JPS649222A - Highly conductive poly-2,5-thienylenevinylene composition - Google Patents

Highly conductive poly-2,5-thienylenevinylene composition

Info

Publication number
JPS649222A
JPS649222A JP30786386A JP30786386A JPS649222A JP S649222 A JPS649222 A JP S649222A JP 30786386 A JP30786386 A JP 30786386A JP 30786386 A JP30786386 A JP 30786386A JP S649222 A JPS649222 A JP S649222A
Authority
JP
Japan
Prior art keywords
thienylenevinylene
alkoxy group
poly
dopant
elimination
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP30786386A
Other languages
Japanese (ja)
Other versions
JPH048446B2 (en
Inventor
Kazumoto Murase
Toshihiro Onishi
Masanobu Noguchi
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
National Institute of Advanced Industrial Science and Technology AIST
Original Assignee
Agency of Industrial Science and Technology
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Agency of Industrial Science and Technology filed Critical Agency of Industrial Science and Technology
Priority to JP30786386A priority Critical patent/JPS649222A/en
Priority to US07/013,628 priority patent/US5053166A/en
Priority to DE19873704411 priority patent/DE3704411A1/en
Priority to DE3743443A priority patent/DE3743443C2/de
Publication of JPS649222A publication Critical patent/JPS649222A/en
Publication of JPH048446B2 publication Critical patent/JPH048446B2/ja
Granted legal-status Critical Current

Links

Landscapes

  • Polyoxymethylene Polymers And Polymers With Carbon-To-Carbon Bonds (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

PURPOSE:To obtain the title compsn. contg. poly-2,5-thienylenevinylene obtd. by treating a specified polymer precursor for the elimination of its alkoxy group and a dopant as essential components, which is very excellent in conductivity and useful as electric and electronic materials. CONSTITUTION:A 2,5-thienylenedimethylene bissulfonium salt monomer of formula I (where R2-3 are 1-10C hydrocarbon groups; A<-> is a halogen, OH, COOH, BF4 or a counter ion such as perchlorate ion) is submitted to a condensation polymn., and the polymer has its side chain substd. with an alkoxy group (OR1 group) to give a polythienylenevinylene polymer precursor consisting of recurring units of formula II (where R1 is R2). The product is then treated for the elimination of its alkoxy group by heating, for example, at 0-400 deg.C for 1min-10hr to give poly-2,5-thienylenevinylene A. The component A is then doped by adding thereto a dopant B such as an electron acceptor (a), e.g., a halogen compd. or a Lewis acid or an electron donor (b), e.g., an alkali metal or a quat. NH4 salt.
JP30786386A 1986-02-18 1986-12-25 Highly conductive poly-2,5-thienylenevinylene composition Granted JPS649222A (en)

Priority Applications (4)

Application Number Priority Date Filing Date Title
JP30786386A JPS649222A (en) 1986-09-18 1986-12-25 Highly conductive poly-2,5-thienylenevinylene composition
US07/013,628 US5053166A (en) 1986-02-18 1987-02-11 Hetero-arylene vinylene polymer and highly conductive composition thereof
DE19873704411 DE3704411A1 (en) 1986-02-18 1987-02-12 STRETCHED POLY (HETEROARYLENVINYLENE) MOLDING, PRECURSOR POLYMER USED IN ITS PRODUCTION, METHOD FOR THE PRODUCTION THEREOF AND THE CONTAINING HIGH CONDUCTIVITY THEREOF
DE3743443A DE3743443C2 (en) 1986-09-18 1987-02-12

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP21797086 1986-09-18
JP30786386A JPS649222A (en) 1986-09-18 1986-12-25 Highly conductive poly-2,5-thienylenevinylene composition

Publications (2)

Publication Number Publication Date
JPS649222A true JPS649222A (en) 1989-01-12
JPH048446B2 JPH048446B2 (en) 1992-02-17

Family

ID=26522320

Family Applications (1)

Application Number Title Priority Date Filing Date
JP30786386A Granted JPS649222A (en) 1986-02-18 1986-12-25 Highly conductive poly-2,5-thienylenevinylene composition

Country Status (1)

Country Link
JP (1) JPS649222A (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5622784A (en) * 1986-01-21 1997-04-22 Seiko Epson Corporation Synthetic resin ophthalmic lens having an inorganic coating
US5759643A (en) * 1987-01-16 1998-06-02 Seiko Epson Corporation Polarizing plate and method of production
US5783299A (en) * 1986-01-21 1998-07-21 Seiko Epson Corporation Polarizer plate with anti-stain layer
US6942924B2 (en) 2001-10-31 2005-09-13 Chemat Technology, Inc. Radiation-curable anti-reflective coating system

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS61148231A (en) * 1984-11-17 1986-07-05 ザ　ブリテイツシユ　ペトロリユ−ム　コムパニ−　ピ−エルシ− Novel conductive polymer

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS61148231A (en) * 1984-11-17 1986-07-05 ザ　ブリテイツシユ　ペトロリユ−ム　コムパニ−　ピ−エルシ− Novel conductive polymer

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5622784A (en) * 1986-01-21 1997-04-22 Seiko Epson Corporation Synthetic resin ophthalmic lens having an inorganic coating
US5783299A (en) * 1986-01-21 1998-07-21 Seiko Epson Corporation Polarizer plate with anti-stain layer
US5759643A (en) * 1987-01-16 1998-06-02 Seiko Epson Corporation Polarizing plate and method of production
US6942924B2 (en) 2001-10-31 2005-09-13 Chemat Technology, Inc. Radiation-curable anti-reflective coating system

Also Published As

Publication number Publication date
JPH048446B2 (en) 1992-02-17

Similar Documents

Publication Publication Date Title
Murase et al. Highly conducting poly (phenylene vinylene) derivatives via soluble precursor process
Satoh et al. Dependences of electrical and mechanical properties of conducting polypyrrole films on conditions of electrochemical polymerization in an aqueous medium
Zagórska et al. Chemical synthesis and characterization of soluble poly (4, 4′-dialkyl-2, 2′-bithiophenes)
PT85579B (en) PROCESS FOR THE PREPARATION OF ELECTRICALLY CONDUCTIVE SOLUVE POLYMERS
Hou et al. The effect of different lithium salts on conductivity of comb-like polymer electrolyte with chelating functional group
ES8401512A1 (en) Liquid compositions for treating solid surfaces with transparent coatings and varnishes, application method and coatings obtained.
KR840008670A (en) Conductive composition
Schlenoff et al. Elimination of ion-exchanged precursors to poly (phenylenevinylene)
JPS649222A (en) Highly conductive poly-2,5-thienylenevinylene composition
GB951521A (en) Organosilicon polymers
WO1998003499A1 (en) Novel self-acid-doped highly conducting polythiophenes
US5053166A (en) Hetero-arylene vinylene polymer and highly conductive composition thereof
US4868284A (en) Process for producing stretched molded articles of conjugated polymers and highly conductive compositions of said polymers
KR100242220B1 (en) Electrically conductive alternating copolymer and method of preparing such a copolymer
US5407987A (en) Polycyclic aromatic group - pendant polysilanes and conductive polymers derived therefrom
Gillespie et al. ANTIMONY TETRAFLUORIDE MONOFLUOROSULPHATE: PREPARATION, PROPERTIES, AND STRUCTURE
OA07446A (en) Tetrakis trialkyl siloxy alanates of alkali metals, their solid solutions with plastics and their applications in the constitution of conductive elements for electrochemical generators.
US4755326A (en) Electron-donor dopant, method of improving conductivity of polymers by doping therewith, and a polymer so treated
ES8307267A1 (en) Process for making polytetramethyleneadipamide.
Kulszewicz-Bajer Spectroscopic properties of polyaniline protonated with poly (alkylene phosphates)
EP0023596A1 (en) Process for preparing electrically conductive polyphenylenes and their use in electrical engineering and in rendering plastics antistatic
JPS5736168A (en) Electrical insulating coating compound having heat resistance
Webster Aryl migration under electron impact conditions
Levon et al. Electrically conducting compound synthesized from lignin and sulfur
EP0037924B1 (en) Process for preparing electrically conducting polycondensates and their use in electrical engineering and as antistatic additives for plastics

Legal Events

Date Code Title Description
EXPY Cancellation because of completion of term