JPS646274A - Synthesis of 1h-pyrazolo(1.5-b)-1,2,4-triazole derivative - Google Patents
Synthesis of 1h-pyrazolo(1.5-b)-1,2,4-triazole derivativeInfo
- Publication number
- JPS646274A JPS646274A JP7625287A JP7625287A JPS646274A JP S646274 A JPS646274 A JP S646274A JP 7625287 A JP7625287 A JP 7625287A JP 7625287 A JP7625287 A JP 7625287A JP S646274 A JPS646274 A JP S646274A
- Authority
- JP
- Japan
- Prior art keywords
- formula
- compound
- oxime
- pyrazolo
- triazole derivative
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C7/00—Multicolour photographic processes or agents therefor; Regeneration of such processing agents; Photosensitive materials for multicolour processes
- G03C7/30—Colour processes using colour-coupling substances; Materials therefor; Preparing or processing such materials
- G03C7/32—Colour coupling substances
- G03C7/36—Couplers containing compounds with active methylene groups
- G03C7/38—Couplers containing compounds with active methylene groups in rings
- G03C7/381—Heterocyclic compounds
- G03C7/382—Heterocyclic compounds with two heterocyclic rings
- G03C7/3825—Heterocyclic compounds with two heterocyclic rings the nuclei containing only nitrogen as hetero atoms
- G03C7/3835—Heterocyclic compounds with two heterocyclic rings the nuclei containing only nitrogen as hetero atoms four nitrogen atoms
Abstract
PURPOSE:To obtain the title compound which is useful as a coupler for silver salt color photography in low costs in high yield with reduced by-products by subjecting an N-pyrazolylamide oxime bearing a substituent in the 4-position to ring closure reaction. CONSTITUTION:An N-pyrazolylamide oxime of formula I (R1 is H, substituent; R2 is substitutent other than aryloxy and amino groups; R3 is H, alkyl, aryl, heteroring) such as an amide oxime of formula II is subjected to dehydrative ring closure reaction, preferably in the presence of a base using a suitable dehydrating agent to give 1H-pyrazolo[1,5-b]-1,2,4-triazole derivative of formula III such as a compound of formula IV. The compound of formula I is obtained by allowing a compound of formula I to react with an orthoester or imidate followed by reaction with hydroxylamine.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP62076252A JPH07100705B2 (en) | 1986-11-19 | 1987-03-31 | Method for synthesizing 1H-pyrazolo [1,5-b-1,2,4-triazole derivative |
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP27623286 | 1986-11-19 | ||
JP61-276232 | 1986-11-19 | ||
JP62076252A JPH07100705B2 (en) | 1986-11-19 | 1987-03-31 | Method for synthesizing 1H-pyrazolo [1,5-b-1,2,4-triazole derivative |
Related Child Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP6196303A Division JP2563231B2 (en) | 1986-11-19 | 1994-07-29 | Method for synthesizing 1H-pyrazolo [1,5-b] -1,2,4-triazole derivative |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS646274A true JPS646274A (en) | 1989-01-10 |
JPH07100705B2 JPH07100705B2 (en) | 1995-11-01 |
Family
ID=26417410
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP62076252A Expired - Fee Related JPH07100705B2 (en) | 1986-11-19 | 1987-03-31 | Method for synthesizing 1H-pyrazolo [1,5-b-1,2,4-triazole derivative |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPH07100705B2 (en) |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS60172982A (en) * | 1984-02-16 | 1985-09-06 | Fuji Photo Film Co Ltd | Pyrazolo(1,5-b)(1,2,4)triazole derivative |
JPS60197688A (en) * | 1984-03-22 | 1985-10-07 | Fuji Photo Film Co Ltd | Preparation of pyrazolo(1,5-b)(1,2,4)triazole derivative |
-
1987
- 1987-03-31 JP JP62076252A patent/JPH07100705B2/en not_active Expired - Fee Related
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS60172982A (en) * | 1984-02-16 | 1985-09-06 | Fuji Photo Film Co Ltd | Pyrazolo(1,5-b)(1,2,4)triazole derivative |
JPS60197688A (en) * | 1984-03-22 | 1985-10-07 | Fuji Photo Film Co Ltd | Preparation of pyrazolo(1,5-b)(1,2,4)triazole derivative |
Also Published As
Publication number | Publication date |
---|---|
JPH07100705B2 (en) | 1995-11-01 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
LAPS | Cancellation because of no payment of annual fees |