JPS6426585A - Cis-3-chloro-4-silyloxy-2-cyclopenten-1-ols, production thereof and production of 3-chloro-4-silyloxy-2-cyclopenten-1-ones by using said compounds - Google Patents

Cis-3-chloro-4-silyloxy-2-cyclopenten-1-ols, production thereof and production of 3-chloro-4-silyloxy-2-cyclopenten-1-ones by using said compounds

Info

Publication number
JPS6426585A
JPS6426585A JP62183041A JP18304187A JPS6426585A JP S6426585 A JPS6426585 A JP S6426585A JP 62183041 A JP62183041 A JP 62183041A JP 18304187 A JP18304187 A JP 18304187A JP S6426585 A JPS6426585 A JP S6426585A
Authority
JP
Japan
Prior art keywords
cyclopenten
chloro
silyloxy
production
ols
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP62183041A
Other languages
Japanese (ja)
Other versions
JP2627507B2 (en
Inventor
Kenji Mori
Tei Takeuchi
Masakazu Yuya
Shigeo Takeda
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Fuji Yakuhin Kogyo KK
Original Assignee
Fuji Yakuhin Kogyo KK
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Fuji Yakuhin Kogyo KK filed Critical Fuji Yakuhin Kogyo KK
Priority to JP62183041A priority Critical patent/JP2627507B2/en
Publication of JPS6426585A publication Critical patent/JPS6426585A/en
Application granted granted Critical
Publication of JP2627507B2 publication Critical patent/JP2627507B2/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/55—Design of synthesis routes, e.g. reducing the use of auxiliary or protecting groups

Abstract

NEW MATERIAL:A compound expressed by formula I [R<1> represents silyl which is a protecting group of OH; * denotes asymmetric center and represents stereoisomers of (1S, 4R), (1R, 4S) derived therefrom or a mixture thereof]. EXAMPLE:4-tert-Butyldimethylsilyloxy-3-chloro-2-cyclopenten-1-ol. USE:An intermediate for synthesis of punaglandin having carcinostatic and antiviral action. PREPARATION:An ester expressed by formula II (example; 3-acetoxy-5-tert- butyldimethylsilyloxy-1-chlorocyclopentene) is hydrolyzed in the presence of an enzyme (example; liver esterase).
JP62183041A 1987-07-22 1987-07-22 Cis-3-chloro-4-silyloxy-2-cyclopenten-1-ols and their production Expired - Lifetime JP2627507B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP62183041A JP2627507B2 (en) 1987-07-22 1987-07-22 Cis-3-chloro-4-silyloxy-2-cyclopenten-1-ols and their production

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP62183041A JP2627507B2 (en) 1987-07-22 1987-07-22 Cis-3-chloro-4-silyloxy-2-cyclopenten-1-ols and their production

Related Child Applications (1)

Application Number Title Priority Date Filing Date
JP8327444A Division JP2709807B2 (en) 1996-11-01 1996-11-01 Process for producing 3-chloro-4-silyloxy-2-cyclopenten-1-ones

Publications (2)

Publication Number Publication Date
JPS6426585A true JPS6426585A (en) 1989-01-27
JP2627507B2 JP2627507B2 (en) 1997-07-09

Family

ID=16128703

Family Applications (1)

Application Number Title Priority Date Filing Date
JP62183041A Expired - Lifetime JP2627507B2 (en) 1987-07-22 1987-07-22 Cis-3-chloro-4-silyloxy-2-cyclopenten-1-ols and their production

Country Status (1)

Country Link
JP (1) JP2627507B2 (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5207764A (en) * 1990-10-16 1993-05-04 Sharp Kabushiki Kaisha Tumbler type washing/drying machine

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5207764A (en) * 1990-10-16 1993-05-04 Sharp Kabushiki Kaisha Tumbler type washing/drying machine

Also Published As

Publication number Publication date
JP2627507B2 (en) 1997-07-09

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