JPS641707A - Catalyst for highly stereoregular polymerization of alpha-olefins - Google Patents
Catalyst for highly stereoregular polymerization of alpha-olefinsInfo
- Publication number
- JPS641707A JPS641707A JP15660487A JP15660487A JPS641707A JP S641707 A JPS641707 A JP S641707A JP 15660487 A JP15660487 A JP 15660487A JP 15660487 A JP15660487 A JP 15660487A JP S641707 A JPS641707 A JP S641707A
- Authority
- JP
- Japan
- Prior art keywords
- solid
- compound
- catalyst
- substance
- organoaluminum compound
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Landscapes
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Abstract
PURPOSE: To obtain a catalyst capable of producing polymers having extremely high stereoregularity while maintaining high activity in using for polymerizing an α-olefin, comprising a solid catalytic component prepared by specific method, an epoxy-p-menthane compound and an organoaluminum compound.
CONSTITUTION: A catalyst comprising (A) a solid catalytic component prepared by suspending a dialkoxymagnesium in an aromatic hydrocarbon liquid at normal temperature, reacting the suspension with TiCl4 and an aromatic dicarboxylic acid diester at 80W135°C, separating the prepared solid substance, further reacting the solid substance with TiCl4 to give a solid reaction product, bringing a Si compound shown by the formula (R is alkyl, cycloalkyl, vinyl or aryl; R' is alkyl; 0≤m<4) into contact with the solid reaction product and then bringing an organoaluminum compound into contact with the substance, (B) an epoxy-p-menthane compound and (C) an organoaluminum compound.
COPYRIGHT: (C)1989,JPO&Japio
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP15660487A JP2514035B2 (en) | 1987-06-25 | 1987-06-25 | Catalyst for highly stereoregular polymerization of α-olefins |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP15660487A JP2514035B2 (en) | 1987-06-25 | 1987-06-25 | Catalyst for highly stereoregular polymerization of α-olefins |
Publications (3)
Publication Number | Publication Date |
---|---|
JPH011707A JPH011707A (en) | 1989-01-06 |
JPS641707A true JPS641707A (en) | 1989-01-06 |
JP2514035B2 JP2514035B2 (en) | 1996-07-10 |
Family
ID=15631372
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP15660487A Expired - Lifetime JP2514035B2 (en) | 1987-06-25 | 1987-06-25 | Catalyst for highly stereoregular polymerization of α-olefins |
Country Status (1)
Country | Link |
---|---|
JP (1) | JP2514035B2 (en) |
-
1987
- 1987-06-25 JP JP15660487A patent/JP2514035B2/en not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
---|---|
JP2514035B2 (en) | 1996-07-10 |
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