JPWO2018066466A1 - Hydrogen generation face sheet - Google Patents

Hydrogen generation face sheet Download PDF

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JPWO2018066466A1
JPWO2018066466A1 JP2018543870A JP2018543870A JPWO2018066466A1 JP WO2018066466 A1 JPWO2018066466 A1 JP WO2018066466A1 JP 2018543870 A JP2018543870 A JP 2018543870A JP 2018543870 A JP2018543870 A JP 2018543870A JP WO2018066466 A1 JPWO2018066466 A1 JP WO2018066466A1
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sheet
sheet member
hydrogen
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water
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隆 竹原
隆 竹原
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隆 竹原
隆 竹原
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    • AHUMAN NECESSITIES
    • A45HAND OR TRAVELLING ARTICLES
    • A45DHAIRDRESSING OR SHAVING EQUIPMENT; EQUIPMENT FOR COSMETICS OR COSMETIC TREATMENTS, e.g. FOR MANICURING OR PEDICURING
    • A45D44/00Other cosmetic or toiletry articles, e.g. for hairdressers' rooms
    • A45D44/22Face shaping devices, e.g. chin straps; Wrinkle removers, e.g. stretching the skin
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/02Cosmetics or similar toiletry preparations characterised by special physical form
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • A61K8/26Aluminium; Compounds thereof
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00Preparations for care of the skin
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00Preparations for care of the skin
    • A61Q19/08Anti-ageing preparations
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/06Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents
    • C01B3/08Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents with metals
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30Hydrogen technology
    • Y02E60/36Hydrogen production from non-carbon containing sources, e.g. by water electrolysis

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  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Public Health (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Veterinary Medicine (AREA)
  • Birds (AREA)
  • Epidemiology (AREA)
  • Dermatology (AREA)
  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Gerontology & Geriatric Medicine (AREA)
  • Cosmetics (AREA)

Abstract

【課題】本発明は、簡易な構成及び作業で水と金属との反応により水素を発生させながら、外部への漏水防止と顔表面等の肌表面への十分な水素付与とを同時に達成し得る水素発生式フェイスシートを提供することを目的とする。【解決手段】上記課題のため、本発明の水素発生式フェイスシートは、少なくとも可撓性を有するシート形状の第一シート部材と、一部または全部が不織布からなる可撓性を有するシート形状の第二シート部材とを備え、前記第一シート部材の表面には、水を組成に含むゲル状材が塗布されており、前記第二シート部材の表面には、水と反応することにより水素を発生させる金属粒子が予め含まれ又は塗布されており、前記第一シート部材の表面と前記第二シート部材の表面とは、当接可能である、ことを特徴とする、【選択図】図1The present invention can simultaneously achieve water leakage prevention and sufficient hydrogen application to the skin surface such as the face surface while generating hydrogen by the reaction of water and metal with a simple configuration and work. An object is to provide a hydrogen generating face sheet. In order to solve the above problems, the hydrogen generating face sheet of the present invention has at least a flexible sheet-shaped first sheet member and a flexible sheet-shaped sheet partly or entirely made of a nonwoven fabric. A gel-like material containing water in the composition is applied to the surface of the first sheet member, and hydrogen is reacted to the surface of the second sheet member by reacting with water. Metal particles to be generated are preliminarily contained or coated, and the surface of the first sheet member and the surface of the second sheet member can be brought into contact with each other.

Description

本発明は、水と金属との反応による水素を使用者の体表面に付与することができる水素発生シートに関する。   The present invention relates to a hydrogen generating sheet capable of imparting hydrogen to a user's body surface by reaction of water and metal.

活性酸素は酸化力が非常に強く、人間の体内に侵入した細菌やウイルスを除去する役割を有する一方で、人間の正常な細胞をも攻撃し、損傷させてしまうことが調べられている。過剰な活性酸素の存在は、正常な細胞を損傷させる可能性を上昇させ、細胞の劣化及び細胞の変異、又はこれに伴う肌の老化などのリスクを発生させる。   Active oxygen has a very strong oxidizing power and has been investigated to attack and damage normal human cells while removing bacteria and viruses that have invaded the human body. The presence of excess active oxygen increases the likelihood of damaging normal cells, creating risks such as cell degradation and cell mutation, or associated skin aging.

近年、水素が活性酸素を除去することが研究により明らかになり、健康や美容に効果的であると注目されている。水素と活性酸素との反応では、反応物として水のみを発生するため、人体への悪影響が非常に少ない。従って、特に活性酸素が身体に発生しやすい、運動時や、飲食時、喫煙時、紫外線・汚染環境下での滞在時、睡眠不足、長時間労働等の高いストレスを受けた時等の種々の状態における老化の防止や美容・健康促進のために、水素を身体に取り入れることが推奨されている。特に、肌の老化防止や美容のためには水素を直接に肌(体表面)に付与することが推奨されている。   In recent years, research has revealed that hydrogen removes active oxygen, and has attracted attention as being effective for health and beauty. In the reaction between hydrogen and active oxygen, only water is generated as a reactant, so that there is very little adverse effect on the human body. Therefore, especially when active oxygen is likely to occur in the body, when exercising, eating and drinking, smoking, staying under ultraviolet light / contaminated environment, lack of sleep, long working hours, etc. It is recommended to incorporate hydrogen into the body to prevent aging in the condition and to promote beauty and health. In particular, it is recommended to apply hydrogen directly to the skin (body surface) for preventing skin aging and beauty.

水素を直接肌に付与する場合、水素は気体であるため空気中に拡散しやすく、一般には水素を水溶液に溶解させた水素水溶液(以下、水素水と称する。)を肌に付与している。また特に顔や目などの特定の部位を狙って水素水を付与する場合は、コットン等の吸水性布地に水素水を染み込ませ、布地を肌やまぶたに当接している。しかしながら、この方法では、布地に染み込ませる水素水の量を調整する必要がある。水素水量を確保しつつ肌から水垂れる等を防止する必要があるからである。また、水素水を染み込ませた布地からは短時間で水素が抜けてしまうため、十分な効果を得るためには何度も繰り返し注水を行う必要があった。さらにこの方法の場合、注水用の水素水の準備が必要であり、経時的な水素含有量の低下(容器からの水素漏洩やや、他物質との反応による水素量低下)から、在庫管理が必要となる汎用化には問題があった。   When hydrogen is directly applied to the skin, since hydrogen is a gas, it is easily diffused into the air, and generally an aqueous hydrogen solution in which hydrogen is dissolved in an aqueous solution (hereinafter referred to as hydrogen water) is applied to the skin. In particular, when hydrogen water is applied to specific parts such as the face and eyes, hydrogen water is soaked into a water absorbent fabric such as cotton, and the fabric is in contact with the skin and eyelids. However, in this method, it is necessary to adjust the amount of hydrogen water soaked into the fabric. This is because it is necessary to prevent dripping from the skin while securing the amount of hydrogen water. Further, since hydrogen escapes from the fabric soaked with hydrogen water in a short time, it was necessary to repeat water injection repeatedly to obtain a sufficient effect. Furthermore, in this method, it is necessary to prepare hydrogen water for water injection, and inventory management is necessary due to a decrease in hydrogen content over time (hydrogen leakage from the container and a decrease in hydrogen content due to reaction with other substances). There was a problem with generalization.

この問題に対して、使用時に水素を生成させながら、直接水素を顔表面や眼球に付与する方法の試用されている。この方法では、使用時に水と金属との反応により水素を発生させる機構を用いている。具体的には、水が封入されたシート形状の部材と金属が付着したシート形状の部材とを重ね合わせ、使用直前に水が封入されたシートを針等の突起物等により破断することで水を金属と接触させ、水素を発生させる。その後、重ね合わせたシートを顔表面に当接させると、発生した水素の直接の顔表面への付与が可能となる。この方法であれば、水素水を予め用意する必要がなく、水量調整の必要もない。また、顔表面上で水素発生反応させるため繰り返しの注水操作も要しない。さらに、シートを顔表面に当接することで顔表面上からの水分の蒸発を防止し、水素発生中に水蒸気も発生するため、水素水の付与中において顔表面の保湿も実現される。
しかしながら、上述の方法では、水が封入されたシートの破断というユーザによる不確実な作業が必要であり、破断を誤ると水と金属との接触が不十分となり所望の水素量を確保できない可能性がある。また逆に、シート外部へ水漏れも考えられ、水分が顔表面等に垂れるなど使用感を損なうおそれもあった。
この問題を解決するには、上記装置全体をさらにシートで覆う(特許文献1参照)、別個のシート破断機構を備える等が考えられるが、美容・健康目的に使い捨てが想定されることを考慮すれば、部材点数が多く、コストも増加し、好ましくない。
In order to solve this problem, a method of directly applying hydrogen to the face surface or eyeball while generating hydrogen during use has been tried. This method uses a mechanism for generating hydrogen by reaction of water and metal during use. Specifically, a sheet-shaped member filled with water and a sheet-shaped member attached with metal are overlapped, and the sheet filled with water is broken by a protrusion such as a needle just before use to remove water. Is brought into contact with a metal to generate hydrogen. Thereafter, when the superposed sheets are brought into contact with the face surface, the generated hydrogen can be directly applied to the face surface. With this method, it is not necessary to prepare hydrogen water in advance, and there is no need to adjust the amount of water. In addition, repeated water injection operations are not required because of the hydrogen generation reaction on the face surface. Furthermore, moisture is prevented from evaporating from the face surface by contacting the sheet with the face surface, and water vapor is also generated during the generation of hydrogen, so that moisture retention on the face surface is also realized during the application of hydrogen water.
However, the above-described method requires an uncertain operation by the user to break the sheet in which water is sealed, and if the breakage is incorrect, there is a possibility that contact between the water and the metal becomes insufficient and a desired amount of hydrogen cannot be secured. There is. On the other hand, water leakage may occur outside the seat, which may impair the feeling of use such as dripping water on the face surface.
In order to solve this problem, it is conceivable to further cover the entire apparatus with a sheet (see Patent Document 1), or to provide a separate sheet breaking mechanism. In this case, the number of members is large and the cost increases, which is not preferable.

特開2013−126948号公報JP2013-126948A

本発明は、上記事情に鑑みて創作されたものであり、簡易な構成及び作業で水と金属との反応により水素を発生させながら、外部への漏水防止と顔表面等の肌表面への十分な水素付与とを同時に達成し得る水素発生式フェイスシートを提供することを目的とする。   The present invention was created in view of the above circumstances, while preventing hydrogen leakage to the outside and sufficiently applying to the skin surface such as the face surface while generating hydrogen by the reaction of water and metal with a simple configuration and work. An object of the present invention is to provide a hydrogen generating face sheet capable of simultaneously achieving proper hydrogenation.

上述の課題を解決するために、本発明の水素発生式フェイスシートは、少なくとも可撓性を有するシート形状の第一シート部材と、一部または全部が不織布からなる可撓性を有するシート形状の第二シート部材とを備え、前記第一シート部材の表面には、水を組成に含むゲル状材が塗布されており、前記第二シート部材の表面には、水と反応することにより水素を発生させる金属粒子が予め含まれ又は塗布されており、前記第一シート部材の表面と前記第二シート部材の表面とは、当接可能である、ことを特徴とする。   In order to solve the above-described problems, the hydrogen generating face sheet of the present invention has at least a flexible sheet-shaped first sheet member and a flexible sheet-shaped sheet part or all made of a nonwoven fabric. A gel-like material containing water in the composition is applied to the surface of the first sheet member, and hydrogen is reacted to the surface of the second sheet member by reacting with water. Metal particles to be generated are preliminarily contained or applied, and the surface of the first sheet member and the surface of the second sheet member can contact each other.

本発明の水素発生式フェイスシート(以下、本シートと称する。)では、第一シート部材の表面と第二シート部材の表面とを当接させるだけで、水素を発生させることができる。
従来、水と金属とによる水素発生反応の効率性を優先考慮し、水溶液の粘度が小さく、金属との接触面積が大きい水溶液を使用していた。これに対して、本シートでは、粘性が高いゲル状の水溶液を使用することで水の漏洩を回避しつつ、顔表面への水素付与量の確保が可能な簡易構成例を提供していると言える。
In the hydrogen generating face sheet (hereinafter referred to as the present sheet) of the present invention, hydrogen can be generated simply by bringing the surface of the first sheet member into contact with the surface of the second sheet member.
Conventionally, in consideration of the efficiency of the hydrogen generation reaction between water and metal, an aqueous solution having a low viscosity of the aqueous solution and a large contact area with the metal has been used. On the other hand, this sheet provides a simple configuration example that can secure the amount of hydrogen applied to the face surface while avoiding water leakage by using a highly viscous gelled aqueous solution. I can say that.

具体的には、第一シート部材には水を組成に含むゲル状材が塗布され、水素発生反応前〜終了後まで第一シート部から水分漏出が防止される。また、第一シート部材と第二シート部材とを当接させ第二シート部材に配置される金属粒子にゲル状材が容易に接触するため水素の発生反応効率が良好である。さらに、ゲル状材を塗布する、2枚のシートを当接させる、という簡易かつ安価な構成で達成している点も有利である。さらに、第一シート部と第二シート部とが可撓性を備えることにより、本シートは顔表面の凹凸に対しても密な当接が可能である。   Specifically, a gel-like material containing water in the composition is applied to the first sheet member, and moisture leakage is prevented from the first sheet portion before and after the hydrogen generation reaction. Further, since the gel material easily contacts the metal particles arranged on the second sheet member by bringing the first sheet member and the second sheet member into contact with each other, the hydrogen generation reaction efficiency is good. Furthermore, it is advantageous in that it is achieved with a simple and inexpensive configuration in which two sheets for applying a gel material are brought into contact with each other. Furthermore, since the first sheet portion and the second sheet portion have flexibility, the sheet can be in close contact with the unevenness of the face surface.

また本シートは、前記金属粒子としてカルシウムを含む、ことが好ましい。   Moreover, it is preferable that this sheet contains calcium as the metal particles.

上述の本シートによると、水素発生反応において反応熱の発生が小さく、かつゲル状材が熱を緩衝することから、顔表面に反応熱が伝わりにくく低温での本シートの使用が可能となる。本シートを使用することで清涼感を確保しつつ水素ガスを付与できる、特に高温時や体温の上昇時等に使用者ニーズに合致する。   According to the above-described present sheet, the generation of reaction heat is small in the hydrogen generation reaction, and the gel material buffers the heat, so that the reaction heat is not easily transmitted to the face surface, and the sheet can be used at a low temperature. By using this sheet, it is possible to apply hydrogen gas while ensuring a refreshing feeling, especially when the temperature is high or when the body temperature is rising.

前記金属粒子としてアルミニウム又はマグネシウムを含むことも好ましい。   It is also preferable that the metal particles include aluminum or magnesium.

上述の本シートによると、水素発生反応において反応熱の発生が大きく高温での本シートの使用が可能となる。本シートを使用することで、あたたかい使用感を得つつ水素ガスを付与できることから、特に寒温時や体温の下降時等に使用者ニーズに合致する。   According to the above-mentioned present sheet, generation of reaction heat is large in the hydrogen generation reaction, and the present sheet can be used at a high temperature. By using this sheet, it is possible to apply hydrogen gas while obtaining a warm feeling of use, so that it meets the user's needs especially at cold temperatures or when the body temperature drops.

前記第一シート部材と前記第二シート部材とは、連結して一枚のシート状に形成され、
使用時に、第一シート部材と第二シート部材との境界近傍で折り曲げて重ね合わせることで、前記第一シート部材の表面又は裏面と前記第二シート部材の金属粒子側とを当接させても良い。
The first sheet member and the second sheet member are connected to form a single sheet,
At the time of use, even if the first sheet member and the second sheet member are folded near each other and overlapped, the front surface or the back surface of the first sheet member and the metal particle side of the second sheet member may be brought into contact with each other. good.

上述の本シートによると、1枚のシートを折り曲げて重ね合わせるだけで、水素を発生させることができるため、より簡易な操作によって顔表面に水素ガスを付与することができる。従って、使用者にとってさらに扱いやすく、市場性が高い。   According to the above-described present sheet, hydrogen can be generated simply by folding and superimposing one sheet, so that hydrogen gas can be applied to the face surface by a simpler operation. Therefore, it is easier for the user to handle and the marketability is high.

前記ゲル状材が、所望の匂い成分や、冷感成分を含んでも良い。   The gel material may contain a desired odor component or a cooling sensation component.

上述の本シートによると、使用中に使用者が所望の匂いを感じることができ、より好ましい使用感を得ることが可能となる。本シートを使用することで、清涼感をさらに確保しつつ水素ガスを付与できる。   According to the present sheet described above, the user can feel a desired odor during use, and a more preferable feeling of use can be obtained. By using this sheet | seat, hydrogen gas can be provided, ensuring a refreshing feeling further.

第一シート部材の表面上又は第二シート部材の表面上に通気性かつ溶媒非浸透性のシートを備えても良い。   A breathable and solvent-impermeable sheet may be provided on the surface of the first sheet member or the surface of the second sheet member.

上述の本シートによると、第一シート部12又は第二シート部16の素材を溶媒浸透性によらず任意に選択可能であるため、低コストでの本シートの提供が可能となる。   According to the above-described main sheet, since the material of the first sheet portion 12 or the second sheet portion 16 can be arbitrarily selected regardless of the solvent permeability, the main sheet can be provided at a low cost.

第一シート部材が溶媒不浸透性の素材で構成されることが好ましい。また、第二シート部材が、水溶液が外部へ漏れ出さない程度の溶媒浸透性の素材で構成されることが好ましい。   The first sheet member is preferably composed of a solvent-impermeable material. Moreover, it is preferable that a 2nd sheet | seat member is comprised with the solvent permeable raw material of the grade which aqueous solution does not leak outside.

上述の本シートによると、ゲル状材が第二シート部表面上又は内部の金属粒子に接触しやすくなり、より効果的な水素発生が可能となる。   According to the present sheet described above, the gel material can easily come into contact with the metal particles on or inside the second sheet portion, and more effective hydrogen generation is possible.

本発明によれば、請求項記載の方法により、安価かつ簡易な構成で、顔面への液垂れを防止しつつ、顔表面に水素を付与することができる水素発生式フェイスシートが提供される。   According to the present invention, there is provided a hydrogen generating face sheet capable of imparting hydrogen to the face surface while preventing liquid dripping on the face with an inexpensive and simple structure by the method described in the claims.

本発明の概念図を示しており、(a)は第一シート部材の斜視図、(b)は第二シート部材の斜視図を示している。The conceptual diagram of this invention is shown, (a) is a perspective view of a 1st sheet | seat member, (b) has shown the perspective view of a 2nd sheet | seat member. 本発明の概念図を示しており、(b)は第一シート部材のA-A断面図、第二シート部材のB-B断面図、(c)は使用時の本発明の水素発生式フェイスシートの断面図(A-A断面及びB-B断面)を示している。The conceptual diagram of this invention is shown, (b) is AA sectional drawing of a 1st sheet member, BB sectional drawing of a 2nd sheet member, (c) is sectional drawing of the hydrogen generation type face sheet of this invention at the time of use (AA cross section and BB cross section) are shown. 本発明の他の実施形態を示しており、(a)は本発明の水素発生式フェイスシートの他の実施形態の使用前の斜視図、(b)は本発明の水素発生式フェイスシートの実施形態の使用前のC-C断面図、(c)は本発明の水素発生式フェイスシートの実施形態の使用時のC-C断面図を示している。Fig. 3 shows another embodiment of the present invention, in which (a) is a perspective view before use of another embodiment of the hydrogen generating face sheet of the present invention, and (b) is an implementation of the hydrogen generating face sheet of the present invention. CC sectional drawing before use of a form, (c) has shown CC sectional drawing at the time of use of embodiment of the hydrogen generation type face sheet of the present invention. 本発明の水素発生式フェイスシートの他の実施形態の斜視図を示している。The perspective view of other embodiments of the hydrogen generation type face sheet of the present invention is shown. 本発明の水素発生式フェイスシートの他の実施形態の正面図を示している。The front view of other embodiment of the hydrogen generation type face sheet of the present invention is shown. 本発明の水素発生式フェイスシートの第二シート部材の他の実施形態の断面図を示している。Sectional drawing of other embodiment of the 2nd sheet | seat member of the hydrogen generation type face sheet of this invention is shown.

以下に、本発明の水素発生シートの実施形態の代表例を、図1〜5を参照しながら詳細に説明する。なお、本発明の水素発生シートは、図示されるものに限られず、また図示及び説明の内容を一般常識の範囲内で改変したものをも含むことはいうまでもない。また各図は、容易な理解のために、必要に応じて寸法、比又は数を誇張して表示している場合もある。   Below, the representative example of embodiment of the hydrogen generation sheet | seat of this invention is demonstrated in detail, referring FIGS. Note that the hydrogen generation sheet of the present invention is not limited to the illustrated one, and it is needless to say that the contents of the illustration and the explanation are modified within the range of general common sense. Each figure may be exaggerated in size, ratio, or number as necessary for easy understanding.

まず、本水素シートの構成の基本となる概念について図1を参照して説明する。図1(a)は本シートの構成要素である第一シート部材の斜視図を、(b)は第二シート部材の斜視図を、それぞれ示す。図1(a)には、長方形のシート形状の第一シート部材12が示され、第一シート部12の表面(図1(a)における上面)には、第一シート部の中心から全体に周囲近傍を除いてゲル状材14が塗布されている。図1(b)には、長方形のシート形状の第二シート部材16が示され、第二シート部16の表面(図1(b)における上面)には、金属粒子18が複数配置されている。
First, the basic concept of the configuration of the hydrogen sheet will be described with reference to FIG. FIG. 1A is a perspective view of a first sheet member that is a component of the sheet, and FIG. 1B is a perspective view of a second sheet member. FIG. 1A shows a rectangular sheet-shaped first sheet member 12, and the surface of the first sheet portion 12 (upper surface in FIG. 1A) is entirely from the center of the first sheet portion. A gel material 14 is applied except in the vicinity of the periphery. FIG. 1B shows a rectangular sheet-shaped second sheet member 16, and a plurality of metal particles 18 are arranged on the surface of the second sheet portion 16 (upper surface in FIG. 1B). .

次に各部材について詳細に説明する。
第一シート部材12は、可撓性を備えた四角形のシート状であり、ゲル状材14が染み出ない程度の溶媒浸透性の低い不織布で構成される。第一シート部材12の形状は、コストの点から成形の容易な長方形状とし、顔面への使用物であるという点から一般的なマスクサイズ〜顔面を覆う程度の大きさとしている。ゲル状材14は、水を組成に含む四角形のシート形状のゲルであり、第一シート部材12の表面(紙面上方側の面)の周囲近傍を除き略全体に塗布される。ゲル状材14は、粘性を有するものであり、第一シート部材12を任意の方向に傾けても常温において第一シート部材12から移動し零れることがない。ゲル状材14の形状は、使用時の利便性から図1(a)で示すような四角形状だけでなく第一シート部材12の全範囲又は周囲近傍以外の全範囲を覆う形状も考えられる。
Next, each member will be described in detail.
The first sheet member 12 is a quadrangular sheet having flexibility, and is composed of a non-woven fabric with low solvent permeability so that the gel material 14 does not bleed out. The shape of the 1st sheet | seat member 12 is made into the rectangular shape which is easy to shape | mold from the point of cost, and is a magnitude | size which is a grade which covers the general mask size-the face from the point that it is a use thing to a face. The gel-like material 14 is a rectangular sheet-shaped gel containing water in its composition, and is applied to substantially the entire surface except for the vicinity of the surface of the first sheet member 12 (the surface on the upper side of the paper). The gel material 14 has a viscosity, and even if the first sheet member 12 is tilted in an arbitrary direction, the gel material 14 does not move from the first sheet member 12 at normal temperature and spill. The shape of the gel material 14 may be a shape that covers not only the quadrangular shape as shown in FIG. 1A but also the entire range of the first sheet member 12 or the entire range other than the vicinity, for convenience in use.

第二シート部材16は、可撓性を有し、ゲル状材14が内部に浸透できる程度の溶媒浸透性を備える不織布等で構成されるが、第一シート部材16同様にゲル状材14が染み出ない程度での溶媒浸透性を有する。第二シート部材16の形状及び大きさについては、第一シート部材12と同様であるが、使用感の良好な他の例も考えられる。図1(b)において粒子形状で略示するように金属粒子18は、第二シート部材16の表面上に固定して配置される。また、図1(b)では円形で金属粒子18を略示するが、あくまで模式的に示しており、実際には微粒子が密に第二シート部材16表面上に配置されている。また、金属粒子18は、第二シート部材16の表面上だけでなく内部にも配置されており、ゲル状材14が自重や手力等で第二シート部材16に浸透することで金属部18とゲル状材14との接触が生じる。さらに、金属粒子18が第二シート部材16に配置される平面上の範囲は、反応の効率を考慮してゲル状材14の塗布範囲内であるが、これには限らない。   The second sheet member 16 is made of a non-woven fabric or the like that has flexibility and has solvent permeability enough to allow the gel material 14 to permeate the inside. It has solvent permeability to the extent that it does not exude. The shape and size of the second sheet member 16 are the same as those of the first sheet member 12, but other examples with good usability can be considered. As schematically shown in the particle shape in FIG. 1B, the metal particles 18 are fixedly disposed on the surface of the second sheet member 16. In addition, in FIG. 1B, the metal particles 18 are schematically shown in a circular shape, but are schematically illustrated to the last, and actually, the fine particles are densely arranged on the surface of the second sheet member 16. The metal particles 18 are disposed not only on the surface of the second sheet member 16 but also inside thereof, and the gel material 14 penetrates into the second sheet member 16 by its own weight, hand force, or the like, so that the metal portion 18 is obtained. Contact with the gel material 14. Furthermore, the range on the plane where the metal particles 18 are disposed on the second sheet member 16 is within the application range of the gel material 14 in consideration of the efficiency of the reaction, but is not limited thereto.

金属としては一例としてカルシウムが採用され、Ca+2H2O→Ca(OH)2+H2で反応する。   As an example, calcium is used as the metal, and the reaction is Ca + 2H2O → Ca (OH) 2 + H2.

本シートの構成により、第一シート部材12のゲル状材14が塗布される表面と、第二シート部材16の金属粒子18が配置される表面とを互いに対向するように当接させると、ゲル状材14に含まれる水と金属粒子18に含まれる金属とが反応し、水素が発生する。発生した水素ガスは、第一シート部材12、第二シート部材16、及び該2つのシート部材の隙間から、本シートの外部へと放出される。
水素発生後の本シートを顔表面に当接すると、顔表面に水素を付与することとなる。
When the surface of the first sheet member 12 on which the gel-like material 14 is applied and the surface of the second sheet member 16 on which the metal particles 18 are disposed are brought into contact with each other so as to face each other, The water contained in the shaped material 14 reacts with the metal contained in the metal particles 18 to generate hydrogen. The generated hydrogen gas is released from the first sheet member 12, the second sheet member 16, and the gap between the two sheet members to the outside of the sheet.
When this sheet after hydrogen generation is brought into contact with the face surface, hydrogen is imparted to the face surface.

図2(a)、(b)、(c)を用いて、本シートの構成をさらに説明する。図2(a)は図1(a)のA-A断面図を、図2(b)は図1(b)のB-B断面図を、図2(c)は第一シート部材12と第二シート部材16とを、図の矢印で示すようにゲル状材14側及び金属粒子18側を当接させた場合の断面図(A-A断面及びB-B断面)を示す。図2(a)に示すように、第一シート部材12の表面(紙面上方)にゲル状材14が塗布されている。また図2(b)に示すように、第二シート部材16の表面及び内部に金属粒子18が配置され又は含まれている。   The configuration of the sheet will be further described with reference to FIGS. 2 (a), (b), and (c). 2A is a cross-sectional view taken along the line AA in FIG. 1A, FIG. 2B is a cross-sectional view taken along the line BB in FIG. 1B, and FIG. 2C is the first sheet member 12 and the second sheet member. 16 is a cross-sectional view (AA cross section and BB cross section) when the gel material 14 side and the metal particle 18 side are brought into contact with each other as indicated by arrows in the figure. As shown in FIG. 2A, the gel material 14 is applied to the surface (upper side of the paper) of the first sheet member 12. Further, as shown in FIG. 2B, metal particles 18 are arranged or included on the surface and inside of the second sheet member 16.

使用時には、図2(c)に示すように、第一シート部材12の表面と第二シート部材16の表面とを当接させることで、ゲル状材14が溶媒浸透性を備える不織布で構成される第二シート部材16の内部に浸透し、ゲル状材14と金属粒子18とが十分に接触する。この結果、水と金属とが反応し、水素を発生させる。ゲル状材14が粘性を備えるため、第一シート部材12と第二シート部材16との間や第二シート部材16の裏面等から、本シート10の外部へとゲル状材14が流出しない。また、第一シート部材12及び第二シート部材16は共に可撓性を有するため、両シートを当接させた本シート10を顔表面に貼り付けると、顔表面の凸凹に合わせて本シートが顔表面に対して密に当接させることができる。   At the time of use, as shown in FIG.2 (c), the gel-like material 14 is comprised with the nonwoven fabric provided with solvent permeability by making the surface of the 1st sheet member 12 and the surface of the 2nd sheet member 16 contact | abut. The gel material 14 and the metal particles 18 are sufficiently in contact with each other. As a result, water and metal react to generate hydrogen. Since the gel material 14 has viscosity, the gel material 14 does not flow out of the main sheet 10 from between the first sheet member 12 and the second sheet member 16 or from the back surface of the second sheet member 16. Further, since both the first sheet member 12 and the second sheet member 16 are flexible, when the main sheet 10 with both sheets in contact with each other is affixed to the face surface, the main sheet is aligned with the unevenness of the face surface. It can be brought into close contact with the face surface.

次に使用感を考慮した他の実施形態について図2(c)を参考に説明する。
他の実施形態として、本シート10の使用時に、本シート10の第一シート部材12側を顔面上に貼り付け、金属粒子18の金属の主組成としてカルシウムを含むものが挙げられる。本構成の本シートでは、水素発生の反応熱の発生中心である第二シート部材16の内部近傍と顔表面との距離が第一シート部材12よって保たれることにより、顔表面への反応熱の影響が少なくなる。また、カルシウムは水素発生の反応熱が他の金属と比較して低いため、本シート使用時に使用者は反応熱を感じにくく、低温の使用感を得ることができる。
Next, another embodiment considering the feeling of use will be described with reference to FIG.
As another embodiment, at the time of use of this sheet 10, the 1st sheet member 12 side of this sheet 10 is stuck on the face, and what contains calcium as a metal main composition of metal particle 18 is mentioned. In the present sheet of this configuration, the distance between the vicinity of the inside of the second sheet member 16 that is the generation center of the reaction heat of hydrogen generation and the face surface is maintained by the first sheet member 12, so that the reaction heat to the face surface Less influence. Further, since calcium has a lower reaction heat for hydrogen generation than other metals, the user is less likely to feel the reaction heat when using the sheet, and can obtain a low-temperature feeling.

他の実施形態として、本シート10の使用時に、本シート10の第二シート部材12側を顔面上に貼り付け、金属粒子18の金属の主組成としてアルミニウム(又はマグネシウム)を含むものが挙げられる。本構成の本シートでは、水素発生の反応熱の発生中心である第二シート部材16の内部近傍と顔表面とが近接し、顔表面への反応熱の影響が大きくなる。また、アルミニウム(又はマグネシウム)は水素発生の反応熱がカルシウムと比較して高いため、本シート使用時に使用者は反応熱を感じやすく、高温の使用感を得ることができる。   As another embodiment, when the sheet 10 is used, the second sheet member 12 side of the sheet 10 is pasted on the face, and the metal main composition of the metal particles 18 includes aluminum (or magnesium). . In the present sheet having this configuration, the vicinity of the inside of the second sheet member 16 that is the generation center of the reaction heat of hydrogen generation and the face surface are close to each other, and the influence of the reaction heat on the face surface is increased. In addition, since aluminum (or magnesium) has a higher heat of reaction for hydrogen generation than calcium, the user can easily feel the heat of reaction when using the sheet, and can obtain a high temperature feeling.

また、他の実施形態として、図3(a)に示すように、第一シート部材12と第二シート部材16とが折り目部20で連結して一枚のシート状に形成されるものが挙げられる。図3(a)は、本シート110の模式図の斜視図である。いずれも長方形状の第一シート部材12と第二シート部材16とがそれぞれの一辺を折り目部20として連結して一体となった構成であり、ゲル状材14及び金属粒子18はそれぞれ第一シート部材12及び第二シート部材16の表面(紙面上方)に配置又は含まれている。折り目部20及び折り目部20の近傍の第一シート材12と第二シート部材16とは、本シート110を折り目部20に沿って180°折り曲げることが可能な可撓性を備え、折り目部20には一例として第一シート部12と同様の不織布が用いられる。本シート110を、折り目部20に沿って谷折りで折り曲げることで、第一シート部材12と第二シート部材16とを重ね合わせることができる。   Moreover, as other embodiment, as shown to Fig.3 (a), the 1st sheet | seat member 12 and the 2nd sheet | seat member 16 are connected by the crease | fold part 20, and what is formed in one sheet form is mentioned. It is done. FIG. 3A is a schematic perspective view of the sheet 110. In each case, the rectangular first sheet member 12 and the second sheet member 16 are integrated by connecting one side of each of the first sheet member 12 and the second sheet member 16 as the crease portion 20, and each of the gel material 14 and the metal particles 18 is the first sheet. The member 12 and the second sheet member 16 are arranged or included on the surface (above the paper surface). The first sheet material 12 and the second sheet member 16 in the vicinity of the crease part 20 and the crease part 20 have flexibility capable of bending the main sheet 110 along the crease part 20 by 180 °, and the crease part 20. As an example, the same non-woven fabric as the first sheet portion 12 is used. The first sheet member 12 and the second sheet member 16 can be overlapped by bending the sheet 110 by valley folding along the fold line 20.

本構成について図3(b)、(c)を用いてさらに説明する。図3(b)は本シート110の図3(a)におけるC-C断面図を示す。図3(b)第一シート部材12と第二シート部材16とが折り目部20で連結している。使用時は、折り目部20に沿って、図3(b)において矢印で示すように本シート110を折り曲げ、第一シート部材12と第二シート部材16とを重ね合わせる。図3(c)は図3(b)の本シート110を折り曲げた使用時の断面図(C-C断面)を示す。本シートを折り目部20に沿って折り曲げると、図3(c)に示すように、折り目部20近傍で本シート110が180°折り曲げられ、第一シート部材12と第二シート部材16とが略平行に当接される。   This configuration will be further described with reference to FIGS. 3B and 3C. FIG. 3B is a cross-sectional view of the sheet 110 taken along the line CC in FIG. FIG. 3B shows that the first sheet member 12 and the second sheet member 16 are connected by the crease portion 20. At the time of use, the main sheet 110 is folded along the crease portion 20 as indicated by an arrow in FIG. 3B, and the first sheet member 12 and the second sheet member 16 are overlapped. FIG. 3C is a cross-sectional view (C-C cross section) in use in which the sheet 110 of FIG. 3B is folded. When the main sheet is folded along the fold portion 20, as shown in FIG. 3C, the main sheet 110 is folded by 180 ° in the vicinity of the fold portion 20, and the first sheet member 12 and the second sheet member 16 are approximately formed. Abutted in parallel.

なお、図3(a)、(b)、(c)では、折り目部20が第一シート部材12及び第二シート部材16の一辺を連結しているが、本シート110がシート状に一体となっていればよく、一辺の一部だけを連結する実施形態でも良いことは言うまでもない。   3A, 3 </ b> B, and 3 </ b> C, the fold portion 20 connects one side of the first sheet member 12 and the second sheet member 16, but the sheet 110 is integrally formed in a sheet shape. Needless to say, an embodiment in which only a part of one side is connected may be used.

ここで、使用時を考慮した好ましい実施形態について説明する。
図4は、一対の耳あて部材22を備えた本シート210を示す。本シート210は、第一シート部材12と第二シート部材16とを先述した手法により重ね合わせたものに対して、一対の耳あて部材22を取り付けたものである。耳あて部材22は、伸縮性を有するひも形状であり、一例としてゴムが用いられる。図4に示すように、一つの耳あて部材22の両端部は、第一シート部材12の裏面(紙面上方)の一辺の近傍に、第一シート部材12の一辺に略平行に取り付けられている。他方の耳あて部材22は、該一辺と向かい合う一辺の近傍に、同様に対に取り付けられている。使用者は、マスクのように、各耳あて部材22を両耳に引っ掛けることで顔表面へ貼り付けた本シートへの固定性が高まる。
Here, a preferred embodiment in consideration of use will be described.
FIG. 4 shows the main sheet 210 provided with a pair of ear contact members 22. The present sheet 210 is obtained by attaching a pair of ear contact members 22 to the first sheet member 12 and the second sheet member 16 which are overlapped by the method described above. The ear contact member 22 has a stretchable string shape, and rubber is used as an example. As shown in FIG. 4, both end portions of one ear contact member 22 are attached in the vicinity of one side of the back surface (upper side of the paper) of the first sheet member 12 and substantially parallel to one side of the first sheet member 12. . The other ear contact member 22 is similarly attached in pairs near one side facing the one side. Like a mask, the user hooks each ear contact member 22 to both ears, so that the fixability to the sheet attached to the face surface is enhanced.

図4に示す耳あて部材22を取り付ける場所としては、第二シート部材16の裏面(紙面下方)も採用される。 また、他に、耳あて部材22を取り付ける場所は、使用時に使用者の顔表面に対して本シートが安定すれば良く、例えば第一シート部材12又は第二シート部材16の表面(各シート部材が当接)でもよい。   As a place for attaching the ear contact member 22 shown in FIG. In addition, it is only necessary that the ear contact member 22 is attached to the surface of the user's face when the sheet is used. For example, the surface of the first sheet member 12 or the second sheet member 16 (each sheet member) May be contact).

図5は、鼻用切り込み部24と、口用開口部26と、顔用切り込み部28とを備えた本シート310を正面から見た図を示す。第一シート部材12と第二シート部材16と(図示しない)には、それぞれ重ね合わせた時に合わさるように、鼻用切り込み部24と、口用開口部26と、顔用切り込み部28a、b、c、dが設けられている。結果として、使用時には図5に示すように、本シートにおいて、鼻用切り込み部24と、口用開口部26と、顔用切り込み部28が実現される。   FIG. 5 shows a front view of the present sheet 310 including the nasal cut portion 24, the mouth opening portion 26, and the facial cut portion 28. The first sheet member 12 and the second sheet member 16 (not shown) are each fitted with a nasal cutout 24, a mouth opening 26, and facial cutouts 28a, 28b, 28a, b so c and d are provided. As a result, as shown in FIG. 5, the nose cut portion 24, the mouth opening portion 26, and the face cut portion 28 are realized in the present sheet at the time of use.

鼻用切り込み部24は、各シート部材の中央近傍に設けられる、上方から下方に緩やかに広がる略U字状の切れ込みである。本シート310を顔面へ貼り付けると、使用者の鼻が鼻用切れ込み部24に囲まれたシート部分を押出し、鼻が本シート310外部から覗かれる。口用開口部26は、各シート部材の下方近傍に設けられる、略楕円形状の開口部である。本シート310を顔面へ貼り付けると、使用者の口が口用開口部26を通じて本シート310外部から覗かれる。顔用切り込み部28は、図5に示すように、各シート部材の周囲の上部(28a、b)及び下部(28c、d)に左右に対となって設けられる、切れ込みである。本シート310を顔面へ貼り付けると、顔用切り込み部28a〜dによって、本シート310が顔面の凹凸に対してより密に当接される。   The nasal cut portion 24 is a substantially U-shaped cut that is provided in the vicinity of the center of each sheet member and gradually spreads downward from above. When this sheet 310 is attached to the face, the user's nose pushes out the sheet portion surrounded by the nasal cut portion 24, and the nose is viewed from the outside of the sheet 310. The mouth opening 26 is a substantially elliptical opening provided in the lower vicinity of each sheet member. When the sheet 310 is attached to the face, the user's mouth is viewed from the outside of the sheet 310 through the mouth opening 26. As shown in FIG. 5, the face cut portions 28 are cuts provided in pairs on the left and right at the upper part (28a, b) and the lower part (28c, d) around each sheet member. When this sheet 310 is affixed to the face, the sheet 310 is brought into closer contact with the unevenness of the face by the face cut portions 28a to 28d.

本シートによると、顔面にシートがフィットし、シートが縒れることなく顔表面全体をシートで覆うことができ、さらに、鼻及び口がシート外部へ通じ、使用時においても呼吸が容易となる。また、鼻表面には、鼻用切れ込み部24に囲まれたシート部分が当接され、水素の付与が可能となる。
図5では、鼻及び口呼吸用として、鼻用切り込み部24及び口用開口部26を備えた本シート310が示されるが、必要に応じて目用の開口部を備えることも考えられる。
According to this sheet, the sheet fits on the face, the entire surface of the face can be covered with the sheet without squeezing, and the nose and mouth communicate with the outside of the sheet, so that breathing is facilitated even during use. Moreover, the sheet | seat part enclosed by the nose cut | notch part 24 contact | abuts on the nose surface, and provision of hydrogen is attained.
In FIG. 5, the present sheet 310 including the nasal notch 24 and the mouth opening 26 is shown for breathing the nose and mouth, but it is also conceivable to include an eye opening as necessary.

次に、その他の好ましい実施形態について各部材等ごとに説明する。
他の実施形態として、第一シート部材12のゲル状材14が塗布されない面(例えば図2(c)の紙面上方)及び第二シート部材16の金属粒子18が塗布されない面(例えば図2(c)の紙面下方)のいずれか一方は、水素不透過又は難透過の素材である構成が挙げられる。第一シート部材12が水素不透過素材等で構成された面を有する場合は第二シート部材16を、第二シート部材16が水素不透過素材等で構成された面を有する場合は第一シート部材12を、顔表面に貼り付けて本シート10を用いると、顔表面側とは反対側の外部への、本シート10から発生した水素の拡散を防止でき、より効率的に水素を顔表面に付与することができる。
Next, other preferred embodiments will be described for each member.
As other embodiments, the surface of the first sheet member 12 to which the gel material 14 is not applied (for example, above the paper surface of FIG. 2C) and the surface of the second sheet member 16 to which the metal particles 18 are not applied (for example, FIG. Any one of (under the paper surface of c)) may be a hydrogen impermeable or hardly permeable material. When the first sheet member 12 has a surface made of a hydrogen-impermeable material or the like, the second sheet member 16 is used, and when the second sheet member 16 has a surface made of a hydrogen-impermeable material or the like, the first sheet. When the sheet 12 is used with the member 12 attached to the face surface, diffusion of hydrogen generated from the sheet 10 to the outside opposite to the face surface side can be prevented, and hydrogen can be more efficiently transferred to the face surface. Can be granted.

他の実施形態として、第一シート部材12表面上又は第二シート部材16表面上に通気性かつ溶媒非浸透性のフィルム(一例として、ポリ塩化ビニリデン)を備えるものが挙げられる。本構成のシートでは、ゲル状材14と金属粒子18との接触がフィルムで挟まれることでより密となり、また、フィルム第一シート部12又は第二シート部16の素材を溶媒浸透性によらず任意に選択可能である。   As another embodiment, a film provided with a gas-permeable and solvent-impermeable film (for example, polyvinylidene chloride) on the surface of the first sheet member 12 or the surface of the second sheet member 16 can be mentioned. In the sheet having this configuration, the contact between the gel material 14 and the metal particles 18 becomes denser by being sandwiched between the films, and the material of the film first sheet portion 12 or the second sheet portion 16 is made to be solvent permeable. Any selection is possible.

他の実施形態として、図6の第二シート部材の断面図(図1(b)におけるB-B断面図)に示すように、第二シート部材16が、溶媒浸透性素材と溶媒非浸透性素材の2層構造であるものが挙げられる。第二シート部材16の上層(紙面上方)は溶媒を浸透する浸透部30、下層は溶媒を浸透させない非浸透部32で構成され、金属粒子18は、浸透部30の上面に塗布又は内部に含まれている。本構成のシートでは、第一シート部材12を第二シート部材16の浸透部30に当接すると、ゲル状材14は、浸透部30の上面及び内部に行き渡り金属粒子18と接触するが、非浸透部32よりも下方へは移動できない。従って、本シートの使用時に、反応を効果的に行いつつ、ゲル状材14が本シートの外部へと漏れ出すことを防止できる。   As another embodiment, as shown in the sectional view of the second sheet member in FIG. 6 (BB sectional view in FIG. 1B), the second sheet member 16 is made of a solvent permeable material and a solvent non-permeable material. What has a two-layer structure is mentioned. The upper layer (above the paper surface) of the second sheet member 16 is composed of a permeation portion 30 that permeates the solvent, and the lower layer is composed of a non-permeation portion 32 that does not permeate the solvent, and the metal particles 18 are applied to or included in the top surface of the permeation portion 30. It is. In the sheet having this configuration, when the first sheet member 12 is brought into contact with the permeation portion 30 of the second sheet member 16, the gel material 14 spreads over the upper surface and the inside of the permeation portion 30 and comes into contact with the metal particles 18. It cannot move below the infiltration portion 32. Therefore, it is possible to prevent the gel material 14 from leaking out of the sheet while effectively performing a reaction when the sheet is used.

他の実施形態として、ゲル状材14は、冷感成分又は匂い成分を備える構成が挙げられる。ゲル状材14が、例えばメントール等の冷感成分を備えていると、使用者は本シートを使用時に、顔表面に貼り付ける第一シート部材12又は第二シート部材14からひんやりとした感覚を得ることが可能となる。また、ゲル状材14が、匂い成分を備えていると、使用者は本シートを使用時に、該匂い成分が第一シート部材12又は第二シート部材14を通過して使用者の顔表面上の鼻を刺激し、匂い成分を任意とすることで所望の匂いを得ることができる。   As another embodiment, the gel material 14 includes a configuration including a cooling sensation component or an odor component. When the gel-like material 14 includes a cooling sensation component such as menthol, the user feels a cool sensation from the first sheet member 12 or the second sheet member 14 applied to the face surface when the sheet is used. Can be obtained. Further, when the gel material 14 includes an odor component, when the user uses the sheet, the odor component passes through the first sheet member 12 or the second sheet member 14 and is on the user's face surface. The desired odor can be obtained by stimulating the nose and making the odor component optional.

他の実施形態として、金属粒子18は、金属そのものの粒子に限らず、金属を粒状若しくは粉末状としたもの、金属を任意の立体形状としたもの、非反応物(例えば球状物やシート状物)の表面に金属を固定したもの、又はこれらを組み合わせた構成が自由に選択され得る。一例として、プラスチックやセラミック等の球状物の表面に金属の粒子を焼き付けて固定したものを、第二シート部材に複数備える構成が挙げられる。本構成によると、必要な金属が少量でよく、かつゲル状材14との反応時に金属が凝集するなどして所望の反応速度が達成できないことを防止し、安定した水素発生が可能となる。   As other embodiments, the metal particles 18 are not limited to particles of the metal itself, but the metal is in a granular or powder form, the metal is in an arbitrary three-dimensional shape, or a non-reacted material (for example, a spherical object or a sheet-like object). A structure in which a metal is fixed to the surface of the above or a combination of these may be freely selected. As an example, the structure which equips the 2nd sheet | seat member with what fixed | baked and fixed the metal particle on the surface of spherical objects, such as a plastics and a ceramic, is mentioned. According to this configuration, a small amount of metal is required, and it is possible to prevent a desired reaction rate from being achieved due to the aggregation of the metal during the reaction with the gel material 14, and stable hydrogen generation is possible.

10 水素発生式フェイスシート(本シート)
12 第一シート部材
14 ゲル状材
16 第二シート部材
18 金属粒子
20 折り目部
22 耳あて部材
24 鼻用切れ込み部
26 口用開口部
28a、b、c、d 顔用切れ込み部
30 浸透部
32 非浸透部
110 水素発生式フェイスシート(本シート)
210 水素発生式フェイスシート(本シート)
310 水素発生式フェイスシート(本シート)
10 Hydrogen generation face sheet (this sheet)
12 1st sheet member 14 Gel-like material 16 2nd sheet member 18 Metal particle 20 Crease part 22 Ear contact member 24 Nose cut part 26 Opening part 28a, b, c, d Face cut part 30 Penetration part 32 Non Penetration part 110 Hydrogen generation type face sheet (this sheet)
210 Hydrogen generation face sheet (this sheet)
310 Hydrogen generation face sheet (this sheet)

Claims (5)

少なくとも可撓性を有するシート形状の第一シート部材と、一部または全部が不織布からなる可撓性を有するシート形状の第二シート部材とを備え、
前記第一シート部材の表面には、水を組成に含むゲル状材が塗布されており、
前記第二シート部材の表面には、水と反応することにより水素を発生させる金属粒子が予め含まれ又は塗布されており、
前記第一シート部材の表面と前記第二シート部材の表面とは、当接可能である、
ことを特徴とする、
水素発生式フェイスシート。
A sheet-shaped first sheet member having at least flexibility, and a flexible sheet-shaped second sheet member partially or entirely made of a nonwoven fabric,
On the surface of the first sheet member, a gel material containing water in the composition is applied,
The surface of the second sheet member contains or is coated beforehand with metal particles that generate hydrogen by reacting with water,
The surface of the first sheet member and the surface of the second sheet member can be contacted,
It is characterized by
Hydrogen generation face sheet.
前記金属粒子としてカルシウムを含む、
ことを特徴とする、
請求項1に記載の水素発生式フェイスシート。
Containing calcium as the metal particles,
It is characterized by
The hydrogen generating face sheet according to claim 1.
前記金属粒子としてアルミニウム又はマグネシウムを含む、
ことを特徴とする、
請求項1に記載の水素発生式フェイスシート。
Containing aluminum or magnesium as the metal particles,
It is characterized by
The hydrogen generating face sheet according to claim 1.
前記第一シート部材と前記第二シート部材とは、連結して一枚のシート状に形成され、
第一シート部材と第二シート部材との境界近傍に、折り曲げることで、前記第一シート部材の表面又は裏面と前記第二シート部材の金属粒子側とを当接可能な折り目部を備える
ことを特徴とする、
請求項1〜3のいずれか1項に記載の水素発生式フェイスシート。
The first sheet member and the second sheet member are connected to form a single sheet,
A crease portion is provided in the vicinity of the boundary between the first sheet member and the second sheet member so that the front surface or the back surface of the first sheet member can be brought into contact with the metal particle side of the second sheet member. Features
The hydrogen generating face sheet according to any one of claims 1 to 3.
前記ゲル状材が、所望の匂い成分を組成に含む、
ことを特徴とする、
請求項1〜4のいずれか1項に記載の水素発生式フェイスシート。
The gel material contains a desired odor component in the composition,
It is characterized by
The hydrogen generating face sheet according to any one of claims 1 to 4.
JP2018543870A 2016-10-04 2017-09-29 Hydrogen generation face sheet Pending JPWO2018066466A1 (en)

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Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2007501286A (en) * 2003-06-11 2007-01-25 ザ プロクター アンド ギャンブル カンパニー Ready-to-use devices containing preformed hydrogel products
JP2015218124A (en) * 2014-05-15 2015-12-07 株式会社エムジェイ Cosmetic
JP2016525525A (en) * 2013-07-22 2016-08-25 ロレアル Kit for whitening the user's body surface, associated methods and processes

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100787413B1 (en) * 2005-05-25 2007-12-21 강장옥 Method for making mask pack comprising acorn gel of porous type
US20080292541A1 (en) * 2005-11-10 2008-11-27 Hiromaito Co. Ltd. Hydrogen Generating Agent and Use Thereof
JP6046936B2 (en) * 2012-07-23 2016-12-21 クラシエホームプロダクツ株式会社 Hydrogen generating cloth, hydrogen generating paper, and production method thereof
JP6081729B2 (en) * 2012-07-31 2017-02-15 クラシエホームプロダクツ株式会社 Hydrogen generating composition
JP2014084233A (en) * 2012-10-19 2014-05-12 Seiji Endo Dry sheet for generating hydrogen
JP2015107928A (en) * 2013-12-04 2015-06-11 株式会社タイキ Carbonic acid generating sheet
JP2015199672A (en) * 2014-04-04 2015-11-12 株式会社 ナチュラル Manufacturing method of hydrogen cream containing reduction fine powder
CN204193090U (en) * 2014-10-28 2015-03-11 友荃科技实业股份有限公司 Oxyhydrogen beauty care mask

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2007501286A (en) * 2003-06-11 2007-01-25 ザ プロクター アンド ギャンブル カンパニー Ready-to-use devices containing preformed hydrogel products
JP2016525525A (en) * 2013-07-22 2016-08-25 ロレアル Kit for whitening the user's body surface, associated methods and processes
JP2015218124A (en) * 2014-05-15 2015-12-07 株式会社エムジェイ Cosmetic

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