JPS6469B2 - - Google Patents
Info
- Publication number
- JPS6469B2 JPS6469B2 JP7888581A JP7888581A JPS6469B2 JP S6469 B2 JPS6469 B2 JP S6469B2 JP 7888581 A JP7888581 A JP 7888581A JP 7888581 A JP7888581 A JP 7888581A JP S6469 B2 JPS6469 B2 JP S6469B2
- Authority
- JP
- Japan
- Prior art keywords
- water
- weight
- potassium carbonate
- fire extinguishing
- extinguishing agent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 claims description 34
- 239000003795 chemical substances by application Substances 0.000 claims description 26
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims description 18
- 229910000027 potassium carbonate Inorganic materials 0.000 claims description 17
- 239000004094 surface-active agent Substances 0.000 claims description 13
- 125000003709 fluoroalkyl group Chemical group 0.000 claims description 9
- 239000000243 solution Substances 0.000 claims description 9
- MFKRHJVUCZRDTF-UHFFFAOYSA-N 3-methoxy-3-methylbutan-1-ol Chemical compound COC(C)(C)CCO MFKRHJVUCZRDTF-UHFFFAOYSA-N 0.000 claims description 7
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims description 7
- 239000007864 aqueous solution Substances 0.000 claims description 7
- 239000004202 carbamide Substances 0.000 claims description 7
- POAOYUHQDCAZBD-UHFFFAOYSA-N 2-butoxyethanol Chemical compound CCCCOCCO POAOYUHQDCAZBD-UHFFFAOYSA-N 0.000 claims description 5
- 229920001451 polypropylene glycol Polymers 0.000 claims 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 35
- 230000000694 effects Effects 0.000 description 10
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 8
- 229910052731 fluorine Inorganic materials 0.000 description 8
- 239000011737 fluorine Substances 0.000 description 8
- -1 alkali metal salts Chemical class 0.000 description 7
- 239000007788 liquid Substances 0.000 description 7
- 238000002156 mixing Methods 0.000 description 6
- 239000007921 spray Substances 0.000 description 6
- 150000001875 compounds Chemical class 0.000 description 4
- 239000006260 foam Substances 0.000 description 4
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 3
- 239000000654 additive Substances 0.000 description 3
- 229910052783 alkali metal Inorganic materials 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- TYJJADVDDVDEDZ-UHFFFAOYSA-M potassium hydrogencarbonate Chemical compound [K+].OC([O-])=O TYJJADVDDVDEDZ-UHFFFAOYSA-M 0.000 description 3
- 238000001556 precipitation Methods 0.000 description 3
- 238000000926 separation method Methods 0.000 description 3
- 238000005507 spraying Methods 0.000 description 3
- JSGVZVOGOQILFM-UHFFFAOYSA-N 3-methoxy-1-butanol Chemical compound COC(C)CCO JSGVZVOGOQILFM-UHFFFAOYSA-N 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- 239000008186 active pharmaceutical agent Substances 0.000 description 2
- 230000000996 additive effect Effects 0.000 description 2
- 238000002485 combustion reaction Methods 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 238000007710 freezing Methods 0.000 description 2
- 230000008014 freezing Effects 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 239000011550 stock solution Substances 0.000 description 2
- 150000001298 alcohols Chemical class 0.000 description 1
- 229910052910 alkali metal silicate Inorganic materials 0.000 description 1
- 229940037003 alum Drugs 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 238000007865 diluting Methods 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- CBOIHMRHGLHBPB-UHFFFAOYSA-N hydroxymethyl Chemical compound O[CH2] CBOIHMRHGLHBPB-UHFFFAOYSA-N 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 239000011259 mixed solution Substances 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 238000005185 salting out Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 229920003169 water-soluble polymer Polymers 0.000 description 1
Landscapes
- Fire-Extinguishing Compositions (AREA)
Description
本発明は、消防隊等の防水する消火水に数％程
度の割合で混入することにより消火効果を高める
消火強化薬剤として用いられる消火薬剤に関す
る。
一般に、火災時における延焼面積１m2当りの放
水量は約1.5トンと云われており、このため、延
焼をまぬがれたにもかかわらず、中・高層住宅、
マンシヨン等の建築物では階下に位置する世帯が
著しい水損被害を被るという事態を生じており、
近項においては水損被害が焼損被害を上回るよう
な状況に至つている。
そこで、水損被害を極力抑えるために、水に特
殊な消火薬剤を混入し、できるだけ少量の水で消
火効果を上げることが考えられている。
このような消火薬剤としては、火災中における
燃焼の連鎖反応を阻害する負触媒効果を有すると
共に防災作用も持つアルカリ金属塩が知られてお
り、例えば、35重量％程度の炭酸カリウム
K2CO3を水に溶解した小型消火器用の強火液消
火剤が存在する。そこで、この強火液消火剤を原
液としてそのまま数％程度の割合で水に混入して
放水することが考えられるが、消火水に占める炭
酸カリウムの割合が少なすぎるため、水だけを放
水した場合と比較してそれほど大きな消火効果は
得られない。
一方、上記の炭酸カリウム高濃度水溶液にフツ
素系界面活性剤が混入できれば、液体の拡散およ
び浸透性が高まつて燃焼面を良く濡らし、更にハ
ロゲンの化学作用も加つて消火効果が高められ
る。しかしながら、炭酸カリウム高濃度水溶液中
に単にフツ素系界面活性剤を添加したのでは、塩
析現象により界面活性剤が析出して溶解しない。
そこで、従来、パーフルオロアルキルスルホネ
ート或はパーフルオロアルキルカーボネイトの如
きフツ素系化合物を２重量％程度添加してフツ素
系界面活性剤を炭酸カリウム水溶液に溶解させた
消火薬剤が提案されている（特開昭51−150900）。
しかし、この消火薬剤はパーフルオロアルキル
スルホネート等のフツ素系化合物の添加でフツ素
系界面活性剤を溶解したとしても、溶液中に占め
る炭酸カリウムの割合は３重量％程度と少なく、
このような消火薬剤を水に数％の割合で混入して
放水したとしても、水損被害を低減するに定る消
火効果は期待できない。
更に、炭酸、燐酸等のアルカリ金属塩、みよう
ばん、硅酸アルカリ塩等の無機塩を多量に添加し
た消火薬剤を原液にすることも考えられるが、水
に希釈した状態で充分な消火効果を得ようとする
には、アルカリ金属塩及び無機塩の溶解飽和域を
越える量を混入する必要があり、消火原液中に不
溶解成分が折出沈殿し、安定した水損抑制用の消
火薬剤原液が得られないという状況にある。
ところで、近年において、泡消火剤用の添加剤
として、フルオロアルキル基及び水可溶基を有す
るフツ素系界面活性剤が開発され（特開昭55−
52768）、ユニダインDS−301（登録商標）として
市販されている。
そこで、本願発明者等は、ユニダインDS−301
として知られた水溶性高分子界面活性剤を混入し
た水損抑制用の消火薬剤原液を作り出すことがで
きないかという点に着目して幾多の実験を繰り返
えした結果、炭酸カリウムの他に、Ａ火災（一般
火災）に対し消火効果があり且つ凍結温度を下げ
ることでも知られている尿素（NH2）2COを加え、
更に、プロピレングリコール、３−メチル−３−
メトキシブタノール、エチレングリコールモノブ
チエーテルを溶剤とすることによりフルオロアル
キル基及び水可溶基を有する水溶性高分子界面活
性剤を炭酸カリウム水溶液に完全に解溶させるこ
とに成功し、本発明を完成したものである。
すなわち、本発明は、炭酸カリウムと尿素の水
溶液中に、プロピレングリコール、３−メチル−
３−メトキシブタノール成びエチレングリコール
モノブチルエーテルの各々、又はプロピレングリ
コール及び３−メチル−３−メトキシブタノール
の各々を媒介として、フルオロアルキル基及び水
溶性基を有する水溶性高分子界面活性剤を混入し
て完全溶解させた消火薬剤を要旨とする。
更に詳細に述べるならば、本発明は、全溶液中
に占める炭酸カリウムK2CO3の割合が10重量％
以上であり、且つ炭酸カリウムK2CO3と尿素
（NH2）2COとの合計割合が20重量％以上であり、
両者の合計割合を最大30重量％程度とし、水に希
釈した場合の消火効果を充分に高めるものであ
る。
また、上記の炭酸カリウムK2CO3と尿素
（NH2）2COの水溶液に、１〜３重量％のフルオロ
アルキル基及び水可溶性基を有する水溶性高分子
界面活性剤（ユニダインDS−301）を完全に溶解
させるため、プロピレングリコールCH3CH
（OH）CH2OHの割合を５〜20重量％、３−メチ
ル３−メトキシブタノール
The present invention relates to a fire extinguishing agent that is used as a fire extinguishing agent that enhances the fire extinguishing effect by mixing it into waterproof fire extinguishing water for fire brigade and the like at a ratio of about several percent. In general, it is said that the amount of water sprayed per 1 m2 of area where the fire spreads is approximately 1.5 tons.
In buildings such as condominiums, households located on the floors below are experiencing significant water damage.
In recent years, we have reached a situation where water damage exceeds fire damage. Therefore, in order to minimize water damage, it is being considered to mix special fire extinguishing agents into water to increase the fire extinguishing effect using as little water as possible. As such extinguishing agents, alkali metal salts are known that have a negative catalytic effect that inhibits the chain reaction of combustion during a fire, and also have a disaster prevention effect.For example, about 35% by weight of potassium carbonate
There is a strong liquid fire extinguishing agent for small fire extinguishers that has K 2 CO 3 dissolved in water. Therefore, it is possible to mix this strong liquid fire extinguishing agent into water at a ratio of several percent as a raw solution and spray it with water, but since the proportion of potassium carbonate in the fire extinguishing water is too small, it is difficult to spray water alone. In comparison, the fire extinguishing effect is not that great. On the other hand, if a fluorine-based surfactant can be mixed into the above-mentioned aqueous solution of high concentration of potassium carbonate, the diffusion and permeability of the liquid will be increased to wet the combustion surface well, and the chemical action of the halogen will also be added to enhance the fire extinguishing effect. However, if a fluorine-containing surfactant is simply added to a highly concentrated potassium carbonate aqueous solution, the surfactant will precipitate due to a salting-out phenomenon and will not dissolve. Therefore, a fire extinguishing agent has been proposed in which a fluorine-based surfactant is dissolved in an aqueous potassium carbonate solution by adding about 2% by weight of a fluorine-based compound such as perfluoroalkyl sulfonate or perfluoroalkyl carbonate ( (Japanese Patent Application Publication No. 51-150900). However, even if this fire extinguishing agent dissolves the fluorine-based surfactant by adding a fluorine-based compound such as perfluoroalkyl sulfonate, the proportion of potassium carbonate in the solution is as small as about 3% by weight.
Even if a few percent of such fire extinguishing agent is mixed with water and water is sprayed, no fire extinguishing effect can be expected to reduce water damage. Furthermore, it is possible to use a undiluted extinguishing agent containing a large amount of alkali metal salts such as carbonic acid or phosphoric acid, or inorganic salts such as alum or alkali silicate; In order to achieve this, it is necessary to mix the alkali metal salts and inorganic salts in an amount exceeding the dissolution saturation range, and insoluble components are precipitated in the extinguishing solution, resulting in a stable extinguishing agent solution for suppressing water damage. The situation is that it is not possible to obtain. Incidentally, in recent years, fluorine-based surfactants having a fluoroalkyl group and a water-soluble group have been developed as additives for fire extinguishing foam (Japanese Patent Application Laid-Open No. 1983-1999).
52768) and is commercially available as Unidyne DS-301 (registered trademark). Therefore, the inventors of the present application have developed the Unidyne DS-301
After repeated numerous experiments, we focused on whether it was possible to create a stock solution of fire extinguishing agent for water damage control that contained a water-soluble polymeric surfactant known as potassium carbonate. Adding urea (NH 2 ) 2 CO, which has an extinguishing effect on A fires (general fires) and is also known to lower freezing temperatures,
Furthermore, propylene glycol, 3-methyl-3-
By using methoxybutanol and ethylene glycol monobutyether as solvents, we succeeded in completely dissolving a water-soluble polymeric surfactant having a fluoroalkyl group and a water-soluble group in an aqueous potassium carbonate solution, and completed the present invention. This is what I did. That is, in the present invention, propylene glycol, 3-methyl-
A water-soluble polymeric surfactant having a fluoroalkyl group and a water-soluble group is mixed through each of 3-methoxybutanol and ethylene glycol monobutyl ether, or each of propylene glycol and 3-methyl-3-methoxybutanol. The main point is to use extinguishing agents that have been completely dissolved. More specifically, in the present invention, the proportion of potassium carbonate K 2 CO 3 in the whole solution is 10% by weight.
or more, and the total proportion of potassium carbonate K 2 CO 3 and urea (NH 2 ) 2 CO is 20% by weight or more,
The total proportion of both is about 30% by weight at most, which sufficiently increases the fire extinguishing effect when diluted with water. In addition, a water-soluble polymeric surfactant (Unidyne DS - 301) having 1 to 3% by weight of a fluoroalkyl group and a water-soluble group is added to the above aqueous solution of potassium carbonate K 2 CO 3 and urea (NH 2 ) 2 CO. To completely dissolve the propylene glycol CH 3 CH
The proportion of (OH) CH2OH is 5-20% by weight, 3-methyl 3-methoxybutanol
【式】の割合又は３−メチ
ル−３−メトキシブタノールとエチレングリコー
ルモノブチルエーテル
Ratio of [formula] or 3-methyl-3-methoxybutanol and ethylene glycol monobutyl ether
【式】の合計割合を0.5〜
3.0重量％として添加するようにしたものである。
ここで、フルオロアルキル基及び水可溶性基を
有する水溶性高分子界面活性剤（ユニダインDS
−301）は、フルオロアルキル基及び水可溶性基
中のフツ素含有量が10重量％以上であり、25℃に
おいて水に少なくとも0.1重量％溶解することが
でき、且つ、0.1〜5.0重量％水溶液の表面張力が
25℃で50dyn／cmを越えない平均分子量5000以上
の水溶性高分子化合物であり、泡消火剤、特にア
ルコール、ケトン、エステルアルデヒド等の水溶
可燃性液体用泡消火剤に、泡の極性有機液体への
溶解性を減少する効果を持たせ、安定な泡を形成
するための添加剤として開発されている。尚、フ
ルオロアルキル基及び水可溶性基を有する高分子
化合物は50重量％であり、残りの50重量％がイソ
プロピルアルコール等の溶剤が占める。
次に実施例を示して本発明を詳しく説明する。
実施例１〜４および比較例１〜３
全溶液中に占める炭酸カリウムの割合を10重量
％以上、且つ炭酸カリウムと尿素との合計割合が
20重量％以上とした場合について、混合溶液に分
離、沈殿を起さない臨界混合割合として次表１の
混合割合を得た。The total proportion of [Formula] is 0.5 to 3.0% by weight. Here, a water-soluble polymeric surfactant having a fluoroalkyl group and a water-soluble group (Unidyne DS
-301) has a fluorine content in the fluoroalkyl group and water-soluble group of 10% by weight or more, can be dissolved in water at 25°C by at least 0.1% by weight, and can be dissolved in a 0.1 to 5.0% by weight aqueous solution. surface tension
It is a water-soluble polymer compound with an average molecular weight of 5000 or more that does not exceed 50 dyn/cm at 25℃, and is used as a foam fire extinguisher, especially for water-soluble flammable liquids such as alcohols, ketones, and ester aldehydes. It has been developed as an additive to reduce the solubility of foam and form stable foam. The polymer compound having a fluoroalkyl group and a water-soluble group accounts for 50% by weight, and the remaining 50% by weight is occupied by a solvent such as isopropyl alcohol. Next, the present invention will be explained in detail with reference to Examples. Examples 1 to 4 and Comparative Examples 1 to 3 The proportion of potassium carbonate in the total solution is 10% by weight or more, and the total proportion of potassium carbonate and urea is
In the case of 20% by weight or more, the mixing ratios shown in Table 1 below were obtained as critical mixing ratios that do not cause separation or precipitation in the mixed solution.
【表】
一方、次表−２は炭酸カリウムの水溶液にユニ
ダインDS−301を添加した比較例１〜３を示して
おり、比較例１〜３のいずれについても、混合液
は混濁し、静置することにより分離、沈殿を起
し、ユニダインDS−301は炭酸カリウム溶液中で
は完全に溶解しない。[Table] On the other hand, Table 2 below shows Comparative Examples 1 to 3 in which Unidyne DS-301 was added to an aqueous solution of potassium carbonate. This causes separation and precipitation, and Unidyne DS-301 does not completely dissolve in potassium carbonate solution.
【表】
実施例１〜４で得られた本発明の消火薬剤は、
いずれも黄褐色の完全に透明な液体であり、−20
℃に於いても分離、沈殿及び凍結はみられず、安
定した性状を示した。
実施例 ５
全溶液中に占める炭酸カリウムの割合を10重量
％以上、且つ炭酸カリウムと尿素の合計割合を20
重量％以上とし、添加剤としてエチレングリコー
ルモノブチルエーテルを含めない場合の臨界混合
割合を次表−３のように得た。[Table] The fire extinguishing agents of the present invention obtained in Examples 1 to 4 are:
Both are yellow-brown, completely transparent liquids, −20
Even at ℃, no separation, precipitation, or freezing was observed, indicating stable properties. Example 5 The proportion of potassium carbonate in the whole solution is 10% by weight or more, and the total proportion of potassium carbonate and urea is 20% by weight.
The critical mixing ratio was obtained as shown in Table 3 below, when the amount was % by weight or more and ethylene glycol monobutyl ether was not included as an additive.
【表】
この実施例５の混合液も、実施例１〜４の混合
液と同じ性状を示した。
実施例１〜５で得られた本発明の消火薬剤を３
〜６％のプレミツクス水溶液とし、木材火災模型
に棒状又は噴霧状に放水したところ、単なる水の
放水と比較して数段の消火性能の向上がみられ、
且つ再燃を抑制することができるという効果が確
認された。
次に、本発明の消火薬剤の用途を説明する。以
上の説明で明らかにされた消火薬剤は、消火原液
としてタンク等に保管し、使用時には加圧送水装
置により圧送される水に混合器を使つて３〜６％
の割合で混合させ、放水ノズルから放水させる。
この場合、延焼面積１m2当りに必要とする水量
は本発明の消火薬剤の混合により大幅に低減でき
るので、消防隊の使用する消防用ノズルの口径を
小さくして放水量を少くするようにする。
その結果、従来と同等の消火効果を得るに必要
とする放水量は大幅に低減され、建築物あるいは
家財に及ぼす水損被害を消火能力を損うことなく
大幅に低減できる。
また本発明の消火薬剤の他の使用法として、建
築物の水系消火設備を利用して消火水に消火薬剤
を混入し、その結果、従来と同等の消火能力を得
るための放射水量は大幅に低減できるので、消火
栓ノズル、スプリンクラーヘツド、水噴霧ヘツド
を小型小流量化して水損の抑制を図り、これに伴
つて送水装置及び配管設備が小型化にできて設備
費用の低減をももたらす。
更に、一般家庭用として火災時に本発明の消火
薬剤を水に混合して火源に放水する方法、あるい
は本発明の消火薬剤を数倍にうすめるか或いはそ
のまま小型消火器又は自動消火器の消火薬剤とし
て使用することも可能である。[Table] The liquid mixture of Example 5 also showed the same properties as the liquid mixtures of Examples 1 to 4. The fire extinguishing agent of the present invention obtained in Examples 1 to 5 was
When using a ~6% Premix aqueous solution and spraying water on a wooden fire model in the form of a stick or spray, it was found that the fire extinguishing performance was improved several times compared to simply spraying water.
Moreover, the effect of suppressing flare-up was confirmed. Next, the uses of the fire extinguishing agent of the present invention will be explained. The extinguishing agent clarified in the above explanation is stored in a tank etc. as an extinguishing stock solution, and when used, it is mixed with water pumped by a pressurized water supply device using a mixer to mix 3 to 6%.
Mix at the following ratio and spray water from the water spray nozzle. In this case, the amount of water required per square meter of fire spread area can be significantly reduced by mixing the extinguishing agent of the present invention, so the diameter of the fire nozzle used by the fire brigade should be made smaller to reduce the amount of water sprayed. . As a result, the amount of water required to achieve the same fire extinguishing effect as before is significantly reduced, and water damage to buildings or household goods can be significantly reduced without impairing the fire extinguishing ability. Another method of using the fire extinguishing agent of the present invention is to mix the fire extinguishing agent into fire extinguishing water using a water-based fire extinguishing system in a building. Therefore, water loss can be suppressed by making fire hydrant nozzles, sprinkler heads, and water spray heads smaller and smaller in flow rate, thereby reducing the size of water supply devices and piping equipment, which also results in a reduction in equipment costs. Furthermore, for general household use, there is a method of mixing the extinguishing agent of the present invention with water and spraying it on the fire source in the event of a fire, or diluting the extinguishing agent of the present invention several times, or using it as an extinguishing agent of a small fire extinguisher or an automatic fire extinguisher. It is also possible to use it as
Claims (1)
ングリコール、３−メチル−３−メトキシブタノ
ール及びエチレングリコールモノブチルエーテル
の各々、又はプロピレングリコール及び３−メチ
ル−３−メトキシブタノールの各々を媒介とし
て、フルオロアルキル基及び水溶性基を有する水
溶性高分子界面活性剤を混入したことを特徴とす
る消火薬剤。 ２ 全溶液中に占める炭酸カリウムの割合が10重
量％以上で、且つ炭酸カリウムと尿素の合計割合
が20重量％以上である特許請求の範囲第１項記載
の消火薬剤。 ３ 全溶液中に占めるポリプロピレングリコール
の割合が５〜20重量％、３−メチル−３−メトキ
シブタノールの割合又は３−メチル−３−メトキ
シブタノールとエチレングリコールモノブチルエ
ーテルとの合計割合が0.5〜3.0重量％となるよう
に添加し、フルオロアルキルキ基及び水溶性基を
有する水溶性高分子界面活性剤を1.0〜3.0重量％
混入して完全に溶解した特許請求の範囲第２項記
載の消火薬剤。[Scope of Claims] 1 Each of propylene glycol, 3-methyl-3-methoxybutanol and ethylene glycol monobutyl ether, or each of propylene glycol and 3-methyl-3-methoxybutanol is added to an aqueous solution of potassium carbonate and urea. A fire extinguishing agent characterized by containing a water-soluble polymeric surfactant having a fluoroalkyl group and a water-soluble group as a mediator. 2. The extinguishing agent according to claim 1, wherein the proportion of potassium carbonate in the whole solution is 10% by weight or more, and the total proportion of potassium carbonate and urea is 20% by weight or more. 3 The proportion of polypropylene glycol in the whole solution is 5 to 20% by weight, and the proportion of 3-methyl-3-methoxybutanol or the total proportion of 3-methyl-3-methoxybutanol and ethylene glycol monobutyl ether is 0.5 to 3.0% by weight. %, and 1.0 to 3.0% by weight of a water-soluble polymeric surfactant having a fluoroalkyl group and a water-soluble group.
The extinguishing agent according to claim 2, which is mixed and completely dissolved.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP7888581A JPS57192573A (en) | 1981-05-25 | 1981-05-25 | Fire fighting agent |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP7888581A JPS57192573A (en) | 1981-05-25 | 1981-05-25 | Fire fighting agent |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS57192573A JPS57192573A (en) | 1982-11-26 |
| JPS6469B2 true JPS6469B2 (en) | 1989-01-05 |
Family
ID=13674260
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP7888581A Granted JPS57192573A (en) | 1981-05-25 | 1981-05-25 | Fire fighting agent |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS57192573A (en) |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2005075436A2 (en) | 2004-02-05 | 2005-08-18 | Probiodrug Ag | Novel inhibitors of glutaminyl cyclase |
| WO2008055945A1 (en) | 2006-11-09 | 2008-05-15 | Probiodrug Ag | 3-hydr0xy-1,5-dihydr0-pyrr0l-2-one derivatives as inhibitors of glutaminyl cyclase for the treatment of ulcer, cancer and other diseases |
| WO2008065141A1 (en) | 2006-11-30 | 2008-06-05 | Probiodrug Ag | Novel inhibitors of glutaminyl cyclase |
| WO2008104580A1 (en) | 2007-03-01 | 2008-09-04 | Probiodrug Ag | New use of glutaminyl cyclase inhibitors |
| WO2011110613A1 (en) | 2010-03-10 | 2011-09-15 | Probiodrug Ag | Heterocyclic inhibitors of glutaminyl cyclase (qc, ec 2.3.2.5) |
| WO2011131748A2 (en) | 2010-04-21 | 2011-10-27 | Probiodrug Ag | Novel inhibitors |
| WO2012123563A1 (en) | 2011-03-16 | 2012-09-20 | Probiodrug Ag | Benz imidazole derivatives as inhibitors of glutaminyl cyclase |
| EP3461819A1 (en) | 2017-09-29 | 2019-04-03 | Probiodrug AG | Inhibitors of glutaminyl cyclase |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH062166B2 (en) * | 1985-03-11 | 1994-01-12 | 横浜市 | Aerosol fire extinguisher |
| JPH08257157A (en) * | 1995-03-24 | 1996-10-08 | Ebisu Kagaku Kenkyusho:Kk | Fire extinguishing hand-grenade |
| CN103476463B (en) * | 2011-12-15 | 2015-11-25 | 中岛浩幸 | The preparation method of petroleum fire extinguishing chemical and throwing type fire annihilator |
| GB2497820B (en) * | 2012-02-23 | 2013-11-27 | Wcm Products Ltd | Fire-extiguishing compositions and apparatus |
-
1981
- 1981-05-25 JP JP7888581A patent/JPS57192573A/en active Granted
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2005075436A2 (en) | 2004-02-05 | 2005-08-18 | Probiodrug Ag | Novel inhibitors of glutaminyl cyclase |
| WO2008055945A1 (en) | 2006-11-09 | 2008-05-15 | Probiodrug Ag | 3-hydr0xy-1,5-dihydr0-pyrr0l-2-one derivatives as inhibitors of glutaminyl cyclase for the treatment of ulcer, cancer and other diseases |
| WO2008065141A1 (en) | 2006-11-30 | 2008-06-05 | Probiodrug Ag | Novel inhibitors of glutaminyl cyclase |
| WO2008104580A1 (en) | 2007-03-01 | 2008-09-04 | Probiodrug Ag | New use of glutaminyl cyclase inhibitors |
| WO2011110613A1 (en) | 2010-03-10 | 2011-09-15 | Probiodrug Ag | Heterocyclic inhibitors of glutaminyl cyclase (qc, ec 2.3.2.5) |
| WO2011131748A2 (en) | 2010-04-21 | 2011-10-27 | Probiodrug Ag | Novel inhibitors |
| WO2012123563A1 (en) | 2011-03-16 | 2012-09-20 | Probiodrug Ag | Benz imidazole derivatives as inhibitors of glutaminyl cyclase |
| EP3461819A1 (en) | 2017-09-29 | 2019-04-03 | Probiodrug AG | Inhibitors of glutaminyl cyclase |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS57192573A (en) | 1982-11-26 |
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