JPS64433B2 - - Google Patents
Info
- Publication number
- JPS64433B2 JPS64433B2 JP55069610A JP6961080A JPS64433B2 JP S64433 B2 JPS64433 B2 JP S64433B2 JP 55069610 A JP55069610 A JP 55069610A JP 6961080 A JP6961080 A JP 6961080A JP S64433 B2 JPS64433 B2 JP S64433B2
- Authority
- JP
- Japan
- Prior art keywords
- water
- weight
- parts
- ink
- oil
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 20
- 239000003960 organic solvent Substances 0.000 claims description 6
- 239000011259 mixed solution Substances 0.000 claims description 5
- 229910001854 alkali hydroxide Inorganic materials 0.000 claims description 3
- 150000008044 alkali metal hydroxides Chemical class 0.000 claims description 3
- 150000004668 long chain fatty acids Chemical class 0.000 claims description 3
- 239000000976 ink Substances 0.000 description 21
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 9
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 9
- 239000007788 liquid Substances 0.000 description 6
- 239000000975 dye Substances 0.000 description 4
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 3
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 3
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 3
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 3
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 239000005642 Oleic acid Substances 0.000 description 3
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 3
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 3
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 3
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 2
- -1 clear Substances 0.000 description 2
- DIOQZVSQGTUSAI-UHFFFAOYSA-N decane Chemical compound CCCCCCCCCC DIOQZVSQGTUSAI-UHFFFAOYSA-N 0.000 description 2
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 2
- 239000000839 emulsion Substances 0.000 description 2
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- LQNUZADURLCDLV-UHFFFAOYSA-N nitrobenzene Chemical compound [O-][N+](=O)C1=CC=CC=C1 LQNUZADURLCDLV-UHFFFAOYSA-N 0.000 description 2
- 239000007764 o/w emulsion Substances 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- VZGDMQKNWNREIO-UHFFFAOYSA-N tetrachloromethane Chemical compound ClC(Cl)(Cl)Cl VZGDMQKNWNREIO-UHFFFAOYSA-N 0.000 description 2
- OYHQOLUKZRVURQ-NTGFUMLPSA-N (9Z,12Z)-9,10,12,13-tetratritiooctadeca-9,12-dienoic acid Chemical compound C(CCCCCCC\C(=C(/C\C(=C(/CCCCC)\[3H])\[3H])\[3H])\[3H])(=O)O OYHQOLUKZRVURQ-NTGFUMLPSA-N 0.000 description 1
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 239000005639 Lauric acid Substances 0.000 description 1
- 235000021314 Palmitic acid Nutrition 0.000 description 1
- XBDQKXXYIPTUBI-UHFFFAOYSA-M Propionate Chemical compound CCC([O-])=O XBDQKXXYIPTUBI-UHFFFAOYSA-M 0.000 description 1
- 235000021355 Stearic acid Nutrition 0.000 description 1
- KXKVLQRXCPHEJC-UHFFFAOYSA-N acetic acid trimethyl ester Natural products COC(C)=O KXKVLQRXCPHEJC-UHFFFAOYSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000003792 electrolyte Substances 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- WQEPLUUGTLDZJY-UHFFFAOYSA-N n-Pentadecanoic acid Natural products CCCCCCCCCCCCCCC(O)=O WQEPLUUGTLDZJY-UHFFFAOYSA-N 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- 235000021313 oleic acid Nutrition 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 150000004671 saturated fatty acids Chemical class 0.000 description 1
- 235000003441 saturated fatty acids Nutrition 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 235000021122 unsaturated fatty acids Nutrition 0.000 description 1
- 150000004670 unsaturated fatty acids Chemical class 0.000 description 1
Landscapes
- Inks, Pencil-Leads, Or Crayons (AREA)
Description
【発明の詳細な説明】
本発明は、耐水性を改良したインクジエツト記
録用インクに関する。DETAILED DESCRIPTION OF THE INVENTION The present invention relates to an inkjet recording ink with improved water resistance.
従来、インクジエツト記録用インクは、水溶性
染料を溶解した水性インクと、油溶性染料を溶解
した油性インクとがあるが、水性インクは導電
性、低粘性、不燃性などの長所があるものの、生
成画像の耐水性が不十分である欠点がある。油性
インクは、画像の耐水性は十分であるが、インク
の比電導度が高く、これを低くするために電解質
を添加すると、ノズル詰りがしばしば発生する
し、又、粘度も比較的高いのでこの点からもノズ
ル詰りの惧れがある。その他可燃性であることな
どから、環境汚染上にも問題がある。 Conventionally, inkjet recording inks include water-based inks with water-soluble dyes dissolved in them, and oil-based inks with oil-soluble dyes dissolved in them.While water-based inks have advantages such as conductivity, low viscosity, and nonflammability, There is a drawback that the water resistance of the image is insufficient. Oil-based inks have sufficient water resistance for images, but the specific conductivity of the ink is high, and adding electrolyte to lower this will often cause nozzle clogging, and the viscosity is relatively high, so it is difficult to use oil-based inks. There is also a risk of nozzle clogging. In addition, because it is flammable, it also poses a problem in terms of environmental pollution.
そこで、本発明は、水性インクの長所すなわ
ち、導電性、低粘性、不燃性を維持したままで、
画像の耐水性を油性インクと同程度まで改良する
安定な水中油滴型エマルジヨンインクを提供する
ことを目的とするものである。 Therefore, the present invention maintains the advantages of water-based ink, that is, conductivity, low viscosity, and nonflammability.
The object of the present invention is to provide a stable oil-in-water emulsion ink that improves the water resistance of images to the same level as oil-based inks.
すなわち、本発明は、
(a) 水と相溶性をもたない有機溶媒、
(b) 長鎖脂肪酸、
(c) 上記(a)(b)の混合溶液に溶解し、かつ水には溶
解しない染料、
(d) 水酸化アルカリ、
および(e)水、を少なくとも含有することを特徴
とするインクジエツト記録用インクである。 That is, the present invention provides (a) an organic solvent that is not compatible with water, (b) a long-chain fatty acid, and (c) a compound that is soluble in the mixed solution of (a) and (b) above, but is not soluble in water. An inkjet recording ink characterized by containing at least a dye, (d) an alkali hydroxide, and (e) water.
本発明に使用する。 Used in the present invention.
(a) 水と相溶性をもたない有機溶媒としては、ベ
ンゼン、トルエン、ニトロベンゼン等の芳香族
炭化水素、四塩化炭素、シクロヘキサンおよび
ヘキサン、デカン等の脂肪族炭化水素などが挙
げられる。又、水とわずかに相溶性をもつ有機
溶媒も使用可能であり、例えば酢酸メチル、酢
酸エチル、メチルエチルケトンなどを使用でき
るので、本発明ではこれらをも含めて、水と相
溶性をもたないと表現した。以上の有機溶媒が
挙げられるが、インクの蒸発乾固によるノズル
詰りを完全に防止するためには、沸点が100〜
250℃である有機溶媒を使用することが好まし
い。(a) Examples of organic solvents that are not compatible with water include aromatic hydrocarbons such as benzene, toluene, and nitrobenzene, and aliphatic hydrocarbons such as carbon tetrachloride, cyclohexane, hexane, and decane. Furthermore, it is also possible to use organic solvents that are slightly miscible with water, such as methyl acetate, ethyl acetate, and methyl ethyl ketone. expressed. The above organic solvents can be used, but in order to completely prevent nozzle clogging due to evaporation of ink to dryness, it is necessary to have a boiling point of 100 to
Preference is given to using organic solvents that are at 250°C.
(b) 長鎖脂肪酸としては、オレイン酸、リノレイ
ン酸等の不飽和脂肪酸、ステアリン酸、パルミ
チン酸、ラウリル酸等の飽和脂肪酸などを使用
し得る。(b) As the long-chain fatty acid, unsaturated fatty acids such as oleic acid and linoleic acid, and saturated fatty acids such as stearic acid, palmitic acid, and lauric acid can be used.
(c) 上記(a)(b)の混合溶液に溶解し、かつ水には溶
解しない染料としては、オイルブラツクHBB、
同BS、オイルピンク○＃308、オイルブルー
BOS、オイルイエロー○＃105（以上オリエント
化学(株)製）などを使用し得る。(c) Dyes that dissolve in the mixed solution of (a) and (b) above but do not dissolve in water include oil black HBB,
Same BS, oil pink○#308, oil blue
BOS, Oil Yellow #105 (manufactured by Orient Chemical Co., Ltd.), etc. may be used.
(d) 水酸化アルカリとしては、水酸化ナトリウム
又は水酸化カリウムが使用し得る。(d) As the alkali hydroxide, sodium hydroxide or potassium hydroxide can be used.
上記各成分の好ましい配合割合は、(a)成分が５
〜40重量部、(b)成分が0.5〜15重量部、(c)成分が
0.5〜7.0重量部、(d)成分が0.05〜5.0重量部、(e)成
分が100重量部である。 The preferred blending ratio of each of the above components is that component (a) is 5
~40 parts by weight, component (b) 0.5 to 15 parts by weight, component (c)
0.5 to 7.0 parts by weight, component (d) 0.05 to 5.0 parts by weight, and component (e) 100 parts by weight.
これらの成分を用いて本発明インクを製造する
には、まず(a)成分と(b)成分とを溶解し、この混合
液に(c)成分を溶解し、ついで、これを(d)成分と(e)
成分との混合水溶液中に混合する。 To manufacture the ink of the present invention using these components, first dissolve the components (a) and (b), dissolve the component (c) in this mixed solution, and then add the component (d). and(e)
Mix the ingredients into an aqueous solution.
本発明インクは、水中油滴型エマルジヨンタイ
プのもので、分散相の粒径が0.5μm以下と極めて
微小であり、かつ導電性、低粘性、不燃性のもの
でノズルと電歪素子を含む印写ヘツド内で100K
Hz以上の超音波振動によつても破壊しない安定な
エマルジヨンであり、また上記の超音波振動によ
つて、仮にエマルジヨンが破壊したとしても、再
乳化し得るので、ノズル詰りを生ずるようなこと
がない。 The ink of the present invention is an oil-in-water emulsion type in which the dispersed phase has an extremely small particle size of 0.5 μm or less, is electrically conductive, has low viscosity, is nonflammable, and includes a nozzle and an electrostrictive element. 100K in printing head
It is a stable emulsion that will not be destroyed even by ultrasonic vibrations of Hz or higher, and even if the emulsion is destroyed by the above-mentioned ultrasonic vibrations, it can be re-emulsified, so nozzle clogging will not occur. do not have.
なお、界面活性剤など通常の添加剤を用いても
よい。 Note that ordinary additives such as surfactants may also be used.
つぎに実施例について説明する。 Next, examples will be described.
実施例 １
(a) トルエン 100 重量部
(b) オレイン酸 25 重量部
(c) オイルブラツクHBB（オリエント化学(株)製）
9.0重量部
を用い、(a)と(b)とを溶解してから、この混合溶液
に(c)を溶解してＡ液とした。Example 1 (a) Toluene 100 parts by weight (b) Oleic acid 25 parts by weight (c) Oil black HBB (manufactured by Orient Chemical Co., Ltd.)
Using 9.0 parts by weight, (a) and (b) were dissolved, and then (c) was dissolved in this mixed solution to obtain liquid A.
(d) 水酸化ナトリウム 3.6重量部 (e) イオン交換水 500 重量部 を混合してＢ液とした。(d) Sodium hydroxide 3.6 parts by weight (e) 500 parts by weight of ion-exchanged water were mixed to obtain liquid B.
Ｂ液にＡ液を加えて混合して、本発明インクと
した。このインクの導電性は7.7mv／cm、粘性は
1.3cpであつた。 The ink of the present invention was prepared by adding and mixing the A liquid to the B liquid. The conductivity of this ink is 7.7mv/cm, and the viscosity is
It was 1.3 cp.
このインクを用いてインクジエツト記録をした
ところ、耐水性のある鮮明な画像が長期に亘つて
得られた。 When inkjet recording was performed using this ink, clear, water-resistant images were obtained for a long period of time.
実施例 ２
(a) トルエン 100 重量部
(b) オレイン酸 20 重量部
(c) オイルブラツクHBB（オリエント化学(株)製）
9.5重量部
を混合し、さらにメタノール10重量部を混合して
Ａ液とした。Example 2 (a) Toluene 100 parts by weight (b) Oleic acid 20 parts by weight (c) Oil black HBB (manufactured by Orient Chemical Co., Ltd.)
9.5 parts by weight were mixed, and 10 parts by weight of methanol were further mixed to obtain liquid A.
(d) 水酸化ナトリウム 2.4重量部
(e) イオン交換水 500 重量部
を混合し、さらに、これに非イオン界面活性剤
（商品名TL−10、日光ケミカルズ(株)製）２重量
部、エチレングリコール50重量部、ソデイウムオ
マジン（オーリン製）１重量部を加えてＢ液とし
た。(d) 2.4 parts by weight of sodium hydroxide (e) 500 parts by weight of ion-exchanged water are mixed, and to this is added 2 parts by weight of a nonionic surfactant (trade name TL-10, manufactured by Nikko Chemicals Co., Ltd.) and ethylene. 50 parts by weight of glycol and 1 part by weight of Sodium Omazine (manufactured by Orlin) were added to prepare liquid B.
Ｂ液にＡ液を加えて、約３時間、50℃に加温し
て撹拌することによつて本発明インクとした。 The ink of the present invention was prepared by adding Solution A to Solution B and stirring at 50° C. for about 3 hours.
このインクの導電性は5.3mv／cm、粘性は
2.7cpであつた。 The conductivity of this ink is 5.3mv/cm, and the viscosity is
It was 2.7cp.
このインクを用いてインクジエツト記録をした
ところ、耐水性のある鮮明な画像が長期に亘つて
得られた。 When inkjet recording was performed using this ink, clear, water-resistant images were obtained for a long period of time.
Claims (1)
解しない染料、 (d) 水酸化アルカリ、 および(e)水、を少なくとも含有することを特徴
とするインクジエツト記録用インク。[Claims] 1 (a) an organic solvent that is incompatible with water, (b) a long-chain fatty acid, (c) soluble in the mixed solution of (a) and (b) above, and soluble in water. 1. An inkjet recording ink comprising at least the following: (d) an alkali hydroxide; and (e) water.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP6961080A JPS56166274A (en) | 1980-05-27 | 1980-05-27 | Ink for ink jet recording |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP6961080A JPS56166274A (en) | 1980-05-27 | 1980-05-27 | Ink for ink jet recording |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS56166274A JPS56166274A (en) | 1981-12-21 |
| JPS64433B2 true JPS64433B2 (en) | 1989-01-06 |
Family
ID=13407786
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP6961080A Granted JPS56166274A (en) | 1980-05-27 | 1980-05-27 | Ink for ink jet recording |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS56166274A (en) |
Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4793264A (en) * | 1981-12-07 | 1988-12-27 | Dataproducts Corporation | Low corrosion impulse ink jet ink containing anti-oxidant |
| JPS62207375A (en) * | 1986-03-07 | 1987-09-11 | Fuji Xerox Co Ltd | Ink composition for use in ink jet recording |
| JPS62297368A (en) * | 1986-06-17 | 1987-12-24 | Fuji Xerox Co Ltd | Composition for recording |
| JPH0826262B2 (en) * | 1988-06-07 | 1996-03-13 | キヤノン株式会社 | ink |
| JP2011202088A (en) * | 2010-03-26 | 2011-10-13 | Seiko Epson Corp | Inkjet recording apparatus |
| JP2011201220A (en) | 2010-03-26 | 2011-10-13 | Seiko Epson Corp | Inkjet recording device |
| JP2011201219A (en) | 2010-03-26 | 2011-10-13 | Seiko Epson Corp | Inkjet recording apparatus |
| JPWO2011121727A1 (en) * | 2010-03-30 | 2013-07-04 | キヤノン株式会社 | Colored particles |
| JP2015091970A (en) * | 2014-11-25 | 2015-05-14 | セイコーエプソン株式会社 | Ink jet ink |
| JP2016121357A (en) * | 2016-01-25 | 2016-07-07 | セイコーエプソン株式会社 | Inkjet ink |
-
1980
- 1980-05-27 JP JP6961080A patent/JPS56166274A/en active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| JPS56166274A (en) | 1981-12-21 |
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