JPS6360107A - Production of calcium drug - Google Patents
Production of calcium drugInfo
- Publication number
- JPS6360107A JPS6360107A JP20439986A JP20439986A JPS6360107A JP S6360107 A JPS6360107 A JP S6360107A JP 20439986 A JP20439986 A JP 20439986A JP 20439986 A JP20439986 A JP 20439986A JP S6360107 A JPS6360107 A JP S6360107A
- Authority
- JP
- Japan
- Prior art keywords
- shell
- calcium
- crusher
- water
- dried
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000011575 calcium Substances 0.000 title claims abstract description 19
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 title claims abstract description 18
- 229910052791 calcium Inorganic materials 0.000 title claims abstract description 18
- 238000004519 manufacturing process Methods 0.000 title claims description 8
- 239000003814 drug Substances 0.000 title abstract 3
- 229940079593 drug Drugs 0.000 title abstract 3
- 235000020637 scallop Nutrition 0.000 claims abstract description 7
- 241000237509 Patinopecten sp. Species 0.000 claims abstract description 6
- 238000005406 washing Methods 0.000 claims abstract description 4
- 239000013535 sea water Substances 0.000 claims abstract description 3
- 238000010438 heat treatment Methods 0.000 claims abstract 3
- 239000003795 chemical substances by application Substances 0.000 claims description 10
- 239000000126 substance Substances 0.000 claims description 5
- 238000010304 firing Methods 0.000 claims description 4
- 150000003839 salts Chemical class 0.000 abstract description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 3
- 238000004140 cleaning Methods 0.000 abstract description 2
- 238000001354 calcination Methods 0.000 abstract 2
- 239000000843 powder Substances 0.000 abstract 1
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 238000003860 storage Methods 0.000 description 2
- 229910021532 Calcite Inorganic materials 0.000 description 1
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- 241000237502 Ostreidae Species 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 241000237503 Pectinidae Species 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 239000011449 brick Substances 0.000 description 1
- 229910001628 calcium chloride Inorganic materials 0.000 description 1
- 239000001110 calcium chloride Substances 0.000 description 1
- WUKWITHWXAAZEY-UHFFFAOYSA-L calcium difluoride Chemical compound [F-].[F-].[Ca+2] WUKWITHWXAAZEY-UHFFFAOYSA-L 0.000 description 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 1
- 239000003638 chemical reducing agent Substances 0.000 description 1
- 238000005868 electrolysis reaction Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000003337 fertilizer Substances 0.000 description 1
- 230000009970 fire resistant effect Effects 0.000 description 1
- 150000004673 fluoride salts Chemical class 0.000 description 1
- 239000010436 fluorite Substances 0.000 description 1
- 238000007429 general method Methods 0.000 description 1
- 239000010440 gypsum Substances 0.000 description 1
- -1 gypsum Chemical class 0.000 description 1
- 229910052602 gypsum Inorganic materials 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000004579 marble Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 235000020636 oyster Nutrition 0.000 description 1
- 235000021317 phosphate Nutrition 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- 238000005292 vacuum distillation Methods 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01F—COMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM, CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THE RARE-EARTH METALS
- C01F11/00—Compounds of calcium, strontium, or barium
- C01F11/02—Oxides or hydroxides
- C01F11/04—Oxides or hydroxides by thermal decomposition
- C01F11/06—Oxides or hydroxides by thermal decomposition of carbonates
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Geology (AREA)
- Inorganic Chemistry (AREA)
- Compounds Of Alkaline-Earth Elements, Aluminum Or Rare-Earth Metals (AREA)
Abstract
Description
【発明の詳細な説明】
〔産業上の利用分野〕
本発明はカルシウム剤、主として工業的に用いられ、各
種金属の脱酸剤、還元剤、あるいは合金、肥料等に幅広
〈実施することができるカルシウム剤の製造方法に関す
る。[Detailed Description of the Invention] [Industrial Field of Application] The present invention is applicable to a wide range of applications such as calcium agents, mainly used industrially, and deoxidizing agents and reducing agents for various metals, alloys, fertilizers, etc. The present invention relates to a method for producing a calcium agent.
一般的にカルシウムは方解石、大理石等の炭酸塩、石膏
等の硫酸塩として存在し、蛍石等のフッ化物、リン酸塩
としても産している。このカルシウムは天然中に遊離し
た状態では産出することはなく、工業的に得るために通
常は塩化カルシウムを主成分とする融解塩電解法により
、製品としては真空蒸留によって精製されるものとなっ
ている。Calcium generally exists as carbonates such as calcite and marble, sulfates such as gypsum, and also as fluorides and phosphates such as fluorite. Calcium is not produced in a free state in nature, and in order to obtain it industrially, it is usually purified by molten salt electrolysis using calcium chloride as the main component, and by vacuum distillation as a product. There is.
しかしながら、この従来の一般的なカルシウムの製造方
法は、それなりの大規模な化学工業プラントを必要とし
、安易には得ることができず、製品価格もその分高騰し
てしまうものとなっていた。However, this conventional general method for producing calcium requires a fairly large-scale chemical industrial plant, cannot be obtained easily, and the product price increases accordingly.
そこで、本発明は係る従来の技術の問題点に着目してな
されたもので、゛容易に゛しかも安価にてカルシウム剤
を得ることができるようにしたカルシウム剤の製造方法
を提供することを目的としている。Therefore, the present invention was made focusing on the problems of the related art, and an object of the present invention is to provide a method for producing a calcium agent that allows the calcium agent to be obtained easily and at low cost. It is said that
〔問題点を解決しようとするための手段〕この目的を達
成するために、本発明に係るカルシウム剤の製造方法は
、貝殻を洗浄して一度加熱した後、クラッシャーで適宜
大きさのチップ状に形成し、異物を除いてから高温で焼
成することを特徴としている。[Means for solving the problem] In order to achieve this objective, the method for producing a calcium agent according to the present invention is to wash seashells, heat them once, and then crush them into appropriately sized chips using a crusher. It is characterized by being formed, removing foreign substances, and then firing at a high temperature.
１−記したような製造方法を採ることによって、大がか
りな化学工業プラントを必要とせず、容易にしかも安価
にカルシウム剤を得ることができることとなるのである
。1- By adopting the production method described above, a calcium agent can be obtained easily and at low cost without the need for a large-scale chemical industrial plant.
次に、本発明の詳細な説明する。 Next, the present invention will be explained in detail.
未発用の実施に使用される原料は大量に存在し、しかも
極めて低廉な価格で供給され、カルシウム成分を大量に
含有した貝殻、それも大型で上板状に近″く取り扱い易
い帆立貝の貝殻を採用した。The raw materials used for the unexploited method exist in large quantities and are supplied at extremely low prices, such as shells containing a large amount of calcium, especially scallop shells, which are large and almost plate-shaped and easy to handle. It was adopted.
この帆立貝の＠殻をまず海水によって洗浄する。この洗
浄は汚・れを落とすと同時に水分と塩分を添加する意味
合いが含まれる。The scallop shells are first washed with seawater. This cleaning involves removing dirt and grime while also adding moisture and salt.
次いで、この洗浄の後に、スパイラルフィーダー式のロ
ータリーマシンによって熱気流で一度加熱し、乾燥させ
る。Next, after this washing, it is heated once with a hot air stream by a spiral feeder type rotary machine and dried.
この加熱乾燥させた帆立貝の貝殻はクラッシャーによっ
て適宜大きさのチップ状に砕き形成され、異物を取り除
いて後、このチップ状に形成された貝殻はオイルバーナ
ーを用いた耐熱窯によって摂氏１４００度乃至１８００
度程度０高温で焼成されるものとなっている。この焼成
された貝殻はその後ミル等によって粉化させる等は自在
である。尚、前記焼成も貝殻をひつくり返して混ぜ、数
回繰り返し行なうと更に良く、ｌ］的によっては溶解す
るまで焼くこともできる。The heated and dried scallop shells are crushed into appropriately sized chips using a crusher, and after removing foreign matter, the chip-shaped shells are heated to 1400 to 1800 degrees Celsius in a heat-resistant kiln using an oil burner.
It is fired at a high temperature of about 0°C. The fired shells can then be pulverized using a mill or the like. The above-mentioned baking process is even better if the shells are turned over and mixed several times, and depending on the target, it may be baked until the mixture is dissolved.
又、この焼成作業に使用される耐熱窯はレンガ等の耐火
材で形成された窯下をチェーン機構で摺動する平皿状の
収容部を有し、その収容部にチップ状の貝殻を均して置
き、窯下に送り込む構成となっているもので、外にＡが
す空気を冷却するため木を通す細バイブを内蔵し、温度
センサーと連結された煙突が備えられている。In addition, the heat-resistant kiln used for this firing work has a flat tray-shaped storage part made of fire-resistant material such as brick that slides under the kiln using a chain mechanism, and the chip-shaped shells are leveled in the storage part. The structure is such that the air is placed under the kiln and sent to the bottom of the kiln.It has a built-in thin vibrator that passes through the wood to cool the outside air, and is equipped with a chimney connected to a temperature sensor.
尚、得られた製品は１００ｇ中にカルシウムが６８ 、
６ｇ 、その他ナトリウムが５４０ｍｇ、マグネシウム
が１４５ｍｇ、リンが７８ｍｇ、カリウムが８．４ｍｇ
、鉄が４．８ｍｇという成分比となっており、ｐｈ値は
１０倍量の水を加えて１１．９を示した。In addition, the obtained product contains 68% calcium in 100g,
6g, other sodium 540mg, magnesium 145mg, phosphorus 78mg, potassium 8.4mg
The component ratio was 4.8 mg of iron, and the pH value was 11.9 when 10 times the amount of water was added.
又、本発明の実施には取り扱い性や入手性から帆立貝の
貝殻を使用したが、カキ等の＠殻を代替することも勿論
６（能である。Further, in carrying out the present invention, scallop shells were used due to ease of handling and availability, but it is of course possible to use oyster shells instead.
Ｌ述したように本発明によれば、原料として極めて低廉
で、カルシウム成分を大量に含有し、しかも大量に存在
する帆立貝等の貝殻を用い、その製造工程も簡易なもの
となっているので、大がかりな化学工業プラントを必要
とせず、容易にしかも安価にカルシウム剤を得ることが
できるものとなっている。As mentioned above, according to the present invention, shells such as scallops, which are extremely inexpensive and contain large amounts of calcium components, are used as raw materials, and the manufacturing process is simple. Calcium agents can be obtained easily and at low cost without the need for large-scale chemical industrial plants.
Claims (2)
適宜大きさのチップ状に形成し、異物を除いてから高温
で焼成することを特徴とするカルシウム剤の製造方法。(1) A method for producing a calcium agent, which comprises washing shells, heating them once, forming them into chips of an appropriate size using a crusher, removing foreign substances, and then firing them at a high temperature.
て行なわれ、その後の加熱はロータリーマシンによる気
流でなされ、焼成温度は摂氏１４００度以上とすること
を特徴とする特許請求の範囲第１項に記載のカルシウム
剤の製造方法。(2) The shell is a scallop shell, the washing is carried out with seawater, the subsequent heating is carried out with an air current from a rotary machine, and the firing temperature is set to 1400 degrees Celsius or more. A method for producing a calcium agent as described in .
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP20439986A JPS6360107A (en) | 1986-08-30 | 1986-08-30 | Production of calcium drug |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP20439986A JPS6360107A (en) | 1986-08-30 | 1986-08-30 | Production of calcium drug |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPS6360107A true JPS6360107A (en) | 1988-03-16 |
Family
ID=16489897
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP20439986A Pending JPS6360107A (en) | 1986-08-30 | 1986-08-30 | Production of calcium drug |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS6360107A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2000072685A1 (en) * | 1999-05-31 | 2000-12-07 | Houzawa, Hiromi | Method for producing bactericide |
| JP2001240416A (en) * | 2000-02-28 | 2001-09-04 | Shozo Hori | Seashell powder for multi purpose application and its manufacturing method |
| JP2001354415A (en) * | 2000-06-09 | 2001-12-25 | Hokkaido Kyodo Sekkai Kk | Method for manufacturing lightweight calcium carbonate |
| JP2009234807A (en) * | 2008-03-25 | 2009-10-15 | Yamagata Three Top:Kk | Shell calcium powder and method for producing the same |
-
1986
- 1986-08-30 JP JP20439986A patent/JPS6360107A/en active Pending
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2000072685A1 (en) * | 1999-05-31 | 2000-12-07 | Houzawa, Hiromi | Method for producing bactericide |
| JP2001240416A (en) * | 2000-02-28 | 2001-09-04 | Shozo Hori | Seashell powder for multi purpose application and its manufacturing method |
| JP2001354415A (en) * | 2000-06-09 | 2001-12-25 | Hokkaido Kyodo Sekkai Kk | Method for manufacturing lightweight calcium carbonate |
| JP2009234807A (en) * | 2008-03-25 | 2009-10-15 | Yamagata Three Top:Kk | Shell calcium powder and method for producing the same |
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