JPS6419030A - Optically active benzene derivative and its preparation - Google Patents
Optically active benzene derivative and its preparationInfo
- Publication number
- JPS6419030A JPS6419030A JP9662988A JP9662988A JPS6419030A JP S6419030 A JPS6419030 A JP S6419030A JP 9662988 A JP9662988 A JP 9662988A JP 9662988 A JP9662988 A JP 9662988A JP S6419030 A JPS6419030 A JP S6419030A
- Authority
- JP
- Japan
- Prior art keywords
- formula
- optically active
- halogen
- preparation
- benzene derivative
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Landscapes
- Preparation Of Compounds By Using Micro-Organisms (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
NEW MATERIAL:An optically active benzene derivative of formula I (R is 1-20C alkyl which may contain halogen atoms, alkoxyalkyl; Z is H, halogen). EXAMPLE:(+)-4-(1'-Propoxyethyl)phenol. USE:It is useful as an intermediate of medicines and agrochemicals, especially used as a liquid crystal material. PREPARATION:An optically active ether derivative of formula II (A is H, lower alkyl, lower alkoxy, halogen; * is asymmetric carbon atom) is subjected to debenzylation to give the compound of formula I. The compound of formula II is obtained by condensation reaction of an optically active alcohol of formula III with an alkylating agent of formula IV (X is halogen, -OSO2R''; R'' is lower alkyl, substituted phenyl).
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP9662988A JP2508797B2 (en) | 1987-04-21 | 1988-04-19 | Optically active benzene derivative and method for producing the same |
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP62-99051 | 1987-04-21 | ||
JP9905187 | 1987-04-21 | ||
JP9662988A JP2508797B2 (en) | 1987-04-21 | 1988-04-19 | Optically active benzene derivative and method for producing the same |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS6419030A true JPS6419030A (en) | 1989-01-23 |
JP2508797B2 JP2508797B2 (en) | 1996-06-19 |
Family
ID=26437809
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP9662988A Expired - Lifetime JP2508797B2 (en) | 1987-04-21 | 1988-04-19 | Optically active benzene derivative and method for producing the same |
Country Status (1)
Country | Link |
---|---|
JP (1) | JP2508797B2 (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH02304040A (en) * | 1989-05-16 | 1990-12-17 | Sumitomo Chem Co Ltd | Optically active ether derivative, its production, liquid crystal material containing same compound as active component and optical switching device containing same material |
JP2008274895A (en) * | 2007-05-07 | 2008-11-13 | Mikuni Corp | Seal structure of exhaust valve |
-
1988
- 1988-04-19 JP JP9662988A patent/JP2508797B2/en not_active Expired - Lifetime
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH02304040A (en) * | 1989-05-16 | 1990-12-17 | Sumitomo Chem Co Ltd | Optically active ether derivative, its production, liquid crystal material containing same compound as active component and optical switching device containing same material |
JP2008274895A (en) * | 2007-05-07 | 2008-11-13 | Mikuni Corp | Seal structure of exhaust valve |
Also Published As
Publication number | Publication date |
---|---|
JP2508797B2 (en) | 1996-06-19 |
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