JPS644548B2 - - Google Patents
Info
- Publication number
- JPS644548B2 JPS644548B2 JP56145214A JP14521481A JPS644548B2 JP S644548 B2 JPS644548 B2 JP S644548B2 JP 56145214 A JP56145214 A JP 56145214A JP 14521481 A JP14521481 A JP 14521481A JP S644548 B2 JPS644548 B2 JP S644548B2
- Authority
- JP
- Japan
- Prior art keywords
- parts
- correction fluid
- correction
- imidazoline
- manufactured
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000002989 correction material Substances 0.000 claims description 15
- 150000002462 imidazolines Chemical class 0.000 claims description 12
- 239000003960 organic solvent Substances 0.000 claims description 6
- 239000011347 resin Substances 0.000 claims description 5
- 229920005989 resin Polymers 0.000 claims description 5
- 125000000217 alkyl group Chemical group 0.000 claims description 4
- 125000005313 fatty acid group Chemical group 0.000 claims description 3
- 239000012463 white pigment Substances 0.000 claims description 3
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 2
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 8
- UAEPNZWRGJTJPN-UHFFFAOYSA-N methylcyclohexane Chemical compound CC1CCCCC1 UAEPNZWRGJTJPN-UHFFFAOYSA-N 0.000 description 8
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N titanium dioxide Inorganic materials O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 7
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
- 239000011248 coating agent Substances 0.000 description 5
- 238000000576 coating method Methods 0.000 description 5
- 238000001035 drying Methods 0.000 description 5
- 229920000178 Acrylic resin Polymers 0.000 description 4
- 239000004925 Acrylic resin Substances 0.000 description 4
- 239000007788 liquid Substances 0.000 description 4
- GYNNXHKOJHMOHS-UHFFFAOYSA-N methyl-cycloheptane Natural products CC1CCCCCC1 GYNNXHKOJHMOHS-UHFFFAOYSA-N 0.000 description 4
- TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 4
- 239000003973 paint Substances 0.000 description 4
- 239000000049 pigment Substances 0.000 description 4
- SZIFAVKTNFCBPC-UHFFFAOYSA-N 2-chloroethanol Chemical compound OCCCl SZIFAVKTNFCBPC-UHFFFAOYSA-N 0.000 description 3
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 229930195733 hydrocarbon Natural products 0.000 description 3
- 150000002430 hydrocarbons Chemical class 0.000 description 3
- 239000003921 oil Substances 0.000 description 3
- 235000019198 oils Nutrition 0.000 description 3
- UOCLXMDMGBRAIB-UHFFFAOYSA-N 1,1,1-trichloroethane Chemical compound CC(Cl)(Cl)Cl UOCLXMDMGBRAIB-UHFFFAOYSA-N 0.000 description 2
- QPFMBZIOSGYJDE-UHFFFAOYSA-N 1,1,2,2-tetrachloroethane Chemical compound ClC(Cl)C(Cl)Cl QPFMBZIOSGYJDE-UHFFFAOYSA-N 0.000 description 2
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- 239000004215 Carbon black (E152) Substances 0.000 description 2
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 2
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- IIEWJVIFRVWJOD-UHFFFAOYSA-N ethylcyclohexane Chemical compound CCC1CCCCC1 IIEWJVIFRVWJOD-UHFFFAOYSA-N 0.000 description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 2
- MTNDZQHUAFNZQY-UHFFFAOYSA-N imidazoline Chemical compound C1CN=CN1 MTNDZQHUAFNZQY-UHFFFAOYSA-N 0.000 description 2
- 125000002636 imidazolinyl group Chemical group 0.000 description 2
- 239000002736 nonionic surfactant Substances 0.000 description 2
- XNLICIUVMPYHGG-UHFFFAOYSA-N pentan-2-one Chemical compound CCCC(C)=O XNLICIUVMPYHGG-UHFFFAOYSA-N 0.000 description 2
- 229940083254 peripheral vasodilators imidazoline derivative Drugs 0.000 description 2
- 239000004014 plasticizer Substances 0.000 description 2
- 230000001846 repelling effect Effects 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 239000008096 xylene Substances 0.000 description 2
- BGJSXRVXTHVRSN-UHFFFAOYSA-N 1,3,5-trioxane Chemical compound C1OCOCO1 BGJSXRVXTHVRSN-UHFFFAOYSA-N 0.000 description 1
- RYHBNJHYFVUHQT-UHFFFAOYSA-N 1,4-Dioxane Chemical compound C1COCCO1 RYHBNJHYFVUHQT-UHFFFAOYSA-N 0.000 description 1
- DURPTKYDGMDSBL-UHFFFAOYSA-N 1-butoxybutane Chemical compound CCCCOCCCC DURPTKYDGMDSBL-UHFFFAOYSA-N 0.000 description 1
- WBNCHVFLFSFIGK-UHFFFAOYSA-N 2-chlorooxirane Chemical class ClC1CO1 WBNCHVFLFSFIGK-UHFFFAOYSA-N 0.000 description 1
- FERIUCNNQQJTOY-UHFFFAOYSA-M Butyrate Chemical compound CCCC([O-])=O FERIUCNNQQJTOY-UHFFFAOYSA-M 0.000 description 1
- KMTRUDSVKNLOMY-UHFFFAOYSA-N Ethylene carbonate Chemical compound O=C1OCCO1 KMTRUDSVKNLOMY-UHFFFAOYSA-N 0.000 description 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 1
- 239000004606 Fillers/Extenders Substances 0.000 description 1
- 229920000297 Rayon Polymers 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 229920000180 alkyd Polymers 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 235000019864 coconut oil Nutrition 0.000 description 1
- 239000003240 coconut oil Substances 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 150000008282 halocarbons Chemical class 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- -1 hydroxyethyl group Chemical group 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- SOQBVABWOPYFQZ-UHFFFAOYSA-N oxygen(2-);titanium(4+) Chemical class [O-2].[O-2].[Ti+4] SOQBVABWOPYFQZ-UHFFFAOYSA-N 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 239000004645 polyester resin Substances 0.000 description 1
- 229920001225 polyester resin Polymers 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 238000004062 sedimentation Methods 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 125000001424 substituent group Chemical group 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D10/00—Correcting fluids, e.g. fluid media for correction of typographical errors by coating
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Paints Or Removers (AREA)
Description
【発明の詳細な説明】
本発明は、修正液に関し、更に詳しくは、修正
個所の塗膜を水性インキ使用の万年筆、サインペ
ンなどにより再筆記可能にするとともに再筆記し
た筆跡の乾燥性に優れた塗膜が得られるようにな
した修正液に関するものである。DETAILED DESCRIPTION OF THE INVENTION The present invention relates to a correction fluid, and more specifically, the present invention relates to a correction fluid that enables rewriting of the paint film of a correction area with a fountain pen, felt-tip pen, etc. using water-based ink, and has excellent drying properties for rewritten handwriting. This invention relates to a correction fluid that allows a coating film to be obtained.
従来、油性の修正液により修正した個所は、疎
水性を呈しているため、水性インキ使用の万年
筆、サインペンなどにより再筆記した場合、水性
インキがはじかれてしまい再筆記が困難あるいは
再筆記できたとしても筆跡の乾燥が悪いという問
題を有していた。 Conventionally, areas that have been corrected with oil-based correction fluid are hydrophobic, so when rewriting with a fountain pen, felt-tip pen, etc. that uses water-based ink, the water-based ink is repelled, making it difficult or possible to rewrite. However, there was a problem that the handwriting did not dry properly.
本発明者らは、上述せる問題を解決すべく、油
性の修正液に添加する物質について種々検討した
結果、遂に本発明を完成したものであつて、本発
明は、白色顔料と、有機溶剤と、有機溶剤に可能
な樹脂と、下記一般式で示すイミダゾリン誘導体
とからなる修正液を要旨とするものである。 In order to solve the above-mentioned problems, the present inventors have finally completed the present invention as a result of various studies on substances to be added to oil-based correction fluid. The gist of the invention is a correction fluid consisting of a resin that can be used in an organic solvent and an imidazoline derivative represented by the following general formula.
(R1は、アルキル基、フエニル基、脂肪酸残
基を示し、R2は水素原子、アルキル基を示す。)
本発明に於て、一般式で示すイミダゾリン誘導
体を使用することによつて、修正個所の塗膜面に
水性インキで筆記した場合、何故、水性インキを
はじくことなく再筆記可能であつて、再筆記した
筆跡の乾燥が良好になるのかは定かでないが、イ
ミダゾリン誘導体の2位及び/又は4位の置換基
が親油性基として働き、1位のヒドロキシエチル
基の水酸基が親水性基として働くため、イミダゾ
リン誘導体は、非イオン性の界面活性剤と同様の
機能を有しており、この機能と前述の親水性の水
酸基の機能とにより、塗膜へのインキののりを良
好にし、インキのはじき防止、更にはインキの塗
膜への浸透を良好にし筆跡の乾燥が良好になるも
のと思われる。又、本発明に於けるイミダゾリン
誘導体は、前述のように非イオン界面活性剤と同
様の機能を有しており、顔料の分散性向上、沈降
防止にも寄与しているものと思われる。 (R 1 represents an alkyl group, a phenyl group, or a fatty acid residue, and R 2 represents a hydrogen atom or an alkyl group.) In the present invention, by using an imidazoline derivative represented by the general formula, It is not clear why when writing with water-based ink on the painted surface of a spot, it is possible to re-write without repelling the water-based ink and the re-written handwriting dries well, but the 2nd position of the imidazoline derivative and The imidazoline derivative has the same function as a nonionic surfactant because the substituent at the / or 4th position acts as a lipophilic group and the hydroxyl group of the hydroxyethyl group at the 1st position acts as a hydrophilic group. This function and the above-mentioned hydrophilic hydroxyl function allow the ink to adhere well to the paint film, prevent the ink from repelling, and further improve the penetration of the ink into the paint film, resulting in better drying of handwriting. It seems to be. Further, the imidazoline derivative in the present invention has the same function as a nonionic surfactant as described above, and is thought to contribute to improving pigment dispersibility and preventing sedimentation.
以下、本発明の組成について説明する。 The composition of the present invention will be explained below.
白色顔料は、筆跡を隠蔽するために使用するも
のであつて、ルチル型、アナターゼ型などの各種
の酸化チタンが使用でき、市販のものとしては、
タイトーンSR―1、同R―650、同R―3L、同
R―310、同A―110、同A―150、同R―5N(以
上、堺化学工業(株)製)タイペークR―580、同R
―550、同R―930、同A―100、同A―220(以上、
石原産業(株)製)、クロノスKR―310、同KR―
380、同KR―480、同KA―10、同KA―20、同
KA―30(以上、チタン工業(株)製)などが挙げら
れ、他の成分などを考慮すると、その使用量は修
正液全量に対して20〜50重量%が好ましい。 The white pigment is used to hide handwriting, and various titanium oxides such as rutile type and anatase type can be used, and commercially available ones include:
Taitone SR-1, Taitone R-650, Taipei R-3L, Taipei R-310, A-110, A-150, Taipei R-5N (manufactured by Sakai Chemical Industry Co., Ltd.) Taipeku R-580, Same R
-550, R-930, A-100, A-220 (and above,
(manufactured by Ishihara Sangyo Co., Ltd.), Kronos KR-310, KR-
380, KR-480, KA-10, KA-20, same
Examples include KA-30 (manufactured by Titan Kogyo Co., Ltd.), and in consideration of other components, the amount used is preferably 20 to 50% by weight based on the total amount of correction fluid.
有機溶剤は、樹脂の溶解、粘度調整などに使用
されるもので、トルエン、キシレン、n―ヘプタ
ン、n―オクタン、シクロヘキサン、メチルシク
ロヘキサンなどの炭化水素系、1,1,1―トリ
クロルエタン、テトラクロルエチレンなどのハロ
ゲン炭化水素系、1,4―ジオキサン、n―ブチ
ルエーテル、トリオキサンなどのエーテル系、エ
チルメチルケトン、メチル―n―プロピルケトン
などのケトン系、ギ酸プロピル、酢酸エチルなど
のエステル系などがあり、修正した個所の塗膜の
乾燥時間を考慮すれば沸点が70℃〜150℃のもの
が好ましく、単独もしくは混合して使用可能であ
り、その使用量は修正液全量に対して30〜60重量
%が好ましい。 Organic solvents are used for dissolving resins, adjusting viscosity, etc., and include hydrocarbons such as toluene, xylene, n-heptane, n-octane, cyclohexane, and methylcyclohexane, 1,1,1-trichloroethane, and tetrachloroethane. Halogenated hydrocarbons such as chlorethylene, ethers such as 1,4-dioxane, n-butyl ether, trioxane, ketones such as ethyl methyl ketone and methyl-n-propyl ketone, esters such as propyl formate and ethyl acetate, etc. Considering the drying time of the paint film in the corrected area, it is preferable to use one with a boiling point of 70°C to 150°C, and it can be used alone or in combination, and the amount used is 30 to 150°C based on the total amount of correction liquid. 60% by weight is preferred.
尚、n―ヘプタン、n―オクタンなどのパラフ
イン系炭化水素や、シクロヘキサン、メチルシク
ロヘキサンなどのナフテン系炭化水素を有機溶剤
として使用すれば、油性インキの筆跡をも修正す
ることができるものである。 Note that if a paraffinic hydrocarbon such as n-heptane or n-octane or a naphthenic hydrocarbon such as cyclohexane or methylcyclohexane is used as an organic solvent, it is possible to correct handwriting made with oil-based ink.
有機溶剤に可溶な樹脂としては、一例を挙げる
と、アクリル樹脂、アルキツド樹脂、ビニル樹
脂、ポリエステル樹脂などがあり、単独もしくは
混合して使用可能であり、その使用量は修正液全
量に対して5〜20重量%が好ましい。 Examples of resins soluble in organic solvents include acrylic resins, alkyd resins, vinyl resins, and polyester resins, which can be used alone or in combination, and the amount used is based on the total amount of correction fluid. 5 to 20% by weight is preferred.
本発明の骨子である一般式で示されるイミダゾ
リン誘導体は、2位及び/又は4位の置換イミダ
ゾリンの1位に酸化エチレンあるいはエチレンカ
ーボナートを付加するか、エチレンクロールヒド
リンで置換するかして、1―ヒドロキシエチル化
物としたものであり、市販されているものあるい
は、前述のように合成したものであつてもよく、
その使用量は修正液全量に対して、0.1重量%以
下では効果が少ないことがあり、3重量%以上で
はこれ以上の効果が期待できないため、0.1〜3
重量%が好ましい。 The imidazoline derivative represented by the general formula, which is the gist of the present invention, can be obtained by adding ethylene oxide or ethylene carbonate to the 1st position of the imidazoline substituted at the 2nd and/or 4th positions, or by substituting it with ethylene chlorohydrin. , 1-hydroxyethylated product, which may be commercially available or synthesized as described above,
If the amount used is less than 0.1% by weight based on the total amount of correction fluid, the effect may be small, and if it is more than 3% by weight, no further effect can be expected.
Weight percent is preferred.
尚、上記せる成分の他に紙などの筆記面と色調
を合わせる為に着色顔料を、隠蔽力を向上させる
為にシリカ、炭酸カルシウムなどの体質顔料を、
顔料の分散安定性の為に分散剤や沈降防止剤を、
粘度調整の為に増粘剤を、塗膜の硬さを調整する
為に可塑剤を、塗布性能を良好にならしめる為に
フロー向上剤やレベリング剤を適宜少量添加する
ことができる。 In addition to the above ingredients, coloring pigments are added to match the color tone with the writing surface such as paper, and extender pigments such as silica and calcium carbonate are added to improve hiding power.
Dispersants and anti-settling agents are used to stabilize the dispersion of pigments.
A thickener may be added to adjust the viscosity, a plasticizer may be added to adjust the hardness of the coating film, and a flow improver or leveling agent may be added in small amounts to improve coating performance.
本発明の修正液は、上記各成分をボールミル、
アトライター、サンドグライダーなどの撹拌分散
機を使用して分散混合することによつて得られ
る。 The correction fluid of the present invention is produced by mixing the above components in a ball mill,
It can be obtained by dispersing and mixing using a stirring disperser such as an attritor or a sand glider.
このようにして得られた本発明の修正液で修正
した個所の塗膜は、水性インキで再筆記できると
ともに再筆記した筆跡の乾燥も良好なものであ
る。 The thus obtained coating film at the location corrected with the correction fluid of the present invention can be rewritten with water-based ink, and the rewritten handwriting dries well.
以下、実施例に従い、本発明を更に詳細に説明
するが、実施例中「部」とあるのは「重量部」を
示す。 Hereinafter, the present invention will be described in more detail with reference to Examples, where "parts" in the Examples indicate "parts by weight."
実施例 1
クロノスKR―380(白色顔料) 60部
ダイヤナールBR105(三菱レイヨン(株)製、アク
リル樹脂) 15部
キシレン 70部
イミダゾリン誘導体 1部
(R1=ヤシ油脂肪酸残基、R2=Hであるイ
ミダゾリン誘導体、川研フアインケミカル(株)
製)
ミズカシルP―801(水沢化学(株)、微細シリカ)
2部
上記各成分をボールミルにて24時間分散処理し
て修正液を得た。Example 1 Kronos KR-380 (white pigment) 60 parts Dianal BR105 (manufactured by Mitsubishi Rayon Co., Ltd., acrylic resin) 15 parts xylene 70 parts imidazoline derivative 1 part (R1 = coconut oil fatty acid residue, R2 = H Imidazoline derivatives, Kawaken Huain Chemical Co., Ltd.
Mizukasil P-801 (Mizusawa Chemical Co., Ltd., fine silica)
2 parts Each of the above components was dispersed in a ball mill for 24 hours to obtain a correction liquid.
実施例 2
クロノスKR―380 60部
パラロイドB―66(ローム&ハース社製、アク
リル樹脂) 12部
1,1,1―トリクロロエタン 110部
イミダゾリン誘導体 1部
(R1=C11H23、R2=Hである2.4位置換イ
ミダゾリン(C11ZL、四国化成工業(株)製)の1
位をエチレンクロールヒドリンにて置換したも
の。)
ミズカシルP―801 2部
MA―100(三菱化成(株)製、カーボンブラツク)
0.02部
上記各成分をボールミルにて24時間分散処理し
て修正液を得た。Example 2 Kronos KR-380 60 parts Paraloid B-66 (manufactured by Rohm & Haas, acrylic resin) 12 parts 1,1,1-trichloroethane 110 parts Imidazoline derivative 1 part (2.4 position where R1=C11H23, R2=H) 1 of converted imidazoline (C11ZL, manufactured by Shikoku Kasei Kogyo Co., Ltd.)
Substituted with ethylene chlorohydrin at position. ) Mizukasil P-801 2 parts MA-100 (manufactured by Mitsubishi Kasei Corporation, carbon black)
0.02 parts Each of the above components was dispersed in a ball mill for 24 hours to obtain a correction liquid.
実施例 3
クロノスKR―480 60部
パラロイドB―67(ローム&ハース社製、アク
リル樹脂) 12部
メチルシクロヘキサン 40部
エチルシクロヘキサン 20部
イミダゾリン誘導体 1部
(R1=C2H5、R2=CH3である2.4位置換イ
ミダゾリン(2E・4MZL、四国化成工業(株)製)
の1位をエチレンクロールヒドリンにて置換し
たもの。)
ミズカシルP―801 1.5部
DOA(大八化学(株)、可塑剤) 4部
上記各成分をボールミルにて24時間分散処理し
て修正液を得た。Example 3 Kronos KR-480 60 parts Paraloid B-67 (manufactured by Rohm & Haas, acrylic resin) 12 parts Methylcyclohexane 40 parts Ethylcyclohexane 20 parts Imidazoline derivative 1 part (2.4-position substitution where R1=C2H5, R2=CH3 Imidazoline (2E/4MZL, manufactured by Shikoku Kasei Kogyo Co., Ltd.)
The 1st position of is substituted with ethylene chlorohydrin. ) Mizukashiru P-801 1.5 parts DOA (Daihachi Kagaku Co., Ltd., plasticizer) 4 parts The above components were dispersed in a ball mill for 24 hours to obtain a correction fluid.
実施例 4
クロノスKR―380 60部
ダイヤナールBR―105 15部
メチルシクロヘキサン 40部
ペガゾールLA(モービル石油(株)、パラフイン系
溶剤) 20部
イミダゾリン誘導体(実施例1と同様なもの)
1部
ミズカシルP―801 1.5部
DOA 3部
ポリフローS(共栄社油脂(株)、フロー向上剤)
0.2部
上記各成分をボールミルにて24時間分散処理し
て修正液を得た。Example 4 Kronos KR-380 60 parts Dianal BR-105 15 parts Methylcyclohexane 40 parts Pegazol LA (Mobil Oil Co., Ltd., paraffinic solvent) 20 parts Imidazoline derivative (same as Example 1)
1 part Mizukasil P-801 1.5 parts DOA 3 parts Polyflow S (Kyoeisha Yushi Co., Ltd., flow improver)
0.2 parts Each of the above components was dispersed in a ball mill for 24 hours to obtain a correction liquid.
比較例 1〜4
実施例1〜4のイミダゾリン誘導体を除いた他
は実施例1と同様にして修正液を得た。Comparative Examples 1 to 4 Correction fluids were obtained in the same manner as in Example 1, except that the imidazoline derivatives of Examples 1 to 4 were removed.
実施例1〜4、比較例1〜4の修正液の隠蔽
率、再筆記性、塗膜乾燥時間、指触乾燥時間の試
験結果を表―1に示す。 Table 1 shows the test results of the hiding rate, rewriteability, coating film drying time, and touch drying time of the correction fluids of Examples 1 to 4 and Comparative Examples 1 to 4.
Claims (1)
樹脂と、下記一般式で示すイミダゾリン誘導体と
からなる修正液。 (R1は、アルキル基、フエニル基、脂肪酸残
基を示し、R2は水素原子、アルキル基を示す。)[Scope of Claims] 1. A correction fluid comprising a white pigment, an organic solvent, a resin soluble in the organic solvent, and an imidazoline derivative represented by the following general formula. (R 1 represents an alkyl group, phenyl group, or fatty acid residue; R 2 represents a hydrogen atom or an alkyl group.)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP56145214A JPS5849761A (en) | 1981-09-14 | 1981-09-14 | Correction fluid |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP56145214A JPS5849761A (en) | 1981-09-14 | 1981-09-14 | Correction fluid |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS5849761A JPS5849761A (en) | 1983-03-24 |
JPS644548B2 true JPS644548B2 (en) | 1989-01-26 |
Family
ID=15380004
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP56145214A Granted JPS5849761A (en) | 1981-09-14 | 1981-09-14 | Correction fluid |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS5849761A (en) |
Families Citing this family (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS606765A (en) * | 1983-06-27 | 1985-01-14 | Pentel Kk | Retouching liquid |
JPS608376A (en) * | 1983-06-27 | 1985-01-17 | Pentel Kk | Eraser solution |
GB9211760D0 (en) * | 1992-06-03 | 1992-07-15 | Gillette Co | Correction fluids |
JPH07166114A (en) * | 1993-10-12 | 1995-06-27 | Orient Chem Ind Ltd | Correcting solution of coloring recording material |
ZA955550B (en) * | 1994-07-08 | 1996-02-16 | Gillette Co | Aqueous correction fluids |
US5922400A (en) * | 1997-01-09 | 1999-07-13 | The Gillette Company | Correction fluid |
-
1981
- 1981-09-14 JP JP56145214A patent/JPS5849761A/en active Granted
Also Published As
Publication number | Publication date |
---|---|
JPS5849761A (en) | 1983-03-24 |
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