JPS645832B2 - - Google Patents
Info
- Publication number
- JPS645832B2 JPS645832B2 JP7406282A JP7406282A JPS645832B2 JP S645832 B2 JPS645832 B2 JP S645832B2 JP 7406282 A JP7406282 A JP 7406282A JP 7406282 A JP7406282 A JP 7406282A JP S645832 B2 JPS645832 B2 JP S645832B2
- Authority
- JP
- Japan
- Prior art keywords
- water
- transfer
- soluble support
- contact angle
- coating film
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000011248 coating agent Substances 0.000 claims description 24
- 238000000576 coating method Methods 0.000 claims description 24
- 238000007639 printing Methods 0.000 claims description 22
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 18
- 238000010023 transfer printing Methods 0.000 claims description 17
- 238000000034 method Methods 0.000 claims description 11
- 238000005299 abrasion Methods 0.000 claims description 9
- 239000003973 paint Substances 0.000 claims description 8
- 229920003002 synthetic resin Polymers 0.000 claims description 8
- 239000000057 synthetic resin Substances 0.000 claims description 8
- 101150014174 calm gene Proteins 0.000 claims description 2
- 238000005507 spraying Methods 0.000 claims description 2
- 239000000976 ink Substances 0.000 description 17
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 9
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 9
- 239000000463 material Substances 0.000 description 9
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 6
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 5
- 239000004372 Polyvinyl alcohol Substances 0.000 description 4
- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 description 4
- 230000000704 physical effect Effects 0.000 description 4
- 229920002451 polyvinyl alcohol Polymers 0.000 description 4
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 3
- 239000004579 marble Substances 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 238000004062 sedimentation Methods 0.000 description 3
- SVONRAPFKPVNKG-UHFFFAOYSA-N 2-ethoxyethyl acetate Chemical compound CCOCCOC(C)=O SVONRAPFKPVNKG-UHFFFAOYSA-N 0.000 description 2
- 239000004593 Epoxy Substances 0.000 description 2
- NTIZESTWPVYFNL-UHFFFAOYSA-N Methyl isobutyl ketone Chemical compound CC(C)CC(C)=O NTIZESTWPVYFNL-UHFFFAOYSA-N 0.000 description 2
- 230000005856 abnormality Effects 0.000 description 2
- 239000001913 cellulose Substances 0.000 description 2
- 229920002678 cellulose Polymers 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 229920000728 polyester Polymers 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 239000007921 spray Substances 0.000 description 2
- 230000002087 whitening effect Effects 0.000 description 2
- 239000002023 wood Substances 0.000 description 2
- ZNQVEEAIQZEUHB-UHFFFAOYSA-N 2-ethoxyethanol Chemical compound CCOCCO ZNQVEEAIQZEUHB-UHFFFAOYSA-N 0.000 description 1
- 239000004925 Acrylic resin Substances 0.000 description 1
- 229920000178 Acrylic resin Polymers 0.000 description 1
- 229920001817 Agar Polymers 0.000 description 1
- 241001465754 Metazoa Species 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- 239000004721 Polyphenylene oxide Substances 0.000 description 1
- XBDQKXXYIPTUBI-UHFFFAOYSA-M Propionate Chemical compound CCC([O-])=O XBDQKXXYIPTUBI-UHFFFAOYSA-M 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- 230000002159 abnormal effect Effects 0.000 description 1
- KXKVLQRXCPHEJC-UHFFFAOYSA-N acetic acid trimethyl ester Natural products COC(C)=O KXKVLQRXCPHEJC-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- 239000008272 agar Substances 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- -1 etc. Chemical compound 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 230000001678 irradiating effect Effects 0.000 description 1
- GJRQTCIYDGXPES-UHFFFAOYSA-N iso-butyl acetate Natural products CC(C)COC(C)=O GJRQTCIYDGXPES-UHFFFAOYSA-N 0.000 description 1
- FGKJLKRYENPLQH-UHFFFAOYSA-M isocaproate Chemical compound CC(C)CCC([O-])=O FGKJLKRYENPLQH-UHFFFAOYSA-M 0.000 description 1
- OQAGVSWESNCJJT-UHFFFAOYSA-N isovaleric acid methyl ester Natural products COC(=O)CC(C)C OQAGVSWESNCJJT-UHFFFAOYSA-N 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 230000000873 masking effect Effects 0.000 description 1
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 1
- 229920001225 polyester resin Polymers 0.000 description 1
- 239000004645 polyester resin Substances 0.000 description 1
- 239000004926 polymethyl methacrylate Substances 0.000 description 1
- 229920006380 polyphenylene oxide Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 229920005992 thermoplastic resin Polymers 0.000 description 1
- 229920001187 thermosetting polymer Polymers 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/025—Duplicating or marking methods; Sheet materials for use therein by transferring ink from the master sheet
Landscapes
- Decoration By Transfer Pictures (AREA)
- Printing Methods (AREA)
Description
【発明の詳細な説明】
この発明は、水の接触角50〜80゜の塗膜を形成
可能な印刷インキ又は塗料でシート状の水溶性支
持体上にパターンを付した後、水溶性支持体を水
面に浮かべた状態で合成樹脂製の被転写物品を水
溶性支持体に押圧しながら全部又は一部を沈降さ
せて液圧により転写して印刷する方法に関する。
上記液圧転写印刷法は、合成樹脂成形品等にお
け立体面（凹凸面）に対する印刷方法として特公
昭52−41682号公報において提案されている。し
かしこの方法の場合、印刷インキ等の被転写面に
対する付着性（密着性）が十分でなく、得られた
転写印刷面はテーピングテスト（いわゆるゴバン
目テスト）に耐え得ないものが多く、当然、その
まま自動車内・外装品の如く高度の耐候性、耐摩
耗性等を要求される物品への適用は困難であつ
た。
この発明は、上記にかんがみて、転写印刷面の
付着性が良好で、さらには、高度の耐候性、耐摩
耗性を要求される物品への適用も可能である液圧
転写印刷法を提供することを目的とする。
この発明の液圧転写印刷法は、水の接触角50〜
80゜の塗膜を形成可能な印刷インキ又は塗料でパ
ターンを付した水溶性支持体を水面に浮かべて合
成樹脂製の被転写物品へ液圧により転写して印刷
するに際して、転写直前に水溶性支持体のパター
ン付着面又は被転写面にSP値７〜11cal１／２・cm
−３／２のシンナーを散布し、さらに転写後、耐候
性及び耐摩耗性に優れた水の接触角50〜80゜の透
明塗膜を転写印刷面上に形成することにより上記
目的を達成する。
以下、この発明の方法を、図例に基づいて説明
する。
(1) 水の接触角（以下単に「接触角」という）50
〜80゜の塗膜を形成可能な印刷インキ又は塗料
１でシート状の水溶性支持体２上にパターンを
付する。
上記において印刷インキ又は塗料（以下「印
刷インキ等」と略す）として接触角が50〜80゜
である塗膜を形成可能なものを使用するのは、
合成樹脂製の被転写物品に対する印刷インキ等
の付着性を良好とするためである（大部分の合
成樹脂成形品の接触角50〜80゜）。これらの印刷
インキ等の膜形成要素としては、諸物性に優れ
伸び性を有するウレタン系が望ましいが、アク
リル系、ポリエステル系、エポキシ系又はこれ
らの混合系であつてもよい。水溶性支持体の材
料としては、ポリビニルアルコール（PVAL）、
ニカワ、澱粉、セルローズ、寒天等水に素早く
溶解するものなら合成、天然特に限定されな
い。パターンの水溶性支持体上への付し方は、
通常の凸板・凹板印刷等に限られずマスキング
法等を用いた塗装によつてもよい。パターンの
態様は、木目・花柄・大理石・動物・漫画の主
人公・幾何学模様等何れでも適用できる。
(2) 上記(1)で得た水溶性支持体２を第１図に示す
ように水面Ｗ上に浮かべた状態で合成樹脂製の
被転写物品３を水溶性支持体２に押圧しながら
全部又は一部を沈降させて液圧により転写す
る。この際、転写直前に水溶性支持体２のパタ
ーンは付着面又は被転写物品３の被転写面に
SP値（溶解パラメータ）７〜11cal１／２・cm
−３／２のシンナーを散布しておいて印刷インキ
等１を軟化させる。この軟化作用が印刷インキ
等の被転写面に対する付着性を良好にすると推
定される。
シンナーのSP値７〜11cal１／２・cm−３／２は、
印刷インキ等と相溶性有する範囲内を示す。具
体的には、芳香族としてトルエン、キシレン
等、エステルとして酢酸メチル、酢酸エチル、
酢酸イソブチル等、ケトンとしてMEK、
MIBK等、セロソルブ（商品名：UCC社製造）
として酢酸セロソルブ、ブチルセロソルブ等を
例示できるが通常これらを混合して用いる。被
転写物品の合成樹脂材料は接触角50〜80゜の
ABS、PC、PMMA、AS、PS、ポリフエニレ
ンオキシド等の熱可塑性樹脂又はPF、UP、
EP等の熱硬化性樹脂が好ましいが、PE、PP
のような表面活性の小さな樹脂でもプライマー
処理又はプラズマ等による表面活性化処理によ
り適用可能となる。
(3) 上記(2)で転写後、被転写物品３に残存してい
る水溶性支持体を洗い落し乾燥させ、耐候性及
び耐摩耗性に優れた接触角50〜80゜の透明塗膜
５を転写印刷面１上に形成する（第２図参照）。
ここで透明塗膜５における接触角が50〜80゜
であるのは、印刷インキ等で形成される塗膜の
接触角と近似させて転写印刷面に対する密着性
を向上させるためである。また、透明塗膜５の
形成材料としては、ポリウレタンが物性上一番
望ましいが、アクリル樹脂、ポリエステル樹脂
等でもよい。また、塗膜厚は５〜40μとする。
こうして合成樹脂製の被転写物品に付された転
写印刷面は、下記の実施例からも明らかなように
被転写面に対する密着性が良好であるとともに、
耐候性及び耐摩耗性に優れた透明塗膜で保護され
ているので苛酷な条件下で使用される自動車の内
外装品等にも適用できる。
次に、実施例を示すが、被転写物品及び試験項
目は下記の如くである。
＜被転写物品＞
第１実施例…ABS樹脂製自動車メータパネル
（横400×縦250×深さ100×板厚３mm）
第２実施例…ABS樹脂製自動車用メータパネ
ル（横300×縦200×深さ50×板厚３mm）
第３実施例…ABS樹脂製自動車メータパネル
（形状は第２実施例と同じ）
＜試験方法＞
(a) 耐摩耗性…テーパ摩耗試験機CS−10（テーパ
社(株)製造）を用いて荷重500ｇを与えながら速
度100rpmで試験片を回転させ摩耗の程度をチ
エツクした。
(b) 耐湿性…40℃×95％RHの雰囲気中に試験片
を400h放置後テーピング剥離試験を行ない剥
離の有無をチエツクした。
(c) 耐光性…フエードメータ（スガ試験機(株)製
造）を用い試験片を800h紫外線照射後、テー
ピング剥離試験を行ない、剥離の有無をチエツ
クした。
(d) 耐酸性…0.1NH2SO4aq（室温）に試験片を
24h浸漬後、外観異常（ふくれ、白化等）の有
無を目視チエツクした。
(e) 耐アルカリ性…0.1NNaOHaq（室温）に試験
片を24h浸漬後、外観異常（ふくれ、白化等）
の有無を目視チエツクした。
＜第１実施例＞
二液型アクリルウレタンインキ（塗膜接触角
66゜）で木目パターンが印刷された水溶性支持体
（MW800のPVAL、厚さ10μm）を水面に浮かべ、
転写する直前に混合シンナー（トルエン、MEK、
MIBK、酢酸セロソルブ、酢酸エチルが当重量比
からなる）をスプレーで印刷面に散布し、前記被
転写物品を水溶性支持体に押圧しながらゆつくり
沈降させて（沈降速度100cm／min）十分に転写
後、被転写物品上の水溶性支持体の残滓を水で洗
い落して70℃×60min乾燥し、続いて二液型アク
リルウレタン塗料（塗膜接触角65゜）を転写印刷
面上に20μmの厚さに塗布して70℃×60min硬化
させて透明塗膜を形成した。得られた転写印刷面
は奇麗な木目パターンを示し、第１表に示すよう
な優れた諸物性を示した。
＜第２実施例＞
一液型アクリルウレタンインキ（接触角塗膜
64゜）で花柄パターンが印刷された水溶性支持体
（MW2000のPVAL、厚さ3μm）を水面に浮かべ、
転写する直前に混合シンナー（第１実施例と同
一）をスプレーで印刷面に散布し、前記被転写物
品を水溶性支持体に押圧しながらをゆつくりと沈
降させて（沈降速度150cm／min）十分に転写後、
被転写物品上の水溶性支持体の残滓を水で洗い落
して70℃×30min乾燥し、続いて２液型ポリエス
テルウレタン塗料（塗膜接触角61゜）を転写印刷
面上に15μmの厚さに塗布して70℃×60min硬化
させて透明塗膜を形成した。得られた転写印刷面
は奇麗な花柄パターンを示し、試験結果は第１実
施例と同様（第１表）であり、特に耐摩耗性は
700回でも異常なしであつた。
＜第３実施例＞
エポキシ系インキ（塗膜接触角68゜）で大理石
パターンが印刷された水溶性支持体（MW2000の
セルロース、厚さ5μm）を水面に浮かべ、転写す
る直前に混合シンナー（トルエン、MEK、酢酸
エチルが当重量比からなる）をスプレーで印刷面
に散布し、前記被転写物品を水溶性支持体に押圧
しながらをゆつくり沈降させて（沈降速度100
cm／min）十分に転写後、被転写物品上の水溶性
支持体の残滓を水で洗い落して70℃×45min乾燥
し、続いて二液型アクリルウレタン塗料（塗膜接
触角63゜）を転写印刷面上に20μmの厚さに塗布し
て70℃×60mm硬化させて透明塗膜を形成た。得ら
れた転写印刷面は奇麗な大理石パターンを示し、
試験結果は第１実施例と同様（第１表）であり、
特に耐摩耗性は800回でも異常なしであつた。
なお、いずれの実施例においてもシンナー散布
せずに転写した場合は、転写印刷面の被転写面に
対する付着性が良好でなく、透明塗膜で保護して
も当初から各物性試験に耐えうるものではなかつ
た。
【表】DETAILED DESCRIPTION OF THE INVENTION This invention involves applying a pattern to a sheet-like water-soluble support with a printing ink or paint capable of forming a coating film with a water contact angle of 50 to 80°, and then applying a pattern to the water-soluble support. The present invention relates to a method of printing by transferring a synthetic resin article floating on the water surface by pressing it against a water-soluble support, allowing all or part of the article to settle, and then transferring and printing using hydraulic pressure. The above-mentioned hydraulic transfer printing method has been proposed in Japanese Patent Publication No. 41682/1982 as a printing method for three-dimensional surfaces (uneven surfaces) of synthetic resin molded products and the like. However, in the case of this method, the adhesion (adhesion) of the printing ink etc. to the transferred surface is insufficient, and the resulting transfer printed surface often cannot withstand the taping test (so-called goblin test). It has been difficult to apply it as it is to articles that require a high degree of weather resistance, abrasion resistance, etc., such as interior and exterior parts of automobiles. In view of the above, the present invention provides a hydraulic transfer printing method that has good adhesion on the transfer printing surface and can also be applied to articles that require high weather resistance and abrasion resistance. The purpose is to The hydraulic transfer printing method of this invention has a water contact angle of 50~
When a water-soluble support patterned with a printing ink or paint capable of forming an 80° coating film is floated on the water surface and transferred to a synthetic resin transfer object using hydraulic pressure, the water-soluble support is patterned immediately before transfer. Spray thinner with an SP value of 7 to 11 cal1/2 cm -3/2 on the pattern-attached surface or transfer surface of the support, and after transfer, apply a water contact angle of 50 to 80, which has excellent weather resistance and abrasion resistance. The above object is achieved by forming a transparent coating film of .degree. on the transfer printing surface. Hereinafter, the method of the present invention will be explained based on illustrated examples. (1) Water contact angle (hereinafter simply referred to as "contact angle")50
A pattern is applied onto a sheet-shaped water-soluble support 2 using a printing ink or coating material 1 capable of forming a coating film of up to 80°. In the above, the printing ink or paint (hereinafter abbreviated as "printing ink, etc.") that can form a coating film with a contact angle of 50 to 80 degrees is used because:
This is to improve the adhesion of printing ink, etc. to the transfer object made of synthetic resin (the contact angle of most synthetic resin molded objects is 50 to 80 degrees). The film-forming element for these printing inks and the like is preferably a urethane-based material having excellent physical properties and stretchability, but it may also be an acrylic-based material, a polyester-based material, an epoxy-based material, or a mixture thereof. Materials for the water-soluble support include polyvinyl alcohol (PVAL),
There are no particular limitations on synthetic or natural materials as long as they dissolve quickly in water, such as glue, starch, cellulose, agar, etc. How to apply the pattern on the water-soluble support
It is not limited to ordinary convex or concave printing, but may also be painted using a masking method or the like. Any form of pattern can be applied, such as wood grain, floral patterns, marble, animals, cartoon characters, geometric patterns, etc. (2) With the water-soluble support 2 obtained in (1) above floating on the water surface W as shown in FIG. Alternatively, a portion may be settled and transferred using hydraulic pressure. At this time, immediately before transfer, the pattern of the water-soluble support 2 is applied to the adhering surface or the transfer surface of the transfer object 3.
Spray thinner with an SP value (dissolution parameter) of 7 to 11 cal 1/2 cm -3/2 to soften the printing ink, etc. 1. It is presumed that this softening effect improves the adhesion of printing ink and the like to the transfer surface. The SP value of the thinner is 7 to 11cal1/2·cm-3/2, which is within the range of compatibility with printing ink, etc. Specifically, aromatics include toluene, xylene, etc., esters include methyl acetate, ethyl acetate,
MEK as a ketone, such as isobutyl acetate,
MIBK, etc., cellosolve (product name: manufactured by UCC)
Examples include cellosolve acetate and cellosolve butyl, but usually a mixture of these is used. The synthetic resin material of the transferred article has a contact angle of 50 to 80°.
Thermoplastic resins such as ABS, PC, PMMA, AS, PS, polyphenylene oxide, PF, UP,
Thermosetting resins such as EP are preferred, but PE, PP
Even resins with low surface activity can be applied by primer treatment or surface activation treatment using plasma or the like. (3) After the transfer in (2) above, the water-soluble support remaining on the transferred article 3 is washed off and dried to form a transparent coating film 5 with a contact angle of 50 to 80° with excellent weather resistance and abrasion resistance. is formed on the transfer printing surface 1 (see FIG. 2). The reason why the contact angle of the transparent coating film 5 is 50 to 80° is to approximate the contact angle of a coating film formed with printing ink or the like, thereby improving adhesion to the transfer printing surface. Further, as the material for forming the transparent coating film 5, polyurethane is most desirable in terms of physical properties, but acrylic resin, polyester resin, etc. may also be used. Further, the coating film thickness is 5 to 40μ. The transfer printing surface applied to the synthetic resin transfer object in this way has good adhesion to the transfer surface, as is clear from the examples below, and
Since it is protected by a transparent coating with excellent weather resistance and abrasion resistance, it can also be applied to interior and exterior parts of automobiles used under harsh conditions. Next, Examples will be shown, and the transferred articles and test items are as follows. <Articles to be transferred> First example... ABS resin automobile meter panel (width 400 x length 250 x depth 100 x plate thickness 3 mm) Second example... ABS resin automobile meter panel (width 300 x length 200 x depth 50 x plate thickness 3 mm) 3rd example: ABS resin automobile meter panel (shape is the same as the 2nd example) <Test method> (a) Abrasion resistance: Taper abrasion tester CS-10 (Taper Co., Ltd.) The degree of wear was checked by rotating the test piece at a speed of 100 rpm while applying a load of 500 g. (b) Moisture resistance: After leaving the test piece in an atmosphere of 40°C x 95% RH for 400 hours, a taping peel test was conducted to check for peeling. (c) Light resistance: After irradiating the test piece with ultraviolet rays for 800 hours using a fade meter (manufactured by Suga Test Instruments Co., Ltd.), a taping peel test was conducted to check for peeling. (d) Acid resistance…Place the test piece in 0.1NH 2 SO 4 aq (room temperature).
After 24 hours of immersion, the samples were visually checked for appearance abnormalities (blisters, whitening, etc.). (e) Alkali resistance...Abnormal appearance (blister, whitening, etc.) after immersing the test piece in 0.1N NaOHaq (room temperature) for 24 hours.
A visual check was made to see if there was any. <First example> Two-component acrylic urethane ink (coating film contact angle
A water-soluble support (PVAL with M W 800, thickness 10 μm) with a wood grain pattern printed at an angle of 66°) was floated on the water surface.
Mix thinner (toluene, MEK,
MIBK, cellosolve acetate, and ethyl acetate (consisting of equivalent weight ratios) are sprayed onto the printing surface, and the transferred article is slowly allowed to settle while being pressed against a water-soluble support (sedimentation speed: 100 cm/min). After the transfer, the residue of the water-soluble support on the transferred article is washed off with water and dried at 70°C for 60 minutes, and then a two-component acrylic urethane paint (film contact angle 65°) is applied to the transfer printing surface with a thickness of 20 μm. A transparent coating film was formed by coating the film to a thickness of 100°C and curing it at 70°C for 60 minutes. The resulting transfer printed surface showed a beautiful grain pattern and exhibited excellent physical properties as shown in Table 1. <Second Example> One-component acrylic urethane ink (contact angle coating film)
A water-soluble support (PVAL of M W 2000, thickness 3 μm) with a floral pattern printed at an angle of 64°) was floated on the water surface.
Immediately before transfer, mixed thinner (same as in the first example) was sprayed onto the printing surface, and the transferred article was slowly allowed to settle while being pressed against a water-soluble support (sedimentation speed: 150 cm/min). After sufficient transfer,
The residue of the water-soluble support on the transferred article was washed off with water and dried at 70°C for 30 minutes, and then a two-component polyester urethane paint (film contact angle 61°) was applied to a thickness of 15 μm on the transfer printing surface. A transparent coating film was formed by applying the coating to a substrate and curing it at 70°C for 60 minutes. The obtained transfer printing surface showed a beautiful floral pattern, and the test results were the same as in the first example (Table 1), especially in terms of abrasion resistance.
There were no abnormalities even after 700 cycles. <Third Example> A water-soluble support (cellulose of M W 2000, thickness 5 μm) on which a marble pattern was printed with epoxy ink (contact angle of coating film 68°) was floated on the water surface and mixed with thinner immediately before transfer. (composed of toluene, MEK, and ethyl acetate in the same weight ratio) was sprayed onto the printing surface, and the transferred article was slowly allowed to settle while being pressed against a water-soluble support (sedimentation rate: 100%).
cm/min) After sufficient transfer, the residue of the water-soluble support on the transferred article is washed off with water and dried at 70°C for 45 minutes, and then a two-component acrylic urethane paint (film contact angle 63°) is applied. It was applied to a thickness of 20 μm on the transfer printing surface and cured at 70° C. x 60 mm to form a transparent coating film. The resulting transfer printing surface shows a beautiful marble pattern,
The test results are the same as in the first example (Table 1),
In particular, the wear resistance remained unchanged even after 800 cycles. In addition, in any of the examples, when the transfer was performed without spraying thinner, the adhesion of the transfer printing surface to the transferred surface was not good, and even if it was protected with a transparent coating, it could withstand each physical property test from the beginning. It wasn't. 【table】
第１図は本発明の方法を示す概略端面図、第２
図は本発明の方法で得た転写印刷面の構成を示す
拡大断面図である。
１……印刷インキ又は塗料（印刷インキ等）、
２……水溶性支持体、３……被転写物品、５……
透明塗膜、Ｗ……水面。
FIG. 1 is a schematic end view showing the method of the invention;
The figure is an enlarged sectional view showing the structure of a transfer printing surface obtained by the method of the present invention. 1...Printing ink or paint (printing ink, etc.),
2...Water-soluble support, 3...Transferred article, 5...
Transparent coating film, W...Water surface.
Claims (1)
な印刷インキ又は塗料でシート状の水溶性支持体
上にパターンを付した後、該水溶性支持体を水面
に浮かべた状態で合成樹脂製の被転写物品を前記
水溶性支持体に押圧しながら全部又は一部を沈降
させて液圧により転写して印刷する方法におい
て、 転写直前に水溶性支持体のパターン付着面又は
被転写物品の被転写面にSP値７〜11cal1/2・cm
３／２のシンナーを散布し、さらに転写後耐候性及
び耐摩耗性に優れた水の接触角50〜80゜の透明塗
膜を転写印刷面上に形成することを特徴とする液
圧転写印刷法。[Scope of Claims] 1. After applying a pattern on a sheet-like water-soluble support with a printing ink or paint capable of forming a coating film having a water contact angle of 50 to 80°, the water-soluble support is In a method in which a transfer object made of synthetic resin is pressed against the water-soluble support while floating on the water surface, all or part of it settles and is transferred and printed using hydraulic pressure. SP value 7 to 11 cal1/2 cm on the pattern attachment surface or the transfer surface of the transfer object
Hydraulic transfer printing characterized by spraying 3/2 thinner and further forming a transparent coating film with a water contact angle of 50 to 80 degrees with excellent weather resistance and abrasion resistance on the transfer printing surface after transfer. Law.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP7406282A JPS58191187A (en) | 1982-04-30 | 1982-04-30 | Liquid pressure transfer printing method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP7406282A JPS58191187A (en) | 1982-04-30 | 1982-04-30 | Liquid pressure transfer printing method |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS58191187A JPS58191187A (en) | 1983-11-08 |
| JPS645832B2 true JPS645832B2 (en) | 1989-02-01 |
Family
ID=13536327
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP7406282A Granted JPS58191187A (en) | 1982-04-30 | 1982-04-30 | Liquid pressure transfer printing method |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS58191187A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102700343A (en) * | 2012-05-14 | 2012-10-03 | 华南理工大学 | Water transfer printing method for decorative plate of plant fiber molding wall |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NL1002760C2 (en) * | 1996-04-02 | 1997-10-03 | New Impression B V I O | Transfer printing system for three dimensional object |
| GB2342071A (en) * | 1998-10-01 | 2000-04-05 | Hamilton Hargreaves | Printing method and apparatus |
| TWI382934B (en) | 2003-10-22 | 2013-01-21 | Kuraray Co | Hydraulic transfer method,sheet for hydraulic transfer and base film for hydraulic transfer |
| EP2105319A1 (en) * | 2008-03-28 | 2009-09-30 | Tsung-Chun Chou | Method for printing the surface of a chair base by water transfer printing and the chair base structure |
| CN104149511A (en) * | 2014-06-27 | 2014-11-19 | 桐城市福润包装材料有限公司 | Water-transfer printing technology |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5431405A (en) * | 1977-08-15 | 1979-03-08 | Lion Corp | Dispersing agent for coal in oil containing dialkylsulfosuccinic ester salt |
| JPS6058718B2 (en) * | 1977-08-19 | 1985-12-21 | 大日本印刷株式会社 | Curved surface printing method |
| JPS5841752B2 (en) * | 1978-09-07 | 1983-09-14 | 日本合成化学工業株式会社 | Transfer printing method |
| JPS5841753B2 (en) * | 1978-09-09 | 1983-09-14 | 日本合成化学工業株式会社 | Transfer printing method |
| JPS55148190A (en) * | 1979-05-07 | 1980-11-18 | Toppan Printing Co Ltd | Printing method |
-
1982
- 1982-04-30 JP JP7406282A patent/JPS58191187A/en active Granted
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102700343A (en) * | 2012-05-14 | 2012-10-03 | 华南理工大学 | Water transfer printing method for decorative plate of plant fiber molding wall |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS58191187A (en) | 1983-11-08 |
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