JPS6367641B2 - - Google Patents

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Publication number
JPS6367641B2
JPS6367641B2 JP54017402A JP1740279A JPS6367641B2 JP S6367641 B2 JPS6367641 B2 JP S6367641B2 JP 54017402 A JP54017402 A JP 54017402A JP 1740279 A JP1740279 A JP 1740279A JP S6367641 B2 JPS6367641 B2 JP S6367641B2
Authority
JP
Japan
Prior art keywords
bearing
temperature
pressure water
flow meter
cobalt
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
JP54017402A
Other languages
Japanese (ja)
Other versions
JPS55110754A (en
Inventor
Yoshio Senoo
Takehiro Shimomura
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Tokico Ltd
Original Assignee
Tokico Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Tokico Ltd filed Critical Tokico Ltd
Priority to JP1740279A priority Critical patent/JPS55110754A/en
Publication of JPS55110754A publication Critical patent/JPS55110754A/en
Publication of JPS6367641B2 publication Critical patent/JPS6367641B2/ja
Granted legal-status Critical Current

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  • Measuring Volume Flow (AREA)
  • Sliding-Contact Bearings (AREA)

Description

【発明の詳細な説明】[Detailed description of the invention]

本発明は、被測流体として高温高圧水が流され
る配管途中に、流量測定用羽根車を軸受を介して
回転自在に設けた高温高圧水用フローメータに関
する。 尚この明細書において流量とは単位時間当りに
配管を流れる高温高圧水の量のことであり、該単
位時間当りの流量に基づき該流量を時間に関して
積算することにより総流量を求め得る。 タービン式フローメータの羽根車の軸受には、
従来カーボン、リン青銅の如きメタル、超硬合
金、又はテフロンの如き樹脂が用いられている。
しかし乍ら、これら材料からなる軸受及びこの軸
受を用いたフローメータは、例えば温度300℃水
圧88Kg/cm2以下では長期に亘つては安定な機能を
発揮し難い。即ち、高温高圧下においては、カー
ボン軸受は、組織の脱落、メタル軸受は高温酸化
による腐蝕摩耗、そして樹脂軸受は熱劣化による
変質を夫々生起し、いずれも長期使用に耐え得な
い。また、超硬合金からなる軸受は、結合材とし
て作用するコバルト、ニツケル、クロム若しくは
モリブデン等の金属の高温酸化により、タングス
テンカーバイド、チタンカーバイド等の組織の脱
落を生起し、異常摩耗或いはカジリを発生すると
して超硬合金からなる軸受は使用されていないの
が実情である。 本発明は前記諸点に鑑みなされたものであり、
その目的とするところは、高温高圧水下において
も、耐腐蝕性、耐摩耗性、耐熱性及び靭性に優れ
長期の使用に耐え得る高温高圧水用軸受を有して
おり、長期間高温高圧水の流量を確実に測定し得
るフローメータを提供することにある。 本発明によれば、前記目的は、被測流体として
100℃、1気圧以上の高温高圧水が流れる配管途
中に流量測定用羽根車を軸受を介して回転自在に
設けた高温高圧水用フローメータにおいて、前記
軸受は、タングステンカーバイドをニツケル及び
コバルトからなる結合材で結合してなり、ニツケ
ル及びコバルトを夫々3乃至10重量%を含む超硬
合金からなる高温高圧水用フローメータにより達
成される。 次に本発明による好ましい一具体例のフローメ
ータを図面に基づいて説明する。 第1図において、1は、ハブ2と、このハブ2
の外周に複数枚植設された羽根3とからなる羽根
車であり、羽根車1は、ブツシユ4及びジヤーナ
ル5を介して軸6に回転可能に支持されている。
軸6の両端は、支持部材を介してタービンフロー
メータのケーシングに支持されている。ラジアル
方向の軸受の外輪としてのブツシユ4は、ハブ2
の中心中空部においてハブ2に嵌着されており、
羽根車1の回転と共に回転する。一方、ラジアル
方向の軸受の内輪としてのジヤーナル5は、その
中心中空部に軸6が嵌入されて、軸6に固着され
ている。7は、ブツシユ4に対するスラスト軸受
であり、羽根車1の両側において軸6に固着さ
れ、羽根3に対して被測定流体を案内する上流側
コーン部材8及び下流側コーン部材9に設けられ
ている。従つて、羽根車1の回転に際し、ブツシ
ユ4の内周面10がジヤーナル5の外周面に対し
て摺動し、またブツシユ4の両側面11が夫々ス
ラスト軸受7の側面12に対して摺動する。ここ
で、軸受を構成する、ブツシユ4、ジヤーナル5
及びスラスト軸受7の夫々を、結合材としてニツ
ケル及びコバルトを含有するタングステンカーバ
イドからなる超硬合金により形成すると、被測定
流体である水が高温かつ高圧、例えば温度最大
300℃、圧力88Kg/cm2の場合においても、ブツシ
ユ4、ジヤーナル5及びスラスト軸受7には、酸
化、組織の欠落はほとんど生起しないことが判明
した。尚、ニツケル及びコバルトを夫々3ないし
10重量%含ませることにより、より好ましい結果
が得られる。その結果、以上の如き構成を有する
フローメータでは長時間確実に100℃、1気圧以
上の高温高圧水の流量を測定し得る。 これに対してニツケルにより結合したタングス
テンカーバイドからなる軸受を用いた場合、高温
高圧水では軸受の組織の欠落が早期に発生し、ま
たコバルトにより結合したタングステンカーバイ
ドからなる軸受を用いた場合、軸受に腐蝕が生
じ、いずれの場合も極めて軸受の耐久性に劣り、
フローメータを長時間使用し得ないことが判明し
た。尚、クロムカーバイド又はチタンカーバイド
等の超硬合金材料によりブツシユ4等を形成した
場合においても、高温高圧水下では欠落又は腐蝕
を生じ、高温高圧下の長期の使用に耐え得ない。 尚、高温高圧水用のタービン式フローメータの
軸受の内輪のみ、又は外輪若しくはスラスト軸受
のみを前記組成で形式してもよく、加えて、前記
具体例に示すハブを外輪とし、軸を内輪として軸
受を構成してもよい。 次に、第2図を参照しながら、タングステンカ
ーバイドの結合材としてニツケルとコバルトを用
いた超硬合金製軸受によつて得られる効果につい
て述べる。 この効果を確認するための試験方法は下記の通
りである。 第2図に示すようにオートクレーブの蓋体(図
示せず)に気密且つ回転自在に取り付けられた軸
6の一端側にジヤーナル5を嵌着し、このジヤー
ナル5が軸6と一体的に回転し得るようにした。
羽根3の中心部にブツシユ4を固着し、ブツシユ
4を備えた羽根3を、軸6に嵌着されたジヤーナ
ル5に嵌入した後、ジヤーナル5の一端と摺動可
能なようにスラスト軸受7を軸6に固定し、軸6
の他端側に装着されたモータが回転した際に、羽
根3の軸受を構成するブツシユ4とジヤーナル
5、及び、ブツシユ4とスラスト軸受7との間で
それぞれ摺動が生起されるようにした。 同様にして、別の羽根を軸受を構成するブツシ
ユ、ジヤーナル及びスラスト軸受を介して軸6に
取り付け、一回の試験で対照超硬合金で形成され
た対照軸受と試験超硬合金で形成された試験軸受
の双方を同時に試験し得るようにした。 このようにして、軸受を介して軸6に取り付け
られた2個の羽根はオートクレーブ蓋体に取り付
けた回転止め20により固定し、軸6が回転した
際にこれらの羽根が回転し得ないようにした。 内容積約0.5のオートクレーブ内に0.4の蒸
溜水を入れた後、軸受を介して軸6に取り付けら
れた2個の羽根をオートクレーブ内に挿入して、
これらの軸受と羽根を蒸溜水中に浸漬し、オート
クレーブを90Kg/cm2以上の圧力に耐えるように密
閉した。 オートクレーブの内部空間に設けたヒータによ
り蒸溜水を300℃の温度に加熱し、所定期間この
温度下で軸6を回転させた後、軸6に取り付けた
軸受をオートクレーブ外に取り出し、顕微鏡観察
により軸受の腐蝕状況(摺動面と非摺動面の双
方)と摺動キズを評価した。蒸溜水の温度はオー
トクレーブ蓋体に設けた温度計により、またオー
トクレーブ内圧はオートクレーブ蓋体に取り付け
られた圧力計によつて計測した。 対照超硬合金(WC―5.3Co)で形成した対照
軸受と、試験超硬合金(WC―6Co―7Ni)で形
成した試験軸受について温度300℃、圧力87.6
Kg/cm2の条件下で腐蝕・摺動試験を行つた結果を
下表に示す(超硬合金組成を表す数値は重量%を
示す)。
The present invention relates to a high-temperature, high-pressure water flow meter in which a flow rate measuring impeller is rotatably provided via a bearing in the middle of a pipe through which high-temperature, high-pressure water flows as a fluid to be measured. In this specification, the flow rate refers to the amount of high-temperature, high-pressure water flowing through a pipe per unit time, and the total flow rate can be determined by integrating the flow rate over time based on the flow rate per unit time. The impeller bearing of a turbine flow meter has
Conventionally, carbon, metals such as phosphor bronze, cemented carbide, or resins such as Teflon have been used.
However, bearings made of these materials and flow meters using these bearings are difficult to exhibit stable functionality over a long period of time, for example, at temperatures of 300° C. and water pressures of 88 kg/cm 2 or less. That is, under high temperature and high pressure conditions, carbon bearings suffer from loss of structure, metal bearings undergo corrosive wear due to high temperature oxidation, and resin bearings undergo deterioration due to thermal deterioration, and none of these bearings can withstand long-term use. In addition, in bearings made of cemented carbide, high-temperature oxidation of metals such as cobalt, nickel, chromium, or molybdenum, which act as binders, causes structures such as tungsten carbide and titanium carbide to fall off, resulting in abnormal wear or galling. However, the reality is that bearings made of cemented carbide are not used. The present invention has been made in view of the above points,
The purpose is to provide bearings for high-temperature, high-pressure water that have excellent corrosion resistance, wear resistance, heat resistance, and toughness, and can withstand long-term use even under high-temperature, high-pressure water. An object of the present invention is to provide a flow meter that can reliably measure the flow rate of According to the invention, the purpose is to
A high-temperature, high-pressure water flow meter in which a flow rate measuring impeller is rotatably installed via a bearing in the middle of a pipe through which high-temperature, high-pressure water of 100° C. and 1 atm or more flows, and the bearing is made of tungsten carbide, nickel, and cobalt. This is achieved by a high-temperature, high-pressure water flow meter made of cemented carbide, which is bonded with a binder and contains 3 to 10% by weight of nickel and cobalt, respectively. Next, a preferred example of a flow meter according to the present invention will be explained based on the drawings. In FIG. 1, 1 indicates a hub 2 and this hub 2.
The impeller 1 is rotatably supported by a shaft 6 via a bush 4 and a journal 5.
Both ends of the shaft 6 are supported by the casing of the turbine flow meter via support members. The bush 4 as the outer ring of the radial bearing is connected to the hub 2.
is fitted into the hub 2 in the central hollow part of the
It rotates with the rotation of the impeller 1. On the other hand, the journal 5, which serves as the inner ring of the radial bearing, has a shaft 6 fitted into its central hollow portion and is fixed to the shaft 6. 7 is a thrust bearing for the bush 4, which is fixed to the shaft 6 on both sides of the impeller 1 and provided in the upstream cone member 8 and the downstream cone member 9 that guide the fluid to be measured with respect to the impeller 3. . Therefore, when the impeller 1 rotates, the inner circumferential surface 10 of the bush 4 slides against the outer circumferential surface of the journal 5, and both side surfaces 11 of the bush 4 slide against the respective side surfaces 12 of the thrust bearing 7. do. Here, a bush 4 and a journal 5 that constitute a bearing are shown.
If each of the thrust bearings 7 and 7 is made of a cemented carbide made of tungsten carbide containing nickel and cobalt as a binder, water, which is the fluid to be measured, will be exposed to high temperature and high pressure, for example, at maximum temperature.
It was found that even at 300° C. and a pressure of 88 kg/cm 2 , almost no oxidation or loss of structure occurred in the bush 4, journal 5, and thrust bearing 7. In addition, nickel and cobalt are each 3 or
More preferable results can be obtained by including 10% by weight. As a result, the flow meter having the above configuration can reliably measure the flow rate of high-temperature, high-pressure water at 100° C. and 1 atm or more for a long period of time. On the other hand, when a bearing made of tungsten carbide bonded with nickel is used, the structure of the bearing quickly breaks down in high-temperature, high-pressure water, and when a bearing made of tungsten carbide bonded with cobalt is used, Corrosion occurs, and in either case, the durability of the bearing is extremely poor.
It turned out that the flow meter could not be used for a long time. Even if the bushing 4 is made of a cemented carbide material such as chromium carbide or titanium carbide, it will chip or corrode under high-temperature, high-pressure water, and cannot withstand long-term use under high-temperature and high-pressure conditions. In addition, only the inner ring, or only the outer ring or thrust bearing of the bearing of a turbine-type flow meter for high-temperature, high-pressure water may be formed with the above composition.In addition, the hub shown in the above specific example may be used as the outer ring, and the shaft may be used as the inner ring. A bearing may also be provided. Next, with reference to FIG. 2, the effects obtained by a cemented carbide bearing using nickel and cobalt as binding materials for tungsten carbide will be described. The test method for confirming this effect is as follows. As shown in FIG. 2, a journal 5 is fitted onto one end of a shaft 6 that is airtightly and rotatably attached to the lid of an autoclave (not shown), and this journal 5 rotates integrally with the shaft 6. I tried to get it.
After fixing a bush 4 to the center of the blade 3 and fitting the blade 3 with the bush 4 into a journal 5 fitted to a shaft 6, a thrust bearing 7 is attached so that it can slide on one end of the journal 5. fixed to shaft 6,
When the motor attached to the other end rotates, sliding is caused between the bush 4 and the journal 5, which constitute the bearing of the blade 3, and between the bush 4 and the thrust bearing 7, respectively. . Similarly, another vane was attached to the shaft 6 through the bushing, journal and thrust bearings that constitute the bearing, and in one test a control bearing formed of the control cemented carbide and a test bearing formed of the test cemented carbide were tested. Both test bearings could be tested at the same time. In this way, the two blades attached to the shaft 6 via the bearings are fixed by the rotation stopper 20 attached to the autoclave lid, so that these blades cannot rotate when the shaft 6 rotates. did. After pouring 0.4 volume of distilled water into an autoclave with an internal volume of approximately 0.5, insert the two blades attached to the shaft 6 via bearings into the autoclave.
These bearings and vanes were immersed in distilled water, and the autoclave was sealed to withstand a pressure of 90 kg/cm 2 or more. Distilled water is heated to a temperature of 300°C by a heater installed in the interior space of the autoclave, and after rotating the shaft 6 at this temperature for a predetermined period of time, the bearing attached to the shaft 6 is taken out of the autoclave, and the bearing is determined by microscopic observation. The corrosion status (both sliding and non-sliding surfaces) and sliding scratches were evaluated. The temperature of the distilled water was measured with a thermometer attached to the autoclave lid, and the autoclave internal pressure was measured with a pressure gauge attached to the autoclave lid. Temperature 300°C and pressure 87.6 for control bearing formed from control cemented carbide (WC-5.3Co) and test bearing formed from test cemented carbide (WC-6Co-7Ni).
The table below shows the results of corrosion and sliding tests conducted under Kg/cm 2 conditions (numbers representing cemented carbide compositions indicate weight %).

【表】 試験結果は次の基準に従つて評価された。 ◎ 非常に優れる(変化なし) 〇 優れる(少し変化が認められるが実用上問
題なし) △ やや劣る(条件次第では使用し得る) × 劣る(使用し得ない) 上記の結果から、タングステンカーバイド
(WC)にニツケル(7重量%)とコバルト(6
重量%)を含ませることにより、この組成を有す
る軸受を温度300℃、圧力88Kg/cm2の条件で使用
した場合でも、タングステンカーバイドに5.3重
量%のコバルトを含む軸受に較べて、耐蝕性、耐
摩耗性においてWC―6Co―7Niの組成を有する
軸受が優れていることが明らかとなつた。 前記の如く、本発明による高温高圧水用フロー
メータでは、軸受が高温高圧水下においても耐腐
蝕性に優れているため長期に亘りその機能を発揮
し得、特にニツケル又はコバルト等、単体の結合
材からなるタングステンカーバイドによるものよ
り、靭性を有しているため、欠落が生じ難く、好
ましい高温高圧水用軸受として機能し、フローメ
ータが長期間確実に動作する。 以上のとおり、本発明高温高圧水用フローメー
タでは、その軸受が、タングステンカーバイドを
ニツケル及びコバルトからなる結合材で結合して
なるものであるために、高温高圧水下において軸
受の耐腐蝕性、耐摩耗性、耐熱性及び靭性が高
い。 すなわち、結合材にニツケルが含まれない場合
には、軸受の耐腐蝕性が低く、結合材が高温高圧
水下で酸化されて靭性等が低下すると共に、タン
グステンカーバイド等組織の脱落がおこり易くな
り、高温高圧水下で軸受が比較的短期間で劣化し
てしまう虞れがあり、一方結合材にコバルトが含
まれない場合には、タングステンカーバイド組織
が強く結合され難く、組織の脱落がおこり易く、
耐摩耗性等が低くなり、軸受が比較的短期間で劣
化してしまう虞れがあるが、本発明高温高圧水用
フローメータの軸受では、結合材がニツケル及び
コバルトからなり、且つニツケル及びコバルトが
それぞれ3ないし10重量%含まれているために前
記耐腐蝕性、耐摩耗性、及び靭性がすべて高く維
持され、長期の使用に耐え得る。その結果フロー
メータが長期間確実に動作する。 すなわち、ニツケルまたはコバルトが3重量%
未満である場合、タングステンカーバイド組織の
脱落がおこり易く、耐摩耗性等が低下する虞れが
あり、一方、ニツケルまたはコバルトが10重量%
を越える場合、軸受としての硬さが低下して耐摩
耗性が低下する虞れがある。
[Table] Test results were evaluated according to the following criteria. ◎ Very good (no change) 〇 Excellent (a little change is observed, but there is no practical problem) △ Slightly inferior (can be used depending on the conditions) × Poor (cannot be used) From the above results, tungsten carbide (WC ), nickel (7% by weight) and cobalt (6% by weight)
By including 5.3% by weight of cobalt in tungsten carbide, even when a bearing with this composition is used at a temperature of 300°C and a pressure of 88 kg/ cm2 , it has better corrosion resistance and better corrosion resistance than a bearing containing 5.3% by weight of cobalt in tungsten carbide. It has become clear that bearings with the composition WC-6Co-7Ni are superior in wear resistance. As mentioned above, in the high-temperature, high-pressure water flow meter according to the present invention, the bearing has excellent corrosion resistance even under high-temperature, high-pressure water, so it can perform its function for a long period of time. Since it has more toughness than the material made of tungsten carbide, it is less likely to chip and functions as a preferred bearing for high-temperature, high-pressure water, allowing the flow meter to operate reliably for a long period of time. As described above, in the high-temperature, high-pressure water flow meter of the present invention, since the bearing is made by bonding tungsten carbide with a bonding material made of nickel and cobalt, the corrosion resistance of the bearing under high-temperature and high-pressure water is low. High wear resistance, heat resistance and toughness. In other words, if the bonding material does not contain nickel, the corrosion resistance of the bearing will be low, and the bonding material will be oxidized under high-temperature, high-pressure water, resulting in a decrease in toughness, and the structure such as tungsten carbide will easily fall off. , there is a risk that the bearing will deteriorate in a relatively short period of time under high-temperature, high-pressure water.On the other hand, if the bonding material does not contain cobalt, the tungsten carbide structure will be difficult to bond strongly, and the structure will easily fall off. ,
There is a risk that the wear resistance etc. will decrease and the bearing will deteriorate in a relatively short period of time, but in the bearing of the high temperature and high pressure water flow meter of the present invention, the binding material is made of nickel and cobalt, and the bonding material is made of nickel and cobalt. Since the composition contains 3 to 10% by weight of each, the corrosion resistance, abrasion resistance, and toughness are all maintained at high levels and can withstand long-term use. As a result, the flow meter operates reliably for a long period of time. i.e. 3% by weight of nickel or cobalt
If the tungsten carbide structure is less than 10% by weight, the tungsten carbide structure may easily fall off and wear resistance may deteriorate.
If it exceeds this, there is a risk that the hardness of the bearing will decrease and the wear resistance will decrease.

【図面の簡単な説明】[Brief explanation of drawings]

第1図は本発明高温高圧水用フローメータの好
ましい一具体例のタービン式フローメータの説明
図、第2図は、本発明高温高圧水用フローメータ
に用いられる軸受の腐蝕摺動試験における軸受の
配置を示す図である。 1……羽根車、2……ハブ、3……羽根、4…
…ブツシユ、5……ジヤーナル、6……軸、7…
…スラスト軸受、20……回転止め。
Fig. 1 is an explanatory diagram of a turbine type flow meter as a preferred example of the flow meter for high temperature and high pressure water of the present invention, and Fig. 2 shows bearings used in the corrosion sliding test of the bearing used in the flow meter for high temperature and high pressure water of the present invention. FIG. 1... Impeller, 2... Hub, 3... Vane, 4...
...Butsuyu, 5...Journal, 6...Axis, 7...
...Thrust bearing, 20... Rotation stopper.

Claims (1)

【特許請求の範囲】 1 被測流体として100℃、1気圧以上の高温高
圧水が流れる配管途中に流量測定用羽根車を軸受
を介して回転自在に設けた高温高圧水用フローメ
ータにおいて、 前記軸受は、タングステンカーバイドをニツケ
ル及びコバルトからなる結合材で結合してなり、
ニツケル及びコバルトを夫々3乃至10重量%を含
む超硬合金からなる高温高圧水用フローメータ。
[Scope of Claims] 1. A high-temperature, high-pressure water flow meter in which a flow rate measuring impeller is rotatably provided via a bearing in the middle of a pipe through which high-temperature, high-pressure water of 100° C. and 1 atm or more flows as a fluid to be measured, comprising: The bearing is made by bonding tungsten carbide with a bonding material made of nickel and cobalt.
A high-temperature, high-pressure water flow meter made of cemented carbide containing 3 to 10% by weight of nickel and cobalt.
JP1740279A 1979-02-16 1979-02-16 High temperature, high pressure water use bearing Granted JPS55110754A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP1740279A JPS55110754A (en) 1979-02-16 1979-02-16 High temperature, high pressure water use bearing

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP1740279A JPS55110754A (en) 1979-02-16 1979-02-16 High temperature, high pressure water use bearing

Publications (2)

Publication Number Publication Date
JPS55110754A JPS55110754A (en) 1980-08-26
JPS6367641B2 true JPS6367641B2 (en) 1988-12-27

Family

ID=11942993

Family Applications (1)

Application Number Title Priority Date Filing Date
JP1740279A Granted JPS55110754A (en) 1979-02-16 1979-02-16 High temperature, high pressure water use bearing

Country Status (1)

Country Link
JP (1) JPS55110754A (en)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS596422A (en) * 1982-06-30 1984-01-13 Masuda Seiki Kk Bearing device
DE3483214D1 (en) * 1983-03-28 1990-10-25 Kennametal Inc ROLL FOR HOT ROLLING STEEL.

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS49126707A (en) * 1973-04-05 1974-12-04
JPS5130513A (en) * 1974-09-09 1976-03-15 Tokyo Shibaura Electric Co CHOKOGOKIN
JPS5352214A (en) * 1976-10-25 1978-05-12 Toshiba Tungaloy Co Ltd Machine parts consisting of hard porous sintered product and process for production thereof

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS49126707A (en) * 1973-04-05 1974-12-04
JPS5130513A (en) * 1974-09-09 1976-03-15 Tokyo Shibaura Electric Co CHOKOGOKIN
JPS5352214A (en) * 1976-10-25 1978-05-12 Toshiba Tungaloy Co Ltd Machine parts consisting of hard porous sintered product and process for production thereof

Also Published As

Publication number Publication date
JPS55110754A (en) 1980-08-26

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