JPWO2009028483A1 - Oil composition - Google Patents
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- JPWO2009028483A1 JPWO2009028483A1 JP2009530119A JP2009530119A JPWO2009028483A1 JP WO2009028483 A1 JPWO2009028483 A1 JP WO2009028483A1 JP 2009530119 A JP2009530119 A JP 2009530119A JP 2009530119 A JP2009530119 A JP 2009530119A JP WO2009028483 A1 JPWO2009028483 A1 JP WO2009028483A1
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- oil
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- transesterified
- roasted
- fat
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- 239000000203 mixture Substances 0.000 title claims abstract description 140
- 239000003921 oil Substances 0.000 claims abstract description 834
- 235000019198 oils Nutrition 0.000 claims abstract description 832
- 239000003549 soybean oil Substances 0.000 claims abstract description 153
- 235000012424 soybean oil Nutrition 0.000 claims abstract description 153
- 239000008159 sesame oil Substances 0.000 claims abstract description 115
- 235000011803 sesame oil Nutrition 0.000 claims abstract description 115
- 239000000796 flavoring agent Substances 0.000 claims abstract description 107
- 235000019634 flavors Nutrition 0.000 claims abstract description 106
- 230000001877 deodorizing effect Effects 0.000 claims abstract description 20
- 239000003925 fat Substances 0.000 claims description 306
- 235000019197 fats Nutrition 0.000 claims description 295
- 235000019645 odor Nutrition 0.000 claims description 219
- 235000019484 Rapeseed oil Nutrition 0.000 claims description 75
- 235000005687 corn oil Nutrition 0.000 claims description 58
- 239000002285 corn oil Substances 0.000 claims description 58
- 230000004907 flux Effects 0.000 claims description 49
- 235000019482 Palm oil Nutrition 0.000 claims description 46
- 239000002540 palm oil Substances 0.000 claims description 46
- 238000000034 method Methods 0.000 claims description 34
- 235000013305 food Nutrition 0.000 claims description 24
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 22
- 235000014593 oils and fats Nutrition 0.000 claims description 10
- 239000004033 plastic Substances 0.000 claims description 6
- 229920003023 plastic Polymers 0.000 claims description 6
- 235000015173 baked goods and baking mixes Nutrition 0.000 claims description 5
- 239000006071 cream Substances 0.000 claims description 5
- 239000000839 emulsion Substances 0.000 claims description 5
- 238000005187 foaming Methods 0.000 claims description 3
- 235000011850 desserts Nutrition 0.000 claims 2
- 239000002994 raw material Substances 0.000 abstract description 27
- 238000010438 heat treatment Methods 0.000 abstract description 22
- 238000012360 testing method Methods 0.000 description 41
- 230000001953 sensory effect Effects 0.000 description 37
- 239000000047 product Substances 0.000 description 29
- 238000011156 evaluation Methods 0.000 description 15
- 238000004519 manufacturing process Methods 0.000 description 14
- 230000008569 process Effects 0.000 description 14
- 238000005406 washing Methods 0.000 description 14
- 238000004042 decolorization Methods 0.000 description 13
- 238000003825 pressing Methods 0.000 description 13
- 238000011282 treatment Methods 0.000 description 13
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 12
- 230000006866 deterioration Effects 0.000 description 11
- 239000002244 precipitate Substances 0.000 description 11
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 10
- 238000010411 cooking Methods 0.000 description 10
- 239000003463 adsorbent Substances 0.000 description 9
- 238000004332 deodorization Methods 0.000 description 9
- 241000207961 Sesamum Species 0.000 description 8
- 235000003434 Sesamum indicum Nutrition 0.000 description 8
- 239000003513 alkali Substances 0.000 description 8
- 244000068988 Glycine max Species 0.000 description 7
- 235000010469 Glycine max Nutrition 0.000 description 7
- 235000013606 potato chips Nutrition 0.000 description 7
- 238000007670 refining Methods 0.000 description 7
- 240000002791 Brassica napus Species 0.000 description 6
- 235000004977 Brassica sinapistrum Nutrition 0.000 description 6
- 235000009508 confectionery Nutrition 0.000 description 6
- 238000001914 filtration Methods 0.000 description 6
- 238000002156 mixing Methods 0.000 description 6
- 238000000746 purification Methods 0.000 description 6
- 239000000243 solution Substances 0.000 description 6
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 5
- 238000005119 centrifugation Methods 0.000 description 5
- 239000004927 clay Substances 0.000 description 5
- 238000000605 extraction Methods 0.000 description 5
- DTOSIQBPPRVQHS-PDBXOOCHSA-N alpha-linolenic acid Chemical compound CC\C=C/C\C=C/C\C=C/CCCCCCCC(O)=O DTOSIQBPPRVQHS-PDBXOOCHSA-N 0.000 description 4
- 239000007864 aqueous solution Substances 0.000 description 4
- 239000006103 coloring component Substances 0.000 description 4
- 239000010779 crude oil Substances 0.000 description 4
- 238000001035 drying Methods 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- -1 etc.) Substances 0.000 description 4
- 230000001629 suppression Effects 0.000 description 4
- 239000004698 Polyethylene Substances 0.000 description 3
- 239000000654 additive Substances 0.000 description 3
- 235000014113 dietary fatty acids Nutrition 0.000 description 3
- 239000000194 fatty acid Substances 0.000 description 3
- 229930195729 fatty acid Natural products 0.000 description 3
- 150000004665 fatty acids Chemical class 0.000 description 3
- 239000003205 fragrance Substances 0.000 description 3
- 230000006872 improvement Effects 0.000 description 3
- 150000002978 peroxides Chemical class 0.000 description 3
- 150000003904 phospholipids Chemical class 0.000 description 3
- 229920000573 polyethylene Polymers 0.000 description 3
- 238000012545 processing Methods 0.000 description 3
- 238000004904 shortening Methods 0.000 description 3
- 238000003860 storage Methods 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- 244000061456 Solanum tuberosum Species 0.000 description 2
- 235000002595 Solanum tuberosum Nutrition 0.000 description 2
- 230000000996 additive effect Effects 0.000 description 2
- 235000020661 alpha-linolenic acid Nutrition 0.000 description 2
- 238000007865 diluting Methods 0.000 description 2
- 239000008157 edible vegetable oil Substances 0.000 description 2
- 235000021588 free fatty acids Nutrition 0.000 description 2
- 239000012676 herbal extract Substances 0.000 description 2
- 229960004488 linolenic acid Drugs 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Chemical class 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 238000001556 precipitation Methods 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 239000000344 soap Substances 0.000 description 2
- 238000001256 steam distillation Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 244000046052 Phaseolus vulgaris Species 0.000 description 1
- 235000010627 Phaseolus vulgaris Nutrition 0.000 description 1
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 1
- 229930006000 Sucrose Natural products 0.000 description 1
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 description 1
- 230000002159 abnormal effect Effects 0.000 description 1
- 150000001299 aldehydes Chemical class 0.000 description 1
- 239000012670 alkaline solution Substances 0.000 description 1
- 230000036528 appetite Effects 0.000 description 1
- 235000019789 appetite Nutrition 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 238000004364 calculation method Methods 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 235000013339 cereals Nutrition 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 229930002875 chlorophyll Natural products 0.000 description 1
- 235000019804 chlorophyll Nutrition 0.000 description 1
- ATNHDLDRLWWWCB-AENOIHSZSA-M chlorophyll a Chemical compound C1([C@@H](C(=O)OC)C(=O)C2=C3C)=C2N2C3=CC(C(CC)=C3C)=[N+]4C3=CC3=C(C=C)C(C)=C5N3[Mg-2]42[N+]2=C1[C@@H](CCC(=O)OC\C=C(/C)CCC[C@H](C)CCC[C@H](C)CCCC(C)C)[C@H](C)C2=C5 ATNHDLDRLWWWCB-AENOIHSZSA-M 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 description 1
- 244000013123 dwarf bean Species 0.000 description 1
- 235000013312 flour Nutrition 0.000 description 1
- 238000011010 flushing procedure Methods 0.000 description 1
- 238000007429 general method Methods 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 238000004898 kneading Methods 0.000 description 1
- 206010025482 malaise Diseases 0.000 description 1
- 235000013310 margarine Nutrition 0.000 description 1
- 239000003264 margarine Substances 0.000 description 1
- 230000000873 masking effect Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 229910052901 montmorillonite Inorganic materials 0.000 description 1
- 230000003472 neutralizing effect Effects 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 238000007127 saponification reaction Methods 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 239000006228 supernatant Substances 0.000 description 1
- 238000005809 transesterification reaction Methods 0.000 description 1
- 150000003626 triacylglycerols Chemical class 0.000 description 1
- 235000015112 vegetable and seed oil Nutrition 0.000 description 1
- 239000008158 vegetable oil Substances 0.000 description 1
- 230000017260 vegetative to reproductive phase transition of meristem Effects 0.000 description 1
- 238000009875 water degumming Methods 0.000 description 1
- 239000008256 whipped cream Substances 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23D—EDIBLE OILS OR FATS, e.g. MARGARINES, SHORTENINGS, COOKING OILS
- A23D9/00—Other edible oils or fats, e.g. shortenings, cooking oils
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23D—EDIBLE OILS OR FATS, e.g. MARGARINES, SHORTENINGS, COOKING OILS
- A23D9/00—Other edible oils or fats, e.g. shortenings, cooking oils
- A23D9/02—Other edible oils or fats, e.g. shortenings, cooking oils characterised by the production or working-up
- A23D9/04—Working-up
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
- A23L11/00—Pulses, i.e. fruits of leguminous plants, for production of food; Products from legumes; Preparation or treatment thereof
- A23L11/30—Removing undesirable substances, e.g. bitter substances
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
- A23L5/00—Preparation or treatment of foods or foodstuffs, in general; Food or foodstuffs obtained thereby; Materials therefor
- A23L5/10—General methods of cooking foods, e.g. by roasting or frying
- A23L5/11—General methods of cooking foods, e.g. by roasting or frying using oil
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
- A23L5/00—Preparation or treatment of foods or foodstuffs, in general; Food or foodstuffs obtained thereby; Materials therefor
- A23L5/20—Removal of unwanted matter, e.g. deodorisation or detoxification
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
- A23L5/00—Preparation or treatment of foods or foodstuffs, in general; Food or foodstuffs obtained thereby; Materials therefor
- A23L5/20—Removal of unwanted matter, e.g. deodorisation or detoxification
- A23L5/27—Removal of unwanted matter, e.g. deodorisation or detoxification by chemical treatment, by adsorption or by absorption
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
- A23L9/00—Puddings; Cream substitutes; Preparation or treatment thereof
- A23L9/20—Cream substitutes
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11B—PRODUCING, e.g. BY PRESSING RAW MATERIALS OR BY EXTRACTION FROM WASTE MATERIALS, REFINING OR PRESERVING FATS, FATTY SUBSTANCES, e.g. LANOLIN, FATTY OILS OR WAXES; ESSENTIAL OILS; PERFUMES
- C11B3/00—Refining fats or fatty oils
- C11B3/12—Refining fats or fatty oils by distillation
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11C—FATTY ACIDS FROM FATS, OILS OR WAXES; CANDLES; FATS, OILS OR FATTY ACIDS BY CHEMICAL MODIFICATION OF FATS, OILS, OR FATTY ACIDS OBTAINED THEREFROM
- C11C3/00—Fats, oils, or fatty acids by chemical modification of fats, oils, or fatty acids obtained therefrom
- C11C3/04—Fats, oils, or fatty acids by chemical modification of fats, oils, or fatty acids obtained therefrom by esterification of fats or fatty oils
- C11C3/10—Ester interchange
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Food Science & Technology (AREA)
- Polymers & Plastics (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Health & Medical Sciences (AREA)
- Nutrition Science (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Wood Science & Technology (AREA)
- General Chemical & Material Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Botany (AREA)
- Microbiology (AREA)
- Edible Oils And Fats (AREA)
- Fats And Perfumes (AREA)
- Grain Derivatives (AREA)
- Confectionery (AREA)
Abstract
大豆油等の臭気を有する油脂に焙煎ゴマ油等の焙煎油を含有させても含有させた焙煎油の生風味が実質的にせず、また、大豆油等の油脂が有する原料特有の不快な臭い(例えば、大豆油での青臭さ)や、戻り臭、加熱臭が抑制された油脂組成物を提供すること。臭気を有する油脂と、脱臭工程を経て製造された焙煎油と、を含有する油脂組成物であって、該油脂組成物中の前記焙煎油の含有量が、前記臭気を有する油脂自体が有する臭気を実質的に抑制し、かつ、前記焙煎油の風味を実質的に感じない量とすることで戻り臭等が抑制することができる。Even if the roasted oil such as roasted sesame oil is added to the odorous oil such as soybean oil, the raw flavor of the roasted oil contained is not substantial, and the unpleasantness peculiar to the raw materials possessed by the fat such as soybean oil To provide an oil / fat composition in which an unpleasant odor (for example, a blue odor in soybean oil), a return odor, and a heating odor are suppressed. An oil / fat composition containing an odorous fat and a roasted oil produced through a deodorizing step, wherein the content of the roasted oil in the oil / fat composition is the fat / oil having the odor itself. The return odor and the like can be suppressed by setting the amount to substantially suppress the odor of the roasting oil and substantially not feel the flavor of the roasted oil.
Description
本発明は、大豆油等の原料特有の不快な臭い、保存時の戻り臭、および加熱調理時の加熱臭が抑制された油脂組成物に関する。 The present invention relates to an oil and fat composition in which unpleasant odor peculiar to raw materials such as soybean oil, a return odor during storage, and a heating odor during cooking are suppressed.
植物油は、精製した直後は問題のない風味でも、光や熱等によって劣化し、風味上問題になる。一般的には、フラックス油、エゴマ油等のαリノレン酸を多く含む油脂は、安定性が低く、風味劣化しやすいため、食用としての用途は限られる。 Even if the vegetable oil has no problem immediately after refining, it is deteriorated by light, heat, etc., and becomes a problem in flavor. In general, fats and oils containing a large amount of α-linolenic acid, such as flux oil and sesame oil, have low stability and are liable to deteriorate in flavor, so that their edible uses are limited.
しかし、αリノレン酸が多くない油脂でも、風味上、問題となる場合がある。特に、大豆油およびコーン油等は、「原料特有の不快な臭い」(大豆油の「青臭さ」、コーン油の「穀物の様な臭い」)が問題となる場合がある。従って、これらの「原料特有の不快な臭い」の改善が求められている。 However, even fats and oils that are not rich in α-linolenic acid may cause problems in flavor. In particular, soybean oil, corn oil and the like may have a problem of “unpleasant odor peculiar to raw materials” (“blue smell” of soybean oil, “grainy smell” of corn oil). Therefore, improvement of these “unpleasant odors peculiar to raw materials” is demanded.
また、大豆油は、劣化の初期の段階に特有の「戻り臭」が発生することから、風味上の面で使用を制限されることがある。コーン油、パーム油についても、劣化の初期の段階に特有の「戻り臭」が発生することから、風味上の面で使用を制限されることがある。「戻り臭」とは、油の劣化過程の初期段階で、過酸化物価がほとんど上昇していない段階において発生する異臭のことである。特に、大豆油においてはこの戻り臭が発生しやすく、その臭いも独特の「青豆臭」を発する。戻り臭の発生の大きな要因として光の影響がある。このため、プラスチック製の透明容器に収容した大豆油は、戻り臭の発生が常に大きな問題とされてきた。一方、パーム油の「戻り臭」は、冷暗所に保管していても発生するため、大豆油同様に使用量を制限される。また、パーム油は、精製油として輸入されることが多いが、その間に「戻り臭」等により風味劣化を起こすので、再精製を行い、風味を改善して製品化している。従って、これらの「戻り臭」の改善が求められている。 In addition, since soybean oil produces a “return odor” peculiar to the initial stage of deterioration, its use may be restricted in terms of flavor. As for corn oil and palm oil, the “return odor” peculiar to the initial stage of deterioration is generated, so that the use of corn oil and palm oil may be restricted in terms of flavor. The “return odor” is an abnormal odor that is generated at the initial stage of the deterioration process of the oil and at a stage where the peroxide value hardly increases. In particular, soybean oil tends to generate this return odor, and the odor also produces a unique “green bean odor”. The influence of light is a major factor in the generation of return odor. For this reason, the generation of a return odor has always been a major problem with soybean oil contained in a plastic transparent container. On the other hand, since the “return odor” of palm oil is generated even when stored in a cool and dark place, the amount of use is limited like soybean oil. In addition, palm oil is often imported as refined oil, but during that period, flavor deterioration occurs due to “return odor” and the like, so re-refining is performed to improve the flavor and commercialize the product. Therefore, improvement of these “return odors” is demanded.
また、高温に加熱された多量の食用油脂に食材を投入して行う加熱調理、すなわち揚げ物調理では、熱や水分、被調理品の成分等によって、油に様々な劣化が生じる。油の加熱による劣化としては、トリグリセリドから脂肪酸が遊離する加水分解反応や、酸化反応における二次生成物である様々なケトンやアルデヒド等の化合物の発生があり、これらの化合物が空気中に揮散し、異臭や刺激臭の原因となっている。このような物質の中には、所謂「油酔い」の原因と考えられるものも含まれており、調理する者の食欲減退を引き起こし、揚げ物調理を行う意欲を失わせることにもつながっている。これらの加熱調理時における油の加熱による劣化は、「加熱臭」と呼ばれている。特に、大豆油は、使用頻度が多いことから、「加熱臭」が問題となることがある。従って、これらの「加熱臭」の改善が求められている。 In addition, in cooking that is performed by adding food to a large amount of edible oils and fats heated to a high temperature, that is, deep-fried food cooking, various deteriorations occur in the oil depending on heat, moisture, ingredients of the food to be cooked, and the like. Degradation due to heating of oil includes hydrolysis reaction that liberates fatty acids from triglycerides and generation of various ketones and aldehydes, which are secondary products in oxidation reactions, and these compounds volatilize in the air. Causes off-flavors and pungent odors. Some of these substances are considered to be the cause of so-called “oil sickness”, which causes a decrease in appetite of cooks and leads to loss of willingness to cook fried foods. The deterioration due to heating of oil during cooking is called “heating odor”. In particular, since soybean oil is frequently used, “heating odor” may be a problem. Therefore, improvement of these “heating odors” is required.
これを解消するものとして、例えば、特許文献1には大豆油に菜種油を添加して、大豆油の戻り臭や加熱調理時に発生する加熱臭を低減させた大豆・菜種配合油が開示されている。 In order to solve this problem, for example, Patent Document 1 discloses a soybean / rapeseed compounded oil in which rapeseed oil is added to soybean oil to reduce the return odor of soybean oil and the heating odor generated during cooking. .
また、ハーブエキスと焙煎ゴマ油等の香味油とを添加して、ハーブエキスの匂いと香味油の好ましい香り風味とでマスキングすることが通常に行われている(例えば、特許文献2)。
しかしながら、特許文献1では、大豆油の青臭さや戻り臭は、低減されているが十分でない。また、特許文献2では、油脂中に2〜6%の焙煎ゴマ油を添加しているので、調理品にゴマ風味がつき、汎用性は低い。例えば、ゴマ油の生風味がついた大豆油をドレッシングに入れると、ゴマ風味がするドレッシングとなり、用途が限定される。また、フライ調理でも常にフライ調理品(天ぷら等)にゴマ風味がつくため、フライ調理品本来の風味を損ねることになる等、汎用性に欠けることになる。 However, in Patent Document 1, the blue odor and return odor of soybean oil are reduced but not sufficient. Moreover, in patent document 2, since 2-6% roasted sesame oil is added in fats and oils, a sesame flavor is attached to cooking goods, and versatility is low. For example, if soybean oil with a raw flavor of sesame oil is added to the dressing, it becomes a dressing with a sesame flavor, and its use is limited. Moreover, since the sesame flavor is always added to the fried cooked product (tempura, etc.) even in the fried cooking, the original flavor of the fried cooked product is impaired, and the versatility is lacking.
このように、焙煎ゴマ油等の香味油を添加し、この香味油の風味を付与することで、大豆油等の油脂が有する原料特有の不快な臭いや、戻り臭、加熱臭等を抑制することは行われているが、添加した香味油の風味を付与することなく、青臭さや戻り臭、加熱臭を抑制することは検討されていない。 In this way, by adding flavor oil such as roasted sesame oil and imparting the flavor of this flavor oil, the unpleasant odor, return odor, heating odor, etc. peculiar to raw materials of oils such as soybean oil are suppressed. However, it has not been studied to suppress the blue odor, the return odor, and the heating odor without imparting the flavor of the added flavor oil.
以上の課題に鑑み、本発明の目的は、大豆油、コーン油、パーム系油脂、フラックス油、エゴマ油等の油脂に焙煎ゴマ油等の焙煎油を添加しても添加した焙煎油の生風味が実質的にせず、また、大豆油、コーン油、パーム系油脂、フラックス油、エゴマ油等の油脂が有する原料特有の不快な臭い(例えば、大豆油での青臭さ)や、戻り臭、加熱臭が抑制された油脂組成物を提供することにある。 In view of the above problems, the object of the present invention is to add roasted oil such as roasted sesame oil to fats and oils such as soybean oil, corn oil, palm oil and fat, flux oil and sesame oil. Raw flavor is not substantial, and unpleasant odor peculiar to raw materials (for example, blue odor in soybean oil) or return odor, such as soybean oil, corn oil, palm oil fat, flux oil, sesame oil, etc. It is in providing the oil-fat composition in which the heating odor was suppressed.
本発明者らは、上記課題を解決すべく鋭意研究を重ね検討した結果、大豆油、コーン油、パーム系油脂、フラックス油、エゴマ油等の油脂中に焙煎油を極微量添加することで、添加した焙煎油の風味がせず、また、大豆油等の油脂が有する原料特有の不快な臭いや、戻り臭が抑制されるという知見を得、本発明を完成するに至った。より具体的には、本発明は以下のようなものを提供する。 As a result of intensive studies to solve the above problems, the present inventors have added a very small amount of roasting oil to fats and oils such as soybean oil, corn oil, palm oil and fat, flux oil and sesame oil. The inventors have obtained the knowledge that the added roasted oil does not have a flavor and that the unpleasant odor peculiar to raw materials possessed by fats and oils such as soybean oil and the return odor are suppressed, and the present invention has been completed. More specifically, the present invention provides the following.
(1) 臭気を有する油脂と、脱臭工程を経て製造された焙煎油と、を含有する油脂組成物であって、該油脂組成物中の前記焙煎油の含有量が、前記臭気を有する油脂自体が有する臭気を実質的に抑制し、かつ、前記焙煎油の風味を実質的に感じない量である油脂組成物。 (1) An oil / fat composition containing an odorous fat and oil and a roasted oil produced through a deodorizing step, wherein the content of the roasted oil in the oil / fat composition has the odor. An oil / fat composition in an amount that substantially suppresses the odor of the oil / fat itself and does not substantially feel the flavor of the roasted oil.
発明者の鋭意研究の成果により、焙煎油は、芳香がしない濃度でも臭いを抑制する効果があることを見出した。焙煎油を大豆油、コーン油、パーム系油脂、フラックス油、エゴマ油等の臭気を有する油脂に含有させることにより、臭気の発生が抑制される。また、その含有量は、大豆油、コーン油、パーム系油脂、フラックス油、エゴマ油等の油脂が有する臭気を実質的に抑制し、かつ、焙煎油の風味を実質的に感じない量であるので、焙煎油の芳香や風味が強すぎて油脂組成物の使用用途が限定されることがない。焙煎油は臭気を有する油脂の戻り臭等を抑制するが、特に、大豆油のように原料特有の不快な臭いがして、かつ、劣化したときに不快な臭いが増す度合いが大きい油脂に対する臭いの抑制に優れる。 As a result of inventor's earnest research, it has been found that roasting oil has an effect of suppressing odor even at a concentration without aroma. Occurrence of odors can be suppressed by adding roasting oil to odorous oils such as soybean oil, corn oil, palm oil and fat, flux oil, and sesame oil. In addition, its content is an amount that substantially suppresses the odor of oils such as soybean oil, corn oil, palm oil, flux oil, sesame oil, and does not substantially feel the flavor of roasted oil. Therefore, the fragrance and flavor of the roasted oil are not so strong that the usage of the oil and fat composition is not limited. Roasted oil suppresses the return odor and the like of odorous fats and oils, especially for fats and oils that have an unpleasant odor peculiar to raw materials such as soybean oil and have a high degree of unpleasant odor when deteriorated. Excellent odor control.
ここで、臭気とは、油脂自体が有する原料特有の不快な臭い、例えば、大豆油の「青臭さ」、油脂をしばらく置いておくと油脂自体はそれほど劣化していないもの(過酸化物価5程度)でも出てくる不快な臭いである「戻り臭」、および油脂を加熱したときに発生する刺激臭である「加熱臭」を意味する。また、「油脂自体が有する臭気を実質的に抑制し、かつ、焙煎油の風味を実質的に感じない量」とは、用いる油脂と焙煎油との組み合わせによって適宜決定されるが、本発明においては、通常用いられる焙煎油の含有量に比して、その含有量が極めて低いことを特徴としている。なお、「油脂自体が有する臭気を実質的に抑制」、とは、例えば、後述する実施例の官能検査において、パネル20名中、11名以上、好ましくは15名以上が、油脂自体が有する臭気を感じないと評価した場合である。「焙煎油の風味を実質的に感じない」とは、例えば、後述する実施例の官能検査において、パネル20名中、11名以上、好ましくは15名以上が、焙煎油の風味を感じないと評価した場合である。 Here, the odor is an unpleasant odor peculiar to the raw material of the oil and fat itself, for example, the “blue odor” of soybean oil, and the oil and fat itself does not deteriorate so much after being left for a while (peroxide value of about 5) ) Means a “return odor” which is an unpleasant odor that comes out, and a “heating odor” which is an irritating odor generated when oils and fats are heated. The “amount that substantially suppresses the odor of the oil itself and does not substantially feel the flavor of the roasted oil” is appropriately determined depending on the combination of the oil and roasted oil used. The invention is characterized in that its content is extremely low as compared with the content of usually used roasting oil. Note that “substantially suppresses the odor of the fat and oil itself” means, for example, the odor that the fat and oil itself has in 11 or more, preferably 15 or more of the 20 panelists in the sensory test of the examples described later. It is a case where it is evaluated that it does not feel. “Substantially feel no roasted oil flavor” means that, for example, in the sensory test of the examples described later, among the 20 panelists, 11 or more, preferably 15 or more feel the roasted oil flavor. This is the case when it is evaluated as not.
(2) 前記脱臭工程を経て製造された焙煎油は、脱臭焙煎ゴマ油、脱臭焙煎大豆油および脱臭焙煎菜種油からなる群から選ばれる1種または2種以上である(1)に記載の油脂組成物。 (2) The roasted oil produced through the deodorizing step is one or more selected from the group consisting of deodorized roasted sesame oil, deodorized roasted soybean oil, and deodorized roasted rapeseed oil. Oil composition.
焙煎油は、香ばしい香りと個性的な風味が特徴であるが、戻り臭等の臭気を微量で効果的に抑制できるので好ましい。脱臭工程を経ていない通常の焙煎油(未脱臭焙煎油)を、臭気を有する油脂に含有させる場合、その添加量が微量であるため、製造時において、精密な添加・混合精度が必要になる。一方、脱臭工程を経て製造された焙煎油(脱臭焙煎油)は、脱臭工程を経ていない通常の焙煎油(未脱臭焙煎油)に比べて風味がまろやかであるため、脱臭工程を経て製造された焙煎油(脱臭焙煎油)を、臭気を有する油脂に含有させる場合、その添加量の自由度が高くなり、製造時において、高い添加・混合精度を必要としない。従って、臭気を有する油脂に含有させる焙煎油として、脱臭工程を経て製造された焙煎油(脱臭焙煎油)を使用すると、製造時における添加・混合精度の誤差による品質のバラツキがより少なくなるため、品質がより安定したものを製造することができる。 Roasted oil is characterized by a fragrant scent and a unique flavor, but is preferable because it can effectively suppress odors such as return odor in a small amount. When normal roasted oil that has not been deodorized (non-deodorized roasted oil) is added to odorous fats and oils, the amount added is very small, so precise addition and mixing accuracy is required during production. Become. On the other hand, roasted oil (deodorized roasted oil) produced through the deodorizing process has a milder flavor than ordinary roasted oil (non-deodorized roasted oil) that has not undergone the deodorizing process. When the roasted oil (deodorized roasted oil) manufactured through the process is contained in a fat or oil having an odor, the degree of freedom in the amount of addition increases, and high addition / mixing accuracy is not required during manufacture. Therefore, when roasted oil produced through the deodorization process (deodorized roasted oil) is used as roasted oil to be included in odorous fats and oils, there is less variation in quality due to errors in addition and mixing accuracy during production. Therefore, a more stable product can be manufactured.
本明細書において、「脱臭焙煎ゴマ油」とは、詳細は後述するが、未脱臭焙煎ゴマ油を脱臭したものである。「脱臭焙煎ゴマ油」は、必要に応じて通常の油脂の精製工程で行われている脱ガム、脱酸、水洗、脱色等の処理を行うこともできる。 In the present specification, “deodorized roasted sesame oil” is deodorized non-deodorized roasted sesame oil, which will be described in detail later. “Deodorized roasted sesame oil” can be subjected to treatments such as degumming, deoxidation, washing with water, and decolorization, which are performed in a normal oil refining process, as necessary.
本明細書において、「脱臭焙煎大豆油」とは、詳細は後述するが、未脱臭焙煎大豆油を脱臭したものである。「脱臭焙煎大豆油」は、必要に応じて通常の油脂の精製工程で行われている脱ガム、脱酸、水洗、脱色等の処理を行うことができる。 In the present specification, “deodorized roasted soybean oil” is a product obtained by deodorizing non-deodorized roasted soybean oil, as will be described in detail later. “Deodorized roasted soybean oil” can be subjected to treatments such as degumming, deoxidation, washing with water, and decolorization, which are performed in a normal oil refining process, as necessary.
本明細書において、「脱臭焙煎菜種油」とは、詳細は後述するが、未脱臭焙煎菜種油を脱臭したものである。「脱臭焙煎菜種油」は、必要に応じて通常の油脂の精製工程で行われている脱ガム、脱酸、水洗、脱色等の処理を行うことができる。 In the present specification, “deodorized roasted rapeseed oil” is deodorized non-deodorized roasted rapeseed oil, which will be described in detail later. The “deodorized roasted rapeseed oil” can be subjected to treatments such as degumming, deoxidation, washing with water, and decolorization, which are performed in a normal oil and fat refining process, as necessary.
(3) 前記焙煎油が前記脱臭焙煎ゴマ油を含むものである場合、前記臭気を有する油脂に相当する量に対して、前記脱臭焙煎ゴマ油を、質量割合で10〜10000ppm含んでなる、(1)または(2)に記載の油脂組成物。 (3) When the roasted oil includes the deodorized roasted sesame oil, the deodorized roasted sesame oil is included in a mass ratio of 10 to 10,000 ppm with respect to the amount corresponding to the fat and oil having the odor. ) Or (2).
(4) 前記焙煎油が前記脱臭焙煎大豆油を含むものである場合、前記臭気を有する油脂に相当する量に対して、前記脱臭焙煎大豆油を、質量割合で100〜100000ppm含んでなる、(1)から(2)のいずれかに記載の油脂組成物。 (4) When the roasted oil contains the deodorized roasted soybean oil, the deodorized roasted soybean oil is included in a mass ratio of 100 to 100,000 ppm with respect to the amount corresponding to the fat and oil having the odor. (1) The oil-fat composition in any one of (2).
(5) 前記焙煎油が前記脱臭焙煎菜種油を含むものである場合、前記臭気を有する油脂に相当する量に対して、前記脱臭焙煎菜種油を、質量割合で100〜100000ppm含んでなる、(1)から(2)のいずれかに記載の油脂組成物。 (5) When the roasted oil contains the deodorized roasted rapeseed oil, the deodorized roasted rapeseed oil is contained in an amount of 100 to 100,000 ppm in a mass ratio with respect to the amount corresponding to the fat and oil having the odor. ) To (2).
(6) 前記臭気を有する油脂は、大豆油、大豆油のエステル交換油、大豆油を含む混合油のエステル交換油、コーン油、コーン油のエステル交換油、コーン油を含む混合油のエステル交換油、パーム系油脂、パーム系油脂のエステル交換油、パーム系油脂を含む混合油のエステル交換油、フラックス油、フラックス油のエステル交換油、フラックス油を含む混合油のエステル交換油、エゴマ油、エゴマ油のエステル交換油、エゴマ油を含む混合油のエステル交換油からなる群から選ばれる1種または2種以上である(1)から(5)のいずれかに記載の油脂組成物。 (6) The fats and oils having the odor are soybean oil, transesterified oil of soybean oil, transesterified oil of mixed oil containing soybean oil, corn oil, transesterified oil of corn oil, transesterified mixed oil containing corn oil. Oil, palm oil and fat, transesterified oil of palm oil and fat, transesterified oil of mixed oil containing palm oil and fat, flux oil, transesterified oil of flux oil, transesterified oil of mixed oil containing flux oil, egoma oil, The fat and oil composition according to any one of (1) to (5), which is one or more selected from the group consisting of transesterified oil of sesame oil and transesterified oil of mixed oil containing sesame oil.
大豆油、コーン油、パーム系油脂、フラックス油、エゴマ油等の油脂が有する戻り臭等の臭気は、大豆油、コーン油、パーム系油脂、フラックス油、エゴマ油等の油脂に(3)から(5)に記載した僅かな量を含有させることで抑制することができる。このため、本発明の油脂組成物は、含有させた焙煎油の風味がせず、様々な用途に使用することができる。 Odors such as soybean oil, corn oil, palm oil, flux oil, sesame oil and other odors such as return odor are added to oils such as soybean oil, corn oil, palm oil, flux oil, sesame oil (3) It can suppress by containing the slight quantity described in (5). For this reason, the oil and fat composition of the present invention does not have the flavor of the roasted oil contained, and can be used for various applications.
(7) (1)から(6)のいずれか1項に記載の油脂組成物を使用した加工品であって、該加工品が、油ちょう食品、炒め物、可塑性油脂組成物、油脂コーティング食品、起泡性水中油型乳化物、コーヒークリーム、フラワーペースト、冷菓または焼き菓子である加工品。 (7) A processed product using the oil / fat composition according to any one of (1) to (6), wherein the processed product is an oil-boiled food, a stir-fried food, a plastic oil / fat composition, or an oil-coated food. Processed products that are foamable oil-in-water emulsions, coffee creams, flower pastes, frozen or baked goods.
上記(1)から(6)いずれかに記載の油脂組成物は、原料特有の不快な臭い、例えば、大豆油における青臭さや、戻り臭および加熱調理時の加熱臭が抑制され、かつ、含有させた焙煎油の生風味がしないので、この油脂組成物を使用した油ちょう食品等の加工品は、原料特有の不快な臭いや焙煎油風味が付与されることがない。そのため、加工品として用いても、また、炒め料理、焼き料理、フライ調理等の調理に用いても、原料特有の不快な臭いや戻り臭、加熱臭が抑制された加工品本来の風味が得られる。 The oil and fat composition according to any one of (1) to (6) above contains an unpleasant odor peculiar to raw materials, for example, a blue odor in soybean oil, a return odor and a heating odor during cooking, and is contained. Since the roasted oil does not have a raw flavor, processed products such as oily foods using this oil and fat composition do not have an unpleasant smell or roasted oil flavor peculiar to raw materials. Therefore, even if it is used as a processed product, or used for cooking such as stir-fried food, grilled food, and fried food, the original flavor of the processed product with suppressed unpleasant odor, return odor, and heated odor peculiar to raw materials is obtained. It is done.
(8) 臭気を有する油脂を含有する油脂組成物中に、脱臭工程を経て製造された焙煎油を含有させることにより、前記臭気を有する油脂自体が有する臭気と前記焙煎油の風味を同時に抑制する方法。 (8) By containing the roasted oil produced through the deodorizing step in the oil / fat composition containing the odorous fat, the odor of the odorous oil itself and the flavor of the roasted oil are simultaneously obtained. How to suppress.
脱臭工程を経て製造された焙煎油は芳香や風味(香味ともいう)に優れるので、上記のように、この焙煎油を大豆油、コーン油、パーム系油脂、フラックス油、エゴマ油等の油脂に自己臭抑制剤として微量含有させることにより、油脂自体が有する青臭さ、戻り臭、および加熱臭等の臭気を実質的に抑制し、かつ、焙煎油の風味を実質的に感じないという効果を奏する。このため、油脂自体が有する臭気、および焙煎油の風味を同時に抑制する方法として有用である。 Since the roasted oil produced through the deodorization process is excellent in aroma and flavor (also called flavor), as described above, this roasted oil can be used for soybean oil, corn oil, palm oil, flux oil, egoma oil, etc. By containing a small amount of oil and fat as a self-odor suppressant, it is possible to substantially suppress odors such as the blue odor, return odor, and heating odor of the oil itself, and to substantially not feel the flavor of roasted oil. There is an effect. For this reason, it is useful as a method for simultaneously suppressing the odor of the oil and fat itself and the flavor of the roasted oil.
(9) 臭気を有する油脂と、未脱臭焙煎ゴマ油とを含有する油脂組成物であって、該油脂組成物中の前記未脱臭焙煎ゴマ油の含有量が、前記臭気を有する油脂に相当する量に対して、質量割合で2〜2500ppmである油脂組成物。臭気を有する油脂:大豆油、大豆油のエステル交換油、大豆油を含む混合油のエステル交換油、コーン油、コーン油のエステル交換油、コーン油を含む混合油のエステル交換油、パーム系油脂、パーム系油脂のエステル交換油、パーム系油脂を含む混合油のエステル交換油、フラックス油、フラックス油のエステル交換油、フラックス油を含む混合油のエステル交換油、エゴマ油、エゴマ油のエステル交換油、エゴマ油を含む混合油のエステル交換油からなる群から選ばれる1種または2種以上。 (9) An oil / fat composition containing odorous fat and oil and non-deodorized roasted sesame oil, wherein the content of the non-deodorized roasted sesame oil in the oil / fat composition corresponds to the oil / fat having the odor. The oil-and-fat composition which is 2-2500 ppm by mass ratio with respect to quantity. Odorous fats and oils: Soybean oil, transesterified oil of soybean oil, transesterified oil of mixed oil containing soybean oil, corn oil, transesterified oil of corn oil, transesterified oil of mixed oil containing corn oil, palm oil Transesterified oil of palm-based fats and oils, transesterified oils of mixed oils containing palm-based fats and oils, flux oils, transesterified oils of flux oils, transesterified oils of mixed oils containing fluxed oils, sesame oils, transesterified oils of sesame oils 1 type (s) or 2 or more types chosen from the group which consists of transesterified oil of mixed oil containing oil and egoma oil.
本明細書において、「未脱臭焙煎ゴマ油」とは、詳細は後述するが、ゴマを焙煎し、圧搾により搾油したものであり、脱臭処理を行っていないものである。「未脱臭焙煎ゴマ油」は、必要に応じて搾油後、沈殿物の除去、脱ガム、脱酸、乾燥等の処理を行うこともできる。 In the present specification, “non-deodorized roasted sesame oil”, as will be described in detail later, is a product obtained by roasting sesame and pressing it by pressing and not performing a deodorizing treatment. “Non-deodorized roasted sesame oil” can be subjected to treatments such as removal of precipitates, degumming, deoxidation, and drying after squeezing if necessary.
(10) 臭気を有する油脂と、未脱臭焙煎大豆油とを含有する油脂組成物であって、該油脂組成物中の前記未脱臭焙煎大豆油の含有量が、前記臭気を有する油脂に相当する量に対して、質量割合で25〜5000ppmである油脂組成物。臭気を有する油脂:大豆油、大豆油のエステル交換油、大豆油を含む混合油のエステル交換油、コーン油、コーン油のエステル交換油、コーン油を含む混合油のエステル交換油、パーム系油脂、パーム系油脂のエステル交換油、パーム系油脂を含む混合油のエステル交換油、フラックス油、フラックス油のエステル交換油、フラックス油を含む混合油のエステル交換油、エゴマ油、エゴマ油のエステル交換油、エゴマ油を含む混合油のエステル交換油からなる群から選ばれる1種または2種以上。 (10) An oil / fat composition containing an odorous fat and oil and an undeodorized roasted soybean oil, wherein the content of the non-deodorized roasted soybean oil in the oil / fat composition is the oil / fat having the odor. The oil-and-fat composition which is 25-5000 ppm by mass ratio with respect to the quantity corresponding. Odorous fats and oils: Soybean oil, transesterified oil of soybean oil, transesterified oil of mixed oil containing soybean oil, corn oil, transesterified oil of corn oil, transesterified oil of mixed oil containing corn oil, palm oil Transesterified oil of palm-based fats and oils, transesterified oils of mixed oils containing palm-based fats and oils, flux oils, transesterified oils of flux oils, transesterified oils of mixed oils containing fluxed oils, sesame oils, transesterified oils of sesame oils 1 type (s) or 2 or more types chosen from the group which consists of transesterified oil of mixed oil containing oil and egoma oil.
本明細書において、「未脱臭焙煎大豆油」とは、詳細は後述するが、大豆を焙煎し、圧搾により搾油したものであり、脱臭処理を行っていないものである。「未脱臭焙煎大豆油」は、必要に応じて搾油後、沈殿物の除去、脱ガム、脱酸、乾燥等の処理を行うこともできる。 In the present specification, “non-deodorized roasted soybean oil”, as will be described in detail later, is a product obtained by roasting soybeans and squeezing the oil by squeezing and not performing a deodorizing treatment. “Non-deodorized roasted soybean oil” can be subjected to processing such as precipitation removal, degumming, deoxidation, drying, etc., if necessary after oil extraction.
(11) 臭気を有する油脂と、未脱臭焙煎菜種油とを含有する油脂組成物であって、該油脂組成物中の前記未脱臭焙煎菜種油の含有量が、前記臭気を有する油脂に相当する量に対して、質量割合で25〜50000ppmである油脂組成物。臭気を有する油脂:大豆油、大豆油のエステル交換油、大豆油を含む混合油のエステル交換油、コーン油、コーン油のエステル交換油、コーン油を含む混合油のエステル交換油、パーム系油脂、パーム系油脂のエステル交換油、パーム系油脂を含む混合油のエステル交換油、フラックス油、フラックス油のエステル交換油、フラックス油を含む混合油のエステル交換油、エゴマ油、エゴマ油のエステル交換油、エゴマ油を含む混合油のエステル交換油からなる群から選ばれる1種または2種以上。 (11) An oil / fat composition containing an odorous fat and oil and an undeodorized roasted rapeseed oil, wherein the content of the non-deodorized roasted rapeseed oil in the oil / fat composition corresponds to the oil / fat having the odor. The oil-and-fat composition which is 25-50000 ppm by mass ratio with respect to quantity. Odorous fats and oils: Soybean oil, transesterified oil of soybean oil, transesterified oil of mixed oil containing soybean oil, corn oil, transesterified oil of corn oil, transesterified oil of mixed oil containing corn oil, palm oil Transesterified oil of palm-based fats and oils, transesterified oils of mixed oils containing palm-based fats and oils, flux oils, transesterified oils of flux oils, transesterified oils of mixed oils containing fluxed oils, sesame oils, transesterified oils of sesame oils 1 type (s) or 2 or more types chosen from the group which consists of transesterified oil of mixed oil containing oil and egoma oil.
本明細書において、「未脱臭焙煎菜種油」とは、詳細は後述するが、菜種を焙煎し、圧搾により搾油したものであり、脱臭処理を行っていないものである。「未脱臭焙煎菜種油」は、必要に応じて搾油後、沈殿物の除去、脱ガム、脱酸、乾燥等の処理を行うこともできる。 In the present specification, “non-deodorized roasted rapeseed oil”, which will be described in detail later, is obtained by roasting rapeseed and squeezing oil by squeezing and not performing a deodorizing treatment. “Non-deodorized roasted rapeseed oil” can be subjected to processing such as precipitation removal, degumming, deoxidation, drying, etc., if necessary after oil extraction.
大豆油、コーン油、パーム系油脂、フラックス油、エゴマ油等の油脂が有する戻り臭等の臭気は、大豆油、コーン油、パーム系油脂、フラックス油、エゴマ油等の油脂に(9)から(11)に記載した僅かな量を含有させることで抑制することができる。このため、本発明の油脂組成物は、含有させた焙煎油の風味がせず、様々な用途に使用することができる。 Odor such as soybean oil, corn oil, palm oil fat, flux oil, sesame oil and other odors such as return odors are added to oils such as soybean oil, corn oil, palm oil fat, flux oil, sesame oil, etc. from (9) It can suppress by containing the slight amount described in (11). For this reason, the oil and fat composition of the present invention does not have the flavor of the roasted oil contained, and can be used for various applications.
(12) (9)から(11)のいずれか1項に記載の油脂組成物を使用した加工品であって、該加工品が、油ちょう食品、炒め物、可塑性油脂組成物、油脂コーティング食品、起泡性水中油型乳化物、コーヒークリーム、フラワーペースト、冷菓または焼き菓子である加工品。 (12) A processed product using the oil / fat composition according to any one of (9) to (11), wherein the processed product is an oil-boiled food, a stir-fried food, a plastic oil / fat composition, or an oil / fat-coated food. Processed products that are foamable oil-in-water emulsions, coffee creams, flower pastes, frozen or baked goods.
(13) 臭気を有する油脂を含有する油脂組成物中に、前記臭気を有する油脂に相当する量に対して、質量割合で2〜2500ppmの未脱臭焙煎ゴマ油を含有させることにより、前記臭気を有する油脂自体が有する臭気と前記未脱臭焙煎ゴマ油の風味を同時に抑制する方法。臭気を有する油脂:大豆油、大豆油のエステル交換油、大豆油を含む混合油のエステル交換油、コーン油、コーン油のエステル交換油、コーン油を含む混合油のエステル交換油、パーム系油脂、パーム系油脂のエステル交換油、パーム系油脂を含む混合油のエステル交換油、フラックス油、フラックス油のエステル交換油、フラックス油を含む混合油のエステル交換油、エゴマ油、エゴマ油のエステル交換油、エゴマ油を含む混合油のエステル交換油からなる群から選ばれる1種または2種以上。 (13) In the oil and fat composition containing the odorous fats and oils, the odor is reduced by adding 2 to 2500 ppm of non-deodorized roasted sesame oil in a mass ratio with respect to the amount corresponding to the odorous fats and oils. A method for simultaneously suppressing the odor of the oil and fat itself and the flavor of the non-deodorized roasted sesame oil. Odorous fats and oils: Soybean oil, transesterified oil of soybean oil, transesterified oil of mixed oil containing soybean oil, corn oil, transesterified oil of corn oil, transesterified oil of mixed oil containing corn oil, palm oil Transesterified oil of palm-based fats and oils, transesterified oils of mixed oils containing palm-based fats and oils, flux oils, transesterified oils of flux oils, transesterified oils of mixed oils containing fluxed oils, sesame oils, transesterified oils of sesame oils 1 type (s) or 2 or more types chosen from the group which consists of transesterified oil of mixed oil containing oil and egoma oil.
(14) 臭気を有する油脂を含有する油脂組成物中に、前記臭気を有する油脂に相当する量に対して、質量割合で25〜50000ppmの未脱臭焙煎菜種油を含有させすることにより、前記臭気を有する油脂自体が有する臭気と前記未脱臭焙煎菜種油の風味を同時に抑制する方法。臭気を有する油脂:大豆油、大豆油のエステル交換油、大豆油を含む混合油のエステル交換油、コーン油、コーン油のエステル交換油、コーン油を含む混合油のエステル交換油、パーム系油脂、パーム系油脂のエステル交換油、パーム系油脂を含む混合油のエステル交換油、フラックス油、フラックス油のエステル交換油、フラックス油を含む混合油のエステル交換油、エゴマ油、エゴマ油のエステル交換油、エゴマ油を含む混合油のエステル交換油からなる群から選ばれる1種または2種以上。 (14) The odor is obtained by adding 25 to 50000 ppm of non-deodorized roasted rapeseed oil in a mass ratio with respect to the amount corresponding to the odorous fat in the fat or oil composition containing the odorous fat or oil. The method of suppressing simultaneously the odor which the fats and oils which have this, and the flavor of the said non-deodorized roasted rapeseed oil. Odorous fats and oils: Soybean oil, transesterified oil of soybean oil, transesterified oil of mixed oil containing soybean oil, corn oil, transesterified oil of corn oil, transesterified oil of mixed oil containing corn oil, palm oil Transesterified oil of palm-based fats and oils, transesterified oils of mixed oils containing palm-based fats and oils, flux oils, transesterified oils of flux oils, transesterified oils of mixed oils containing fluxed oils, sesame oils, transesterified oils of sesame oils 1 type (s) or 2 or more types chosen from the group which consists of transesterified oil of mixed oil containing oil and egoma oil.
(15) 臭気を有する油脂を含有する油脂組成物中に、前記臭気を有する油脂に相当する量に対して、質量割合で25〜5000ppmの未脱臭焙煎大豆油を含有させることにより、前記臭気を有する油脂自体が有する臭気と前記未脱臭焙煎大豆油の風味を同時に抑制する方法。臭気を有する油脂:大豆油、大豆油のエステル交換油、大豆油を含む混合油のエステル交換油、コーン油、コーン油のエステル交換油、コーン油を含む混合油のエステル交換油、パーム系油脂、パーム系油脂のエステル交換油、パーム系油脂を含む混合油のエステル交換油、フラックス油、フラックス油のエステル交換油、フラックス油を含む混合油のエステル交換油、エゴマ油、エゴマ油のエステル交換油、エゴマ油を含む混合油のエステル交換油からなる群から選ばれる1種または2種以上。 (15) The odor can be obtained by adding 25 to 5000 ppm of non-deodorized roasted soybean oil in a mass ratio with respect to the amount corresponding to the odorous fat in the fat or oil composition containing the odorous fat. A method for simultaneously suppressing the odor of the oil and fat itself having a flavor and the flavor of the non-deodorized roasted soybean oil. Odorous fats and oils: Soybean oil, transesterified oil of soybean oil, transesterified oil of mixed oil containing soybean oil, corn oil, transesterified oil of corn oil, transesterified oil of mixed oil containing corn oil, palm oil Transesterified oil of palm-based fats and oils, transesterified oils of mixed oils containing palm-based fats and oils, flux oils, transesterified oils of flux oils, transesterified oils of mixed oils containing fluxed oils, sesame oils, transesterified oils of sesame oils 1 type (s) or 2 or more types chosen from the group which consists of transesterified oil of mixed oil containing oil and egoma oil.
本発明の油脂組成物によれば、大豆油、パーム系油脂、フラックス油、エゴマ油等の油脂が有する原料特有の不快な臭い、例えば、大豆油における青臭さや、戻り臭、加熱臭の発生が抑制されるようになった。また、焙煎油の含有量が微量であるため焙煎油の風味がしないので、調理品への焙煎油風味が付与されることがない。 According to the oil and fat composition of the present invention, unpleasant odor peculiar to raw materials possessed by oils and fats such as soybean oil, palm oil and fat, flux oil and sesame oil, for example, generation of blue odor, return odor and heating odor in soybean oil It came to be suppressed. In addition, since the roasting oil content is very small, the roasting oil does not have a flavor, so that the roasted oil flavor is not imparted to the cooked product.
本発明は、臭気を有する油脂と、焙煎油とを含有する油脂組成物であって、油脂組成物中の焙煎油の含有量が、臭気を有する油脂自体が有する臭気を実質的に抑制し、かつ、焙煎油の風味を実質的に感じない量であることを特徴とする。臭気を有する油脂を含有する油脂組成物中に、焙煎油を含有させることにより、臭気を有する油脂特有の不快な臭いを抑制し、かつ、焙煎油の風味を実質的に感じないものとすることができる。 The present invention is an oil and fat composition containing an odorous fat and oil and roasted oil, and the content of the roasted oil in the fat and oil composition substantially suppresses the odor of the odorous oil itself. And it is the quantity which does not feel the flavor of roasting oil substantially. By containing roasting oil in the fat and oil composition containing odorous fats and oils, the unpleasant smell peculiar to odorous fats and oils is suppressed, and the flavor of the roasting oil is not substantially felt. can do.
以下、本発明の実施形態について詳細に説明するが、本発明は、以下の実施形態に何ら限定されるものではなく、本発明の目的の範囲内において、適宜変更を加えて実施することができる。なお、説明が重複する箇所については、適宜説明を省略する場合があるが、発明の趣旨を限定するものではない。 Hereinafter, embodiments of the present invention will be described in detail. However, the present invention is not limited to the following embodiments, and can be implemented with appropriate modifications within the scope of the object of the present invention. . In addition, although description may be abbreviate | omitted suitably about the location where description overlaps, the meaning of invention is not limited.
[臭気を有する油脂]
本発明において、臭気を有する油脂とは、油脂自体が有する原料特有の不快な臭い(例えば、大豆油の「青臭さ」コーン油の「穀物臭」)、油脂をしばらく置いておくと油脂自体はそれほど傷んでいないもの(過酸化物価5程度)でも出てくる不快な臭いである「戻り臭」、油脂を加熱したときに発生する刺激臭である「加熱臭」を有する油脂を意味する。臭気を有する油脂の具体例としては、例えば、大豆油、パーム系油脂(例えば、パーム油、パームオレイン等のパーム油の分別油、パーム油の硬化油等)、コーン油、フラックス油、エゴマ油等や、これらの油脂のエステル交換油、これらの油脂を含む混合油のエステル交換油等が挙げられる。これらの臭気を有する油脂は、1種または2種以上を用いることができる。[Oil with odor]
In the present invention, the fat and oil having an odor is an unpleasant odor peculiar to the raw material of the fat and oil itself (for example, the “blue odor” of soybean oil and the “cereal odor” of corn oil). It means fats and oils having a “return odor” which is an unpleasant odor that is not so damaged (peroxide value of about 5) and a “heating odor” which is an irritating odor generated when the oil is heated. Specific examples of odorous oils include, for example, soybean oil, palm oil (for example, palm oil, palm oil fractionated oil, palm oil hardened oil, etc.), corn oil, flux oil, sesame oil, etc. Etc., transesterified oils of these fats and oils, mixed oils containing these fats and oils, and the like. 1 type, or 2 or more types can be used for the fats and oils which have these odors.
臭気を有する油脂は、新油(種子から搾油した直後、あるいは酸化されていない油脂)であっても、光に曝した曝光油(搾油後、光等に曝されて生風味時の不快な臭いが増した油脂)や加熱時の加熱臭が増した油脂であってもよい。本発明によれば、曝光油や加熱臭が増した油脂でも臭気が抑制されることから、この効果は長時間持続する。 Even if the fats and oils with odor are new oils (immediately after squeezing from seeds or unoxidized fats and oils), the exposed oil exposed to light (after squeezing, exposed to light, etc., unpleasant odor when raw flavored) Or fats with increased heating odor upon heating. According to the present invention, the effect is maintained for a long time because the odor is suppressed even with oils and oils with increased exposure odor and exposure oil.
本発明の油脂組成物は、前記の臭気を有する油脂に他の油脂をブレンドした混合油としてもよい。ブレンドに使用される油脂は特に規定されず、前記臭気を有する油脂以外の通常、食用油に使用される油脂を使用することができる。 The oil and fat composition of the present invention may be a mixed oil obtained by blending other oils and fats with the oils and fats having the above odor. The fats and oils used for blending are not particularly defined, and fats and oils usually used for edible oils other than the fats and oils having the odor can be used.
[焙煎油]
本発明において使用される焙煎油は、臭気を有する油脂の不快な臭い(例えば、原料特有の不快な臭い、戻り臭、加熱臭)等を抑制するために含有させる。本発明において使用される焙煎油は、脱臭処理せずに製造される焙煎油である未脱臭焙煎油や脱臭工程を経て製造される焙煎油である脱臭焙煎油が挙げられる。未脱臭焙煎油は、特に限定されないが、例えば、未脱臭焙煎ゴマ油、未脱臭焙煎大豆油、未脱臭焙煎菜種油を使用することが好ましい。また、脱臭焙煎油は、特に限定されないが、例えば、脱臭焙煎ゴマ油、脱臭焙煎大豆油、脱臭焙煎菜種油を使用することが好ましい。これらの焙煎油は、1種または2種以上を用いることができる。[Roasting oil]
The roasted oil used in the present invention is contained in order to suppress unpleasant odors of odorous fats and oils (for example, unpleasant odors peculiar to raw materials, return odors, heated odors). Examples of the roasting oil used in the present invention include non-deodorized roasting oil that is roasted oil that is manufactured without deodorizing treatment and deodorized roasting oil that is roasted oil manufactured through a deodorizing process. The non-deodorized roasted oil is not particularly limited. For example, it is preferable to use non-deodorized roasted sesame oil, non-deodorized roasted soybean oil, and non-deodorized roasted rapeseed oil. The deodorized roasted oil is not particularly limited, but it is preferable to use, for example, deodorized roasted sesame oil, deodorized roasted soybean oil, and deodorized roasted rapeseed oil. These roasting oils can be used alone or in combination of two or more.
未脱臭焙煎油は、脱臭処理せずに製造されるため、製造コスト面でメリットがある。 Undeodorized roasted oil is produced without deodorizing treatment, and therefore has an advantage in terms of production cost.
脱臭焙煎油は、通常の焙煎油(未脱臭焙煎油)の特徴である香ばしい香りと個性的な風味が弱く、風味がまろやかであるにもかかわらず、臭気を有する油脂の不快な臭い(例えば、原料特有の不快な臭い、戻り臭、加熱臭)等を抑制することができる。また、脱臭焙煎油を使用すると、その添加量の自由度が高くなるため、製造時における添加・混合精度の誤差による品質のバラツキがより少なくなり、品質がより安定したものを製造することができる。 Deodorized roasting oil is an unpleasant odor of fats and oils that have a fragrant fragrance and a characteristic flavor that are characteristic of normal roasting oil (non-deodorized roasting oil), but has a mild flavor and a mild flavor. (For example, unpleasant odor peculiar to raw materials, return odor, heating odor) and the like can be suppressed. In addition, the use of deodorized roasted oil increases the degree of freedom in the amount of addition, so there is less variation in quality due to errors in the addition and mixing accuracy during production, and it is possible to produce a more stable quality. it can.
<焙煎油の含有量>
焙煎油の含有量は、臭気を有する油脂特有の不快な臭いを抑制し、かつ、焙煎油の風味を実質的に感じない程度に含有させることが好ましい。なお、本願において、油脂組成物中の焙煎油の含有量は、油脂組成物中に含まれる焙煎油の量を、臭気有する油脂に相当する量(臭気を有する油脂がエステル交換油を含む場合には、当該エステル交換油部分については、その原料のうちの臭気を有する油脂に相当する量)当たりに換算した値(質量割合)で表される。<Content of roasting oil>
The content of roasting oil is preferably included so as to suppress an unpleasant odor peculiar to fats and oils having an odor and to substantially not feel the flavor of roasting oil. In addition, in this application, content of the roasting oil in fats and oils composition is the quantity of the roasting oil contained in fats and oils composition, the amount equivalent to fats and oils with an odor (fats and oils with an odor include transesterified oils) In this case, the transesterified oil part is represented by a value (mass ratio) converted per per unit amount of the raw material.
焙煎油が脱臭焙煎ゴマ油の場合、臭気を有する油脂に相当する量に対して、脱臭焙煎ゴマ油を質量割合で10〜10000ppm含有させることが好ましく、25〜10000ppm含有させることがより好ましく、50〜5000ppm含有させることが最も好ましい。脱臭焙煎ゴマ油の含有量が上記範囲にあると、臭気を有する油脂特有の不快な臭いを抑制し、かつ、焙煎油の風味を実質的に感じないものとすることができる。 When roasting oil is deodorized roasted sesame oil, it is preferable to contain deodorized roasted sesame oil in a mass ratio of 10 to 10,000 ppm, more preferably 25 to 10,000 ppm, relative to the amount corresponding to odorous fats and oils. It is most preferable to contain 50 to 5000 ppm. When the content of the deodorized roasted sesame oil is in the above range, an unpleasant odor peculiar to fats and oils having an odor can be suppressed, and the flavor of the roasted oil can be substantially not felt.
焙煎油が脱臭焙煎大豆油の場合、臭気を有する油脂に相当する量に対して、脱臭焙煎大豆油を質量割合で100〜100000ppm含有させることが好ましく、500〜100000ppm含有させることがより好ましく、500〜50000ppm含有させることが最も好ましい。脱臭焙煎大豆油の含有量が上記範囲にあると、臭気を有する油脂特有の不快な臭いを抑制し、かつ、焙煎油の風味を実質的に感じないものとすることができる。 When the roasting oil is deodorized roasted soybean oil, it is preferable to contain deodorized roasted soybean oil in a mass ratio of 100 to 100,000 ppm, more preferably 500 to 100,000 ppm based on the amount corresponding to the odorous fats and oils. Preferably, it is most preferable to make it contain 500-50000 ppm. When the content of the deodorized roasted soybean oil is in the above range, an unpleasant odor peculiar to fats and oils having an odor can be suppressed, and the flavor of the roasted oil can be substantially not felt.
焙煎油が脱臭焙煎菜種油の場合、臭気を有する油脂に相当する量に対して、脱臭焙煎菜種油を質量割合で100〜100000ppm含有させることが好ましく、500〜100000ppm含有させることがより好ましく、500〜50000ppm含有させることが最も好ましい。脱臭焙煎菜種油の含有量が上記範囲にあると、臭気を有する油脂特有の不快な臭いを抑制し、かつ、焙煎油の風味を実質的に感じないものとすることができる。 When the roasting oil is a deodorized roasted rapeseed oil, the deodorized roasted rapeseed oil is preferably contained in a mass ratio of 100 to 100,000 ppm, more preferably 500 to 100,000 ppm, relative to the amount corresponding to the odorous fats and oils. Most preferably, the content is 500 to 50,000 ppm. When the content of the deodorized roasted rapeseed oil is in the above range, an unpleasant odor peculiar to fats and oils having an odor can be suppressed, and the flavor of the roasted oil can be substantially not felt.
焙煎油が未脱臭焙煎ゴマ油の場合、臭気を有する油脂に相当する量に対して、未脱臭焙煎ゴマ油を質量割合で2〜2500ppm含有させることが好ましく、2ppm以上37.5ppm未満含有させることがより好ましく、10〜35ppm含有させることが最も好ましい。未脱臭焙煎ゴマ油の含有量が上記範囲にあると、臭気を有する油脂特有の不快な臭いを抑制し、かつ、焙煎油の風味を実質的に感じないものとすることができる。 When the roasting oil is non-deodorized roasted sesame oil, it is preferable to contain the non-deodorized roasted sesame oil in an amount of 2 to 2500 ppm by mass ratio with respect to the amount corresponding to the odorous fats and oils. It is more preferable to contain 10 to 35 ppm. When the content of the non-deodorized roasted sesame oil is in the above range, an unpleasant odor peculiar to fats and oils having an odor can be suppressed, and the flavor of the roasted oil can be substantially not felt.
焙煎油が未脱臭焙煎大豆油の場合、臭気を有する油脂に相当する量に対して、未脱臭焙煎大豆油を質量割合で25〜5000ppm含有させることが好ましく、25ppm以上100ppm未満含有させることがより好ましく、100〜3000ppm含有させることがより好ましく、30ppm以上100ppm未満ppm含有させることがさらに好ましく、50ppm以上100ppm未満ppm含有させることが最も好ましい。未脱臭焙煎大豆油の含有量が上記範囲にあると、臭気を有する油脂特有の不快な臭いを抑制し、かつ、焙煎油の風味を実質的に感じないものとすることができる。 When the roasted oil is non-deodorized roasted soybean oil, it is preferable to contain 25 to 5000 ppm of undeodorized roasted soybean oil in a mass ratio with respect to the amount corresponding to the odorous fat and oil, and 25 ppm or more and less than 100 ppm. It is more preferable to contain 100 to 3000 ppm, more preferably 30 ppm to less than 100 ppm, and most preferably 50 ppm to less than 100 ppm. When the content of the non-deodorized roasted soybean oil is in the above range, an unpleasant odor peculiar to fats and oils having an odor can be suppressed, and the flavor of the roasted oil can be substantially not felt.
焙煎油が未脱臭焙煎菜種油の場合、臭気を有する油脂に相当する量に対して、未脱臭焙煎菜種油を質量割合で25〜50000ppm含有させることが好ましく、25〜5000ppm含有させることがより好ましく、50〜3000ppm含有させることが最も好ましい。未脱臭焙煎菜種油の含有量が上記範囲にあると、臭気を有する油脂特有の不快な臭いを抑制し、かつ、焙煎油の風味を実質的に感じないものとすることができる。 When roasting oil is non-deodorized roasted rapeseed oil, it is preferable to contain non-deodorized roasted rapeseed oil in an amount of 25 to 50000 ppm by mass relative to the amount corresponding to odorous fats and oils, and more preferably 25 to 5000 ppm. Preferably, it is most preferable to make it contain 50-3000 ppm. When the content of the non-deodorized roasted rapeseed oil is in the above range, an unpleasant odor peculiar to fats and oils having an odor can be suppressed, and the flavor of the roasted oil can be substantially not felt.
ここで、「前記油脂組成物中に含まれる前記焙煎油の量を、前記臭気を有する油脂に相当する量(前記臭気を有する油脂がエステル交換油を含む場合には、当該エステル交換油部分については、エステル交換油の原料に用いた油脂のうちの臭気を有する油脂に相当する量)当たりに換算した場合」の油脂組成物中の焙煎油の含有量(ppm)としては、例えば、臭気を有する油脂が大豆油、焙煎油が脱臭焙煎ゴマ油の場合、以下の式(1)で表すことができる。なお、臭気を有する油脂に相当する量とは、例えば大豆油の場合、エステル交換油の有無にかかわらず、油脂組成物中に用いられた大豆油の量を指す。 Here, “the amount of the roasted oil contained in the oil / fat composition is an amount corresponding to the oil / fat having the odor (if the oil / fat having the odor contains a transesterified oil, the transesterified oil portion As for the content (ppm) of roasted oil in the oil and fat composition of “when converted per oil and fat having an odor among the oils and fats used as the raw material for the transesterified oil”, for example, When the odorous fat is soybean oil and the roasted oil is deodorized roasted sesame oil, it can be expressed by the following formula (1). For example, in the case of soybean oil, the amount corresponding to the fat or oil having an odor refers to the amount of soybean oil used in the oil or fat composition regardless of the presence or absence of the transesterified oil.
例えば、大豆油100gを含有する油脂組成物において、脱臭焙煎ゴマ油を10000ppm含有させるには、脱臭焙煎ゴマ油を1g含有させればよい。また、例えば、大豆油のみを原料としたエステル交換油100gを含有する油脂組成物において、脱臭焙煎ゴマ油を10000ppm含有させるには、脱臭焙煎ゴマ油を1g含有させればよい。また、原料のうち大豆油の含量が50質量%であるエステル交換油100gを含有する油脂組成物において、脱臭焙煎ゴマ油を10000ppm含有させるには、脱臭焙煎ゴマ油を0.5g含有させればよい。 For example, in an oil and fat composition containing 100 g of soybean oil, 1 g of deodorized roasted sesame oil may be contained in order to contain 10,000 ppm of deodorized roasted sesame oil. Further, for example, in an oil and fat composition containing 100 g of transesterified oil made only from soybean oil, 1 g of deodorized roasted sesame oil may be contained in order to contain 10,000 ppm of deodorized roasted sesame oil. In addition, in an oil / fat composition containing 100 g of transesterified oil having a soybean oil content of 50% by mass in the raw material, to contain 10,000 ppm of deodorized roasted sesame oil, 0.5 g of deodorized roasted sesame oil should be contained. Good.
本発明の油脂組成物中の焙煎油を除く油脂が臭気を有する油脂のみの場合、焙煎油の含有量(ppm)は、焙煎油の量を、臭気を有する油脂の量当たりに換算した値を意味する。具体的には、油脂組成物中の焙煎油を除く油脂が大豆油のみからなり、焙煎油が脱臭焙煎ゴマ油である場合、油脂組成物中の脱臭焙煎ゴマ油の含有量は、大豆油の質量に対して、質量割合で10〜10000ppmであることが好ましい。 When the fats and oils excluding the roasting oil in the oil and fat composition of the present invention are only fats and oils having an odor, the content (ppm) of roasting oil is converted to the amount of the roasting oil per the amount of the fats and oils having an odor Means the value. Specifically, when the fat and oil excluding the roasted oil in the fat and oil composition consists only of soybean oil and the roasted oil is deodorized roasted sesame oil, the content of the deodorized roasted sesame oil in the fat and oil composition is large. It is preferable that it is 10-10000 ppm by mass ratio with respect to the mass of bean oil.
本発明では、油脂組成物中の焙煎油を除く油脂として、大豆油等の臭気を有する油脂に、その他の油脂をブレンドした混合油を使用してもよい。この場合、焙煎油の含有量(ppm)は、焙煎油の量を、混合油中の臭気を有する油脂の量当たりに換算した値を意味する。油脂組成物中の焙煎油を除く油脂が大豆油50%と菜種油50%との混合油において、大豆油の質量当たりに換算して50ppmとなるように含有する場合とは、混合油に対しては1/2倍の25ppmとなるように含有することを意味する。 In this invention, you may use the mixed oil which blended other fats and oils to fats and oils which have odors, such as soybean oil, as fats and oils except the roasting oil in fats and oils composition. In this case, the content (ppm) of roasting oil means a value obtained by converting the amount of roasting oil to the amount of fats and oils having an odor in the mixed oil. When the fats and oils excluding roasted oil in the oil and fat composition contain 50% soybean oil and 50% rapeseed oil so as to be 50 ppm in terms of mass per soybean oil, It means that it is contained so as to be 25 ppm of 1/2.
また、本発明では、焙煎油を除く油脂組成物中の油脂として、少なくとも臭気を有する油脂を原料としたエステル交換油を使用してもよい。この場合、焙煎油の含有量(ppm)は、例えば、原料大豆油100%のエステル交換油(原料が大豆油のみからなるエステル交換油)であれば、上記の油脂組成物中の焙煎油を除く油脂が臭気を有する油脂のみの場合と同様に考える。すなわち、具体的には、焙煎油を除く油脂組成物中の油脂が原料大豆油100%のエステル交換油のみからなり、焙煎油が脱臭焙煎ゴマ油である場合、油脂組成物中の脱臭焙煎ゴマ油の含有量は、原料大豆油の質量に対して、質量割合で10〜10000ppmであることが好ましい。 Moreover, in this invention, you may use the transesterification oil which used the fats and oils which have an odor at least as fats and oils in fats and oils compositions except roasting oil. In this case, if the content (ppm) of the roasted oil is, for example, a transesterified oil of 100% raw soybean oil (the transesterified oil whose raw material is only soybean oil), the roasted oil in the above oil composition It is considered in the same way as when the fats and oils except oil are only odorous fats and oils. Specifically, when the fats and oils in the fat and oil composition excluding the roasting oil consist only of transesterified oil of the raw material soybean oil 100%, and the roasting oil is deodorized roasted sesame oil, the deodorization in the fat and oil composition It is preferable that content of roasted sesame oil is 10-10000 ppm by mass ratio with respect to the mass of raw material soybean oil.
一方、例えば、原料大豆油50%と原料菜種油50%のような混合油のエステル交換油の場合には、焙煎油の含有量(ppm)は、焙煎油の量を、混合油中の原料大豆油の質量当たりに換算した値を意味する。具体的には、原料大豆油50%と原料菜種油50%の混合油のエステル交換油において、原料大豆油あたりに換算して50ppmとなるように含有する場合とは、混合油に対しては1/2倍の25ppmとなるように含有することを意味する。 On the other hand, for example, in the case of a mixed oil transesterified oil such as 50% raw soybean oil and 50% raw rapeseed oil, the content (ppm) of roasted oil is the amount of roasted oil in the mixed oil. It means the value converted per mass of raw soybean oil. Specifically, in a transesterified oil of a mixed oil of 50% raw soybean oil and 50% raw rapeseed oil, the case of containing 50 ppm in terms of raw soybean oil is 1 for the mixed oil. It means that it is contained so as to be 25 ppm of / 2 times.
上記の混合油と、エステル交換油と、その他の油脂とは適宜ブレンドされていてもよい。この場合においても、本発明における油脂組成物中の焙煎油の含有量(ppm)は、上記の算出方法を基に、油脂組成物中の焙煎油の量を、臭気を有する油脂に相当する量の総量(臭気を有する油脂がエステル交換油脂を含む場合には、当該エステル交換油部分については、その原料油脂のうちの臭気を有する油脂に相当する量)当たりに換算して求められる。 Said mixed oil, transesterified oil, and other fats and oils may be blended suitably. Even in this case, the content (ppm) of the roasted oil in the oil / fat composition according to the present invention corresponds to the amount of the roasted oil in the oil / fat composition based on the above calculation method. It is obtained by conversion per total amount (when the odorous oil contains transesterified oil and fat, the transesterified oil part is an amount corresponding to the odorous oil and fat in the raw oil and fat).
この焙煎油は、例えば、焙煎処理していない油糧種子から搾油した油等の他の油脂で薄めて用いてもよいが、薄めて用いる場合には、焙煎油100%換算当たりで上記含有量とする。 This roasted oil may be used by diluting with other fats and oils such as oil squeezed from oil seeds that have not been roasted, but in the case of diluting and using, It is said content.
さらに、本発明の油脂組成物中には、食用油脂に用いられる一般的な添加剤を含有させることができる。この添加剤の用途は特に問わないが、例えば、結晶抑制や花さき性向上のために用いられる。油脂組成物中に添加剤が含まれている場合であっても、焙煎油の量は、油脂組成物中に用いられた臭気を有する油脂に換算して求められる。 Furthermore, the oil and fat composition of the present invention may contain general additives used for edible fats and oils. The use of this additive is not particularly limited. For example, it is used for suppressing crystallization and improving flowering properties. Even when the oil and fat composition contains an additive, the amount of roasted oil is determined in terms of the oil and fat having an odor used in the oil and fat composition.
<未脱臭焙煎油の製造方法>
未脱臭焙煎ゴマ油、未脱臭焙煎大豆油、未脱臭焙煎菜種油等の未脱臭焙煎油は、通常の焙煎油と同様な製法によって製造することができる。具体的には、原料であるゴマ、大豆、菜種等を焙煎した後、圧搾により搾油することにより製造することができる。未脱臭焙煎ゴマ油、未脱臭焙煎大豆油、未脱臭焙煎菜種油等の未脱臭焙煎油は、脱臭処理を行っていないものである。<Method for producing non-deodorized roasted oil>
Non-deodorized roasted oil such as non-deodorized roasted sesame oil, non-deodorized roasted soybean oil, non-deodorized roasted rapeseed oil, etc. can be produced by the same production method as ordinary roasted oil. Specifically, it can be produced by roasting raw materials such as sesame seeds, soybeans, rapeseed and the like and then squeezing them by pressing. Non-deodorized roasted oils such as non-deodorized roasted sesame oil, non-deodorized roasted soybean oil, and non-deodorized roasted rapeseed oil are those that have not been deodorized.
未脱臭焙煎油は、圧搾により搾油することにより得られる粗油をそのまま使用することができるが、脱臭を除く一般的な油脂の精製を行うことができる。精製方法としては、例えば、沈殿物の除去、脱ガム、脱酸、水洗、脱色等の一般的な油脂の精製が挙げられる。特に、未脱臭焙煎油は、搾油後、沈殿物の除去のために、静置、ろ過等を行うことが好ましく、また、リン脂質が多い場合には脱ガムすることが好ましい。 Undeodorized roasted oil can be used as it is crude oil obtained by squeezing by pressing, but general oils and fats can be purified excluding deodorization. Examples of the purification method include purification of general fats and oils such as precipitate removal, degumming, deoxidation, water washing, and decolorization. In particular, the non-deodorized roasted oil is preferably subjected to standing, filtration and the like after the oil extraction to remove the precipitate, and when there is a large amount of phospholipid, it is preferably degummed.
<脱臭焙煎油の製造方法>
通常、焙煎油は、それ自体の風味や芳香を生かした油であるため、焙煎油としては、精製を行わずに、原料を焙煎した後、圧搾により搾油することにより得られる粗油(本願における未脱臭焙煎油)がそのまま使用される。よって、油脂の一般的な精製方法である脱臭工程についても、通常、焙煎油の製造においては行われない。しかし、本発明で使用する脱臭焙煎ゴマ油、脱臭焙煎大豆油、脱臭焙煎菜種油等の脱臭工程を経て製造される焙煎油である脱臭焙煎油は、粗油(本願における未脱臭焙煎油)に脱臭処理を行ったものである。<Method for producing deodorized roasting oil>
Normally, roasted oil is an oil that makes use of its own flavor and aroma, so as roasted oil, it is a crude oil obtained by roasting raw materials without refining and then pressing the oil by pressing. (Undeodorized roasted oil in the present application) is used as it is. Therefore, the deodorizing step, which is a general method for refining fats and oils, is usually not performed in the production of roasted oil. However, deodorized roasted oil, which is a roasted oil produced through a deodorizing process such as deodorized roasted sesame oil, deodorized roasted soybean oil, and deodorized roasted rapeseed oil used in the present invention, is a crude oil (undeodorized roasted oil in the present application). (Deodorizing oil) is deodorized.
脱臭焙煎ゴマ油、脱臭焙煎大豆油、脱臭焙煎菜種油等の脱臭焙煎油は、原料であるゴマ、大豆、菜種等を焙煎した後、圧搾により搾油することにより得られる未脱臭焙煎ゴマ油、未脱臭焙煎大豆油、未脱臭焙煎菜種油等の未脱臭焙煎油を、脱臭処理することにより製造することができる。 Deodorized roasted oil such as deodorized roasted sesame oil, deodorized roasted soybean oil, and deodorized roasted rapeseed oil is a non-deodorized roasted oil obtained by roasting sesame seeds, soybeans, rapeseed, etc. Non-deodorized roasted oils such as sesame oil, non-deodorized roasted soybean oil, and non-deodorized roasted rapeseed oil can be produced by deodorizing treatment.
脱臭焙煎油は、圧搾により搾油した後、脱臭処理したものを、そのまま使用することもできるが、脱臭以外の一般的な油脂の精製を行うことができる。精製方法としては、例えば、沈殿物の除去、脱ガム、脱酸、水洗、脱色等の一般的な油脂の精製が挙げられる。 The deodorized roasted oil can be used as it is after it has been squeezed by pressing and then subjected to deodorization treatment, but general oils and fats other than deodorization can be purified. Examples of the purification method include purification of general fats and oils such as precipitate removal, degumming, deoxidation, water washing, and decolorization.
未脱臭焙煎油および脱臭焙煎油は、例えば、以下に記載した焙煎条件、圧搾条件、精製条件で製造することができる。 Undeodorized roasting oil and deodorized roasting oil can be produced, for example, under the roasting conditions, pressing conditions, and purification conditions described below.
焙煎条件は適宜変更することができ、特に限定されない。焙煎温度は品温が110〜260℃になるように焙煎することが好ましい。130〜200℃が特に風味上、好ましい。焙煎時間は、特に限定されないが、品温が焙煎温度に到達して1〜60分焙煎することが好ましく、2〜30分焙煎することがより好ましい。また、品温までの温度を上昇させる方法は、特に限定されるものではないが、一定の上昇率(例えば、10〜20℃上昇/分)で徐々に温度上昇させることが好ましい。 The roasting conditions can be changed as appropriate and are not particularly limited. The roasting temperature is preferably roasted so that the product temperature is 110 to 260 ° C. 130-200 degreeC is especially preferable on flavor. The roasting time is not particularly limited, but the roasting time is preferably 1 to 60 minutes after the product temperature reaches the roasting temperature, and more preferably 2 to 30 minutes. The method for raising the temperature up to the product temperature is not particularly limited, but it is preferable to gradually raise the temperature at a constant rate of increase (for example, 10 to 20 ° C./min).
焙煎方法は特に限定されないが、例えば、外部より電熱、熱風、バーナー、マイクロ波等を介して加熱することにより行うことができる。また、使用する焙煎機は特に限定されないが、例えば、回転流動床式、回転ドラム式、ロータリーキルン式等を使用することができる。 The roasting method is not particularly limited. For example, the roasting method can be performed by heating from the outside via electric heat, hot air, a burner, a microwave, or the like. Moreover, although the roasting machine to be used is not specifically limited, For example, a rotating fluidized bed type, a rotating drum type, a rotary kiln type etc. can be used.
圧搾に用いる圧搾機は、特に型式は問わないが、例えば円筒状に形成されたケーシングとその内部に回転自在に設けられたスクリューよりなるエキスペラー式圧搾機を好適に利用することができる。回転数や処理量は適宜調整することができる。 The type of the press used for pressing is not particularly limited. For example, an expeller-type pressing machine including a casing formed in a cylindrical shape and a screw rotatably provided therein can be preferably used. The number of rotations and the amount of processing can be adjusted as appropriate.
沈殿物の除去方法として、搾油後にろ過、もしくは1日〜約1週間室温にて静置し、上澄みを分取もしくはろ過する方法が挙げられるが、これに限定するものではない。 Examples of the method for removing the precipitate include, but are not limited to, a method of filtering after oil extraction, or a method of standing at room temperature for 1 day to about 1 week and fractionating or filtering the supernatant.
また、リン脂質の除去として、温度70〜80℃、水添加量3質量%(対圧搾粗油)の条件下、遠心分離機で遠心分離されることで脱ガム処理がなされ、乾燥後、再度ろ過する方法が挙げられるが、これに限定するものではない。 In addition, as removal of phospholipid, degumming treatment is performed by centrifuging with a centrifuge under the conditions of a temperature of 70 to 80 ° C. and a water addition amount of 3 mass% (compressed crude oil). Although the method of filtering is mentioned, It is not limited to this.
油脂に、0.05〜0.5質量%のリン酸を添加し、同混合物に対して5〜40%過剰のアルカリ水溶液を添加し、遠心分離により、沈殿物を除去する(脱酸工程)。脱酸工程を行うことにより、油脂中に含まれる遊離した脂肪酸を除去することができる。また、油脂中に含まれるリン脂質や金属塩、着色成分等も除去することができる。なお、沈殿物を除去する方法は、遠心分離に限定されず、静置分離等公知の種々の方法を使用することができる。 Add 0.05 to 0.5 mass% phosphoric acid to the oil and fat, add 5 to 40% excess alkaline aqueous solution to the mixture, and remove the precipitate by centrifugation (deoxidation step) . By performing a deoxidation process, the free fatty acid contained in fats and oils can be removed. Further, phospholipids, metal salts, coloring components and the like contained in the oil and fat can also be removed. The method for removing the precipitate is not limited to centrifugation, and various known methods such as stationary separation can be used.
アルカリ水溶液の添加量は、油脂中に含まれる遊離した脂肪酸の量によって決定される。アルカリ水溶液は、遊離した脂肪酸を中和するために必要な量よりも油脂とリン酸との混合物に対して5〜40%過剰に添加することが好ましい。アルカリ水溶液の添加量が5%未満であると、油脂中に遊離した脂肪酸を十分に除去することができない場合がある。一方、アルカリ水溶液の添加量が40質量%以下であると、油脂のけん化分解を抑えられ、収量の低下を抑えられる。 The addition amount of the aqueous alkaline solution is determined by the amount of free fatty acid contained in the fat. The aqueous alkali solution is preferably added in an excess of 5 to 40% with respect to the mixture of oil and phosphoric acid, compared to the amount necessary for neutralizing the liberated fatty acid. If the addition amount of the alkaline aqueous solution is less than 5%, the fatty acid liberated in the fat or oil may not be sufficiently removed. On the other hand, when the addition amount of the aqueous alkali solution is 40% by mass or less, saponification decomposition of fats and oils can be suppressed, and a decrease in yield can be suppressed.
脱酸工程で使用するアルカリ水溶液は、特に限定されず、例えば、水酸化ナトリウム水溶液、水酸化カリウム水溶液等公知の種々のアルカリ水溶液を使用することができる。 The aqueous alkali solution used in the deoxidation step is not particularly limited, and various known aqueous alkali solutions such as an aqueous sodium hydroxide solution and an aqueous potassium hydroxide solution can be used.
脱酸工程後、油脂中に含まれる石鹸(アルカリ成分)を除去するために水洗を行う(水洗工程)。水洗工程は、アルカリ成分を除去することができれば水洗でなくてもよく、例えば、湯を使用してアルカリ成分を除去してもよい。なお、水洗工程後、必要に応じて脱酸、水洗された油脂を乾燥させてもよい。 After the deoxidation step, washing with water is performed to remove the soap (alkali component) contained in the oil (flushing step). The washing step may not be washing with water as long as the alkali component can be removed. For example, the alkali component may be removed using hot water. In addition, you may dry the fats and oils which were deoxidized and washed with water after the water washing process as needed.
水洗工程後、油脂中に含まれる着色成分を吸着除去し、色の薄い精製油を得るために脱色工程を行う。また、脱色工程により、水洗工程にて除去することができなかったアルカリ成分、酸化促進や着色の原因となる各種金属塩、クロロフィル等の着色成分、その他風味や安定性に影響する成分を除去することができる。 After the water washing step, the decolorization step is performed in order to adsorb and remove the coloring components contained in the fat and oil and to obtain a light colored refined oil. In addition, the decolorization step removes alkali components that could not be removed in the water washing step, various metal salts that cause oxidation promotion and coloring, coloring components such as chlorophyll, and other components that affect flavor and stability. be able to.
脱色工程は、油脂に吸着剤を添加することにより行う。油脂に添加する吸着剤は、適宜変更することができるが、例えば、モンモリロナイトを主成分とする白色から黄褐色の粘度好物である白土を酸処理した活性白土、活性炭等公知の種々の吸着剤を使用することができる。これらは単独で使用してもよいが、複数組み合わせて使用してもよい。 A decoloring process is performed by adding an adsorbent to fats and oils. The adsorbent to be added to the fats and oils can be appropriately changed. For example, various known adsorbents such as activated clay and activated carbon obtained by acid-treating white clay, which is a white to yellowish brownish favorite material mainly composed of montmorillonite, are used. Can be used. These may be used alone or in combination.
吸着剤の添加量は、油脂中に含まれる着色成分量によって適宜変化させることができるが、例えば、油脂に対して0.2質量%以上であることが好ましい。吸着剤の添加量が0.2質量%以上であると、脱色の効率がよく、また、脱酸工程で残存している石鹸分も除去することが可能である。 The addition amount of the adsorbent can be appropriately changed depending on the amount of the coloring component contained in the oil or fat, and is preferably 0.2% by mass or more with respect to the oil or fat, for example. When the amount of adsorbent added is 0.2% by mass or more, the decolorization efficiency is good, and the soap remaining in the deoxidation step can be removed.
油脂と吸着剤との接触条件は、油脂によって適宜変更することができるが、例えば90〜120℃で10〜40分間接触させることが好ましい。この条件で効率的に脱色工程を行うことができる。 Although the contact conditions of fats and oils and an adsorbent can be suitably changed with fats and oils, it is preferable to make it contact for 10 to 40 minutes, for example at 90-120 degreeC. Under this condition, the decolorization step can be performed efficiently.
また、油脂と吸着剤とを接触させる際、水分の存在により吸着剤の吸着効率の低下を防止するとともに、酸素の存在による油脂の酸化を防止するために、減圧下で油脂と吸着剤とを接触させ、脱色工程を行うことが好ましい。 In addition, when contacting the fats and oils with the adsorbent, the presence of moisture prevents the adsorption efficiency of the adsorbents from decreasing and also prevents the fats and oils from being oxidized due to the presence of oxygen. It is preferable to perform a decoloring process by making it contact.
脱色工程終了後、フィルタープレス等によりろ過し、吸着剤を除去する。 After completion of the decolorization step, the adsorbent is removed by filtration with a filter press or the like.
脱臭工程は、揮発性物質等を除去することができれば、脱臭方法は特に限定されないが、例えば、油脂の精製に通常用いられる減圧水蒸気蒸留にて脱臭することが好ましい。 In the deodorization step, the deodorization method is not particularly limited as long as volatile substances and the like can be removed. For example, it is preferable to deodorize by depressurization steam distillation which is usually used for oil and fat purification.
減圧水蒸気蒸留は、焙煎油の臭気の強さにより適宜変更されるが、例えば、減圧下、120〜260℃で30〜180分間行うことが好ましい。 The reduced-pressure steam distillation is appropriately changed depending on the odor intensity of the roasting oil, and is preferably performed, for example, at 120 to 260 ° C. for 30 to 180 minutes under reduced pressure.
脱臭工程後、精製油、すなわち脱臭焙煎ゴマ油、脱臭焙煎大豆油または脱臭焙煎菜種油を得ることができる。 After the deodorization step, refined oil, that is, deodorized roasted sesame oil, deodorized roasted soybean oil or deodorized roasted rapeseed oil can be obtained.
[油脂組成物を使用した加工品]
本発明の油脂組成物を使用することで、油脂組成物の臭気(例えば、青臭さ、穀物のような臭い、戻り臭、加熱臭)等が改善された加工品を製造することができる。すなわち、本発明の油脂組成物は、原料特有の不快な臭い、例えば、大豆における青臭さや、戻り臭および加熱調理時の加熱臭が抑制され、かつ、含有させた焙煎油の生風味がしないので、この油脂組成物を使用した油ちょう食品等の加工品は、原料特有の不快な臭いや焙煎油風味が付与されることがない。そのため、加工品として用いても原料特有の不快な臭いや戻り臭、加熱臭が抑制された加工品本来の風味が得られる。[Processed products using oil and fat compositions]
By using the oil and fat composition of the present invention, a processed product in which the odor of the oil and fat composition (for example, blue odor, grainy odor, return odor, heated odor) and the like can be produced. That is, the fat and oil composition of the present invention has an unpleasant odor peculiar to raw materials, for example, a blue odor in soybeans, a return odor and a heating odor during cooking, and does not have a raw flavor of the roasted oil contained therein. Therefore, processed products such as oily foods using this oil and fat composition do not have an unpleasant odor or roasted oil flavor peculiar to raw materials. Therefore, even if it is used as a processed product, the original flavor of the processed product in which the unpleasant odor, return odor and heating odor peculiar to the raw material are suppressed can be obtained.
かかる加工品としては、特に限定されず、例えば、ポテトチップス等の油ちょう食品、炒め物、マーガリン、ショートニング等の可塑性油脂組成物、油脂コーティング食品、ホイップクリーム等の起泡性水中油型乳化物、コーヒークリーム、フラワーペースト、冷菓、焼き菓子等が挙げられる。 Such processed products are not particularly limited, for example, oily foods such as potato chips, fried foods, plastic oils and fats compositions such as margarine and shortening, oil-coated foods, foaming oil-in-water emulsions such as whipped cream , Coffee cream, flower paste, frozen confectionery, baked confectionery and the like.
以下、実施例により本発明をさらに詳細に説明するが、本発明はこれらに限定されるものではない。 EXAMPLES Hereinafter, although an Example demonstrates this invention further in detail, this invention is not limited to these.
<未脱臭焙煎ゴマ油の製造>
ゴマをゴマの品温が130〜200℃の範囲で約2分間、焙煎を行い、圧搾により搾油した。搾油後、室温にて1週間静置し、沈殿物を分離した。さらに室温にて1週間静置し、沈殿物を分離して未脱臭焙煎ゴマ油を得た。<Manufacture of non-deodorized roasted sesame oil>
The sesame was roasted for about 2 minutes in the range of the sesame product temperature in the range of 130 to 200 ° C. and squeezed by pressing. After squeezing, the mixture was allowed to stand at room temperature for 1 week to separate the precipitate. Furthermore, it left still at room temperature for 1 week, the deposit was isolate | separated, and the undeodorized roasted sesame oil was obtained.
<脱臭焙煎ゴマ油の製造>
未脱臭焙煎ゴマ油に、焙煎油に対して0.1質量%のリン酸を添加し、同混合物に対して20%過剰の水酸化ナトリウム水溶液を添加し、遠心分離により、沈殿物を除去した。水洗の後、減圧下、90〜120℃で10〜20分間、活性白土と接触させて脱色を行った。得られた脱色油を250℃で90分間脱臭を行い、脱臭焙煎ゴマ油を得た。<Manufacture of deodorized roasted sesame oil>
Add non-deodorized roasted sesame oil with 0.1 mass% phosphoric acid to roasted oil, add 20% excess sodium hydroxide aqueous solution to the mixture, and remove precipitate by centrifugation. did. After washing with water, decolorization was performed by contacting with activated clay at 90 to 120 ° C. for 10 to 20 minutes under reduced pressure. The obtained decolorized oil was deodorized at 250 ° C. for 90 minutes to obtain a deodorized roasted sesame oil.
<未脱臭焙煎大豆油の製造>
大豆を大豆の品温が130〜220℃の範囲で約10分間、焙煎を行い、圧搾により搾油した。搾油後、約1日静置し、ろ過を行い、未脱臭焙煎大豆油を得た。<Manufacture of non-deodorized roasted soybean oil>
The soybean was roasted for about 10 minutes in the range of the soybean temperature of 130 to 220 ° C. and squeezed by pressing. After squeezing, the mixture was allowed to stand for about 1 day and filtered to obtain an undeodorized roasted soybean oil.
<脱臭焙煎大豆油の製造>
未脱臭焙煎大豆油に、焙煎油に対して0.2質量%のリン酸を添加し、同混合物に対して20%過剰の水酸化ナトリウム水溶液を添加し、遠心分離により、沈殿物を除去した。水洗の後、減圧下、90〜120℃で10〜20分間、活性白土と接触させて脱色を行った。得られた脱色油を250℃で90分間脱臭を行い、脱臭焙煎大豆油を得た。<Manufacture of deodorized roasted soybean oil>
To non-deodorized roasted soybean oil, 0.2% by mass of phosphoric acid is added to the roasted oil, 20% excess aqueous sodium hydroxide solution is added to the mixture, and the precipitate is removed by centrifugation. Removed. After washing with water, decolorization was performed by contacting with activated clay at 90 to 120 ° C. for 10 to 20 minutes under reduced pressure. The obtained decolorized oil was deodorized at 250 ° C. for 90 minutes to obtain a deodorized roasted soybean oil.
<未脱臭焙煎菜種油の製造>
菜種を菜種の品温が130〜200℃の範囲で約5分間、焙煎を行い、圧搾により搾油した。搾油後、水脱ガム、乾燥、ろ過を行い、未脱臭焙煎菜種油を得た。<Manufacture of non-deodorized roasted rapeseed oil>
The rapeseed was roasted for about 5 minutes in the range of the rapeseed product temperature in the range of 130 to 200 ° C. and squeezed by pressing. After oil extraction, water degumming, drying and filtration were performed to obtain an undeodorized roasted rapeseed oil.
<脱臭焙煎菜種油>
未脱臭焙煎菜種油に、焙煎油に対して0.1質量%のリン酸を添加し、同混合物に対して20%過剰の水酸化ナトリウム水溶液を添加し、遠心分離により、沈殿物を除去した。水洗の後、減圧下、90〜120℃で10〜20分間、活性白土と接触させて脱色を行った。得られた脱色油を250℃で90分間脱臭を行い、脱臭焙煎菜種油を得た。<Deodorized roasted rapeseed oil>
Add 0.1% by mass phosphoric acid to roasted rapeseed oil, add 20% excess sodium hydroxide aqueous solution to the same mixture, and remove precipitates by centrifugation. did. After washing with water, decolorization was performed by contacting with activated clay at 90 to 120 ° C. for 10 to 20 minutes under reduced pressure. The obtained decolorized oil was deodorized at 250 ° C. for 90 minutes to obtain a deodorized roasted rapeseed oil.
[試験例1]
(油脂組成物の戻り臭(劣化臭)抑制効果)
表1に示したように、大豆油中の未脱臭焙煎ゴマ油の含有量を変化させた油脂組成物をそれぞれ調製した。脱臭焙煎ゴマ油を含有させた油脂組成物、未脱臭焙煎菜種油を含有させた油脂組成物、脱臭焙煎菜種油を含有させた油脂組成物、未脱臭焙煎大豆油を含有させた油脂組成物および脱臭焙煎大豆油を含有させた油脂組成物も同様に調製した。[Test Example 1]
(Return odor (deterioration odor) suppression effect of oil and fat composition)
As shown in Table 1, oil and fat compositions in which the content of undeodorized roasted sesame oil in soybean oil was changed were prepared. Oil and fat composition containing deodorized roasted sesame oil, Oil and fat composition containing non-deodorized roasted rapeseed oil, Oil and fat composition containing deodorized roasted rapeseed oil, Oil and fat composition containing non-deodorized roasted rapeseed oil A fat composition containing deodorized roasted soybean oil was also prepared in the same manner.
<曝光試験>
調製した各油脂組成物を500ml共栓付き三角フラスコに200ml入れ、栓をした後、7000lxで16時間照射することにより、曝光試験を行い、これを官能評価用サンプルとした。<Exposure test>
200 ml of each prepared oil and fat composition was put into a 500 ml conical flask with a stopper, stoppered, and irradiated with 7000 lx for 16 hours to perform an exposure test, which was used as a sample for sensory evaluation.
<試験結果>
(焙煎油の風味の有無)
官能評価用サンプルを20℃に保ちながら官能試験を行った。官能試験の評価は、20名のパネルにより行った。焙煎油の風味を感じないと答えたパネルが15名以上の場合を「○」とし、焙煎油の風味を感じないと答えたパネルが11名以上15未満の場合を「△」とし、焙煎油の風味を感じないと答えたパネルが10名以下の場合を「×」とした。結果を表1に示す。<Test results>
(With or without roasted oil flavor)
A sensory test was performed while keeping the sample for sensory evaluation at 20 ° C. The sensory test was evaluated by a panel of 20 people. The case where there are 15 or more panelists who answered that they do not feel the flavor of roasting oil is indicated as “◯”, and the case where the panel which responded that they do not feel the flavor of roasting oil is 11 or more is indicated as “△”. A case where 10 or fewer panelists answered that they did not feel the flavor of roasting oil was indicated as “x”. The results are shown in Table 1.
(戻り臭の有無)
官能評価用サンプルを20℃に保ちながら官能試験を行った。官能試験の評価は、20名のパネルにより行った。戻り臭(劣化臭)が感じないと答えたパネルが15名以上の場合を「○」とし、戻り臭を感じないと答えたパネルが11名以上15未満の場合を「△」とし、戻り臭を感じないと答えたパネルが10名以下の場合を「×」とした。結果を表1に示す。(With or without return odor)
A sensory test was performed while keeping the sample for sensory evaluation at 20 ° C. The sensory test was evaluated by a panel of 20 people. If there are 15 or more panelists who do not feel a return odor (deteriorated odor), “○” is assigned. The case where there were 10 or less panel members who answered that they did not feel “x” was indicated as “x”. The results are shown in Table 1.
表1より、未脱臭焙煎ゴマ油を含有させた油脂組成物は、未脱臭焙煎ゴマ油の含有量が37.5〜75ppmの範囲において、未脱臭焙煎ゴマ油の風味および大豆油の戻り臭を感じなかった。 From Table 1, the fat composition containing non-deodorized roasted sesame oil has the flavor of non-deodorized roasted sesame oil and the return odor of soybean oil in the range of 37.5 to 75 ppm of non-deodorized roasted sesame oil. I didn't feel it.
表1より、脱臭焙煎ゴマ油を含有させた油脂組成物は、脱臭焙煎ゴマ油の含有量が10〜10000ppmの範囲において、脱臭焙煎ゴマ油の風味および大豆油の戻り臭を感じなかった。 From Table 1, the fat and oil composition containing the deodorized roasted sesame oil did not feel the flavor of the deodorized roasted sesame oil and the return odor of soybean oil when the content of the deodorized roasted sesame oil was in the range of 10 to 10,000 ppm.
表1より、未脱臭焙煎菜種油を含有させた油脂組成物は、未脱臭焙煎菜種油の含有量が25〜5000ppmの範囲において、未脱臭焙煎菜種油の風味および大豆油の戻り臭を感じなかった。 From Table 1, the fat composition containing non-deodorized roasted rapeseed oil does not feel the flavor of non-deodorized roasted rapeseed oil and the return odor of soybean oil in the range of the content of non-deodorized roasted rapeseed oil of 25 to 5000 ppm. It was.
表1より、脱臭焙煎菜種油を含有させた油脂組成物は、脱臭焙煎菜種油の含有量が100〜100000ppmの範囲において、脱臭焙煎菜種油の風味および大豆油の戻り臭を感じなかった。 From Table 1, the fat and oil composition containing the deodorized roasted rapeseed oil did not feel the flavor of the deodorized roasted rapeseed oil and the return odor of soybean oil when the content of the deodorized roasted rapeseed oil was in the range of 100 to 100,000 ppm.
表1より、未脱臭焙煎大豆油を含有させた油脂組成物は、未脱臭焙煎大豆油の含有量が25〜5000ppmの範囲において、未脱臭焙煎大豆油の風味および大豆油の戻り臭を感じなかった。 From Table 1, the fat and oil composition containing the non-deodorized roasted soybean oil has the flavor of the non-deodorized roasted soybean oil and the return odor of the soybean oil in the range where the content of the non-deodorized roasted soybean oil is 25 to 5000 ppm. I did not feel.
表1より、脱臭焙煎大豆油を含有させた油脂組成物は、脱臭焙煎大豆油の含有量が100〜100000ppmの範囲において、脱臭焙煎大豆油の風味および大豆油の戻り臭を感じなかった。 From Table 1, the fat and oil composition containing the deodorized roasted soybean oil does not feel the flavor of the deodorized roasted soybean oil and the return odor of the soybean oil when the content of the deodorized roasted soybean oil is in the range of 100 to 100,000 ppm. It was.
[試験例2]
(油脂組成物の戻り臭(劣化臭)抑制効果)
パーム油中に未脱臭焙煎菜種油を1000ppm含有させることにより、油脂組成物を調製した。[Test Example 2]
(Return odor (deterioration odor) suppression effect of oil and fat composition)
An oil and fat composition was prepared by containing 1000 ppm of non-deodorized roasted rapeseed oil in palm oil.
<保存試験>
調製した油脂組成物を100mlポリエチレン製採水瓶に80g入れ、キャップをした後、20℃に保ちながら暗所にて7週間保存した。保存した油脂組成物は、1週間ごとに採取し、官能評価用サンプルとした。なお、5℃に保ちながら保存した以外は同様な方法で保存した場合も試験を行った。<Storage test>
80 g of the prepared oil / fat composition was put into a 100 ml polyethylene water bottle, capped, and stored in a dark place for 7 weeks while keeping at 20 ° C. The preserved oil and fat composition was collected every week and used as a sensory evaluation sample. The test was also conducted when the sample was stored in the same manner except that it was stored at 5 ° C.
<試験結果>
(焙煎油の風味の有無)
官能評価用サンプルを20℃に保ちながら官能試験を行った。官能試験の評価は、20名のパネルにより行った。焙煎油の風味を感じないと答えたパネルが15名以上の場合を「○」とし、焙煎油の風味を感じないと答えたパネルが11名以上15未満の場合を「△」とし、焙煎油の風味を感じないと答えたパネルが10名以下の場合を「×」とした。20℃で保存した場合の結果を表2に、5℃で保存した場合の結果を表3に示す。<Test results>
(With or without roasted oil flavor)
A sensory test was performed while keeping the sample for sensory evaluation at 20 ° C. The sensory test was evaluated by a panel of 20 people. The case where there are 15 or more panelists who answered that they do not feel the flavor of roasting oil is indicated as “◯”, and the case where the panel which responded that they do not feel the flavor of roasting oil is 11 or more is indicated as “△”. A case where 10 or fewer panelists answered that they did not feel the flavor of roasting oil was indicated as “x”. The results when stored at 20 ° C. are shown in Table 2, and the results when stored at 5 ° C. are shown in Table 3.
(戻り臭の有無)
官能評価用サンプルを20℃に保ちながら官能試験を行った。官能試験の評価は、20名のパネルにより行った。戻り臭(劣化臭)が感じないと答えたパネルが15名以上の場合を「○」とし、戻り臭を感じないと答えたパネルが11名以上15未満の場合を「△」とし、戻り臭を感じないと答えたパネルが10名以下の場合を「×」とした。20℃で保存した場合の結果を表2に、5℃で保存した場合の結果を表3に示す。(With or without return odor)
A sensory test was performed while keeping the sample for sensory evaluation at 20 ° C. The sensory test was evaluated by a panel of 20 people. If there are 15 or more panelists who do not feel a return odor (deteriorated odor), “○” is assigned. The case where there were 10 or less panel members who answered that they did not feel “x” was indicated as “x”. The results when stored at 20 ° C. are shown in Table 2, and the results when stored at 5 ° C. are shown in Table 3.
表2より、20℃にて保存した場合、未脱臭焙煎菜種油を含有させていないパーム油単品は、4週間経過するとパーム油の戻り臭が発生したのに対し、未脱臭焙煎菜種油を1000ppmパーム油に含有させた油脂組成物は、5週間までパーム油の戻り臭が発生しなかったとともに、未脱臭焙煎菜種油の風味も感じなかった。 From Table 2, when stored at 20 ° C., the palm oil alone containing no undeodorized roasted rapeseed oil produced a return odor of palm oil after 4 weeks, whereas the deodorized roasted rapeseed oil was 1000 ppm. The oil and fat composition contained in the palm oil did not generate the return odor of the palm oil until 5 weeks, and did not feel the flavor of the undeodorized roasted rapeseed oil.
また、表3より、5℃で保存した場合、未脱臭焙煎菜種油を含有させていないパーム油単品は、2週間経過するとパーム油の戻り臭が発生したのに対し、未脱臭焙煎菜種油を1000ppmパーム油に含有させた油脂組成物は、4週間までパーム油の戻り臭が発生しなかったとともに、未脱臭焙煎菜種油の風味も感じなかった。 In addition, from Table 3, when stored at 5 ° C., the palm oil alone containing no undeodorized roasted rapeseed oil produced a return odor of palm oil after 2 weeks. The fat and oil composition contained in 1000 ppm palm oil did not generate a return odor of palm oil until 4 weeks, and did not feel the flavor of undeodorized roasted rapeseed oil.
[試験例3]
(油脂組成物の戻り臭(劣化臭)抑制効果)
表4に示したように、フラックス油:菜種油を3:7にブレンドした油中の未脱臭焙煎ゴマ油の含有量を変化させた油脂組成物をそれぞれ調製した。脱臭焙煎ゴマ油を含有させた油脂組成物、脱臭焙煎菜種油を含有させた油脂組成物も同様に調製した。[Test Example 3]
(Return odor (deterioration odor) suppression effect of oil and fat composition)
As shown in Table 4, each fat and oil composition was prepared by changing the content of undeodorized roasted sesame oil in the oil blended with flux oil: rapeseed oil at 3: 7. An oil / fat composition containing deodorized roasted sesame oil and an oil / fat composition containing deodorized roasted rapeseed oil were similarly prepared.
<保存試験>
調製した各油脂組成物をPETボトル(容量600g)に600g入れ、栓をした後、40℃に保ちながら暗所にて4週間保存し、これを官能評価用サンプルとした。<Storage test>
600 g of each prepared oil and fat composition was put into a PET bottle (capacity 600 g), stoppered, and stored for 4 weeks in a dark place while keeping at 40 ° C., and this was used as a sample for sensory evaluation.
<試験結果>
(焙煎油の風味の有無)
官能評価用サンプルを20℃に保ちながら官能試験を行った。官能試験の評価は、20名のパネルにより行った。焙煎油の風味を感じないと答えたパネルが15名以上の場合を「○」とし、焙煎油の風味を感じないと答えたパネルが11名以上15未満の場合を「△」とし、焙煎油の風味を感じないと答えたパネルが10名以下の場合を「×」とした。結果を表4に示す。<Test results>
(With or without roasted oil flavor)
A sensory test was performed while keeping the sample for sensory evaluation at 20 ° C. The sensory test was evaluated by a panel of 20 people. The case where there are 15 or more panelists who answered that they do not feel the flavor of roasting oil is indicated as “◯”, and the case where the panel which responded that they do not feel the flavor of roasting oil is 11 or more is indicated as “△”. A case where 10 or fewer panelists answered that they did not feel the flavor of roasting oil was indicated as “x”. The results are shown in Table 4.
(戻り臭の有無)
官能評価用サンプルを20℃に保ちながら官能試験を行った。官能試験の評価は、20名のパネルにより行った。戻り臭(劣化臭)が感じないと答えたパネルが15名以上の場合を「○」とし、戻り臭を感じないと答えたパネルが11名以上15未満の場合を「△」とし、戻り臭を感じないと答えたパネルが10名以下の場合を「×」とした。結果を表4に示す。(With or without return odor)
A sensory test was performed while keeping the sample for sensory evaluation at 20 ° C. The sensory test was evaluated by a panel of 20 people. If there are 15 or more panelists who do not feel a return odor (deteriorated odor), “○” is assigned. The case where there were 10 or less panel members who answered that they did not feel “x” was indicated as “x”. The results are shown in Table 4.
表4より、未脱臭焙煎ゴマ油を含有させたフラックス油と菜種油とのブレンド油は、未脱臭焙煎ゴマ油の含有量が37.5〜75ppmの範囲において、未脱臭焙煎ゴマ油の風味およびフラックス油と菜種油とのブレンド油の戻り臭を感じなかった。 From Table 4, the blended oil of rapeseed oil and rapeseed oil containing non-deodorized roasted sesame oil has a flavor and flux of non-deodorized roasted sesame oil in the range of 37.5 to 75 ppm of non-deodorized roasted sesame oil. The return odor of the blend oil of oil and rapeseed oil was not felt.
また、表4より、脱臭焙煎ゴマ油を含有させたフラックス油と菜種油とのブレンド油は、脱臭焙煎ゴマ油の含有量が50〜5000ppmの範囲において、脱臭焙煎ゴマ油の風味を感じず、50〜50000ppmの範囲において、フラックス油と菜種油とのブレンド油の戻り臭を感じなかった。 Moreover, from Table 4, the blend oil of the flux oil and rapeseed oil containing the deodorized roasted sesame oil does not feel the flavor of the deodorized roasted sesame oil when the content of the deodorized roasted sesame oil is in the range of 50 to 5000 ppm. In the range of ˜50000 ppm, the return odor of the blend oil of flux oil and rapeseed oil was not felt.
さらに、表4より、脱臭焙煎菜種油を含有させたフラックス油と菜種油とのブレンド油は、脱臭焙煎菜種油の含有量が500〜50000ppmの範囲において、脱臭焙煎菜種油の風味を感じず、500〜200000ppmの範囲において、フラックス油と菜種油とのブレンド油の戻り臭を感じなかった。 Furthermore, from Table 4, the blend oil of the flux oil and rapeseed oil containing the deodorized roasted rapeseed oil does not feel the flavor of the deodorized roasted rapeseed oil when the content of the deodorized roasted rapeseed oil is 500 to 50000 ppm. In the range of ˜200000 ppm, the return odor of the blend oil of flux oil and rapeseed oil was not felt.
[試験例4]
(ポテトチップスの戻り臭(劣化臭)抑制効果)
表5に示したように、大豆油中の未脱臭焙煎菜種油の含有量を変化させた油脂組成物をそれぞれ調製し、各油脂組成物を用いてポテトチップスを作成した。ポテトチップスは、予めスライサーでスライスしたジャガイモを各油脂組成物で170〜180℃で2分30秒油ちょうすることにより作成した。また、未脱臭焙煎大豆油を含有させた油脂組成物を使用した場合も同様にポテトチップスを作成した。[Test Example 4]
(Return odor (deterioration odor) suppression effect of potato chips)
As shown in Table 5, oil compositions with different contents of non-deodorized roasted rapeseed oil in soybean oil were prepared, and potato chips were prepared using each oil composition. Potato chips were prepared by oiling potato sliced with a slicer in advance at 170 to 180 ° C. for 2 minutes and 30 seconds with each oil composition. Also, potato chips were prepared in the same manner when an oil and fat composition containing undeodorized roasted soybean oil was used.
<曝光試験>
各油脂組成物を用いて作成した各ポテトチップスをそれぞれ透明ポリエチレン製袋に入れ、密封した後、7000lxで40時間照射することにより、曝光試験を行い、これを官能評価用サンプルとした。<Exposure test>
Each potato chip prepared using each oil and fat composition was put in a transparent polyethylene bag, sealed, and then irradiated with 7000 lx for 40 hours to perform an exposure test, which was used as a sample for sensory evaluation.
<試験結果>
(焙煎油の風味の有無)
官能評価用サンプルを20℃に保ちながら官能試験を行った。官能試験の評価は、20名のパネルにより行った。焙煎油の風味を感じないと答えたパネルが15名以上の場合を「○」とし、焙煎油の風味を感じないと答えたパネルが11名以上15未満の場合を「△」とし、焙煎油の風味を感じないと答えたパネルが10名以下の場合を「×」とした。結果を表5に示す。<Test results>
(With or without roasted oil flavor)
A sensory test was performed while keeping the sample for sensory evaluation at 20 ° C. The sensory test was evaluated by a panel of 20 people. The case where there are 15 or more panelists who answered that they do not feel the flavor of roasting oil is indicated as “◯”, and the case where the panel which responded that they do not feel the flavor of roasting oil is 11 or more is indicated as “△”. A case where 10 or fewer panelists answered that they did not feel the flavor of roasting oil was indicated as “x”. The results are shown in Table 5.
(戻り臭の有無)
官能評価用サンプルを20℃に保ちながら官能試験を行った。官能試験の評価は、20名のパネルにより行った。戻り臭(劣化臭)が感じないと答えたパネルが15名以上の場合を「○」とし、戻り臭を感じないと答えたパネルが11名以上15未満の場合を「△」とし、戻り臭を感じないと答えたパネルが10名以下の場合を「×」とした。結果を表5に示す。(With or without return odor)
A sensory test was performed while keeping the sample for sensory evaluation at 20 ° C. The sensory test was evaluated by a panel of 20 people. If there are 15 or more panelists who do not feel a return odor (deteriorated odor), “○” is assigned. The case where there were 10 or less panel members who answered that they did not feel “x” was indicated as “x”. The results are shown in Table 5.
表5より、未脱臭焙煎菜種油を含有させた油脂組成物で油ちょうしたポテトチップスは、未脱臭焙煎菜種油の含有量が25〜50000ppmの範囲において、未脱臭焙煎菜種油の風味および大豆油の戻り臭を感じなかった。 From Table 5, the potato chips oiled with the oil and fat composition containing the non-deodorized roasted rapeseed oil has a non-deodorized roasted rapeseed oil flavor and soybean oil in the range of the content of the non-deodorized roasted rapeseed oil in the range of 25 to 50000 ppm. I did not feel the return odor.
また、表5より、未脱臭焙煎大豆油を含有させた油脂組成物で油ちょうしたポテトチップスは、未脱臭焙煎大豆油の含有量が25〜100ppmの範囲において、未脱臭焙煎大豆油の風味および大豆油の戻り臭を感じなかった。 In addition, from Table 5, the potato chips oiled with the fat composition containing the non-deodorized roasted soybean oil has a non-deodorized roasted soybean oil content in the range of 25 to 100 ppm. I did not feel the flavor and the return odor of soybean oil.
[試験例5]
(焼き菓子の戻り臭(劣化臭)抑制効果)
表6に示したように、パーム油中の未脱臭焙煎ゴマ油の含有量を変化させた油脂組成物をそれぞれ調製した。各油脂組成物を用いて急冷練り合わせ処理を行い、ショートニングを得た。ショートニングに上白糖を加え、ホイップすることにより、全卵を徐々に加えた。その後、薄力粉、ベーキングパウダーを加えて混合し、パウンド型に流し込み上火180℃、下火160℃で40分間焼成することにより、焼き菓子を作成した。なお、下記菓子の材料の配合部は表6に示すとおりである。[Test Example 5]
(Return odor (deterioration odor) control effect of baked goods)
As shown in Table 6, each fat composition was prepared by changing the content of undeodorized roasted sesame oil in palm oil. Each oil and fat composition was used for rapid cooling and kneading treatment to obtain a shortening. Whole egg was gradually added by adding top white sugar to shortening and whipping. Then, the weak flour and baking powder were added and mixed, poured into a pound mold and baked for 40 minutes at 180 ° C. and 160 ° C. on the upper flame to prepare baked confectionery. In addition, the compounding part of the following confectionery materials is as shown in Table 6.
<曝光試験>
各油脂組成物を用いて調製した各焼き菓子をそれぞれ透明ポリエチレン製袋に入れ、密封した後、7000lxで40時間照射することにより、曝光試験を行い、これを官能評価用サンプルとした。<Exposure test>
Each baked confectionery prepared using each oil / fat composition was put in a transparent polyethylene bag, sealed, and then irradiated at 7000 lx for 40 hours to perform an exposure test, which was used as a sample for sensory evaluation.
<試験結果>
(焙煎油の風味の有無)
官能評価用サンプルを20℃に保ちながら官能試験を行った。官能試験の評価は、20名のパネルにより行った。焙煎油の風味を感じないと答えたパネルが15名以上の場合を「○」とし、焙煎油の風味を感じないと答えたパネルが11名以上15未満の場合を「△」とし、焙煎油の風味を感じないと答えたパネルが10名以下の場合を「×」とした。結果を表7に示す。<Test results>
(With or without roasted oil flavor)
A sensory test was performed while keeping the sample for sensory evaluation at 20 ° C. The sensory test was evaluated by a panel of 20 people. The case where there are 15 or more panelists who answered that they do not feel the flavor of roasting oil is indicated as “◯”, and the case where the panel which responded that they do not feel the flavor of roasting oil is 11 or more is indicated as “△”. A case where 10 or fewer panelists answered that they did not feel the flavor of roasting oil was indicated as “x”. The results are shown in Table 7.
(戻り臭の有無)
官能評価用サンプルを20℃に保ちながら官能試験を行った。官能試験の評価は、20名のパネルにより行った。戻り臭(劣化臭)が感じないと答えたパネルが15名以上の場合を「○」とし、戻り臭を感じないと答えたパネルが11名以上15未満の場合を「△」とし、戻り臭を感じないと答えたパネルが10名以下の場合を「×」とした。結果を表7に示す。 (With or without return odor)
A sensory test was performed while keeping the sample for sensory evaluation at 20 ° C. The sensory test was evaluated by a panel of 20 people. If there are 15 or more panelists who do not feel a return odor (deteriorated odor), “○” is assigned. The case where there were 10 or less panel members who answered that they did not feel “x” was indicated as “x”. The results are shown in Table 7.
表7より、未脱臭焙煎ゴマ油を含有させた油脂組成物を用いて作成した焼き菓子は、未脱臭焙煎ゴマ油の含有量が2〜2500ppmの範囲において、未脱臭焙煎ゴマ油の風味およびパーム油の戻り臭を感じなかった。 From Table 7, the baked confectionery prepared using the fat and oil composition containing the non-deodorized roasted sesame oil has the flavor of the non-deodorized roasted sesame oil and the palm in the range where the content of the non-deodorized roasted sesame oil is 2 to 2500 ppm. I did not feel the odor of oil.
Claims (15)
臭気を有する油脂:大豆油、大豆油のエステル交換油、大豆油を含む混合油のエステル交換油、コーン油、コーン油のエステル交換油、コーン油を含む混合油のエステル交換油、パーム系油脂、パーム系油脂のエステル交換油、パーム系油脂を含む混合油のエステル交換油、フラックス油、フラックス油のエステル交換油、フラックス油を含む混合油のエステル交換油、エゴマ油、エゴマ油のエステル交換油、エゴマ油を含む混合油のエステル交換油からなる群から選ばれる1種または2種以上。An oil / fat composition containing an odorous oil and an undeodorized roasted sesame oil, wherein the content of the non-deodorized roasted sesame oil in the oil / fat composition is equivalent to the amount of the oil / fat having the odor An oil and fat composition having a mass ratio of 2 to 2500 ppm.
Odorous fats and oils: Soybean oil, transesterified oil of soybean oil, transesterified oil of mixed oil containing soybean oil, corn oil, transesterified oil of corn oil, transesterified oil of mixed oil containing corn oil, palm oil Transesterified oil of palm-based fats and oils, transesterified oils of mixed oils containing palm-based fats and oils, flux oils, transesterified oils of flux oils, transesterified oils of mixed oils containing fluxed oils, sesame oils, transesterified oils of sesame oils 1 type (s) or 2 or more types chosen from the group which consists of transesterified oil of mixed oil containing oil and egoma oil.
臭気を有する油脂:大豆油、大豆油のエステル交換油、大豆油を含む混合油のエステル交換油、コーン油、コーン油のエステル交換油、コーン油を含む混合油のエステル交換油、パーム系油脂、パーム系油脂のエステル交換油、パーム系油脂を含む混合油のエステル交換油、フラックス油、フラックス油のエステル交換油、フラックス油を含む混合油のエステル交換油、エゴマ油、エゴマ油のエステル交換油、エゴマ油を含む混合油のエステル交換油からなる群から選ばれる1種または2種以上。An oil / fat composition containing an odorous oil and non-deodorized roasted soybean oil, wherein the content of the non-deodorized roasted soybean oil in the oil / fat composition is equivalent to the oil / fat having the odor The oil-and-fat composition which is 25-5000 ppm by mass ratio.
Odorous fats and oils: Soybean oil, transesterified oil of soybean oil, transesterified oil of mixed oil containing soybean oil, corn oil, transesterified oil of corn oil, transesterified oil of mixed oil containing corn oil, palm oil Transesterified oil of palm-based fats and oils, transesterified oils of mixed oils containing palm-based fats and oils, flux oils, transesterified oils of flux oils, transesterified oils of mixed oils containing fluxed oils, sesame oils, transesterified oils of sesame oils 1 type (s) or 2 or more types chosen from the group which consists of transesterified oil of mixed oil containing oil and egoma oil.
臭気を有する油脂:大豆油、大豆油のエステル交換油、大豆油を含む混合油のエステル交換油、コーン油、コーン油のエステル交換油、コーン油を含む混合油のエステル交換油、パーム系油脂、パーム系油脂のエステル交換油、パーム系油脂を含む混合油のエステル交換油、フラックス油、フラックス油のエステル交換油、フラックス油を含む混合油のエステル交換油、エゴマ油、エゴマ油のエステル交換油、エゴマ油を含む混合油のエステル交換油からなる群から選ばれる1種または2種以上。An oil / fat composition containing an odorous fat and an undeodorized roasted rapeseed oil, wherein the content of the non-deodorized roasted rapeseed oil in the oil / fat composition is equivalent to the amount of the oil / fat having the odor An oil and fat composition having a mass ratio of 25 to 50000 ppm.
Odorous fats and oils: Soybean oil, transesterified oil of soybean oil, transesterified oil of mixed oil containing soybean oil, corn oil, transesterified oil of corn oil, transesterified oil of mixed oil containing corn oil, palm oil Transesterified oil of palm-based fats and oils, transesterified oils of mixed oils containing palm-based fats and oils, flux oils, transesterified oils of flux oils, transesterified oils of mixed oils containing fluxed oils, sesame oils, transesterified oils of sesame oils 1 type (s) or 2 or more types chosen from the group which consists of transesterified oil of mixed oil containing oil and egoma oil.
臭気を有する油脂:大豆油、大豆油のエステル交換油、大豆油を含む混合油のエステル交換油、コーン油、コーン油のエステル交換油、コーン油を含む混合油のエステル交換油、パーム系油脂、パーム系油脂のエステル交換油、パーム系油脂を含む混合油のエステル交換油、フラックス油、フラックス油のエステル交換油、フラックス油を含む混合油のエステル交換油、エゴマ油、エゴマ油のエステル交換油、エゴマ油を含む混合油のエステル交換油からなる群から選ばれる1種または2種以上。In an oil and fat composition containing a fat and oil having an odor, the undeodorized roasted sesame oil having a mass ratio of 2 to 2500 ppm with respect to the amount corresponding to the oil and fat having the odor is added to the fat and oil itself having the odor. The method of suppressing the odor which this has and the flavor of the said non-deodorized roasted sesame oil simultaneously.
Odorous fats and oils: Soybean oil, transesterified oil of soybean oil, transesterified oil of mixed oil containing soybean oil, corn oil, transesterified oil of corn oil, transesterified oil of mixed oil containing corn oil, palm oil Transesterified oil of palm-based fats and oils, transesterified oils of mixed oils containing palm-based fats and oils, flux oils, transesterified oils of flux oils, transesterified oils of mixed oils containing fluxed oils, sesame oils, transesterified oils of sesame oils 1 type (s) or 2 or more types chosen from the group which consists of transesterified oil of mixed oil containing oil and egoma oil.
臭気を有する油脂:大豆油、大豆油のエステル交換油、大豆油を含む混合油のエステル交換油、コーン油、コーン油のエステル交換油、コーン油を含む混合油のエステル交換油、パーム系油脂、パーム系油脂のエステル交換油、パーム系油脂を含む混合油のエステル交換油、フラックス油、フラックス油のエステル交換油、フラックス油を含む混合油のエステル交換油、エゴマ油、エゴマ油のエステル交換油、エゴマ油を含む混合油のエステル交換油からなる群から選ばれる1種または2種以上。In the oil and fat composition containing the odorous fats and oils, the fat and oil itself having the odors by containing 25 to 50000 ppm of non-deodorized roasted rapeseed oil in a mass ratio with respect to the amount corresponding to the fats and oils having the odor. The method of suppressing the odor which this has and the flavor of the said non-deodorized roasted rapeseed oil simultaneously.
Odorous fats and oils: Soybean oil, transesterified oil of soybean oil, transesterified oil of mixed oil containing soybean oil, corn oil, transesterified oil of corn oil, transesterified oil of mixed oil containing corn oil, palm oil Transesterified oil of palm-based fats and oils, transesterified oils of mixed oils containing palm-based fats and oils, flux oils, transesterified oils of flux oils, transesterified oils of mixed oils containing fluxed oils, sesame oils, transesterified oils of sesame oils 1 type (s) or 2 or more types chosen from the group which consists of transesterified oil of mixed oil containing oil and egoma oil.
臭気を有する油脂:大豆油、大豆油のエステル交換油、大豆油を含む混合油のエステル交換油、コーン油、コーン油のエステル交換油、コーン油を含む混合油のエステル交換油、パーム系油脂、パーム系油脂のエステル交換油、パーム系油脂を含む混合油のエステル交換油、フラックス油、フラックス油のエステル交換油、フラックス油を含む混合油のエステル交換油、エゴマ油、エゴマ油のエステル交換油、エゴマ油を含む混合油のエステル交換油からなる群から選ばれる1種または2種以上。The fat and oil having the odor by containing 25 to 5000 ppm of non-deodorized roasted soybean oil in a mass ratio with respect to the amount corresponding to the fat and oil having the odor in the fat and oil composition containing the fat and oil having the odor. A method for simultaneously suppressing the odor of itself and the flavor of the non-deodorized roasted soybean oil.
Odorous fats and oils: Soybean oil, transesterified oil of soybean oil, transesterified oil of mixed oil containing soybean oil, corn oil, transesterified oil of corn oil, transesterified oil of mixed oil containing corn oil, palm oil Transesterified oil of palm-based fats and oils, transesterified oils of mixed oils containing palm-based fats and oils, flux oils, transesterified oils of flux oils, transesterified oils of mixed oils containing fluxed oils, sesame oils, transesterified oils of sesame oils 1 type (s) or 2 or more types chosen from the group which consists of transesterified oil of mixed oil containing oil and egoma oil.
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CN103153077B (en) * | 2010-12-03 | 2014-07-23 | 日清奥利友集团株式会社 | Fat composition for foaming oil-in-water emulsion and foaming oil-in-water emulsion containing same |
JP6232325B2 (en) * | 2014-03-26 | 2017-11-15 | 日清オイリオグループ株式会社 | Oil and fat composition for cooking, method for producing the same and food |
CN105795004A (en) * | 2014-12-29 | 2016-07-27 | 丰益(上海)生物技术研发中心有限公司 | Oil composition capable of improving flavor and preparation method thereof |
JP6801958B2 (en) * | 2015-12-24 | 2020-12-16 | 日清オイリオグループ株式会社 | Method for producing roasted oil and method for producing edible oil and fat composition |
JP6863796B2 (en) * | 2017-03-30 | 2021-04-21 | 日清オイリオグループ株式会社 | Stir-fry cooking oil composition |
TW201841570A (en) * | 2017-04-03 | 2018-12-01 | 日商J 制油股份有限公司 | Method for manufacturing edible fat and oil composition and method for masking unpleasant flavor of food material |
JP6845074B2 (en) * | 2017-04-28 | 2021-03-17 | 株式会社Adeka | Oil and fat composition for bakery |
JP7118070B2 (en) * | 2017-08-08 | 2022-08-15 | 株式会社J-オイルミルズ | Heated odor inhibitor for oil and fat composition for heat cooking, method for suppressing heat odor of fat and oil composition for heat cooking, and method for producing oil and fat composition for heat cooking |
JP7171577B2 (en) * | 2017-08-08 | 2022-11-15 | 株式会社J-オイルミルズ | Agent for reducing oiliness of heat-cooked food and method for reducing oiliness of heat-cooked food |
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JP7235470B2 (en) * | 2018-09-21 | 2023-03-08 | 株式会社J-オイルミルズ | Grassy odor reducing agent for soybean oil and method for reducing grassy odor of soybean oil contained in heat-cooked food |
CN110358626A (en) * | 2019-08-07 | 2019-10-22 | 广州大学 | A kind of method that sesamolin inhibits ethylene oxidic ester to generate during grease deodorization |
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