JPS6354213A - Molding die - Google Patents

Molding die

Info

Publication number
JPS6354213A
JPS6354213A JP61197335A JP19733586A JPS6354213A JP S6354213 A JPS6354213 A JP S6354213A JP 61197335 A JP61197335 A JP 61197335A JP 19733586 A JP19733586 A JP 19733586A JP S6354213 A JPS6354213 A JP S6354213A
Authority
JP
Japan
Prior art keywords
ceramic
mold
spraying
nickel
metal
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP61197335A
Other languages
Japanese (ja)
Inventor
Yoshihiko Fujii
藤井 吉彦
Hideo Sekiguchi
関口 秀雄
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Bridgestone Corp
Original Assignee
Bridgestone Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Bridgestone Corp filed Critical Bridgestone Corp
Priority to JP61197335A priority Critical patent/JPS6354213A/en
Publication of JPS6354213A publication Critical patent/JPS6354213A/en
Pending legal-status Critical Current

Links

Landscapes

  • Moulds For Moulding Plastics Or The Like (AREA)
  • Tyre Moulding (AREA)

Abstract

PURPOSE:To prevent the edge or the like of a mold from wearing and deforming and at the same time make it possible to manufacture a molded item with glossy surface texture by a method wherein the surface of metal and/or ceramic spray films, which are formed onto a molding die, is polished. CONSTITUTION:When the forming of a spray film by ceramic spraying material is intended, a method to be adopted is the spraying of metal-based spraying material, preferably nickel-aluminum, nickel-chrome, molybdenum-nickel- aluminum composites or the like as ground coating material in order to enhance the adhesion between a mold and ceramic and in addition the spraying of ceramic as face coating material. Ceramic or ceramic-containing spraying material excellent in wear resistance is exemplified by Al2O3, Al2O3.TiO2 composite, TiO2, WC or the like. The surface of the formed spray film layer with satin surface texture is polished into a surface roughness of which is 1.0-3.6mum, preferably about 2.0-3.6mum, in centerline average height (Ra value).

Description

【発明の詳細な説明】 りえ上立坦■盈1 本発明は、成形用金型に関する。更に詳しくは、金型の
成形面に溶射皮膜を設けさらに該皮膜表面を研摩するこ
とにより、光沢性を有するゴム等の成形品、例えば、タ
イヤ、チューブ、防振ゴム、ベルト、ゴムクローラ−笠
の製造に好適な成形用金型を提供するものである。
DETAILED DESCRIPTION OF THE INVENTION The present invention relates to a mold for molding. More specifically, by providing a thermal spray coating on the molding surface of the mold and polishing the coating surface, it is possible to produce glossy molded products such as rubber, such as tires, tubes, anti-vibration rubber, belts, and rubber crawler hats. The present invention provides a mold suitable for manufacturing.

K米五U漬 成形面に金属および/またはセラミックスを溶射して、
溶射皮膜を形成させた金型を用いて型子地肌の合成樹脂
成形品か得られることは、特開昭56−28811号に
より、既に知られている。
Metals and/or ceramics are sprayed on the molded surface of K rice 5 U,
It is already known from JP-A-56-28811 that a synthetic resin molded article with a mold base can be obtained using a mold on which a thermally sprayed coating is formed.

また内在する性質として、耐摩耗性溶射皮膜の場合は金
型の摩耗による変形が防止できることか認められる。
It is also recognized that as an inherent property, in the case of a wear-resistant thermal spray coating, deformation due to mold wear can be prevented.

発11が解決しようとする問題点 前記した従来の方法では金型の!9!耗は防!してきる
が、型子地肌の成形品が得られ、光沢性表面を有する成
形品を得ることはてきなかった。
The problem that Problem 11 aims to solve is that in the conventional method described above, the mold! 9! Prevent wear and tear! However, a molded product with a mold surface was obtained, but a molded product with a glossy surface could not be obtained.

問題点を解決するための手段 本9.明は、前記従来の問題点を解決し、金型の摩耗が
防l卜され、かつ光沢性を有する成形品が得られる成形
用金型を提供するものである。即ち、金型の成形面の少
なくとも−・部に金属および/又はセラミックスの溶射
皮膜層を有し、該溶射皮膜層の表面か研斥されてなるこ
とを特徴とする成形用金型、を要旨とするものである。
Book of means to solve problems 9. The object of the present invention is to provide a molding die that solves the above-mentioned conventional problems, prevents wear of the die, and provides a molded product with gloss. That is, the gist is a molding die characterized in that it has a thermally sprayed coating layer of metal and/or ceramics on at least part of its molding surface, and the surface of the thermally sprayed coating layer is polished. That is.

以下に本発明の詳細な説明する。The present invention will be explained in detail below.

本発明において、金型の材質としては、通常、金型に用
いられる全ての金属が使用できるか、特に鉄、アルミニ
ウムが好ましい。
In the present invention, as the material for the mold, all metals normally used for molds can be used, but iron and aluminum are particularly preferred.

未発11において、金型の成形面に溶射する溶射材料で
ある金属及び/又はセラミックスのうち、溶射金属材料
としては、^l 、 Ti 、 B 、Cr、訃、Ta
 、 Fe 、Si 、 * 、 Co 、 Ni 、
 Zn 、Y 等或いはこれらの合金か挙げられる。ま
た、セラミックス溶射材料としては、上述した金属の酸
化物、窒化物、炭化物、硼化物等が挙げられる。より具
体的には、金属酸化物としてはAlzO* 、Ti1t
、Cr20x 、 5if2、ZrO2,YtOz 、
 IgO、CaO等、金属窒化物としてはAIN 、 
TiN 、 5iiN4、ZrN 、 RN等、金属炭
化物としてはTiC、SiC、WC、ZrC1Cr、、
C= 、114c等、金属硼化物としてはTiC2、Z
rB、 、1IloB、等が使用し得る。これらの金属
、セラミックスは、1種を単独で或は2!!以上を組合
せて用いることができる。
In Misaki No. 11, among the metals and/or ceramics that are the thermal spraying materials to be thermally sprayed on the molding surface of the mold, the thermal spraying metal materials include ^l, Ti, B, Cr, Ta, and Ta.
, Fe, Si, *, Co, Ni,
Examples include Zn, Y, etc., or alloys thereof. Furthermore, examples of the ceramic spraying material include the above-mentioned metal oxides, nitrides, carbides, borides, and the like. More specifically, the metal oxides include AlzO*, Ti1t
, Cr20x, 5if2, ZrO2, YtOz,
Metal nitrides such as IgO and CaO include AIN,
TiN, 5iiN4, ZrN, RN, etc.; metal carbides include TiC, SiC, WC, ZrC1Cr, etc.
C=, 114c, etc., and metal borides such as TiC2, Z
rB, , 1IloB, etc. may be used. These metals and ceramics can be used singly or in combination! ! The above can be used in combination.

更に、金属とセラミックスとを併用しても良い。Furthermore, metals and ceramics may be used together.

市販溶射材料としては、昭和電工(株)の「プラズマ溶
射材料Cl0COAT 1品−覧表」及び第一メテコ(
株)の「メテコ溶射用市版粉末材料表」に記佐されてい
るもの等を用いることができる。
Commercially available thermal spraying materials include Showa Denko K.K.'s "Plasma spraying material Cl0COAT 1 product list" and Daiichi Metco (
Those listed in the "Meteco Thermal Spraying Powder Material Table" published by Co., Ltd. can be used.

特に、本発明においては、耐摩耗性に優れていることか
ら、セラミックスあるいはセラミックスを多く含有する
溶射材料を用いるのが好ましく、とりわけ^1□g、 
、 Al2O,・ TiC2複we等が好ましい。
In particular, in the present invention, it is preferable to use ceramics or thermal spraying materials containing a large amount of ceramics because of their excellent wear resistance.
, Al2O, .TiC2 complex, etc. are preferable.

溶射材料の形状としては特に制限はなく、粉末、ワイヤ
ー及び棒状等、溶射装置に適したものであれば良い。
There is no particular restriction on the shape of the thermal spray material, and any shape suitable for the thermal spraying device may be used, such as powder, wire, or rod shape.

溶射法としても特に制限はなく、プラズマ溶射法、アー
ク溶射法、ガスフレーム溶射法、爆発溶射法等を採用す
ることかできる。
There are no particular restrictions on the thermal spraying method, and plasma spraying, arc spraying, gas flame spraying, explosive thermal spraying, and the like may be employed.

溶射により形成する溶射膜の厚みは、薄すぎると本発明
による改に効果が低く,また厚すぎると剥離等の聞届か
生起する恐れがあることから,−般には.20 〜30
0gm、特に50〜150uLmとするのが好ましい。
If the thickness of the sprayed film formed by thermal spraying is too thin, the effect of the present invention will be low, and if it is too thick, there is a risk of peeling or other problems. 20-30
It is preferable to set it as 0gm, especially 50-150uLm.

なお、本発明において、セラミックス溶射材料により溶
射膜を形成する場合、金型とセラミックスとの密着力を
向上させるために、金属系溶射材料,好ましくはニッケ
ル・アルミニウム、ニッケル・クロム、モリブデン・ニ
ッケル・アルミニウム複合体等を下地材として溶射し、
その上に上塗材としてセラミックスを溶射する方法を採
用することもてきる。この場合には、上塗材のセラミッ
クスの耐摩耗性と、下地材の金属による密着性により、
溶射膜は長期間良好に保持される。
In the present invention, when forming a sprayed film using a ceramic sprayed material, a metallic sprayed material, preferably nickel-aluminum, nickel-chromium, molybdenum-nickel, etc. is used to improve the adhesion between the mold and the ceramic. Spraying aluminum composite etc. as a base material,
A method of thermally spraying ceramics as a top coat material can also be adopted. In this case, due to the wear resistance of the ceramic top coat material and the adhesion of the metal base material,
The sprayed coating retains well for a long period of time.

本発明の成形用金型は,このようにして形成された金属
および/又はセラミックスの溶射皮膜層の表面が研摩さ
れてなるものである.一般に、金属および/又はセラミ
ックスを溶射して得られる皮膜の表面は型子地肌となる
0未発IJ+においては形成された型子地肌の溶射皮膜
層の表面を研摩処理することにより,その表面粗さを中
心線モ均粗さくRa値)で1.0 〜3.6終、とりわ
け、 2.0 〜3、6島程度の粗さとするのか好適で
ある。
The molding die of the present invention is obtained by polishing the surface of the metal and/or ceramic sprayed coating layer thus formed. In general, the surface of the coating obtained by thermal spraying metals and/or ceramics becomes the mold base.In unfired IJ+, the surface of the sprayed coating layer on the mold base is polished to make the surface rough. It is preferable to set the center line roughness (Ra value) to 1.0 to 3.6, particularly 2.0 to 3.6 islands.

研摩処理後の表面の型子地肌の粗さが細かすぎる場合に
は、成形品の表面に空気溜が多発するのて好ましくない
.また過度に粗い場合には,研摩の効果か少なく、光沢
肌か得られない。
If the surface roughness of the mold surface after polishing is too fine, this is undesirable because air pockets will occur frequently on the surface of the molded product. Also, if the surface is too rough, the polishing effect will be low and a glossy surface will not be obtained.

溶射皮膜層の研摩方法としては、特にv1限はなく1例
えば、アルミナ、炭化ケイ稟,ダイヤモンド等の研摩材
料よりなる研摩布,研摩紙,砥石等により乾式又は湿式
にて,自由研削する方法および精密研削する方法等が挙
げられる。
The method of polishing the sprayed coating layer is not particularly limited; for example, a dry or wet method of free grinding with an abrasive cloth, abrasive paper, a grindstone, etc. made of an abrasive material such as alumina, silicon carbide, diamond, etc.; Examples include precision grinding methods.

なお、成形用金型における溶射皮膜層の形成位置として
は、金型成形面の少なくとも一部の耐摩耗性か必要とさ
れる部分が含まれていればよく。
The sprayed coating layer may be formed at a position in the molding die as long as it includes at least a part of the molding surface where wear resistance is required.

具体的には金型のはぶち部分等が例示される。A specific example is the edge of a mold.

[作 用] 従来のl&形面に金属および/またはセラミックスの溶
射皮膜層を有する成形用金型は、成形面の耐摩耗性にす
ぐれるが、ゴムやプラスチックスな成形すると光沢のな
い型子地肌の成形品が得られるにすぎなかった。
[Function] Conventional molding molds with a metal and/or ceramic sprayed coating layer on the L& shape surface have excellent abrasion resistance on the molding surface, but when molded with rubber or plastic, the mold becomes dull. Only a bare molded product was obtained.

これに対し1本発明においては金型の成形面に形成され
た溶射皮膜層の表面が研摩され,これにより小さな面植
の平坦な先端を有する突部か複数形成されたような表面
が設けられるので型子地肌の場合の光が乱反射されるの
と異なり,平坦な部分か光を一定方向に反射するため光
沢を有する。
In contrast, in the present invention, the surface of the sprayed coating layer formed on the molding surface of the mold is polished, thereby providing a surface with a plurality of small protrusions each having a flat tip. Therefore, unlike the surface of the mold, where light is diffusely reflected, the flat parts reflect light in a certain direction, giving it a glossy appearance.

従って、本発明の金型によりゴムやプラスチックスな成
形すると1表面に光沢を有するゴムやプラスチックスの
成形品か得られる。
Therefore, when rubber or plastic is molded using the mold of the present invention, a molded product of rubber or plastic that has gloss on one surface can be obtained.

[実施例] 以下に実施例及び比較例を挙げて、本発明をより具体的
に説明するか、本発明はその要旨を超えない限り、以下
の実施例に制限されるものではない。
[Examples] The present invention will be described below in more detail with reference to Examples and Comparative Examples, and the present invention is not limited to the following Examples unless it exceeds the gist thereof.

なお、実施例及び比較例において、中心線平均粗さくR
a)は表面粗さ測定器により測定した。また光沢度は変
角光沢針により60”の角度で測定した。
In addition, in the examples and comparative examples, the center line average roughness R
A) was measured using a surface roughness measuring device. Glossiness was also measured at an angle of 60'' using a variable angle glossy needle.

実施例1 ゴム加硫用金型の成形面にニッケル・クロム合金(粒径
30−5ル)を下地材として20uL厚さにプラズマ溶
射し、更にアルミナ・チタニア複合材(粒径25−5u
L)を北塗り材として60ル厚さにプラズマ溶射した。
Example 1 A nickel-chromium alloy (particle size 30-5 μL) was plasma sprayed on the molding surface of a rubber vulcanization mold to a thickness of 20 μL as a base material, and an alumina-titania composite material (particle size 25-5 μL) was further applied to the molding surface of a rubber vulcanization mold.
L) was plasma sprayed to a thickness of 60 l as a north coating material.

得られた溶射皮膜のRa値は4.コ終てあった。次いで
この溶射皮膜表面を研摩布CC−800(研摩材:炭化
ケイ素9粒度:800)を使用してRa=3.0までみ
かいた。この表面の光沢度は2.コてあり、光沢かある
。また該金型によりゴムをプレス加硫したところ、ゴム
成形品の表面の光沢度は2.2であり、光沢があった。
The Ra value of the obtained thermal spray coating was 4. It was over. Next, the surface of this sprayed coating was polished to Ra=3.0 using an abrasive cloth CC-800 (abrasive material: silicon carbide 9 particle size: 800). The gloss level of this surface is 2. It's shiny and shiny. When the rubber was press-vulcanized using the mold, the surface gloss of the rubber molded product was 2.2 and was glossy.

比較例1 ゴム加硫用金型の成形面にニッケル・クロム合金(粒径
30−5延)を下地材として20ル厚さにプラズマ溶射
し、更にアルミナ・チタニア複合材(粒径25−5u)
を上塗り材として60鉢厚さにプラズマ溶射した。
Comparative Example 1 A nickel-chromium alloy (particle size 30-5 μm) was plasma sprayed on the molding surface of a rubber vulcanization mold to a thickness of 20 μl as a base material, and an alumina-titania composite material (particle size 25-5 μm )
was plasma sprayed to a thickness of 60 mm as a top coat.

得られた溶射皮膜のRa値は4−33Lであった0表面
は型子地肌であり、光沢度は0.6で光沢かない、また
該金型によりゴムをプレス加硫したところ、ゴム成形品
の表面も型子地肌であり、光沢度は0.6で光沢がない
The Ra value of the obtained thermal spray coating was 4-33L.The surface was the surface of the mold, and the gloss was 0.6, which was not glossy.Also, when the rubber was press-vulcanized using the mold, the rubber molded product was The surface is also a molded surface, and the gloss level is 0.6, meaning there is no gloss.

比較例2 ゴム加硫用金型の成形面にニッケル・クロム合金(粒径
5o−51L)を下地材として201Lノ°1さにプラ
ズマ溶射し、更にアルミナ・チタニア複合材(粒径25
−5牌)を上塗り材として60鉢厚さにプラズマ溶射し
た。
Comparative Example 2 A nickel-chromium alloy (particle size 5o-51L) was plasma sprayed on the molding surface of a rubber vulcanization mold at 201L as a base material, and an alumina-titania composite material (particle size 25
-5 tiles) was plasma sprayed to a thickness of 60 pots as a top coat material.

得られた溶射皮膜のRa値は4.3鉢であった0次いで
この溶射皮膜表面を研J9!布CC−800を使用して
Ra= 3.7 gまてみかいた。この表面の光沢度は
0.8であり、光沢かない、また該金型によりゴムをプ
レス加硫したところ、ゴム成形品の表面の光沢度は0.
8てあり、光沢かない。
The Ra value of the obtained thermal sprayed coating was 4.3. The surface of this thermal sprayed coating was then polished by J9! Using cloth CC-800, I measured Ra=3.7 g. The gloss level of this surface was 0.8, which was not glossy. When the rubber was press-vulcanized using the mold, the gloss level of the surface of the rubber molded product was 0.8.
8 and is not shiny.

[5?!明の効果コ 以上詳述した通り、本発明の成形用金型は金型の成形面
の少なくとも一部に金属および/又はセラミンクスの溶
射皮膜層を有し、該溶射皮膜層の表面が研摩されている
ものてあり、これにより、金型のはぶち等の摩耗、変形
か防止されるとともに光沢肌を有する成形品を製造でき
る。また、溶射層のエアー拡散効果によりベントホール
を廃止したり、数を少なくしてもエアー溜りのない成形
品をSSI造することかてきる。
[5? ! As detailed above, the molding die of the present invention has a thermally sprayed coating layer of metal and/or ceramics on at least a part of the molding surface of the mold, and the surface of the thermally sprayed coating layer is polished. This prevents abrasion and deformation of the edges of the mold, and allows the production of molded products with glossy surfaces. Furthermore, due to the air diffusion effect of the sprayed layer, it is possible to eliminate vent holes or reduce the number of vent holes to produce a molded product without air pockets using SSI.

従って、未発171の成形用金型は光沢状の外観を有す
るタイヤ、防振ゴム、ゴムクローラ、コンベアベルト、
チューブ、可撓管、発泡ゴム製品等のゴム成形品や発泡
または非発泡のプラスチック成形品を製造するのに有効
である。
Therefore, the unreleased 171 molds include tires with a glossy appearance, anti-vibration rubber, rubber crawlers, conveyor belts,
It is effective for manufacturing rubber molded products such as tubes, flexible pipes, foamed rubber products, and foamed or non-foamed plastic molded products.

Claims (1)

【特許請求の範囲】[Claims] (1)金型の成形面の少なくとも一部に金属および/又
はセラミックスの溶射皮膜層を有し、該溶射皮膜層の表
面が研摩されてなることを特徴とする成形用金型。
(1) A molding die characterized in that it has a thermally sprayed coating layer of metal and/or ceramics on at least a portion of its molding surface, and the surface of the thermally sprayed coating layer is polished.
JP61197335A 1986-08-25 1986-08-25 Molding die Pending JPS6354213A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP61197335A JPS6354213A (en) 1986-08-25 1986-08-25 Molding die

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP61197335A JPS6354213A (en) 1986-08-25 1986-08-25 Molding die

Publications (1)

Publication Number Publication Date
JPS6354213A true JPS6354213A (en) 1988-03-08

Family

ID=16372757

Family Applications (1)

Application Number Title Priority Date Filing Date
JP61197335A Pending JPS6354213A (en) 1986-08-25 1986-08-25 Molding die

Country Status (1)

Country Link
JP (1) JPS6354213A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH05192931A (en) * 1992-01-17 1993-08-03 Maeda Seikan Kk Mold for molding resin product and production thereof
JP2006116717A (en) * 2004-10-19 2006-05-11 Tigers Polymer Corp Blow mold

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH05192931A (en) * 1992-01-17 1993-08-03 Maeda Seikan Kk Mold for molding resin product and production thereof
JP2006116717A (en) * 2004-10-19 2006-05-11 Tigers Polymer Corp Blow mold

Similar Documents

Publication Publication Date Title
DE69303474D1 (en) Flexible abrasive belt coated with maleimide resin
MY105513A (en) Slide fastener and fastener elements therefor.
RU92016414A (en) ABRASIVE PARTICLES, ABRASIVE PRODUCT IN THE FORM OF ABRASIVE PRODUCT WITH A COATING, METHOD OF MANUFACTURING ABRASIVE PARTICLES
JPS61215279A (en) Slide member coated with ceramic material component
PL312496A1 (en) Shaped element coated with diamonds
CN102527899A (en) Mold for plastic forming and a method for producing the same, and method for forging aluminum material
CA2294953A1 (en) Flexible abrasive body
JPS6354213A (en) Molding die
US2690065A (en) Ceramic ware
JPS6056791B2 (en) hot plate
GB1420010A (en) Low-friction wear-resistant material and process for making the same
JPH0530795B2 (en)
JPH07166318A (en) Mask for forming coating pattern
JP2011163815A (en) Timepiece component, manufacturing method thereof, and aesthetic treatment method of timepiece component
JPS5939785A (en) Dressing gold color member
JPS5852467A (en) Machine member having sprayed layer formed by water plasma spraying
TW355154B (en) Coated abrasive belt adapted for use at elevated temperature and process for conditioning a metal surface at elevated temperature
JPH03271125A (en) Mold for molding glass
JPS586970A (en) Coated sintered hard alloy member
JPS63190153A (en) Thermally metal-sprayed product
JP2530616B2 (en) Coated ZrO 2 system ceramics and method for producing the same
JPH01142071A (en) Production of double coated metal
Kremer et al. Ultrasonic machining applied to ceramic materials
GB2068121A (en) A measuring body having a protective coating
JPH02311281A (en) Honeycomb surface plate