JPS6366867B2 - - Google Patents
Info
- Publication number
- JPS6366867B2 JPS6366867B2 JP55105358A JP10535880A JPS6366867B2 JP S6366867 B2 JPS6366867 B2 JP S6366867B2 JP 55105358 A JP55105358 A JP 55105358A JP 10535880 A JP10535880 A JP 10535880A JP S6366867 B2 JPS6366867 B2 JP S6366867B2
- Authority
- JP
- Japan
- Prior art keywords
- oil
- parts
- water
- synthetic resin
- manufactured
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 229920003002 synthetic resin Polymers 0.000 claims description 22
- 239000000057 synthetic resin Substances 0.000 claims description 22
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 22
- 239000000839 emulsion Substances 0.000 claims description 20
- 239000003960 organic solvent Substances 0.000 claims description 4
- 239000000976 ink Substances 0.000 description 26
- 239000000975 dye Substances 0.000 description 25
- 239000000126 substance Substances 0.000 description 10
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 9
- 229920005989 resin Polymers 0.000 description 9
- 239000011347 resin Substances 0.000 description 9
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 6
- 239000002904 solvent Substances 0.000 description 6
- 239000000203 mixture Substances 0.000 description 5
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 3
- XNWFRZJHXBZDAG-UHFFFAOYSA-N 2-METHOXYETHANOL Chemical compound COCCO XNWFRZJHXBZDAG-UHFFFAOYSA-N 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 3
- 230000000740 bleeding effect Effects 0.000 description 3
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 3
- 238000004043 dyeing Methods 0.000 description 3
- 239000002244 precipitate Substances 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 2
- QPQKUYVSJWQSDY-UHFFFAOYSA-N 4-phenyldiazenylaniline Chemical compound C1=CC(N)=CC=C1N=NC1=CC=CC=C1 QPQKUYVSJWQSDY-UHFFFAOYSA-N 0.000 description 2
- 244000276331 Citrus maxima Species 0.000 description 2
- QUSNBJAOOMFDIB-UHFFFAOYSA-N Ethylamine Chemical compound CCN QUSNBJAOOMFDIB-UHFFFAOYSA-N 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- MRQIXHXHHPWVIL-ISLYRVAYSA-N Sudan I Chemical compound OC1=CC=C2C=CC=CC2=C1\N=N\C1=CC=CC=C1 MRQIXHXHHPWVIL-ISLYRVAYSA-N 0.000 description 2
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 2
- HQABUPZFAYXKJW-UHFFFAOYSA-N butan-1-amine Chemical compound CCCCN HQABUPZFAYXKJW-UHFFFAOYSA-N 0.000 description 2
- JQVDAXLFBXTEQA-UHFFFAOYSA-N dibutylamine Chemical compound CCCCNCCCC JQVDAXLFBXTEQA-UHFFFAOYSA-N 0.000 description 2
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 description 2
- 229940058015 1,3-butylene glycol Drugs 0.000 description 1
- FBMQNRKSAWNXBT-UHFFFAOYSA-N 1,4-diaminoanthracene-9,10-dione Chemical compound O=C1C2=CC=CC=C2C(=O)C2=C1C(N)=CC=C2N FBMQNRKSAWNXBT-UHFFFAOYSA-N 0.000 description 1
- HXKKHQJGJAFBHI-UHFFFAOYSA-N 1-aminopropan-2-ol Chemical compound CC(O)CN HXKKHQJGJAFBHI-UHFFFAOYSA-N 0.000 description 1
- SBASXUCJHJRPEV-UHFFFAOYSA-N 2-(2-methoxyethoxy)ethanol Chemical compound COCCOCCO SBASXUCJHJRPEV-UHFFFAOYSA-N 0.000 description 1
- POAOYUHQDCAZBD-UHFFFAOYSA-N 2-butoxyethanol Chemical compound CCCCOCCO POAOYUHQDCAZBD-UHFFFAOYSA-N 0.000 description 1
- ZNQVEEAIQZEUHB-UHFFFAOYSA-N 2-ethoxyethanol Chemical compound CCOCCO ZNQVEEAIQZEUHB-UHFFFAOYSA-N 0.000 description 1
- JCYPECIVGRXBMO-UHFFFAOYSA-N 4-(dimethylamino)azobenzene Chemical compound C1=CC(N(C)C)=CC=C1N=NC1=CC=CC=C1 JCYPECIVGRXBMO-UHFFFAOYSA-N 0.000 description 1
- SILZUVHOJDAKAS-UHFFFAOYSA-N 4-(naphthalen-1-yldiazenyl)naphthalen-1-amine Chemical compound C12=CC=CC=C2C(N)=CC=C1N=NC1=CC=CC2=CC=CC=C12 SILZUVHOJDAKAS-UHFFFAOYSA-N 0.000 description 1
- AMPCGOAFZFKBGH-UHFFFAOYSA-N 4-[[4-(dimethylamino)phenyl]-(4-methyliminocyclohexa-2,5-dien-1-ylidene)methyl]-n,n-dimethylaniline Chemical compound C1=CC(=NC)C=CC1=C(C=1C=CC(=CC=1)N(C)C)C1=CC=C(N(C)C)C=C1 AMPCGOAFZFKBGH-UHFFFAOYSA-N 0.000 description 1
- BPTKLSBRRJFNHJ-UHFFFAOYSA-N 4-phenyldiazenylbenzene-1,3-diol Chemical compound OC1=CC(O)=CC=C1N=NC1=CC=CC=C1 BPTKLSBRRJFNHJ-UHFFFAOYSA-N 0.000 description 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- 239000002174 Styrene-butadiene Substances 0.000 description 1
- YCUVUDODLRLVIC-UHFFFAOYSA-N Sudan black B Chemical compound C1=CC(=C23)NC(C)(C)NC2=CC=CC3=C1N=NC(C1=CC=CC=C11)=CC=C1N=NC1=CC=CC=C1 YCUVUDODLRLVIC-UHFFFAOYSA-N 0.000 description 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 1
- LHIJANUOQQMGNT-UHFFFAOYSA-N aminoethylethanolamine Chemical compound NCCNCCO LHIJANUOQQMGNT-UHFFFAOYSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical compound C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 description 1
- 235000019437 butane-1,3-diol Nutrition 0.000 description 1
- MRQIXHXHHPWVIL-UHFFFAOYSA-N chembl1397023 Chemical compound OC1=CC=C2C=CC=CC2=C1N=NC1=CC=CC=C1 MRQIXHXHHPWVIL-UHFFFAOYSA-N 0.000 description 1
- ALLOLPOYFRLCCX-UHFFFAOYSA-N chembl1986529 Chemical compound COC1=CC=CC=C1N=NC1=C(O)C=CC2=CC=CC=C12 ALLOLPOYFRLCCX-UHFFFAOYSA-N 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 229960002887 deanol Drugs 0.000 description 1
- HPNMFZURTQLUMO-UHFFFAOYSA-N diethylamine Chemical compound CCNCC HPNMFZURTQLUMO-UHFFFAOYSA-N 0.000 description 1
- 229940028356 diethylene glycol monobutyl ether Drugs 0.000 description 1
- XXJWXESWEXIICW-UHFFFAOYSA-N diethylene glycol monoethyl ether Chemical compound CCOCCOCCO XXJWXESWEXIICW-UHFFFAOYSA-N 0.000 description 1
- 229940075557 diethylene glycol monoethyl ether Drugs 0.000 description 1
- 239000012972 dimethylethanolamine Substances 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 229960005150 glycerol Drugs 0.000 description 1
- 150000002334 glycols Chemical class 0.000 description 1
- 239000003906 humectant Substances 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 229940102253 isopropanolamine Drugs 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- CRVGTESFCCXCTH-UHFFFAOYSA-N methyl diethanolamine Chemical compound OCCN(C)CCO CRVGTESFCCXCTH-UHFFFAOYSA-N 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- JCGNDDUYTRNOFT-UHFFFAOYSA-N oxolane-2,4-dione Chemical compound O=C1COC(=O)C1 JCGNDDUYTRNOFT-UHFFFAOYSA-N 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 230000003449 preventive effect Effects 0.000 description 1
- 229960004063 propylene glycol Drugs 0.000 description 1
- TVRGPOFMYCMNRB-UHFFFAOYSA-N quinizarine green ss Chemical compound C1=CC(C)=CC=C1NC(C=1C(=O)C2=CC=CC=C2C(=O)C=11)=CC=C1NC1=CC=C(C)C=C1 TVRGPOFMYCMNRB-UHFFFAOYSA-N 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 239000011115 styrene butadiene Substances 0.000 description 1
- 229920003048 styrene butadiene rubber Polymers 0.000 description 1
- 239000006228 supernatant Substances 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- YODZTKMDCQEPHD-UHFFFAOYSA-N thiodiglycol Chemical compound OCCSCCO YODZTKMDCQEPHD-UHFFFAOYSA-N 0.000 description 1
- 229950006389 thiodiglycol Drugs 0.000 description 1
- AODQPPLFAXTBJS-UHFFFAOYSA-M victoria blue 4R Chemical compound [Cl-].C1=CC(N(C)C)=CC=C1C(C=1C=CC(=CC=1)N(C)C)=C(C=C1)C2=CC=CC=C2C1=[N+](C)C1=CC=CC=C1 AODQPPLFAXTBJS-UHFFFAOYSA-M 0.000 description 1
Description
本発明は、油溶性染料を使用した水性インキに
関するものである。
従来、油性インキは水性インキに比し、耐水性
は良好なものの、紙などに筆記した場合、筆跡の
滲み、裏移りなどの問題があり、又、水性インキ
は油性インキに比し筆跡の滲み、裏移りなどの問
題は少ないが、耐水性に劣るという問題があつ
た。
本発明者らは、油溶性染料を使用した水性イン
キが得られれば、上述せる問題が解決できるもの
との発想に基づき、鋭意研究の結果本発明を完成
したものであつて、即ち、本発明は、油溶性染料
と、Ｏ／Ｗ型合成樹脂エマルジヨンと、水溶性有
機溶剤と、水とから少なくともなる水性インキを
要旨とするものである。
本発明で特に重要なことは、水性インキに油溶
性染料と、Ｏ／Ｗ型合成樹脂エマルジヨンを使用
することにある。
つまり、Ｏ／Ｗ型合成樹脂エマルジヨン中の合
成樹脂に油溶性染料が染着し、通常水性インキに
使用し得ない油溶性染料が使用可能となり、耐水
性が向上するものと考えられる。
又、溶剤として水溶性有機溶剤を使用している
ところから、筆跡の滲み、裏移りの少ないインキ
が得られるものである。
更には、油溶性染料、合成樹脂エマルジヨンを
使用しているため、ガラス、プラスチツクなどの
非滲透性物質にも筆記が可能であり、定着性良好
な筆跡が得られるものである。
以下、本発明を詳細に説明する。
油溶性染料は、着色剤として使用されるが、そ
の使用形態は、Ｏ／Ｗ型合成樹脂エマルジヨン中
の合成樹脂に染着されて使用されるため、合成樹
脂を染着し易いものが好ましく、一例を挙げれ
ば、C.I.ソルベントエロー２、同６、同14、同
15、同16、同19、同21、同33、同56、同61、同
80、C.I.ソルベントオレンジ１、同２、同５、同
６、同14、同37、同40、同44、同45、C.I.ソルベ
ントレツド１、同３、同８、同23、同24、同25、
同27、同30、同49、同81、同82、同83、同84、同
100、同109、同121、C.I.デイスパースレツド９、
C.I.ソルベントバイオレツト８、同13、同14、同
21、同27、C.I.デイスパースバイオレツト１、C.
I.ソルベントブルー２、同11、同12、同25、同
35、同36、同55、同73、C.I.ソルベントグリーン
３、C.I.ソルベントブラウン３、同５、同20、同
37、C.I.ソルベントブラツク３、同５、同22、同
23などや、各種市販の樹脂着色用の油溶性染料な
どがあり、これらを単独もしくは混合して使用可
能であり、その使用量は、油溶性染料の種類、
Ｏ／Ｗ型合成樹脂エマルジヨンの種類、使用目的
によつて異なるが、一般的にはＯ／Ｗ型合成樹脂
エマルジヨンの樹脂分に対して0.1〜50重量％が
好ましい。
Ｏ／Ｗ型合成樹脂エマルジヨンとしては、プラ
イマルAC−33、プライマルAC−61（日本アクリ
ル化学(株)製）、ジユリマーET530（日本純薬(株)製）
などのアクリル系合成樹脂エマルジヨンや、サイ
ビノールGH100（サイデン化学(株)製）、ニカゾー
ルRX−472、ニカゾールCL100C（日本カーバイ
ト工業(株)製）、セビアンＡ−351（ダイセル化学工
業(株)製）などの酢酸ビニル系合成樹脂エマルジヨ
ンや、ニボールLX204（日本ゼオン(株)製）、インス
ターボンドKM−500（松栄化学工業(株)製）などの
スチレン−ブタジエン系合成樹脂エマルジヨンな
どが挙げられ、単独もしくは混合して使用可能で
あり、その使用量はインキ全量に対して樹脂分で
２〜30重量％が好ましい。
水溶性有機溶剤としては、エチレングリコー
ル、ジエチレングリコール、トリエチレングリコ
ール、プロピレングリコール、１、３−ブチレン
グリコール、チオジグリコール、エチレングリコ
ールモノメチルエーテル、エチレングリコールモ
ノエチルエーテル、エチレングリコールモノブチ
ルエーテル、エチレングリコールモノメチルエー
テルアセテート、ジエチレングリコールモノメチ
ルエーテル、ジエチレングリコールモノブチルエ
ーテル、ジエチレングリコールモノエチルエーテ
ル、グリセリンなどのグリコール類及びその誘導
体や、モノエタノールアミン、ジエタノールアミ
ン、トリエタノールアミン、イソプロパノールア
ミン、Ｎ−メチルジエタノールアミン、Ｎ、
N′−ジメチルエタノールアミン、２−（２−アミ
ノエチルアミノ）エタノールなどのＮ−アルカノ
ールアミン類や、エチルアミン、ジエチルアミ
ン、トリエチルアミン、ブチルアミン、ジブチル
アミンなどのＮ−アルキルアミン類などが挙げら
れ、単独もしくは混合して使用可能であり、その
使用量は、インキ全量に対して１〜40重量％が好
ましい。
水は主溶剤として使用せられるものでその使用
量はエマルジヨンに含まれる水を含めてインキ全
量に対して40〜85重量％が好ましい。
その他必要に応じて、各種の界面活性剤や、防
腐剤、PH調整剤、防錆剤、保湿剤などを添加して
もよい。
次にインキの製造方法について簡単に述べる
と、上述した成分を単に撹拌混合しインキを得る
方法と、油溶性染料とＯ／Ｗ型合成樹脂エマルジ
ヨンとを先に混合し、合成樹脂に油溶性染料を染
着せしめてから他の成分を加えインキを得る方法
がある。又、インキを製造する際に沈澱物が生じ
た場合は、過などを行ない、沈澱物を取り除い
ておく方が好ましい。
以下、本発明を実施例に従い、更に詳細に説明
するが、実施例中単に「部」とあるのは「重量
部」を示す。
実施例 １
バリフアストレツド＃1308…油溶性染料（オリエ
ント化学工業(株)製） 4.7部
バリフアストエロー＃3104…油溶性染料（オリエ
ント化学工業(株)製） 0.1部
プラマイルAC−333…Ｏ／Ｗ型アクリル系合成樹
脂エマルジヨン（日本アクリル化学(株)製、樹脂分
46％） 35.0部
エチレングリコール 5.0部
水 55.1部
炭酸ナトリウム（PH調整剤） 0.1部
上記各成分の配合物を30℃に加温し、16時間撹
拌混合し、赤色インキを得た。
実施例 ２
バリフアストブルー＃1603…油溶性染料（オリエ
ント化学工業(株)製） 2.7部
ビクトリアブルーF4R…油溶性染料（BASF社
製） 2.2部
ニカゾールRX−472…Ｏ／Ｗ型酢酸ビニル系合
成樹脂エマルジヨン（日本カーバイド工業(株)製、
樹脂分50％） 33.0部
エチレングリコール 5.0部
エタノールアミン 0.5部
水 56.5部
上記各成分の配合物を30℃に保温し、10時間撹
拌後、静置し上澄液を採り、青色インキを得た。
実施例 ３
バリフアストブルー＃1603…油溶性染料（オリエ
ント化学工業(株)製） 3.7部
バリフアストエロー＃3104…油溶性染料（オリエ
ント化学工業(株)製） 3.3部
ジユリマーET−530…Ｏ／Ｗ型アクリル系合成樹
脂エマルジヨン（日本純薬(株)製、樹脂分30％）
75.0部
トリエチレングリコール 5.0部
ジエタノールアミン 3.0部
水 10.0部
上記各成分の配合物を30℃に保温して、12時間
撹拌後、過を行ない沈澱物を取り除き、緑色イ
ンキを得た。
実施例 ４
バリフアーストエロー＃3104…油溶性染料（オリ
エント化学工業(株)製） 4.5部
ザボンフアストオレンジRR…油溶性染料
（BASF社製） 2.5部
ニカゾールCL−100C…Ｏ／Ｗ型酢酸ビニル系合
成樹脂エマルジヨン（日本カーバイド工業(株)製、
樹脂分55％） 25.0部
プライマルAC−33…Ｏ／Ｗ型合成樹脂エマルジ
ヨン（日本アクリル化学(株)製、樹脂分46％）
30.0部
エチレングリコールモノメチルエーテル 7.0部
水 31.0部
上記成分のうち、バリフアーストエロー
＃3104、ザボンフアストオレンジRRの油溶性染
料とニカゾールCL−100C、プライマルAC−33
の合成樹脂エマルジヨンとを混合し、油溶性染料
を合成樹脂エマルジヨンに染着せしめた後、他の
成分を加え撹拌混合して黄色インキを得た。
実施例１〜４で得られたインキの耐水性試験、
滲み試験、裏移り試験の結果を表−１に示す。
The present invention relates to water-based inks using oil-soluble dyes. Conventionally, oil-based inks have better water resistance than water-based inks, but when written on paper, etc., there are problems such as bleeding and set-off of handwriting, and water-based inks also have better water resistance than oil-based inks. Although there were few problems such as set-off, there was a problem of poor water resistance. The present inventors have completed the present invention as a result of intensive research based on the idea that the above-mentioned problems can be solved if a water-based ink using an oil-soluble dye is obtained. is a water-based ink comprising at least an oil-soluble dye, an O/W type synthetic resin emulsion, a water-soluble organic solvent, and water. What is particularly important in the present invention is the use of an oil-soluble dye and an O/W type synthetic resin emulsion in the water-based ink. In other words, it is thought that the oil-soluble dye dyes the synthetic resin in the O/W type synthetic resin emulsion, making it possible to use oil-soluble dyes that cannot normally be used in water-based inks, and improving water resistance. Furthermore, since a water-soluble organic solvent is used as the solvent, an ink with less bleeding and set-off of handwriting can be obtained. Furthermore, since oil-soluble dyes and synthetic resin emulsions are used, it is possible to write on non-permeable materials such as glass and plastic, and it is possible to obtain handwriting with good fixability. The present invention will be explained in detail below. The oil-soluble dye is used as a coloring agent, but since it is used by dyeing the synthetic resin in the O/W type synthetic resin emulsion, it is preferable to use a dye that can easily dye the synthetic resin. For example, CI Solvent Yellow 2, CI Solvent Yellow 6, CI Solvent Yellow 14, CI Solvent Yellow
15, 16, 19, 21, 33, 56, 61,
80, CI Solvent Orange 1, 2, 5, 6, 14, 37, 40, 44, 45, CI Solvent Red 1, 3, 8, 23, 24, twenty five,
27, 30, 49, 81, 82, 83, 84, 49
100, 109, 121, CI dispersion thread 9,
CI Solvent Violet 8, 13, 14, 14
21, 27, CI Disperse Violet 1, C.
I.Solvent Blue 2, Same 11, Same 12, Same 25, Same
35, 36, 55, 73, CI Solvent Green 3, CI Solvent Brown 3, 5, 20, 73
37, CI Solvent Black 3, CI Solvent Black 5, CI Solvent Black 22, CI Solvent Black
23, and various commercially available oil-soluble dyes for resin coloring, which can be used alone or in combination, and the amount used depends on the type of oil-soluble dye,
Although it varies depending on the type of O/W type synthetic resin emulsion and the purpose of use, it is generally preferable to use 0.1 to 50% by weight based on the resin content of the O/W type synthetic resin emulsion. O/W type synthetic resin emulsions include Primal AC-33, Primal AC-61 (manufactured by Nippon Acrylic Chemical Co., Ltd.), and Jurimer ET530 (manufactured by Nippon Pure Chemical Industries, Ltd.).
Acrylic synthetic resin emulsion such as Cybinol GH100 (manufactured by Saiden Chemical Co., Ltd.), Nikazole RX-472, Nikazole CL100C (manufactured by Nippon Carbide Industries, Ltd.), Cevian A-351 (manufactured by Daicel Chemical Industries, Ltd.) ) and styrene-butadiene synthetic resin emulsions such as Nibor LX204 (manufactured by Nippon Zeon Co., Ltd.) and Instarbond KM-500 (manufactured by Shoei Chemical Industry Co., Ltd.). , can be used alone or in combination, and the amount used is preferably 2 to 30% by weight of the resin based on the total amount of the ink. Examples of water-soluble organic solvents include ethylene glycol, diethylene glycol, triethylene glycol, propylene glycol, 1,3-butylene glycol, thiodiglycol, ethylene glycol monomethyl ether, ethylene glycol monoethyl ether, ethylene glycol monobutyl ether, and ethylene glycol monomethyl ether. Glycols and their derivatives such as acetate, diethylene glycol monomethyl ether, diethylene glycol monobutyl ether, diethylene glycol monoethyl ether, glycerin, monoethanolamine, diethanolamine, triethanolamine, isopropanolamine, N-methyldiethanolamine, N,
Examples include N-alkanolamines such as N'-dimethylethanolamine and 2-(2-aminoethylamino)ethanol, and N-alkylamines such as ethylamine, diethylamine, triethylamine, butylamine, and dibutylamine. They can be used in combination, and the amount used is preferably 1 to 40% by weight based on the total amount of the ink. Water is used as the main solvent, and the amount used is preferably 40 to 85% by weight based on the total amount of the ink, including the water contained in the emulsion. In addition, various surfactants, preservatives, PH regulators, rust preventives, humectants, etc. may be added as necessary. Next, to briefly describe the ink manufacturing method, there are two methods: one is to simply stir and mix the above-mentioned components to obtain ink, and the other is to first mix an oil-soluble dye and an O/W type synthetic resin emulsion, then add the oil-soluble dye to the synthetic resin. There is a method to obtain ink by dyeing the ink and then adding other ingredients. Further, if a precipitate is generated during the production of the ink, it is preferable to remove the precipitate by filtration or the like. Hereinafter, the present invention will be explained in more detail with reference to Examples. In the Examples, "parts" simply indicate "parts by weight." Example 1 Varifast Yellow #1308...Oil-soluble dye (manufactured by Orient Chemical Industry Co., Ltd.) 4.7 parts Varifast Yellow #3104...Oil-soluble dye (manufactured by Orient Chemical Industry Co., Ltd.) 0.1 part Plamile AC-333...O/ W-type acrylic synthetic resin emulsion (manufactured by Nippon Acrylic Chemical Co., Ltd., resin content)
46%) 35.0 parts Ethylene glycol 5.0 parts Water 55.1 parts Sodium carbonate (PH adjuster) 0.1 part The mixture of each of the above components was heated to 30°C and mixed with stirring for 16 hours to obtain a red ink. Example 2 Varifast Blue #1603...Oil-soluble dye (manufactured by Orient Chemical Industry Co., Ltd.) 2.7 parts Victoria Blue F4R...Oil-soluble dye (manufactured by BASF) 2.2 parts Nikazole RX-472...O/W type vinyl acetate-based synthesis Resin emulsion (manufactured by Nippon Carbide Industries Co., Ltd.)
Resin content: 50%) 33.0 parts Ethylene glycol 5.0 parts Ethanolamine 0.5 parts Water 56.5 parts The mixture of each of the above components was kept at 30°C, stirred for 10 hours, left to stand, and the supernatant liquid was collected to obtain blue ink. . Example 3 Varifast Blue #1603...Oil-soluble dye (manufactured by Orient Chemical Industry Co., Ltd.) 3.7 parts Varifast Yellow #3104...Oil-soluble dye (manufactured by Orient Chemical Industry Co., Ltd.) 3.3 parts Dyurimer ET-530...O/ W-type acrylic synthetic resin emulsion (manufactured by Nippon Pure Chemical Industries, Ltd., resin content 30%)
75.0 parts Triethylene glycol 5.0 parts Diethanolamine 3.0 parts Water 10.0 parts The mixture of each of the above components was kept at 30°C and stirred for 12 hours, then filtered to remove the precipitate to obtain a green ink. Example 4 Varifast Yellow #3104...Oil-soluble dye (manufactured by Orient Chemical Industry Co., Ltd.) 4.5 parts Pomelo Fast Orange RR...Oil-soluble dye (manufactured by BASF) 2.5 parts Nicasole CL-100C...O/W type vinyl acetate type Synthetic resin emulsion (manufactured by Nippon Carbide Industries Co., Ltd.)
Resin content 55%) 25.0 parts Primal AC-33...O/W type synthetic resin emulsion (manufactured by Nippon Acrylic Chemical Co., Ltd., resin content 46%)
30.0 parts Ethylene glycol monomethyl ether 7.0 parts Water 31.0 parts Among the above ingredients, oil-soluble dyes such as Balifu First Yellow #3104, Pomelo Fast Orange RR, Nikazole CL-100C, Primal AC-33
After mixing with a synthetic resin emulsion and dyeing the synthetic resin emulsion with an oil-soluble dye, other components were added and mixed with stirring to obtain a yellow ink. Water resistance test of inks obtained in Examples 1 to 4,
Table 1 shows the results of the bleeding test and set-off test.
【表】
尚、実施例１〜４のインキは、プラスチツク
板、ガラス板などの非滲透性物質にも筆記でき、
定着性良好なものである。
以上のように本発明で得られるインキは、耐水
性が良好であり、筆跡の滲み、裏移りを防止した
インキであり、筆記具用インキは勿論のこと、印
刷用、記録計用、スタンプ用などのインキとして
も好適なものである。[Table] The inks of Examples 1 to 4 can also be used to write on non-permeable materials such as plastic plates and glass plates.
It has good fixing properties. As described above, the ink obtained by the present invention has good water resistance and prevents handwriting from blurring and set-off, and can be used not only for writing instruments, but also for printing, recorders, stamps, etc. It is also suitable as an ink.
Claims (1)
ンと、水溶性有機溶剤と、水とから少なくともな
る水性インキ。1. A water-based ink comprising at least an oil-soluble dye, an O/W type synthetic resin emulsion, a water-soluble organic solvent, and water.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP10535880A JPS5730772A (en) | 1980-07-30 | 1980-07-30 | Water-based ink |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP10535880A JPS5730772A (en) | 1980-07-30 | 1980-07-30 | Water-based ink |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS5730772A JPS5730772A (en) | 1982-02-19 |
| JPS6366867B2 true JPS6366867B2 (en) | 1988-12-22 |
Family
ID=14405496
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP10535880A Granted JPS5730772A (en) | 1980-07-30 | 1980-07-30 | Water-based ink |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS5730772A (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH03237171A (en) * | 1990-02-13 | 1991-10-23 | Sakura Color Prod Corp | Erasable aqueous ink composition |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5458504A (en) * | 1977-10-18 | 1979-05-11 | Fuji Photo Film Co Ltd | Ink jet recording ink composition |
| JPS55157668A (en) * | 1979-05-28 | 1980-12-08 | Masaaki Takeshita | Water-based writing utensil |
-
1980
- 1980-07-30 JP JP10535880A patent/JPS5730772A/en active Granted
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5458504A (en) * | 1977-10-18 | 1979-05-11 | Fuji Photo Film Co Ltd | Ink jet recording ink composition |
| JPS55157668A (en) * | 1979-05-28 | 1980-12-08 | Masaaki Takeshita | Water-based writing utensil |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS5730772A (en) | 1982-02-19 |
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