JPS6434947A - Acrylic acid esters - Google Patents
Acrylic acid estersInfo
- Publication number
- JPS6434947A JPS6434947A JP19133787A JP19133787A JPS6434947A JP S6434947 A JPS6434947 A JP S6434947A JP 19133787 A JP19133787 A JP 19133787A JP 19133787 A JP19133787 A JP 19133787A JP S6434947 A JPS6434947 A JP S6434947A
- Authority
- JP
- Japan
- Prior art keywords
- alcohol
- amount
- acrylic
- catalyst
- methacrylic acid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Adhesives Or Adhesive Processes (AREA)
Abstract
NEW MATERIAL:3-Hydroxy-3-methylbutyl (meth)acrylates expressed by the formula (R is H or methyl). USE:A raw material for adhesives, tacky agents, coatings, printing inks, etc., having low odor and viscosity, anaerobic and ultraviolet ray curability and capable of exhibiting excellent adhesive properties and high adhesive strength. PREPARATION:The primary hydroxyl group part of an alcohol (e.g. 3- methylbutane-1,3-diol) is subjected to ester interchange reaction with an acrylic or methacrylic acid ester to afford the aimed compounds expressed by the formula. The above-mentioned reaction is preferably carried out in the presence of a polymerization inhibitor (e.g. hydroquinone) and a catalyst [e.g. iron complex of N,N-bis(salicylidene)-ethylenediamine] at 70-130 deg.C. The acrylic or methacrylic acid ester is used in a molar amount of 1.5-10 times based on the alcohol and the catalyst is used in an amount of 0.2-4.0wt.% based on the alcohol. The polymerization inhibitor is used in an amount of 0.1-2.0g based on 1mol. alcohol.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP19133787A JPS6434947A (en) | 1987-07-30 | 1987-07-30 | Acrylic acid esters |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP19133787A JPS6434947A (en) | 1987-07-30 | 1987-07-30 | Acrylic acid esters |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPS6434947A true JPS6434947A (en) | 1989-02-06 |
Family
ID=16272883
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP19133787A Pending JPS6434947A (en) | 1987-07-30 | 1987-07-30 | Acrylic acid esters |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS6434947A (en) |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0594109A1 (en) * | 1992-10-19 | 1994-04-27 | Union Carbide Chemicals & Plastics Technology Corporation | Hindered-hydroxyl functional (meth)acrylate esters, copolymers containing them and compositions including same |
| EP1253134A1 (en) * | 2001-04-26 | 2002-10-30 | Mitsubishi Gas Chemical Company, Inc. | Vinyl-polymerizable monomer having tertiary hydroxyl group and polymer |
| JP2016155997A (en) * | 2015-02-24 | 2016-09-01 | 株式会社リコー | Active energy ray-curable composition, active energy ray-curable ink, composition storage container, apparatus for forming two-dimensional or three-dimensional image, method for forming two-dimensional or three-dimensional image, cured product, decorative body, and active energy ray-polymerizable compound |
| KR20170128338A (en) | 2015-03-12 | 2017-11-22 | 주식회사 쿠라레 | (Meth) acrylic acid ester compound |
| JP2017226619A (en) * | 2016-06-22 | 2017-12-28 | 株式会社クラレ | Production method of (meth)acrylic ester compound |
| JP2018104360A (en) * | 2016-12-27 | 2018-07-05 | 株式会社クラレ | Process for producing ester |
| JP2018104379A (en) * | 2016-12-28 | 2018-07-05 | 三菱瓦斯化学株式会社 | Manufacturing method and composition of 2-methyl-2-hydroxy-1-propyl(meth)acrylate and/or 3-methyl-3-hydroxy-1-butyl(meth)acrylate |
| WO2023017788A1 (en) * | 2021-08-11 | 2023-02-16 | 大倉工業株式会社 | Anaerobic adhesive composition |
-
1987
- 1987-07-30 JP JP19133787A patent/JPS6434947A/en active Pending
Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0594109A1 (en) * | 1992-10-19 | 1994-04-27 | Union Carbide Chemicals & Plastics Technology Corporation | Hindered-hydroxyl functional (meth)acrylate esters, copolymers containing them and compositions including same |
| JPH06199953A (en) * | 1992-10-19 | 1994-07-19 | Union Carbide Chem & Plast Technol Corp | Copolymer containing hindered-hydroxyl-functional (meth)acrylate and composition containing same |
| EP1253134A1 (en) * | 2001-04-26 | 2002-10-30 | Mitsubishi Gas Chemical Company, Inc. | Vinyl-polymerizable monomer having tertiary hydroxyl group and polymer |
| KR100868147B1 (en) * | 2001-04-26 | 2008-11-10 | 미츠비시 가스 가가쿠 가부시키가이샤 | Vinyl-polymerizable monomer having tertiary hydroxyl group and polymer |
| JP2016155997A (en) * | 2015-02-24 | 2016-09-01 | 株式会社リコー | Active energy ray-curable composition, active energy ray-curable ink, composition storage container, apparatus for forming two-dimensional or three-dimensional image, method for forming two-dimensional or three-dimensional image, cured product, decorative body, and active energy ray-polymerizable compound |
| KR20170128338A (en) | 2015-03-12 | 2017-11-22 | 주식회사 쿠라레 | (Meth) acrylic acid ester compound |
| CN107428664A (en) * | 2015-03-12 | 2017-12-01 | 株式会社可乐丽 | （Methyl）The manufacture method of acrylate compounds |
| JPWO2016143732A1 (en) * | 2015-03-12 | 2017-12-28 | 株式会社クラレ | Method for producing (meth) acrylic acid ester compound |
| JP2017226619A (en) * | 2016-06-22 | 2017-12-28 | 株式会社クラレ | Production method of (meth)acrylic ester compound |
| JP2018104360A (en) * | 2016-12-27 | 2018-07-05 | 株式会社クラレ | Process for producing ester |
| JP2018104379A (en) * | 2016-12-28 | 2018-07-05 | 三菱瓦斯化学株式会社 | Manufacturing method and composition of 2-methyl-2-hydroxy-1-propyl(meth)acrylate and/or 3-methyl-3-hydroxy-1-butyl(meth)acrylate |
| WO2023017788A1 (en) * | 2021-08-11 | 2023-02-16 | 大倉工業株式会社 | Anaerobic adhesive composition |
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