JPWO2005096830A1 - Production method - Google Patents

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JPWO2005096830A1
JPWO2005096830A1 JP2006511972A JP2006511972A JPWO2005096830A1 JP WO2005096830 A1 JPWO2005096830 A1 JP WO2005096830A1 JP 2006511972 A JP2006511972 A JP 2006511972A JP 2006511972 A JP2006511972 A JP 2006511972A JP WO2005096830 A1 JPWO2005096830 A1 JP WO2005096830A1
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dough
low
sugar
sweetness
wrapping
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嘉章 石坂
嘉章 石坂
秀信 松浪
秀信 松浪
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Fuji Oil Co Ltd
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Fuji Oil Co Ltd
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    • AHUMAN NECESSITIES
    • A21BAKING; EDIBLE DOUGHS
    • A21DTREATMENT, e.g. PRESERVATION, OF FLOUR OR DOUGH, e.g. BY ADDITION OF MATERIALS; BAKING; BAKERY PRODUCTS; PRESERVATION THEREOF
    • A21D13/00Finished or partly finished bakery products
    • A21D13/04Products made from materials other than rye or wheat flour
    • A21D13/045Products made from materials other than rye or wheat flour from leguminous plants
    • AHUMAN NECESSITIES
    • A21BAKING; EDIBLE DOUGHS
    • A21DTREATMENT, e.g. PRESERVATION, OF FLOUR OR DOUGH, e.g. BY ADDITION OF MATERIALS; BAKING; BAKERY PRODUCTS; PRESERVATION THEREOF
    • A21D13/00Finished or partly finished bakery products
    • A21D13/04Products made from materials other than rye or wheat flour
    • AHUMAN NECESSITIES
    • A21BAKING; EDIBLE DOUGHS
    • A21DTREATMENT, e.g. PRESERVATION, OF FLOUR OR DOUGH, e.g. BY ADDITION OF MATERIALS; BAKING; BAKERY PRODUCTS; PRESERVATION THEREOF
    • A21D13/00Finished or partly finished bakery products
    • A21D13/04Products made from materials other than rye or wheat flour
    • A21D13/047Products made from materials other than rye or wheat flour from cereals other than rye or wheat, e.g. rice
    • AHUMAN NECESSITIES
    • A21BAKING; EDIBLE DOUGHS
    • A21DTREATMENT, e.g. PRESERVATION, OF FLOUR OR DOUGH, e.g. BY ADDITION OF MATERIALS; BAKING; BAKERY PRODUCTS; PRESERVATION THEREOF
    • A21D13/00Finished or partly finished bakery products
    • A21D13/20Partially or completely coated products
    • A21D13/22Partially or completely coated products coated before baking
    • AHUMAN NECESSITIES
    • A21BAKING; EDIBLE DOUGHS
    • A21DTREATMENT, e.g. PRESERVATION, OF FLOUR OR DOUGH, e.g. BY ADDITION OF MATERIALS; BAKING; BAKERY PRODUCTS; PRESERVATION THEREOF
    • A21D13/00Finished or partly finished bakery products
    • A21D13/30Filled, to be filled or stuffed products
    • A21D13/31Filled, to be filled or stuffed products filled before baking
    • AHUMAN NECESSITIES
    • A21BAKING; EDIBLE DOUGHS
    • A21DTREATMENT, e.g. PRESERVATION, OF FLOUR OR DOUGH, e.g. BY ADDITION OF MATERIALS; BAKING; BAKERY PRODUCTS; PRESERVATION THEREOF
    • A21D13/00Finished or partly finished bakery products
    • A21D13/40Products characterised by the type, form or use
    • AHUMAN NECESSITIES
    • A21BAKING; EDIBLE DOUGHS
    • A21DTREATMENT, e.g. PRESERVATION, OF FLOUR OR DOUGH, e.g. BY ADDITION OF MATERIALS; BAKING; BAKERY PRODUCTS; PRESERVATION THEREOF
    • A21D15/00Preserving finished, partly finished or par-baked bakery products; Improving
    • A21D15/02Preserving finished, partly finished or par-baked bakery products; Improving by cooling, e.g. refrigeration, freezing
    • AHUMAN NECESSITIES
    • A21BAKING; EDIBLE DOUGHS
    • A21DTREATMENT, e.g. PRESERVATION, OF FLOUR OR DOUGH, e.g. BY ADDITION OF MATERIALS; BAKING; BAKERY PRODUCTS; PRESERVATION THEREOF
    • A21D2/00Treatment of flour or dough by adding materials thereto before or during baking
    • A21D2/08Treatment of flour or dough by adding materials thereto before or during baking by adding organic substances
    • A21D2/14Organic oxygen compounds
    • A21D2/18Carbohydrates
    • A21D2/181Sugars or sugar alcohols

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  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Food Science & Technology (AREA)
  • Botany (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Molecular Biology (AREA)
  • Cereal-Derived Products (AREA)
  • Bakery Products And Manufacturing Methods Therefor (AREA)
  • Confectionery (AREA)

Abstract

本発明は、包餡等に代表される具との組合せ作業が比較的低温で可能であって作業性がよく、甘味がマイルドであるため具の風味・物性に対し制限が少なく、且つ冷凍・冷蔵での耐性が強く、さらに冷凍・冷蔵域とそれ以上の温度域との間を変化する温度履歴に繰り返し晒されてもひび割れや硬化といった老化現象が抑制された餅状生地とそれを用いた餅種食品、およびその製造法を開発することを本発明の目的とする。本発明は、餅状生地に低甘味液糖とその他の低甘味等を含む糖類を加えて調製する事によって、包餡等の作業が低温で可能であって作業性がよく、且つ冷凍・冷蔵での耐性が強く、さらに冷凍・冷蔵域とそれ以上の温度域との間を変化する温度履歴に繰り返し晒されてもひび割れや硬化といった老化現象の発生が抑制され、低甘味であり、具の風味・物性に制限の少ない餅種菓子が製法できる。The present invention can be combined with tools such as wrapping at a relatively low temperature, has good workability, and has a mild sweetness, so there are few restrictions on the flavor and physical properties of the tools, and Using cocoon-like dough that has strong resistance to refrigeration and that has suppressed aging phenomena such as cracking and hardening even when it is repeatedly exposed to a temperature history that changes between freezing and refrigeration and higher temperature ranges. It is an object of the present invention to develop a grape food and a method for producing the same. The present invention is prepared by adding a low-sweet liquid sugar and other low-sweetness sugars to a koji-like dough, so that the operation of wrapping can be performed at low temperature and the workability is good, and it is frozen and refrigerated. It is highly resistant to aging, and even after repeated exposure to a temperature history that changes between freezing and refrigeration and higher temperature ranges, the occurrence of aging phenomena such as cracking and hardening is suppressed, and the sweetness is low. Can produce confectionery confectionery with few restrictions on flavor and physical properties.

Description

本発明は、包餡等に代表される具との組合せ作業が比較的低温で可能であって作業性がよく、甘味がマイルドであるため具の風味・物性に対し制限が少なく、且つ冷凍・冷蔵での耐性が強く、さらに冷凍・冷蔵域とそれ以上の温度域との間を変化する温度履歴に繰り返し晒されてもひび割れや硬化といった老化現象が抑制された餅状生地とそれを用いた餅種食品、およびその製造法に関するものである。 The present invention can be combined with tools such as wrapping at a relatively low temperature, has good workability, and has a mild sweetness, so there are few restrictions on the flavor and physical properties of the tools, and Using cocoon-like dough that has strong resistance to refrigeration, and has suppressed aging phenomena such as cracking and hardening even if it is repeatedly exposed to a temperature history that changes between freezing and refrigeration and higher temperature ranges. The present invention relates to varieties of foods and methods for producing them.

従来より餅または餅状生地は、単独、あるいは表面にキナコや胡麻、砂糖醤油といったタレ類を塗布したり、中に餡類といった「具」を封入して喫食されてきた。
しかしながら食文化が多様化するにしたがって、食品一般について冷凍・冷蔵温度域での喫食がなされたり、あるいは冷凍・冷蔵域で保存した後に常温に戻して、喫食したりする用途に用いられるようになったり、また、薄く展延して具を挟んだり、包んだりとその用いられ方も多岐に富み、さらに組み合わせる具にしても餡にとどまらず、チーズやクリームといった耐熱保形性や甘味度の低い具との組合せも多くなってきており、そういった需要の条件を満たす餅状食品は市場から大きな要求があった。
Conventionally, rice cakes or rice cake-like doughs have been eaten alone or with a sauce such as quinako, sesame or sugar soy sauce applied on the surface, or encased "stuff" such as rice cakes.
However, as food culture diversifies, food is generally eaten in the freezer / refrigerated temperature range, or is stored in the freezer / refrigerated region and then returned to room temperature for use. There are also a wide variety of uses such as thinly spreading and sandwiching and wrapping tools, and even combining tools are not limited to strawberries, but have low heat-resistant shape retention and sweetness such as cheese and cream The number of combinations with ingredients has increased, and there has been a great demand from the market for rice cake foods that satisfy these demands.

しかし、従来の餅状生地は水分の保持能力が低く常温及び冷蔵温度・開放系で放置されると水分を失って硬化・ひび割れしたり、また澱粉が老化して、いわゆる「搗き立ての餅」のような展延性が失われてしまう。
この現象は冷凍では糖の保水力を用いてある程度は解決することができたが、餅状生地の甘味度が上昇してしまうため、用途が限られてしまうという問題があった。またそのような技術を用いても冷蔵温度域、あるいは冷凍・冷蔵温度域から室温にもどす工程を反復する状態での餅状生地の老化を防止することはできなかった。
また、組合せ作業をする際に、従来の餅状生地は餅本来の柔軟性・可塑性・展延性を発揮するには、ある程度高温で、特に35℃を超える温度域で作業する必要があった。
しかし、具はその餅状生地の作業適適性である高温において常に好適な作業性を示すものばかりとは限らず、特に最近は嗜好の変化や市場の要求に合わせてさまざまな具や形態、さらには冷凍・冷蔵状態で保存・喫食を意図した商品への応用が為された餅種食品が増えてきており、その餅状生地の作業適性である比較的高温での十分な保形性(ボディ)を持ち得ないものも増えてきている。
However, the conventional cocoon-like dough has a low moisture retention capacity, and when left at room temperature and refrigerated temperature / open system, it loses moisture and hardens and cracks, and the starch ages, so-called `` freshly cooked rice cake '' Such extensibility is lost.
This phenomenon can be solved to some extent by freezing the sugar in freezing, but there is a problem that the sweetness of the candy-like dough increases and the use is limited. Moreover, even if such a technique was used, it was not possible to prevent aging of the cocoon-shaped dough in a state where the process of returning to the room temperature from the refrigeration temperature range or the freezing / refrigeration temperature range was repeated.
Further, when performing the combination work, it has been necessary to work the conventional cocoon-shaped fabric at a certain high temperature, particularly in a temperature range exceeding 35 ° C., in order to exhibit the inherent flexibility, plasticity, and spreadability of the cocoon.
However, tools do not always show suitable workability at high temperature, which is the work suitability of the bowl-like fabric, especially recently, various tools and forms according to changing tastes and market demands, There are an increasing number of varieties of foods that have been applied to products intended to be stored and eaten in a frozen or refrigerated state. Sufficient shape retention at relatively high temperatures (body) ) Is increasing.

組合せに供される具としては様々なものがあるが餡や調理調味されたひき肉があげられる。こういった具をフィリングと総称しているが、そのフィリングの中でも、高温での作業が困難であるものの一例としてはクリーム類、チョコレート類といったもの、さらに極端な例としてはアイスクリームなどが挙げられる。
従来の餅状生地をこれらの高温での耐性をもたない具が作業を適正にできる温度、例えば35℃以下、特に30℃以下まで温度を下げて用いと、餅状生地は薄く延ばせない、あるいは均一な厚みにできない、ちぎれ、穴が開くといった問題が生じる。
逆に、従来の餅状生地の作業適正温度でそういった高温での耐性を持たない具を包餡といった作業に供すると、具のボディが失われ、作業中に流動し、餅生地からこぼれ落ちたり、十分に包餡されずはみ出したり、また菌が繁殖しやすくなり衛生上の問題が発生しかねない。
また、それらの具に高温での耐性を付与しようとすると、口溶けや風味といったものを犠牲にせざるを得ず、商品価値の低いものしか得られないといった欠点があった。
There are various kinds of ingredients that can be used in the combination, but examples include salmon and cooked ground meat. These tools are collectively referred to as fillings. Examples of those fillings that are difficult to work at high temperatures include creams and chocolates, and more extreme examples include ice creams. .
When the temperature is reduced to a temperature at which tools having no resistance at high temperatures can work properly, such as 35 ° C. or lower, particularly 30 ° C. or lower, the conventional wrinkled fabric cannot be thinly stretched. Or the problem that it cannot be made uniform thickness, a tear, and a hole open arises.
On the other hand, if a tool that does not have such high temperature resistance is used for wrapping at the proper working temperature of the conventional koji-like fabric, the body of the tool is lost, it flows during the work, and spills from the koji fabric, If it is not sufficiently encased, it may protrude and bacteria may easily propagate, which may cause sanitary problems.
In addition, when trying to impart resistance at high temperatures to these ingredients, there is a drawback in that only those with a low commercial value can be obtained, such as melting in the mouth and flavor.

他方、従来から、餅状生地の食感の劣化を抑える研究はなされていた。
例えば、もち米:うるち米が略100〜85:0〜15で構成されるでん粉と糖類と水との混合加熱により得られる餅状生地(粘弾性物)で冷菓類を被覆する被覆冷菓からなり、前記餅状生地(粘弾性物)が、でん粉を3〜55重量%、砂糖と麦芽糖が1:0.5〜2の比率で全糖類量の50重量%以上を占める糖類を20〜70重量%、水を25〜40重量%含有することを特徴とする方法が考案されている(例えば、特許文献1参照)が、冷凍での、しかも餅状生地の甘味度がかなり高い為、具の風味設計に制限を受け、しかも包餡等の作業性の向上については記載されていない。
On the other hand, studies have been made to suppress the deterioration of the texture of the cocoon-shaped dough.
For example, glutinous rice: made of coated cold confectionery that coats frozen confectionery with a dough-like dough (viscoelastic material) obtained by mixing and heating starch, sugar, and water composed of approximately 100 to 85: 0 to 15, The cocoon-like dough (viscoelastic material) is 3 to 55% by weight of starch, 20 to 70% by weight of saccharides in which sugar and malt sugar account for 50% by weight or more of the total saccharides in a ratio of 1: 0.5 to 2 A method characterized by containing 25 to 40% by weight of water has been devised (see, for example, Patent Document 1), but since the sweetness of the frozen dough is quite high, the flavor of the ingredients There is no description on improvement of workability such as wrapping due to limitations in design.

また、餅類を製造するに際し、β−アミラーゼとトレハロースを含有する餅類の老化防止用組成物を添加することを特徴とする方法が考案されている(例えば、特許文献1参照)が、これについても包餡等の作業性の向上については記載されていない。
従って、従来方法に依る餅種食品は冷蔵・冷凍の工程により、澱粉の老化に伴う品質の劣化を抑えきれず、しかも餅状生地の甘味度が高い為、具の風味に制限が生じやすく、しかも包餡等の作業を高温で行わなくてはならないため、餅状生地の成型が困難だったり、具の物性に制限が生じたり、あるいは具の食感を犠牲にして耐熱性を向上させたりする必要があり、一方で前述の通り、最近では食文化が多様化から市場からのニーズが多様化しており、そのニーズに対応できる、具の風味・物性に制限の少ない、且つ作業性のよい餅種菓子の製法への要求はきわめて高いものがあった。
特開2002−272382号公報(第1−9頁) 特開平9−107899号公報(第1−4頁)
In addition, a method has been devised which comprises adding a composition for preventing aging of moss containing β-amylase and trehalose when producing moss (see, for example, Patent Document 1). There is no mention of improving workability such as wrapping.
Therefore, the varieties of foods based on the conventional method cannot suppress deterioration of quality due to aging of starch due to the refrigeration / frozen process, and the sweetness of the candy-like dough is high, so the flavor of the ingredients tends to be limited, Moreover, since the work such as wrapping must be done at a high temperature, it is difficult to mold the bowl-shaped dough, the physical properties of the tool are limited, or the heat resistance is improved at the expense of the texture of the tool. On the other hand, as described above, the needs of the market have diversified recently due to the diversification of food culture, there are few restrictions on the flavor and physical properties of the ingredients, and the workability is good There was a very high demand for the production method for confectionery.
JP 2002-272382 A (page 1-9) JP-A-9-107899 (page 1-4)

包餡等の具との組み合わせ作業が比較的低温で可能であり、餅状生地の甘味がマイルドであるため具の風味・物性に対し制限が少なく、且つ冷凍・冷蔵での耐性が強く、さらに冷凍・冷蔵域とそれ以上の温度域との間を変化する温度履歴に繰り返し晒されてもひび割れや硬化といった老化現象の発生が抑制された餅状生地とそれを用いた餅種食品、およびその製造法を開発することを本発明の目的とする。   Can be combined with other ingredients such as wrapping at a relatively low temperature. The sweetness of the dough is mild, so there are few restrictions on the flavor and physical properties of the ingredients, and the resistance to freezing and refrigeration is strong. A cocoon-like dough in which the occurrence of aging phenomena such as cracking and hardening is suppressed even if it is repeatedly exposed to a temperature history that changes between a freezing / refrigerated area and a temperature range above, and a varieties of food using the same It is an object of the present invention to develop a manufacturing method.

本発明者らは、上記目的を達成するために鋭意研究をおこなった結果、餅状生地に低甘味糖を含む糖類を加えて調製する事によって、低甘味で具の風味・物性に制限の少なく、包餡等の組み合わせ作業が低温で可能であって作業性がよく、且つ冷凍・冷蔵での耐性が強く、さらに冷凍・冷蔵域とそれ以上の温度域との間を変化する温度履歴に繰り返し晒されてもひび割れや硬化といった老化現象の発生が抑制された餅種食品が製造できるという知見を得、本発明を完成するに至った。
すなわち、本発明は、
(1)穀粉に対し低甘味糖を含む糖類を加えて調製した餅状生地を具と組み合わせ成型することを特徴とする餅種食品の製造法であり、(2)具がフィリング類である(1)記載の製造法であり、(3)フィリング類がクリーム類、ムース類またはチョコレート類である(2)記載の製造法であり、(4)具との組み合わせ成型時の温度が35℃以下である(1)記載の餅種食品の製造法であり、(5)組み合わせ成型を包餡によって行う(1)記載の餅種食品の製造法であり、(6)低甘味糖が穀粉100重量部に対して14重量部以上である(1)記載の製造法であり、(7)低甘味糖を含む糖類の合計が穀粉に対して45重量%以下である(1)記載の製造法であり、(8)具との組み合わせ成型後に冷凍または冷蔵し、さらに室温に戻す工程があることを特徴とする(1)記載の餅種食品の製造法であり、(9)組み合わせ成型後に冷凍または冷蔵と室温に戻す工程を反復する(8)記載の餅種食品の製造法であり、(10低甘味糖を含む糖類を加えて調製してなる餅状生地である。
As a result of diligent research to achieve the above object, the present inventors have added a saccharide containing a low-sweet sugar to a koji-like dough, thereby reducing the flavor and physical properties of the ingredients with low sweetness. Combined work such as wrapping is possible at low temperature, good workability, strong resistance to freezing and refrigeration, and repeated temperature history changing between freezing and refrigeration area and higher temperature range The present inventors have obtained the knowledge that, even when exposed, it is possible to produce dairy foods in which the occurrence of aging phenomena such as cracking and hardening is suppressed, the present invention has been completed.
That is, the present invention
(1) A method for producing a potato seed food characterized in that a candy-like dough prepared by adding a saccharide containing a low-sweet sugar to flour is combined with a mold, and (2) the ingredient is a filling ( (1) The manufacturing method according to (2), wherein the fillings are creams, mousses or chocolates. (4) The temperature at the time of combination molding with the ingredient is 35 ° C. or lower. (1) The method for producing a grape seed food according to (1), (5) The method for producing a grape seed food according to (1), wherein the combination molding is performed by wrapping, and (6) low-sweet sugar is 100 weight of flour. (7) The production method according to (1), wherein the total amount of saccharides including low-sweet sugar is 45% by weight or less based on flour. Yes, (8) Freeze or refrigerate after combination molding with tools, and return to room temperature (9) The method for producing a potato seed food according to (8), wherein the step of freezing or refrigeration and returning to room temperature is repeated after combination molding. It is a cocoon-like dough prepared by adding a saccharide containing 10 low-sweet sugars.

本発明によって、包餡等に代表される具との組合せ作業が比較的低温で可能であり、甘味がマイルドであるため具の風味・物性に対し制限が少なく、且つ冷凍・冷蔵での耐性が強く、さらに冷凍・冷蔵域とそれ以上の温度域との間を変化する温度履歴に繰り返し晒されてもひび割れや硬化といった老化現象の発生が抑制された餅種菓子を製法できる利点がある。   According to the present invention, it is possible to combine with typified foods such as wrapping at a relatively low temperature, and since the sweetness is mild, there are few restrictions on the flavor and physical properties of the stuffed material, and resistance to freezing and refrigeration is achieved. Further, there is an advantage that a confectionery confectionery can be produced in which the occurrence of aging phenomenon such as cracking and hardening is suppressed even if it is repeatedly exposed to a temperature history that changes between a frozen / refrigerated region and a temperature range higher than that.

本発明において言うところの餅状生地は、米を代表とする穀粉と水を用いたもので、餅や求肥あるいはそれと同様の粘性と弾力に富んだ食品を広く指称する。   The rice cake-like dough referred to in the present invention uses flour and water represented by rice, and widely refers to rice cake, fertilizer, or foods rich in viscosity and elasticity similar to those.

これは通常、穀粉と水を混ぜ合せ、加熱し、捏和してこれに低甘味糖を含む糖類を加えて、得ることができる。
穀粉の種類は特に限定されないが、米をひいて粉にした米穀粉(粳(うるち)米や糯(もち)米といった品種の違いにより様々な種類がある)、小麦粉、粟(あわ)粉、トウモロコシ粉、蕎麦(そば)粉等、あるいはそれら複数を組合わせて用いる事ができるが、餅としての弾力性・展延性を出しやすい穀粉、主にアミロペクチン含有量の多い種類のもの、粳品種よりは糯品種の方がより望ましい。
穀粉と水分との量についても、常法に従い設定してかまわない。通常穀粉100部に対して水50〜70重量部の範囲であり、保水性が少ない穀粉(例えば輸入米由来の餅粉)の場合は通常穀粉100部に対して水60〜80重量部程度とすることで使用が可能である。
This can usually be obtained by mixing flour and water, heating, kneading and adding a saccharide containing low sweetness sugar to this.
There are no particular restrictions on the type of flour, but rice flour that has been crushed with rice (various types such as glutinous rice and glutinous rice are available), wheat flour, and potato flour , Corn flour, buckwheat flour (buckwheat noodles), etc., or a combination of them, but flour that is easy to produce elasticity and spreadability as straw, mainly varieties with high amylopectin content The grape variety is more desirable.
The amount of flour and moisture may be set according to a conventional method. In the case of flour with a low water retention (for example, rice flour derived from imported rice), the water is about 60 to 80 parts by weight with respect to 100 parts of normal flour. It is possible to use it.

加熱方法に関しても特に限定はされないが、蒸し器を用いて蒸し上げる方法が一般的である。
加熱時間は、用いる方法や装置により異なるが、糯粉の澱粉がα化するまでの時間が適当で、一例としては蒸練機を用いた場合では7分間、輸入米由来の餅粉を用いた場合は10分間程度と、やや加熱時間を延ばすといった対応が必要であるが、既存の方法に準じて用いる事が可能である。
捏和方法も同様に特に限定はされないが臼と杵を用いて「搗く」のが一般的であるが、蒸練機により加熱・捏和を行ってもよい。
The heating method is not particularly limited, but a method of steaming using a steamer is common.
The heating time varies depending on the method and apparatus to be used, but the time until the starch of starch is pregelatinized is appropriate. For example, when using a steaming machine, the starch from the imported rice is used for 7 minutes. In such a case, it is necessary to take a measure such as slightly extending the heating time as about 10 minutes, but it can be used in accordance with an existing method.
Similarly, the kneading method is not particularly limited, but “kneading” is generally performed using a mortar and a koji. However, heating and kneading may be performed with a steamer.

餅状生地に添加された糖類には餅状生地の老化を防止する機能や餅状生地の低温での可塑性・展延性を向上させる機能があるが、特に低温での可塑性・展延性の向上は、低温度域での餅状生地と具の組み合わせ成型の作業性の向上効果があり、前述の高温度域での作業に適さない具との組み合わせ作業において効果的である。
ただ、老化防止も低温での可塑性・展延性の向上も、高甘味糖を多量に用いると餅状生地の甘味度が上昇してしまい、具との組み合わせ成型をして餅種食品とした場合に具の風味の阻害をしてしまう。これは特に具が甘くない場合に特に望ましくない。
The sugar added to the cocoon-like fabric has the function of preventing aging of the cocoon-like fabric and the function of improving the plasticity and spreadability of the cocoon-like fabric at low temperatures. There is an effect of improving the workability of the combination molding of the bowl-shaped dough and the tool in the low temperature range, and it is effective in the combination work with the tool not suitable for the above-described work in the high temperature range.
However, both the prevention of aging and the improvement of plasticity and spreadability at low temperatures, when the use of a large amount of high-sweet sugar increases the sweetness of the dough-like dough, and when it is combined with ingredients and made into varieties Inhibits the flavor of ingredients. This is particularly undesirable when the ingredients are not sweet.

糖は糖液で用いるのが好ましく、液糖、または固体の糖を水に溶解させて、あるいは液糖と固形の糖を併用して用いてもよい。
ただし、原料とする糖類は低甘味糖であることが必要である。ここで低甘味糖とは、甘味度(ここでは一定濃度のショ糖溶液と同じ甘味の強さを示す被験甘味料の濃度の比較。ショ糖を1とする)が0.4以下の糖が好ましい。
糖液の糖濃度は望ましくは固体の糖が残っていない状態で用いるのが望ましく、通常は60〜80重量%の範囲が良い。
また、老化防止と低温での可塑性・展延性の向上の機能がより強い糖を用いるのが好ましい。最適にはには、マルトースおよびマルトシルトレハロースの使用が推奨され、重量比でマルトース:マルトシルトレハロース=0:100〜80:20であることが望ましい。
The sugar is preferably used in a sugar solution, and liquid sugar or solid sugar may be dissolved in water, or liquid sugar and solid sugar may be used in combination.
However, the saccharide used as a raw material needs to be a low sweet sugar. Here, the low-sweet sugar is a sugar having a sweetness level (in this case, a comparison of the concentrations of the test sweeteners exhibiting the same sweetness intensity as a sucrose solution having a constant concentration. Sucrose is 1). preferable.
The sugar concentration of the sugar solution is desirably used in a state where no solid sugar remains, and is usually in the range of 60 to 80% by weight.
Further, it is preferable to use a sugar having a stronger function of preventing aging and improving plasticity and spreadability at low temperatures. Optimally, use of maltose and maltosyl trehalose is recommended, and it is desirable that maltose: maltosyl trehalose = 0: 100 to 80:20 by weight ratio.

上記加熱・捏和した穀粉と上記に内容の糖液と混ぜ合わせる。
混合比率は穀粉100重量部に対し糖液(糖濃度70〜75重量%程度として)換算で20重量部以上、糖換算で14重量部以上が望ましく、より好ましくは液糖換算で30重量部以上、糖換算で21重量部以上が望ましい。この下限を糖類の量が下回ると餅状生地の甘味度は低くても可塑性・展延性の向上の機能が充分に発揮できない。
また、餅状生地の甘味度が具の風味を阻害しない範囲でなら低甘味ではないものを併用してもかまわないが、低甘味糖を含めた糖類の総量として、液糖換算で穀粉100部に対し60重量部以下、糖換算で45重量部以下が望ましい。この上限を上回ると、たとえ全量低甘味糖を用いても餅状生地の甘味度が具の風味を阻害する程度に上昇しかねず、また餅状生地が柔かくなり過ぎ、具との組み合わせに適さない状態になる。
混ぜ合わす方法についても、特に限定はされないが、一般的には、ケーキミキサーと呼ばれる装置によりフック形状のアームを用い、低速で生地が均一になるよう混ぜ合わせるのがよい。混ぜ合わせた後に放冷して具との組合せ成型に供する。
Mix the above heated and kneaded flour with the sugar solution of the above content.
The mixing ratio is preferably 20 parts by weight or more in terms of sugar liquid (sugar concentration of about 70 to 75% by weight) with respect to 100 parts by weight of flour, more preferably 14 parts by weight or more in terms of sugar, and more preferably 30 parts by weight or more in terms of liquid sugar. The amount is preferably 21 parts by weight or more in terms of sugar. If the amount of saccharide falls below this lower limit, the function of improving plasticity and spreadability cannot be sufficiently exhibited even if the sweetness of the candy-like dough is low.
In addition, if the sweetness of the dough-like dough does not inhibit the flavor of the ingredients, it may be used in combination with non-low sweetness, but the total amount of saccharides including low sweetness sugar is 100 parts flour in terms of liquid sugar. 60 parts by weight or less, and 45 parts by weight or less in terms of sugar is desirable. Above this limit, the sweetness of the dough-like dough may increase to the extent that it impairs the flavor of the ingredients, even if all of the low-sugar sugar is used, and the dough-like dough becomes too soft, making it suitable for combination with ingredients. No state.
The method of mixing is not particularly limited, but generally, it is preferable to mix using a hook-shaped arm with a device called a cake mixer so that the dough becomes uniform at low speed. After mixing, it is allowed to cool and used for combination molding with tools.

餅状生地と組み合わせる具は特に限定はされないが、最近では嗜好の変化や市場の要求に合わせてさまざまな具や形態、さらには冷凍・冷蔵状態で保存・喫食を意図した商品への応用が為された餅種食品が増えてきており、したがって具もフィリング類、特に具が高温になると流動性が増し、餅状生地との組合せ工程の作業性に悪影響が生じたり、または高温での作業が可能な程度まで具の耐熱性を向上させたが為、口溶けを犠牲にしなくてはならないようなフィリング類、一例を挙げるとクリーム類またはムース類またはチョコレート類においてより効果的であり、またそういった高温での耐性有さない具と餅状生地との組み合わせ成型時の温度は35℃以下、特に好ましくは30℃以下であることが望ましい。
具と餅状生地を組合わせたものは餅種食品と称し、代表的なものとしては包餡(具を餅状生地で包み込むこと:例、大福餅)が挙げられるが他にはサンド(単独あるいは複数の餅状生地で具を挟み込むこと。具は外気に一部露呈している)等の成型も挙げられる。
There are no particular restrictions on the ingredients to be combined with the cocoon-shaped dough, but recently there are various ingredients and forms to meet changing tastes and market demands, as well as applications for products intended to be stored and eaten in a frozen or refrigerated state. As a result, there is an increase in the amount of processed varieties of foods, so the ingredients also become fillings, especially when the ingredients become hot, the fluidity increases, and the workability of the combination process with the dough-like dough is adversely affected, or work at high temperatures It is more effective in fillings, such as creams, mousses, or chocolates, where the heat resistance of the ingredients has been improved to the extent possible, and must be sacrificed in the mouth, such as creams, mousses or chocolates. It is desirable that the temperature at the time of the combination molding of the non-resistant tool and the cocoon-like material is 35 ° C. or less, particularly preferably 30 ° C. or less.
A combination of ingredients and candy-like dough is called varieties of food, and typical examples include wrapping (wrapping ingredients with candy-like dough: eg, Daifuku candy), but sand (single) Alternatively, the tool may be sandwiched between a plurality of bowl-shaped fabrics (the tool is partially exposed to the outside air).

このようにして作成された餅種食品は包餡等に代表される具との組合せ作業が比較的低温で可能であり、甘味がマイルドであるため具の風味・物性に対し制限が少なく、且つ冷凍・冷蔵での耐性が強く、さらに冷凍・冷蔵域とそれ以上の温度域との間を変化する温度履歴に繰り返し晒されてもひび割れや硬化といった老化現象が抑制された餅状生地とそれを用いた餅種食品が作成できる。   The sourdough food prepared in this way can be combined with ingredients represented by wrapping etc. at a relatively low temperature, and since the sweetness is mild, there are few restrictions on the flavor and physical properties of the ingredients, and It has a strong resistance to freezing and refrigeration, and it has a cocoon-like dough that suppresses aging phenomena such as cracking and hardening even when it is repeatedly exposed to a temperature history that changes between the freezing and refrigeration areas and higher temperatures. The used varieties can be made.

以下に本発明の実施例を示し、本発明をより詳細に説明するが、本発明の精神は以下の実施例に限定されるものではない。なお、例中、%及び部は重量基準を意味する。   Examples of the present invention will be described below to explain the present invention in more detail. However, the spirit of the present invention is not limited to the following examples. In the examples,% and part mean weight basis.

<実施例1>
表1の配合に従って、蒸練機(株式会社コバード社製)に餅粉(日の本穀粉株式会社社製「紫餅粉」(国産米原料))と水を混練したものを入れ、12分間98℃の温度で蒸す。
以上の工程とは別に表1の配合に従って精製マルトース(株式会社林原商事製「サンマルトS」)、マルトシルトレハロースシラップ(株式会社林原商事製「ハローデックス」、)と水を均一に混合し糖液を用意する。
蒸し上がった餅状生地ベースに別に作成しておいた蒸し上がった餅を、ケーキミキサー(株式会社愛工舎社製「マイティー60」)に移し、糖液を数回に分け加え(フック使用、回転数:低速)番重に移し、放冷して餅状生地として包餡等の作業に供する。
この餅状生地と具としてホイップクリーム(不二製油株式会社「レジェール20」を8%加糖、比重0.5までホイップ)、包餡装置(株式会社コバード社製「AR−88」)にて作業温度22℃にてその作業性を評価、また包餡した餅種食品を虐待試験に供し、その冷凍・冷蔵耐性の評価を行った。
<Example 1>
According to the composition in Table 1, a kneading powder (manufactured by Nihonhon Flour Co., Ltd. “purple rice flour” (domestic rice raw material)) and water are mixed in a steaming machine (Covard Co., Ltd.) for 12 minutes Steam at a temperature of 98 ° C.
Separately from the above steps, purified maltose (“Sanmaruto S” manufactured by Hayashibara Shoji Co., Ltd.), maltosyl trehalose syrup (“Hellodex” manufactured by Hayashibara Shoji Co., Ltd.) and water are uniformly mixed according to the composition in Table 1 and the sugar solution Prepare.
The steamed rice cake prepared separately on the steamed rice cake base is transferred to a cake mixer ("Mighty 60" manufactured by Aikosha Co., Ltd.), and the sugar solution is added several times (using hook, rotating) Number: Low speed) Move to the weight and let it cool and serve as candy-like dough for wrapping.
Worked with whipped cream (Fuji Oil Co., Ltd. “Reger 20” with 8% sugar added, whipped to a specific gravity of 0.5) and wrapping device (“AR-88” manufactured by Kovard Co., Ltd.) The workability was evaluated at a temperature of 22 ° C., and the packaged grape food was subjected to an abuse test to evaluate its resistance to freezing and refrigeration.

<実施例2・実施例3・比較例1・比較例2・比較例3>
表1の配合に従い、実施例1と同様の製法にて餅種食品を得、評価を行った。なお、グラニュー糖は(フジ日本精糖株式会社社製)、還元水飴は(株式会社林原商事社製「HS−30」)をもちいた。
評価は表1に配合と共に示した。
<Example 2, Example 3, Comparative Example 1, Comparative Example 2, Comparative Example 3>
According to the composition shown in Table 1, grape seed food was obtained by the same production method as in Example 1 and evaluated. Granulated sugar (Fuji Nippon Seika Co., Ltd.) and reduced starch syrup (Hayashibara Shoji "HS-30") were used.
The evaluation is shown in Table 1 together with the formulation.

[表1]

Figure 2005096830
※1 包餡適正
○:22℃でも包餡可能。
(耐熱性を付与されていないフィリング類を具として包餡可能)
△:30℃以上で包餡可能。
×:40℃以上で包餡可能。
−:包餡作業自体ができない。(老化評価も不能)
○と△までは包餡の作業適正あり。
※2 甘味評価
○:具の特徴を阻害しない、可食用容器的な存在。
△:甘さ的には抑えられているが、数個食べると具の風味に影響があるレベルの甘さ。
×:具の風味を損なうレベルの甘さ。
○と△までは具の風味設計の自由度が高く、利用価値が認められる範囲。
※3 老化評価(虐待試験後(※4)に評価)
○:虐待試験前の餅の食感と変わらない。
△:やや堅くなっているものの十分に喫食可能な食感。
×:老化が進み、堅く脆く喫食には適さない状態。
−:評価不能
※4 虐待試験
緩慢冷凍(冷風を吹き付ける急速冷凍ではなく、−18℃雰囲気下での冷凍を指す)後、7日間−18℃で冷凍保管、さらに冷蔵庫5℃雰囲気下放置にて解凍、その後3日間5℃冷蔵保管、再び−18℃(緩慢冷凍)で再冷凍、3日間−18℃で冷凍保存、冷蔵庫5℃雰囲気下放置で再解凍。[Table 1]
Figure 2005096830
* 1 Suitable for packaging ○: Can be packaged even at 22 ℃.
(Can be filled with fillings that are not heat-resistant)
Δ: Can be packaged at 30 ° C or higher.
X: Can be wrapped at 40 ° C or higher.
-: The wrapping operation itself cannot be performed. (Aging assessment is also impossible)
○ and △ are appropriate for wrapping.
* 2 Sweetness evaluation ○: An edible container that does not interfere with the characteristics of the ingredients.
(Triangle | delta): The sweetness of the level which is suppressed in sweetness but has an influence on the flavor of an ingredient | tool when eating several.
X: Sweetness at a level that impairs the flavor of the ingredients.
The range up to ○ and △ is a range in which the degree of freedom in the design of ingredients is high and the utility value is recognized.
* 3 Aging assessment (evaluated after abuse test (* 4))
○: It is not different from the texture of moth before the abuse test.
(Triangle | delta): The food texture which can be eaten enough, although it becomes a little hard.
X: Aging is progressing, it is hard and brittle and is not suitable for eating.
-: Not appreciable * 4 Abuse test Slow freezing (Refers to freezing in an atmosphere of -18 ° C, not quick freezing with cold air), then stored frozen at -18 ° C for 7 days, then left in a refrigerator at 5 ° C. Thawed, then refrigerated at 5 ° C for 3 days, re-frozen at -18 ° C (slow freezing), stored frozen at -18 ° C for 3 days, re-thawed in a refrigerator at 5 ° C.

実施例1と実施例2は、22℃でも包餡作業性が良好であり、且つ餅状生地の甘味は具の特徴を阻害せず、虐待試験においても餅の食感を維持したものであった。
実施例3も実施例1と実施例2に比べると若干包餡作業性が堅い感じはあるが、30℃で十分に包餡作業が可能であり、具の特徴を阻害せず、虐待試験においても餅の食感を維持したものであった。
一方、比較例1・比較例2は、従来型の甘味度の高い糖を使用したものであるが、包餡作業温度を下げると餅状生地が堅く、展延性、弾力性を失う為、40℃程度までしか包餡作業温度を下げる事ができなかった。また、比較例1は虐待試験においても容易く老化が進み、餅の食感を維持できないものであった。
また、比較例1・比較例2の糖の量をさらに倍程度まで上昇させた比較例3(既存の老化耐性を付与された餅状生地としてもちいられる配合はこのレベル)も包餡適正・老化耐性に目立った改善は認められず、しかもその甘味度はいよいよ具の特徴を阻害するものとなった。
In Examples 1 and 2, the wrapping workability was good even at 22 ° C., and the sweetness of the koji-like dough did not hinder the characteristics of the ingredients, and the texture of the koji was maintained even in the abuse test. It was.
Although Example 3 also seems to have a slightly harder wrapping workability than Examples 1 and 2, it can be fully wrapped at 30 ° C., does not interfere with the characteristics of the tool, and is used in an abuse test. Also maintained the texture of the crab.
On the other hand, Comparative Example 1 and Comparative Example 2 are those using a conventional sugar having a high sweetness, but when the wrapping operation temperature is lowered, the cocoon-like dough becomes stiff and loses its spreadability and elasticity. The packaging operation temperature could only be lowered to about ℃. Further, Comparative Example 1 was easily aged even in the abuse test and could not maintain the texture of moths.
In addition, Comparative Example 3 in which the amount of sugar of Comparative Example 1 and Comparative Example 2 is further increased to about twice (existing aging-resistant koji-like dough is used at this level) is also suitable for aging and aging There was no noticeable improvement in tolerance, and the sweetness finally hindered the characteristics of the ingredients.

<実施例4・実施例5・比較例4・比較例5>
表2の配合に従い、実施例1と同様の製法にて餅種食品を得、評価を行った。
評価は表2に同条件の実施例1と共に示した。
<Example 4 / Example 5 / Comparative Example 4 / Comparative Example 5>
According to the formulation of Table 2, the varieties of food were obtained by the same production method as in Example 1 and evaluated.
The evaluation is shown in Table 2 together with Example 1 under the same conditions.

[表2]

Figure 2005096830
※ 評価方法は表1の系と同じ[Table 2]
Figure 2005096830
* The evaluation method is the same as the system in Table 1.

実施例4は、実施例1に比べると包餡作業性は若干堅い感じはあるが30℃でも十分に包餡作業が可能、虐待試験においてもやや堅く締まった感じはあるが十分に餅の食感を維持し、餅状生地の甘味は具の特徴を阻害しないものであった。
また、実施例5は実施例1に比べると包餡作業性は餅状生地が若干柔らかい感じはあるが22℃でも十分に包餡作業性が良好であり、また虐待試験においてもやや柔らかい感じはあるものの、十分に餅の食感を維持したものであり、餅状生地の甘味は実施例1に比べるとやや増しているものの、実用可能な程度であった。
In Example 4, the wrapping workability is slightly harder than that in Example 1, but the wrapping work can be performed sufficiently even at 30 ° C. The sweetness of the dough-like dough did not interfere with the characteristics of the ingredients.
In addition, the wrapping workability of Example 5 is slightly softer than that of Example 1, but the wrapping workability is sufficiently good even at 22 ° C. Although it was, the texture of the koji was sufficiently maintained, and the sweetness of the koji-shaped dough was slightly higher than that of Example 1, but was practical.

一方、比較例4は餅状生地の甘味は具の特徴を阻害しないものであったが、包餡作業温度を下げると餅状生地が堅く、展延性、弾力性を失う為、40℃程度までしか包餡作業温度を下げる事ができなかった。虐待試験においても容易く老化が進み、餅の食感を維持できず、商品価値のないものであった。
また、比較例5は餅状生地の甘味は具の特徴を阻害するレベルまで強く、かつ、餅状生地が柔らかすぎて包餡作業性がわるく、商品価値のないものであった。(虐待試験に供することはできなかった)
On the other hand, in Comparative Example 4, the sweetness of the candy-like dough did not inhibit the characteristics of the ingredients, but when the wrapping operation temperature was lowered, the candy-like dough became stiff and lost its extensibility and elasticity. Only the wrapping temperature could be lowered. In the abuse test, aging easily progressed, and the texture of the cocoon could not be maintained, and the product value was not good.
Further, in Comparative Example 5, the sweetness of the candy-like dough was strong enough to inhibit the characteristics of the ingredients, and the candy-like dough was too soft, resulting in poor wrapping workability and no commercial value. (We were not able to take the abuse test)

<実施例1・実施例2・実施例6・実施例7・比較例6>
表3の配合に従い、実施例1と同様の製法にて餅種食品を得、評価を行った。
評価は表3に同条件の実施例1・実施例2と共に示した。なお、リキッドマルトースは(株)ニッシ社製「リキッドマルトース80」をもちいた。
<Example 1, Example 2, Example 6, Example 7, Comparative Example 6>
According to the composition shown in Table 3, a soy seed food was obtained by the same production method as in Example 1 and evaluated.
The evaluation is shown in Table 3 together with Example 1 and Example 2 under the same conditions. The liquid maltose used was “Liquid Maltose 80” manufactured by Nisshi Corporation.

[表3]

Figure 2005096830
[Table 3]
Figure 2005096830

実施例6は実施例1のマルトシルトレハロースシラップを一部リキッドマルトースに置き換えたものであるが、同じ量を精製マルトースに置き換えた実施例2に比べやや保湿力が高いものの、包餡作業性、甘味評価、老化耐性においては実施例2と同程度であった。
また、実施例7では低甘味糖・低甘味液糖の範疇ではない水飴に置き換えたものであるが、水飴自体には前述の包餡作業性、老化耐性への貢献はマルトースほどではないし、甘味度がやや上昇するのではあるが、低甘味糖であるマルトシルトレハロースシラップが20部以上であれば包餡作業性、老化耐性は商品として利用できる程度であった。
ただ、比較例6で示す通り、マルトシルトレハロースシラップ単品であったならば十分に効果が期待できるはずの量である50部であっても、他の、低甘味糖でない糖類と合わせたトータル量が多すぎると餅状生地が柔らかくなりすぎて包餡作業性が悪くなり商品としては利用できないものであった。
Example 6 is obtained by partially replacing the maltosyl trehalose syrup of Example 1 with liquid maltose, but has a slightly higher moisturizing power than that of Example 2 in which the same amount was replaced with purified maltose. The sweetness evaluation and aging resistance were similar to those in Example 2.
Further, in Example 7, it was replaced with varicella which is not a category of low sweet sugar and low sweet liquid sugar, but the varicella itself does not contribute to the above-mentioned wrapping workability and aging resistance as much as maltose. Although the degree slightly increased, if the maltosyl trehalose syrup, which is a low sweet sugar, was 20 parts or more, the wrapping workability and the aging resistance were only usable as commercial products.
However, as shown in Comparative Example 6, even if it was 50 parts, which should be sufficiently effective if it was a single product of maltosyl trehalose syrup, the total amount combined with other sugars that are not low-sweet sugars If the amount is too large, the candy-like fabric becomes too soft and the wrapping workability is deteriorated so that it cannot be used as a product.

本発明によって、包餡等に代表される具との組合せ作業が比較的低温で可能であって作業性がよく、甘味がマイルドであるため具の風味・物性に対し制限が少なく、且つ冷凍・冷蔵での耐性が強く、さらに冷凍・冷蔵域とそれ以上の温度域との間を変化する温度履歴に繰り返し晒されてもひび割れや硬化といった老化現象が抑制された餅種菓子が作成できる。   According to the present invention, the combination work with tools represented by wrapping can be performed at a relatively low temperature, the workability is good, and the sweetness is mild, so there are few restrictions on the flavor and physical properties of the tools, and A confectionery can be made that has high resistance to refrigeration and that has been suppressed from aging such as cracking and hardening even when it is repeatedly exposed to a temperature history that changes between the freezing and refrigeration regions and higher temperature regions.

Claims (10)

穀粉に対し低甘味糖を含む糖類を加えて調製した餅状生地を具と組み合わせ成型することを特徴とする餅種食品の製造法。 A method for producing a cereal food, characterized in that a candy-like dough prepared by adding a saccharide containing low-sweet sugar to flour is combined and molded. 具がフィリング類である請求項1記載の製造法。 The method according to claim 1, wherein the tool is a filling. フィリング類がクリーム類、ムース類またはチョコレート類である請求項2記載の製造法。 The process according to claim 2, wherein the fillings are creams, mousses or chocolates. 具との組み合わせ成型時の温度が35℃以下である請求項1記載の餅種食品の製造法。 The method for producing a grape food according to claim 1, wherein the temperature at the time of combination molding with the ingredients is 35 ° C or lower. 組み合わせ成型を包餡によって行う請求項1記載の餅種食品の製造法。 The method for producing a varieties of foods according to claim 1, wherein the combination molding is performed by wrapping. 低甘味糖が穀粉100重量部に対して14重量部以上である請求項1記載の製造法。 The process according to claim 1, wherein the low-sweet sugar is 14 parts by weight or more with respect to 100 parts by weight of flour. 低甘味糖を含む糖類の合計が穀粉に対して45重量%以下である請求項1記載の製造法。 The method according to claim 1, wherein the total amount of sugars including low sweet sugar is 45% by weight or less based on flour. 組み合わせ成型後にさらに冷凍または冷蔵し、その後室温に戻すことを特徴とする請求項1記載の餅種食品の製造法。 The method for producing a grape seed food according to claim 1, further comprising freezing or refrigeration after the combination molding, and then returning to room temperature. 組み合わせ成型後に冷凍または冷蔵と室温に戻す工程を反復する請求項8記載の餅種食品の製造法。 The method for producing a potato food according to claim 8, wherein the step of freezing or refrigeration and returning to room temperature is repeated after combination molding. 低甘味糖を含む糖類を加えて調製してなる餅状生地。 A cocoon-shaped dough prepared by adding sugars including low-sweet sugar.
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JPH08242784A (en) * 1995-03-09 1996-09-24 Riken Vitamin Co Ltd Starchy food, its aging prevention method and aging preventing agent
JPH0984524A (en) * 1995-09-26 1997-03-31 Matsutani Chem Ind Ltd Rice cake sweet
JPH09107899A (en) * 1995-10-20 1997-04-28 Towa Chem Ind Co Ltd Composition for preventing rice cakes from aging and production of rice cakes using the same

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JPH0873504A (en) * 1994-06-27 1996-03-19 Hayashibara Biochem Lab Inc Nonreducing sugar, its production, and its use
JPH08242784A (en) * 1995-03-09 1996-09-24 Riken Vitamin Co Ltd Starchy food, its aging prevention method and aging preventing agent
JPH0984524A (en) * 1995-09-26 1997-03-31 Matsutani Chem Ind Ltd Rice cake sweet
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