JPS6373243A - Resist pattern forming method - Google Patents

Resist pattern forming method

Info

Publication number
JPS6373243A
JPS6373243A JP22023486A JP22023486A JPS6373243A JP S6373243 A JPS6373243 A JP S6373243A JP 22023486 A JP22023486 A JP 22023486A JP 22023486 A JP22023486 A JP 22023486A JP S6373243 A JPS6373243 A JP S6373243A
Authority
JP
Japan
Prior art keywords
resist pattern
resist
light
film
moisture
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP22023486A
Other languages
Japanese (ja)
Inventor
Toru Koyama
徹 小山
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mitsubishi Electric Corp
Original Assignee
Mitsubishi Electric Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mitsubishi Electric Corp filed Critical Mitsubishi Electric Corp
Priority to JP22023486A priority Critical patent/JPS6373243A/en
Publication of JPS6373243A publication Critical patent/JPS6373243A/en
Pending legal-status Critical Current

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Classifications

    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03FPHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
    • G03F7/00Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
    • G03F7/004Photosensitive materials
    • G03F7/09Photosensitive materials characterised by structural details, e.g. supports, auxiliary layers
    • G03F7/091Photosensitive materials characterised by structural details, e.g. supports, auxiliary layers characterised by antireflection means or light filtering or absorbing means, e.g. anti-halation, contrast enhancement

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  • Engineering & Computer Science (AREA)
  • Architecture (AREA)
  • Structural Engineering (AREA)
  • Physics & Mathematics (AREA)
  • General Physics & Mathematics (AREA)
  • Photosensitive Polymer And Photoresist Processing (AREA)

Abstract

PURPOSE:To improve a residual film ratio of an unexposed part of a resist film and a cross-sectional shape of the resist pattern by radiating light contg. a wavelength capable of decomposing a photosensitive agent to the resist film in an atmosphere which does not contain a moisture, before processing it. CONSTITUTION:The resist pattern is formed by radiating the light 4 contg. the wavelength capable of decomposing the photosensitive agent to the resist film 2 which is formed on the substrate 1 to be treated, using a mask 3, thereby selectively exposing the film 2. Next, the film 2 is wholly exposed by the light 4 having the wavelength capable of decomposing the photosensitive agent in the atmosphere which does not contain moisture (for example, <=10<-1>g/m<3> absolute moisture content), followed by processing it to form the prescribed resist pattern. Thus, the degree of insolubility to alkali of the unexposed part increases, and the selectivity of dissolution to the developer in the exposed and the unexposed parts increases. Thus, the residual film ratio of the unexposed part after processing and the cross-sectional shape of the resist pattern are improved.

Description

【発明の詳細な説明】 〔産業上の利用分野〕 この発明は、レジストパターンの形成方法に関するもの
である。
DETAILED DESCRIPTION OF THE INVENTION [Field of Industrial Application] The present invention relates to a method for forming a resist pattern.

〔従来の技術〕[Conventional technology]

第2図(a)〜(C)は従来のポジ型フォトレジストの
レジストパターン形成方法の工程を示す断面図であり、
まず、第2図(a)に示すように、被加工基板1上にレ
ジス) L! 2を’1 布tzプリベークし、次いで
、第2図(b)に示すように、マスク3を用いてレジス
ト膜2を感光剤の分解波長を含む光4による選択露光を
行った後、第2図(C)に示すように現像を行い、レジ
ストパターンを形成する。
FIGS. 2(a) to 2(C) are cross-sectional views showing the steps of a conventional resist pattern forming method for positive photoresist,
First, as shown in FIG. 2(a), a resist (L!) is placed on the substrate 1 to be processed. As shown in FIG. 2(b), the resist film 2 is selectively exposed to light 4 containing the decomposition wavelength of the photosensitizer using a mask 3, and then a second Development is performed as shown in Figure (C) to form a resist pattern.

一般にポジ型フォトレジストは、下記の一般式(I)で
表されるナフトキノンジアジドの誘導体を感光剤とし、
一般式(II )で表されるクレゾール型ノボラック樹
脂をバインダ樹脂としている。
Generally, positive photoresists use a naphthoquinonediazide derivative represented by the following general formula (I) as a photosensitizer, and
A cresol type novolak resin represented by the general formula (II) is used as the binder resin.

第2図(a)のレジスト膜2中は、一般式CI)と(I
I )の混合状態になっている。また、第2図(b)で
は、露光部2aにおいて感光剤(I)が光分解し、まず
、下記の一般式(III)で表されるケテンを生成する
。そして、さらにこのケテンは、空気中の水分により加
水分解され、一般式(IV)で表されるインデンガルポ
ン酸に速やかに移行する。
In the resist film 2 of FIG. 2(a), general formulas CI) and (I
I) is in a mixed state. Further, in FIG. 2(b), the photosensitizer (I) is photodecomposed in the exposed portion 2a, and first, ketene represented by the following general formula (III) is generated. Further, this ketene is hydrolyzed by moisture in the air and rapidly converts to indengalponic acid represented by general formula (IV).

○ (I)       (III)       (rv
)一般式(I)から(IV)への変化は、アルカリ難溶
物から易溶物への変化を意味する。この時点で変化して
いない未露光部は、一般式CI)と(II)の混合状態
にあり、露光部2aは(IV)と(’II)の混合状態
にある。
○ (I) (III) (rv
) The change from general formula (I) to (IV) means a change from a poorly soluble alkali to an easily soluble alkali. The unexposed area, which has not changed at this point, is in a mixed state of general formulas CI) and (II), and the exposed part 2a is in a mixed state of (IV) and ('II).

第2図(C)の現像工程では、アルカリ現像液を使用す
るため、一般式(IV) 、 (II)のいずれもアル
カリ可溶性である露光部2aは速やかに溶解し、アルカ
リ難溶物を含む未露光部は溶解せずにレジストパターン
を形成する。
In the developing step of FIG. 2(C), since an alkaline developer is used, the exposed area 2a of general formulas (IV) and (II), both of which are alkali-soluble, is quickly dissolved and contains poorly alkali-soluble substances. A resist pattern is formed in the unexposed area without being dissolved.

以上がポジ型フォトレジストのパターン形成方法および
その原理である。
The above is the method of forming a positive photoresist pattern and its principle.

〔発明が解決しようとする問題点〕[Problem that the invention seeks to solve]

上記のような従来のレジストパターン形成方法において
は、現像時、レジスト膜2に未露光部が残存するのは、
アルカリ難溶性の感光剤(I)とアルカリ可溶性のバイ
ンダ樹脂(II)との混合効果により、全体としてアル
カリ難溶性になっているためであるが、アルカリ可溶成
分の現像液中への溶出はやはり避けられず、未露光部の
膜減りが生じる。この膜減りは、レジメ) ffM厚の
減少、未露光部残膜率の低下と同時に、パターンエツジ
の角取れ、パターンの細り等のレジストパターン断面形
状の悪化につながっている。
In the conventional resist pattern forming method as described above, unexposed areas remaining in the resist film 2 during development are caused by
This is because the mixing effect of the poorly alkali-soluble photosensitizer (I) and the alkali-soluble binder resin (II) makes it poorly alkali-soluble as a whole, but the elution of alkali-soluble components into the developer is This is unavoidable, and film thinning occurs in unexposed areas. This thinning of the film leads to a decrease in the regimen) ffM thickness and a decrease in the remaining film rate in unexposed areas, as well as deterioration of the cross-sectional shape of the resist pattern, such as chamfering of pattern edges and thinning of the pattern.

この発明は、上記の問題点を解消するためになされたも
ので、レジスト膜の未露光部残膜率の向上およびレジス
トパターン断面形状の向上を可能にするレジストパター
ン形成方法を得ることを目的とするものである。
The present invention was made to solve the above problems, and an object of the present invention is to obtain a resist pattern forming method that makes it possible to improve the residual film rate of the unexposed part of the resist film and the cross-sectional shape of the resist pattern. It is something to do.

〔問題点を解決するための手段〕[Means for solving problems]

この発明に係るレジストパターン形成方法は、現像処理
前にレジスト膜に水分の存在しない雰囲気中で感光剤の
分解波長を含む光を照射するものである。
In the resist pattern forming method according to the present invention, a resist film is irradiated with light having a decomposition wavelength of a photosensitizer in an atmosphere free of moisture before development.

〔作用〕[Effect]

この発明においては、レジストHの未露光部の感光剤と
バインダ樹脂との間にエステル結合を生成し、アルカリ
可溶成分であるバインダ樹脂をアルカリ不溶化すること
から、現像液に対する露光部と未露光部の溶解選択性が
強められる。
In this invention, an ester bond is generated between the photosensitive agent and the binder resin in the unexposed area of the resist H, and the binder resin, which is an alkali-soluble component, is rendered alkali-insoluble. The solubility selectivity of the parts is enhanced.

〔実施例〕〔Example〕

第1図(a)〜(d)はこの発明のポジ型フォトレジス
トのパターン形成方法の工程を示す断面図であり、第1
図(a)、(b)、(d)は、第2図(a)〜(C)の
従来と同様の工程であり、第1図(C)はこの発明の主
要工程で、水分の存在しない雰囲気中における感光剤の
分解波長を含む光4の全面照射状態を示している。
FIGS. 1(a) to 1(d) are cross-sectional views showing the steps of the positive photoresist pattern forming method of the present invention.
Figures (a), (b), and (d) are the same steps as the conventional process shown in Figures 2 (a) to (C), and Figure 1 (C) is the main process of this invention, in which the presence of moisture is present. The figure shows a state in which the entire surface is irradiated with light 4 that includes the decomposition wavelength of the photosensitizer in an atmosphere with no heat.

すなわち、第1図(a)、(b)に示すように、被加工
基板1上に形成されたレジスト膜2に、マスク3を用い
て感光剤の分解波長を含む光4を照射して選択的に露光
し、レジストパターンを形成する。その後、第1図(C
)に示すように、水分の存在しない雰囲気中(例えば絶
対水分量1×10川g/m3以下)において感光剤の分
解波長を含む光4の全面照射を行い、現像して第1図(
d)に示すように、所望のレジストパターンを形成する
That is, as shown in FIGS. 1(a) and 1(b), a resist film 2 formed on a substrate 1 to be processed is irradiated with light 4 containing the decomposition wavelength of the photosensitizer using a mask 3, and selected. to form a resist pattern. After that, Figure 1 (C
), the entire surface is irradiated with light 4 that includes the decomposition wavelength of the photosensitizer in an atmosphere without moisture (for example, absolute moisture content is 1 x 10 g/m3 or less), and developed to produce a
As shown in d), a desired resist pattern is formed.

上記工程のうち、第1図(C)に示す工程の水分の存在
しない雰囲気とは、空気中の水分を除去した状IEを意
味し、これは真空下あるいは窒素。
Among the above steps, the moisture-free atmosphere in the step shown in FIG. 1(C) means an IE in which moisture in the air has been removed, and this is under vacuum or nitrogen.

アルゴン等の不活性なガスによる置換により可能である
。また、照射する感光剤の分解波長を含む光4は、第1
図(b)で照射する通常の露光と同質の光、すなわち通
常、波長365 n m 、 405nm、436nm
のいずれか、あるいはすべてを含む光であればよい。た
だし、光架橋生成の可能性のある波長300nm以下の
光を含んではならない。さらに、光の照度および照射エ
ネルギーも、第1図(b)の通常の露光と同程度でよい
This is possible by replacing with an inert gas such as argon. Further, the light 4 including the decomposition wavelength of the photosensitive agent to be irradiated is the first
Light of the same quality as the normal exposure irradiated in figure (b), that is, usually wavelengths of 365 nm, 405 nm, 436 nm
Any light that includes any or all of the above is sufficient. However, it must not contain light with a wavelength of 300 nm or less, which may cause photocrosslinking. Furthermore, the illuminance and irradiation energy of the light may be on the same level as the normal exposure shown in FIG. 1(b).

以下に、第1図(C)の処理を従来方法に付加すること
により、現像の未露光部残膜率の向上およびレジストパ
ターン断面形状の向上等の効果が得られる理由を述べる
The reason why adding the process shown in FIG. 1(C) to the conventional method provides effects such as an improvement in the residual film rate in the unexposed area during development and an improvement in the cross-sectional shape of the resist pattern will be described below.

上述のとおり、第1図(b)の選択露光後、未露光部は
一般式(I)でナフトキノンジアジドの誘導体と、一般
式(n )で表されるクレゾール型ノボラックとの混合
状態にあり、露光部2aは、一般式(I)が変化して生
成した一般式(IV)で表されるインデンカルボン酸と
、一般式(II)のクレゾール型ノボラックとの混合状
態にある。この状態のときに、第1図(C)の処理、す
なわち水分の存在しない雰囲気下で感光剤の分解波長を
含む光4を全面照射すると、未露光部の感光剤は光分解
し、一般式(III)で表されるケテンを生成する。そ
して、ここでもし雰囲気中に水分が存在すれば、前述の
ように、ケテンは一般式(IV)のインデンカルボン酸
に変化するが、水分の存在しない雰囲気下では、ケテン
は一般式(V)で表されるように、クレゾール型ノボラ
ックの水酸基との間にエステル結合を生成する。
As mentioned above, after the selective exposure shown in FIG. 1(b), the unexposed area is in a mixed state of the naphthoquinone diazide derivative represented by the general formula (I) and the cresol type novolak represented by the general formula (n), The exposed area 2a is in a mixed state of indenecarboxylic acid represented by general formula (IV) produced by changing general formula (I) and cresol type novolac of general formula (II). In this state, when the entire surface is irradiated with light 4 containing the decomposition wavelength of the photosensitizer in an atmosphere without moisture, the photosensitizer in the unexposed area is photodecomposed, and the general formula A ketene represented by (III) is produced. If moisture is present in the atmosphere, ketene changes to indenecarboxylic acid of general formula (IV) as described above, but in an atmosphere without moisture, ketene changes to indenecarboxylic acid of general formula (V). As shown, an ester bond is formed between the hydroxyl group of the cresol type novolac.

り難溶性である一般式(I)がアルカリ可溶性である一
般式(rV)に変化するのに対し、水分非存在下での露
光では、アルカリ可溶性の一般式CU)がアルカリ難溶
性である一般式(V)に変化することを意味する。この
ようにして未露光部は、アルカリ可溶成分であるクレゾ
ール型ノボラックが、感光剤とエステル結合することに
よりアルカリ難溶化する。また、露光部2aでは、第1
図(b)の時点で感光剤は分解し、既に一般式(17)
のインデンカルボン酸に変化しているため、感光剤の分
解波長を含む光4を照射しても、変化は生じない。
However, when exposed to light in the absence of water, the alkali-soluble general formula (CU) changes to the alkali-soluble general formula (rV), which is poorly soluble. It means changing to formula (V). In this way, the unexposed area becomes poorly alkali-soluble by forming an ester bond with the photosensitizer by the cresol-type novolak, which is an alkali-soluble component. Further, in the exposure section 2a, the first
At the time of figure (b), the photosensitizer has decomposed and the general formula (17) has already been expressed.
Since it has changed to indene carboxylic acid, no change occurs even if it is irradiated with light 4 that includes the decomposition wavelength of the photosensitizer.

したがって、通常の空気中での選択露光後、現像処理前
に水分の存在しない雰囲気中で感光剤の分解波長を含む
光4を全面照射すると、未露光部が露光部2aに対して
選択的に変化し、アルカリ可溶成分が難溶化することに
より未露光部のアルカリ難溶度が増大する。そしてこの
ことは、現像液に対する露光部2aと未露光部との溶解
選択性の増大を意味し、その結果として、現像後の未露
光部残膜率の向上およびレジストパターン断面形状の向
上等の効果を与える。
Therefore, if the entire surface is irradiated with light 4 containing the decomposition wavelength of the photosensitizer in an atmosphere without moisture after selective exposure in normal air and before development processing, the unexposed areas will be selectively exposed to the exposed areas 2a. As a result, the alkali-soluble component becomes less soluble, thereby increasing the alkali-solubility of the unexposed area. This means an increase in dissolution selectivity between the exposed area 2a and the unexposed area with respect to the developer, and as a result, an improvement in the remaining film rate in the unexposed area after development and an improvement in the cross-sectional shape of the resist pattern. give effect.

なお、第1図(C)の処理は、詳細を前記した感光剤の
分解波長を含む光4を発生する光源と、真空状態あるい
は不活性なガスによる空気の置換を可能にした照射室を
有する装置を使用することにより可能である。しかし、
照射部に上記のような水分の存在しない雰囲気を作り出
す機能を付加すれば、ステッパープロジェクション等の
通常の露光装置でも処理可能となる。
The process shown in FIG. 1(C) has a light source that generates light 4 containing the decomposition wavelength of the photosensitizer described in detail above, and an irradiation chamber that allows air to be replaced by a vacuum state or an inert gas. This is possible by using a device. but,
If the function of creating an atmosphere free of moisture as described above is added to the irradiation section, processing can be performed using a normal exposure apparatus such as a stepper projection.

〔発明の効果〕 この発明は以上説明したとおり、レジスト膜を選択的に
露光し、現像処理することによって所定のレジストパタ
ーンを形成する方法において、現像処理前に水分の存在
しない雰囲気中で感光剤の分解波長を含む光を全面照射
する工程を付加するようにしたので、未露光部のアルカ
リ難溶度を増大させ、現像液に対する露光部と未露光部
の溶解選択性の増大が可能となる。そして、この結果と
して、現像後の未露光部残膜率の向上およびレジストパ
ターン断面形状の向上といった極めて大なる効果が得ら
れる。
[Effects of the Invention] As explained above, the present invention provides a method for forming a predetermined resist pattern by selectively exposing a resist film to light and developing it, in which a photosensitive agent is applied in an atmosphere free of moisture before the development process. By adding a step of irradiating the entire surface with light having a decomposition wavelength of . As a result, extremely large effects such as an improvement in the remaining film rate in the unexposed area after development and an improvement in the cross-sectional shape of the resist pattern can be obtained.

【図面の簡単な説明】[Brief explanation of the drawing]

第1図はこの発明の2=実施例を示すポジ型フォトレジ
ストのパターン形成方法の工程断面図、第2図は従来の
ポジ型フォトレジストのパターン形成方法の工程断面図
である。 図において、1は被加工基板、2はレジスト膜、3はマ
スク、4は感光剤の分解波長を含む光である。 なお、各図中の同一符号は同一または和名部分を示す。 代理人 大 岩 増 雄    (外2名)第1図 第2図 手続補正書(0発) 6岸3 20 昭和     月  日 「 特許庁長官殿              ゛”l −
: −tl、事件の表示   特願昭81−22023
4号2、発明の名称   レジストパターン形成方法3
、補正をする者 5、補正の対象 明細書の発明の詳細な説明の欄 6、補正の内容 (1)明細、!3第7頁1〜2行の「さらに、・・・・
・・同程度でよい。」を削除する。 (2)同じく第9頁19行の「ステッパープロジェクシ
ョン」を、「ステッパー、プロジェクション」と補正す
る。 以上
FIG. 1 is a process cross-sectional view of a positive photoresist pattern forming method showing a second embodiment of the present invention, and FIG. 2 is a process cross-sectional view of a conventional positive photoresist pattern forming method. In the figure, 1 is a substrate to be processed, 2 is a resist film, 3 is a mask, and 4 is light containing a decomposition wavelength of the photosensitizer. Note that the same reference numerals in each figure indicate the same parts or parts with Japanese names. Agent Masuo Oiwa (2 others) Figure 1 Figure 2 Procedural amendments (0) 6 Kishi 3 20 Showa Month Day ``Dear Commissioner of the Japan Patent Office゛''l -
: -tl, Display of incident Patent application 1981-22023
No. 4 2, Title of the invention: Resist pattern forming method 3
, Person making the amendment 5, Detailed description of the invention in the specification to be amended 6, Contents of the amendment (1) Specification,! 3, page 7, lines 1-2, “Furthermore,...
...The same level is fine. ” to be deleted. (2) Similarly, "Stepper Projection" on page 9, line 19 is corrected to "Stepper, Projection."that's all

Claims (2)

【特許請求の範囲】[Claims] (1)被加工基板上にレジスト膜を塗布し、ベーキング
後所定のパターンを選択的に露光し、現像処理すること
によってレジストパターンを形成する方法において、前
記現像処理前に前記レジスト膜に水分の存在しない雰囲
気中で感光剤の分解波長を含む光を照射する工程を含む
ことを特徴とするレジストパターン形成方法。
(1) In a method of forming a resist pattern by coating a resist film on a substrate to be processed, baking it, selectively exposing a predetermined pattern to light, and developing it, the resist film is free of moisture before the development process. A resist pattern forming method comprising the step of irradiating light having a decomposition wavelength of a photosensitizer in an atmosphere that does not exist.
(2)レジストは、ナフトキノンジアジドの誘導体とク
レゾール型ノボラック樹脂との組み合わせで構成される
ポジ型フォトレジストからなり、かつ水分の存在しない
雰囲気を真空あるいは不活性なガスによる置換、充填に
より作り出すことを特徴とする特許請求の範囲第(1)
項記載のレジストパターン形成方法。
(2) The resist is a positive photoresist composed of a combination of a naphthoquinone diazide derivative and a cresol type novolak resin, and a moisture-free atmosphere is created by vacuum or by replacing or filling with an inert gas. Characteristic Claim No. (1)
The resist pattern forming method described in Section 1.
JP22023486A 1986-09-17 1986-09-17 Resist pattern forming method Pending JPS6373243A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP22023486A JPS6373243A (en) 1986-09-17 1986-09-17 Resist pattern forming method

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP22023486A JPS6373243A (en) 1986-09-17 1986-09-17 Resist pattern forming method

Publications (1)

Publication Number Publication Date
JPS6373243A true JPS6373243A (en) 1988-04-02

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
JP22023486A Pending JPS6373243A (en) 1986-09-17 1986-09-17 Resist pattern forming method

Country Status (1)

Country Link
JP (1) JPS6373243A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH01243052A (en) * 1988-03-24 1989-09-27 Matsushita Electron Corp Resist pattern forming method
JPH02264960A (en) * 1989-04-06 1990-10-29 Matsushita Electron Corp Resist pattern forming method
JPH02264961A (en) * 1989-04-06 1990-10-29 Matsushita Electron Corp Resist pattern forming method

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH01243052A (en) * 1988-03-24 1989-09-27 Matsushita Electron Corp Resist pattern forming method
JPH02264960A (en) * 1989-04-06 1990-10-29 Matsushita Electron Corp Resist pattern forming method
JPH02264961A (en) * 1989-04-06 1990-10-29 Matsushita Electron Corp Resist pattern forming method

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