JPS6399267A - Inorganic composition for repairing damaged equipments - Google Patents

Inorganic composition for repairing damaged equipments

Info

Publication number
JPS6399267A
JPS6399267A JP24413786A JP24413786A JPS6399267A JP S6399267 A JPS6399267 A JP S6399267A JP 24413786 A JP24413786 A JP 24413786A JP 24413786 A JP24413786 A JP 24413786A JP S6399267 A JPS6399267 A JP S6399267A
Authority
JP
Japan
Prior art keywords
inorganic composition
metal
repair
alkali silicate
inorganic
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP24413786A
Other languages
Japanese (ja)
Inventor
Yuzo Kawahara
雄三 川原
Yukio Iida
飯田 往男
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mitsubishi Heavy Industries Ltd
Original Assignee
Mitsubishi Heavy Industries Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mitsubishi Heavy Industries Ltd filed Critical Mitsubishi Heavy Industries Ltd
Priority to JP24413786A priority Critical patent/JPS6399267A/en
Publication of JPS6399267A publication Critical patent/JPS6399267A/en
Pending legal-status Critical Current

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Abstract

PURPOSE:To provide an inorganic composition for repairing damages of various equipment, containers, etc., to be put in service at high or low temperatures, enabling and repair to be performed readily in a short time and at low cost, comprising metallic powder, metal oxide, metal carbonate and alkali silicate. CONSTITUTION:The objective composition comprising (A) metallic powder (pref. with a size 1-500mum; e.g., of Al, W, Mo, Fe, Cr, Ni, Cu), (B) metal oxide (e.g., Al2O3, TiO2, Cr2O3, Fe2O3, Fe3O4, MgO, 3Al2O3.2SiO2), (C) metal carbonate (e.g., CaCO3, Na2CO3, MgCO3), and (D) alkali silicate (e.g., sodium silicate).

Description

【発明の詳細な説明】 〔産業上の利用分野〕 本発明は高温度、低温度で使用される各種機器装置、容
器等およびそれらの構成部品の損傷部補修用の無機組成
物に関する。
DETAILED DESCRIPTION OF THE INVENTION [Field of Industrial Application] The present invention relates to an inorganic composition for repairing damaged parts of various equipment, containers, etc. used at high and low temperatures, and their component parts.

〔従来の技術〕[Conventional technology]

各種条件で使用される機器、装置、容器等では使用中の
損傷、劣化、腐食、によシ定期的補修、突発的補修が必
要とされる場合があシ、従来、金属−材料では溶接、肉
盛等の方法が一般的であシ、また、有機材料では溶接、
接着材を用いる方法等が一般に採用されている。
Equipment, devices, containers, etc. used under various conditions may require periodic or unexpected repairs to prevent damage, deterioration, or corrosion during use. Conventionally, metal materials have been welded, Methods such as overlaying are common, and for organic materials, welding,
A method using an adhesive is generally adopted.

これらの従来用いられている方法のうち溶接法には次の
ような欠点がある。
Among these conventionally used methods, the welding method has the following drawbacks.

(1)溶接による方法は簡便ではあるが、現場で補修す
る時には溶接装置の搬入、電源の確保、熟練作業者の確
保等が必要となシ、場所によってはこれらの準備が不可
能な場合もあシ、また、コスト、工期等を要する。
(1) Welding is a simple method, but when repairing on-site, it is necessary to bring in welding equipment, secure a power supply, secure skilled workers, etc., and these preparations may not be possible depending on the location. However, it also requires cost, construction time, etc.

(2)材料によっては溶接が不可能なものもある。(2) Some materials cannot be welded.

(3)溶接する際には洗浄、錆落し、プラスト処理等前
処理および開先加工切断等が必要となシ、これに要する
費用、手間が多大となる。
(3) When welding, pre-treatments such as cleaning, rust removal, and blast treatment, and beveling cutting are required, which requires a great deal of cost and effort.

また、予熱、後熱処理等の加熱が必要な場合がある。Further, heating such as preheating and post-heat treatment may be necessary.

(4)補修を実施する際に天候、雰囲気調節等が必要と
なる場合がある。
(4) When carrying out repairs, it may be necessary to adjust the weather and atmosphere.

(5)溶接によシ欠陥が発生する場合がある。(5) Welding defects may occur.

(6)溶接部の耐腐食性が劣化したシ残留応力、熱影響
によシ使用上の障害が発生する場合がある。
(6) Problems in use may occur due to residual stress and thermal effects due to deteriorated corrosion resistance of the welded part.

(7)場合によっては工場まで搬入して補修しなければ
ならない。
(7) In some cases, it may be necessary to transport the product to the factory for repair.

(8)溶接ヒユーム煙の発生、作業足場の不安定、感電
等安全上の問題が発生する。
(8) Safety problems such as welding fume, unstable work footing, and electric shock may occur.

また肉盛法には上記溶接法と同様な欠点があり、接rW
 jflJ法ではその適用に当って金属板表面の前処理
に手間がか−シ、有機接着剤の場合には耐熱温度が低い
など接着性に問題がある。
In addition, the overlay method has the same drawbacks as the welding method described above, and
When applying the jflJ method, it requires a lot of effort to pre-treat the surface of the metal plate, and in the case of organic adhesives, there are problems with adhesion such as low heat resistance.

〔発明が解決しようとする問題点〕[Problem that the invention seeks to solve]

本発明は上記従来法におけるような欠点のない機器類損
傷部の補修材を提供しようとするものである。
The present invention aims to provide a repair material for damaged parts of equipment that does not have the drawbacks of the above-mentioned conventional methods.

〔問題点を解決するための手段〕[Means for solving problems]

本発明は金属粉、金属酸化物、金属炭酸塩及び珪酸アル
カリを含有してなることを特徴とする機器類損傷部補修
用の無機質組成物である。
The present invention is an inorganic composition for repairing damaged parts of equipment, which is characterized by containing metal powder, metal oxide, metal carbonate, and alkali silicate.

すなわち本発明は従来の機器類損傷部の補修法の欠点を
克服するため下記組成の無機組成物を用いたものである
That is, the present invention uses an inorganic composition having the following composition in order to overcome the drawbacks of conventional repair methods for damaged parts of equipment.

(1)入手性、取り扱いが容易であシ、長期間保管が可
能である無機質の珪酸アルカリをバインダとすることに
より、耐熱性向上を計った。
(1) Heat resistance was improved by using an inorganic alkali silicate as a binder, which is easily available, easy to handle, and can be stored for a long time.

珪酸アルカリの中では珪酸すh’Jウムが一般的である
が本発明品に対しては珪酸リチウム、珪酸カリウム等も
使用できる。
Among the alkali silicates, h'Jium silicate is commonly used, but lithium silicate, potassium silicate, etc. can also be used for the product of the present invention.

(2)被覆材中に適量の金属粉を混合することにより、
被覆材の■熱膨張係数、■熱伝導率等をコントローμし
皮膜の耐熱性、耐熱@撃性、密着性を数倍し、剥虐、削
れ等の欠陥発生を防止した。これらの性質は金属粉が基
材金属と焼結する条件で加熱あるいは使用することによ
り、焼結金属粉のアンカ効果が起こり一層密着性が良好
となる。−また熱交換等の用途に対しても充分使用でき
る。又、金属粉を混合することによシ、金属自体の持つ
耐食性、耐摩耗性、耐熱性等の特性を皮膜に付与するこ
とができる。
(2) By mixing an appropriate amount of metal powder into the coating material,
By controlling the coating material's thermal expansion coefficient and thermal conductivity, the film's heat resistance, heat impact resistance, and adhesion are multiplied, thereby preventing defects such as abrasion and abrasion. By heating or using these properties under conditions where the metal powder is sintered with the base metal, the anchor effect of the sintered metal powder occurs and the adhesion becomes even better. - It can also be used satisfactorily for purposes such as heat exchange. Furthermore, by mixing metal powder, the properties of the metal itself, such as corrosion resistance, abrasion resistance, and heat resistance, can be imparted to the film.

(3)金属酸化物、金属炭酸塩をともに皮膜形成の骨材
として用いることにより被覆材の膜形成能が向上し、常
温乾燥および低温加熱によシ気孔の少ない密着性良好な
皮膜を形成させることができる。また耐水性、耐薬品性
等が向上する。
(3) By using both metal oxides and metal carbonates as aggregates for film formation, the film-forming ability of the coating material is improved, and a film with good adhesion with few pores can be formed by drying at room temperature and heating at low temperature. be able to. Also, water resistance, chemical resistance, etc. are improved.

以上が本発明品の各構成要素の主な作用であるが、具体
的な用い方は次のようである。
The above are the main effects of each component of the product of the present invention, and the specific usage is as follows.

(1)珪酸アルカリ;被覆方法(例えばスプレー。(1) Alkali silicate; coating method (eg spraying).

はけ塗υ等)および他の構成成分の種類、量等に合せて
、配合割合を適量に調節することができる。珪酸アルカ
リの性質として水と良く混合し合うことから、水による
粘度、濃度調節が可能である。また、市販されている固
体珪酸アルカリを被覆時に水と混合して用いることもで
きる。
The blending ratio can be adjusted to an appropriate amount depending on the type and amount of the brush coating (brush coating υ, etc.) and other constituent components. Since the nature of alkali silicate is that it mixes well with water, it is possible to adjust the viscosity and concentration with water. Furthermore, a commercially available solid alkali silicate may be mixed with water at the time of coating.

(2)金属粉末;本発明方法の金属粉末の粒度は一般的
には1〜500pmのものであるが、その形状、大きさ
には特に規定はなく、被覆可能なものであれば使用でき
る。一般的には、AL、 W、 Mo、 Fe、 Cr
、 Ni、 Cuなどの金属及びそれらの合金が用いら
れる。
(2) Metal powder: The particle size of the metal powder used in the method of the present invention is generally from 1 to 500 pm, but there are no particular restrictions on its shape and size, and it can be used as long as it can be coated. Generally, AL, W, Mo, Fe, Cr
, Ni, Cu, and alloys thereof are used.

(3)骨材:本発明では金属酸化物、金属炭酸塩をとも
に骨材として添加するが、添加する物質の数は必要に応
じて増すこともできる。例えばAl40B、 TiO2
,Cr2O3,FezO3,Fe1ons MrO等の
金属酸化物あるいは3A740B’2SiO1,Cab
”AJ40B’2SiO1,CaO’MfO”2SiO
1等の複合酸化物を必要に応じて用いることができる。
(3) Aggregate: In the present invention, both metal oxides and metal carbonates are added as aggregates, but the number of substances to be added can be increased as necessary. For example, Al40B, TiO2
, Cr2O3, FezO3, Fe1ons MrO or other metal oxides or 3A740B'2SiO1, Cab
"AJ40B'2SiO1, CaO'MfO"2SiO
Composite oxides such as No. 1 can be used as necessary.

また、金属炭酸塩としてはCaC01,Na1CO1,
MfC03等を用いることができるこれら炭酸塩は珪酸
アルカリの硬化剤としても作用することが知られている
が、必要に応じて他のリン酸塩、水酸化物、硼酸塩等の
硬化剤を用いることができる。一般に、これら骨材の粒
度はSOOμm以下のものが用いられる。
In addition, metal carbonates include CaC01, Na1CO1,
MfC03 etc. can be used. Although these carbonates are known to also act as hardening agents for alkali silicate, other hardening agents such as phosphates, hydroxides, borates etc. can be used as necessary. be able to. Generally, the particle size of these aggregates used is SOOμm or less.

〔作用〕[Effect]

一般に機器等を補修する場合、色々な原因、要因によシ
破損、損耗、消失等が起った部分を同一材質あるいは異
種材質で補充する必要があるが、これらの補充材はその
使用環境で充分な強度耐久性を有することが必要とされ
る。本発明の機器類損傷部補修材では前に提出した無機
質被覆材(特願昭61〜38402)等の容易に補充可
能で乾燥硬化後は優れた耐久性をもつ物質を用いるもの
で次の機能、作用を有している。
Generally, when repairing equipment, etc., it is necessary to replenish parts that have been damaged, worn out, lost, etc. due to various causes or factors with the same or different materials, but these replenishing materials are suitable for the usage environment. It is required to have sufficient strength and durability. The repair material for damaged parts of equipment of the present invention uses a material that can be easily replenished and has excellent durability after drying and hardening, such as the previously submitted inorganic coating material (Patent Application No. 61-38402), and has the following functions: , has an effect.

(1)施工性;流動物であるため施工に際しては誰にで
もでき、大きな設備を必要とし ないことから、迅速、低費用で行な うことができる。
(1) Workability: Since it is a fluid, anyone can install it, and since it does not require large equipment, it can be done quickly and at low cost.

(2)耐久性;使用環境において比較的長期間の耐久性
が必要とされるが、本発明の無 機質組成物を用いた場合、耐熱性。
(2) Durability: Relatively long-term durability is required in the usage environment, but when the inorganic composition of the present invention is used, it has heat resistance.

耐熱衝撃性、耐薬品性等が優れてお り補修部において基材と同等あるい は、それ以上の耐久性を確保できる。Excellent thermal shock resistance, chemical resistance, etc. In the repaired area, it is equivalent to or equal to the base material. can ensure greater durability.

また圧力が負荷している部分等強度 面での強化が要求されるような部位 に対しては、金属、無機質で作られ た繊維・布等の補強材を同時に埋め 込むことによシ目的を達成すること が可能である。Also, the strength of the parts where pressure is applied Areas that require surface reinforcement For those made of metal or inorganic materials Fill in reinforcing materials such as fibers and cloth at the same time. to achieve one's purpose by is possible.

(3)接着性;乾燥後の基材との付着力は溶接等に比べ
ると小さいものの、特に大きな 力が作用しない部分の補修に対して は充分使用できる。また、使用環境 が高温、低温においても強固な付着 力を維持することができる。
(3) Adhesion: Although the adhesion force to the base material after drying is smaller than that of welding, etc., it can be used satisfactorily for repairing areas where no particularly large force is applied. In addition, strong adhesion can be maintained even in high and low temperature environments.

(4)安全性:人体に害を及ぼすことはなく、また、基
材に対しても、熱影響、残留応力 等の害を及ぼさずに使用できる。
(4) Safety: It does not cause any harm to the human body, and it can be used without causing any harm to the base material, such as thermal effects or residual stress.

以下、本発明の具体的な実施例を、下表の無機質組成物
を使用して行った。
Hereinafter, specific examples of the present invention were carried out using the inorganic compositions shown in the table below.

*;主成分Sing、Nano 、A/40g、MfO
、KIOで、5iO1;73%、 CaO:8〜10%
、 A740H、Nag O、M? O:各1.5〜&
5%の化合物 実施例1;第1図に熱交換器管板7ランジ部の補修例を
示した。燃焼ガス中に含ま れる喘食成分により管板フランジ部 が腐食損傷を受けたため損傷部5を 削除して上記無機質組成物6を充填 した。図中、1はガス室(炭素m>、 2は本体胴板(炭素鋼)、3はチュ ーブ(ステンレスN)、4はボルト 穴である。
*;Main components Sing, Nano, A/40g, MfO
, KIO, 5iO1; 73%, CaO: 8-10%
, A740H, Nag O, M? O: 1.5~&
5% Compound Example 1: Fig. 1 shows an example of repair of the flange portion of heat exchanger tube sheet 7. Since the tube plate flange portion was corroded and damaged by the wheezing components contained in the combustion gas, the damaged portion 5 was removed and filled with the above-mentioned inorganic composition 6. In the figure, 1 is a gas chamber (carbon m>), 2 is a main body plate (carbon steel), 3 is a tube (stainless steel N), and 4 is a bolt hole.

実施例2:第2図に煙道の補修例を示す。煙道管1はチ
タンで製作されており溶接 が困難であつ永ため、炭素鋼2のあ て板を補修部3に無機質組成物4で はシつけ、煙道にあいた腐食孔をふ さいだ。
Example 2: Figure 2 shows an example of flue repair. The flue pipe 1 is made of titanium, and welding is difficult and takes a long time, so a carbon steel patch plate 2 is applied to the repaired part 3 with an inorganic composition 4 to close the corrosion hole in the flue.

実施例3:第3図に煙道の補修例を示す。煙道1は炭素
鋼製で内面にFRPライニ ング2が施工されているが、FRP ライニング2の劣化により煙道1本 体が損傷したので現地でフイニング した新煙道1を溶接で接続した。そ の溶接部3の周辺を上記無機質組成 物4で補修を行なった例である。
Example 3: Figure 3 shows an example of flue repair. The flue 1 is made of carbon steel and has an FRP lining 2 installed on its inner surface, but due to deterioration of the FRP lining 2, the flue 1 itself was damaged, so a new flue 1, which was finned on site, was connected by welding. This is an example in which the area around the welded portion 3 was repaired using the inorganic composition 4 described above.

実施例4;反応容器の補修例を第4図に示す。Example 4: An example of repair of a reaction vessel is shown in FIG.

外板1の小さな貫通孔発生部を無機 質組成物2を充填して埋めた。Inorganic material is used to form small through-holes in the outer panel It was filled with quality composition 2 and buried.

〔発明の効果〕〔Effect of the invention〕

実施例に示したように補修を極めて簡便に短期間、低コ
ストで行なうことができ、また、従来法の溶接等を行な
った時に生ずる残留応力、熱影響等の密書を回避するこ
とができる。
As shown in the embodiments, repairs can be carried out very simply, in a short period of time, and at low cost, and secretions such as residual stress and thermal effects that occur when welding using conventional methods can be avoided.

さらに従来補修不可能な部分、材料についても本発明無
機質組成物を用いて補修することが可能である。
Furthermore, parts and materials that cannot be repaired conventionally can be repaired using the inorganic composition of the present invention.

【図面の簡単な説明】[Brief explanation of the drawing]

第1〜第4図に、本発明補修用無機組成物を具体的機器
に過用した場合を説明するための図である。 復代理人  内 1)  明 復代理人  萩 原 亮 − 復代理人  安 西 篤 夫 第3図 第4図
1 to 4 are diagrams for explaining cases where the inorganic composition for repair of the present invention is overused in specific equipment. Sub-Agents 1) Meifuku Agent Ryo Hagiwara - Sub-Agent Atsuo Anzai Figure 3 Figure 4

Claims (1)

【特許請求の範囲】[Claims] 金属粉、金属酸化物、金属炭酸塩及び珪酸アルカリを含
有してなることを特徴とする機器類損傷部補修用の無機
質組成物。
An inorganic composition for repairing damaged parts of equipment, characterized by containing metal powder, metal oxide, metal carbonate, and alkali silicate.
JP24413786A 1986-10-16 1986-10-16 Inorganic composition for repairing damaged equipments Pending JPS6399267A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP24413786A JPS6399267A (en) 1986-10-16 1986-10-16 Inorganic composition for repairing damaged equipments

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP24413786A JPS6399267A (en) 1986-10-16 1986-10-16 Inorganic composition for repairing damaged equipments

Publications (1)

Publication Number Publication Date
JPS6399267A true JPS6399267A (en) 1988-04-30

Family

ID=17114309

Family Applications (1)

Application Number Title Priority Date Filing Date
JP24413786A Pending JPS6399267A (en) 1986-10-16 1986-10-16 Inorganic composition for repairing damaged equipments

Country Status (1)

Country Link
JP (1) JPS6399267A (en)

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