JPS6451145A - Dehydrogenating catalyst - Google Patents
Dehydrogenating catalystInfo
- Publication number
- JPS6451145A JPS6451145A JP63187044A JP18704488A JPS6451145A JP S6451145 A JPS6451145 A JP S6451145A JP 63187044 A JP63187044 A JP 63187044A JP 18704488 A JP18704488 A JP 18704488A JP S6451145 A JPS6451145 A JP S6451145A
- Authority
- JP
- Japan
- Prior art keywords
- catalyst
- base material
- straight chain
- porous base
- dehydrogenation
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000003054 catalyst Substances 0.000 title abstract 4
- 238000006356 dehydrogenation reaction Methods 0.000 abstract 3
- 229910052738 indium Inorganic materials 0.000 abstract 2
- 239000000463 material Substances 0.000 abstract 2
- 229910052751 metal Inorganic materials 0.000 abstract 2
- 239000002184 metal Substances 0.000 abstract 2
- 229910052697 platinum Inorganic materials 0.000 abstract 2
- 229910052716 thallium Inorganic materials 0.000 abstract 2
- 229910052718 tin Inorganic materials 0.000 abstract 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 1
- 229910052784 alkaline earth metal Inorganic materials 0.000 abstract 1
- 150000001342 alkaline earth metals Chemical class 0.000 abstract 1
- 150000001336 alkenes Chemical class 0.000 abstract 1
- 238000000151 deposition Methods 0.000 abstract 1
- 239000008246 gaseous mixture Substances 0.000 abstract 1
- 229910052739 hydrogen Inorganic materials 0.000 abstract 1
- 239000001257 hydrogen Substances 0.000 abstract 1
- 239000007788 liquid Substances 0.000 abstract 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 abstract 1
- 239000012188 paraffin wax Substances 0.000 abstract 1
- 239000007787 solid Substances 0.000 abstract 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/56—Platinum group metals
- B01J23/62—Platinum group metals with gallium, indium, thallium, germanium, tin or lead
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
- C07C5/32—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen
- C07C5/327—Formation of non-aromatic carbon-to-carbon double bonds only
- C07C5/333—Catalytic processes
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
PURPOSE: To form a dehydrogenation catalyst by depositing 0.1 to 1 wt.% Pt, 0.1 to 1 wt.% Sn, 0.05 to 1 wt.% In, 0.01 to 1 wt.% Tl and 0.05 to 3.5 wt.% alkaline metal, etc., on a granular porous base material. CONSTITUTION: The dehydrogenation catalyst deposited with 0.1 to 1 wt.% Pt, 0.1 to 1 wt.% Sn, 0.05 to 1 wt.% In, 0.01 to 1 wt.% Tl and 0.05 to 3.5 wt.% alkaline metal or alkaline earth metal on the solid granular porous base material by specifying the weight of In to Tl to 0.3:1 to 6:1 and the weight ratio of Pt to (In+Tl) to 0.3:1 to 1.5 to 1 is formed. A gaseous mixture of hydrogen and straight chain paraffin having 9-20C per molecule is supplied to the catalyst at 400 to 500 deg.C, pressure 0.5 to 5 kg/cm<2> and liquid spatial velocity 5 to 100 hours<-1> , by which the straight chain olefin is recovered from the dehydrogenation product.
Applications Claiming Priority (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
IT21559/87A IT1222426B (en) | 1987-07-31 | 1987-07-31 | Dehydrogenation catalyst |
IT21559A/87 | 1987-07-31 | ||
IT23149/87A IT1223578B (en) | 1987-12-22 | 1987-12-22 | Dehydrogenation catalyst |
IT23149A/87 | 1987-12-22 |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS6451145A true JPS6451145A (en) | 1989-02-27 |
JP2594464B2 JP2594464B2 (en) | 1997-03-26 |
Family
ID=26327932
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP63187044A Expired - Lifetime JP2594464B2 (en) | 1987-07-31 | 1988-07-28 | Dehydrogenation catalyst |
Country Status (5)
Country | Link |
---|---|
JP (1) | JP2594464B2 (en) |
KR (1) | KR920010010B1 (en) |
CN (1) | CN1020418C (en) |
ES (1) | ES2008818A6 (en) |
IN (1) | IN171590B (en) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH01176452A (en) * | 1987-12-28 | 1989-07-12 | Uop Inc | Laminar catalyst particle for dehydrogenation reaction |
WO2017159371A1 (en) * | 2016-03-15 | 2017-09-21 | Jxエネルギー株式会社 | Conjugated diene production method |
JP2019137661A (en) * | 2018-02-15 | 2019-08-22 | Jxtgエネルギー株式会社 | Method for producing alkene |
Families Citing this family (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1088396C (en) * | 1997-11-28 | 2002-07-31 | 中国石油化工集团公司 | Ball-aluminium oxide containing lithium |
CN100434407C (en) * | 2006-01-19 | 2008-11-19 | 中国石油化工股份有限公司 | Method for preparing propylene by dehydrogenating propane |
CN102380426B (en) * | 2010-09-06 | 2013-06-05 | 中国石油化工股份有限公司 | Activation method of dehydrogenation catalyst |
CN102380425B (en) * | 2010-09-06 | 2013-07-24 | 中国石油化工股份有限公司 | Dehydrogenation catalyst reduction method |
CN102909094B (en) * | 2011-08-01 | 2014-12-31 | 中国石油化工股份有限公司 | Activation method for dehydrogenation catalyst at low temperature |
CN102909015B (en) * | 2011-08-01 | 2016-02-10 | 中国石油化工股份有限公司 | With the method containing CO gas reduction activation of dehydrogenation catalyst |
CN102909012B (en) * | 2011-08-01 | 2015-04-01 | 中国石油化工股份有限公司 | Activation method for dehydrogenation catalyst |
CN102910998B (en) * | 2011-08-01 | 2014-08-20 | 中国石油化工股份有限公司 | Dehydrogenation method for light alkanes |
CN102909096B (en) * | 2011-08-01 | 2014-12-31 | 中国石油化工股份有限公司 | Dehydrogenation catalyst activation method combining high-temperature reduction of short duration with low-temperature reduction |
CN103041808B (en) * | 2011-10-17 | 2015-04-01 | 中国石油化工股份有限公司 | Preparation method of dehydrogenation catalyst for simultaneously performing water vapor dechloridation and activation of catalyst |
CN103041807B (en) * | 2011-10-17 | 2015-04-01 | 中国石油化工股份有限公司 | Preparation method of dehydrogenation catalyst for firstly reducing and further vulcanizing during dechloridation process of water vapor |
-
1988
- 1988-07-11 IN IN487/MAS/88A patent/IN171590B/en unknown
- 1988-07-28 JP JP63187044A patent/JP2594464B2/en not_active Expired - Lifetime
- 1988-07-29 ES ES8802781A patent/ES2008818A6/en not_active Expired
- 1988-07-30 CN CN88104700A patent/CN1020418C/en not_active Expired - Fee Related
- 1988-08-01 KR KR1019880009787A patent/KR920010010B1/en active IP Right Grant
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH01176452A (en) * | 1987-12-28 | 1989-07-12 | Uop Inc | Laminar catalyst particle for dehydrogenation reaction |
WO2017159371A1 (en) * | 2016-03-15 | 2017-09-21 | Jxエネルギー株式会社 | Conjugated diene production method |
JP2019137661A (en) * | 2018-02-15 | 2019-08-22 | Jxtgエネルギー株式会社 | Method for producing alkene |
Also Published As
Publication number | Publication date |
---|---|
CN1033756A (en) | 1989-07-12 |
IN171590B (en) | 1992-11-21 |
KR920010010B1 (en) | 1992-11-10 |
ES2008818A6 (en) | 1989-08-01 |
JP2594464B2 (en) | 1997-03-26 |
CN1020418C (en) | 1993-05-05 |
KR890001634A (en) | 1989-03-28 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
JPS6451145A (en) | Dehydrogenating catalyst | |
CA2104822A1 (en) | Mgapso molecular sieve and use thereof | |
FR2412538A1 (en) | SILVER BASED CATALYZERS FOR ETHYLENE OXIDE PRODUCTION | |
EP0348902A3 (en) | Direct synthesis process for organohalohydrosilanes | |
KR830007724A (en) | Process for preparing catalyst composition for polymerizing ethylene | |
JPS6422349A (en) | Catalyst | |
JPS6451144A (en) | Catalyst for dehydrogenation reaction and its production | |
JPS52136103A (en) | Preparation of vinyl chloride | |
EP0128510A3 (en) | Process for producing difluoromethane | |
JPS52136104A (en) | Preparation of vinyl chloride | |
CA2101193A1 (en) | Novel process of alkoxy and aryloxy isothiocyanate preparation | |
CA2103116A1 (en) | Production of Para-Xylene by Selective Methylation of Toluene with Methyl Halides | |
JPS5651419A (en) | Hydrogenation of acetylene contained in hydrogen chloride gas, and preparation of 1,2-dichloroethane | |
JPS5499788A (en) | Cyclohexane dehydrogenation catalyst and dehydrogena tion reaction method | |
Shim et al. | Poly (U)-directed transamidation between adenosine 5'-phosphorimidazolide and 5'-phosphoadenosine 2'(3')-glycine ester | |
GB1494612A (en) | Preparation of phenylcyclohexane | |
MY100113A (en) | Hydrocarbon conversion catalyst containing a bifurcated alkali component | |
JPS6490038A (en) | High macro perforated catalyst for selective hydrogenation of olefin hydrocarbon | |
GB1467990A (en) | Continuous manufacture of n-alkylated arylamines | |
TH12377EX (en) | Catalyst hydrochlorination systems and processes for vinyl production Chloride from acetylene And hydrogen chloride, with this catalytic system | |
JPS5615216A (en) | Production of 1,3-dione | |
李卫星 et al. | ab initio CALCULATION ON CAPTODATIVE EFFECT OF GLYCINE RADICAL | |
CA2002243A1 (en) | Method for preparing p-isobutylstyrene | |
Barri | Chemical process and catalyst | |
JPS5572123A (en) | Preparation of styrene |