JPS6381175A - Waterproofing coating agent - Google Patents
Waterproofing coating agentInfo
- Publication number
- JPS6381175A JPS6381175A JP22706286A JP22706286A JPS6381175A JP S6381175 A JPS6381175 A JP S6381175A JP 22706286 A JP22706286 A JP 22706286A JP 22706286 A JP22706286 A JP 22706286A JP S6381175 A JPS6381175 A JP S6381175A
- Authority
- JP
- Japan
- Prior art keywords
- solution
- waterproof coating
- butyl rubber
- component
- coating agent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000011248 coating agent Substances 0.000 title claims abstract description 36
- 238000004078 waterproofing Methods 0.000 title description 5
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 18
- 229920005549 butyl rubber Polymers 0.000 claims abstract description 15
- 239000000843 powder Substances 0.000 claims abstract description 14
- -1 isocyanate compound Chemical class 0.000 claims abstract description 9
- 244000043261 Hevea brasiliensis Species 0.000 claims abstract description 8
- 239000012948 isocyanate Substances 0.000 claims abstract description 8
- 229920003052 natural elastomer Polymers 0.000 claims abstract description 8
- 229920001194 natural rubber Polymers 0.000 claims abstract description 8
- 239000003960 organic solvent Substances 0.000 claims abstract description 8
- 239000004576 sand Substances 0.000 claims abstract description 6
- 239000000377 silicon dioxide Substances 0.000 claims abstract description 6
- 238000000576 coating method Methods 0.000 claims description 33
- 239000000463 material Substances 0.000 claims description 12
- 239000000203 mixture Substances 0.000 claims description 5
- 239000003795 chemical substances by application Substances 0.000 claims description 4
- 239000002075 main ingredient Substances 0.000 claims description 4
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 abstract description 12
- UPMLOUAZCHDJJD-UHFFFAOYSA-N 4,4'-Diphenylmethane Diisocyanate Chemical compound C1=CC(N=C=O)=CC=C1CC1=CC=C(N=C=O)C=C1 UPMLOUAZCHDJJD-UHFFFAOYSA-N 0.000 abstract description 4
- 238000002156 mixing Methods 0.000 abstract description 4
- 239000000758 substrate Substances 0.000 abstract description 3
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 abstract description 2
- 239000008096 xylene Substances 0.000 abstract description 2
- 238000012360 testing method Methods 0.000 description 5
- 238000005299 abrasion Methods 0.000 description 4
- 230000000704 physical effect Effects 0.000 description 4
- 238000003756 stirring Methods 0.000 description 4
- 238000010276 construction Methods 0.000 description 3
- ALQLPWJFHRMHIU-UHFFFAOYSA-N 1,4-diisocyanatobenzene Chemical compound O=C=NC1=CC=C(N=C=O)C=C1 ALQLPWJFHRMHIU-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 238000010292 electrical insulation Methods 0.000 description 2
- 239000004570 mortar (masonry) Substances 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- ZXHZWRZAWJVPIC-UHFFFAOYSA-N 1,2-diisocyanatonaphthalene Chemical compound C1=CC=CC2=C(N=C=O)C(N=C=O)=CC=C21 ZXHZWRZAWJVPIC-UHFFFAOYSA-N 0.000 description 1
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 238000005452 bending Methods 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 238000007689 inspection Methods 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 230000035939 shock Effects 0.000 description 1
- DVKJHBMWWAPEIU-UHFFFAOYSA-N toluene 2,4-diisocyanate Chemical compound CC1=CC=C(N=C=O)C=C1N=C=O DVKJHBMWWAPEIU-UHFFFAOYSA-N 0.000 description 1
- 238000011041 water permeability test Methods 0.000 description 1
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
- Paints Or Removers (AREA)
Abstract
Description
【発明の詳細な説明】
本発明は、ブチルゴムの有機溶剤溶液を主体とした防水
被覆剤に関する。DETAILED DESCRIPTION OF THE INVENTION The present invention relates to a waterproof coating material mainly comprising a solution of butyl rubber in an organic solvent.
ブチルゴムは、耐オゾン性、耐老化性、耐候性、気密性
、耐熱性、電気絶縁性、耐化学薬品性、衝撃吸収性、耐
摩耗性、弾力性、対抗張性、防水性など、すぐれた特性
を有するため、成形品として多くのものが知られている
。Butyl rubber has excellent properties such as ozone resistance, aging resistance, weather resistance, airtightness, heat resistance, electrical insulation, chemical resistance, shock absorption, abrasion resistance, elasticity, anti-tension properties, and waterproof properties. Due to their characteristics, many molded products are known.
このような特性を有するため、防水被覆剤としての利用
も試みられたが、溶液として塗布した場合に、基材との
接着性、引張り強度、耐候性、および耐摩耗性の点で十
分に満足すべきものかえられず、結局、防水用としては
ブチルゴムをシートに成形し、これを防水工事用として
現場において接着剤で貼り付ける方法がとられていたも
のである。Due to these properties, attempts have been made to use it as a waterproof coating, but when applied as a solution, the adhesion to the substrate, tensile strength, weather resistance, and abrasion resistance are fully satisfactory. What should have been done could not be changed, and in the end, the method used for waterproofing was to form butyl rubber into sheets and paste them with adhesive on site for waterproofing work.
本発明者は、ブチルゴムの防水性能を活かし基材との接
着性、引張り強度、耐候性、および耐摩耗性にすぐれた
防水被覆剤について研究を重ねた結果、その硬化剤とし
てイソシアネート化合物を使用することにより、上記特
性がすぐれた防水被覆剤を得ることを見い出し、本発明
に至ったものである。As a result of repeated research into waterproof coatings that take advantage of the waterproof performance of butyl rubber and have excellent adhesion to substrates, tensile strength, weather resistance, and abrasion resistance, the inventors have discovered the use of isocyanate compounds as the curing agent. The inventors have discovered that a waterproof coating having the above-mentioned properties can be obtained by doing so, and have thus arrived at the present invention.
本発明の防水被覆剤は、溶液状で直接施工面に塗布する
ことができるため、従来のようなシート施工に比較して
、格段に作業性にすぐれ、しかも、より完全な防水塗膜
が効率的に形成することができるという特徴を有する。The waterproof coating material of the present invention can be directly applied to the construction surface in solution form, so it is much easier to work with than conventional sheet construction, and moreover, a more complete waterproof coating is produced more efficiently. It has the characteristic that it can be formed in a specific manner.
本発明によれば、ブチルゴムの有機溶剤溶液を主剤とし
、これに、硬化剤としてイソシアネート化合物を使用す
ることにより１強力な防水塗膜を形成する防水被覆剤か
えられるものである。According to the present invention, a waterproof coating that forms a strong waterproof coating film is obtained by using a solution of butyl rubber in an organic solvent as the main ingredient and using an isocyanate compound as a hardening agent.
また、本発明の防水被覆主剤に天然ゴム粉末を添加する
と、塗膜の弾性を増強することができるし、また、珪砂
粉末を添加すると、塗膜の硬度を高めることができ、こ
れら配合剤は必要に応じて併用することもできる。In addition, adding natural rubber powder to the main waterproof coating material of the present invention can enhance the elasticity of the coating film, and adding silica sand powder can increase the hardness of the coating film. They can also be used together if necessary.
主剤を構成するブチルゴムは、それを溶解する有機溶剤
に溶解して溶液状にするものであり。Butyl rubber, which constitutes the main ingredient, is dissolved in an organic solvent to form a solution.
有機溶剤としては、トルエンまたはキシレンが特に好ま
しい。Particularly preferred organic solvents are toluene or xylene.
天然ゴム粉末とは常法により加硫した天然ゴムを粉末化
したものであり、その粒度は大体４０メツシユ以下のも
のが塗膜の性能上好ましく、その添加率はブチルゴム溶
液に対して１０〜２５（重量）％が好ましく、１５〜２
０％が特に好ましい。Natural rubber powder is powdered natural rubber that has been vulcanized by a conventional method, and its particle size is preferably about 40 mesh or less for the performance of the coating film, and the addition rate is 10 to 25 mesh to the butyl rubber solution. (weight)%, preferably 15-2
0% is particularly preferred.
また、珪砂粉末は２７０メツシユ以下の微細なものが好
適に使用され、混合割合はブチルゴム溶液に対して５〜
１５％が好ましく、天然ゴム粉末と一緒に添加する場合
は、両者の添加率はブチルゴム溶液に対して２５％を超
えないことが好ましい。In addition, fine silica sand powder of 270 mesh or less is preferably used, and the mixing ratio is 5 to 5 to butyl rubber solution.
15% is preferred, and when added together with natural rubber powder, it is preferred that the addition rate of both does not exceed 25% relative to the butyl rubber solution.
硬化剤としてのイソシアネート化合物は防水被覆主剤に
対して、約３〜４％の量を添加するのが好ましく、通常
、１８Ｑ缶入りの防水被覆主剤に対しては予じめ別の容
器に約５４０ｃｃ〜？２０圓のイソシアネート化合物を
入れたものを用意しておき、工事現場にて両者を混合攪
拌し、塗布するのが便利である。It is preferable to add the isocyanate compound as a hardening agent in an amount of about 3 to 4% to the main waterproof coating material. Usually, about 540 cc of the main waterproof coating material in a 18Q can is added in advance to a separate container. ~? It is convenient to prepare a product containing 20 g of isocyanate compound, mix and stir the two at the construction site, and apply the mixture.
この際、塗膜の硬化反応は混合攪拌開始後約１時間で開
始しく気温２ｏ℃の場合）、約３時間後には耐水性の塗
膜を形成する。At this time, the curing reaction of the coating film starts about 1 hour after the start of mixing and stirring (at a temperature of 2° C.), and a water-resistant coating film is formed after about 3 hours.
しかし、この段階ではまだ塗膜の強度が十分でなく、２
４時間後に歩行に耐える程度の強度になるが１重量物や
突起物を設置するのに十分な強度が得られるのには約５
日程度の時間が必要である。However, at this stage, the strength of the coating film was still insufficient, and 2
After 4 hours, it will be strong enough to withstand walking, but it will take about 5 hours to get enough strength to place heavy objects or protrusions.
It takes about a day.
本発明において使用するインシアネート化合物としては
、芳香族イソシアネートが好適に使用することができる
。As the incyanate compound used in the present invention, aromatic isocyanates can be suitably used.
具体的には、
ジフェニルメタンジイソシアネート
パラフェニレンジイソシアネート
クロロフェニルジイソシアネート
トルエンジイソシアネート
ナフタレンジイソシアネート
などが使用され、特に好ましくはジフェニルメタンジイ
ソシアネートが使用される。Specifically, diphenylmethane diisocyanate, p-phenylene diisocyanate, chlorophenyl diisocyanate, toluene diisocyanate, naphthalene diisocyanate, etc. are used, and diphenylmethane diisocyanate is particularly preferably used.
本発明の防水被覆剤は、上記の様な特性を有するため、
一般屋上防水、廊下、ベランダの防水、コンクリートや
金属の耐酸塗装、水槽などの内部塗装、化学工場の耐酸
法塗装、電気絶縁塗装、一般防錆塗装などの巾広い用途
に用いられるものであり、とくに、天然粉末ゴムを添加
した防水被覆剤を歩行面に塗布した場合は防水性とあわ
せて適度の弾性があるため、歩行者に快適な歩行性を与
えることができる。Since the waterproof coating material of the present invention has the above characteristics,
It is used for a wide range of applications such as general rooftop waterproofing, waterproofing of hallways and balconies, acid-resistant coating of concrete and metal, interior coating of water tanks, acid-resistant coating of chemical factories, electrical insulation coating, and general anti-corrosion coating. In particular, when a waterproof coating containing natural powder rubber is applied to the walking surface, it has not only waterproof properties but also appropriate elasticity, so it can provide pedestrians with a comfortable walking experience.
実施例 １゜
ブチルゴム２００ｋｇをトルエン８０Ｑに溶解し、十分
に攪拌してブチルゴムのトルエン溶液をつくる。こうし
てつくった約２００ Ｑの防水被覆主剤に約７．６Ｑの
ジフェニルメタンジイソシアネートを混合しすばやく攪
拌する。Example 1 200 kg of butyl rubber was dissolved in 80Q toluene and thoroughly stirred to prepare a toluene solution of butyl rubber. Approximately 7.6 Q of diphenylmethane diisocyanate is mixed with approximately 200 Q of the waterproof coating base material prepared in this manner and stirred rapidly.
こうしてえられた防水被覆剤を基材（フレキシブル板、
およびモルタル板）に、約１．５ｍの厚さにヘラ塗りし
約１４日間室温で養生し、物性試験に供した。The waterproof coating obtained in this way is used as a base material (flexible board,
The mixture was applied to a mortar plate (and a mortar board) to a thickness of about 1.5 m, cured at room temperature for about 14 days, and then subjected to physical property tests.
このものを、財団法人 日本塗料検査協会果皮部検査所
に物性試験を依頼したところ別表に示す試験結果が報告
された。When we requested physical property testing of this material to the Pericarp Division Inspection Center of the Japan Paint Inspection Association, the test results shown in the attached table were reported.
実施例 ２゜
実施例１でえられた防水被覆主剤２００１２に４０メツ
シユ以下の粒径を有する天然ゴム粉末２５蹟を混合し、
約３時間両者が均質になるまで十分に攪拌する。この混
合攪拌を十分に行わないと、えられた塗膜は不均質にな
り十分な耐候性かえられない。Example 2゜ 25 pieces of natural rubber powder having a particle size of 40 mesh or less were mixed with the waterproof coating base material 20012 obtained in Example 1,
Stir thoroughly for about 3 hours until both are homogeneous. If this mixing and stirring is not carried out sufficiently, the resulting coating film will be non-uniform and will not have sufficient weather resistance.
これに、７Ｑのパラフェニレンジイソシアネートを混合
し、フレキシブル板に約２ｎｎの厚さにヘラ塗りし、１
４日後実施例１と同様に物性を試験したところ次の結果
をえた・
透水試験（ｍ 、ｇ ） ｏ、。Mix this with 7Q paraphenylene diisocyanate, apply it on a flexible board to a thickness of about 2nn, and
After 4 days, physical properties were tested in the same manner as in Example 1, and the following results were obtained: Water permeability test (m, g) o.
引張り強さくｋｇ／ａＪ） ９．８付着強さくｋ
ｇ ｆ ／ａＪ） ４．５摩耗試験（ｍｇ）
２１ｇ促進耐候試験 ねれ、及びはが
れなしまた、天然ゴム粉末にさらに珪砂粉末を加えたも
の、および珪砂粉末のみを添加した防水被覆主剤を使用
したものも、上記とほぼ同様の物性を示し、いずれも強
力な防水塗膜かえられることが確かめられた。Tensile strength kg/aJ) 9.8 Adhesion strength k
g f /aJ) 4.5 Abrasion test (mg)
21g Accelerated Weathering Test No bending or peeling In addition, products containing natural rubber powder with silica sand powder added, and products using a waterproof coating base material containing only silica sand powder, showed almost the same physical properties as above, and eventually It was also confirmed that a strong waterproof coating could be created.
Claims (2)
と、硬化剤としてのイソシアネート化合物からなること
を特徴とする防水被覆剤。(1) A waterproof coating agent comprising a waterproof coating main ingredient consisting of a solution of butyl rubber in an organic solvent and an isocyanate compound as a curing agent.
よび／または、珪砂粉末を混合したものを防水被覆主剤
とすることを特徴とする特許請求の範囲第１項記載の防
水被覆剤。(2) The waterproof coating material according to claim 1, characterized in that the waterproof coating main ingredient is a mixture of natural rubber powder and/or silica sand powder in an organic solvent solution of butyl rubber.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP22706286A JPS6381175A (en) | 1986-09-25 | 1986-09-25 | Waterproofing coating agent |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP22706286A JPS6381175A (en) | 1986-09-25 | 1986-09-25 | Waterproofing coating agent |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS6381175A true JPS6381175A (en) | 1988-04-12 |
| JPH0375583B2 JPH0375583B2 (en) | 1991-12-02 |
Family
ID=16854930
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP22706286A Granted JPS6381175A (en) | 1986-09-25 | 1986-09-25 | Waterproofing coating agent |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS6381175A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH02158670A (en) * | 1988-12-09 | 1990-06-19 | Mataichiro Hirao | Conductive and heat-insulation type water-proof coating agent |
| KR100421333B1 (en) * | 2001-05-15 | 2004-03-06 | 중앙방수기업주식회사 | Coating for waterproofing mainly consisting of styrene butadien styrene resin mixed with rubber powder and manufacturing method thereof |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS51585A (en) * | 1974-06-24 | 1976-01-06 | Toray Industries | SEKISOFUIRUMU |
-
1986
- 1986-09-25 JP JP22706286A patent/JPS6381175A/en active Granted
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS51585A (en) * | 1974-06-24 | 1976-01-06 | Toray Industries | SEKISOFUIRUMU |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH02158670A (en) * | 1988-12-09 | 1990-06-19 | Mataichiro Hirao | Conductive and heat-insulation type water-proof coating agent |
| KR100421333B1 (en) * | 2001-05-15 | 2004-03-06 | 중앙방수기업주식회사 | Coating for waterproofing mainly consisting of styrene butadien styrene resin mixed with rubber powder and manufacturing method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0375583B2 (en) | 1991-12-02 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JPH0791455B2 (en) | Composition for coating, sealing and protecting an object to be treated | |
| JPH0196277A (en) | Adhesive composition | |
| JPS6381175A (en) | Waterproofing coating agent | |
| JPH111656A (en) | Aqueous primer composition | |
| JP2000007989A5 (en) | ||
| JPS6126676A (en) | Urethane resin coating material composition | |
| JPH09183942A (en) | Air-drying polyurethane coating material | |
| JPH0932239A (en) | Tiling/dressing method for outer wall material | |
| JPS6328474B2 (en) | ||
| RU2086596C1 (en) | Hydroinsulating composition for coatings | |
| JPS63130676A (en) | Two-pack epoxy coating composition | |
| JPS6328923B2 (en) | ||
| RU2790264C2 (en) | Polyurethane protective coating | |
| JPH02158670A (en) | Conductive and heat-insulation type water-proof coating agent | |
| JPH08311392A (en) | Epoxy resin coating material | |
| JPS5817177A (en) | Coating composition for power transmission pylon | |
| RU2176228C1 (en) | Composition for anticorrosive and hydroinsulating coatings | |
| JPS625192B2 (en) | ||
| RU2126808C1 (en) | Epoxy composition for applying to filling floors | |
| SU1560539A1 (en) | Composition for coating | |
| RU2188838C1 (en) | Polyurethane composition for coatings | |
| RU2192440C1 (en) | Polyurethane composite for cover | |
| CN106752244B (en) | Aqueous double-component atomic ash and preparation method thereof | |
| SU907032A1 (en) | Waterproofing composition | |
| JP2833676B2 (en) | Concrete floor coating method |