JPS6349484A - Thermal transfer sheet - Google Patents
Thermal transfer sheetInfo
- Publication number
- JPS6349484A JPS6349484A JP61193480A JP19348086A JPS6349484A JP S6349484 A JPS6349484 A JP S6349484A JP 61193480 A JP61193480 A JP 61193480A JP 19348086 A JP19348086 A JP 19348086A JP S6349484 A JPS6349484 A JP S6349484A
- Authority
- JP
- Japan
- Prior art keywords
- heat
- layer
- sensitive
- transfer layer
- resistant
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- -1 alkali metal salt Chemical class 0.000 claims abstract description 27
- 238000000576 coating method Methods 0.000 claims abstract description 21
- 239000011248 coating agent Substances 0.000 claims abstract description 20
- 239000002585 base Substances 0.000 claims abstract description 19
- 238000000859 sublimation Methods 0.000 claims abstract description 15
- 230000008022 sublimation Effects 0.000 claims abstract description 15
- 239000000463 material Substances 0.000 claims abstract description 12
- 229910052783 alkali metal Inorganic materials 0.000 claims abstract description 9
- 229910052784 alkaline earth metal Inorganic materials 0.000 claims abstract description 9
- 230000005865 ionizing radiation Effects 0.000 claims abstract description 9
- 229920000642 polymer Polymers 0.000 claims abstract description 6
- 239000000178 monomer Substances 0.000 claims abstract 2
- 229920005989 resin Polymers 0.000 claims description 15
- 239000011347 resin Substances 0.000 claims description 15
- 229920005862 polyol Polymers 0.000 claims description 8
- 150000002148 esters Chemical class 0.000 claims description 7
- 238000002844 melting Methods 0.000 claims description 6
- 239000011230 binding agent Substances 0.000 claims description 5
- 125000004432 carbon atom Chemical group C* 0.000 claims description 5
- 239000003795 chemical substances by application Substances 0.000 claims description 5
- 239000003086 colorant Substances 0.000 claims description 4
- 229920001187 thermosetting polymer Polymers 0.000 claims description 4
- 239000012948 isocyanate Substances 0.000 claims description 3
- 150000002513 isocyanates Chemical class 0.000 claims description 3
- 230000008018 melting Effects 0.000 claims description 3
- 239000000049 pigment Substances 0.000 claims description 2
- 150000002430 hydrocarbons Chemical group 0.000 claims 1
- 229920003002 synthetic resin Polymers 0.000 claims 1
- 239000000057 synthetic resin Substances 0.000 claims 1
- 150000003014 phosphoric acid esters Chemical class 0.000 abstract description 11
- 125000001183 hydrocarbyl group Chemical group 0.000 abstract description 4
- 239000002985 plastic film Substances 0.000 abstract description 4
- 229920006255 plastic film Polymers 0.000 abstract description 4
- 230000001678 irradiating effect Effects 0.000 abstract 2
- 230000004927 fusion Effects 0.000 abstract 1
- 239000000203 mixture Substances 0.000 description 23
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 11
- 239000000126 substance Substances 0.000 description 11
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 7
- 238000000034 method Methods 0.000 description 7
- 239000001993 wax Substances 0.000 description 7
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 6
- 239000000975 dye Substances 0.000 description 6
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 5
- 239000000123 paper Substances 0.000 description 5
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 5
- 229920006267 polyester film Polymers 0.000 description 5
- 239000004926 polymethyl methacrylate Substances 0.000 description 5
- DVQHRBFGRZHMSR-UHFFFAOYSA-N sodium methyl 2,2-dimethyl-4,6-dioxo-5-(N-prop-2-enoxy-C-propylcarbonimidoyl)cyclohexane-1-carboxylate Chemical compound [Na+].C=CCON=C(CCC)[C-]1C(=O)CC(C)(C)C(C(=O)OC)C1=O DVQHRBFGRZHMSR-UHFFFAOYSA-N 0.000 description 5
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 5
- 239000004925 Acrylic resin Substances 0.000 description 4
- 229920000178 Acrylic resin Polymers 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 238000010894 electron beam technology Methods 0.000 description 4
- 229920002037 poly(vinyl butyral) polymer Polymers 0.000 description 4
- 229920000728 polyester Polymers 0.000 description 4
- 229920001225 polyester resin Polymers 0.000 description 4
- 239000004645 polyester resin Substances 0.000 description 4
- 150000003609 titanium compounds Chemical class 0.000 description 4
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 3
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 3
- 230000001070 adhesive effect Effects 0.000 description 3
- 230000000903 blocking effect Effects 0.000 description 3
- 229920002301 cellulose acetate Polymers 0.000 description 3
- 239000002738 chelating agent Substances 0.000 description 3
- 125000004386 diacrylate group Chemical group 0.000 description 3
- 235000014113 dietary fatty acids Nutrition 0.000 description 3
- 239000000194 fatty acid Substances 0.000 description 3
- 229930195729 fatty acid Natural products 0.000 description 3
- 229920001296 polysiloxane Polymers 0.000 description 3
- 239000002893 slag Substances 0.000 description 3
- 239000010936 titanium Substances 0.000 description 3
- 229910052719 titanium Inorganic materials 0.000 description 3
- RTTZISZSHSCFRH-UHFFFAOYSA-N 1,3-bis(isocyanatomethyl)benzene Chemical compound O=C=NCC1=CC=CC(CN=C=O)=C1 RTTZISZSHSCFRH-UHFFFAOYSA-N 0.000 description 2
- AZQWKYJCGOJGHM-UHFFFAOYSA-N 1,4-benzoquinone Chemical compound O=C1C=CC(=O)C=C1 AZQWKYJCGOJGHM-UHFFFAOYSA-N 0.000 description 2
- KWOLFJPFCHCOCG-UHFFFAOYSA-N Acetophenone Chemical compound CC(=O)C1=CC=CC=C1 KWOLFJPFCHCOCG-UHFFFAOYSA-N 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 description 2
- 229920000877 Melamine resin Polymers 0.000 description 2
- 229910019142 PO4 Inorganic materials 0.000 description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- 239000000853 adhesive Substances 0.000 description 2
- 150000001340 alkali metals Chemical class 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 125000005442 diisocyanate group Chemical group 0.000 description 2
- 239000000986 disperse dye Substances 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 229920001971 elastomer Polymers 0.000 description 2
- 150000004665 fatty acids Chemical class 0.000 description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- LYRFLYHAGKPMFH-UHFFFAOYSA-N octadecanamide Chemical compound CCCCCCCCCCCCCCCCCC(N)=O LYRFLYHAGKPMFH-UHFFFAOYSA-N 0.000 description 2
- 239000012188 paraffin wax Substances 0.000 description 2
- 239000010452 phosphate Substances 0.000 description 2
- 229920001228 polyisocyanate Polymers 0.000 description 2
- 239000005056 polyisocyanate Substances 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- 229920002545 silicone oil Polymers 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 238000003860 storage Methods 0.000 description 2
- 230000037303 wrinkles Effects 0.000 description 2
- QOSTVEDABRQTSU-UHFFFAOYSA-N 1,4-bis(methylamino)anthracene-9,10-dione Chemical compound O=C1C2=CC=CC=C2C(=O)C2=C1C(NC)=CC=C2NC QOSTVEDABRQTSU-UHFFFAOYSA-N 0.000 description 1
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- ZNQVEEAIQZEUHB-UHFFFAOYSA-N 2-ethoxyethanol Chemical compound CCOCCO ZNQVEEAIQZEUHB-UHFFFAOYSA-N 0.000 description 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 229920000298 Cellophane Polymers 0.000 description 1
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 description 1
- 229920003314 Elvaloy® Polymers 0.000 description 1
- 239000004593 Epoxy Substances 0.000 description 1
- UAUDZVJPLUQNMU-UHFFFAOYSA-N Erucasaeureamid Natural products CCCCCCCCC=CCCCCCCCCCCCC(N)=O UAUDZVJPLUQNMU-UHFFFAOYSA-N 0.000 description 1
- 239000001856 Ethyl cellulose Substances 0.000 description 1
- ZZSNKZQZMQGXPY-UHFFFAOYSA-N Ethyl cellulose Chemical compound CCOCC1OC(OC)C(OCC)C(OCC)C1OC1C(O)C(O)C(OC)C(CO)O1 ZZSNKZQZMQGXPY-UHFFFAOYSA-N 0.000 description 1
- 239000004606 Fillers/Extenders Substances 0.000 description 1
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 description 1
- 239000004354 Hydroxyethyl cellulose Substances 0.000 description 1
- 229920002153 Hydroxypropyl cellulose Polymers 0.000 description 1
- 239000004166 Lanolin Substances 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 1
- 239000000020 Nitrocellulose Substances 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- 239000004642 Polyimide Substances 0.000 description 1
- 239000004734 Polyphenylene sulfide Substances 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- 229920001800 Shellac Polymers 0.000 description 1
- 239000004163 Spermaceti wax Substances 0.000 description 1
- 239000004809 Teflon Substances 0.000 description 1
- 229920006362 Teflon® Polymers 0.000 description 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 description 1
- 208000000260 Warts Diseases 0.000 description 1
- UKLDJPRMSDWDSL-UHFFFAOYSA-L [dibutyl(dodecanoyloxy)stannyl] dodecanoate Chemical compound CCCCCCCCCCCC(=O)O[Sn](CCCC)(CCCC)OC(=O)CCCCCCCCCCC UKLDJPRMSDWDSL-UHFFFAOYSA-L 0.000 description 1
- 150000001342 alkaline earth metals Chemical class 0.000 description 1
- 125000001204 arachidyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000012298 atmosphere Substances 0.000 description 1
- 235000013871 bee wax Nutrition 0.000 description 1
- 239000012166 beeswax Substances 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 239000004204 candelilla wax Substances 0.000 description 1
- 235000013868 candelilla wax Nutrition 0.000 description 1
- 229940073532 candelilla wax Drugs 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000004203 carnauba wax Substances 0.000 description 1
- 235000013869 carnauba wax Nutrition 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 229920006217 cellulose acetate butyrate Polymers 0.000 description 1
- 239000012461 cellulose resin Substances 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 229910052570 clay Inorganic materials 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 229910001873 dinitrogen Inorganic materials 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000004043 dyeing Methods 0.000 description 1
- UAUDZVJPLUQNMU-KTKRTIGZSA-N erucamide Chemical compound CCCCCCCC\C=C/CCCCCCCCCCCC(N)=O UAUDZVJPLUQNMU-KTKRTIGZSA-N 0.000 description 1
- 229920001249 ethyl cellulose Polymers 0.000 description 1
- 235000019325 ethyl cellulose Nutrition 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 238000007756 gravure coating Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- IUJAMGNYPWYUPM-UHFFFAOYSA-N hentriacontane Chemical compound CCCCCCCCCCCCCCCCCCCCCCCCCCCCCCC IUJAMGNYPWYUPM-UHFFFAOYSA-N 0.000 description 1
- PZDUWXKXFAIFOR-UHFFFAOYSA-N hexadecyl prop-2-enoate Chemical compound CCCCCCCCCCCCCCCCOC(=O)C=C PZDUWXKXFAIFOR-UHFFFAOYSA-N 0.000 description 1
- 238000007757 hot melt coating Methods 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 1
- 239000001863 hydroxypropyl cellulose Substances 0.000 description 1
- 235000010977 hydroxypropyl cellulose Nutrition 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 239000001023 inorganic pigment Substances 0.000 description 1
- ZXEKIIBDNHEJCQ-UHFFFAOYSA-N isobutanol Chemical compound CC(C)CO ZXEKIIBDNHEJCQ-UHFFFAOYSA-N 0.000 description 1
- 235000019388 lanolin Nutrition 0.000 description 1
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 description 1
- 239000001095 magnesium carbonate Substances 0.000 description 1
- 229910000021 magnesium carbonate Inorganic materials 0.000 description 1
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 description 1
- 229920000609 methyl cellulose Polymers 0.000 description 1
- 239000001923 methylcellulose Substances 0.000 description 1
- 235000010981 methylcellulose Nutrition 0.000 description 1
- 239000004200 microcrystalline wax Substances 0.000 description 1
- 235000019808 microcrystalline wax Nutrition 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 125000001421 myristyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 229920001220 nitrocellulos Polymers 0.000 description 1
- 239000012299 nitrogen atmosphere Substances 0.000 description 1
- 125000001117 oleyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])/C([H])=C([H])\C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 235000019809 paraffin wax Nutrition 0.000 description 1
- 125000002958 pentadecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 1
- 235000019271 petrolatum Nutrition 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 229920002401 polyacrylamide Polymers 0.000 description 1
- 239000004417 polycarbonate Substances 0.000 description 1
- 229920000515 polycarbonate Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 229920000139 polyethylene terephthalate Polymers 0.000 description 1
- 239000005020 polyethylene terephthalate Substances 0.000 description 1
- 229920001721 polyimide Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 150000003077 polyols Chemical class 0.000 description 1
- 229920000069 polyphenylene sulfide Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229920005749 polyurethane resin Polymers 0.000 description 1
- 229920002689 polyvinyl acetate Polymers 0.000 description 1
- 239000011118 polyvinyl acetate Substances 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 1
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 1
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
- 239000013615 primer Substances 0.000 description 1
- 239000002987 primer (paints) Substances 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 239000004208 shellac Substances 0.000 description 1
- 235000013874 shellac Nutrition 0.000 description 1
- ZLGIYFNHBLSMPS-ATJNOEHPSA-N shellac Chemical compound OCCCCCC(O)C(O)CCCCCCCC(O)=O.C1C23[C@H](C(O)=O)CCC2[C@](C)(CO)[C@@H]1C(C(O)=O)=C[C@@H]3O ZLGIYFNHBLSMPS-ATJNOEHPSA-N 0.000 description 1
- 229940113147 shellac Drugs 0.000 description 1
- 201000010153 skin papilloma Diseases 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 235000019385 spermaceti wax Nutrition 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 229940037312 stearamide Drugs 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- 238000011282 treatment Methods 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 238000004804 winding Methods 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/26—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used
- B41M5/40—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used characterised by the base backcoat, intermediate, or covering layers, e.g. for thermal transfer dye-donor or dye-receiver sheets; Heat, radiation filtering or absorbing means or layers; combined with other image registration layers or compositions; Special originals for reproduction by thermography
- B41M5/405—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used characterised by the base backcoat, intermediate, or covering layers, e.g. for thermal transfer dye-donor or dye-receiver sheets; Heat, radiation filtering or absorbing means or layers; combined with other image registration layers or compositions; Special originals for reproduction by thermography characterised by layers cured by radiation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/26—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used
- B41M5/40—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used characterised by the base backcoat, intermediate, or covering layers, e.g. for thermal transfer dye-donor or dye-receiver sheets; Heat, radiation filtering or absorbing means or layers; combined with other image registration layers or compositions; Special originals for reproduction by thermography
- B41M5/42—Intermediate, backcoat, or covering layers
- B41M5/423—Intermediate, backcoat, or covering layers characterised by non-macromolecular compounds, e.g. waxes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/26—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used
- B41M5/40—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used characterised by the base backcoat, intermediate, or covering layers, e.g. for thermal transfer dye-donor or dye-receiver sheets; Heat, radiation filtering or absorbing means or layers; combined with other image registration layers or compositions; Special originals for reproduction by thermography
- B41M5/42—Intermediate, backcoat, or covering layers
- B41M5/426—Intermediate, backcoat, or covering layers characterised by inorganic compounds, e.g. metals, metal salts, metal complexes
Landscapes
- Physics & Mathematics (AREA)
- Optics & Photonics (AREA)
- Impression-Transfer Materials And Handling Thereof (AREA)
- Thermal Transfer Or Thermal Recording In General (AREA)
Abstract
Description
〔産業上の利用分野〕
、二の発明は、感熱転写シートに関するものであって、
サーマルヘッドへのスティッキング、および、滓の付着
を防止したものである。
〔従来の技術〕
コンピュータやワードプロセッサの出カブリントをｑ
２Ｈ転写によって行なう場合、■熱移行性の感熱昇華転
写シートを利用する方式と、■感熱溶融転写シートを利
用する方式の２つの方式がある。
いずれの方式によるとしても、転写シートのヘースフィ
ルムは、ポリエステルフィルムなどのプラスチックフィ
ルムであることがｔｉｎであるから、サーマルヘッドへ
のスティッキングを防止することや、サーマルヘッド上
での円滑な走行を確保することは、いずれも重要なこと
である。
これらの目的で、ヘースフィルムの転写層の反対側、即
ち、サーマルヘッドとの接触面倒にスティンキング防止
層を設けることが従来から行なわれているが、満足すべ
きものではなく、スティッキングの防止をより確実にす
ること、サーマルへ、ドへの滓の付着を防止すること、
および、サーマルヘッド上でのより円滑な走行を確保す
る方策の要望がある。
〔発明が解決しようとする問題点〕
この発明においては、感熱転写シートに対する上記した
要望をより一層満足させる感熱転写シートを堤供するこ
とを目的とする。
〔問題点を解決するための手段〕
この発明は、
「 基体シートの一方の面に、忌熱転写層を有しており
、他方の面には、下記の＋ａ＋〜ｔｃ＋の各成分からな
る塗工材料の電離放射線１眉射による硬化塗膜からなる
耐熱スリップ層を有することを特徴とする感熱転写シー
ト。
ｆａｔ炭素数１２以上の直鎖炭化水素基とラジカル重合
性不飽和基とを有する。＃量体５０〜７０重量％
ｆｂｌポリマー ３０〜５０重量％ｆｃｌ
リン酸エステルまたはリン酸エステルのアルカリ金属塩
もしくはアルカリ土類金属塩 １〜
２０重量％ｊを要旨とするものである。
以下に、この発明の感熱転写シートを構成する、基体シ
ート、感熱転写層、および耐熱スリップ層について、順
に説明する。
■困ヱニ上
基体シートとしては、耐熱性のあるプラスチックフィル
ムか、紙が使用できる。
例えば、ポリエステル、ポリプロピレン、セロファン、
アセテート、ポリカーボネート、ポリイミド、もしくは
ポリフェニレンサルファイドなどのプラスチックフィル
ム、または、コンデンサー祇もしくはパラフィン祇など
の紙が挙げられ、これらのうちでも、厚みが均一である
こと、表面が平滑であること、プリンター内での取り扱
い操作が容易であることなどの理想からポリエステルフ
ィルムを使用することが最も一般的である。
一３ノ１粘」Ｌｌ−
感熱転写層には、大別すると感熱昇華転写層と窓？ｊ！
、溶融転写層の２つのタイプがあり、これら自体は従来
使用されているものでよい。
また、感熱転写層として、色相の異なる複数の層を用い
ると、色を重ねて印字することもできる。
瀝じＹ昇」Ｌ（」す[Industrial Application Field] The second invention relates to a thermal transfer sheet,
This prevents sticking and slag from adhering to the thermal head. [Prior art] Printing the output of a computer or word processor
When performing 2H transfer, there are two methods: (1) a method using a heat-transferable heat-sensitive sublimation transfer sheet, and (2) a method using a heat-sensitive melt transfer sheet. Regardless of which method is used, the heath film of the transfer sheet is a plastic film such as polyester film, so it is necessary to prevent sticking to the thermal head and to ensure smooth running on the thermal head. All of these are important to ensure. For these purposes, it has been conventional practice to provide an anti-stinking layer on the opposite side of the transfer layer of the heat film, that is, on the side that contacts the thermal head, but this is not satisfactory and it is difficult to prevent sticking. To make it more reliable, to prevent slag from adhering to thermals and doors,
Additionally, there is a demand for measures to ensure smoother running on the thermal head. [Problems to be Solved by the Invention] An object of the present invention is to provide a heat-sensitive transfer sheet that further satisfies the above-mentioned demands for a heat-sensitive transfer sheet. [Means for Solving the Problems] This invention provides: ``One side of the base sheet has a heat-resistant transfer layer, and the other side is coated with each of the following components +a+ to tc+. A heat-sensitive transfer sheet characterized by having a heat-resistant slip layer consisting of a coating film cured by ionizing radiation of a material.fat has a linear hydrocarbon group having 12 or more carbon atoms and a radically polymerizable unsaturated group.# 50-70% by weight fbl polymer 30-50% by weight fcl
Phosphoric ester or alkali metal salt or alkaline earth metal salt of phosphoric ester 1-
The gist is 20% by weight. Below, the base sheet, the heat-sensitive transfer layer, and the heat-resistant slip layer that constitute the heat-sensitive transfer sheet of the present invention will be explained in order. ■As the upper base sheet, heat-resistant plastic film or paper can be used. For example, polyester, polypropylene, cellophane,
Examples include plastic films such as acetate, polycarbonate, polyimide, or polyphenylene sulfide, or papers such as condenser or paraffin. Polyester film is most commonly used because of its ease of handling. 13 No. 1 Adhesive"Ll- Thermal transfer layers can be roughly divided into heat-sensitive sublimation transfer layers and windows? j!
There are two types of fused transfer layers, which themselves may be conventionally used. Further, if a plurality of layers having different hues are used as the heat-sensitive transfer layer, it is also possible to print in overlapping colors. Death Y Noboru'L('su
【
感熱昇華転写層に含まれる染料は、分散染料であること
が望ましく、通常１５０〜４００前後の分子量を有して
いるとか望ましい。
感熱昇華転写層に含まれるバインダーは、耐熱性が高く
、しかも加熱された場合に染料の移行を妨げないもので
あり、例えば、次のようなものである：
セルロース系樹脂として、エチルセルロース、ヒドロキ
シエチルセルロース、ヒドロキシプロピルセルロース、
メチルセルロース、酢酸セルロース、酢酪酸セルロース
など、
ビニル系樹脂として、ポリビニルアルコール、ポリ酢酸
ビニル、ポリビニルブチラール、ポリビニルピロリドン
、ポリエステル、ポリアクリルアミドなど。
感熱昇華転写層を基体シート上に形成するには、バイン
ダーをン容剤で？容解し、のぞましくは染料も溶解して
インキを作成し、適当な塗布、印刷方法を利用して皮膜
化すればよい。
１島熱ン容融重え」す上屋り
感熱溶融転写層に含まれる着色剤は、有ＲｆＲ料、無機
顔料、もしくは染料である。
感熱溶融転写層に含まれるバインダーとしては、多くは
、ワックスが用いられる。
ワックスとしては、マイクロクリスタリンワックス、カ
ルナバワックス、モしくはパラフィンワックスがよく用
いられるが、他に、フィッシャートロプンヱワックス、
各種低分子量ポリエチレンおよび一部の変性ワックス、
脂肪酸エステル、脂肪酸アミド、木ろう、蜜ろう、鯨ろ
う、いぼたろう、羊毛ろう、セラック、カンデリラワッ
クス、ペトロラクタムなどがある。
この他、樹脂も用いられることがある。
感熱溶融転写層を基体ソート上に形成するには、着色剤
とバインダーとを溶融混練し、ホットメルトコーティン
グするのがよいが、他に通常の印刷、塗布方式を利用し
ても行なえる。
百す 熱 ス リ ノ ブ Ｒ可
耐熱スリップ層は、下記＋ａｌ〜ｆｃ）の成分を混合し
た塗工材料を、基体シートの感熱転写層とは反対側に塗
布し、硬化させることにより形成される。
ｆａｔの成分は、炭素数１２以上の直鎖炭化水素基とラ
ジカル重合性不飽和基とを有する単１体であり、炭素数
１２以上の直鎖炭化水素基を有しているので、耐熱スリ
ップ層の表面に滑性を与えることができる上、ラジカル
重合性不飽和基が電離放射線照射により架橋硬化する。
具体的には（ａｌの成分として、次のようなものが挙げ
られる；
（メタ）アクリル酸ラウリル（この表３己は、メタクリ
ル酸ラウリルとアクリル酸ラウリルの両方を指す、以下
も同様）、（メタ）アクリル酸セチル、（メタ）アクリ
ル酸ステアリル、（メタ）アクリル酸ミリスチル、（メ
タ）アクリル酸ペンタデシル、（メタ）アクリル酸ノナ
デンル、（メタ）アクリル酸エイコシル、（メタ）アク
リル酸オレイル、（メタ）アクリル酸エライジル、（メ
タ）アクリル酸すルイル、（メタ）アクリル酸すルニル
、（メタ）アクリル酸へヘニル。
この他、トリメチロールプロパン、ペンタエリスリトー
ルなどの多価アルコールの水酸基の一部を、アクリル酸
あるいはメタアクリル酸でエステル化し、残りの水酸基
を炭素数１２以上の高級脂肪酸でエステル化した化合物
もｆａｔの成分として使用できる。
このｆａｔの成分は、塗工材料中、５０〜７０重債％使
用することがよく、５０重量％未満では滑性が充分でな
く、７０重量％を越えると被膜強度を低下させる。
中）の成分のポリマーは、耐熱スリップ層の被膜を構成
するものであり、アクリル樹脂、ポリエステル樹脂、若
しくはポリウレタン樹脂などが挙げられ、市販品の例と
しては、アクリル樹脂では、三菱レイヨンｎ製のダイヤ
ナール、協和ガス化学■製のバラペット、ポリエステル
樹脂では、東洋紡■製のバイロン、成田薬品工業■製の
タケネートなどがある。
上記のポリマーのうち、アクリル樹脂、特にポリメタク
リル酸メチル樹脂は耐熱性が高く、また、感熱転写層が
昇華タイプの場合に耐熱スリップ層への染料の移行によ
る染着が防止できる点でよい。
なお、上記のポリマーの末端もしくは側鎖にアクリル基
を導入して（ａｌの成分との反応性を高めることにより
電離放射線の照射効果を向上させ、耐熱性の向上を図る
ことができる。
この（ｂｌの成分は、塗工材料中、３０〜５０重号％使
用することがよく、３０重量％未満では被膜強度が充分
でなく、５０重呈％を越えると相対的にｆａｔの成分の
割合が低下する結果、スティッキングを起こしやすくな
る。
（Ｃ１の成分は耐熱スリップ層に滑性、およびヘッドと
の離型性を与えるものであり、下記式（ｒ）のリン酸エ
ステル、または、リン酸エステルのアルカリ金属塩（も
しくはリン酸エステルのアルカリ土類金属塩）である。
リン酸エステルの場合は、式（１）中、ＡｌＢは、一方
が水素、他方が
Ｒ（ＣＨｚ ＣＨｔ Ｏ）−であり、リン酸エステルの
アルカリ金属塩（もしくはリン酸エステルのアルカリ土
類金属塩）の場合は、式（ｒ）中Ａ、ＢはＨ、アルカリ
金属（もしくはアルカリ土類金属）である。
リン酸エステルとしては、第一工業製薬■製のプライサ
ーフ２０日Ｓ、東邦化学■製のＧＡＦＡＣＲ３７１０が
、また、リン酸エステルのアルカリ金属塩もしくはアル
カリ土類金属塩としては、ＧＡＦＡＣＲＤ７２０などが
用いられる。アルカリ金属塩（もしくは゛リン酸エステ
ルのアルカリ土類金属塩）としては、ナトリウム塩が好
ましい。
リン酸エステルと、リン酸エステルのアルカリ金属塩（
もしくはリン酸エステルのアルカリ土類金属塩）は併用
してもよい。
この（Ｃ１の成分は、塗工材料中、１〜２０重Ｈ１％の
割合で用いられるが、特によいのは、１〜１０重量％の
範囲である。ここで、１ｍＭ％未満では滑性が充分でな
く、また、２０重星％を越えると、巻き取ったなどにブ
ロッキングしやずく、さらには、感熱転写層が昇華タイ
プのときは、染料が耐熱スリップ層に移行しやすくなる
ので好ましくない。
上記（ａ）〜（ｃ）の成分以外にも、巻き取り状１辺で
のブロッキングを防止する意味で、ｉｌのタルク、シリ
カ、炭酸カルシウム、テフロンパウダー、シリコーンパ
ウダー、などの粒状物質、もしくは、シリコーンオイル
、ステアリン酸アマイド、エルカ酸アマイドなどを添加
することもよい。
さらに、貯蔵安定剤としてハイドロキノン、ハイドＩ］
キノンモノメチルエーテルなどの重合禁止剤を添加して
、保存性を高めることもできる。
電離放射線として紫外線を使用する場合にはさらに、ベ
ンゾ・イン系、アセトフェノン系、ペンヅフェノン系な
どの紫外線増感剤を加えるとよい。
上記の各成分は、溶剤で溶解するなどして適当な方？ｂ
で混合して塗工材ｔ４とし、塗布、若しくは印刷方式、
例えば、ロールコーティング、グラビアコーティング、
スクリーンコーティング、ファウンテン：１−ティング
などにより、基体シートの背面に固形分が０．１〜５ｇ
／ｄ、より好ましくは１〜２ｇ／ｍ（Ｉｇ／ｍは被膜厚
み１μｍに相当）になるように塗布し、溶剤を蒸発させ
た後、電離放射線を照射する。電離放射線としては電子
線、紫外線、γ線などが使用できる。電子線、γ線の場
合にその線量は１〜２０Ｍｒａｄ程度である。
ここで、被膜の厚みが０，１μｍ未満であると耐熱スリ
ップ層の効果が充分でなく、５μｍを越えるとサーマル
ヘッドからの熱伝達が悪くなって印字濃度の低下を招く
。
なお、耐熱スリップ層を設けるのと、感熱転写層を設け
るのとは、いずれを先にしても構わない。
ｌノとｌ
耐熱スリップ層を設けることにより、この発明の目的は
達せられるが、場合によっては、感熱プリンターなどの
内部で搬送する際に感熱転写シートに加わる張力もしく
はサーマルヘッドの印字圧によっては、感熱転写シート
のけ送に問題が生じろことがある。
このような場合には、耐熱スリップ層と基体シートの間
に、熱硬化性樹脂と硬化剤とが反応して硬化した硬化に
（脂でできた耐熱層を設けることが望ましい。
熱硬化性樹脂と硬化剤との組み合わせは、代表的なもの
としては、ポリビニルブチラールと多価イソシアネート
、アクリルポリオールと多価イソシアネート、酢酸セル
ロースとチタンキレート剤、および、ポリエステルと有
機チタン化合物であり、それらを含めて、市場で入手で
きるものの商品名・配合割合などを以下の配合例に示す
。なお、以下の記載において「主」とは熱硬化性樹脂を
、「硬ゴとは硬化剤をそれぞれ指す。
■立■
（１）主−・・−ポリビニルブチラール（積木化学製、
エスレソクＢＸ−１１００部
硬−ジイソシアネート（式日薬品製、タケネー ト Ｄ
ＩＩＯＮ ４
５ 部（２）主−ウレタンポリオール（大ロ本インキ
製、ＤＦ３０−５５） １００部硬・−・
・ポリイソシアネート （大日本インキ製、パーツ、り
Ｄ−７５０） ２０部（３）主−・・ウレタ
ンポリオール（大日本インキ製、ＤＦ３０−５５）にＣ
ｏ１％を添加
１００部
硬−・・（２）と同様
＋４１ 主−アクリルポリオール（大日木インキ製、ア
クリルデックＡ−８０１Ｐ
硬・・−・−（２）と同様
（５）主−・−ポリエステル（東洋鋳型、バイロン２０
０ １００部
硬−・−（２）と同様 ２０部
（６）主・−＋５＋と同様 １００
部硬−・チタンキレート剤（日本曹達型、チタボンド５
０ ５〜１０部
（７）主−・−（５）と同様 １０
０部硬−・−・有機チタン化合物（日本曹達型、Ａ−１
０１０部
（８）主−・・−（５）と同様
１００部硬−・・−有機チタン化合物（日本曹達型、Ｂ
−１０１０部
＋９１ 主・・・−・酢酸セルロース（パーキュレス製
、Ｌ２０） １００部硬−・・−チ
タンキレート剤（日本曹達型、チタボンド５０（＋６＋
と同様） ５部００主・・・−（９）と同
様 １００部硬−・ポリイソシアネ
ート （大日本インキ製、バーノックＤ−７５０）
１０部αＤ主−ニトロセルロース（ダイセル製
、ニドセロ５Ｓ７４） ２０〜５０部硬−
・−αのと同様 ５０〜２０部（２）主
−・−塩化ゴム（旭電化、ＣＲ−１０）１００部
硬−ａＯＩと同様 ３０部α１
主−・・−αりと同様 １００部
硬−・−有機チタン化合物（日本曹達製、Ｂ−１０（＋
８１と同様） １０部０４１主−メラミ
ン（日立化成製、メラミン４５）１００部
！−−−−−パラトルエンスルホン酸 ２０１上
記の組み合わせのうちアクリルポリオールを使用したも
のが、耐熱性、耐汚染性の点で好ましい。
耐熱層には、上記の熱硬化性樹脂と硬化剤の他、加工適
性向上、巻取のブロッキング防止のため、体質顔料の添
加が好ましいことがある。
この目的に合う体ＭＨ料の例は、炭酸マグネシウム、シ
リカ、クレー、酸化チタン、および酸化亜鉛である。配
合量は、通常は、重量基準で樹脂の５〜４０％が適当で
ある。添加混合は、３本ロールミルもしくはサンドミル
を使用して充分な分散を図るのがよい。
土旦亘立１
この発明の感熱転写層は基本的には以上のような構造を
有しているが、以下のような付加的な処理を行なうこと
もできる。
まず、感熱転写層と基体シートの間、基体シートと耐熱
スリップ層の間、もしくは基体シートと耐熱層との間に
は、各層の接着力を向上させる目的でブライマー層を設
けてもよい、フ゛チイマー層の材料としては既知のもの
を使用することができ、例えば、アクリル系樹脂、ポリ
エステル樹脂、ポリオールとジイソシアネートなどのプ
ライマー、層を用いれば、基体シートとしてポリエステ
ルフィルムを使用したときに、特に接着性が向上する。
〔作用・効果〕
この発明においては、以上に説明したように（ａ）〜（
ｃ）の３成分からなる塗工材料が塗布され、硬化した耐
熱スリップ層を有しているので、サーマルヘッド上を走
行する際にスティンキングを生じることがなく、サーマ
ルヘッドへの滓の付着がない上、円滑な走行が可能にな
る。
１隻皇土
（感熱昇華転写シート）
ベースフィルムとして厚み６μｍのポリエステルフィル
ム（東し製、ルミラー）の片面に、下記の組成からなる
耐熱スリツプ層形成用インキ組成物をワイヤーバー＃６
を用いて塗布し、塗膜を温風乾燥させた後、窒素ガス雰
囲気下で１７５ＫＶに加速された電子線を５ Ｍｒａｄ
照射し、塗膜を硬化させた。
耐熱スリノブ層形成用インキ、３ＬＦＩＩステアリル基
含有ジアクリレー）−ｍ−−７０部（東亜合成製、アロ
二ノクスＭ−２３３）ポリメタクリル酸メチル樹脂−・
−−−−ｍ−・−・−−３０部（住友化学製、スミペッ
クスＭＨＯ）
リン酸エステル・−一一一一・・−−−−−一−−−−
−−−・・−・−−−−一一−ｉ部（第−工業製薬製、
ブライサーフ２０８ Ｓ）トルエンー−−−−一−−−
−−−−−−−−−−−−−−−一・・−−−−−一−
−−−−−−−−−４００部別に下記の組成の感熱昇華
転写層形成用インキ組成物を調製し、ベースフィルムの
耐熱スリップ層を設けたのとは反対の面に、ワイヤーバ
ー＃１０を用いて塗布し、塗膜を温風乾燥させ、約１．
２ｇ／ｒｒｔの転写層を形成して、感熱昇華転写シート
を得た。
１ユ選ユ１Ｊ」形成用インキ組成物
分散染料−・−＝−−−一−−−−・−・−−一−−−
−−・−＝−・−・・−・・・−−−−一−−・−・−
・−−−４部（日本化薬製、カヤセットブルーフ１４）
ポリビニルブチラール樹脂−一−−−−−−−−−−−
−・−−４，３部（積木化学製、エスレックＢＸ−１）
トルエン−・−・−・・・・−・−・−・・−・・・・
−−一−−・・−・−・・−−−一一一−・−ｍ−−−
・４０部メチルエチルケトン・・−・−・−・−・−・
−・−一一−−−−−・・−一−−−−−・−・４０部
イソブタノール−・・・・−・−・−・・・−・−・−
−ｍ−−−・〜・−・−・−・・・・−・−・−・１０
部（受像シート）
ヘースシートとして厚み１５０μｍの合成紙（玉子油化
製、ユボＦＰＧ１５０）を用い、下記の組成の受像層形
成用インキ組成物をワイヤーバー＃３６を用いて塗布し
、乾燥して、乾燥時の塗布量が４．ｏｇ／ｒｒｒの受像
層を存する受像シートを得た。
像 形成用インキ組 物
ポリエステル樹脂−・−・・・−・・−一−−−−・・
・−・−・・−・・−・−−一−−−・・−８部（東洋
鋳型、バイロン１０３）
ＥＶＡ系高分子可塑剤−−−−−−・・−−−−−・・
−・−・・・−・−・−・・２部（三井ポリケミカル製
、エルバロイ ７４１Ｐ）アミノ変性シリコーンオイル
・−・・・・０．１２５ 部（イ３越シリコーン製、Ｋ
Ｆ−３９３）エポキシ変性シリコーンオイル−０，１２
５部（信越シリコーン製、Ｘ−２２−３４３）トルエン
−・−・−−−−−一・・−一−−−−−・−・−・−
−−−−−−ｍ−−７０部メチルエチルケトンーーーー
ーーーー−−・・−−一−−−・−・・−・−−−１０
部シクロヘキサノン−−一一一−−・−−−−−−一−
−−−−・−−−一−−−−−−−−−−２０部上記の
ようにして得られた感熱昇華転写シートと受像シートと
を感熱転写層と受像層とが接するようにして重ね、耐熱
スリップ層からサーマルヘッドにより記録を行なった。
記録条件は出力＝】Ｗ／ドツト、 パルス中＝０．３〜
４．５ｍ５ｅｃ 、 ドツト密度＝３ドツト／ｍｍで
ある。
この記録により、スティッキング現象は全く発生せず、
シワの発生もなく、感熱昇華転写シートはスムースに走
行した。印字濃度を反射濃度計（マクベス濃度計ＲＤ
−９１，８） で測定したところ、パルス中４．５ ｍ
５ｅｃの高濃度発色部分の反射ン二度が１．６５であり
、またパルス中０．３ｍ５ｅＣの部分が０．１６と、印
可エネルギーに応じたＩｔ諸二周のある記録が得ら才し
た。
濱ｊし侃」−（耐熱層）
下記組成の耐熱層形成用インキｔＵ成物を準備し、ヘー
スフィルムの片面に、ワイヤーバー＃６を用いて塗布し
た後、温風乾燥させて、耐熱層を形成し、耐熱層上に下
記組成の耐熱スリツプ層形成用インキ組成物をワイヤー
バー＃６を用いて、塗布し、温風乾燥させた後に、１６
５ＫＶじ加速された電子線を窒素雰囲気中で５ Ｍｒａ
ｄ照射して硬化させて、耐熱スリップ層を形成した以外
は、実施例１と同様にした。
釘さ、形成用インキ組成物
アクリルポリオール・−・・・−・−・−・・−・−一
−−−−・・−１５，３部トルエン−−一−−−−−−
−−−−−−−−−−−−−−−・・・・・・・・・−
・・・・・・・・・・・・−・・・−・−４０部メチル
エチルケトン−・・・・・・・−・・・・・−・・・・
・・−・−・−−ｍ＝−−・−・４０ｍジイソシアネー
トーーーーー−−一−・−・−・−・−・−・−・−・
−・−４，７部耐熱スリップ層形成用インキ組成１穎
ステアリル基含有ジアクリレート−・−・−・〜６０部
（東亜合成製、アロニックスＭ−２３３）ポリメタクリ
ル酸メチルｅｌ ＩＢＭ−・・−・−・・・−・−４０
部（住人化学製、スミペックスＭ ＨＯ）リン酸エステ
ルー−−−−−−−−−−−・−−−−一・−・−・・
・・・−・・・・・・・・−・・・・−・−１０部（第
−工業製薬層、プライサーフ２０８ Ｓ）記録の条件は
、出カニ １．５ ｘ １０−３Ｊ／ドツト、パルス巾
： ０．３〜７ ｍ５ｅｃ、ドツト密度：５ドツト／ｍ
ｍで行なった。
この記録においても、スティッキング現象、シワの発生
は全くなく、感熱昇華転写シートはスムースに走行し、
−・夕部分もザラっきがない良好な印字ができた。
去上皇１
（感熱溶融転写シートの作成）
２．６−トルエンジイソシアネート、およびエチルセロ
ソルブを、それぞれの分子中に含まれる −ＮＣ○ と
−ＯＨとのモル比が、１：１になるような割合で混合
し、触媒としてラウリン酸ジブチルスズを混合物の０．
０１４に、Ｎ％投入し、温度を１００°Ｃに保ちつつ、
５時間連続攪拌して、熱溶融性物質へを得た。
この熱溶融性物質Ａを用い、下記の組成の感熱溶融転写
層用組成物を調製し、実鉋例１にｌｉｅって耐熱層を形
成した厚み６μｍのポリエチレンテレフタレートフィル
ムの反対面上に、フィルムを１７０℃に加熱しつつワイ
ヤーバーコーティングにより２μｍの厚みに塗布して、
感熱用転写シートを得た。
恣熱溶融転写コ１」ｌＪＬ屋−惣一
熱溶融性物質Ａ−−−−−−−・−・−・−・・・−・
・−・・・−・・・・・−・−・・・−・−・・・−５
０部トルエンーーーー・・・・・−・−・−・・−・−
・−−−−−−・−・−・−・・−・−・−・・・・・
−・−・・・・・・−３６部カーボンブラック−・−−
−一一−−−−−−−・・−・・・−・−・・・−・−
・・−・−・・・−１０部柔軟性付与剤−一−−−−−
−−−−−−−−−−−−−・−・−・・・−・−・・
・・・・・・・・・・−・−・・・−・−２部（出光面
油製、Ｃ５−５５）
ポリエチレングリコールーーー−−−・・・−・・・・
・・・・・・・・−・・・・・・・−２部（平均分子量
：４０００）
得られた感軌溶融転写シートと、坪量５０ｇ／Ｍの上質
紙とを重ねて、サーマルプリンター（神鋼電機製、５Ｐ
−３０８０）を用いて印字したところ、スティッキング
が発生することなく、上質紙面に黒色のシャープな印字
画像が得られた。
ｍ（耐熱スリップ層の効果）
実施例３と同様に、ただし、耐熱スリップ層の塗布工程
を省いて感熱溶融転写シートを作成し、同様に印字した
ところ、ポリエステルフィルムがサーマルヘッドに融着
して走行不能であった。
、比」交９１１２ （ｔａ＋成分の配合量）実施例１と
同様に、ただし、耐熱スリツプ層形成用インキ組成物と
して下記のものを用いて感熱転写シートを得た。
耐熱スリップ１長羞用インキ組成す
ステアリル基含有ジアクリレート−−−８０部（東亜合
成製、アロニソクスＭ −２３３）ポリメタクリル酸メ
チル樹脂−・−２０部（住人化学製、スミペックスＭ
ＨＯ）リン酸エステル−・−一−−−−−−−−−−・
−−−−−１部（第−工業製薬層、プライサーフ２０８
Ｓ）トルエン・−一一一一一−−・−−−−−−−一
一−−−−−−−−−−−−・４００部実施例１と同様
にして印字したところ、スティッキング現象は発生しな
かったが、ヘッド滓が発生した。
比較例３Ｎａｌ成分の配合量）
実施例１と同様に、ただし、耐熱スリツプ層形成用イン
キ組成物として下記のものを用いて感熱転写シートを得
た。
且公込ユユゴｊ形成 インキ組成
ステアリル凸含有ジアクリレート・−・・−・４０部（
東亜合成型、アロニックスＭ−２３３）ポリメタクリル
酸メチル樹脂−・−・−・・・・・・−６０部（住人化
学製、スミペックスＭＨＯ）
リン酸エステルー−−−一−・・・・・・−・−・・−
・−−−−−・−・−・・−・・−・−・・・・−１部
（第−工業製薬型、プライサーフ２０８ Ｓ）トルエン
ー−一一−−−−−−−−・・・−・−−一−−−−−
・・・−・・−・−・−・・・−・・・・４００部実施
例１と同様にして印字したところ、スティッキングが起
こり、フィルムが破断した。[The dye contained in the heat-sensitive sublimation transfer layer is preferably a disperse dye, and usually has a molecular weight of about 150 to 400. The binder contained in the heat-sensitive sublimation transfer layer has high heat resistance and does not hinder dye transfer when heated, and is, for example, as follows: As a cellulose resin, ethyl cellulose, hydroxyethyl cellulose , hydroxypropyl cellulose,
Methylcellulose, cellulose acetate, cellulose acetate butyrate, etc. Vinyl resins include polyvinyl alcohol, polyvinyl acetate, polyvinyl butyral, polyvinylpyrrolidone, polyester, polyacrylamide, etc. To form a heat-sensitive sublimation transfer layer on a base sheet, is it necessary to use a binder as a carrier? The ink may be prepared by dissolving the ink, preferably by dissolving the dye, and forming a film using an appropriate coating or printing method. The coloring agent contained in the heat-sensitive melting transfer layer is an RfR material, an inorganic pigment, or a dye. Wax is often used as the binder contained in the heat-sensitive melt transfer layer. Microcrystalline wax, carnauba wax, and paraffin wax are often used as waxes, but other waxes include Fischer Tropn's wax,
Various low molecular weight polyethylenes and some modified waxes,
These include fatty acid esters, fatty acid amides, wood wax, beeswax, spermaceti wax, wart wax, wool wax, shellac, candelilla wax, and petrolactam. In addition, resins may also be used. In order to form the heat-sensitive melt transfer layer on the substrate sort, it is preferable to melt and knead the colorant and binder and apply hot-melt coating, but it can also be done by using other conventional printing and coating methods. The heat-resistant slip layer is formed by applying a coating material containing the following ingredients (+al to fc) on the opposite side of the base sheet from the heat-sensitive transfer layer and curing it. . The component of fat is a single substance having a linear hydrocarbon group having 12 or more carbon atoms and a radically polymerizable unsaturated group, and since it has a linear hydrocarbon group having 12 or more carbon atoms, it is a heat-resistant slip In addition to being able to impart lubricity to the surface of the layer, the radically polymerizable unsaturated groups are crosslinked and cured by irradiation with ionizing radiation. Specifically, (as a component of al, the following can be mentioned; Cetyl acrylate (meth), stearyl (meth) acrylate, myristyl (meth) acrylate, pentadecyl (meth) acrylate, nonadene (meth) acrylate, eicosyl (meth) acrylate, oleyl (meth) acrylate, (meth) acrylate ) elaidyl acrylate, suruyl (meth)acrylate, sulunyl (meth)acrylate, hehenyl (meth)acrylate.In addition, some of the hydroxyl groups of polyhydric alcohols such as trimethylolpropane and pentaerythritol, A compound obtained by esterifying with acrylic acid or methacrylic acid and esterifying the remaining hydroxyl group with a higher fatty acid having 12 or more carbon atoms can also be used as a fat component. If it is less than 50% by weight, the slipperiness will not be sufficient, and if it exceeds 70% by weight, the film strength will be reduced. , acrylic resin, polyester resin, or polyurethane resin. Examples of commercially available products include acrylic resins such as Dianar manufactured by Mitsubishi Rayon N and Barapet manufactured by Kyowa Gas Chemical ■, and polyester resins manufactured by Toyobo ■. Byron, manufactured by Narita Pharmaceutical Co., Ltd., and Takenate, manufactured by Narita Pharmaceutical Co., Ltd. Among the above-mentioned polymers, acrylic resins, particularly polymethyl methacrylate resins, have high heat resistance and are advantageous in that they can prevent dyeing due to transfer of dye to the heat-resistant slip layer when the heat-sensitive transfer layer is of a sublimation type. In addition, by introducing an acrylic group into the terminal or side chain of the above polymer, it is possible to improve the ionizing radiation irradiation effect and improve the heat resistance by increasing the reactivity with the (al) component. The bl component is preferably used at 30 to 50% by weight in the coating material; if it is less than 30% by weight, the film strength will not be sufficient, and if it exceeds 50% by weight, the proportion of the fat component will be relatively low. As a result, sticking becomes more likely to occur. (Component C1 gives the heat-resistant slip layer lubricity and releasability from the head, and is a phosphoric acid ester of the following formula (r) or a phosphoric acid ester. is an alkali metal salt (or an alkaline earth metal salt of a phosphoric acid ester). In the case of a phosphoric acid ester, in formula (1), one side of AlB is hydrogen and the other side is R(CHz CHt O)-. , in the case of an alkali metal salt of a phosphoric acid ester (or an alkaline earth metal salt of a phosphoric acid ester), A and B in formula (r) are H and an alkali metal (or an alkaline earth metal). As the alkali metal salt or alkaline earth metal salt of phosphoric acid ester, GAFA CRD720 is used.Alkali metal As the salt (or alkaline earth metal salt of phosphoric ester), sodium salt is preferred. Phosphoric ester and alkali metal salt of phosphoric ester (
or an alkaline earth metal salt of phosphoric acid ester) may be used in combination. This component (C1) is used in the coating material at a ratio of 1 to 20% by weight, but a particularly good range is 1 to 10% by weight. If it is not sufficient, and if it exceeds 20%, blocking occurs when it is wound up, and furthermore, if the heat-sensitive transfer layer is a sublimation type, the dye tends to transfer to the heat-resistant slip layer, which is undesirable. In addition to the above ingredients (a) to (c), in order to prevent blocking on one side of the rolled form, particulate substances such as il talc, silica, calcium carbonate, Teflon powder, silicone powder, etc. , silicone oil, stearamide, erucamide, etc. may also be added.Furthermore, as a storage stabilizer, hydroquinone, Hyde I]
A polymerization inhibitor such as quinone monomethyl ether can also be added to improve storage stability. When ultraviolet rays are used as the ionizing radiation, it is preferable to further add an ultraviolet sensitizer such as benzo-yne, acetophenone, or penduphenone. Can each of the above components be dissolved in a solvent, etc.? b
Mix it to make coating material t4, apply it or print it,
For example, roll coating, gravure coating,
By screen coating, fountain: 1-ting, etc., the solid content is 0.1 to 5 g on the back of the base sheet.
/d, more preferably 1 to 2 g/m (Ig/m corresponds to a coating thickness of 1 μm), and after evaporating the solvent, ionizing radiation is irradiated. As the ionizing radiation, electron beams, ultraviolet rays, gamma rays, etc. can be used. In the case of electron beams and gamma rays, the dose is about 1 to 20 Mrad. Here, if the thickness of the coating is less than 0.1 μm, the effect of the heat-resistant slip layer will not be sufficient, and if it exceeds 5 μm, heat transfer from the thermal head will be poor, leading to a decrease in print density. Note that either the heat-resistant slip layer or the heat-sensitive transfer layer may be provided first. Although the objective of the present invention can be achieved by providing a heat-resistant slip layer, in some cases, depending on the tension applied to the thermal transfer sheet or the printing pressure of the thermal head when conveying it inside a thermal printer, etc. Problems may occur in feeding the thermal transfer sheet. In such a case, it is desirable to provide a heat-resistant layer made of fat between the heat-resistant slip layer and the base sheet, where the thermosetting resin and the curing agent react and harden. Typical combinations of curing agents include polyvinyl butyral and polyvalent isocyanates, acrylic polyols and polyvalent isocyanates, cellulose acetate and titanium chelating agents, and polyesters and organic titanium compounds. The product names and compounding ratios of products available on the market are shown in the following formulation examples.In the following description, ``main'' refers to the thermosetting resin, and ``hard rubber'' refers to the curing agent. ■ (1) Main - Polyvinyl butyral (Made by Block Chemical,
Esresoku BX-1100 parts hard diisocyanate (Takenate D, manufactured by Shikinichi Yakuhin)
IION 4
5 parts (2) Main urethane polyol (manufactured by Dairomoto Ink, DF30-55) 100 parts hard...
・Polyisocyanate (Dainippon Ink, parts, resin D-750) 20 parts (3) Main: Urethane polyol (Dainippon Ink, DF30-55) with C
Added 1% o 100 parts Hardness... Same as (2) +41 Main - Acrylic polyol (manufactured by Dainichi Ink, Acrylic Deck A-801P Hardness... - Same as (2) (5) Main - - Polyester (Toyo Mold, Byron 20
0 100 parts Hard - Same as - (2) 20 parts (6) Main - Same as 5+ 100
Part hardness: Titanium chelating agent (Nippon Soda type, Titabond 5
0 5-10 parts (7) Main - - Same as (5) 10
0 parts hard --- Organic titanium compound (Nippon Soda type, A-1
010 part (8) Main --- Same as (5)
100 parts hard --- organic titanium compound (Nippon Soda type, B
-1010 parts +91 Main cellulose acetate (manufactured by Percules, L20) 100 parts hard titanium chelating agent (Nippon Soda type, Titabond 50 (+6+
) 5 parts 00 main... - Same as (9) 100 parts hard polyisocyanate (Dainippon Ink, Burnock D-750)
10 parts αD main - Nitrocellulose (manufactured by Daicel, Nidocello 5S74) 20-50 parts Hard -
- Same as α 50 to 20 parts (2) Main - Chlorinated rubber (Asahi Denka, CR-10) 100 parts Hard - Same as aOI 30 parts α1
Main - Same as α - 100 parts Hard - Organic titanium compound (manufactured by Nippon Soda, B-10 (+
Same as 81) 10 parts 041 Main - Melamine (manufactured by Hitachi Chemical, Melamine 45) 100 parts! ----Para-toluenesulfonic acid 201 Among the above combinations, those using acrylic polyols are preferred in terms of heat resistance and stain resistance. In addition to the above-mentioned thermosetting resin and curing agent, it may be preferable to add an extender pigment to the heat-resistant layer in order to improve processability and prevent blocking during winding. Examples of body MH materials suitable for this purpose are magnesium carbonate, silica, clay, titanium oxide, and zinc oxide. The appropriate amount is usually 5 to 40% of the resin based on weight. For addition and mixing, it is preferable to use a three-roll mill or a sand mill to achieve sufficient dispersion. Wataru Dotan 1 The heat-sensitive transfer layer of the present invention basically has the structure as described above, but additional treatments such as those described below can also be performed. First, a brimer layer may be provided between the heat-sensitive transfer layer and the base sheet, between the base sheet and the heat-resistant slip layer, or between the base sheet and the heat-resistant layer in order to improve the adhesive strength of each layer. Known materials for the layer can be used, such as acrylic resins, polyester resins, primers such as polyols and diisocyanates, etc. If a layer is used, particularly adhesive properties can be obtained when a polyester film is used as the base sheet. will improve. [Action/Effect] In this invention, as explained above, (a) to (
Since the coating material consisting of the three components c) is applied and has a hardened heat-resistant slip layer, stinking does not occur when running on the thermal head, and slag does not adhere to the thermal head. In addition to this, smooth running is possible. 1 Kodo (Heat-sensitive sublimation transfer sheet) As a base film, a heat-resistant slip layer forming ink composition having the following composition was applied to one side of a 6 μm thick polyester film (Toshi Co., Ltd., Lumirror) wire bar #6
After drying the coating film with hot air, an electron beam accelerated to 175 KV was applied to the film under a nitrogen gas atmosphere for 5 Mrad.
The coating was cured by irradiation. Heat-resistant Slinobu layer forming ink, 3LFII stearyl group-containing diacrylate)-m-70 parts (manufactured by Toagosei Co., Ltd., Aroninox M-233) polymethyl methacrylate resin-・
−−−−m−・−・−−30 parts (manufactured by Sumitomo Chemical, Sumipex MHO) Phosphoric acid ester・−1111・−−−−−1−−−
---・・-・----Part 11-i (manufactured by Dai-ichi Kogyo Seiyaku Co., Ltd.,
Blysurf 208 S) Toluene----1---
−−−−−−−−−−−−−−−1・・−−−−−1−
----------Prepare 400 copies of an ink composition for forming a heat-sensitive sublimation transfer layer with the following composition, and apply wire bar #10 on the opposite side of the base film from which the heat-resistant slip layer was provided. The coating film was dried with warm air, and the coating was dried for about 1.
A transfer layer of 2 g/rrt was formed to obtain a heat-sensitive sublimation transfer sheet. Ink composition for forming 1U selection 1J" Disperse dye - - - = - - - - - - - - - - - -
−−・−＝−・−・・−・−−−−1−−・−・−
・---4 parts (Nippon Kayaku, Kayaset Blue 14)
Polyvinyl butyral resin -1
−・−−4,3 parts (Made by Block Chemical, S-LEC BX-1) Toluene−・−・−・・−・−・−・・−・・
−−１−−・・−・−・・−−−１１１−・−m−−−
・40 parts methyl ethyl ketone・・−・−・−・−・−・
−・−11−−−−−・・−1−−−−−・−・40 parts isobutanol−・−・−・−・−・−・−・−
−m−−−・〜・−・−・−・・・・−・−・−・10
(Image-receiving sheet) A 150-μm-thick synthetic paper (Yubo FPG150, Tamago Yuka Co., Ltd.) was used as a base sheet, and an ink composition for forming an image-receiving layer having the following composition was applied using a wire bar #36, and dried. , the coating amount when dry is 4. An image receiving sheet having an image receiving layer of og/rrr was obtained. Ink composition for image formation polyester resin -------------
・−・−・・−・・−・−−1−−−・・−8 parts (Toyo Mold, Byron 103) EVA polymer plasticizer−−−−−−・・−−−−−・・
-・-・・・・・2 parts (Mitsui Polychemical Co., Ltd., Elvaloy 741P) Amino modified silicone oil・・・・0.125 parts (Mitsui Polychemical Co., Ltd., K
F-393) Epoxy modified silicone oil-0,12
5 parts (manufactured by Shin-Etsu Silicone, X-22-343) Toluene-・-・−−−−−1・・−1−−−−−・−・−・−
-------m--70 parts Methyl ethyl ketone ---------1-------------10
Part cyclohexanone--111--・-----1-
------・---1-------20 copies of the heat-sensitive sublimation transfer sheet and image-receiving sheet obtained as above were placed in such a way that the heat-sensitive transfer layer and the image-receiving layer were in contact with each other. The sheets were stacked one on top of the other, and recording was performed using a thermal head from the heat-resistant slip layer. The recording conditions are output = W/dot, pulsed = 0.3~
4.5 m5ec, dot density = 3 dots/mm. With this recording, no sticking phenomenon occurred at all,
There were no wrinkles and the heat-sensitive sublimation transfer sheet ran smoothly. Print density is reflected by a densitometer (Macbeth densitometer RD)
-91,8) was measured at 4.5 m during the pulse.
The reflection n° of the 5ec high-density colored part was 1.65, and the 0.3m5eC part during the pulse was 0.16, making it possible to obtain a record of two cycles of It depending on the applied energy. ``Hamaj Shinan'' - (Heat-resistant layer) Prepare an ink tU composition for forming a heat-resistant layer with the following composition, apply it to one side of a heat-resistant film using a wire bar #6, and then dry it with warm air to form a heat-resistant layer. After forming a layer and applying an ink composition for forming a heat-resistant slip layer having the following composition on the heat-resistant layer using a wire bar #6 and drying with hot air,
An electron beam accelerated by 5 KV is heated to 5 Mra in a nitrogen atmosphere.
The same procedure as in Example 1 was carried out except that a heat-resistant slip layer was formed by curing by irradiation. Ink composition for forming nails, acrylic polyol --------------1------15,3 parts toluene--1--
−−−−−−−−−−−−−−−・・・・・・・・・・−
・・・・・・・・・・・・−・・・・−・−40 parts Methyl ethyl ketone−・・・・・・・−・・・・・・−・・
・・−・−・−−m=−−・−・40m diisocyanate---1−・−・−・−・−・−・−・−・
-・-4,7 parts Ink composition for forming heat-resistant slip layer 1 Stearyl group-containing diacrylate-・-・-・～60 parts (manufactured by Toagosei Co., Ltd., Aronix M-233) Polymethyl methacrylate el IBM-・・-・−・・・−・−40
(manufactured by Sumitomo Chemical, Sumipex M HO) Phosphoric acid ester ---
・・・－・・・・・・・・・・・・－・・・・−・・10 parts (No. 1 industrial pharmaceutical layer, Price Surf 208 S) Recording conditions are: 1.5 x 10-3 J/dot , pulse width: 0.3 to 7 m5ec, dot density: 5 dots/m
I did it with m. Even in this recording, there was no sticking phenomenon or wrinkles, and the heat-sensitive sublimation transfer sheet ran smoothly.
−・Good printing with no roughness was achieved even in the evening part. Former Emperor 1 (Preparation of heat-sensitive melt transfer sheet) 2. 6-Toluene diisocyanate and ethyl cellosolve are mixed in such a ratio that the molar ratio of -NC○ and -OH contained in each molecule is 1:1. and dibutyltin laurate as a catalyst at 0.0% of the mixture.
Add N% to 014 and maintain the temperature at 100°C.
After continuous stirring for 5 hours, a heat-fusible substance was obtained. Using this heat-melting substance A, a composition for a heat-sensitive melting transfer layer having the following composition was prepared, and the film was placed on the opposite side of a 6 μm thick polyethylene terephthalate film on which a heat-resistant layer was formed by following the method of Example 1. was applied to a thickness of 2 μm using wire bar coating while heating to 170°C.
A heat-sensitive transfer sheet was obtained. Arbitrary heat-melting transfer 1" lJL-ya - Soichi heat-melting substance A
・−・−・・・−・−・・−・−・・5
0 parts toluene・・・・・・−・−・−・・−・−
・−−−−−−・−・−・−・・−・−・−・・・・・
−・−・・・・・・−36 parts carbon black−・−−
−11−−−−−−−・・−・−・−・−・−
・・・・・・・−10 parts Softening agent-1
−−−−−−−−−−−−−・−・−・−・−・・
・・・・・・・・・・-・−・・−・−2 parts (manufactured by Idemitsu Menu Oil Co., Ltd., C5-55) Polyethylene glycol
......-2 parts (average molecular weight: 4000) The obtained track-sensitive melt transfer sheet and high-quality paper with a basis weight of 50 g/M were stacked together to form a thermal printer. (Manufactured by Shinko Electric, 5P
-3080), a sharp black printed image was obtained on the high-quality paper surface without any sticking. m (Effect of heat-resistant slip layer) A heat-sensitive melt transfer sheet was prepared in the same manner as in Example 3, but omitting the step of applying the heat-resistant slip layer, and when printing was performed in the same manner, the polyester film was fused to the thermal head. It was impossible to drive. , Comparison 9112 (Amount of ta+ component) A heat-sensitive transfer sheet was obtained in the same manner as in Example 1, except that the following ink composition for forming a heat-resistant slip layer was used. Heat-resistant slip 1 Long photo ink composition Stearyl group-containing diacrylate ---80 parts (Toagosei Co., Ltd., Alonisox M-233) Polymethyl methacrylate resin ---20 parts (Sumiman Chemical Co., Ltd., Sumipex M
HO) Phosphate ester-・--
------ Part 1 (No. Industrial Pharmaceutical Layer, Pricesurf 208
S) Toluene -11111---11-------400 copies were printed in the same manner as in Example 1, and a sticking phenomenon was observed. Although this did not occur, head scum did occur. Comparative Example 3 Amount of Nal Component) A heat-sensitive transfer sheet was obtained in the same manner as in Example 1, except that the following ink composition for forming a heat-resistant slip layer was used. Formation of Kogome Yuyugoj Ink composition Stearyl convex-containing diacrylate --- 40 parts (
Toagosei type, Aronix M-233) Polymethyl methacrylate resin - 60 parts (Sumipex MHO, Sumitomo Chemical Co., Ltd.) Phosphate ester - - - - −・−・・−
・−−−−−・−・−・・−・・−・−・・・・・1 part (No. 1 Kogyo Seiyaku type, Price Surf 208 S) Toluene-11−−−−−−−・・・−・−−１−−−−−
400 copies were printed in the same manner as in Example 1, but sticking occurred and the film was broken.
Claims (5)
り、他方の面には、下記の（ａ）〜（ｃ）の各成分から
なる塗工材料の電離放射線照射による硬化塗膜からなる
耐熱スリップ層を有することを特徴とする感熱転写シー
ト。 （ａ）炭素数１２以上の直鎖炭化水素基とラジカル重合
性不飽和基とを有する単量体 ５０〜７０重量％ （ｂ）ポリマー３０〜５０重量％ （ｃ）リン酸エステルまたはリン酸エステルのアルカリ
金属塩もしくはアルカリ土類金 属塩１〜２０重量％(1) One side of the base sheet has a heat-sensitive transfer layer, and the other side is coated with a coating material made of the following components (a) to (c) cured by irradiation with ionizing radiation. A heat-sensitive transfer sheet characterized by having a heat-resistant slip layer consisting of a film. (a) 50 to 70% by weight of a monomer having a linear hydrocarbon group having 12 or more carbon atoms and a radically polymerizable unsaturated group (b) 30 to 50% by weight of a polymer (c) Phosphoric ester or phosphoric ester 1 to 20% by weight of an alkali metal salt or alkaline earth metal salt of
成樹脂が硬化剤の作用で硬化した硬化樹脂からなる耐熱
層を有することを特徴とする特許請求の範囲第１項記載
の感熱転写シート。(2) Thermal transfer according to claim 1, characterized in that there is a heat-resistant layer made of a cured resin in which a thermosetting synthetic resin is cured by the action of a curing agent between the base sheet and the heat-resistant slip layer. sheet.
アネートとが硬化した硬化樹脂からなることを特徴とす
る特許請求の範囲第１項記載の感熱転写シート。(3) The heat-sensitive transfer sheet according to claim 1, wherein the heat-resistant layer is made of a cured resin obtained by curing an acrylic polyol resin and a polyvalent isocyanate.
樹脂からなる感熱昇華転写層である特許請求の範囲第１
項〜第３項いずれか記載の感熱転写シート。(4) Claim 1, wherein the heat-sensitive transfer layer is a heat-sensitive sublimation transfer layer comprising a heat-transferable dye and a binder resin.
The heat-sensitive transfer sheet according to any one of Items 1 to 3.
、ワックスからなる感熱溶融転写層である特許請求の範
囲第１項〜第３項いずれか記載の感熱転写シート。(5) The heat-sensitive transfer sheet according to any one of claims 1 to 3, wherein the heat-sensitive transfer layer is a heat-sensitive melting transfer layer comprising a dye or pigment colorant and wax.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP61193480A JP2609850B2 (en) | 1986-08-19 | 1986-08-19 | Thermal transfer sheet |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP61193480A JP2609850B2 (en) | 1986-08-19 | 1986-08-19 | Thermal transfer sheet |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS6349484A true JPS6349484A (en) | 1988-03-02 |
| JP2609850B2 JP2609850B2 (en) | 1997-05-14 |
Family
ID=16308725
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP61193480A Expired - Lifetime JP2609850B2 (en) | 1986-08-19 | 1986-08-19 | Thermal transfer sheet |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP2609850B2 (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2016203433A (en) * | 2015-04-17 | 2016-12-08 | 大日本印刷株式会社 | Thermal transfer sheet |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS59196291A (en) * | 1983-04-21 | 1984-11-07 | Matsushita Electric Ind Co Ltd | Transfer body for heat sensitive recording |
| JPS60259495A (en) * | 1984-02-10 | 1985-12-21 | Canon Inc | Thermal transfer material |
-
1986
- 1986-08-19 JP JP61193480A patent/JP2609850B2/en not_active Expired - Lifetime
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS59196291A (en) * | 1983-04-21 | 1984-11-07 | Matsushita Electric Ind Co Ltd | Transfer body for heat sensitive recording |
| JPS60259495A (en) * | 1984-02-10 | 1985-12-21 | Canon Inc | Thermal transfer material |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2016203433A (en) * | 2015-04-17 | 2016-12-08 | 大日本印刷株式会社 | Thermal transfer sheet |
Also Published As
| Publication number | Publication date |
|---|---|
| JP2609850B2 (en) | 1997-05-14 |
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