JPWO2015005272A1 - Transparent cleansing composition - Google Patents

Abstract

Cleansing composition, component (A): nonionic surfactant with HLB of 1 or more and 12 or less, component (B): nonionic surfactant with HLB of more than 12 and 20 or less, component (C): A liquid oil at 20 ° C., component (D): at least one water-soluble solvent component selected from the group consisting of glycols, glycerols, sugars and sugar alcohols, and component (E): water, The total content of the component (A) and the component (B) is 10 to 40% by mass, the content of the component (C) is 10 to 35% by mass, and the component (D) with respect to the total mass of the cleansing composition. Is 15 to 45 mass%, the content of component (E) is 20 to 60 mass%, and the total content of component (D) and component (E) is 40 to 75 mass%, and The total content of components (A) to (E) is 100% by mass. Not exceed, is the mass ratio of the component (A) and component (B) (A) :( B), 9: 1~4: 6, and a transparent, cleansing compositions.

Description

The present invention relates to a transparent cleansing composition.
This application claims priority on July 12, 2013 based on Japanese Patent Application No. 2013-146025 for which it applied to Japan, and uses the content here.

Conventionally, preparations intended to dissolve and remove makeup cosmetics with oils include aqueous cleansing liquids in which surfactants are used as emulsifiers in water and water-soluble ingredients, and oils in nonionic surfactants in water. Emulsified type emulsions such as emulsions and creams; Oil gel type formulations in which oils are retained with liquid crystal as a surfactant structure; Nonionic surfactants are added as emulsifiers and dissolved in oils Oil-type preparations.

The makeup cosmetics to be cleaned by the cleansing composition are mainly composed of an oil component, and the cleansing power is exhibited by the oil agent and the surfactant blended in the cleansing composition.
In recent years, makeup cosmetics that are difficult to fall off, such as waterproof mascara, have become popular. However, waterproof mascara forms a film to which wax is fixed, and may not be removed unless dissolved with oil. Aqueous cleansing liquid has a good feeling when used and rinsed, but has a problem that the cleansing power is weak and the remaining moist feeling is difficult to feel. In an emulsified type preparation, the oil is finely and stably dispersed in the aqueous phase, so that the original cleaning power of the oil cannot be exhibited and the cleansing power may not be sufficient. Oil-type preparations have the highest cleansing power because oil acts directly on dirt, but may be oily and remain oily during use and rinsing. In addition, since the cleaning power is strong, sebum may be removed excessively, and a feeling of bulkiness may be felt after cleaning. Further, a preparation containing a large amount of oil to enhance the cleansing power may become cloudy as if a film is stretched when it enters the eye. Further, a preparation in which an oily component, an aqueous component, and a surfactant are blended at the same time is often unstable in storage stability, and an odor may be generated over time, so further investigation is necessary.

Patent Document 1 reports a one-phase cleansing composition with improved stretch, containing two types of nonionic surfactants having different HLBs, a water-soluble compound having a hydroxyl group, a liquid oil and water. Yes. However, such cleansing compositions require further consideration to maintain stability. Moreover, the blending ratio of the oil agent is high, the composition itself has an oily feeling, the oily feeling during use is strong, and an oil film may be formed when it enters the eyes.

Patent Document 2 reports that a detergent composition comprising a combination of two types of non-aqueous surfactants, an oil agent, and a polar organic solvent has a large stable temperature range. However, since this composition does not contain water, it is difficult to obtain a clean feeling as a cleansing composition at the time of washing away, and an oil film may be formed when it enters the eyes.

Patent Document 3 describes a one-phase microemulsion composition that contains two types of nonionic surfactants, an oil component, a specific aqueous solvent, and water, and is stable over a wide temperature range. However, when this microemulsion composition is used as a cleansing composition, in makeup cosmetics other than silicone-based makeup, the cleaning power may not be sufficient, and rinsing may leave a silicone feel.

Patent Documents 4 and 5 disclose a liquid crystal composition (liquid crystal phase or isotropic surfactant continuous phase) containing a nonionic surfactant, a water-soluble substance or polar oil having a hydroxyl group, silicone oil, and water. Cosmetics for makeup removal using is described. The makeup remover is well-suited for makeup and has a high makeup-removing effect. However, it may not be satisfactory enough to remove makeup that is difficult to remove, such as a waterproof mascara, and further investigation is required. It is.

Patent Documents 6 and 7 describe a transparent solubilized composition of an oil component containing a sucrose fatty acid ester having good stability in a certain temperature range, but the temperature range is not sufficiently wide and is rinsed. May not provide a refreshing feeling.

In this way, oil-type makeup removers and oil gel-type makeup removers that create liquid crystal structures have weaknesses, and some of the conventionally known cleansing compositions do not have an oily feel during use. Ranging that doesn't feel oil film even if it gets into your eyes, can be washed cleanly without residual feeling, has a moist feeling after cleansing, has sufficient cleansing power for makeup that is hard to remove, such as a waterproof mascara, and also satisfies stability There was no composition.

Japanese Patent Laid-Open No. 4-5213 JP-A-6-293617 JP-A-2005-193134 JP 2000-256124 A JP 2000-256132 A Japanese Patent No. 3360341 Japanese Patent No. 3760516

The purpose of the present invention is that there is no oily feeling during use, it is difficult to feel an oil film even if it mixes with the eyes, it can be washed cleanly without residual feeling, it has a moist feeling after cleansing, and it is a makeup type that is difficult to remove such as a waterproof type mascara An object of the present invention is to provide a cleansing composition having a sufficient cleansing power against the above and having excellent stability.

By using a combination of specific two types of nonionic surfactant, oil agent, water-soluble solvent component and water in a specific ratio, the present inventors have no oiliness during use and may mix with eyes. It is difficult to feel oil film, can be washed cleanly without residual feeling, has a moist feeling after cleansing, and has a cleansing composition that has sufficient cleansing power for makeup that is difficult to remove, such as a waterproof mascara, and has excellent stability. I found out.

That is, the first invention of the present invention comprises the following components (A), (B), (C), (D), and (E):
(A) a nonionic surfactant having an HLB of 12 or less,
(B) a nonionic surfactant greater than HLB 12,
The total content of component (A) and component (B) is 10 to 40% by mass,
(C) 10 to 35% by mass of a liquid oil agent at 20 ° C.,
(D) 15 to 45% by mass of a water-soluble solvent component selected from glycols, glycerins, saccharides and sugar alcohols,
(E) Water 20-60 mass%
The mass ratio of components (A) and (B) is (A) :( B) = 9: 1 to 4: 6, and the total content of components (D) and (E) is 40. It is a transparent cleansing composition which is -75 mass%.

The second invention of the present invention is the cleansing composition according to the first invention, wherein the components (A) and (B) are polyoxyethylene-based nonionic surfactants.

3rd invention of this invention is a cleansing composition as described in 1st or 2nd invention whose component (A) and (B) is polyoxyethylene glycerol fatty acid ester.

According to a fourth aspect of the present invention, in any one of the first to third aspects, the component (C) includes one or more liquid oils having a viscosity at 20 ° C. of 35 mPa · s or less. A cleansing composition.

  According to a fifth aspect of the present invention, the liquid oil agent of component (C) is an ester oil agent containing a branched fatty acid residue having 6 or more carbon atoms and / or a branched aliphatic alcohol residue having 6 or more carbon atoms. It is a cleansing composition according to any one of the first to fourth inventions, characterized by containing at least one species.

  In a sixth aspect of the present invention, any one of the first to fifth aspects, wherein the component (D) is one or more selected from propylene glycol, dipropylene glycol, 1,3-butylene glycol, glycerin, sorbitol, xylitol, and erythritol. It is a cleansing composition as described in 1 invention.

  In the seventh invention of the present invention, 0.001 to 1% by mass of an organic acid as a component (F) and 0.001 to 1 of an organic acid salt composed of an organic acid and a monovalent alkali metal as a component (G). The cleansing composition according to any one of the first to sixth inventions, wherein the cleansing composition contains 5% by mass and the ratio of the component (F) to the component (G) is 5:95 to 5: 5.

That is, the present invention relates to the following.
[1] A cleansing composition,
The cleansing composition comprises:
Component (A): Nonionic surfactant having an HLB of 1 or more and 12 or less, Component (B): Nonionic surfactant having an HLB of more than 12 and 20 or less, Component (C): An oil agent liquid at 20 ° C. Component (D): at least one water-soluble solvent component selected from the group consisting of glycols, glycerins, sugars and sugar alcohols, and component (E): water,
For the total mass of the cleansing composition,
The total content of the component (A) and the component (B) is 10 to 40% by mass,
The content of the component (C) is 10 to 35% by mass,
The content of the component (D) is 15 to 45% by mass,
The content of the component (E) is 20 to 60% by mass, the total content of the component (D) and the component (E) is 40 to 75% by mass, and
The total content of component (A) to component (E) does not exceed 100% by mass,
(A) :( B) which is a mass ratio of the component (A) and the component (B) is 9: 1 to 4: 6,
A cleansing composition that is transparent.
[2] The cleansing composition according to [1], wherein the component (A) and the component (B) are polyoxyethylene-based nonionic surfactants.
[3] The cleansing composition according to [1] or [2], wherein the component (A) and the component (B) are polyoxyethylene glycerin fatty acid esters.
[4] The cleansing composition according to any one of [1] to [3], wherein the component (C) includes at least one liquid oil having a viscosity at 20 ° C. of 1 mPa · s to 35 mPa · s. object.
[5] The component (C) is at least one selected from the group consisting of branched fatty acid residues having 6 to 22 carbon atoms and branched fatty alcohol residues having 6 to 22 carbon atoms. The cleansing composition according to any one of [1] to [4], comprising at least one ester oil agent comprising one residue.
[6] Component (D) is at least one water-soluble solvent component selected from the group consisting of propylene glycol, dipropylene glycol, 1,3-butylene glycol, glycerin, sorbitol, xylitol, and erythritol [1] -The cleansing composition as described in any one of [5].
[7] Further, component (F): an organic acid is 0.001 to 1% by mass relative to the total mass of the cleansing composition, and component (G): an organic acid salt composed of an organic acid and a monovalent alkali metal. Is 0.001 to 1% by mass with respect to the total mass of the cleansing composition, and (F) :( G) is a mass ratio of component (F) and component (G) from 5:95 to 5: 5. The cleansing composition according to any one of [1] to [6], which is 5.

The cleansing composition of the present invention does not feel oily during use, it is difficult to feel an oil film even if it is mixed with eyes, it can be washed cleanly without residual feeling, it has a moist feeling after cleansing, and a drop of waterproof type mascara etc. This cleansing composition has sufficient cleansing power for difficult makeup and has excellent stability.

The nonionic surfactant of component (A) used in the present invention is a nonionic surfactant having an HLB of 1 or more and 12 or less. Preferably it is 8-12, More preferably, it is 9-12. The nonionic surfactant is preferably a polyoxyethylene nonionic surfactant.
Here, “HLB (Hydrophilic Lipophilic Balance)” is an index indicating the molecular weight of the hydrophilic group portion in the total molecular weight of the surfactant, and the polyoxyethylene-based nonionic surfactant is represented by the following formula: This is a value obtained from the Griffin equation of (1).

The “E used in the formula (1)” means the mass% of the polyoxyethylene moiety contained in the surfactant molecule with respect to the total mass of the surfactant molecule, and the component ( Different from E).

Moreover, the measurement of the HLB value of nonionic surfactants (for example, polyglycerin fatty acid ester, sucrose ester, etc.) other than polyoxyethylene-based nonionic surfactant is the atlas method of the following formula (2). Can be calculated.

“A used in the formula (2)” means the acid value (g / mg KOH) of the fatty acid constituting the nonionic surfactant and is different from the component (A) of the present invention.

Specific examples of the nonionic surfactant of component (A) include polyglycerin fatty acid esters such as diglyceryl oleate and diglyceryl isostearate; polyglyceryl esters such as diglycerin 2-ethylhexyl ether and isostearyl glyceryl ether. Glycerin alkyl ether; Polyoxyethylene fatty acid ester such as polyoxyethylene (5) monostearate; Polyoxyethylene glycerin such as polyoxyethylene (8) glyceryl monoisostearate and polyoxyethylene (20) glyceryl triisostearate Examples include fatty acid esters. Among these nonionic surfactants having an HLB of 1 or more and 12 or less, nonionic surfactants having an HLB of 1 or more and 12 or less that are liquid at 20 ° C. can be suitably used, and polyglycerin fatty acid esters such as diglyceryl isostearate; (8) Polyoxyethylene glycerin fatty acid esters such as glyceryl monoisostearate and polyoxyethylene (20) glyceryl triisostearate are preferred, and polyoxyethylene glycerin fatty acid esters are more preferred.
In addition, the number shown in the parenthesis in the above compound name indicates the average added mole number of ethylene oxide.

The nonionic surfactant of component (B) used in the present invention is a nonionic surfactant having an HLB of more than 12 and 20 or less. Preferably HLB is 13-20, More preferably, it is 13-18, Most preferably, it is 13-16. The nonionic surfactant as component (B) is preferably a polyoxyethylene nonionic surfactant having an HLB of more than 12 and 20 or less.
Specific examples of nonionic surfactants having an HLB of more than 12 and 20 or less include polyoxyethylene fatty acid esters such as polyoxyethylene (12) monolaurate and polyoxyethylene (12) monoisostearate; Polyoxyethylene sorbitan fatty acid esters such as oxyethylene (20) sorbitan monooleate; Polyoxyethylene sorbitol fatty acid esters such as polyoxyethylene (60) sorbitol tetraoleate; Polyoxyethylene such as polyoxyethylene (20) octyldodecyl ether Alkyl ethers; polyoxyethylene hydrogenated castor oil derivatives such as polyoxyethylene (60) hydrogenated castor oil; polyoxyethylene glycerin fatty acid esters such as polyoxyethylene (20) glycerol monoisostearate; Sucrose fatty acid esters such as stearic acid ester.
Among these nonionic surfactants having an HLB of more than 12 and 20 or less, nonionic surfactants having a liquid HLB of more than 12 and 20 or less at 20 ° C. can be suitably used, and polyoxyethylene (12) monoisostearate Polyoxyethylene fatty acid esters such as rate; Polyoxyethylene sorbitan fatty acid esters such as polyoxyethylene (20) sorbitan monooleate; Polyoxyethylene sorbitol fatty acid esters such as polyoxyethylene (60) sorbitol tetraoleate; Polyoxyethylene ( 20) Polyoxyethylene glycerin fatty acid esters such as glycerin monoisostearate are preferred, and polyoxyethylene glycerin fatty acid esters are more preferred.
In addition, the number shown in the parenthesis in the above compound name indicates the average added mole number of ethylene oxide. As used herein, “average number of added moles” has the same meaning as described above.

At least one component can be used for each of the component (A) and the component (B), and the total content of the component (A) and the component (B) is 10 to 40 with respect to the total mass of the cleansing composition. % By mass. Especially, it is preferable to contain 15-35 mass%, and it is more preferable to contain 15-23 mass%. When the total content of the component (A) and the component (B) is less than the above range, the resulting cleansing composition becomes cloudy and has poor stability and poor cleansing power, and the components (A) and (B). If the total content is more than the above range, the resulting cleansing composition is nullified and feels oily, resulting in poor moist feeling after washing.

The mass ratio of the component (A) and the component (B) is (A) :( B) (that is, the mass of the component (A): the mass of the component (B)) = 9: 1 to 4: 6. (A) :( B) is preferably 9: 1 to 6: 4, and more preferably 8.5: 1.5 to 7: 3. The effect of this invention is exhibited because the ratio of a component (A) and a component (B) exists in this range.

The oil of component (C) used in the present invention is liquid at 20 ° C.
The term “liquid” as used herein refers to a state indicating the properties of a Newtonian fluid having a viscous property in which the flow shear stress (tangential stress) and the flow velocity gradient (ie, shear rate and shear rate) are proportional. means.
“Oil agent” is a hydrophobic substance that is phase-separated from water and generally means a flammable substance.
As such an oil agent, liquid oils usually used in cosmetics can be used. For example, hydrocarbon oils such as liquid paraffin, light liquid isoparaffin, hydrogenated polyisobutene, squalane; isostearic acid cholesteryl ester, isopropyl palmitate, myristin Isopropyl acid, isopropyl isostearate, octadecyl myristate, isononyl isononanoate, isotridecyl isononanoate, ethylhexyl palmitate, cetyl 2-ethylhexanoate, neopentyl glycol diethylhexanoate, neopentyl glycol dicaprate, tri (2-ethylhexanoate) ) Glycerol, tri (caprylic acid / capric acid) glycerin, glycerin triisostearate, trimethylolpropane triisostearate, tetra 2-ethyl Pentaerythrityl hexanoate, pentaerythrityl tetraisostearate, diglyceryl tetraisostearate, di (capryl / capric acid) propanediol, propanediol diisostearate, polyglyceryl 6-octaprylate, octyldodecyl lactate, diisostearyl malate , Ester oils such as diglyceryl triisostearate, erythrityl tri-2-ethylhexanoate, dipentaerythritol tripolyhydroxystearate, trehalose esters of isostearate, dipentaerythrityl pentaisostearate, 2-ethylhexyl hydroxystearate, polyhydroxystearic acid; alkyl- Ether oils such as 1,3-dimethylbutyl ether and nonylphenyl ether; decamethylcyclopen It can be used terpene oil; siloxane, methyl cyclo polysiloxanes such as octamethylcyclotetrasiloxane, methylpolysiloxane, silicone oils such as methyl phenyl polysiloxane; animal and vegetable oils, such as olive oil.

  Content of the oil agent of a component (C) is 10-35 mass% with respect to the total mass of a cleansing composition, Preferably it is 10-30 mass%, More preferably, it is 12-20 mass%. When the component (C) is less than 10% by mass, the cleansing composition has a non-uniform appearance and poor cleansing power, and when it exceeds 35% by mass, the cleansing composition has a strong oily feeling. When entering, it is difficult to feel an oil film, and separation occurs over time, resulting in a cleansing composition with poor stability.

The liquid oil agent of component (C) has a viscosity at 20 ° C. of 1 mPa · s to 35 mPa · s, preferably 1 mPa · s to 25 mPa · s, more preferably 1 mPa · s to 20 mPa · s. It is preferable that at least one liquid oil agent is included.
Here, “viscosity” means a value measured with a BM viscometer (for example, manufactured by Toki Sangyo Co., Ltd., measurement conditions: rotor No. 1, 60 rpm). In the present invention, the viscosity is defined as a value at 20 ° C. unless otherwise specified, and even when the viscosity is outside the range specified in this specification, the viscosity is corrected to the value at 20 ° C. in this specification. Any viscosity value within the specified range is included in the scope of the present invention.
By blending such a low-viscosity oil, the cleansing composition of the present invention improves the cleansing power and improves the feeling of use.

Examples of liquid oils having a viscosity at 20 ° C. of 1 mPa · s to 35 mPa · s include hydrocarbon oils such as liquid paraffin, light liquid isoparaffin, hydrogenated polyisobutene, and squalane; isopropyl palmitate, isopropyl myristate, isostearin. Isopropyl acid, isononyl isononanoate, isotridecyl isononanoate, ethylhexyl palmitate, cetyl 2-ethylhexanoate, di (2-ethylhexanoic acid) neopentyl glycol, di (capric acid) neopentyl glycol, tri (2-ethylhexanoic acid) ) Ester oils such as glycerin, tri (caprylic acid / capric acid) glycerin, di (capryl / capric acid) propanediol, mecaine such as decamethylcyclopentasiloxane and octamethylcyclotetrasiloxane Le cyclo polysiloxanes, methyl polysiloxanes, and silicone oils such as methyl phenyl polysiloxane. Among them, preferred liquid oils having a viscosity at 20 ° C. of 1 mPa · s to 35 mPa · s include liquid paraffin, light liquid isoparaffin, isononyl isononanoate, isotridecyl isononanoate, ethylhexyl palmitate, cetyl 2-ethylhexanoate, diethyl (2-ethylhexanoic acid) neopentyl glycol or di (capryl / capric acid) propanediol, more preferably isononyl isononanoate, isotridecyl isononanoate, ethylhexyl palmitate, or cetyl 2-ethylhexanoate.

The liquid oil agent of component (C) is at least selected from the group consisting of branched fatty acid residues having 6 to 22 carbon atoms, and branched aliphatic alcohol residues having 6 to 22 carbon atoms. It is preferable to include at least one ester oil having one residue.
The “ester oil agent” in the present invention means an oil agent that contains a compound having an ester structure as a component and is liquid at 20 ° C.
Examples of the branched fatty acid residue having 6 to 22 carbon atoms include isostearic acid residue, isononanoic acid residue, 2-ethylhexanoic acid residue, 2-heptylundecanoic acid residue, and 2-octyldodecanoic acid. Examples include residues.
Examples of the branched aliphatic alcohol residue having 6 to 22 carbon atoms include isononyl alcohol residue, isotridecyl alcohol residue, 2-ethylhexanol residue, 2-heptylundecanol residue, Examples include 2-octyldodecanol residues.
By including such an ester oil agent, it can be set as the cleansing composition excellent in stability, even if it mix | blends an aqueous component highly. Examples of such oils include isopropyl isostearate, isononyl isononanoate, isotridecyl isononanoate, ethylhexyl palmitate, cetyl 2-ethylhexanoate, neopentyl glycol diethylhexanoate, tri (2-ethylhexanoate) glycerin and the like. Among them, isononyl isononanoate, isotridecyl isononanoate, ethylhexyl palmitate, cetyl 2-ethylhexanoate and the like can be suitably used.

The water-soluble solvent component of component (D) used in the present invention is at least one selected from the group consisting of glycols, glycerols, saccharides, and sugar alcohols. Specifically, glycols such as ethylene glycol, propylene glycol, diethylene glycol, dipropylene glycol (hereinafter also referred to as DPG), 1,3-butylene glycol, 1,4-butylene glycol, hexylene glycol, isoprene glycol; Examples thereof include glycerins such as glycerin and diglycerine; sugars such as glucose, fructose, sucrose, trehalose, maltose and maltotriose; sugar alcohols such as sorbitol, maltitol, xylitol, threitol and erythritol. Here, among these water-soluble solvent components, components that are liquid at room temperature (for example, 20 ° C.) can be used as the water-soluble solvent as they are, but at room temperature (for example, 20 ° C.). A solid component, specifically a saccharide, can be used as a water-soluble solvent which is liquid at room temperature (for example, 20 ° C.) by dissolving in water which is a component (E) described later.
“Normal temperature” is a term based on Japanese Industrial Standard and means a temperature of 5 to 35 ° C.
Among these, propylene glycol, dipropylene glycol, 1,3-butylene glycol, glycerin, sorbitol, xylitol, and erythritol are preferable, and dipropylene glycol, glycerin, and sorbitol are more preferable.

At least one component can be used as the component (D), and the content of the component (D) is 15 to 45% by mass, preferably 20 to 40% by mass, particularly preferably based on the total mass of the cleansing composition. Is 25-35 mass%. When the content is in the above range, the resulting cleansing composition is preferable because sufficient cleaning power and stability can be realized. When the content of the component (D) is out of this range, the resulting cleansing composition is separated over time and becomes unstable.

The water of the component (E) used in the present invention is 20 to 60% by mass, preferably 25 to 50% by mass, more preferably 30 to 47% by mass, based on the total mass of the cleansing composition. . When the content is within the above range, the resulting cleansing composition is preferable because it can be washed away with no residual feeling while having sufficient detergency.
When the total content of component (D) and component (E) is 40 to 75 mass%, preferably 50 to 75 mass%, particularly preferably 60 to 72 mass%, based on the total mass of the cleansing composition The resulting cleansing composition is preferred because it provides a feeling of use without oiliness and a washability.

  The contents of the components (A) to (E) used in the present invention have been described so far, but the total content of the components (A) to (E) used in the present invention does not exceed 100% by mass. .

One aspect of the content of component (A) to component (E) used in the present invention described above is as follows:
For the total mass of the cleansing composition,
The total content of component (A) and component (B) is 15 to 35% by mass,
The content of the component (C) is 10 to 30% by mass,
The content of the component (D) is 20 to 40% by mass,
The content of the component (E) is 25 to 50% by mass, and the total content of the component (D) and the component (E) is 50 to 75% by mass, and
The total content of component (A) to component (E) does not exceed 100% by mass,
(A) :( B) which is a mass ratio of a component (A) and a component (B) is 9: 1-6: 4.

In addition, another aspect of the content of the components (A) to (E) used in the present invention described above is as follows:
For the total mass of the cleansing composition,
The total content of component (A) and component (B) is 15 to 23% by mass,
The content of the component (C) is 12 to 20% by mass,
The content of the component (D) is 25 to 35% by mass,
The content of the component (E) is 30 to 47% by mass, and the total content of the component (D) and the component (E) is 60 to 72% by mass, and
The total content of component (A) to component (E) does not exceed 100% by mass,
(A) :( B) which is a mass ratio of a component (A) and a component (B) is 8.5: 1.5-7: 3.

The organic acid of the component (F) used in the present invention is a generic name for organic compounds exhibiting acidity. Among them, lactic acid, citric acid, itaconic acid, succinic acid, fumaric acid, malic acid, tartaric acid and the like can be preferably used. Of these, citric acid, succinic acid, malic acid and tartaric acid are preferable, citric acid and malic acid are more preferable, and citric acid is most preferable.

The organic acid salt of component (G) used in the present invention is a water-soluble salt comprising a neutralized product of an organic acid and an alkali metal used as component (F). Alkali metals are metals of Group 1A of the Periodic Table of Elements, and any of these can be used, but sodium and potassium are particularly preferred.
Specific examples of the organic acid salt of component (G) include sodium lactate, potassium lactate, sodium citrate, potassium citrate, sodium itaconate, potassium itaconate, sodium succinate, potassium succinate, sodium fumarate, Potassium fumarate, sodium malate, potassium malate, sodium tartrate, potassium tartrate and the like can be suitably used.
Among them, sodium citrate, potassium citrate, sodium succinate, potassium succinate, sodium malate, potassium malate, sodium tartrate and potassium tartrate are preferred; sodium citrate, potassium citrate, sodium malate and potassium malate are more preferred. Preferably; sodium citrate and potassium citrate are most preferred.

Content of a component (F) is 0.001-1 mass% with respect to the total mass of a cleansing composition, Preferably it is 0.005-0.5 mass%, More preferably, it is 0.01-0.3 mass. %. Content of a component (G) is 0.001-1 mass% with respect to the total mass of a cleansing composition, Preferably it is 0.005-0.5 mass%, More preferably, it is 0.01-0.3 mass. %. Moreover, (F) :( G) which is a mass ratio of a component (F) and a component (G) is 5: 95-5: 5, Preferably it is 1: 9-4: 6, More preferably, it is 1: 9-3: 7.

Component (F) and component (G) used in the present invention are blended in the above-described content and mass ratio (mass ratio), thereby improving the storage stability of the resulting cleansing composition, and particularly generating odor. Highly effective to suppress.

  Although content of the component (F) and component (G) used for this invention has been demonstrated, in this invention, when using a component (F) and a component (G), the sum total of a component (A) -component (G) The content does not exceed 100% by weight.

In the present invention, when the component (F) and the component (G) are used, one aspect of the content of the components (A) to (G) used in the present invention is as follows:
For the total mass of the cleansing composition,
The total content of component (A) and component (B) is 15 to 35% by mass,
The content of the component (C) is 10 to 30% by mass,
The content of the component (D) is 20 to 40% by mass,
The content of the component (E) is 25 to 50% by mass, and the total content of the component (D) and the component (E) is 50 to 75% by mass,
The content of the component (F) is 0.005 to 0.5 mass%, the content of the component (G) is 0.005 to 0.5 mass%, and
The total content of component (A) to component (G) does not exceed 100% by mass,
(A) :( B) which is a mass ratio of a component (A) and a component (B) is 9: 1-6: 4,
(F) :( G) which is a mass ratio of a component (F) and a component (G) is 1: 9-4: 6.

In the present invention, when the component (F) and the component (G) are used, another aspect of the content of the components (A) to (G) used in the present invention is as follows:
For the total mass of the cleansing composition,
The total content of component (A) and component (B) is 15 to 23% by mass,
The content of the component (C) is 12 to 20% by mass,
The content of the component (D) is 25 to 35% by mass,
The content of the component (E) is 30 to 47% by mass, and the total content of the component (D) and the component (E) is 60 to 72% by mass,
The content of the component (F) is 0.01 to 0.3% by mass, the content of the component (G) is 0.01 to 0.3% by mass, and
The total content of component (A) to component (G) does not exceed 100% by mass,
(A) :( B) which is a mass ratio of the component (A) and the component (B) is 8.5: 1.5 to 7: 3,
(F) :( G) which is a mass ratio of a component (F) and a component (G) is 1: 9-3: 7.

In the cleansing composition of the present invention, as other components, components commonly used for skin-acceptable cleaning agents, for example, skin-acceptable thickeners, bactericides, moisturizers, wetting agents , Coloring agents, preservatives, feel improvers, fragrances, anti-inflammatory agents, whitening agents, antiperspirants, ultraviolet absorbers, antioxidants, various extracts, and the like can be appropriately contained. Moreover, a semi-solid or solid oil component at 20 ° C. can be blended as long as the effects of the present invention are not impaired.
As content of another component, 0.0001-10 mass% is preferable with respect to the total mass of a cleansing composition.

  Although content of the other component used for this invention has been demonstrated, in this invention, when using the other component mentioned above other than a component (A)-component (E), component (A)-component (E) ) And other components described above do not exceed 100 mass%.

In the present invention, when using the component (A) to the component (E) and the other component, one aspect of the content of the component (A) to the component (E) and the other component is:
For the total mass of the cleansing composition,
The total content of component (A) and component (B) is 15 to 35% by mass,
The content of the component (C) is 10 to 30% by mass,
The content of the component (D) is 20 to 40% by mass,
The content of the component (E) is 25 to 50% by mass,
When the total content of the component (D) and the component (E) is 50 to 75% by mass, and the other component is used, the content of the other component is 0.0001 to 10% by mass, and ,
The total content of component (A) to component (E) and the other components does not exceed 100% by mass,
(A) :( B) which is a mass ratio of a component (A) and a component (B) is 9: 1-6: 4.

In the present invention, when using the component (A) to the component (E) and the other component, another aspect of the content of the component (A) to the component (E) and the other component is as follows:
For the total mass of the cleansing composition,
The total content of component (A) and component (B) is 15 to 23% by mass,
The content of the component (C) is 12 to 20% by mass,
The content of the component (D) is 25 to 35% by mass,
The content of the component (E) is 30 to 47% by mass, the total content of the component (D) and the component (E) is 60 to 72% by mass, and the content of the other components is 0.0001 to 10%. Mass%, and
The total content of component (A) to component (E) and the other components described above does not exceed 100% by mass,
(A) :( B) which is a mass ratio of a component (A) and a component (B) is 8.5: 1.5-7: 3.

  Moreover, in this invention, when using the other component mentioned above other than a component (A)-component (G), the total content of a component (A)-component (G) and the other component mentioned above is 100. Does not exceed mass%.

In the present invention, when using the component (A) to the component (G) and the other component, one aspect of the content of the component (A) to the component (G) and the other component is:
For the total mass of the cleansing composition,
The total content of component (A) and component (B) is 15 to 35% by mass,
The content of the component (C) is 10 to 30% by mass,
The content of the component (D) is 20 to 40% by mass,
The content of the component (E) is 25 to 50% by mass, and the total content of the component (D) and the component (E) is 50 to 75% by mass,
When the content of the component (F) is 0.005 to 0.5% by mass, the content of the component (G) is 0.005 to 0.5% by mass, and the above other components, The content of the component is 0.0001 to 10% by mass, and
The total content of component (A) to component (G) and the other components described above does not exceed 100% by mass,
(A) :( B) which is a mass ratio of a component (A) and a component (B) is 9: 1-6: 4,
It is preferable that (F) :( G) which is a mass ratio of a component (F) and a component (G) is 1: 9-4: 6.

In the present invention, when the component (A) to the component (G) and the other component are used, another aspect of the content of the component (A) to the component (G) and the other component is as follows:
For the total mass of the cleansing composition,
The total content of component (A) and component (B) is 15 to 23% by mass,
The content of the component (C) is 12 to 20% by mass,
The content of the component (D) is 25 to 35% by mass,
The content of the component (E) is 30 to 47% by mass, and the total content of the component (D) and the component (E) is 60 to 72% by mass,
When the content of the component (F) is 0.01 to 0.3% by mass, the content of the component (G) is 0.01 to 0.3% by mass, and the above-mentioned other components, The content of the component is 0.0001 to 10% by mass, and
The total content of component (A) to component (G) and the other components described above does not exceed 100% by mass,
(A) :( B) which is a mass ratio of the component (A) and the component (B) is 8.5: 1.5 to 7: 3,
(F) :( G) which is a mass ratio of a component (F) and a component (G) is 1: 9-3: 7.

The cleansing composition of the present invention can be produced by mixing the components (A) to (E) described above. When the component (F), the component (G) and other components are further used as raw materials, these components can also be produced by mixing together with the components (A) to (E). .
In addition, when using raw materials that are solid at room temperature or raw materials that produce gel-like components by mixing at room temperature, all the raw materials are either heated or melted or dissolved in other components. Can be manufactured by uniformly mixing.
The term “uniformly mixed” as used herein means that the components are mixed and dispersed so that the composition and concentration are the same regardless of the portion of the Kunzing composition.
What is necessary is just to mix the said mixing by a well-known method using apparatuses, such as a propeller and a paddle, for example, it is preferable to stir at 10-95 degreeC until it mixes uniformly.
Uniform mixing can be determined by, for example, the visual appearance being transparent.
One aspect of the method for producing the cleansing composition of the present invention includes, for example, component (A), component (B) and component (C), component (D) and component (E), and component (F) and It is a manufacturing method of the cleansing composition including adding a component (G) and stirring all the said components and mixing uniformly.
In the manufacturing method, before mixing all the components, among the components (A) to (G), a component that is a solid component at normal temperature or a component that generates a gel component by mixing at normal temperature is heated and melted. Before mixing all the components, it may include dissolving a solid component at normal temperature or a component that has formed a gel-like component by mixing at normal temperature in another component. Moreover, it is preferable to perform the said heat-melting at 40-95 degreeC.

The cleansing composition of the present invention is a transparent cleansing composition. “Transparent” means that when ion-exchanged water is placed in a control with an ultraviolet-visible spectrophotometer and the absorbance is measured with a cell having a wavelength of 660 nm and an optical path length of 1 cm, the absorbance is 0 or more and 0.6 or less.

As a method of using the cleansing composition of the present invention,
Applying the cleansing composition of the present invention to an object to be cleaned, and rinsing the applied cleansing composition with water or wiping with a wipe selected from the group consisting of cotton, paper and cloth. The usage method is mentioned. The method of use may include applying the cleansing composition to an object to be cleaned and then applying the cleansing composition to a portion to be cleaned with a finger or the like. Further, it may include rinsing with water after wiping with the wipe. The method of use may include diluting the cleansing composition with a diluent before applying it to the object to be cleaned, but it is preferable to use the stock solution without diluting. Moreover, in the said usage method, application | coating of the said cleansing composition may include apply | coating directly to the object of washing | cleaning, or apply | coating through cotton or a nonwoven fabric. The diluent is preferably water. The object to be cleaned is preferably skin to which makeup cosmetics are applied, and the makeup cosmetics are more preferably makeup cosmetics including a waterproof mascara.
Although the usage-amount per wash of the cleansing composition of this invention is not specifically limited, It is 25 mg-250 mg per 1 cm < ² > of the said washing | cleaning objects, More preferably, it is 50 mg-125 mg. In addition, the time taken for each washing is usually 0.5 to 10 minutes, and preferably 1 to 5 minutes.

Other aspects of the invention include:
A cleansing composition comprising:
The cleansing composition comprises:
Component (A): Nonionic surfactant having an HLB of 1 or more and 12 or less, Component (B): Nonionic surfactant having an HLB of more than 12 and 20 or less, Component (C): An oil agent liquid at 20 ° C. Component (D): At least one water-soluble solvent component selected from the group consisting of glycols, glycerins, sugars and sugar alcohols, Component (E): Water, Component (F): Organic acid, and Component (G ): An organic acid salt composed of an organic acid and a monovalent alkali metal,
For the total mass of the cleansing composition,
The total content of the component (A) and the component (B) is 10 to 40% by mass,
The content of the component (C) is 10 to 35% by mass,
The content of the component (D) is 15 to 45% by mass,
The content of the component (E) is 20 to 60% by mass,
The total content of component (D) and component (E) is 40 to 75% by mass,
The content of the component (F) is 0.001 to 1% by mass, the content of the component (G) is 0.001 to 1% by mass, and
The total content of component (A) to component (G) does not exceed 100% by mass,
(A) :( B) which is a mass ratio of the component (A) and the component (B) is 9: 1 to 4: 6,
(F) :( G) which is a mass ratio of the component (F) and the component (G) is 5:95 to 5: 5,
And a cleansing composition that is transparent.

Other aspects of the invention include:
A cleansing composition comprising:
The cleansing composition comprises:
Component (A): Nonionic surfactant having an HLB of 1 or more and 12 or less, Component (B): Nonionic surfactant having an HLB of more than 12 and 20 or less, Component (C): An oil agent liquid at 20 ° C. Component (D): including at least one water-soluble solvent component selected from the group consisting of glycols, glycerins, sugars and sugar alcohols, Component (E): water, and other components,
For the total mass of the cleansing composition,
The total content of the component (A) and the component (B) is 10 to 40% by mass,
The content of the component (C) is 10 to 35% by mass,
The content of the component (D) is 15 to 45% by mass,
The content of the component (E) is 20 to 60% by mass,
When the total content of the component (D) and the component (E) is 40 to 75% by mass, and the other component is used, the content of the other component is 0.0001 to 10% by mass. ,And,
The total content of component (A) to component (E) and the other components does not exceed 100% by mass,
(A) :( B) which is a mass ratio of the component (A) and the component (B) is 9: 1 to 4: 6,
And a cleansing composition that is transparent.

Other aspects of the invention include:
A cleansing composition comprising:
The cleansing composition comprises:
Component (A): Nonionic surfactant having an HLB of 1 or more and 12 or less, Component (B): Nonionic surfactant having an HLB of more than 12 and 20 or less, Component (C): An oil agent liquid at 20 ° C. Component (D): At least one water-soluble solvent component selected from the group consisting of glycols, glycerols, sugars and sugar alcohols, Component (E): Water, Component (F): Organic acid, Component (G) : An organic acid salt composed of an organic acid and a monovalent alkali metal, and other components,
For the total mass of the cleansing composition,
The total content of the component (A) and the component (B) is 10 to 40% by mass,
The content of the component (C) is 10 to 35% by mass,
The content of the component (D) is 15 to 45% by mass,
The content of the component (E) is 20 to 60% by mass,
The total content of component (D) and component (E) is 40 to 75% by mass,
The content of the component (F) is 0.001 to 1% by mass,
When the content of the component (G) is 0.001 to 1% by mass and the other component is used, the content of the other component is 0.0001 to 10% by mass, and
The total content of components (A) to (G) and the other components does not exceed 100% by mass,
(A) :( B) which is a mass ratio of the component (A) and the component (B) is 9: 1 to 4: 6,
(F) :( G) which is a mass ratio of the component (F) and the component (G) is 5:95 to 5: 5,
And a cleansing composition that is transparent.

Other aspects of the invention include:
A cleansing composition comprising:
The cleansing composition comprises:
Component (A): a polyoxyethylene nonionic surfactant having an HLB of 1 or more and 12 or less;
Component (B): a polyoxyethylene nonionic surfactant having an HLB of more than 12 and 20 or less;
Component (C): Liquid oil agent having a viscosity at 20 ° C. of 1 mPa · s or more and 35 mPa · s or less; and a branched fatty acid residue having 6 to 22 carbon atoms and a branched fatty acid having 6 to 22 carbon atoms An ester oil agent having at least one residue selected from the group consisting of aliphatic alcohol residues of at least one selected from the group consisting of an oil agent that is liquid at 20 ° C .;
Component (D): a water-soluble solvent component that is at least one selected from the group consisting of propylene glycol, dipropylene glycol, 1,3-butylene glycol, glycerin, sorbitol, xylitol, and erythritol; and component (E): Including water,
For the total mass of the cleansing composition,
The total content of the component (A) and the component (B) is 10 to 40% by mass,
The content of the component (C) is 10 to 35% by mass,
The content of the component (D) is 15 to 45% by mass,
The content of the component (E) is 20 to 60% by mass, the total content of the component (D) and the component (E) is 40 to 75% by mass, and
The total content of component (A) to component (E) does not exceed 100% by mass,
(A) :( B) which is a mass ratio of the component (A) and the component (B) is 9: 1 to 4: 6,
And a cleansing composition that is transparent.

Other aspects of the invention include:
A cleansing composition comprising:
The cleansing composition comprises:
Component (A): a non-glycol fatty acid ester having an HLB of 1 or more and 12 or less, at least one selected from the group consisting of a polyglycerin alkyl ether, a polyoxyethylene fatty acid ester, and a polyoxyethylene glycerin fatty acid ester Ionic surfactants;
Component (B): Polyoxyethylene fatty acid ester, polyoxyethylene sorbitan fatty acid ester, polyoxyethylene sorbitol fatty acid ester, polyoxyethylene alkyl ether, polyoxyethylene hydrogenated castor oil derivative, polyoxy with HLB of more than 12 and 22 or less A nonionic surfactant which is at least one selected from the group consisting of ethylene glycerin fatty acid ester and sucrose fatty acid ester;
Component (C): liquid paraffin, light liquid isoparaffin, isononyl isononanoate, isotridecyl isononanoate, ethylhexyl palmitate, cetyl 2-ethylhexanoate, neopentyl glycol diethylhexanoate, di (capryl / capric acid) propanediol, isostearic acid An oil agent that is liquid at 20 ° C., which is at least one selected from the group consisting of isopropyl and tri (2-ethylhexanoic acid) glycerin;
Component (D): a water-soluble solvent component that is at least one selected from the group consisting of propylene glycol, dipropylene glycol, 1,3-butylene glycol, glycerin, sorbitol, xylitol, and erythritol; and component (E): Including water,
Total content of component (A) and component (B), content of component (C), content of component (D), content of component (E), and total of component (D) and component (E) The content is the same as described above, and the total content of components (A) to (E) does not exceed 100% by mass,
The mass ratio of the component (A) and the component (B) is the same as described above,
And a cleansing composition that is transparent.

Other aspects of the invention include:
A cleansing composition comprising:
The cleansing composition comprises:
Component (A): Polyoxyethylene glycerin fatty acid ester having an HLB of 1 or more and 12 or less;
Component (B): Polyoxyethylene glycerin fatty acid ester having an HLB of more than 12 and 20 or less;
Component (C): liquid paraffin, light liquid isoparaffin, isononyl isononanoate, isotridecyl isononanoate, ethylhexyl palmitate, cetyl 2-ethylhexanoate, neopentyl glycol diethylhexanoate, di (capryl / capric acid) propanediol, isostearic acid An oil agent that is liquid at 20 ° C., which is at least one selected from the group consisting of isopropyl and tri (2-ethylhexanoic acid) glycerin;
Component (D): a water-soluble solvent component that is at least one selected from the group consisting of propylene glycol, dipropylene glycol, 1,3-butylene glycol, glycerin, sorbitol, xylitol, and erythritol; and component (E): Including water,
Total content of component (A) and component (B), content of component (C), content of component (D), content of component (E), and total of component (D) and component (E) The content is the same as described above, and the total content of components (A) to (E) does not exceed 100% by mass,
The mass ratio of the component (A) and the component (B) is the same as described above,
And a cleansing composition that is transparent.

Other aspects of the invention include:
A cleansing composition comprising:
The cleansing composition comprises:
Component (A): polyoxyethylene glyceryl triisostearate having an HLB of 10;
Component (B): polyoxyethylene glyceryl isostearate having an HLB of 14;
Component (C): an oil agent that is at least one selected from the group consisting of cetyl ethylhexanoate, isononyl isononanoate, and liquid paraffin, and is liquid at 20 ° C .;
Component (D): dipropylene glycol; and component (E): water;
For the total mass of the cleansing composition,
The total content of component (A) and component (B), the content of component (C), the content of component (D), the content of component (E), and the content of component (D) and component (E) The total content is the same as above, and the total content of components (A) to (E) does not exceed 100% by mass,
The mass ratio of the component (A) and the component (B) is the same as described above,
And a cleansing composition that is transparent.

Other aspects of the invention include:
A cleansing composition comprising:
The cleansing composition comprises:
Component (A): polyoxyethylene glyceryl triisostearate having an HLB of 10;
Component (B): polyoxyethylene glyceryl isostearate having an HLB of 14;
Component (C): an oil agent that is at least one selected from the group consisting of cetyl ethylhexanoate, isononyl isononanoate, and liquid paraffin, and is liquid at 20 ° C .;
Component (D): dipropylene glycol; and component (E): water,
For the total mass of the cleansing composition,
The total content of component (A) and component (B) is 15 to 35% by mass,
The content of the component (C) is 10 to 30% by mass,
The content of the component (D) is 20 to 40% by mass,
The content of the component (E) is 25 to 50% by mass, and the total content of the component (D) and the component (E) is 50 to 75% by mass, and
The total content of component (A) to component (E) does not exceed 100% by mass,
(A) :( B) which is a mass ratio of the component (A) and the component (B) is 9: 1 to 4: 6,
And a cleansing composition that is transparent.

Other aspects of the invention include:
A cleansing composition comprising:
The cleansing composition comprises:
Component (A): a polyoxyethylene nonionic surfactant having an HLB of 1 or more and 12 or less;
Component (B): a polyoxyethylene nonionic surfactant having an HLB of more than 12 and 20 or less;
Component (C): Liquid oil agent having a viscosity at 20 ° C. of 1 mPa · s or more and 35 mPa · s or less; and a branched fatty acid residue having 6 to 22 carbon atoms and a branched fatty acid having 6 to 22 carbon atoms An ester oil agent having at least one residue selected from the group consisting of aliphatic alcohol residues of at least one selected from the group consisting of an oil agent that is liquid at 20 ° C .;
Component (D): a water-soluble solvent component that is at least one selected from the group consisting of propylene glycol, dipropylene glycol, 1,3-butylene glycol, glycerin, sorbitol, xylitol, and erythritol;
Ingredient (E): water
Component (F): at least one organic acid selected from the group consisting of citric acid, succinic acid, malic acid, and tartaric acid, and component (G): from the group consisting of citric acid, succinic acid, malic acid, and tartaric acid An organic acid salt consisting of at least one selected organic acid and sodium or potassium,
Total content of component (A) and component (B), content of component (C), content of component (D), content of component (E), total content of component (D) and component (E) The amount, the content of the component (F), and the content of the component (G) are the same as above, and
The total content of component (A) to component (G) does not exceed 100% by mass,
The mass proportion of the component (A) and the component (B) and the mass proportion of the component (F) and the component (G) are the same as described above.
And a cleansing composition that is transparent.

Other aspects of the invention include:
A cleansing composition comprising:
The cleansing composition comprises:
Component (A): a non-glycol fatty acid ester having an HLB of 1 or more and 12 or less, at least one selected from the group consisting of a polyglycerin alkyl ether, a polyoxyethylene fatty acid ester, and a polyoxyethylene glycerin fatty acid ester Ionic surfactants;
Component (B): Polyoxyethylene fatty acid ester, polyoxyethylene sorbitan fatty acid ester, polyoxyethylene sorbitol fatty acid ester, polyoxyethylene alkyl ether, polyoxyethylene hydrogenated castor oil derivative, polyoxyethylene having an HLB of more than 12 and 20 or less A nonionic surfactant which is at least one selected from the group consisting of ethylene glycerin fatty acid ester and sucrose fatty acid ester;
Component (C): liquid paraffin, light liquid isoparaffin, isononyl isononanoate, isotridecyl isononanoate, ethylhexyl palmitate, cetyl 2-ethylhexanoate, neopentyl glycol diethylhexanoate, di (capryl / capric acid) propanediol, isostearic acid An oil agent that is liquid at 20 ° C., which is at least one selected from the group consisting of isopropyl and tri (2-ethylhexanoic acid) glycerin;
Component (D): a water-soluble solvent component that is at least one selected from the group consisting of propylene glycol, dipropylene glycol, 1,3-butylene glycol, glycerin, sorbitol, xylitol, and erythritol;
Component (E): Water component (F): At least one organic acid selected from the group consisting of citric acid, succinic acid, malic acid, and tartaric acid, and component (G): citric acid, succinic acid, malic acid, And an organic acid salt consisting of at least one organic acid selected from the group consisting of tartaric acid and sodium or potassium,
Total content of component (A) and component (B), content of component (C), content of component (D), content of component (E), total content of component (D) and component (E) The amount, the content of the component (F), and the content of the component (G) are the same as above, and
The total content of component (A) to component (G) does not exceed 100% by mass,
The mass proportion of the component (A) and the component (B) and the mass proportion of the component (F) and the component (G) are the same as described above.
And a cleansing composition that is transparent.

Other aspects of the invention include:
A cleansing composition comprising:
The cleansing composition comprises:
Component (A): Polyoxyethylene glycerin fatty acid ester having an HLB of 1 or more and 12 or less;
Component (B): Polyoxyethylene glycerin fatty acid ester having an HLB of more than 12 and 20 or less;
Component (C): liquid paraffin, light liquid isoparaffin, isononyl isononanoate, isotridecyl isononanoate, ethylhexyl palmitate, cetyl 2-ethylhexanoate, neopentyl glycol diethylhexanoate, di (capryl / capric acid) propanediol, isostearic acid An oil agent that is liquid at 20 ° C., which is at least one selected from the group consisting of isopropyl and tri (2-ethylhexanoic acid) glycerin;
Component (D): a water-soluble solvent component that is at least one selected from the group consisting of propylene glycol, dipropylene glycol, 1,3-butylene glycol, glycerin, sorbitol, xylitol, and erythritol;
Component (E): water;
Component (F): at least one organic acid selected from the group consisting of citric acid, succinic acid, malic acid, and tartaric acid, and component (G): from the group consisting of citric acid, succinic acid, malic acid, and tartaric acid An organic acid salt consisting of at least one selected organic acid and sodium or potassium,
Total content of component (A) and component (B), content of component (C), content of component (D), content of component (E), total content of component (D) and component (E) The amount, the content of the component (F), and the content of the component (G) are the same as above, and
The total content of component (A) to component (G) does not exceed 100% by mass,
The mass proportion of the component (A) and the component (B) and the mass proportion of the component (F) and the component (G) are the same as described above.
And a cleansing composition that is transparent.

Other aspects of the invention include:
A cleansing composition comprising:
The cleansing composition comprises:
Component (A): polyoxyethylene glyceryl triisostearate having an HLB of 10;
Component (B): polyoxyethylene glyceryl isostearate having an HLB of 14;
Component (C): an oil agent that is at least one selected from the group consisting of cetyl ethylhexanoate, isononyl isononanoate, and liquid paraffin, and is liquid at 20 ° C .;
Component (D): dipropylene glycol;
Component (E): water;
Component (F): citric acid, and component (G): sodium citrate,
Total content of component (A) and component (B), content of component (C), content of component (D), content of component (E), total content of component (D) and component (E) The amount, the content of the component (F), and the content of the component (G) are the same as above, and
The total content of component (A) to component (G) does not exceed 100% by mass,
The mass proportion of the component (A) and the component (B) and the mass proportion of the component (F) and the component (G) are the same as described above.
And a cleansing composition that is transparent.

Other aspects of the invention include:
A cleansing composition comprising:
The cleansing composition comprises:
Component (A): polyoxyethylene glyceryl triisostearate having an HLB of 10;
Component (B): polyoxyethylene glyceryl isostearate having an HLB of 14;
Component (C): an oil agent that is at least one selected from the group consisting of cetyl ethylhexanoate, isononyl isononanoate, and liquid paraffin, and is liquid at 20 ° C .;
Component (D): dipropylene glycol;
Component (E): water;
Component (F): citric acid, and component (G): sodium citrate,
For the total mass of the cleansing composition,
The total content of component (A) and component (B) is 15 to 23% by mass,
The content of the component (C) is 12 to 20% by mass,
The content of the component (D) is 25 to 35% by mass,
The content of the component (E) is 30 to 47% by mass,
The total content of component (D) and component (E) is 50 to 75% by mass,
The content of the component (F) is 0.01 to 0.3% by mass, the content of the component (G) is 0.01 to 0.3% by mass, and
The total content of component (A) to component (G) does not exceed 100% by mass,
(A) :( B) which is a mass ratio of the component (A) and the component (B) is 9: 1 to 4: 6,
(F) :( G) which is a mass ratio of the component (F) and the component (G) is 5:95 to 5: 5,
And a cleansing composition that is transparent.

Other aspects of the invention include:
Use for cleansing a composition comprising the following component (A), component (B), component (C), component (D) and component (E),
Component (A) is a nonionic surfactant having an HLB of 1 or more and 12 or less,
Component (B) is a nonionic surfactant having an HLB of more than 12 and 20 or less,
Component (C) is a liquid oil at 20 ° C.,
Component (D) is at least one water-soluble solvent component selected from the group consisting of glycols, glycerins, saccharides and sugar alcohols,
Ingredient (E) is water,
With respect to the total mass of the composition,
The total content of the component (A) and the component (B) is 10 to 40% by mass,
The content of the component (C) is 10 to 35% by mass,
The content of the component (D) is 15 to 45% by mass,
The content of the component (E) is 20 to 60% by mass, the total content of the component (D) and the component (E) is 40 to 75% by mass, and
The total content of component (A) to component (E) does not exceed 100% by mass,
(A) :( B) which is a mass ratio of the component (A) and the component (B) is 9: 1 to 4: 6,
Transparent,
Use of the composition for cleansing.

Other aspects of the invention include:
Use for cleansing a composition comprising the following component (A), component (B), component (C), component (D), component (E), component (F) and component (G),
Component (A) is a nonionic surfactant having an HLB of 1 or more and 12 or less,
Component (B) is a nonionic surfactant having an HLB of more than 12 and 20 or less,
Component (C) is a liquid oil at 20 ° C.,
Component (D) is at least one water-soluble solvent component selected from the group consisting of glycols, glycerins, saccharides and sugar alcohols,
Component (E) is water;
Component (F) is an organic acid,
Component (G) is an organic acid salt composed of an organic acid and a monovalent alkali metal,
For the total mass of the cleansing composition,
The total content of the component (A) and the component (B) is 10 to 40% by mass,
The content of the component (C) is 10 to 35% by mass,
The content of the component (D) is 15 to 45% by mass,
The content of the component (E) is 20 to 60% by mass,
The total content of component (D) and component (E) is 40 to 75% by mass,
The content of the component (F) is 0.001 to 1% by mass, the content of the component (G) is 0.001 to 1% by mass, and
The total content of component (A) to component (G) does not exceed 100% by mass,
(A) :( B) which is a mass ratio of the component (A) and the component (B) is 9: 1 to 4: 6,
(F) :( G) which is a mass ratio of the component (F) and the component (G) is 5:95 to 5: 5,
Transparent,
Use for cleansing the composition.

Other aspects of the invention include:
Use of a composition comprising the following component (A), component (B), component (C), component (D) and component (E) for producing a cleansing agent,
Component (A) is a nonionic surfactant having an HLB of 1 or more and 12 or less,
Component (B) is a nonionic surfactant having an HLB of more than 12 and 20 or less,
Component (C) is a liquid oil at 20 ° C.,
Component (D) is at least one water-soluble solvent component selected from the group consisting of glycols, glycerins, saccharides and sugar alcohols,
Ingredient (E) is water,
With respect to the total mass of the composition,
The total content of the component (A) and the component (B) is 10 to 40% by mass,
The content of the component (C) is 10 to 35% by mass,
The content of the component (D) is 15 to 45% by mass,
The content of the component (E) is 20 to 60% by mass, the total content of the component (D) and the component (E) is 40 to 75% by mass, and
The total content of component (A) to component (E) does not exceed 100% by mass,
(A) :( B) which is a mass ratio of the component (A) and the component (B) is 9: 1 to 4: 6,
Transparent,
Use of the composition for producing a cleansing agent.

Other aspects of the invention include:
In the use of a composition comprising the following component (A), component (B), component (C), component (D), component (E), component (F) and component (G) for producing a cleansing agent There,
Component (A) is a nonionic surfactant having an HLB of 1 or more and 12 or less,
Component (B) is a nonionic surfactant having an HLB of more than 12 and 20 or less,
Component (C) is a liquid oil at 20 ° C.,
Component (D) is at least one water-soluble solvent component selected from the group consisting of glycols, glycerins, saccharides and sugar alcohols,
Component (E) is water;
Component (F) is an organic acid,
Component (G) is an organic acid salt composed of an organic acid and a monovalent alkali metal,
With respect to the total mass of the composition,
The total content of the component (A) and the component (B) is 10 to 40% by mass,
The content of the component (C) is 10 to 35% by mass,
The content of the component (D) is 15 to 45% by mass,
The content of the component (E) is 20 to 60% by mass,
The total content of component (D) and component (E) is 40 to 75% by mass,
The content of the component (F) is 0.001 to 1% by mass, the content of the component (G) is 0.001 to 1% by mass, and
The total content of component (A) to component (G) does not exceed 100% by mass,
(A) :( B) which is a mass ratio of the component (A) and the component (B) is 9: 1 to 4: 6,
(F) :( G) which is a mass ratio of the component (F) and the component (G) is 5:95 to 5: 5,
Transparent,
Use of the composition for producing a cleansing agent.

  EXAMPLES Hereinafter, although the Example and comparative example of this invention are shown and this invention is demonstrated in more detail, this invention is not limited to these.

[Examples 1-14, Comparative Examples 1-12]
Cleansing compositions having the compositions shown in Tables 1 to 3 were produced and evaluated for use feeling, cleansing properties, and storage stability. A result is combined with Tables 1-5 and shown.

(Production method)
By putting the components (D) to (E) or the components (D) to (G) in a container containing the components (A) to (C), stirring with a propeller, and uniformly mixing all the components, A cleansing composition was obtained.
The cleansing compositions of Examples 1-14 were transparent liquids.

(Feeling of use)
Each cleansing composition was applied to 10 panelists, and the feeling of use was answered by a questionnaire, and evaluated according to the following criteria. "Oil feeling" evaluated the feeling during use. “Effect of oil film on eyeball”, “rinse”, and “moist feeling after washing” were evaluated during use of the cleansing composition with water or after washing. “Cleansing property” was evaluated by applying a waterproof type mascara to the skin, drying, applying a cleansing composition, blending in and washing off the mascara. The evaluation criteria for each item are shown below.

“Oiliness”
A: Nine or more responded that there was no oiliness.
B: Six to eight people answered that there was no oiliness.
C: 3 to 5 people answered that there was no oiliness.
D: Two or less responded that there was no oiliness.
"Effect of oil film on eyeball"
A: Nine or more responded that they did not feel the oil film.
B: 6-8 responded that they did not feel oil film.
C: Three to five people answered that they did not feel an oil film.
D: Less than 2 responded that they did not feel oil film.
"Rinse"
A: Nine or more responded that rinsing was good.
B: Six to eight people answered that rinsing properties were good.
C: 3 to 5 people answered that rinsing properties were good.
D: Two or less persons answered that the rinsing property was good.
"Moist feeling after washing"
A: Nine or more responded that they had a moist feeling.
B: Six to eight people answered that they had a moist feeling.
C: Three to five people answered that they had a moist feeling.
D: Less than 2 responded that they were moist.
“Cleansing”
A: Nine or more responded that the effect of dropping mascara was high.
B: 6-8 responded that the effect of dropping mascara was high.
C: Three to five people answered that the effect of dropping mascara was high.
D: Less than 2 responded that the effect of dropping mascara was high.

(Storage stability)
The state after storage for 1 month at 50 ° C. was evaluated according to the following criteria. “Appearance” was visually evaluated for the degree of separation, creaming, and turbidity. “Smell” was subjected to a sensory evaluation by a specialized panelist to evaluate the strength of the odor. The evaluation criteria for each item are shown below.

"appearance"
A: Separation, creaming and turbidity were not observed.
B: Slight separation, creaming or turbidity was observed.
C: Any of separation, creaming, and turbidity was clearly observed.
D: Significant separation, creaming or turbidity was observed.
"odor"
A: There was no odor of interest.
B: A slight odor was felt.
C: A distinct smell was felt.
D: A significant odor was felt.

（成分単位：質量％）
※１：サラコス３１８（日清オイリオグループ株式会社）
※２：サラコス１１８（日清オイリオグループ株式会社）
※３：サラコス８１６Ｔ（日清オイリオグループ株式会社）
※４：サラコス９９（日清オイリオグループ株式会社）

(Ingredient unit: mass%)
* 1: Saracos 318 (Nisshin Oillio Group, Inc.)
* 2: Saracos 118 (Nisshin Oillio Group, Inc.)
* 3: Saracos 816T (Nisshin Oillio Group, Inc.)
* 4: Saracos 99 (Nisshin Oillio Group, Inc.)

（成分単位：質量％）
※１：サラコス３１８（日清オイリオグループ株式会社）
※２：サラコス１１８（日清オイリオグループ株式会社）
※３：サラコス８１６Ｔ（日清オイリオグループ株式会社）
※４：サラコス９９（日清オイリオグループ株式会社）

(Ingredient unit: mass%)
* 1: Saracos 318 (Nisshin Oillio Group, Inc.)
* 2: Saracos 118 (Nisshin Oillio Group, Inc.)
* 3: Saracos 816T (Nisshin Oillio Group, Inc.)
* 4: Saracos 99 (Nisshin Oillio Group, Inc.)

（成分単位：質量％）
※１：サラコス３１８（日清オイリオグループ株式会社）
※２：サラコス１１８（日清オイリオグループ株式会社）
※３：サラコス８１６Ｔ（日清オイリオグループ株式会社）
※４：サラコス９９（日清オイリオグループ株式会社）

(Ingredient unit: mass%)
* 1: Saracos 318 (Nisshin Oillio Group, Inc.)
* 2: Saracos 118 (Nisshin Oillio Group, Inc.)
* 3: Saracos 816T (Nisshin Oillio Group, Inc.)
* 4: Saracos 99 (Nisshin Oillio Group, Inc.)

（成分単位：質量％）
※１：サラコス３１８（日清オイリオグループ株式会社）
※２：サラコス１１８（日清オイリオグループ株式会社）
※３：サラコス８１６Ｔ（日清オイリオグループ株式会社）
※４：サラコス９９（日清オイリオグループ株式会社）

(Ingredient unit: mass%)
* 1: Saracos 318 (Nisshin Oillio Group, Inc.)
* 2: Saracos 118 (Nisshin Oillio Group, Inc.)
* 3: Saracos 816T (Nisshin Oillio Group, Inc.)
* 4: Saracos 99 (Nisshin Oillio Group, Inc.)

As can be seen from Tables 1 and 2, all of the cleansing compositions of Examples 1 to 10 have no oily feeling during use, and it is difficult to feel an oil film even if mixed in the eyes, and it can be washed away without a residual feeling, after cleansing It was a cleansing composition that was excellent in moistness, had sufficient cleansing power for makeup that was difficult to remove, such as a waterproof type mascara, and had excellent stability.

On the other hand, as can be seen from Table 3, the cleansing compositions (Comparative Examples 1 to 5) not containing each of the components (A) to (E) did not have good appearance and storage stability. As a result of measuring the absorbance with an ultraviolet-visible spectrophotometer, Example 1 was 0.04, whereas the cleansing composition in which the appearance evaluation of Comparative Examples 9 and 10 was evaluated as cloudy was 2.0. It was.
Moreover, from Tables 1 to 4, Examples 1 to 10, and Comparative Examples 6 to 8 in which the total content and mass ratio (mass ratio) of the component (A) and the component (B) exceed the range defined in the present invention. In contrast, since any of usability, storage stability, and appearance is not good, it is important to make the total content and mass ratio within the scope of the present invention to obtain the above effects. The Moreover, by comparing Examples 1-10 with Comparative Example 9 and Comparative Example 10, the content of component (C), or by comparing Examples 1-10 with Comparative Example 11 and Comparative Example 12, It can be seen that making the content of the component (D) within the scope of the present invention is important for obtaining the above effect.

（成分単位：質量％）
※１：サラコス３１８（日清オイリオグループ株式会社）
※２：サラコス１１８（日清オイリオグループ株式会社）
※３：サラコス８１６Ｔ（日清オイリオグループ株式会社）
※４：サラコス９９（日清オイリオグループ株式会社）

(Ingredient unit: mass%)
* 1: Saracos 318 (Nisshin Oillio Group, Inc.)
* 2: Saracos 118 (Nisshin Oillio Group, Inc.)
* 3: Saracos 816T (Nisshin Oillio Group, Inc.)
* 4: Saracos 99 (Nisshin Oillio Group, Inc.)

From the results in Table 5, all of the cleansing compositions of Examples 11 to 14 have no oily feeling during use, hardly feel an oil film even when mixed in the eyes, can be washed away without a residual feeling, and have a moist feeling after cleansing. It was an excellent cleansing composition having a sufficient cleansing power for difficult-to-remove makeup such as a waterproof mascara and having excellent stability with little change in odor over time.

Moreover, since each cleansing composition of Examples 11-14 whose each content and mass ratio of a component (F) and a component (G) are the scope of the present invention has good evaluation of odor, these components It turns out that it is important in order to acquire the said effect to make each content and mass ratio of this into the range of this invention.

The cleansing composition of the present invention does not feel oily during use, it is difficult to feel an oil film even if it is mixed with eyes, it can be washed cleanly without residual feeling, it has a moist feeling after cleansing, and a drop of waterproof type mascara etc. Since it is a cleansing composition having sufficient cleansing power for difficult makeup and having excellent stability, it is extremely important in industry.

Claims (7)

A cleansing composition comprising:
The cleansing composition comprises:
Component (A): Nonionic surfactant having an HLB of 1 or more and 12 or less, Component (B): Nonionic surfactant having an HLB of more than 12 and 20 or less, Component (C): An oil agent liquid at 20 ° C. Component (D): at least one water-soluble solvent component selected from the group consisting of glycols, glycerins, sugars and sugar alcohols, and component (E): water,
For the total mass of the cleansing composition,
The total content of the component (A) and the component (B) is 10 to 40% by mass,
The content of the component (C) is 10 to 35% by mass,
The content of the component (D) is 15 to 45% by mass,
The content of the component (E) is 20 to 60% by mass, the total content of the component (D) and the component (E) is 40 to 75% by mass, and
The total content of component (A) to component (E) does not exceed 100% by mass,
(A) :( B) which is a mass ratio of the component (A) and the component (B) is 9: 1 to 4: 6,
A cleansing composition that is transparent. The cleansing composition according to claim 1, wherein the component (A) and the component (B) are polyoxyethylene-based nonionic surfactants. The cleansing composition according to claim 1 or 2, wherein the component (A) and the component (B) are polyoxyethylene glycerin fatty acid esters. The cleansing composition according to any one of claims 1 to 3, wherein the component (C) contains at least one liquid oil having a viscosity at 20 ° C of 1 mPa · s to 35 mPa · s.   Component (C) is at least one residue selected from the group consisting of a branched fatty acid residue having 6 to 22 carbon atoms and a branched aliphatic alcohol residue having 6 to 22 carbon atoms. The cleansing composition according to any one of claims 1 to 4, comprising at least one ester oil agent.   The component (D) is at least one selected from the group consisting of propylene glycol, dipropylene glycol, 1,3-butylene glycol, glycerin, sorbitol, xylitol, and erythritol. The cleansing composition as described.   Furthermore, the component (F): the organic acid is 0.001 to 1% by mass relative to the total mass of the cleansing composition, and the component (G) is an organic acid salt composed of an organic acid and a monovalent alkali metal. It is 0.001-1 mass% with respect to the total mass of the cleansing composition, and (F) :( G) which is a mass ratio of a component (F) and a component (G) is 5: 95-5: 5. The cleansing composition according to any one of claims 1 to 6.