工業社）
＊９ シリコーンＫＦ５４（信越化学工業社）
＊１０ シリコーンＫＦ−５４ＨＶ（信越化学工業社）
＊１１ ＦＭＰＳ（モメンティブ・パフォーマンス・マテリアルズ・ジャパン合同会社）
＊１２ エキセコールＤ−５（信越化学工業社）
* 4 KF-96-300cs (Shin-Etsu Chemical Co., Ltd.)
* 5 KF-96-1000cs (Shin-Etsu Chemical Co., Ltd.)
* 6 KF-96-5000cs (Shin-Etsu Chemical Co., Ltd.)
* 7 Methylphenyl silicone PH-1555 (Toray Dow Corning)
* 8 Silicone KF56 (Shin-Etsu Chemical Co., Ltd.)
* 9 Silicone KF54 (Shin-Etsu Chemical Co., Ltd.)
* 10 Silicone KF-54HV (Shin-Etsu Chemical Co., Ltd.)
* 11 FMPS (Momentive Performance Materials Japan LLC)
* 12 Execol D-5 (Shin-Etsu Chemical Co., Ltd.)
表３に示されるとおり、シリコーン油として種々のタイプのものを使用しても、被覆フィルムに対して付着しにくく、指取れや発色にも優れた油性外用剤が得られた。 As shown in Table 3, even if various types of silicone oils were used, an oil-based external preparation that did not easily adhere to the coating film and was excellent in finger removal and color development was obtained.
（実施例２５〜２６及び比較例１５）
下記の表４に掲げた組成を有する油性外用剤（練香水）を用いて、上記実施例１等と同様に、シート状外用剤を作成した。得られた各シート状外用剤について、被覆フィルムへの付着率、指取れを評価し、さらに香りの持続効果についても以下の方法で評価した。油性外用剤の組成、及び、評価結果を下記の表４に併せて示す。(Examples 25 to 26 and Comparative Example 15)
Using the oil-based external preparation (perfume) having the composition shown in Table 4 below, a sheet-shaped external preparation was prepared in the same manner as in Example 1 and the like. For each of the obtained sheet-like external preparations, the adhesion rate to the coating film and the finger removal were evaluated, and the scent-sustaining effect was also evaluated by the following method. The composition of the oil-based external preparation and the evaluation results are also shown in Table 4 below.
＜香りの持続効果＞
専門パネル１０名により実際に手首に塗布してもらい、香りの持続効果を下記の基準に従って判定してもらった。評価Ａ〜Ｂを合格と判断した。<Scent lasting effect>
Ten specialist panels actually applied it to their wrists and asked them to judge the sustained effect of the scent according to the following criteria. Evaluations A to B were judged to be acceptable.
判定基準
Ａ：専門パネル９〜１０名が、香りの持続効果が良いと認めた。
Ｂ：専門パネル７〜８名が、香りの持続効果が良いと認めた。
Ｃ：専門パネル５〜６名が、香りの持続効果が良いと認めた。
Ｄ：専門パネル３〜４名が、香りの持続効果が良いと認めた。
Ｅ：専門パネル２名以下が、香りの持続効果が良いと認めた。Judgment Criteria A: 9 to 10 specialized panels recognized that the scent lasting effect was good.
B: 7 to 8 specialist panels admitted that the scent lasting effect was good.
C: Specialized panels 5 to 6 people recognized that the scent lasting effect was good.
D: Specialized panels 3-4 people admitted that the scent lasting effect was good.
E: Two or less specialist panels recognized that the scent lasting effect was good.
表４に示されるとおり、油性外用剤が粉末成分を含まない場合には、被覆フィルムへの付着を抑えられなかった（比較例１５）。一方、油性外用剤として、シリコーン油を５〜６０質量％、粉末成分を３〜４５質量％含有し、硬度が３５〜１７０ｇｆの範囲を満たす油性外用剤を用いた場合には、被覆フィルムに付着しにくいにも拘わらず、指取れに優れるほか、香りも長時間にわたって持続した（実施例２５〜２６）。 As shown in Table 4, when the oil-based external preparation did not contain the powder component, the adhesion to the coating film could not be suppressed (Comparative Example 15). On the other hand, when an oil-based external preparation containing 5 to 60% by mass of silicone oil and 3 to 45% by mass of powder components and having a hardness in the range of 35 to 170 gf is used as the oil-based external preparation, it adheres to the coating film. Although it was difficult to remove, it was excellent in finger removal and the scent lasted for a long time (Examples 25 to 26).
以下に、本発明のシート状外用剤の処方を例示する。本発明はこれらの処方例によって何ら限定されるものではなく、特許請求の範囲によって特定されるものであることはいうまでもない。なお、配合量は全てシート状外用剤に収容する油性外用剤全量に対する質量％で表す。 The formulation of the sheet-like external preparation of the present invention is illustrated below. It goes without saying that the present invention is not limited to these prescription examples, and is specified by the scope of claims. The blending amount is expressed in mass% with respect to the total amount of the oil-based external preparation contained in the sheet-shaped external preparation.
処方例１：クレンジング剤
（成分名） 配合量（質量％）
１． マイクロクリスタリンワックス ３
２． ポリエチレンワックス １２
３． シリコーン油 ４０
４． トリエチルヘキサノイン １２
５． 流動パラフィン ２３
６． 合成金雲母 ５
７． マイカ ５Prescription example 1: Cleansing agent (ingredient name) Blending amount (mass%)
1. 1. Microcrystalline wax 3
2. 2. Polyethylene wax 12
3. 3. Silicone oil 40
4. Triethylhexanoin 12
5. Liquid paraffin 23
6. Synthetic phlogopite 5
7. Mica 5
処方例２：ネイルケアクリーム
（成分名） 配合量（質量％）
１． マイクロクリスタリンワックス ２．６
２． ポリエチレンワックス １０．４
３． シリコーン油 ２０
４． トリエチルヘキサノイン １７
５． ジイソステアリン酸グリセリル ２０
６． スクワラン ２０
７． 合成金雲母 ５
８． マイカ ５Prescription example 2: Nail care cream (ingredient name) Blending amount (mass%)
1. 1. Microcrystalline wax 2.6
2. 2. Polyethylene wax 10.4
3. 3. Silicone oil 20
4. Triethylhexanoin 17
5. Glyceryl diisostearate 20
6. Squalene 20
7. Synthetic phlogopite 5
8. Mica 5
処方例３：ニキビケア剤
（成分名） 配合量（質量％）
１． マイクロクリスタリンワックス ２．２
２． ポリエチレンワックス ８．８
３． シリコーン油 ２０
４． トリエチルヘキサノイン ２０
５． ジイソステアリン酸グリセリル １７
６． イオウ １
７． 酸化亜鉛 １
８． 合成金雲母 １０
９． マイカ ２０Prescription example 3: Acne care agent (ingredient name) Blending amount (mass%)
1. 1. Microcrystalline wax 2.2
2. 2. Polyethylene wax 8.8
3. 3. Silicone oil 20
4. Triethylhexanoin 20
5. Glyceryl diisostearate 17
6. Sulfur 1
7. Zinc oxide 1
8. Synthetic phlogopite 10
9. Mica 20
処方例４：虫よけ剤
（成分名） 配合量（質量％）
１． マイクロクリスタリンワックス ２．２
２． ポリエチレンワックス ８．８
３． シリコーン油 ２０
４． トリエチルヘキサノイン ２０
５． ジイソステアリン酸グリセリル １８．５
６． ユーカリ油 ０．５
７． 合成金雲母 １０
８． マイカ ２０Prescription example 4: Insect repellent (ingredient name) Blending amount (mass%)
1. 1. Microcrystalline wax 2.2
2. 2. Polyethylene wax 8.8
3. 3. Silicone oil 20
4. Triethylhexanoin 20
5. Glyceryl diisostearate 18.5
6. Eucalyptus oil 0.5
7. Synthetic phlogopite 10
8. Mica 20
処方例５：清涼剤
（成分名） 配合量（質量％）
１． マイクロクリスタリンワックス ２．６
２． ポリエチレンワックス １０．４
３． シリコーン油 ２０
４． トリエチルヘキサノイン １３
５． ジイソステアリン酸グリセリル １４．７
６． 流動パラフィン １８
７． メントール ０．９
８． カンフル ０．４
９． 合成金雲母 １０
１０．マイカ １０Prescription example 5: Cooling agent (ingredient name) Blending amount (mass%)
1. 1. Microcrystalline wax 2.6
2. 2. Polyethylene wax 10.4
3. 3. Silicone oil 20
4. Triethylhexanoin 13
5. Glyceryl diisostearate 14.7
6. Liquid paraffin 18
7. Menthol 0.9
8. Camphor 0.4
9. Synthetic phlogopite 10
10. Mica 10
処方例６：ヘアワックス
（成分名） 配合量（質量％）
１． マイクロクリスタリンワックス ５
２． ビーズワックス ８
３． カルナウバロウ ５
４． ワセリン ５
５． ＰＰＧ−４０ブチル ６
６． テトラエチルヘキサン酸ペンタエリスリチル １０
７． ジメチコン ６ＣＳ ２０
８． ステアリン酸グリセリル（ＳＥ） ２
９． イソステアリン酸 １
１０．色材 ５
１１．タルク ５
１２．マイカ １５
１３．合成金雲母 １３Prescription example 6: Hair wax (ingredient name) Blending amount (mass%)
1. 1. Microcrystalline wax 5
2. 2. Bead wax 8
3. 3. Carnauba wax 5
4. Vaseline 5
5. PPG-40 Butyl 6
6. Pentaerythrityl tetraethylcaproate 10
7. Dimethicone 6CS 20
8. Glyceryl stearate (SE) 2
9. Isostearic acid 1
10. Color material 5
11. Talc 5
12. Mica 15
13. Synthetic phlogopite 13
Claims (6)
基材シートの表面の少なくとも一部に形成された油性外用剤層と、
油性外用剤層の表面を保護するように積層された被覆フィルムと
を有するシート状外用剤であって、
油性外用剤層を構成する油性外用剤が、
（Ａ）シリコーン油を５〜６０質量％、及び
（Ｂ）粉末成分を３〜４５質量％、
含み、かつ、油性外用剤の硬度が３５〜１７０ｇｆである、シート状外用剤。Base sheet and
An oil-based external preparation layer formed on at least a part of the surface of the base sheet,
A sheet-like external preparation having a coating film laminated so as to protect the surface of the oil-based external preparation layer.
The oil-based external preparation that constitutes the oil-based external preparation layer is
(A) Silicone oil 5 to 60% by mass, (B) Powder component 3 to 45% by mass,
A sheet-like external preparation containing the oil-based external preparation and having a hardness of 35 to 170 gf.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2017248135 | 2017-12-25 | ||
| JP2017248135 | 2017-12-25 | ||
| PCT/JP2018/032811 WO2019130664A1 (en) | 2017-12-25 | 2018-09-05 | External sheet preparation |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPWO2019130664A1 true JPWO2019130664A1 (en) | 2020-12-24 |
| JP7256755B2 JP7256755B2 (en) | 2023-04-12 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2019562740A Active JP7256755B2 (en) | 2017-12-25 | 2018-09-05 | Sheet-type topical agent |
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| Country | Link |
|---|---|
| JP (1) | JP7256755B2 (en) |
| TW (1) | TW201927278A (en) |
| WO (1) | WO2019130664A1 (en) |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0576414A (en) * | 1991-09-24 | 1993-03-30 | Kanebo Ltd | Dressing material sample sheet and its manufacture |
| JPH08308633A (en) * | 1995-01-20 | 1996-11-26 | Color Prelude Inc | Cosmetic sampler with integral applicator |
| JP2010030971A (en) * | 2008-07-31 | 2010-02-12 | Shiseido Co Ltd | Cosmetic for correcting inequality |
| JP2014161403A (en) * | 2013-02-22 | 2014-09-08 | Tokiwa Corp | Method for manufacturing powder-cosmetic sheet and powder-cosmetic sheet |
-
2018
- 2018-09-05 JP JP2019562740A patent/JP7256755B2/en active Active
- 2018-09-05 WO PCT/JP2018/032811 patent/WO2019130664A1/en active Application Filing
- 2018-10-01 TW TW107134626A patent/TW201927278A/en unknown
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0576414A (en) * | 1991-09-24 | 1993-03-30 | Kanebo Ltd | Dressing material sample sheet and its manufacture |
| JPH08308633A (en) * | 1995-01-20 | 1996-11-26 | Color Prelude Inc | Cosmetic sampler with integral applicator |
| JP2010030971A (en) * | 2008-07-31 | 2010-02-12 | Shiseido Co Ltd | Cosmetic for correcting inequality |
| JP2014161403A (en) * | 2013-02-22 | 2014-09-08 | Tokiwa Corp | Method for manufacturing powder-cosmetic sheet and powder-cosmetic sheet |
Also Published As
| Publication number | Publication date |
|---|---|
| WO2019130664A1 (en) | 2019-07-04 |
| TW201927278A (en) | 2019-07-16 |
| JP7256755B2 (en) | 2023-04-12 |
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