JPWO2013042792A1 - Food modifier and oil-cooked food modified thereby - Google Patents

Food modifier and oil-cooked food modified thereby Download PDF

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JPWO2013042792A1
JPWO2013042792A1 JP2013534782A JP2013534782A JPWO2013042792A1 JP WO2013042792 A1 JPWO2013042792 A1 JP WO2013042792A1 JP 2013534782 A JP2013534782 A JP 2013534782A JP 2013534782 A JP2013534782 A JP 2013534782A JP WO2013042792 A1 JPWO2013042792 A1 JP WO2013042792A1
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好章 渡邉
好章 渡邉
毅臣 渡邉
毅臣 渡邉
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    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L33/00Modifying nutritive qualities of foods; Dietetic products; Preparation or treatment thereof
    • A23L33/20Reducing nutritive value; Dietetic products with reduced nutritive value
    • A23L33/21Addition of substantially indigestible substances, e.g. dietary fibres
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L19/00Products from fruits or vegetables; Preparation or treatment thereof
    • A23L19/10Products from fruits or vegetables; Preparation or treatment thereof of tuberous or like starch containing root crops
    • A23L19/12Products from fruits or vegetables; Preparation or treatment thereof of tuberous or like starch containing root crops of potatoes
    • A23L19/18Roasted or fried products, e.g. snacks or chips
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L29/00Foods or foodstuffs containing additives; Preparation or treatment thereof
    • A23L29/015Inorganic compounds
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L29/00Foods or foodstuffs containing additives; Preparation or treatment thereof
    • A23L29/20Foods or foodstuffs containing additives; Preparation or treatment thereof containing gelling or thickening agents
    • A23L29/206Foods or foodstuffs containing additives; Preparation or treatment thereof containing gelling or thickening agents of vegetable origin
    • A23L29/244Foods or foodstuffs containing additives; Preparation or treatment thereof containing gelling or thickening agents of vegetable origin from corms, tubers or roots, e.g. glucomannan
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L5/00Preparation or treatment of foods or foodstuffs, in general; Food or foodstuffs obtained thereby; Materials therefor
    • A23L5/10General methods of cooking foods, e.g. by roasting or frying
    • A23L5/15General methods of cooking foods, e.g. by roasting or frying using wave energy, irradiation, electrical means or magnetic fields, e.g. oven cooking or roasting using radiant dry heat
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L7/00Cereal-derived products; Malt products; Preparation or treatment thereof
    • A23L7/10Cereal-derived products
    • A23L7/109Types of pasta, e.g. macaroni or noodles
    • A23L7/111Semi-moist pasta, i.e. containing about 20% of moist; Moist packaged or frozen pasta; Pasta fried or pre-fried in a non-aqueous frying medium, e.g. oil; Packaged pasta to be cooked directly in the package
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L7/00Cereal-derived products; Malt products; Preparation or treatment thereof
    • A23L7/10Cereal-derived products
    • A23L7/157Farinaceous granules for dressing meat, fish or the like
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23VINDEXING SCHEME RELATING TO FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES AND LACTIC OR PROPIONIC ACID BACTERIA USED IN FOODSTUFFS OR FOOD PREPARATION
    • A23V2002/00Food compositions, function of food ingredients or processes for food or foodstuffs

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  • Life Sciences & Earth Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Food Science & Technology (AREA)
  • Nutrition Science (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Polymers & Plastics (AREA)
  • Inorganic Chemistry (AREA)
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  • Mycology (AREA)
  • General Preparation And Processing Of Foods (AREA)
  • Jellies, Jams, And Syrups (AREA)
  • Bakery Products And Manufacturing Methods Therefor (AREA)
  • Grain Derivatives (AREA)

Abstract

【課題】 油揚げ食品の呈味を損なうことなく吸油量を半減させ, しかも冷凍耐性を具備させて揚げ物の冷凍保存を可能とし、レンジアップで食味、風味などを損なうことのない油揚げ食品の食品改質剤の提供。【解決手段】 食物繊維成分に対しイオン化ミネラル成分を組み合わせると、油調理時の油吸収を半減させる保水構造が形成される。希薄水溶液は畜肉、魚肉、海鮮物、野菜などの揚げ物原料を浸漬するか又は揚げ物原料表面に噴霧することによって、原料表面に油の吸収を半減させる保水構造を形成する。油揚げ調理を施すと、フライドポテトでは油調理理時の吸油率を抑制してカロリーは低いが旨味のあるフライドポテトを提供できる。また、冷凍保存してもレンジアップ時に保水機能を発揮し、離水を抑制するので、旨味のある揚げたてフライドポテトをレンジアップで再現し、サクサクした、揚げたて感の再現ができる優れた冷凍レンジアップ食品を提供できる。【選択図】なしPROBLEM TO BE SOLVED: To reduce the amount of oil absorption without sacrificing the taste of fried food, and to make frozen fried food with freezing resistance and to improve the range of the fried food that does not impair the taste, flavor, etc. Provision of quality agents. When an ionized mineral component is combined with a dietary fiber component, a water retention structure is formed that reduces oil absorption by half when cooking oil. The dilute aqueous solution forms a water retaining structure that halves the absorption of oil on the surface of the raw material by immersing or spraying the surface of the deep-fried material such as livestock meat, fish meat, seafood, and vegetables. When fried cooking is performed, fried potatoes can suppress the oil absorption rate during oil cooking, and provide fried potatoes with low calories but delicious. In addition, even if it is stored frozen, it exhibits a water retention function at the time of range up and suppresses water separation. Can provide. [Selection figure] None

Description

本発明は、食物繊維成分に対しイオン化ミネラル成分を配合して油調理時の油吸収を半減させる食品改質剤およびそれを用いて油調理した、レンジアップで食味、風味などを損なうことのない油調理食品に関する。 The present invention blends an ionized mineral component with a dietary fiber component to halve oil absorption during oil cooking, and cooks oil using the same, which does not impair the taste, flavor, etc. Oil cooking food.

電子レンジ加熱調理(レンジアップ)食品は、調理の際に火を使わず、電子レンジによって加熱することで、手軽に調理することができることから、近年その需要が非常に高まってきている。また、この電子レンジ加熱調理食品は、キッチンを汚してしまうことなく食品を可食状態まで手軽に調理することができる。しかも、一人分といった少量でも、手間が掛からず所望の量だけ簡単に調理できることから、その需要が非常に高まってきている。ところが、電子レンジでは生肉や生水産物といった未加熱食材をそのまま加熱調理しても、未加熱食材表面に焼いたような風合いが施されるように処理する調理ができない。そのため、従来の電子レンジ加熱調理(レンジアップ)食品は、予め焼き調理済みの食品を電子レンジで温め直すようにした、ものしかなかった。そして、この焼き調理済みの食品の場合、電子レンジで温め直すと加熱後食品表面に水分が出てしまい、焼き調理後に蒸し調理をしたようで、とても満足できるものではないという欠点がある。 In recent years, the demand for cooking by heating in a microwave oven (range up) has increased greatly because it can be easily cooked by heating with a microwave oven without using fire during cooking. In addition, the microwave cooked food can easily cook the food to an edible state without contaminating the kitchen. Moreover, even a small amount for one person can be easily cooked in a desired amount without taking time and effort, so that the demand for it is increasing. However, in a microwave oven, even when unheated ingredients such as raw meat and raw marine products are cooked as they are, cooking cannot be performed so that the surface of the unheated ingredients is baked. Therefore, the only conventional microwave cooking (range-up) foods are foods that have been cooked in advance in a microwave oven. And in the case of this baked food, if it is reheated with a microwave oven, moisture will come out on the surface of the food after heating, and steamed cooking seems to be done after baked cooking, which is not very satisfactory.

そこで、現在では、電子レンジによる加熱調理でも焼いたような焦げ目を付けるようにした種々の手段が提案されている。例えば、第一の手段として、フィルム状もしくはシート状の基材の表面に、金属薄膜もしくは金属・金属酸化物混合体を蒸着によって設けたマイクロ波発熱層を設け、この基材で食品自体を包むことにより、電子レンジでの加熱時に基材表面で発熱させ、その熱で食品の表面を焼くようにしたものがある(特許文献1)。しかしながら、上記手段では、パイやパン、ピザ等といった水分が少なく平面的な食品であれば焼く調理を行うことができるが、たとえば、生肉や生魚といった水分が多く非平面的で、側面にも焼く調理が要求されることのある未加熱食材を調理する場合、食品より発生する水分により加熱時の温度が上昇し難く、結果的に焼く調理を行うことができない。 In view of this, various means have been proposed at present that are burnt even when cooked with a microwave oven. For example, as a first means, a microwave heating layer provided by vapor deposition of a metal thin film or a metal / metal oxide mixture is provided on the surface of a film or sheet-like substrate, and the food itself is wrapped with this substrate. Thus, there is one in which heat is generated on the surface of the substrate during heating in a microwave oven, and the surface of the food is baked with the heat (Patent Document 1). However, in the above means, baking can be performed with flat foods such as pie, bread, pizza, etc., which are low in water, but for example, raw meat and raw fish are rich in water and non-planar. When cooking unheated foods that may require cooking, the temperature during heating is unlikely to increase due to moisture generated from the food, and as a result, baking cannot be performed.

また、食用油脂と醤油と穀物粉からなる焼き目発生材を未加熱食材の表面に塗布し、この未加熱食材の焼き目生成箇所に隙間が生じないように耐熱性の収容体で包装し、電子レンジを用いて加熱・調理するようにしたレンジアップ食品が提案され(特許文献2)、この改良案として、電子レンジでの加熱によって食材の表面に焼いたような風合いが発生させることのできる調味料において、焦げ付いた調味料によって食材と耐熱性収容体が貼り付いてしまうことを抑止するようにしたレンジアップ用調味料として、粉末カルシウム類、種子類又は金属塩類からなる不溶又は難溶な可食性粒状物を含むものが提案されている(特許文献3)。 In addition, a grilling material made of edible fats and oils, soy sauce and cereal powder is applied to the surface of the unheated food material, and packaged in a heat-resistant container so that no gaps occur in the grilled portion of the unheated food material, A range-up food that is cooked and cooked using a microwave oven has been proposed (Patent Document 2), and as an improved plan, it is possible to generate a texture that is baked on the surface of the food by heating in the microwave oven. In seasonings, as a range-up seasoning that suppresses the sticking of food and heat-resistant containers due to burnt seasonings, it is insoluble or hardly soluble consisting of powdered calcium, seeds or metal salts. The thing containing an edible granular material is proposed (patent document 3).

特開平10−117941号公報Japanese Patent Application Laid-Open No. 10-117941 特開2006−25773号公報JP 2006-25773 A 特開2011−78392号公報JP 2011-78392 A

他方、フライドポテト、エビフライ、トンカツ等のフライ物商品でも同様であって、フライ調理直後の表面のサクサク、パリパリ感は食感として極めて大事であるが、時間が経過すると、内部水分が表出して表面または衣部分をしならせ、フライ物の最も大事な食感
であるサクサク、パリパリ感を阻害することから冷凍保存してレンジアップ処理で調理することは論外である。したがって、現在のところ、フライ物のレンジアップ食品は提供されていない。
On the other hand, the same applies to fried products such as fried potatoes, fried shrimp, and tonkatsu. It is out of the question to cook in the range-up process by freezing it because it obstructs the crispy and crispy texture, which is the most important texture of fried food, by making the surface or clothing part smooth. Therefore, at present, no fried food is available.

本発明はこの様な油調理仕立ての食感であるサクサク、パリパリ感を冷凍食品のレンジアップで再現することは極めて困難であることに着目してなされたもので、油揚げ食品の呈味を損なうことなく吸油量を半減させ, しかも冷凍耐性を具備させて揚げ物の冷凍保存再生を可能とし、レンジアップで食味、風味などを損なうことのない油揚げ食品の提供およびそれを実現する食品改質剤を提供することを目的とする。
本発明者らは、鋭意研究の結果、油調理しようとする食品中の食物繊維成分に対しイオン化カルシウムに代表されるイオン化ミネラル成分を組み合わせると、水溶性食物繊維で形成される保水構造にイオン化ミネラル成分が結合して水分との結合性を高める機能を付与するためか、希薄水溶液にそのまま畜肉、魚肉、海鮮物、野菜などの油調理対象を浸漬するか又は油調理対象表面に噴霧することによって、原料表面に油の吸収を半減させる構造を形成し、そのまま油揚げ調理を施すと、フライドポテトでは油調理理時の吸油率を抑制してカロリーは低いが旨味のあるフライドポテトを提供できることを見出した。また、この油調理理したフライドポテト等のフライ物を冷凍保存してもレンジアップ時に保水機能を発揮し、フライ処理面への吸水を抑制するためか、旨味のある揚げたてのフライドポテトをレンジアップで再現することを見出した。天ぷら及びフライ物対象表面に衣を形成する時もその衣に油吸収を抑制する障壁性を付与し、油揚げ調理時の油吸収率を半減させるだけでなく、各種フライ製品では冷凍保存後レンジアップ時に、衣部分への離水が抑制されるので、サクサクした、優れた冷凍レンジアップ食品を提供できることを見出した。
The present invention was made by paying attention to the fact that it is extremely difficult to reproduce the crispy and crispy textures of such oil-cooked tailored foods by raising the range of frozen foods, which impairs the taste of fried foods. To provide a deep-fried fried food that does not impair the taste, flavor, etc. by providing a freezing storage and regeneration of fried foods that have a refrigeration resistance without halving the amount of oil absorption The purpose is to provide.
As a result of diligent research, the present inventors have found that when an ionized mineral component typified by ionized calcium is combined with a dietary fiber component in a food to be cooked with oil, an ionized mineral is formed into a water retention structure formed by water-soluble dietary fiber. In order to give the function of combining the ingredients to enhance the binding with moisture, or by immersing the oil cooking object such as livestock meat, fish meat, seafood, vegetables etc. in the diluted aqueous solution as it is or spraying it on the surface of the oil cooking object It is found that if the structure of oil absorption on the surface of the raw material is formed in half and the fried cooking is performed as it is, fried potato suppresses the oil absorption rate during oil cooking and can provide a delicious potato with low calories. It was. In addition, even if fried food such as fried potatoes that have been cooked with oil is stored frozen, the water retention function will be demonstrated when the range is raised, and the range of freshly fried French potatoes will be increased to suppress water absorption on the frying surface. It was found to be reproduced with. Even when garments are formed on the surface of tempura and fried foods, the garment is provided with a barrier that suppresses oil absorption, and not only halves the oil absorption rate during frying. At times, we found that we could provide a crisp and excellent frozen range-up food because water release to the garment part was suppressed.

本発明は卵殻、貝殻、豚骨、牛骨、鶏がらなどの天然カルシウム材を焼成後粉砕し、発酵又は醸造酢を用いてイオン化してなる液状又は固形イオン化ミネラル成分を含んでなり、食品中に浸透し、その食物繊維と協働して保水構造を形成可能で、食品油調理時の油吸収率を低下させる機能を有することを特徴とする食品改質剤にある。   The present invention comprises a liquid or solid ionized mineral component obtained by firing and pulverizing natural calcium materials such as eggshells, shells, pork bones, beef bones, and chicken garments, and ionizing them using fermentation or brewed vinegar. It is a food modifier characterized in that it can form a water retention structure in cooperation with its dietary fiber and has a function of reducing the oil absorption rate when cooking food oil.

本発明の食品改質剤は食品への浸透性に優れるイオン化ミネラルを必須成分とするが、有機酸カルシウムを5重量%含有イオン化ミネラル成分に代替して用いてコストを低減することができる。併用できる限度は、5重量%含有イオン化ミネラル成分0.5重量部以上5.0重量部(イオン化ミネラルで0.025〜0.25重量部)に対し0.5重量部以上3.0重量部の比率で配合するのが好ましい。イオン化ミネラルは卵殻、貝殻、豚骨、牛骨、鶏がらなどの天然カルシウム材を焼成後粉砕し、発酵又は醸造酢を用いてイオン化して製造されるが、製造コストが高いためである。イオン化ミネラル成分の機能性を確保しつつ一部代替して有機酸カルシウムを使用することによりコストは低減できるが、イオン化ミネラル成分100ppm以上、好ましくは200ppm以上を確保しておくのが機能上好ましい。なぜなら、イオン化ミネラル成分は細胞のイオンチャンネルにを通じて水と一緒に細胞内液に浸透し、細胞内部に保水される機能を有するため、デンプン粒子は食物繊維の形成する保水機能を強化する機能を有する。したがって、かかる機能を阻害しない範囲で有機酸カルシウムを使用して機能補助するのが好ましく、有機酸カルシウム中デンプン質の改善には特に乳酸カルシウムが好ましい。イオン化カルシウムを主成分とする液状イオン化ミネラル分(およそ5重量%含有)の代替品として5重量%含有イオン化ミネラル成分0.5重量部以上5.0重量部(イオン化ミネラルで0.025〜0.25重量部)に対し0.5重量部以上3.0重量部の比率の範囲で使用されるのが好ましい。   The food modifier of the present invention contains an ionized mineral having excellent permeability to food as an essential component, but the cost can be reduced by using 5% by weight of an organic acid calcium in place of the ionized mineral component. The limit that can be used in combination is 0.5 to 5.0 parts by weight with respect to 5% by weight of the ionized mineral component of 0.5 to 5.0 parts by weight (0.025 to 0.25 parts by weight of ionized mineral). It is preferable to mix | blend in the ratio. Ionized minerals are produced by firing and pulverizing natural calcium materials such as eggshells, seashells, pork bones, beef bones, and chicken ribs, and ionizing them using fermentation or brewed vinegar, but this is because the production costs are high. The cost can be reduced by using organic acid calcium instead of a partial replacement while ensuring the functionality of the ionized mineral component, but it is functionally preferable to secure 100 ppm or more, preferably 200 ppm or more of the ionized mineral component. Because the ionized mineral component penetrates into the intracellular fluid together with water through the ion channel of the cell and has the function of retaining water inside the cell, the starch particles have the function of enhancing the water retention function formed by dietary fiber . Therefore, it is preferable to use organic acid calcium to assist the function within a range not inhibiting such function, and calcium lactate is particularly preferable for improving starch quality in organic acid calcium. As an alternative to the liquid ionized mineral content (contained approximately 5% by weight) mainly composed of ionized calcium, 0.5% by weight to 5.0% by weight of ionized mineral component containing 5% by weight (0.025-0. 25 parts by weight) is preferably used in the range of 0.5 parts by weight or more and 3.0 parts by weight.

更にデンプン粒子内の保水構造を強化するにはグルコマンナン又はコンニャク(通常デンプン等の賦形剤で20重量%含有程度に調製される)成分を5重量%含有イオン化ミネラル成分換算で0.5重量部以上5.0重量部(イオン化ミネラルで0.025〜0.25重量部)に対し0.5重量部以上5重量部(マンナン成分0.1〜1.0重量部)、好ましくは1重量部以下2.5重量部(マンナン成分0.2〜0.5重量部)の重量比率で配合するのがよい。グルコマンナン又はコンニャク粉はデンプンに配合して原料への均等分散性性を高めるのがよく、賦形剤を配合して通常20重量%程度の濃度として使用するのが使い勝手がよい。   Furthermore, in order to reinforce the water retention structure in the starch particles, glucomannan or konjac (usually prepared to contain about 20% by weight of an excipient such as starch) is contained in an amount of 0.5% in terms of ionized mineral component containing 5% by weight. 0.5 parts by weight or more and 5.0 parts by weight (0.025 to 0.25 parts by weight in terms of ionized minerals) 0.5 parts by weight or more and 5 parts by weight (mannan component 0.1 to 1.0 parts by weight), preferably 1 part by weight It is good to mix | blend by the weight ratio of 2.5 parts weight or less (mannan component 0.2-0.5 weight part). Glucomannan or konjac powder is preferably added to starch to improve the uniform dispersibility in the raw material, and it is convenient to use it at a concentration of about 20% by weight by adding an excipient.

食品又は原料組成物中の食物繊維成分に対し、少なくともイオン化カルシウムを含む水溶性イオン化ミネラル成分が結合することにより、デンプン粒子が含有する水溶性食物繊維が形成する保水構造の保水機能が向上し、その結果、その保水構造に対して水溶性ミネラル成分によりフライ処理(油揚げ処理)時の油吸収を低減させる機能(障壁機能)が付与されると思われる。その配合比率は水溶性食物繊維成分に対し水溶性ミネラル成分を10対1から1対1が適当である。立体的に形成される保水構造に対し、その表面に障壁機能を持たせることにより所望の機能が得られるからであり、10対1より比率が小さくなると保水構造における障壁機能が減退し、1対1より比率が大きくても効果の向上は認められない。本発明のイオン化ミネラル成分は中性域で使用されるので、コンニャクマンナン成分のアルカリ性凝固剤とは区別しなければならない。 The water-retaining function of the water-retaining structure formed by the water-soluble dietary fiber contained in the starch particles is improved by binding the water-soluble ionized mineral component containing at least ionized calcium to the dietary fiber component in the food or raw material composition, As a result, it is considered that the water retention structure is provided with a function (barrier function) for reducing oil absorption at the time of frying (frying) by the water-soluble mineral component. The mixing ratio of the water-soluble dietary fiber component to the water-soluble mineral component is 10: 1 to 1: 1. This is because the desired function can be obtained by providing a barrier function on the surface of the three-dimensionally formed water retention structure. When the ratio is smaller than 10: 1, the barrier function in the water retention structure is reduced. Even if the ratio is larger than 1, no improvement in the effect is recognized. Since the ionized mineral component of the present invention is used in the neutral range, it must be distinguished from the alkaline coagulant of the konjac mannan component.

本発明の食品改質剤は、中性希薄水溶液として調製される。かかる希薄水溶液は、イオン化カルシウムを100から5000ppm、好ましくは200ppm以上2500ppmを含み、油揚げ処理前の被対象食品を浸漬または油処理前の被対象食品に噴霧して用いられる。100ppm以下では浸漬又は噴霧処理後の障壁機能の付与効果が十分でなく、5000ppmを超えても浸漬又は噴霧処理後の障壁機能の付与効果が向上しない。ここで、イオン化カルシウム換算とはイオン化カルシウム以外のミネラル成分の障壁機能付与能力はイオン化ミネラルに及ばず、その80%以下であるからその能力を考慮してイオン化カルシウムに換算して100ppmから5000ppmの範囲の希薄水溶液として用いることを意味する。 The food modifier of the present invention is prepared as a neutral dilute aqueous solution. Such dilute aqueous solution contains 100 to 5000 ppm of ionized calcium, preferably 200 ppm or more and 2500 ppm, and is used by immersing or spraying the target food before frying on the target food before oil treatment. If it is 100 ppm or less, the effect of imparting a barrier function after immersion or spray treatment is not sufficient, and even if it exceeds 5000 ppm, the effect of imparting a barrier function after immersion or spray treatment is not improved. Here, in terms of ionized calcium conversion, the barrier function imparting ability of mineral components other than ionized calcium does not reach that of ionized minerals, and is 80% or less. It is meant to be used as a dilute aqueous solution.

また、本発明の食品改質剤はフライ又は天ぷらの衣形成材料に配合して用いることができる。水分を含む衣材料に対しその中にイオン化カルシウム換算で水溶性ミネラル成分を100から5000ppmを含むように調製して使用すればよく、パン粉を使用する場合はパン粉に上記希薄水溶液を噴霧して表面処理する形式で用いることが推奨される。したがって、好ましい組み合わせは5重量%含有イオン化ミネラル成分換算で0.5〜5.0重量部(イオン化ミネラルで0.025〜0.25重量部)、乳酸カルシウム0.5〜3重量部及びグルコマンナン又はコンニャク成分(20重量%含有形態)で0.5〜5.0重量部の比率で配合され、油調理前の固形食品(茹で麺、野菜、炊飯ライス等)を浸漬または食品表面に噴霧して用いるのがよい。 Moreover, the foodstuff modifier of this invention can be mix | blended and used for the fried or tempura clothing formation material. What is necessary is just to prepare and use so that it may contain 100-5000 ppm of water-soluble mineral components in the conversion of ionized calcium with respect to the moisture-containing clothing material, and when using bread crumbs, spray the dilute aqueous solution onto the bread crumbs. It is recommended to use it in the processing format. Therefore, a preferred combination is 0.5 to 5.0 parts by weight (0.025 to 0.25 parts by weight of ionized mineral) in terms of 5% by weight of ionized mineral component, 0.5 to 3 parts by weight of calcium lactate, and glucomannan. Or it is a konjac ingredient (20% by weight containing form) and is blended at a ratio of 0.5 to 5.0 parts by weight, soaking the solid food (boiled noodles, vegetables, cooked rice, etc.) before cooking oil on the surface of the food It is good to use.

また、てんぷら粉組成物の場合は、小麦粉100重量部に対し5重量%含有イオン化ミネラル成分換算で0.5〜5.0重量%(イオン化ミネラルで0.025〜0.25重量部)、乳酸カルシウム0.5〜3.0重量%及びグルコマンナン又はコンニャク成分(20重量%含有形態)で0.5〜5.0重量部を配合して調製されると、改質剤非添加の場合に比して30〜50%油分吸収を減少させることができる。   Moreover, in the case of a tempura flour composition, 0.5 to 5.0% by weight (in terms of ionized minerals, 0.025 to 0.25 parts by weight) in terms of ionized mineral components containing 5% by weight with respect to 100 parts by weight of wheat flour, lactic acid When 0.5 to 5.0 parts by weight of calcium and 0.5 to 5.0 parts by weight of glucomannan or konjac component (20% by weight containing form) are prepared, when no modifier is added Compared with this, oil absorption by 30 to 50% can be reduced.

即席フライ麺およびスパゲッティなどの油調理麺組成物である場合は、小麦粉100重量部に対し5重量%含有イオン化ミネラル成分換算で0.5〜5.0重量%(イオン化ミネラルで0.025〜0.25重量部)、乳酸カルシウム0.5〜3.0重量%及びグルコマンナン又はコンニャク(20重量%含有)成分0.5〜5.0重量部を配合し、改質剤非添加の場合に比して30〜50%油分吸収を減少させることができる。   In the case of oil-cooked noodle compositions such as instant fried noodles and spaghetti, 0.5 to 5.0% by weight in terms of ionized mineral components contained in 5% by weight with respect to 100 parts by weight of flour (0.025 to 0 in terms of ionized minerals) 25 parts by weight), 0.5 to 3.0 parts by weight of calcium lactate and 0.5 to 5.0 parts by weight of glucomannan or konjac (containing 20% by weight) component, and when no modifier is added Compared with this, oil absorption by 30 to 50% can be reduced.

パン粉組成物の場合は、小麦粉100重量部に対し5重量%含有イオン化ミネラル成分換算で0.5〜5.0重量%(イオン化ミネラルで0.025〜0.25重量部)、乳酸カルシウム0.5〜3.0重量%を配合し、改質剤非添加の場合に比して30〜50%油分吸収を減少させることができる。グルコマンナン成分を含有させることができるが発酵時の膨化が抑制される傾向が見られるので、十分に膨化させる場合は使用しなくてもよい。   In the case of a bread crumb composition, 0.5 to 5.0% by weight in terms of ionized mineral component (0.025 to 0.25 parts by weight of ionized mineral) in terms of 5% by weight based on 100 parts by weight of wheat flour, calcium lactate 5 to 3.0% by weight is blended, and oil absorption by 30 to 50% can be reduced as compared with the case where no modifier is added. Although a glucomannan component can be contained, since there is a tendency that expansion during fermentation is suppressed, it may not be used when sufficiently expanding.

イオン化ミネラル成分は卵殻、貝殻、豚骨、牛骨、鶏がらなどの天然カルシウムを原料として調製するのが好ましく、水溶性を付与するため、焼成後撹拌・加温下に酸処理してイオン化し、これを乾燥固化して得るのが好ましいが、乾燥固前の液状のものを用いてもよい。具体的には、卵殻、貝殻、豚骨、牛骨、鶏がらなどの天然カルシウムを焼成後微粉砕し、醸造酢又は発酵処理にて溶解させ、未解離のカルシウム分を好ましくは醸造酢などで酸処理して溶解させ、加熱又は減圧蒸留して固形分を回収し、この回収物を加熱して有機物を蒸散させ、固化して調製するのが好ましい。   The ionized mineral component is preferably prepared from natural calcium such as eggshells, shells, pork bones, beef bones, chicken bones, etc., and is ionized by acid treatment under stirring and heating after baking to impart water solubility. This is preferably obtained by drying and solidifying, but a liquid before drying and solidifying may be used. Specifically, natural calcium such as eggshells, seashells, pork bones, beef bones, chicken bones, etc. is baked and finely pulverized, dissolved by brewing vinegar or fermentation treatment, and undissociated calcium content is preferably obtained by brewing vinegar, etc. It is preferable to prepare it by dissolving it by acid treatment, recovering the solid content by heating or distillation under reduced pressure, and heating the recovered material to evaporate and solidify the organic matter.

以上は必須成分であるが、必要に応じて水溶性食物繊維、例えば、ペクチン、グアーガム(グアー豆酵素分解物)、アガロース又は寒天、ポリデキストロースを含む人工食物繊維、アルギン酸ナトリウム又は海藻粉末、コンブ粉末、イヌリン又はキク科植物の根茎粉末、カラギーナンからなる群から選ばれる1種又は2種以上が添加されてもよい。特にグルコマンナン又はこんにゃく粉末を用いる場合は、適宜その他の水溶性食物繊維の保水構造形成能力を考慮して二成分以上を混合して用いることができる。フライドポテト及びフライドオニオンなどはそのもの自体が食物繊維成分を含有するから、イオン化ミネラル成分のみを噴霧することにより本発明の求める保水構造に障壁機能を持たせる効果がある程度発揮されるので、それを考慮して本発明の食品改質剤の組成を決定するのがよい。   The above are essential components, but water-soluble dietary fiber such as pectin, guar gum (guar bean enzyme degradation product), agarose or agar, artificial dietary fiber containing polydextrose, sodium alginate or seaweed powder, kombu powder as necessary One or two or more selected from the group consisting of inulin or Asteraceae rhizome powder and carrageenan may be added. In particular, when glucomannan or konjac powder is used, two or more components can be mixed and used in consideration of the water retention structure-forming ability of other water-soluble dietary fibers. Since fried potatoes and fried onions themselves contain dietary fiber components, spraying only ionized mineral components exhibits the effect of providing a barrier function to the water retention structure required by the present invention. The composition of the food modifier of the present invention is preferably determined.

従来、食品改質剤として水溶性食物繊維を使用する例として、糊状のこんにゃく原料を白身魚のすり身とを混合・撹拌し、これに石灰水を加えて成形したのちに、加熱凝固したカマボコこんにゃくの製造方法(特開昭55−165776号公報)。また、こんにゃく粉末と水を、アルギニン、ヒスチジンなどの塩基性アミノ酸、及び/又は、炭酸ナトリウム、炭酸カルシウム、リン酸2ナトリウムなどの塩基性塩類の存在下で膨張溶解して、pH9.0〜10.3のアルカリ性を帯びたこんにゃく糊を製造し、このこんにゃく糊を練り肉原料を初めとする食品原料と混合して、こんにゃく糊のゲル化のための加熱と食品原料の加工のための加熱を同時に行うことを特徴とするこんにゃく添加食品の製造方法(特公平7−73482号公報)が提案されているが、上記第1の方法は石灰水(カルシウム塩)を使用しており、上記第2の方法では、塩基性塩類及び/又は塩基性アミノ酸の使用によって、こんにゃく糊はアルカリ性を呈しており、このアルカリ性のこんにゃく糊を練り肉原料などに混合する点が特徴になっているが、実際には、こんにゃく糊のアルカリ性によってソーセージの呈味を損なうことは明らかであり、殊に、肉類をアルカリ側で食すると、苦味と渋みが出て来て、味が顕著に落ちることは良く知られている。また、カルシウム塩を使用した場合、こんにゃく糊を含有する練り肉食品などを一旦冷凍すると、解凍した場合にドリップが発生して、食味、食感がともに低下するという弊害があり、冷凍耐性の点で問題が多いとされていたので、水溶性食物繊維を食品自体に配合するときはカルシウム等のミネラル成分を併用しないのが常識的である。そこで、呈味を損なうことなく、練り肉食品の食感を改良するとともに、冷凍耐性を向上することを技術的課題とし、アルコールで接触処理し、或は処理しないこんにゃく粉末を練り肉原料に混合して、カルシウム塩などを使用せずにそのまま加熱調理することで、呈味性を損なわずに、練り肉食品の食感を有効に改良できるとともに、冷凍耐性をも向上する技術が提案されている(特許文献3)。即ち、こんにゃく粉末を水中に溶解して中性付近のこんにゃくペーストを得るとともに、カルシウム塩、ナトリウム塩などの金属塩の不存在下で、当該こんにゃくペーストをそのまま畜肉、魚肉などの練り肉原料に添加して、加熱調理するのが一般的である。したがって、水溶性食物繊維成分にイオン化カルシウムを含む水溶性ミネラル成分を配合して食品に保水性を付与しつつ障壁機能を持たせることができることは食品改質剤として画期的である。したがって、本発明に係る食品改質剤を用いることにより、種々の改質食品を提供できる。 したがって、本発明に係る食品改質剤を用いることにより、種々の改質食品を提供することを目的とするものでもある。   Conventionally, as an example of using water-soluble dietary fiber as a food modifier, paste-like konjac raw material is mixed and stirred with white fish surimi, lime water is added to this, and then heat-coagulated konjac konjac (Japanese Unexamined Patent Publication No. 55-165776). In addition, konjac powder and water are swelled and dissolved in the presence of basic amino acids such as arginine and histidine and / or basic salts such as sodium carbonate, calcium carbonate and disodium phosphate, and pH 9.0 to 10 .3 alkaline konjac paste is produced, and the konjac paste is kneaded and mixed with food ingredients such as meat ingredients, and then heated for gelatinizing konjac paste and for processing food ingredients. A method for producing a konnyaku-added food (Japanese Patent Publication No. 7-73482), which is characterized by being performed simultaneously, has been proposed, but the first method uses lime water (calcium salt), and the second method described above. In this method, by using basic salts and / or basic amino acids, the konjac paste exhibits alkalinity, and this alkaline konjac paste is kneaded and mixed with the raw material of meat. In fact, it is clear that sausage taste is impaired by the alkalinity of konjac paste, especially when meat is eaten on the alkali side, bitterness and astringency come out. It is well known that the taste drops significantly. In addition, when calcium salt is used, once the frozen meat containing konjac paste is frozen, drip is generated when it is thawed, and both the taste and texture are reduced. Therefore, when water-soluble dietary fiber is added to food itself, it is common sense not to use mineral components such as calcium together. Therefore, the technical problem is to improve the texture of the meat meat without sacrificing the taste and to improve the freezing tolerance, and the konjac powder that is contacted with alcohol or not processed is mixed with the raw material of the meat. In addition, by cooking as it is without using calcium salt etc., a technology has been proposed that can effectively improve the texture of kneaded meat food without impairing the taste, and also improve freezing tolerance (Patent Document 3). In other words, konjac powder is dissolved in water to obtain a konjac paste near neutrality, and in the absence of a metal salt such as calcium salt or sodium salt, the konjac paste is added as it is to raw material of meat such as livestock meat or fish meat. In general, cooking is performed by heating. Therefore, it is epoch-making as a food reforming agent that a water-soluble dietary fiber component can be blended with a water-soluble mineral component containing ionized calcium to impart water retention to the food and provide a barrier function. Therefore, various modified foods can be provided by using the food modifier according to the present invention. Therefore, it is also intended to provide various modified foods by using the food modifier according to the present invention.

第1に、水溶性食物繊維成分に対し、少なくともイオン化カルシウムを含む水溶性ミネラルを配合してなる請求項1に記載の食品改質剤を含む希薄水溶液を、油揚げ処理前の被対象物に直接又はその表面に形成した衣部位に噴霧して障壁性被膜を形成することができ、油揚げ調理しても油吸収を抑制し、ロ-カロリーの油揚げ食品を提供する。   1stly, the dilute aqueous solution containing the food modifier of Claim 1 formed by mix | blending the water-soluble mineral containing at least ionized calcium with respect to a water-soluble dietary fiber component is directly applied to the target object before frying. Alternatively, a barrier coating can be formed by spraying on the garment site formed on the surface, and oil absorption is suppressed even when fried, and a low-calorie fried food is provided.

第2に、油揚げ処理前の被対象物の表面又はその表面に形成した衣材料に本発明の食品改質剤を含ませ、水溶性食物繊維の形成する保水構造の表面に疎機能を付与し、油揚げ処理後、冷凍又は冷蔵してレンジアップにより油揚げ直後のパリパリ感を再現できるレンジアップ用油揚げ食品を提供する。   Secondly, the food modifier of the present invention is included in the surface of the object before the frying process or the clothing material formed on the surface of the object, and the surface of the water retention structure formed by the water-soluble dietary fiber is given a loose function. Provided is a range-up fried food that can reproduce the crisp feeling immediately after frying by freezing or refrigeration after the frying process.

第3に、水溶性食物繊維成分に対し、少なくともイオン化カルシウムを含む水溶性ミネラル成分を配合してなる食品改質剤をてんぷら粉に配合し、イオン化カルシウム換算で100〜5000ppm、好ましくは200〜2500ppmを含ませ、てんぷら衣に対して保水性質と障壁機能を持たせることができる改質てんぷら粉組成物を提供する。   Thirdly, a food modifier comprising a water-soluble dietary fiber component and a water-soluble mineral component containing at least ionized calcium is blended in the tempura powder, and is 100 to 5000 ppm, preferably 200 to 2500 ppm in terms of ionized calcium. And a modified tempura flour composition capable of providing water retention properties and a barrier function to the tempura garment.

第4に、水溶性食物繊維成分に対し、少なくともイオン化カルシウムを含む水溶性ミネラル成分を配合してなる食品改質剤をパン粉に配合または噴霧により付着させ、イオン化カルシウム換算で100〜5000ppm、好ましくは200〜2500ppmを含むことにより、保水性質と障壁機能を持たせた改質パン粉組成物を提供する。   Fourth, a food modifier formed by blending a water-soluble dietary fiber component with a water-soluble mineral component containing at least ionized calcium is added to bread crumbs or attached by spraying, and is 100 to 5000 ppm in terms of ionized calcium, preferably By containing 200-2500 ppm, the modified bread crumb composition which gave the water retention property and the barrier function is provided.

第5に、水溶性食物繊維成分に対し、少なくともイオン化カルシウムを含む水溶性ミネラル成分を配合してなる食品改質剤を小麦粉に配合し、イオン化カルシウム換算で100〜5000ppm、好ましくは200〜2500ppmを含ませ、油揚げ調理する食品に対し保水性質と障壁機能を持たせることができる改質粉組成物を提供する。   Fifth, with respect to the water-soluble dietary fiber component, a food modifier comprising a water-soluble mineral component containing at least ionized calcium is blended in the flour, and 100 to 5000 ppm, preferably 200 to 2500 ppm in terms of ionized calcium. Provided is a modified powder composition that can contain water retaining properties and a barrier function for foods to be fried and cooked.

(イオン化ミネラルAの調製)
貝殻及び卵殻の200ミクロン以下に粉砕し、発酵に必要な澱粉と重量比5:1の割合で配合し、攪拌し、重量比3倍水を加水し、麹菌を加え一定の温度(35℃〜40℃)で5〜7日間発酵させる。発酵終了後当該液に重量比最大25%の酢酸或いはその他の有機酸を加えて未解離のカルシウム等のミネラル分を解離させる。全量溶解、解離した液を加熱或いは減圧蒸留して固形分を回収する。回収した固形分を更に1200℃で加熱して有機物を蒸散させ、純粋なミネラル成分を回収する。回収した固形ミネラルに純水を加水し、用途に応じた濃度のミネラル液を調製する。卵殻の場合次の栄養成分を有している。
成分組成(100g中)
エネルギー 55.0Kcal 蛋白質 0.2g
糖質 0.0g 炭水化物 0.5g
ナトリウム 170mg、カルシウム 2600mg、マグネシウム 230mg
カリウム 69mg、リン 2.5mg
鉄 0.2mg、銅 50 μg、亜鉛 125μg、マンガン 75μg、
珪素 10ppm ヨウ素、イオウ、セレン 0mg、 残部 水分
(Preparation of ionized mineral A)
Grind shellfish and eggshell to 200 microns or less, mix with starch required for fermentation at a ratio of 5: 1 by weight, stir, add 3 times by weight of water, add koji mold, and add a certain temperature (35 ℃ ~ 40 ° C.) for 5-7 days. After completion of fermentation, acetic acid or other organic acid with a maximum weight ratio of 25% is added to the liquid to dissociate undissociated minerals such as calcium. The dissolved and dissociated liquid is heated or distilled under reduced pressure to recover the solid content. The recovered solid content is further heated at 1200 ° C. to evaporate the organic matter, and the pure mineral component is recovered. Pure water is added to the collected solid mineral to prepare a mineral liquid having a concentration according to the intended use. The eggshell has the following nutritional components.
Ingredient composition (in 100g)
Energy 55.0Kcal protein 0.2g
Carbohydrate 0.0g Carbohydrate 0.5g
Sodium 170mg, Calcium 2600mg, Magnesium 230mg
Potassium 69mg, Phosphorus 2.5mg
Iron 0.2 mg, Copper 50 μg, Zinc 125 μg, Manganese 75 μg,
Silicon 10ppm Iodine, sulfur, selenium 0mg, balance moisture

(イオン化ミネラルBの調製)
帆立貝殻から異物を除去し、臭気、色、形状を検査して焼成炉で1100〜1200℃で焼成し、自然冷却後200ミクロン以下に粉砕して金属探知機(10,000ガウス)を通した後400メッシュ以下に篩をかけ、再度金属探知機(10,000ガウス)に通し、品質検査して食添用焼成カルシウムを得る。他方、インドネシア産サトウキビを用い、発酵タンクで発酵させ、濾過して異物を除去した液を限界濾過(0.2μm)に付して菌体を除去し、品質検査して高酸度ビネガーを得る。この高酸度ビネガー85%に上記焼成カルシウム15%の一部を投入して撹拌とともに加熱して溶解させる。次いで焼成カルシウムを一部投入して撹拌とともに加熱して溶解させる。これを三度四度繰り返して焼成カルシウム全体を溶解させる。熟成はマイナス高電位を印加したり、磁力線照射して熟成を加速する。得られたイオン化ミネラル液の組成は次の通りであった(財団法人日本食品分析センターによる)。
イオン化ミネラルBの成分組成(100g中)
エネルギー 32Kcal
水分80.1g 蛋白質 0.1g 糖質 0.1g 脂質 0.1g
灰分 11.8g 炭水化物 8.1g
ナトリウム 46.5mg、カルシウム 4680mg、マグネシウム 10.2mg
カリウム 8.4mg、リン 6.3mg 鉄 0.28mg、銅 0.01mg、亜鉛 検出せず、マンガン 0.11mg、マンガン 0.11mg
衛生規格 一般細菌数 300以下/g 大腸菌 陰性/2.22g
総クロム、ヒ素、鉛、カドミウム、総水銀 検出ぜず
(Preparation of ionized mineral B)
Foreign matter was removed from the scallop shell, odor, color, and shape were inspected, baked at 1100-1200 ° C in a baking oven, pulverized to 200 microns or less after natural cooling, and passed through a metal detector (10,000 Gauss) After sieving to 400 mesh or less, it is passed again through a metal detector (10,000 Gauss), and quality inspection is performed to obtain calcined calcium for food addition. On the other hand, using Indonesian sugarcane, fermented in a fermentation tank, filtered to remove foreign matter, subjected to ultrafiltration (0.2 μm) to remove the cells, quality inspection to obtain a high acidity vinegar. Part of 15% of the calcined calcium is added to 85% of this high acidity vinegar and dissolved by heating with stirring. Next, a part of the calcined calcium is added and heated with stirring to dissolve. This is repeated three or four times to dissolve the entire calcined calcium. The aging is accelerated by applying a minus high potential or irradiating magnetic field lines. The composition of the obtained ionized mineral liquid was as follows (according to the Japan Food Analysis Center).
Component composition of ionized mineral B (in 100g)
Energy 32Kcal
Water 80.1g Protein 0.1g Carbohydrate 0.1g Lipid 0.1g
Ash 11.8g Carbohydrate 8.1g
Sodium 46.5mg, Calcium 4680mg, Magnesium 10.2mg
Potassium 8.4 mg, Phosphorus 6.3 mg Iron 0.28 mg, Copper 0.01 mg, Zinc Not detected, Manganese 0.11 mg, Manganese 0.11 mg
Hygiene standards General bacteria count 300 or less / g E. coli Negative / 2.22g
Total chromium, arsenic, lead, cadmium, total mercury

(食品改質剤中性希薄水溶液の調製)
水溶性食物繊維成分に対し、少なくともイオン化カルシウムをを含む水溶性ミネラル成分を10:1から1対1の重量比率で配合してなる食品改質剤を含む純水に溶解し、中性希薄水溶液とする。水溶性ミネラル成分はイオン化カルシウム換算で100から5000ppm、好ましくは200〜2500ppmの濃度とする。
(Preparation of neutral dilute aqueous solution of food modifier)
A water-soluble dietary fiber component is dissolved in pure water containing a food modifier formed by blending a water-soluble mineral component containing at least ionized calcium at a weight ratio of 10: 1 to 1: 1, and a neutral dilute aqueous solution. And The water-soluble mineral component has a concentration of 100 to 5000 ppm, preferably 200 to 2500 ppm in terms of ionized calcium.

(使用方法)
油揚げ処理前の被対象食品を上記希薄水溶液に浸漬するかまたは油処理前の対象食品に噴霧する。または、水分を含む衣材料総重量に対しイオン化カルシウムを200から2500ppmを含むように配合して用いる。
(how to use)
The target food before frying is immersed in the dilute aqueous solution or sprayed on the target food before oil. Or it mix | blends and uses ionized calcium so that it may contain 200-2500 ppm with respect to the clothing material total weight containing a water | moisture content.

(原料)
水溶性食物繊維成分としては、ペクチン、グアーガム(グアー豆酵素分解物)、アガロース又は寒天、グルコマンナン又はこんにゃく粉末、ポリデキストロースを含む人工食物繊維、アルギン酸ナトリウム又は海藻粉末、コンブ粉末、イヌリン又はキク科植物の根茎粉末、カラギーナンからなる群から選ばれる1種又は二種以上を用いる。特に、水溶性食物繊維成分がグルコマンナン又はこんにゃく粉末が好ましい。
(material)
Water-soluble dietary fiber components include pectin, guar gum (guar bean enzyme degradation product), agarose or agar, glucomannan or konjac powder, artificial dietary fiber containing polydextrose, sodium alginate or seaweed powder, kombu powder, inulin or asteraceae One or more selected from the group consisting of plant rhizome powder and carrageenan is used. In particular, the water-soluble dietary fiber component is preferably glucomannan or konjac powder.

(ポテトフライの調理)
水溶性食物繊維成分としてグルコマンナン100重量部に、上記方法で卵殻からイオン化カルシウムを含む水溶性ミネラル成分を調製して20重量部を配合し、これを純水1000mlに2000ppm(0.2%)となるように添加し、これを100〜200倍に希釈して中性希薄水溶液を調製する。これを短冊に切った生ポテトに直接噴霧して障壁性被膜を形成し、油揚げ調理を施してフライドポテトを調製した。他方、食品改質剤処理を施さない場合のフライドポテトとを調製し、両者の含有油脂量を酸分解法により比較した。本発明の場合100g当り13gであるのに対し従来法では20.3gであった。
(Cooking potato fries)
As a water-soluble dietary fiber component, 100 parts by weight of glucomannan is mixed with 20 parts by weight of a water-soluble mineral component containing ionized calcium from the eggshell by the above method, and 2000 ppm (0.2%) in 1000 ml of pure water. And is diluted 100 to 200 times to prepare a neutral dilute aqueous solution. This was directly sprayed on raw potato cut into strips to form a barrier coating, and fried cooking was performed to prepare french fries. On the other hand, french fries without food modifier treatment were prepared, and the amounts of fats and oils contained in both were compared by acid decomposition. In the case of the present invention, it was 13 g per 100 g, whereas it was 20.3 g in the conventional method.

(エビフライの調理)
水溶性食物繊維成分としてグルコマンナン100重量部に、上記方法で卵殻からイオン化カルシウムを含む水溶性ミネラル成分を調製して30重量部を配合し、これを純水1000mlに3000ppm(0.3%)となるように添加してこれを100〜200倍に希釈して中性希薄水溶液を調製する。これをパン粉仕上げをしたエビフライ衣に噴霧して衣に障壁性機能を持たせ、油揚げ調理を施してエビフライを調製した。他方、食品改質剤処理を施さない場合のエビフライを調製し、両者の含有油脂量を酸分解法により比較した。本発明の場合100g当り17.1gであるのに対し従来法では24.3gであった。
(Cooking shrimp)
As a water-soluble dietary fiber component, 100 parts by weight of glucomannan is prepared by mixing 30 parts by weight of water-soluble mineral components containing ionized calcium from the eggshell by the above method. The resulting solution is diluted to 100 to 200 times to prepare a neutral dilute aqueous solution. This was sprayed on a breaded shrimp fried garment to give the garment a barrier function, and then fried and cooked to prepare fried shrimp. On the other hand, fried shrimp in the case where the food modifier treatment was not applied was prepared, and the amounts of oil and fat contained in both were compared by an acid decomposition method. In the case of the present invention, it was 17.1 g per 100 g, whereas it was 24.3 g in the conventional method.

(トンカツの調理)
水溶性食物繊維成分としてグルコマンナン100重量部に、上記方法で卵殻からイオン化カルシウムを含む水溶性ミネラル成分を調製して50重量部を配合し、これを純水1000mlに5000ppm(0.5%)となるように添加してこれを200倍に希釈して中性希薄水溶液を調製する。これを用いて衣をつけるとともにその上をパン粉仕上げした豚肉に噴霧して衣に障壁性機能を持たせ、油揚げ調理を施してトンカツを調製した。他方、食品改質剤処理を施さない場合のトンカツを調製し、両者の含有油脂量を酸分解法により比較した。本発明の場合100g当り16.4gであるのに対し従来法では36.6gであった。
(Tonkatsu cooking)
As a water-soluble dietary fiber component, 100 parts by weight of glucomannan is prepared by mixing 50 parts by weight of a water-soluble mineral component containing ionized calcium from the eggshell by the above method, and this is added to 1000 ml of pure water at 5000 ppm (0.5%). And is diluted 200 times to prepare a neutral dilute aqueous solution. Using this, the garment was put on and sprayed on the crumbed pork to give the garment a barrier function. On the other hand, tonkatsu in the case where the food modifier treatment was not applied was prepared, and the amounts of fats and oils contained in both were compared by an acid decomposition method. In the case of the present invention, it was 16.4 g per 100 g, whereas it was 36.6 g in the conventional method.

(から揚げ)
水溶性食物繊維成分としてグルコマンナン100重量部に、上記方法で卵殻からイオン化カルシウムを含む水溶性ミネラル成分を調製して30重量部を配合し、これを純水1000mlに5000ppm(0.5%)となるように添加してこれを200倍に希釈して中性希薄水溶液を調製する。これをから揚げ粉に混ぜて衣をつけて衣に障壁性機能を持たせ、油揚げ調理を施してから揚げを調理した。他方、食品改質剤を入れないから揚げ粉でから揚げを調理し、両者の含有油脂量を酸分解法により比較した。本発明の場合100g当り8.1gであるのに対し従来法では25.2gであった。
(fried)
As a water-soluble dietary fiber component, 100 parts by weight of glucomannan is prepared by blending 30 parts by weight of a water-soluble mineral component containing ionized calcium from the eggshell by the above method, and this is added to 1000 ml of pure water at 5000 ppm (0.5%). And is diluted 200 times to prepare a neutral dilute aqueous solution. This was mixed with fried flour and put on clothes to give the clothes a barrier function, and then fried before cooking. On the other hand, fried food was cooked with fried powder because no food modifier was added, and the amounts of fats and oils contained in both were compared by an acid decomposition method. In the case of the present invention, it was 8.1 g per 100 g, whereas in the conventional method, it was 25.2 g.

上記本発明方法で、油揚げ処理後、冷凍した食品はレンジアップで調理しても離水がほとんど見られず、サクサクした揚げたての食感を保持することができる。   In the above-mentioned method of the present invention, after the frying process, the frozen food is almost free of water separation even when cooked in the range up, and can maintain a crispy fresh texture.

したがって、本発明の食品改質剤とてんぷら粉とから、てんぷら衣に対して保水性質と障壁機能を持たせる改質てんぷら粉を提供する。また、パン粉に本発明の改質材を配合すると、保水性質と障壁機能を持たせる改質パン粉を提供する。   Therefore, the modified tempura powder which gives the tempura clothes water retention property and a barrier function from the food modifier of the present invention and the tempura powder is provided. Moreover, when the modifying material of the present invention is blended with bread crumbs, modified bread crumbs having water retaining properties and barrier functions are provided.

(フライ麺の調製)
強力粉300gに塩5g、かん水2g、乳酸カルシウム3g、5%イオン化ミネラル液(By−930)2〜3g、20%コンニャクマンナン粉1〜3g及び水140gを使用してフライ麺生地を調製し、これを油100重量部に5%イオン化ミネラル液(By−930)0.1〜0.5重量部を添加した加熱した180度の油中でフライしてフライ麺を調製した。本発明の改質剤を使用しない場合に比して改質剤が少ない場合で30%、改質剤が多い場合で50%の油の吸収が抑制された。また、油の酸化が防止され、ほぼ20%の油消費が節減されることがわかった。本実施例ではめん生地に本発明の改質剤を配合したが、5%イオン化ミネラル液を希釈して200〜1000ppmの希釈液を調製し、湯上げ麺のフライ乾燥工程前にイオン化ミネラル液に浸漬するかイオン化ミネラル液を噴霧した後フライ乾燥工程に付することにより油吸収を30ないし50%以上低減してフライ即席麺を調製することができる。
(Preparation of fried noodles)
Prepare fried noodle dough using 300 g of strong powder, 2 g of salt water, 2 g of brine, 3 g of calcium lactate, 2-3 g of 5% ionized mineral liquid (By-930), 1-3 g of 20% konjac mannan powder and 140 g of water. Fried noodles were prepared by heating in a heated 180 degree oil in which 0.1 part by weight of 5% ionized mineral liquid (By-930) was added to 100 parts by weight of oil. As compared with the case where the modifier of the present invention is not used, the oil absorption is suppressed by 30% when the modifier is small, and by 50% when the modifier is large. It was also found that oil oxidation was prevented and oil consumption was reduced by almost 20%. In this example, the noodle dough was blended with the modifier of the present invention, but 5% ionized mineral liquid was diluted to prepare a diluted solution of 200 to 1000 ppm. It is possible to prepare fried instant noodles by reducing oil absorption by 30 to 50% or more by dipping or spraying an ionized mineral liquid and then subjecting to a frying drying process.

(フライパン粉の調製)
強力粉4000gにショートニング120g、ブドウ糖70g、ドライイースト65g、塩40g、イーストフード3,5g、乳酸カルシウム40〜120g(対粉1〜3%)、5%イオン化ミネラル液80〜120g(対粉2〜3%)水2600gを混練して発酵させ、パン生地を調製し、常法によりパン固体を焼成し、乾燥又は凍結して粉砕し、乾燥パン粉又は生パン粉を調製した。このパン粉はイオン化ミネラル、乳酸カルシウムの含有量の少ない場合から多くした場合にわたってフライ調製時の油吸収率を30〜50%削減できるパン粉フライを調製することができた。必要に応じて20%コンニャクマンナン粉を添加してパン粉を調製できるが、パンの膨化率が低下するので、水分率の調整が必要な場合以外は20%コンニャクマンナン粉の添加を制限した。なお、水分率が35〜40%を超えると油吸収の低減率はさらに向上することがわかった。また、このパン粉を使用した場合においても油100重量部に5%イオン化ミネラル液(By−930)0.1〜0.5重量部を添加した加熱した180度の油中でフライして油調することにより油の酸化が防止され、ほぼ20%の油消費が節減されることがわかった。常法により調製したパン粉に本発明の改質剤希釈液を噴霧しても所定の油吸収を低減できるのはもちろんである。
(Preparation of frying powder)
4000g of strong powder, shortening 120g, glucose 70g, dry yeast 65g, salt 40g, yeast food 3,5g, calcium lactate 40-120g (powder 1-3%), 5% ionized mineral liquid 80-120g (powder 2-3) %) 2600 g of water was kneaded and fermented to prepare bread dough, bread solids were baked by a conventional method, dried or frozen and ground to prepare dry bread crumbs or raw bread crumbs. This bread crumb was able to prepare bread crumb frying which can reduce the oil absorption rate at the time of frying preparation by 30 to 50% over the cases where the content of ionized mineral and calcium lactate is small to large. If necessary, bread crumbs can be prepared by adding 20% konjac mannan flour. However, since the expansion rate of bread is reduced, the addition of 20% konjac mannan flour was restricted except when the moisture content was required to be adjusted. In addition, when the moisture content exceeded 35 to 40%, it turned out that the reduction rate of oil absorption improves further. Even when this bread crumb is used, it is fried in heated 180 degree oil in which 0.1 part by weight of 5% ionized mineral liquid (By-930) is added to 100 parts by weight of oil. It has been found that this prevents oil oxidation and reduces oil consumption by approximately 20%. Of course, the predetermined oil absorption can be reduced by spraying the modifier diluent of the present invention on bread crumb prepared by a conventional method.

Claims (8)

卵殻、貝殻、豚骨、牛骨、鶏がらなどの天然カルシウム材を焼成後粉砕し、発酵又は醸造酢を用いてイオン化してなる液状又は固形イオン化ミネラル成分を含み、食品中の食物繊維と協働して保水構造を形成可能で、食品油調理時の油吸収率を低下させる機能を有することを特徴とする食品改質剤。   It contains a liquid or solid ionized mineral component that is pulverized after calcination of natural calcium materials such as eggshells, seashells, pork bones, cow bones, and chicken, and is ionized using fermentation or brewed vinegar, and cooperates with dietary fiber in foods. A food reforming agent characterized in that it can function to form a water retaining structure and has a function of reducing the oil absorption rate during cooking of food oil. 更に有機酸カルシウムを5重量%含有イオン化ミネラル成分に代替して配合し、5重量%含有イオン化ミネラル成分換算で0.5重量部以上5.0重量部に対し有機酸カルシウム0.5重量部以上3.0重量部の比率で配合してなる請求項1記載の食品改質剤。   Further, 5% by weight of organic acid calcium is contained in place of the ionized mineral component, and 0.5% by weight or more of organic acid calcium is 0.5 parts by weight or more in terms of 5% by weight of ionized mineral component. The food modifier according to claim 1, which is blended at a ratio of 3.0 parts by weight. 更にグルコマンナン又はコンニャク(20重量%含有)成分を5重量%含有イオン化ミネラル成分換算で0.5〜5重量部に対し0.5〜5重量部の重量比率で配合してなる請求項1記載の食品改質剤。   The glucomannan or konjac component (containing 20% by weight) is further blended at a weight ratio of 0.5 to 5 parts by weight with respect to 0.5 to 5 parts by weight in terms of an ionized mineral component containing 5% by weight. Food modifier. 5重量%含有イオン化ミネラル成分換算で0.5〜5.0重量部、乳酸カルシウム0.5〜3重量部及びグルコマンナン又はコンニャク(20重量%含有)成分0.5〜5.0重量部を含み、油調理前の固形食品を浸漬または食品表面に噴霧して用いる請求項1〜3のいずれかに記載の食品改質剤からなり、水溶液形態でイオン化カルシウムを100ppm以上5000ppm以下を含むことを特徴とする調理前食品処理希薄水溶液。   0.5 to 5.0 parts by weight in terms of 5% by weight-containing ionized mineral component, 0.5 to 3 parts by weight of calcium lactate and 0.5 to 5.0 parts by weight of glucomannan or konjac (20% by weight) component It comprises the food modifier according to any one of claims 1 to 3 which is used by immersing or spraying a solid food before oil cooking on the food surface, and containing 100 ppm or more and 5000 ppm or less of ionized calcium in the form of an aqueous solution. Dilute aqueous solution for food processing before cooking. てんぷら粉組成物であって、請求項1〜3のいずれかに記載の改質剤を小麦粉100重量部に対し5重量%含有イオン化ミネラル成分換算で0.5〜5.0重量%、乳酸カルシウム0.5〜3.0重量%及びグルコマンナン又はコンニャク(20重量%含有)成分0.5〜5.0重量部を含み、改質剤非添加の場合に比して30〜50%油分吸収を減少させることを特徴とするてんぷら粉組成物。   It is a tempura flour composition, containing 5% by weight of the modifier according to any one of claims 1 to 3 in terms of an ionized mineral component with respect to 100 parts by weight of wheat flour, calcium lactate Contains 0.5 to 3.0% by weight and 0.5 to 5.0 parts by weight of glucomannan or konjac (containing 20% by weight) component, and absorbs 30 to 50% of oil as compared to the case where no modifier is added. A tempura flour composition characterized by reducing the amount of tempura. 即席フライ麺およびスパゲッティなどの油調理麺組成物であって、請求項1〜3のいずれかに記載の改質剤を小麦粉100重量部に対し5重量%含有イオン化ミネラル換算で0.5〜5.0重量%、乳酸カルシウム0.5〜3.0重量%及びグルコマンナン又はコンニャク(20重量%含有)成分0.5〜5.0重量部を含み、改質剤非添加の場合に比して30〜50%油分吸収を減少させることを特徴とする油調理理麺組成物。   Oil cooked noodle compositions such as instant fried noodles and spaghetti, and containing 5% by weight of the modifier according to any one of claims 1 to 3 in terms of ionized minerals in an amount of 0.5 to 5 0.05% by weight, calcium lactate 0.5-3.0% by weight and glucomannan or konjac (containing 20% by weight) component 0.5-5.0 parts by weight, compared with the case where no modifier is added An oil-cooked noodle composition characterized by reducing oil absorption by 30 to 50%. パン粉組成物に対し、請求項1又は2に記載の改質剤を小麦粉100重量部に対5重量%含有イオン化ミネラル換算で0.5〜5.0重量%、乳酸カルシウム0.5〜3.0重量%を含み、改質剤非添加の場合に比して30〜50%油分吸収を減少させることを特徴とするフライ用パン粉。   Containing 5% by weight of the modifier of claim 1 or 2 to 100 parts by weight of wheat flour in terms of ionized mineral, 0.5 to 5.0% by weight of calcium lactate, and 0.5 to 3% of calcium lactate. A bread crumb for frying characterized by containing 0% by weight and reducing oil absorption by 30 to 50% as compared with the case where no modifier is added. 請求項6又は7記載のてんぷら粉又はパン粉を衣とし、5重量%含有イオン化ミネラル換算で0.1〜0.5重量%を含む揚げ油にで油調理した後、冷凍保存したことを特徴とするレンジアップ用冷凍油調理食品。 The tempura flour or bread crumbs according to claim 6 or 7 is used as a garment, and after cooking with fried oil containing 0.1 to 0.5% by weight in terms of 5% by weight containing ionized minerals, it is stored frozen. Frozen oil cooked food for range up.
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