JPS6485944A - Production of 1,3-dihydroxyacetone - Google Patents

Production of 1,3-dihydroxyacetone

Info

Publication number
JPS6485944A
JPS6485944A JP62242747A JP24274787A JPS6485944A JP S6485944 A JPS6485944 A JP S6485944A JP 62242747 A JP62242747 A JP 62242747A JP 24274787 A JP24274787 A JP 24274787A JP S6485944 A JPS6485944 A JP S6485944A
Authority
JP
Japan
Prior art keywords
solvent
reaction
formaldehyde
compound
filtered
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP62242747A
Other languages
Japanese (ja)
Other versions
JPH0796515B2 (en
Inventor
Yasuhiko Tanaka
Hiroyasu Saito
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nippon Kasei Chemical Co Ltd
Nihon Kasei Co Ltd
Original Assignee
Nippon Kasei Chemical Co Ltd
Nihon Kasei Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nippon Kasei Chemical Co Ltd, Nihon Kasei Co Ltd filed Critical Nippon Kasei Chemical Co Ltd
Priority to JP62242747A priority Critical patent/JPH0796515B2/en
Publication of JPS6485944A publication Critical patent/JPS6485944A/en
Publication of JPH0796515B2 publication Critical patent/JPH0796515B2/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

PURPOSE:To readily separate, recover and reuse a catalytic component and selectively obtain the titled compound useful as a raw material for medicines and cosmetics in high yield, by using a specific compound capable of exhibiting high catalytic activity and a base as a catalyst and carrying out addition reaction of formaldehyde. CONSTITUTION:Formaldehyde is subjected to addition reaction in a solvent, such as dioxane, while being heated at 50-100 deg.C and stirred using a substance prepared by substituting chloride ions of a quaternary thiazolium salt which is a reaction product of a crosslinked chloromethylpolystyrene with a thiazole compound, such as 5-(2-hydroxyethyl)-4-methylthiazole, with cyanide ions and a base, such as triethylamine, in an equimolar amount. The reaction product is then filtered to separate residues consisting of quaternary thiazolium salt particles. The obtained filtrate is subsequently distilled under reduced pressure to distill away the solvent and afford the aimed compound. The filtered residues are directly or, as necessary, washed with an organic solvent, such as methanol, and reused as a catalytic component in the next reaction.
JP62242747A 1987-09-29 1987-09-29 Method for producing 1,3-dihydroxyacetone Expired - Lifetime JPH0796515B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP62242747A JPH0796515B2 (en) 1987-09-29 1987-09-29 Method for producing 1,3-dihydroxyacetone

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP62242747A JPH0796515B2 (en) 1987-09-29 1987-09-29 Method for producing 1,3-dihydroxyacetone

Publications (2)

Publication Number Publication Date
JPS6485944A true JPS6485944A (en) 1989-03-30
JPH0796515B2 JPH0796515B2 (en) 1995-10-18

Family

ID=17093660

Family Applications (1)

Application Number Title Priority Date Filing Date
JP62242747A Expired - Lifetime JPH0796515B2 (en) 1987-09-29 1987-09-29 Method for producing 1,3-dihydroxyacetone

Country Status (1)

Country Link
JP (1) JPH0796515B2 (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0306215A2 (en) * 1987-08-29 1989-03-08 BP Chemicals Limited Synthesis of glycerol from formaldehyde
US5087761A (en) * 1989-07-26 1992-02-11 Bp Chemicals Limited Synthesis of alpha-hydroxy ketones

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0306215A2 (en) * 1987-08-29 1989-03-08 BP Chemicals Limited Synthesis of glycerol from formaldehyde
US5097089A (en) * 1987-08-29 1992-03-17 Bp Chemicals Limited Synthesis of glycerol from formaldehyde
US5087761A (en) * 1989-07-26 1992-02-11 Bp Chemicals Limited Synthesis of alpha-hydroxy ketones

Also Published As

Publication number Publication date
JPH0796515B2 (en) 1995-10-18

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