JPWO2006003981A1 - Oil-in-water emulsion and food production method using the same - Google Patents

Oil-in-water emulsion and food production method using the same Download PDF

Info

Publication number
JPWO2006003981A1
JPWO2006003981A1 JP2006528795A JP2006528795A JPWO2006003981A1 JP WO2006003981 A1 JPWO2006003981 A1 JP WO2006003981A1 JP 2006528795 A JP2006528795 A JP 2006528795A JP 2006528795 A JP2006528795 A JP 2006528795A JP WO2006003981 A1 JPWO2006003981 A1 JP WO2006003981A1
Authority
JP
Japan
Prior art keywords
oil
water emulsion
fat
water
weight
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP2006528795A
Other languages
Japanese (ja)
Inventor
長尾 恭江
恭江 長尾
江里子 原田
江里子 原田
川島 健
健 川島
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Fuji Oil Co Ltd
Original Assignee
Fuji Oil Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Fuji Oil Co Ltd filed Critical Fuji Oil Co Ltd
Publication of JPWO2006003981A1 publication Critical patent/JPWO2006003981A1/en
Pending legal-status Critical Current

Links

Classifications

    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23GCOCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
    • A23G3/00Sweetmeats; Confectionery; Marzipan; Coated or filled products
    • A23G3/34Sweetmeats, confectionery or marzipan; Processes for the preparation thereof
    • A23G3/50Sweetmeats, confectionery or marzipan; Processes for the preparation thereof characterised by shape, structure or physical form, e.g. products with supported structure
    • A23G3/52Aerated, foamed, cellular or porous products
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23DEDIBLE OILS OR FATS, e.g. MARGARINES, SHORTENINGS, COOKING OILS
    • A23D7/00Edible oil or fat compositions containing an aqueous phase, e.g. margarines
    • A23D7/005Edible oil or fat compositions containing an aqueous phase, e.g. margarines characterised by ingredients other than fatty acid triglycerides
    • A23D7/0053Compositions other than spreads
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23DEDIBLE OILS OR FATS, e.g. MARGARINES, SHORTENINGS, COOKING OILS
    • A23D7/00Edible oil or fat compositions containing an aqueous phase, e.g. margarines
    • A23D7/02Edible oil or fat compositions containing an aqueous phase, e.g. margarines characterised by the production or working-up
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23GCOCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
    • A23G1/00Cocoa; Cocoa products, e.g. chocolate; Substitutes therefor
    • A23G1/30Cocoa products, e.g. chocolate; Substitutes therefor
    • A23G1/50Cocoa products, e.g. chocolate; Substitutes therefor characterised by shape, structure or physical form, e.g. products with an inedible support
    • A23G1/52Aerated, foamed, cellular or porous products, e.g. gas expanded

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Food Science & Technology (AREA)
  • Polymers & Plastics (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Grain Derivatives (AREA)
  • Edible Oils And Fats (AREA)

Abstract

本発明は、本発明の目的は、水中油型乳化物であって、乳化剤を配合せず、且つ風味やオーバーランなどのクリームとしての基本物性を備えた水中油型乳化物を開発することを本発明の目的とし、本発明により通常の水中油型乳化物に比べて高無脂固形分量の乳化物を用いることによって、乳化剤を配合しなくてもクリームとしての基本物性を備えた水中油型乳化物が得られる。The object of the present invention is to develop an oil-in-water emulsion that does not contain an emulsifier and has basic physical properties as a cream such as flavor and overrun. For the purpose of the present invention, an oil-in-water type having basic physical properties as a cream without blending an emulsifier by using an emulsion having a high non-fat solid content compared to a normal oil-in-water emulsion according to the present invention. An emulsion is obtained.

Description

本発明は、水中油型乳化物に関し、詳しくは乳化剤を配合していないことを特徴とする水中油型乳化物に関する。   The present invention relates to an oil-in-water emulsion, and more particularly to an oil-in-water emulsion characterized by not containing an emulsifier.

アイスクリームやケーキ等のトッピングに使用されるホイップクリーム等の起泡性クリーム、あるいはコーヒー用クリーム等の水中油型乳化物は、複数の乳化剤や安定剤である無機化合物を使用するのが一般的である。例えば、ホイップクリームのひとつである植物性クリームは、水、植物性油脂、無脂乳固形分、各種の乳化剤、および安定剤である無機化合物などからなり、予備乳化、均質化、殺菌、冷却、エージングにより製造される。   For foaming creams such as whipped creams used for toppings such as ice cream and cakes, or oil-in-water emulsions such as coffee creams, it is common to use multiple inorganic compounds as emulsifiers and stabilizers. It is. For example, vegetable cream which is one of whipped creams consists of water, vegetable oils and fats, non-fat milk solids, various emulsifiers, and inorganic compounds as stabilizers, pre-emulsification, homogenization, sterilization, cooling, Manufactured by aging.

無機化合物は、リン酸(ヘキサメタリン酸、第二リン酸等)あるいはクエン酸のアルカリ金属塩などが0.1〜1重量%程度使用されるのが一般的である。また、乳化剤としては、大豆レシチン、卵黄レシチンなどのいわゆる天然乳化剤とショ糖脂肪酸エステル、グリセリン脂肪酸エステル、ソルビタン脂肪酸エステル、ポリグリセリン脂肪酸エステル、モノグリセリドなどのいわゆる合成乳化剤(以下これらの乳化剤を合成乳化剤と記す)が組み合わされて使用されており、その総使用量は概略1〜5重量%程度である。このように無機化合物や合成乳化剤の使用は、良好なクリーム物性(オーバーラン、作業性、キメなど)を得るためには不可欠と考えられている。(例えば、非特許文献1・非特許文献2参照)   As the inorganic compound, phosphoric acid (hexametaphosphoric acid, secondary phosphoric acid, etc.) or alkali metal salt of citric acid is generally used in an amount of about 0.1 to 1% by weight. As emulsifiers, so-called natural emulsifiers such as soybean lecithin and egg yolk lecithin and so-called synthetic emulsifiers such as sucrose fatty acid ester, glycerin fatty acid ester, sorbitan fatty acid ester, polyglycerin fatty acid ester and monoglyceride (hereinafter these emulsifiers are referred to as synthetic emulsifiers). The total amount used is about 1 to 5% by weight. Thus, the use of inorganic compounds and synthetic emulsifiers is considered indispensable for obtaining good cream physical properties (overrun, workability, texture, etc.). (For example, see Non-Patent Document 1 and Non-Patent Document 2)

一方で、このような乳化剤、特に合成乳化剤はクリームの風味上好ましくないものである。また、近年の消費者の『健康』意識の増加、天然志向の高まりから、このような合成乳化剤や無機化合物などの添加剤の未使用または低減させた食品の開発が望まれている。しかし水中油型乳化物に関してリン酸塩およびクエン酸塩の総含量を大幅に低減した水中油型乳化物に関して例示されているが、レシチン等は配合されている。(例えば、特許文献1参照)
日高徹著、『食品用乳化剤』(幸書房)(第127〜147頁) 日高徹著『食品添加物の常識』(幸書房)(第41〜43頁、121〜128頁) 特開平10−215783号公報(第1−4頁)
On the other hand, such an emulsifier, especially a synthetic emulsifier, is not preferable in terms of the flavor of the cream. In addition, with the recent increase in consumers' “health” awareness and increasing natural orientation, the development of foods in which such additives as synthetic emulsifiers and inorganic compounds are not used or reduced is desired. However, the oil-in-water emulsion is exemplified with respect to the oil-in-water emulsion in which the total content of phosphate and citrate is greatly reduced, but lecithin and the like are blended. (For example, see Patent Document 1)
Toru Hidaka, “Emulsifier for Food” (Shoshobo) (pp. 127-147) Toru Hidaka, “Common sense of food additives” (Yuki Shobo) (pp. 41-43, 121-128) JP 10-215783 A (page 1-4)

本発明の目的は、水中油型乳化物であって、乳化剤を配合せず、且つ風味やオーバーランなどのクリームとしての基本物性を備えた水中油型乳化物を提供する事である。   An object of the present invention is to provide an oil-in-water emulsion that does not contain an emulsifier and has basic physical properties as a cream such as flavor and overrun.

本発明者らは、上記課題を解決すべく鋭意研究した結果、通常の水中油型乳化物に比べて高無脂固形分量の乳化物を用いることによって、乳化剤を配合しなくてもクリームとしての基本物性を備えた水中油型乳化物とあることを見いだし、本発明を完成したものである。
即ち本発明は、
(1)起泡性を有するクリームで、実質的に乳化剤を配合してないことを特徴とする水中油型乳化物であり、(2)油分が10〜50重量%、水分が10〜50重量%、無脂固形分が10〜70重量%であることを特徴とする(1)記載の水中油型乳化物であり、(3)全無脂固形分に対する無脂乳固形分または無脂カカオ固形分の割合が5〜50重量%である(1)記載の水中油型乳化物であり、(4)油分中の油脂がハードバターまたはSUS(S:飽和脂肪酸、U:トランス体を含まない不飽和脂肪酸)で表されるトリグリセラリドを含むことを特徴とする(1)記載の水中油型乳化物であり、(5)(1)記載の水中油型乳化物を単独で起泡させることを特徴とする起泡済水中油型乳化物の製造法であり、(6)(1)記載の水中油型乳化物と水性組成物とを混合し、起泡させることを特徴とする起泡済水中油型乳化物の製造法であり、(7)(1)記載の水中油型乳化物と水性組成物とを混合し、乳化剤を増すことなしに起泡させることを特徴とする起泡済水中油型乳化物の製造法である。
As a result of diligent research to solve the above-mentioned problems, the present inventors have used a non-fat solid content emulsion as compared with a normal oil-in-water emulsion, thereby providing a cream as a cream without blending an emulsifier. The present invention has been completed by finding that it is an oil-in-water emulsion having basic physical properties.
That is, the present invention
(1) An oil-in-water emulsion characterized by having a foaming property and substantially not containing an emulsifier, (2) 10 to 50% by weight of oil and 10 to 50% by weight of water %, Non-fat solid content is 10 to 70% by weight, (1) oil-in-water emulsion according to (1), (3) non-fat milk solid content or non-fat cacao to total non-fat solid content The oil-in-water emulsion according to (1), wherein the solid content is 5 to 50% by weight, and (4) the fat in the oil does not contain hard butter or SUS (S: saturated fatty acid, U: trans isomer) (3) an oil-in-water emulsion according to (1), wherein the oil-in-water emulsion according to (1) is foamed alone. A method for producing a foamed oil-in-water emulsion, characterized in that the oil-in-water according to (6) (1) An oil-in-water emulsion and an aqueous composition according to (7) (1), wherein the emulsion and the aqueous composition are mixed and foamed. And foaming without increasing the emulsifier, a method for producing a foamed oil-in-water emulsion.

本発明によって、乳化剤を配合しなくても良好な水中油型乳化物を製造することが可能となり、本発明は添加剤の使用により好ましくない風味が付加されることを防止することができるという利点がある。また、従来の乳化剤使用の水中油型乳化物に、本発明品である乳化剤を配合していない水中油型乳化物を一部添加して用いる使用法に際しても、添加先に元からある乳化剤を増やすことなく乳味・コク味の付与や保形性といった特性を付与することが可能である。   According to the present invention, it becomes possible to produce a good oil-in-water emulsion without blending an emulsifier, and the present invention can prevent an unfavorable flavor from being added by using an additive. There is. In addition, when using a conventional oil-in-water emulsion using an emulsifier and adding a part of the oil-in-water emulsion that does not contain the emulsifier of the present invention, the original emulsifier is added to the addition destination. It is possible to impart properties such as imparting milky taste, richness and shape retention without increasing.

本発明において言うところの水中油型乳化物は、油分が10〜50重量%、水分が10〜50重量%、無脂固形分が10〜70重量%であり、起泡性を有するクリームで、乳化剤を配合してないことを特徴とする水中油型乳化物である
ただし、水中油型乳化物の油分が10%未満であると水中油型乳化物の起泡性が低下し、50%を超えると水中油型乳化物の乳化が不安定となり、安定的生産に支障をきたす。好ましくは15%以上、40%以下が望ましい。
The oil-in-water emulsion referred to in the present invention is a cream having a foaming property, wherein the oil content is 10 to 50% by weight, the water content is 10 to 50% by weight, and the non-fat solid content is 10 to 70% by weight. It is an oil-in-water emulsion characterized by not containing an emulsifier. However, if the oil content of the oil-in-water emulsion is less than 10%, the foamability of the oil-in-water emulsion decreases, and 50% If it exceeds, the emulsification of the oil-in-water emulsion becomes unstable, which hinders stable production. Preferably it is 15% or more and 40% or less.

本発明の水中油型乳化物の油脂については特に制限はないが、さらに起泡する機能を強く付与するためには、油分中の油脂がハードバター、特にSUS(S:飽和脂肪酸、U:トランス体を含まない不飽和脂肪酸)で表されるトリグリセラリドを含んでいるのが好ましい。上記SUS(最適にはSOS;Oはオレイン酸)の好適な含有量は、その量がふえるにつれ、口融けの良さと耐熱保形性、解乳化性へ付与される機能も向上するため、好ましくは油分中45%以上、さらに好ましくは70%以上含有していることが望ましい。
上記SUSで表されるトリグリセリドを多く含む油脂としては、カカオバター、シア脂、マンゴー核油、サル脂、イリッペ脂、パーム油及びこれらの分別油等が挙げられ、これらの中から選ばれた1種又は2種以上を使用することができる。また、グリセリドの1、3位を選択的なエステル交換を行い必要な場合には中融点画分を分取することによってSUSで表されるトリグリセリドを多く含む油脂を製造し用いることもできる。
The oil and fat of the oil-in-water emulsion of the present invention is not particularly limited. However, in order to strongly impart the foaming function, the fat in the oil is hard butter, particularly SUS (S: saturated fatty acid, U: trans It is preferable that it contains triglyceride represented by (unsaturated fatty acid not containing body). The preferred content of the above SUS (optimally SOS; O is oleic acid) is preferable because it improves the meltability, heat-resistant shape retention, and the function imparted to demulsification as the amount increases. Is preferably 45% or more, more preferably 70% or more in the oil.
Examples of fats and oils rich in triglycerides represented by SUS include cacao butter, shea fat, mango kernel oil, monkey fat, iripe fat, palm oil, and fractionated oils thereof. Species or two or more can be used. In addition, fats and oils containing a large amount of triglyceride represented by SUS can also be produced and used by selectively transesterifying the 1,3-positions of glycerides and, if necessary, fractionating the middle melting point fraction.

本発明の水中油型乳化物の水分が10%未満であると水中油型乳化物が増粘して、安定的生産に支障をきたす。50%を超えると、水中油型乳化物の乳化が不安定になり安定的生産に支障をきたす。また、ホイップした後の作業性、耐熱保形性、離水耐性が弱くなる。10〜50%の範囲において最適に用いることができる。
水中油型乳化物に含有される水分の由来は特に規定はなく、乳固形分を含む乳製品由来の水分であってもよいし、乳固形分を水に溶解もしくは分散させた場合には溶媒もしくは分散媒の水分でも良い。このほか果汁、ジャム、各種フルーツ類、餡類、チーズ類、ナッツ類、天然蜂蜜、コーヒー、紅茶などの含水食品を一種または二種以上を併用して使用する事もできる。
When the water content of the oil-in-water emulsion of the present invention is less than 10%, the oil-in-water emulsion thickens and hinders stable production. If it exceeds 50%, the emulsification of the oil-in-water emulsion becomes unstable, which hinders stable production. In addition, workability after whipping, heat-resistant shape retention, and water separation resistance are weakened. It can be optimally used in the range of 10 to 50%.
The origin of moisture contained in the oil-in-water emulsion is not particularly specified, and may be moisture derived from dairy products containing milk solids, or a solvent when milk solids are dissolved or dispersed in water. Or the water | moisture content of a dispersion medium may be sufficient. In addition, water-containing foods such as fruit juice, jam, various fruits, potatoes, cheeses, nuts, natural honey, coffee and tea can be used alone or in combination of two or more.

また、水中油型乳化物の無脂固形分が10%以下であると、起泡性クリームへの乳味、コク味付与効果を発揮しがたく、70重量%以上であると水中油型乳化物の粘度が上がり、安定的生産に支障をきたす。最適には水中油型乳化物の無脂固形分が20〜60%の範囲で用いることができる。
上記無脂固形分としては、無脂乳固形分、無脂カカオ固形分、糖類が挙げられる。無脂乳固形分は起泡性クリームへの乳味感、コク味を付与し、無脂カカオ固形分はチョコレート風味やコク味を付与する。
上記無脂乳固形分や無脂カカオ固形分の含有量は、全無脂固形分中、5〜50重量%を占めるのがよい。
上記無脂乳固形分としては、生クリーム、牛乳、濃縮乳、脱脂乳、加糖練乳、無糖練乳、全脂粉乳、脱脂粉乳、バターミルク、バターミルクパウダー、ホエー、ホエーパウダー、カゼイン、カゼインナトリウム、ラクトアルブミン等に含まれる乳由来の無脂固形分が例示でき、単独又は2種以上を組み合わせて用いることもできる。
上記無脂カカオ固形分とは、カカオ豆由来の固形分のうちココアバターを除いた部分であり、無脂カカオ分源としては、カカオマス、ココアパウダー及びこれらを原料とする各種チョコレート、並びにその他の加工品が例示できる。
Moreover, when the non-fat solid content of the oil-in-water emulsion is 10% or less, it is difficult to exert the effect of imparting the milky taste and richness to the foaming cream, and when it is 70% by weight or more, the oil-in-water emulsion is used. Increases the viscosity of the product and hinders stable production. Optimally, the non-fat solid content of the oil-in-water emulsion can be used in the range of 20 to 60%.
Examples of the non-fat solids include non-fat milk solids, non-fat cocoa solids, and saccharides. The non-fat milk solid content imparts a milky taste and richness to the foaming cream, and the non-fat cocoa solid content imparts a chocolate flavor and richness.
The content of the non-fat milk solids and the non-fat cocoa solids should occupy 5 to 50% by weight in the total non-fat solids.
The non-fat milk solid content includes fresh cream, milk, concentrated milk, skim milk, sweetened condensed milk, sugar-free condensed milk, whole milk powder, skim milk powder, butter milk, butter milk powder, whey, whey powder, casein, casein sodium Non-fat solids derived from milk contained in lactalbumin and the like can be exemplified, and can be used alone or in combination of two or more.
The non-fat cocoa solid content is a portion excluding cocoa butter from the solid content derived from cocoa beans, and as the non-fat cocoa content source, cacao mass, cocoa powder and various chocolates made from these, and other A processed product can be exemplified.

上記糖類としては特に限定されないが、例えばブドウ糖、果糖、ショ糖、麦芽糖、酵素糖化水飴、乳糖、還元澱粉糖化物、異性化液糖、ショ糖結合水飴、オリゴ糖、還元糖ポリデキストロース、ソルビトール、還元乳糖、トレハロース、キシロース、キシリトール、マルチトール、エリスリトール、マンニトール、フラクトオリゴ糖、大豆オリゴ糖、ガラクトオリゴ糖、乳果オリゴ糖、ラフィノース、ラクチュロース、パラチノースオリゴ糖、ステビア、アスパルテーム、糖アルコール等の糖類が挙げられる。これらの糖類は、単独で用いることもでき、又は2種以上を組み合わせて用いることもできる。   The saccharide is not particularly limited, for example, glucose, fructose, sucrose, maltose, enzyme saccharified starch syrup, lactose, reduced starch saccharified product, isomerized liquid sugar, sucrose-bound starch syrup, oligosaccharide, reducing sugar polydextrose, sorbitol, Listed sugars such as reduced lactose, trehalose, xylose, xylitol, maltitol, erythritol, mannitol, fructooligosaccharide, soybean oligosaccharide, galactooligosaccharide, dairy oligosaccharide, raffinose, lactulose, palatinose oligosaccharide, stevia, aspartame, sugar alcohol It is done. These saccharides can be used alone or in combination of two or more.

以上に示された、水中油型乳化物の油分、水分、無脂固形分の配合量の関係は、公知の起泡性クリームに比べて低水分・高無脂固形分であり、練乳に比べて高油分であるが、その調製法の主なものを次に例示する。
すなわち本発明の水中油型乳化物の調製法の第一は、上記無脂固形分と上記油脂の一部または全部から一旦チョコレートの製造法に準じた製法によりチョコレート乃至チョコレート様食品の粉末またはそれらの溶融した生地を得、次いで上記無脂固形分や油脂を含んでもよい水性組成物を加えて乳化する方法が挙げられる。チョコレート様食品の製造に際しては通常のチョコレートの製造法を大きく逸脱しない限り特に制限はなく、ロールにより微細化の後、コンチングを行うことができる。
The relationship between the oil content, water content, and non-fat solid content of the oil-in-water emulsion shown above is a low water content and high non-fat solid content compared to known foaming creams, compared to condensed milk The main preparation method is as follows.
That is, the first method for preparing the oil-in-water emulsion of the present invention is to prepare a powder of chocolate or chocolate-like food from the above-mentioned non-fat solid and part or all of the above-mentioned fats by a production method according to the production method of chocolate. And then emulsifying by adding an aqueous composition which may contain the above fat-free solids and fats and oils. There is no restriction | limiting in particular in the case of manufacture of a chocolate-like food, unless it deviates significantly from the normal chocolate manufacturing method, and conching can be performed after refinement | miniaturizing with a roll.

あるいは別の調製方法として、上記無脂固形分と上記油脂それぞれを、水性組成物とを混合した後、30〜70℃に加温する、あるいはどちらか一方または両方を30〜70℃に加温しておいてから混合し、手で攪拌するような緩やかな攪拌方式、あるいは強力な剪断力を加えることのできる高速攪拌方式、例えばホモミキサー等のいずれの方式でも製造することができる。乳化は場合によっては均質化(5〜150kg/cm2)処理を行ってもよい。   Or as another preparation method, after mixing the said non-fat solid and said each fat and oil with an aqueous composition, it heats to 30-70 degreeC, or heats either or both to 30-70 degreeC Then, it can be produced by any method such as a gentle stirring method in which the mixture is mixed and then stirred by hand, or a high-speed stirring method to which a strong shearing force can be applied, for example, a homomixer. The emulsification may be homogenized (5 to 150 kg / cm <2>) depending on circumstances.

上記乳化処理した水中油型乳化物は冷却して製造される。乳化工程あるいは均質化処理の前後で殺菌または滅菌してもよいが、従来のUHT処理を行うクリーム製造ラインでは製造可能な粘度幅が狭く、粘度が上がる要因となりうるので、低温殺菌が推奨される。
また、解乳化しやすくボテ現象の起こりやすいSUS型トリグリセリドを配合しても上記の工程に準じて製造するときは、調製が可能である。
The emulsified oil-in-water emulsion is produced by cooling. Sterilization or sterilization may be performed before or after the emulsification process or homogenization treatment, but pasteurization is recommended because the viscosity range that can be produced is narrow in the cream production line that performs the conventional UHT treatment and may increase the viscosity. .
Moreover, even if SUS type triglyceride which is easy to demulsify and easily causes a bloating phenomenon, it can be prepared when manufactured according to the above process.

次に、本発明の水中油型乳化物添加する対象である水性組成物について説明する。
上記のようにして得られた高無脂固形分乳化物は、水性組成物添加用、とりわけ起泡性油脂組成物(起泡性クリーム)改質用として好適に使用でき、起泡済油脂組成物を製造することができる。
Next, the aqueous composition to which the oil-in-water emulsion of the present invention is added will be described.
The highly fat-free solid emulsion obtained as described above can be suitably used for adding an aqueous composition, particularly for modifying a foamable oil composition (foaming cream). Can be manufactured.

本発明でいうところの水性組成物は生クリームや植物性クリームの各種市販製品といった起泡性油脂組成物にかぎらず、牛乳や濃縮乳、チーズ類といった起泡力をもたない乳製品、さらには豆乳などのようなO/W型乳化物、さらには乳化物ですらないジャム、各種フルーツ類、餡類、天然蜂蜜、コーヒー、紅茶などの含水食品そして水を一種または二種以上を併用して使用する事もでき、特に限定はされず、その製造法は周知慣用の技術や、公知の技術を採用できる。
本来起泡力をもたない乳製品やO/W型乳化物、さらには含水食品そして水などは、水中油型乳化物を混合のみの状態ではコク味を付与することが出来、攪拌により起泡させることも可能である。
コク味や乳味に乏しい起泡性油脂組成物に加える場合はコク味や乳味が向上し、口融けは良いが耐熱保形性、離水耐性が弱い、あるいはその逆の物性の起泡性油脂組成物に加えると、その長所を損なうことなく、短所の機能を補うことができる。
The aqueous composition referred to in the present invention is not limited to a foaming oil / fat composition such as various commercially available products of fresh cream or vegetable cream, but also a milk product having no foaming power such as milk, concentrated milk, cheeses, O / W type emulsions such as soy milk, and also non-emulsified jams, various fruits, potatoes, natural honey, water-containing foods such as coffee and tea, and water. The production method is not particularly limited, and a well-known and commonly used technique or a well-known technique can be adopted as the production method.
Dairy products and O / W emulsions that do not naturally have foaming power, as well as water-containing foods and water, can give a rich taste when only mixed with oil-in-water emulsions. It is also possible to make it foam.
When added to a foaming fat or oil composition with poor body taste or milky taste, the body taste and milky taste are improved and the meltability is good, but the heat-resistant shape retention and water separation resistance are weak, or vice versa. When added to the oil and fat composition, the function of the disadvantage can be compensated without losing the advantage.

ただし、上記、水中油型乳化物中の油脂についての部分でも記載したが、口融けの良さと耐熱保形性、離水耐性をより強く付与するためには、油分中の油脂がハードバターであることが、さらに、起泡する機能をより強く付与するためには、油分中の油脂がSUSで表されるトリグリセリドを含んでいるのがより好ましい。
本発明の水中油型乳化物の、起泡済クリーム中の含有量は、5重量%以上、さらに好ましくは10〜50重量%が適当であり、含有量が少ないと起泡性クリームを改質する効果に乏しい。
起泡性クリームに水中油型乳化物を添加するタイミングはホイップの前、途中、のいずれでもよいがホイップ後であるよりは、ホイップ前や途中に加える方がよい。
また、水中油型乳化物は単独でも起泡が可能である。
However, the oil and fat in the oil-in-water emulsion described above is also described in the part, but in order to impart better meltability, heat-resistant shape retention and water separation resistance, the fat in the oil is hard butter Furthermore, in order to give the foaming function more strongly, it is more preferable that the fat in the oil contains a triglyceride represented by SUS.
The content of the oil-in-water emulsion of the present invention in the foamed cream is suitably 5% by weight or more, more preferably 10 to 50% by weight. When the content is low, the foamable cream is modified. The effect to do is poor.
The timing for adding the oil-in-water emulsion to the foaming cream may be before or during whipping, but it is better to add it before or during whipping than after whipping.
In addition, the oil-in-water emulsion can be foamed alone.

以下に本発明の実施例を示し、本発明をさらに詳しく説明するが、本発明はこれらの実施例に限定されるものではない。なお、例中、%及び部は重量基準を意味する。   EXAMPLES Examples of the present invention will be shown below and the present invention will be described in more detail. However, the present invention is not limited to these examples. In the examples,% and part mean weight basis.

<実施例1>
全脂粉乳 16.0部、砂糖 39.0部、植物性油脂としてはSUSを多く含むタイプであるテンパータイプハードバター(製品名「メラノNEWSS−7」不二製油株式会社製、SUS含量約81%) 45.0部を配合、チョコレート製造の定法に従いチョコレート様食品を製造した。
次いで30℃に加温した水 24.0部に、上記操作にて得られたチョコレート様食品を粉砕したもの 70.0部と上記テンパータイプハードバター 4.0部、砂糖 2.0部を加え混合した。
この混合物を、加温しながらホモミキサー(「T.K.ホモディスパー」特殊機化工業株式会社製)3000rpmにて攪拌を行い、65℃30分保持後、冷却して油分38.4重量%、無脂固形分37.6重量%(無脂乳固形は8.3%)、水分24.0重量%の水中油型乳化物を得た。
このようにして得た水中油型乳化物と、水を70部:30部の割合で混合し、縦型ミキサー(「ホバートミキサーN−50」 ホバートジャパン株式会社製)を使用して起泡させたもの(以降、水中油型乳化起泡物と称する)の作業性・品質の評価を行った。
<Example 1>
Whole milk powder 16.0 parts, sugar 39.0 parts, temper type hard butter which is a type containing a lot of SUS as vegetable oils and fats (product name “Melano NEWSS-7” manufactured by Fuji Oil Co., Ltd., SUS content about 81 %) 45.0 parts were blended, and a chocolate-like food was produced according to a conventional method for producing chocolate.
Next, 20.0 parts of water heated to 30 ° C., 70.0 parts of the crushed chocolate-like food obtained by the above operation, 4.0 parts of the above temper type hard butter, and 2.0 parts of sugar are added. Mixed.
The mixture was stirred at 3000 rpm while heating at 3000 rpm with a homomixer (“TK Homo Disper” manufactured by Tokushu Kika Kogyo Co., Ltd.), held at 65 ° C. for 30 minutes, and then cooled to an oil content of 38.4% by weight. An oil-in-water emulsion having a non-fat solid content of 37.6% by weight (a non-fat milk solid was 8.3%) and a water content of 24.0% by weight was obtained.
The oil-in-water emulsion thus obtained and water were mixed in a ratio of 70 parts: 30 parts, and foamed using a vertical mixer ("Hobart Mixer N-50" manufactured by Hobart Japan Co., Ltd.). Evaluation of the workability and quality of the rice (hereinafter referred to as oil-in-water emulsified foam) was performed.

<比較例1>
実施例1と同様の配合・製法にてチョコレート様食品を得、次いで30℃に加温した水 24.0部に、上記操作にて得られたチョコレート様食品を粉砕したもの 45.0部と上記テンパータイプハードバター 31.0部を加え混合した。
この混合物を実施例1と同様の製法にて、油分53.2重量%、無脂固形分22.8重量%(無脂乳固形は5.3%)、水分24.0重量%の水中油型乳化物を得た。また、このようにして得た水中油型乳化物と、表1の配合に従い実施例1と同様の配合・製法にて起泡させたものの作業性・品質の評価を行った。
<Comparative Example 1>
A chocolate-like food was obtained by the same composition and production method as in Example 1, and then the chocolate-like food obtained by the above operation was pulverized in 24.0 parts of water heated to 30 ° C. 45.0 parts 31.0 parts of the above temper type hard butter was added and mixed.
This mixture was produced in the same manner as in Example 1 except that the oil content was 53.2% by weight, the non-fat solid content was 22.8% (the non-fat milk solid was 5.3%), and the water content was 24.0% by weight. A mold emulsion was obtained. In addition, the oil-in-water emulsion thus obtained and foamed by the same blending and production method as in Example 1 according to the blending in Table 1 were evaluated for workability and quality.

<比較例2>
表1の配合に従い、実施例1の配合に大豆レシチン 0.5部を配合した以外はすべて同様の配合・製法にてチョコレート様食品を得、次いで表1の配合に従い、比較例1の配合にショ糖脂肪酸エステル(「リョートーシュガーエステル S1670」 三菱化学フーズ株式会社製 HLB16)を配合した以外はすべて同様の配合・製法にて加え混合した。
この混合物を、表1の配合に従い実施例1と同様の製法にて、油分53.2重量%、無脂固形分22.8重量%(無脂乳固形は5.3%)、水分24.0重量%の水中油型乳化物を得た。また、このようにして得た水中油型乳化物と、表1の配合に従い実施例1と同様の配合・製法にて起泡させたものの作業性・品質の評価を行った。
<Comparative example 2>
According to the formulation of Table 1, chocolate-like foods were obtained by the same formulation and manufacturing method except that 0.5 part of soybean lecithin was added to the formulation of Example 1, and then the formulation of Comparative Example 1 was made according to the formulation of Table 1. Except for blending sucrose fatty acid ester ("Ryoto Sugar Ester S1670", HLB16 manufactured by Mitsubishi Chemical Foods Co., Ltd.), all were added and mixed in the same composition and production method.
This mixture was prepared in the same manner as in Example 1 according to the formulation shown in Table 1, with an oil content of 53.2% by weight, a non-fat solid content of 22.8% by weight (non-fat milk solid was 5.3%), and a moisture content of 24. A 0 wt% oil-in-water emulsion was obtained. In addition, the oil-in-water emulsion thus obtained and foamed by the same blending and production method as in Example 1 according to the blending in Table 1 were evaluated for workability and quality.

<実施例2>
実施例1で得られた水中油型乳化物と、市販起泡性クリーム(製品名「ライトトッピングSV」、不二製油株式会社製)を20部:80部の割合で混合し、縦型ミキサーを使用して起泡させた。
評価は表1に配合と共に示した。

[表1]

Figure 2006003981
※ 評価基準
○:乳化が安定でホイップ等の作業が良好に出来、食感も軽くてみずみずしく、口溶けが良い。
△:乳化がやや不安定で、やや堅いもののホイップ等の作業が可能、食感もややボテ感があるものの商品価値はあるレベル。
×:乳化が不安定で作業不能、商品価値を損なう悪食感。
−:作製不能。<Example 2>
The oil-in-water emulsion obtained in Example 1 and a commercially available foaming cream (product name “Light Topping SV”, manufactured by Fuji Oil Co., Ltd.) are mixed in a ratio of 20 parts: 80 parts, and a vertical mixer Was used to foam.
The evaluation is shown in Table 1 together with the formulation.

[Table 1]
Figure 2006003981
* Evaluation criteria ○: Emulsification is stable, whipping work can be performed well, the texture is light and fresh, and the mouth melts well.
Δ: Emulsification is slightly unstable, work of whipping etc. of somewhat hard is possible, and the texture is a little sticky, but the product value is at a certain level.
X: Eating emulsification, work impossibility, bad eating feeling that impairs commercial value.
−: Incapable of production.

その結果、実施例1は非常に軽くてみずみずしい、口溶けの良い泡状の食品となり、従来の起泡性クリームを起泡させた場合よりも食感、口溶けともに異なる新しい水中油型乳化起泡物であった。
しかし、比較例1の水中油型乳化物は非常に硬く乳化も不安定であった(油中水型への転相)。また、ホイップしようとしても、そのままでは硬すぎるし、水性成分と混合しようとしてもダマになりうまく起泡させることができなかった。
As a result, Example 1 is a very light and fresh, foamy food with good mouth melting, and a new oil-in-water emulsified foam with different texture and mouth melting than when foaming a conventional foaming cream. Met.
However, the oil-in-water emulsion of Comparative Example 1 was very hard and unstable in emulsification (phase inversion to water-in-oil type). Moreover, even if it tried to whip, it was too hard as it was, and even if it tried to mix with an aqueous component, it became lumpy and could not be made to foam well.

また、比較例1に乳化剤加えた比較例2の水中油型乳化物は、比較例1のものとは違い、乳化は安定であったし、乳化剤を添加して水と混合して水中油型乳化物を作成したのち起泡させたものは、うまく起泡させる事が可能であり、食感も従来の水中油型乳化物として存在するクリーム的なものであった。
すなわち、本願の請求範囲である、油脂や水分・全無脂固形分の範囲を逸脱した比較例1は乳化剤を用いないと乳化できないものであった。
なお市販起泡性クリームには実施例2で用いたような機能重視タイプ、すなわち乳味・コク味はやや劣るものの作業性が良いものがあり、乳味・コク味と作業性といった機能は両立しにくいことは一般に良く知られているが、そういった市販起泡性クリームに実施例1で得られた水中油型乳化物を一部添加することで乳味、コク味を付与と保形性の向上が平易な方法で可能である。
しかも水中油型乳化物自体には乳化剤の添加されていないため、もとの市販起泡性クリームに添加されている乳化剤にあらたに乳化剤を上乗せすることもなく、トータルとして乳化剤の総量を減らし尚且つ、乳味・コク味といったものの付与が可能である事があきらかになった。
Also, the oil-in-water emulsion of Comparative Example 2 in which an emulsifier was added to Comparative Example 1 was different from that of Comparative Example 1, and the emulsification was stable. The foamed foam after the preparation of the emulsion can be foamed well, and the texture is a cream that exists as a conventional oil-in-water emulsion.
That is, Comparative Example 1 which deviates from the range of oils and fats, moisture and total non-fat solids, which is the claimed scope of the present application, cannot be emulsified unless an emulsifier is used.
In addition, some of the commercially available foaming creams have a function-oriented type as used in Example 2, that is, the milk taste and richness are slightly inferior, but the workability is good, and the functions such as milk taste, rich taste and workability are compatible. Although it is generally well-known that it is difficult to do, the addition of a part of the oil-in-water emulsion obtained in Example 1 to such a commercially available foaming cream imparts milky taste and richness and retains shape retention. Improvement is possible in a simple way.
Moreover, since the oil-in-water emulsion itself does not contain an emulsifier, the total amount of the emulsifier is reduced without adding an emulsifier to the emulsifier added to the original commercial foaming cream. It became clear that it was possible to add milky taste and richness.

<実施例3>
実施例1で得た水中油型乳化物と、イチゴピューレ(タカ食品)を60部:40部の割合で混合し、縦型ミキサーを使用して起泡させた。
その結果、苺の風味の強い、みずみずしい泡状の食品となった。なお、用いた苺ピューレは単独では起泡力をほとんど持たなかった。
これにより、それ自身に起泡力を持たないイチゴピューレのようなものに添加することで、特段乳化剤を加えなくとも起泡力が付与される事があきらかになった。
<Example 3>
The oil-in-water emulsion obtained in Example 1 and strawberry puree (hawk food) were mixed at a ratio of 60 parts: 40 parts, and foamed using a vertical mixer.
As a result, it became a fresh, foamy food with a strong strawberry flavor. The cocoon puree used alone had little foaming power.
As a result, it became clear that the foaming power could be imparted without adding a special emulsifier by adding it to a strawberry puree having no foaming power.

<実施例4>
油脂、無脂固形分からチョコレート様食品を製造する過程を経ずに、水中油型乳化物を得る例を示す。
30℃に加温した水 20.0部に全脂粉乳 15.0部、砂糖 25.0部を混合し、そこに植物性油脂としてSUSを多く含むタイプであるテンパータイプハードバター(製品名「メラノNEWSS−7」不二製油株式会社製、SUS含量約81%) 40.0部を混合する。
上記混合物を、加温しながらホモミキサーで3000rpmにて攪拌を行い、65℃30分保持後、冷却して油分43.9重量%、無脂固形分36.1重量%(無脂乳固形11.1%)、水分20.0重量%の水中油型乳化物を得た。このようにして得た水中油型乳化物と、水を70部:30部の割合で混合し、縦型ミキサーを使用して水中油型乳化起泡物の作業性・品質の評価を行った。
<Example 4>
An example of obtaining an oil-in-water emulsion without going through the process of producing a chocolate-like food from fats and fats and non-fat solids is shown.
Temper type hard butter (product name “Product name”) is mixed with 20.0 parts of water heated to 30 ° C. and mixed with 15.0 parts of whole milk powder and 25.0 parts of sugar. 40.0 parts of Melano NEWSS-7 ”manufactured by Fuji Oil Co., Ltd., SUS content of about 81%) are mixed.
The mixture was stirred at 3000 rpm with a homomixer while warming, held at 65 ° C. for 30 minutes, and then cooled to 43.9% oil content, 36.1% non-fat solid content (non-fat milk solid 11 0.1%) and an oil-in-water emulsion having a water content of 20.0% by weight was obtained. The oil-in-water emulsion thus obtained was mixed with water at a ratio of 70 parts: 30 parts, and the workability and quality of the oil-in-water emulsion foam were evaluated using a vertical mixer. .

<実施例5>
表2の配合に従い、実施例4の配合のうち植物性油脂としてSUSを比較的多く含むが融点が実施例4で使用したものよりやや低いタイプであるパーム油中融点部の分別品(製品名「ユニレートP110N」不二製油株式会社製、SUS含量約55%)を用いる以外は全て同様の配合・製法にて水中油型乳化物を得、またこのようにして得た水中油型乳化物を、実施例4と同様の配合・製法で水中油型乳化起泡物の作業性・品質の評価を行った。
<Example 5>
According to the formulation in Table 2, a fractionated product of the middle melting point of palm oil that contains a relatively large amount of SUS as a vegetable oil in the formulation of Example 4 but has a slightly lower melting point than that used in Example 4 (product name) An oil-in-water emulsion was obtained by the same blending and production method except that “Unilate P110N” manufactured by Fuji Oil Co., Ltd., SUS content of about 55%), and the oil-in-water emulsion thus obtained was obtained. The workability and quality of the oil-in-water emulsified foam were evaluated by the same formulation and production method as in Example 4.

<実施例6>
表2の配合に従い、実施例4の配合のうち植物性油脂として、パーム油中融点部を部分硬化しSUSのUの部分の一部をトランス体や飽和脂肪酸に置換したもの(製品名「メルバ31」不二製油株式会社製)を用いる以外は全て同様の配合・製法にて水中油型乳化物を得、またこのようにして得た水中油型乳化物を、実施例4と同様の配合・製法で水中油型乳化起泡物の作業性・品質の評価を行った。
評価は表2に配合と共に示した。
<Example 6>
According to the composition of Table 2, among the blends of Example 4, as the vegetable oil, the palm oil melting point part was partially cured and part of the U part of SUS was replaced with trans isomer or saturated fatty acid (product name “Melva 31 ”(Fuji Oil Co., Ltd.) was used, and an oil-in-water emulsion was obtained by the same blending and production method. The oil-in-water emulsion thus obtained was blended in the same manner as in Example 4. -The workability and quality of the oil-in-water emulsified foam were evaluated by the production method.
The evaluation is shown in Table 2 together with the formulation.

<比較例3>
表2の配合に従い、実施例4の配合のうち植物性油脂として融点が低くSUSを殆ど含まない大豆白絞油を用いる以外は全て同様の配合・製法にて水中油型乳化物を得、またこのようにして得た水中油型乳化物を、実施例4と同様の配合・製法で水中油型乳化起泡物の作業性・品質の評価を行った。
<Comparative Example 3>
According to the formulation of Table 2, an oil-in-water emulsion was obtained by the same formulation and production method except that soybean white squeezed oil having a low melting point and almost no SUS was used as the vegetable oil in the formulation of Example 4, The oil-in-water emulsion thus obtained was evaluated for workability and quality of the oil-in-water emulsion by the same formulation and production method as in Example 4.

[表2]

Figure 2006003981
※ 作業性・食感の評価は実施例と同じ。[Table 2]
Figure 2006003981
* Evaluation of workability and texture is the same as in the examples.

その結果、SUSを多く含む植物性油脂を使用した実施例4、SUSを比較的多く含むが融点は実施例4で使用したものよりやや低い植物性油脂を使用した実施例5はでは、非常に軽くてみずみずしい、口溶けの良い泡状の食品となり、従来の起泡性クリームを起泡させた場合よりも食感、口溶けともに異なる新しい起泡物であった。また硬化によってSUS含有量が実施例5に比べ減少した実施例6も、実施例4に比べると水中油型乳化起泡物の離水が早い点が見られるが十分に商品価値があり、非常に軽くてみずみずしい、口溶けの良い起泡物が得られた。   As a result, Example 4 using vegetable oils and fats containing a lot of SUS, Example 5 using vegetable oils and fats containing a relatively large amount of SUS but having a slightly lower melting point than that used in Example 4, It became a light, fresh and foamy food with good meltability in the mouth, and it was a new foamed product with different texture and meltability than when foaming a conventional foaming cream. In addition, Example 6 in which the SUS content was reduced by curing as compared with Example 5 was also sufficiently commercialized, although it was found that the oil-in-water emulsified foam was earlier in water removal than Example 4, and it was very commercial value. A light and fresh foam with a good melt in the mouth was obtained.

しかし比較例3は乳化が不安定で、冷却中に分離しやすかった。また、長時間ホイップしても、保形性のあるものにはならず起泡しなかった。
これにより油脂、無脂固形分からチョコレート様食品を製造する過程を経ずに、水中油型乳化物を得る事が可能であり、また油脂としてはハードバターまたはSUSで表されるトリグリセラリドを含むのが望ましいという事があきらかになった。
However, in Comparative Example 3, the emulsification was unstable and it was easy to separate during cooling. Further, even when whipped for a long time, it did not foam and did not foam.
Thus, it is possible to obtain an oil-in-water emulsion without going through the process of producing a chocolate-like food from fats and fats and non-fat solids, and the fats and oils contain triglycerides represented by hard butter or SUS. It became clear that it was desirable.

<実施例7>
油分や水分、無脂固形分の異なる水中油型乳化物の本願発明における適正を見る。
30℃に加温した水 24.0部に全脂粉乳 11.2部、砂糖 29.3部を混合し、そこに植物性油脂としてテンパータイプハードバター(製品名「メラノNEWSS−7」不二製油株式会社製) 35.5部を混合する。
<Example 7>
The suitability in the present invention of an oil-in-water emulsion having different oil content, moisture, and non-fat solid content is observed.
24.0 parts of water heated to 30 ° C. 11.2 parts of whole milk powder and 29.3 parts of sugar are mixed, and temper type hard butter (product name “Melano NEWSS-7” Fuji) is added as vegetable oil. 35.5 parts is mixed.

上記混合物を、加温しながらホモミキサー3000rpmにて攪拌を行い、65℃30分保持後、冷却して油分38.4重量%、無脂固形分37.6重量%(無脂乳固形8.3%)、水分24.0重量%の水中油型乳化物を得た。このようにして得た水中油型乳化物を、単独で縦型ミキサーを使用して起泡させ、作業性・品質の評価を行った。   The mixture was stirred at 3000 rpm with a homomixer while warming, held at 65 ° C. for 30 minutes, then cooled and oiled 38.4% by weight, non-fat solids 37.6% by weight (non-fat milk solids 8. 3%) and an oil-in-water emulsion having a water content of 24.0% by weight was obtained. The oil-in-water emulsion thus obtained was foamed using a vertical mixer alone to evaluate workability and quality.

<実施例8>
表3の配合に従い、30℃に加温した水 40.0部に全脂粉乳 11.0部、砂糖 19.0部を混合し、そこに植物性油脂としてテンパータイプハードバター(製品名「メラノNEWSS−7」不二製油株式会社製) 30.0部を混合する。
<Example 8>
According to the composition in Table 3, 40.0 parts of water heated to 30 ° C. was mixed with 11.0 parts of whole milk powder and 19.0 parts of sugar, and then temper type hard butter (product name “Melano” NEWS-7 "(Fuji Oil Co., Ltd.) 30.0 parts are mixed.

上記混合物を、加温しながらホモミキサー3000rpmにて攪拌を行い、65℃30分保持後、冷却して油分32.9重量%、無脂固形分27.1重量%(無脂乳固形8.1%)、水分40.0重量%の水中油型乳化物を得た。このようにして得た水中油型乳化物を、単独で縦型ミキサーを使用して起泡させ、作業性・品質の評価を行った。   The mixture was stirred at 3000 rpm with a homomixer while warming, held at 65 ° C. for 30 minutes, then cooled and oiled 32.9% by weight, non-fat solids 27.1% by weight (non-fat milk solids 8. 1%) and an oil-in-water emulsion having a water content of 40.0% by weight was obtained. The oil-in-water emulsion thus obtained was foamed using a vertical mixer alone to evaluate workability and quality.

<比較例4>
表3の配合に従い、30℃に加温した水 20.0部に脱脂粉乳 30.0部、砂糖 45.0を混合し、そこに植物性油脂としてテンパータイプハードバター(製品名「メラノNEWSS−7」不二製油株式会社製) 5.0部を混合する。
上記混合物を、加温しながらホモミキサー3000rpmにて攪拌を行い、65℃30分保持後、冷却して油分5.0重量%、無脂固形分75.0重量%(無脂乳固形30.0%)、水分20.0重量%の水中油型乳化物を得た。このようにして得た水中油型乳化物を、単独で縦型ミキサーを使用して起泡させ、作業性・品質の評価を行った。
<Comparative example 4>
According to the composition of Table 3, 20.0 parts of water heated to 30 ° C. was mixed with 30.0 parts of skim milk powder and 45.0 of sugar, and temper type hard butter (product name “Melano NEWSS- 7 "Fuji Oil Co., Ltd.) 5.0 parts are mixed.
The above mixture was stirred at 3000 rpm with a homomixer while heating, held at 65 ° C. for 30 minutes, and then cooled to 5.0% by weight of oil and 75.0% by weight of non-fat solids (30. 0%) and an oil-in-water emulsion having a water content of 20.0% by weight was obtained. The oil-in-water emulsion thus obtained was foamed using a vertical mixer alone to evaluate workability and quality.

<比較例5>
表3の配合に従い、30℃に加温した水 55.0部に全脂粉乳 8.3部、砂糖 14.3を混合し、そこに植物性油脂としてテンパータイプハードバター(製品名「メラノNEWSS−7」不二製油株式会社製) 22.5部を混合する。
上記混合物を、加温しながらホモミキサー3000rpmにて攪拌を行い、65℃30分保持後、冷却して油分24.6重量%、無脂固形分20.4重量%(無脂乳固形6.1%)、水分55.0重量%の水中油型乳化物を得た。このようにして得た水中油型乳化物を、単独で縦型ミキサーを使用して起泡させ、作業性・品質の評価を行った。
評価は表2に配合と共に示した。
<Comparative Example 5>
According to the composition of Table 3, 8.3 parts of whole fat milk powder and 14.3 sugar are mixed with 55.0 parts of water heated to 30 ° C., and temper type hard butter (product name “Melano NEWSS” is added thereto as vegetable oil. -7 "Fuji Oil Co., Ltd.) 22.5 parts are mixed.
The mixture is stirred at 3000 rpm with a homomixer while warming, held at 65 ° C. for 30 minutes, and then cooled to 24.6% oil content and 20.4% non-fat solid content (non-fat milk solid 6. 1%) and an oil-in-water emulsion having a water content of 55.0% by weight was obtained. The oil-in-water emulsion thus obtained was foamed using a vertical mixer alone to evaluate workability and quality.
The evaluation is shown in Table 2 together with the formulation.

[表3]

Figure 2006003981
[Table 3]
Figure 2006003981

その結果、実施例8は非常に軽くてみずみずしい、口溶けの良い泡状の食品となり、従来の起泡性クリームを起泡させた場合よりも食感、口溶けともに異なる新しい起泡物であった。また、実施例7は水中油型乳化起泡物単独ではやや固いものの、実施可能であった。   As a result, Example 8 was a very light and fresh, foamy food with good meltability in the mouth, and was a new foamed product with different texture and meltability than when foaming a conventional foamable cream. Moreover, Example 7 was feasible although the oil-in-water type emulsified foam alone was somewhat hard.

しかし、比較例5は水中油型乳化物冷却時に分離しやすく、また長時間ホイップしても保形性のあるものにはならなかった。また比較例4の水中油型乳化物は問題なく作製出来たが、長時間ホイップしても、保形性のあるものにはならず、ホイップしなかった。   However, Comparative Example 5 was easy to separate when the oil-in-water emulsion was cooled, and even if it was whipped for a long time, it did not have shape retention. Further, the oil-in-water emulsion of Comparative Example 4 could be produced without any problem, but even when whipped for a long time, it did not have a shape retaining property and did not whipped.

以上説明したように本発明によって、乳化剤を配合しなくても良好な水中油型乳化物を製造することが可能となり、本発明は添加剤の使用により好ましくない風味が付加されることを防止することができるという効果も有する。また、従来の乳化剤使用の水中油型乳化物に、本発明品である乳化剤を配合していない水中油型乳化物を一部添加して用いる使用法に際しても、添加先に元からある乳化剤を増やすことなく乳味・コク味の付与や保形性といった特性を付与することが可能である。
As described above, according to the present invention, it becomes possible to produce a good oil-in-water emulsion without blending an emulsifier, and the present invention prevents an unfavorable flavor from being added by the use of an additive. It also has the effect that it can be done. In addition, when using a conventional oil-in-water emulsion using an emulsifier and adding a part of the oil-in-water emulsion that does not contain the emulsifier of the present invention, the original emulsifier is added to the addition destination. It is possible to impart properties such as imparting milky taste and richness and shape retention without increasing.

Claims (7)

起泡性を有するクリームで、実質的に乳化剤を配合してないことを特徴とする水中油型乳化物。 An oil-in-water emulsion characterized by being a foaming cream and substantially not containing an emulsifier. 油分が10〜50重量%、水分が10〜50重量%、無脂固形分が10〜70重量%であることを特徴とする請求項1記載の水中油型乳化物。 The oil-in-water emulsion according to claim 1, wherein the oil content is 10 to 50% by weight, the water content is 10 to 50% by weight, and the non-fat solid content is 10 to 70% by weight. 全無脂固形分に対する無脂乳固形分または無脂カカオ固形分の割合が5〜50重量%である請求項1記載の水中油型乳化物。 The oil-in-water emulsion according to claim 1, wherein the ratio of the non-fat milk solid or the non-fat cocoa solid to the total non-fat solid is 5 to 50% by weight. 油分中の油脂がハードバターまたはSUS(S:飽和脂肪酸、U:トランス体を含まない不飽和脂肪酸)で表されるトリグリセラリドを含むことを特徴とする請求項1記載の水中油型乳化物。 2. The oil-in-water emulsion according to claim 1, wherein the oil and fat in the oil contains triglyceride represented by hard butter or SUS (S: saturated fatty acid, U: unsaturated fatty acid not containing trans isomer). 請求項1記載の水中油型乳化物を単独で起泡させることを特徴とする起泡済水中油型乳化物の製造法。 A method for producing a foamed oil-in-water emulsion, wherein the oil-in-water emulsion according to claim 1 is foamed alone. 請求項1記載の水中油型乳化物と水性組成物とを混合し、起泡させることを特徴とする起泡済水中油型乳化物の製造法。 A method for producing a foamed oil-in-water emulsion, wherein the oil-in-water emulsion according to claim 1 and an aqueous composition are mixed and foamed. 請求項1記載の水中油型乳化物と水性組成物とを混合し、乳化剤を増すことなしに起泡させることを特徴とする起泡済水中油型乳化物の製造法。 A method for producing a foamed oil-in-water emulsion, wherein the oil-in-water emulsion according to claim 1 and an aqueous composition are mixed and foamed without increasing the emulsifier.
JP2006528795A 2004-06-30 2005-06-30 Oil-in-water emulsion and food production method using the same Pending JPWO2006003981A1 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
JP2004192799 2004-06-30
JP2004192799 2004-06-30
PCT/JP2005/012051 WO2006003981A1 (en) 2004-06-30 2005-06-30 Oil-in-water emulsion and process for production of food with the same

Publications (1)

Publication Number Publication Date
JPWO2006003981A1 true JPWO2006003981A1 (en) 2008-04-17

Family

ID=35782788

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2006528795A Pending JPWO2006003981A1 (en) 2004-06-30 2005-06-30 Oil-in-water emulsion and food production method using the same

Country Status (2)

Country Link
JP (1) JPWO2006003981A1 (en)
WO (1) WO2006003981A1 (en)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP5609113B2 (en) * 2007-09-10 2014-10-22 不二製油株式会社 Foamable oil-in-water emulsion
JP5146080B2 (en) * 2008-04-25 2013-02-20 不二製油株式会社 Foamable oil-in-water emulsion
PL2335675T3 (en) 2009-12-10 2015-08-31 Neubourg Skin Care Gmbh & Co Kg Emulsifier-free, polymer stabilised foam formulas

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0928296A (en) * 1995-07-19 1997-02-04 Kao Corp Food product utilizing water-containing chocolate, its production and food additive utilizing chocolate
JP2001149014A (en) * 1999-09-17 2001-06-05 Asahi Denka Kogyo Kk Oil-in-water type emulsified chocolate and combined food using the same
JP2002034451A (en) * 2000-07-26 2002-02-05 Kanegafuchi Chem Ind Co Ltd Foaming oil-in-water type composition

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP3235500B2 (en) * 1996-12-05 2001-12-04 不二製油株式会社 Oil-in-water emulsion
US20060134304A1 (en) * 2003-01-16 2006-06-22 Eriko Harada O/W emulsion and process for producing food with the same

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0928296A (en) * 1995-07-19 1997-02-04 Kao Corp Food product utilizing water-containing chocolate, its production and food additive utilizing chocolate
JP2001149014A (en) * 1999-09-17 2001-06-05 Asahi Denka Kogyo Kk Oil-in-water type emulsified chocolate and combined food using the same
JP2002034451A (en) * 2000-07-26 2002-02-05 Kanegafuchi Chem Ind Co Ltd Foaming oil-in-water type composition

Also Published As

Publication number Publication date
WO2006003981A1 (en) 2006-01-12

Similar Documents

Publication Publication Date Title
JP4502839B2 (en) Foamable oil-in-water emulsion composition
JP5635288B2 (en) Foamable oil-in-water emulsion composition
JP4901279B2 (en) Oil composition for foaming oil-in-water emulsified fat
JP5583386B2 (en) Whipped cream
JP5306757B2 (en) Foamable oil-in-water emulsified oil composition
JP2004520042A (en) Dairy products that can be whipped by shaking
WO2005079592A1 (en) Water-containing chocolates and chocolates usable as starting materials thereof
JP5365000B2 (en) Oil-in-water emulsion
JP4882749B2 (en) Oil-in-water emulsion
JP5301373B2 (en) Foamable oil-in-water emulsified oil composition
JP2010051231A (en) Foaming oil-in-water emulsion having low oil content
JP4937156B2 (en) Method for producing oil-in-water emulsion containing milk fat
EP3787414B1 (en) Food composition comprising dairy fat suitable for whipping or foaming and whipped or foamed food composition comprising dairy fat
JPWO2004062384A1 (en) O / W type emulsion and method for producing food using the same
JPH0697966B2 (en) Method for producing foamable oil-in-water emulsion
JPWO2006003981A1 (en) Oil-in-water emulsion and food production method using the same
JP2009095247A (en) Foaming emulsifier composition for cake
JP6154691B2 (en) Suspension for sponge cake
JP2001292695A (en) Oil-in-water type emulsion composition
JP6955326B2 (en) Oil composition for compound cream
JP2012075430A (en) Foamable oil-in-water emulsified oil and fat composition for presenting custard flavor
JP4390375B2 (en) Oil-in-water emulsified fat
JP6062683B2 (en) Oil-in-water emulsion for pudding
JP2006025690A (en) Oil-in-water emulsified product and method for producing food using the same
JP2002017257A (en) Oil and fat composition for foamable cream

Legal Events

Date Code Title Description
A621 Written request for application examination

Free format text: JAPANESE INTERMEDIATE CODE: A621

Effective date: 20080619

A131 Notification of reasons for refusal

Free format text: JAPANESE INTERMEDIATE CODE: A131

Effective date: 20101221

A521 Written amendment

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20110218

A02 Decision of refusal

Free format text: JAPANESE INTERMEDIATE CODE: A02

Effective date: 20120327