JPS6343933A - Directly applicable, plant protecting sheet - Google Patents

Directly applicable, plant protecting sheet

Info

Publication number
JPS6343933A
JPS6343933A JP18884486A JP18884486A JPS6343933A JP S6343933 A JPS6343933 A JP S6343933A JP 18884486 A JP18884486 A JP 18884486A JP 18884486 A JP18884486 A JP 18884486A JP S6343933 A JPS6343933 A JP S6343933A
Authority
JP
Japan
Prior art keywords
film
plant
sheet
porous film
thickness
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP18884486A
Other languages
Japanese (ja)
Inventor
Tatsuo Yoshikawa
吉川 龍男
Akira Kato
彰 加藤
Takeshi Inoue
井上 猛司
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hagiwara Industries Inc
Original Assignee
Hagiwara Industries Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hagiwara Industries Inc filed Critical Hagiwara Industries Inc
Priority to JP18884486A priority Critical patent/JPS6343933A/en
Publication of JPS6343933A publication Critical patent/JPS6343933A/en
Pending legal-status Critical Current

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  • Prevention Of Fouling (AREA)
  • Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)

Abstract

PURPOSE:To obtain the title sheet which does not exert excessive contact pressure on a plant, is light and is excellent in flexibility, gas permeability, a covering effect and a protecting capability, by specifying its thickness, pore diameter and pore density. CONSTITUTION:A suitable pattern is formed on a polyolefin film by pressing, and this film is biaxially oriented while its thin parts are fibrillated to obtain a plant protecting film having a thickness of 0.001-0.2nm, a pore diameter of 0.1-5nm and regularly arranged pores in a pore density of 1-500pores/cm<2>.

Description

【発明の詳細な説明】 (イ)産業上の利用分野 本発明はいわゆるベタ掛けと称する、農作物などの植物
を直接被覆することにより、強風、冷気、高温、低湿、
雨滴、日照などに対して該I!物3保護するための新規
なシートに関する6本発明は被覆する植物にたいして過
大な接触圧を与えず、保温力が優れており、水分の透過
量が適当な大きさであり、優れた保護作用を有する。ま
た、本発明は軽量、安価であり、作業性が良い利点があ
る。
DETAILED DESCRIPTION OF THE INVENTION (a) Industrial Application Field The present invention is a method of directly covering plants such as agricultural products, which is called "beta-kake", to prevent strong winds, cold air, high temperatures, low humidity, etc.
Applicable to raindrops, sunlight, etc.! 3. Novel sheet for protecting objects 6. The present invention does not apply excessive contact pressure to the plants covered, has excellent heat retention ability, has an appropriate amount of moisture permeation, and has an excellent protective effect. have Further, the present invention has the advantage of being lightweight, inexpensive, and easy to work with.

(ロ)従来の技術 農作物などの植物を被覆して外気から遮断して育成する
ことは、古くがらガラス温室、ビニール温室、ビニール
 )・ンイ・ルなど透明を才T4に3よる比較的大きな
横遺物によるmiが多く用いられてきた。
(b) Conventional technology Growing crops and other plants by covering them and shielding them from the outside air has been traditionally done using transparent glass greenhouses, vinyl greenhouses, vinyl greenhouses, etc. mi based on relics has been often used.

これらの保、J[能は潰れているが、通気性および透水
性に乏しいため、高温III害を起こ丁ことがあり、寒
冷紗や不織布などによる′f11.覆が一部行われる。
These materials have been crushed, but due to poor air permeability and water permeability, high temperature damage may occur; Partial cover will be made.

また、ガラスや塩ビ フィルムとの併用ら行われる。し
がし大きな横遺物による被覆は植物の周辺の局部的な気
候条件の制O1lに対し十分でないことがあり、W物に
直接寒冷紗、不織布、フィルム等を被覆することが行b
 tLるようになってきている。
It is also used in combination with glass or PVC film. Covering with a large horizontal material may not be sufficient to control the local climate conditions around the plant, so it is recommended to directly cover the W material with cheesecloth, non-woven fabric, film, etc.
It's starting to become easier.

また、大きなfil遺物は高価で烏る)、乙、気象条件
によっては矯めて不利な情況に追い込まれることがある
。たとえば強風下では植7ζに直接寒冷紗や不織布を被
覆するほうが有効であろうん、安全性も潰れている。
Also, large artifacts are expensive and expensive), and depending on the weather conditions, you may be forced into a disadvantageous situation. For example, in strong winds, it would be more effective to directly cover the plant 7ζ with cheesecloth or non-woven fabric, but it would also be less safe.

一方では、大きな横遺物と必要としない、筒易な保温保
湿が要求されるようになってきた。多くの場合、農作物
の出荷時期を遅らせ、収)5前の品質低下と防止するこ
とが目的である。この場合、現在多く使用されている不
織布は重すぎるうえ、高価である欠点を有する。
On the other hand, there is a growing demand for heat and moisture retention that is easy to carry and does not require large side effects. In many cases, the purpose is to delay the shipping of agricultural products and prevent quality deterioration before harvest. In this case, the currently widely used nonwoven fabrics have the disadvantage of being too heavy and expensive.

このような問題を解決するため、不織布の軽重化の検討
が行われているが、概して不織布は目付けを軽くすると
急速に不均一化する傾向があるうえ、材料が少なくなる
わりには安価にならない七1u点があった。
In order to solve these problems, studies are being conducted to make nonwoven fabrics lighter and heavier, but in general, nonwoven fabrics tend to become uneven quickly when their basis weight is reduced, and they do not become cheaper even though fewer materials are used. There was a 1u point.

(ハ)発明が解決しようとする問題点 本発明は安価で柔軟性、通気性に富み、軽量で、植物に
対する被覆効果および保M能力の優れた、直接Mlする
N物保護シートである。
(c) Problems to be Solved by the Invention The present invention is an inexpensive, flexible, highly breathable, lightweight, direct Ml-containing nitrogen protection sheet that has excellent covering effects on plants and M retaining ability.

(ニ)問題点を解決するための手段 本発明は厚み0.001−輪ないし0.2−m、孔径0
.1論論ないし5−―、孔密度1ないし5000個/c
−2の実質的に規則正しく配列する孔を有するフィルム
を主な材料とする直接被覆する植物保護シートである。
(d) Means for solving the problems The present invention has a thickness of 0.001-0.2 m and a hole diameter of 0.
.. 1 to 5--, pore density 1 to 5000/c
This is a plant protection sheet for direct coating, which is mainly made of a film having 2 substantially regularly arranged holes.

フィルムの素材としてはどのようなものでも良いが、ポ
リオレフィンのように安価で製膜し易いものが好ましい
Although any material may be used for the film, it is preferable to use a material that is inexpensive and easy to form into a film, such as polyolefin.

本発明の直接F11覆する植物cA護レシートに用いら
れる多孔フィルムの邪悪は、その連続部におし)て通常
のフィルムであっても良いが、ρ■本かにフィブリル1
ヒしていることが好ましく、不規則な枝わかれや毛羽を
有していることが好ましい、孔の形状としては円形であ
っても良いが、多角形状あるいはさらに不規則な形のも
のであっても良い。
The problem with the perforated film used in the direct F11 covering plant cA receipt of the present invention is that it may be a regular film in its continuous portion, but
It is preferable that the pores are hollow, and preferably that they have irregular branches or fluff.The pores may be circular in shape, but polygonal or even more irregular in shape. Also good.

本発明において、直接被覆する植物C1,護シートに用
いられる多孔フィルムは、たとえばフィルムに適当なパ
ターンを型押ししたのち、二軸方向に延伸すると同時に
薄肉部分をフィブリル化させて製造する。型押しするパ
ターンはどのようなものでも良く、フィルムを突き抜け
て孔になっても良い。
In the present invention, the porous film used for the plant C1 to be directly covered and the protection sheet is manufactured by, for example, embossing a suitable pattern on the film, then stretching it in biaxial directions and at the same time fibrillating the thin portion. The pattern to be embossed may be of any type, and the pattern may be pierced through the film to form holes.

本発明において、直接被覆する植物保護シートに用いら
れる多孔フィルムの別の製法として、針、円筒形など種
々の形状の刃物、パルス状の放電、レーザー光などによ
ってフィルムに孔をあける方法がある。この場合、針や
刃物は加熱しておき、孔の周辺が盛り上がるように加工
することがフィルムの手触りを柔′らかくするので好ま
しい。
In the present invention, another method for manufacturing the porous film used in the plant protection sheet that is directly covered is a method in which holes are made in the film using a knife, a knife of various shapes such as a cylindrical shape, a pulsed electric discharge, a laser beam, etc. In this case, it is preferable to heat the needle or cutter and process it so that the area around the hole is raised, as this makes the film soft to the touch.

とくに孔の周辺がフィルムの片面の方に盛り上がったも
のが、とくに柔らかく好ましい、この方法において、孔
のできたフィルムをさらに延伸することも可能である。
In particular, a film in which the periphery of the holes is raised toward one side of the film is particularly soft and preferable.In this method, it is also possible to further stretch the film with holes.

本発明において、直接被覆する植物保護シートに用いら
れる多孔フィルムの必要枚数は保護すべき植物及び外気
の条件により一定せず、1枚であっても良いが、好まし
くは2枚以上、20枚以下、鰻も好ましくは3枚ないし
10枚である。また各多孔フィルムの間には若干の絡み
あい、接着。
In the present invention, the required number of porous films used in the plant protection sheet to be directly covered varies depending on the plants to be protected and the outside air conditions, and may be one, but preferably 2 or more and 20 or less. The number of pieces of eel is also preferably 3 to 10 pieces. Also, there is some entanglement and adhesion between each porous film.

ii着等を与えておくことが好ましい。It is preferable to give them ii clothing, etc.

本発明において、直接被覆する植?IJ保護シートに用
いられる多孔フィルムに対して、程々の繊維フリース、
種々の網状構造物、異種の多孔フィルム、発泡物、ある
いはこれらを重ね合わせたものをさらに重ね合わせて使
用することができる。
In the present invention, the plants to be directly covered with Compared to the porous film used for IJ protection sheets, a moderate amount of fiber fleece,
Various net-like structures, different types of porous films, foams, or layers of these may be further layered and used.

好ましくはこれらを接着、融着あるいは絡みあわせによ
り固着させて使用する。11ね合わせる枚数は2ないし
20枚、とくに3ないし10枚が好ましい。
Preferably, these are used by being fixed by adhesion, fusion, or entanglement. The number of sheets to be combined is preferably 2 to 20, particularly 3 to 10.

繊維フリースを重ね合わせたしのは、保温性に優れてお
り、とくにセルロース系繊維やビニロンを用いた場合放
射冷即に対し陵れた保護能力な示す、また繊維を立てた
ものは強風によっておこる脱水の防止効果が優れている
A sheet made of layered fiber fleece has excellent heat retention properties, and especially when cellulose fibers or vinylon are used, it has an excellent ability to protect against radiant cold. Excellent dehydration prevention effect.

繊維フリースとしてはカード上がりのウェブ、紡糸され
る繊維を直ちに捕ff1ffi積したウェブ、ランダム
ウェブなどが用いられる1m繊維フリースは熱接着性の
繊維を混合することが好ましい、熱接着性m&lにより
繊維フリース臼体の邪心の安定化が可能になるばかりで
なく、上ね3わせる池の層との固着にも利用可能となる
。繊維フリースとの接着には、別に接着剤を使用するこ
とも可能であり、多孔フィルムを加熱熔融させて接着す
ることも可能である。
As the fiber fleece, a carded web, a web in which the fibers to be spun are immediately collected, a random web, etc. are used.For the 1m fiber fleece, it is preferable to mix thermobondable fibers. Not only does it become possible to stabilize the evil core of the mortar, but it can also be used to secure it to the layer of pond that is placed on top. It is also possible to use a separate adhesive for adhesion to the fiber fleece, or it is also possible to adhere by heating and melting the porous film.

網状構造物としては繊維あるいはスプリットヤーンをた
てよこに並べてその交点?接着した物、熔融押出し時あ
るいはそれにひき続く過程での延仲等により網状に成型
した物、たとえば長手方向に実質的に平行に配列する第
一のポリマーからなる糸条列と、該ポリマーよりも低融
点のポリマーからなり、該糸条列を埋設する薄い枝及び
この技とほぼ直交する多数の別の糸条列からなる1lL
I状物である。
As a network structure, are fibers or split yarns arranged vertically and horizontally and their intersections? A bonded object, an object formed into a net shape by stretching or the like during melt extrusion or a subsequent process, for example, a thread array consisting of a first polymer arranged substantially parallel to the longitudinal direction, and 1L made of a low melting point polymer and consisting of a thin branch embedding the thread row and a number of other thread rows approximately perpendicular to this thread row.
It is an I-like substance.

本発明の直接被覆する植物深護シートはそのままで被覆
する物品にかぶせ、要すればその周辺を土で埋めて使用
することができるが、粘着テープあるいは接着剤を用い
て張り合わせたり、基礎材等に張り付けることが可能で
あり、熱融着で継ぎ合わせたり、ホッチキスで止めたり
、縫い糸で固定することも可能である。また被覆するま
えにあらかじめ袋状に成型しておくことも可能である。
The plant protection sheet for direct covering of the present invention can be used as it is by covering the object to be covered, and if necessary, filling the surrounding area with soil. It is also possible to attach them to the paper, and it is also possible to heat-seal them, staple them, or secure them with sewing thread. It is also possible to form the material into a bag shape before covering it.

本発明の直接被覆する!ri物cA護シートは他のフィ
ルムなどと継ぎ合わせて使用することも可能である。こ
の場合、保護シートの移動や変形を防止するための支持
ロープやffi錘などを収り付けることが可能である。
Direct coating of the present invention! The RI material cA protection sheet can also be used in conjunction with other films. In this case, it is possible to store support ropes, FFI weights, etc. to prevent movement and deformation of the protective sheet.

本発明の直接被覆する植物保護シートは種々の色に着色
して使用することが出来る。
The plant protection sheet for direct coating of the present invention can be colored in various colors and used.

実施例 1 ポリエチレンのMF45.3のものを用い、KL縁線状
ダイから押し出したのち、ポリエチレンが凝固する前に
、表面温度105”Cの二a類の互いに逆方向において
平行配列する1群を存するエンボスローラーと平坦な表
面を有するアンビルローラーの間に挟んで菱形の隆起部
分規則的に形成したフィルムをつくり、二軸に延伸して
多孔フィルムを得た。この多孔フィルムは目付 8H/
m’、J′Jみの最大値0.08 mm、孔径の平均0
.8 mm、孔密度83個/c−2であり、延伸により
薄肉1ヒした部分では若干ひびわれを生じて、不規則化
しており、若干の毛羽3有していた。
Example 1 Using polyethylene with a MF of 45.3, after extruding it from a KL edge linear die, and before the polyethylene solidified, a group of type 2a materials having a surface temperature of 105"C were arranged in parallel in opposite directions. A film with regularly formed diamond-shaped raised portions was made by sandwiching it between an existing embossing roller and an anvil roller with a flat surface, and was stretched biaxially to obtain a porous film.This porous film had a basis weight of 8H/
m', J'J maximum value 0.08 mm, average pore diameter 0
.. It had a diameter of 8 mm, a hole density of 83 pores/c-2, and had some cracks and irregularities in the thinner part due to stretching, and had some fuzz.

この多孔フィルムを1枚十分成長した白菜の上にかぶせ
て、その周辺に土なかぶせて11月下II)より畑に植
えたままで保存した。外気A−7−12’C湿度20−
571で311上旬まで、なにもかぶせないものと並べ
て観察した。毎週1回被覆3はずし白菜の状態を調べた
。保護シートを用いたものは 2月上旬まで特に異常は
認められず、2月中旬以降には、どうたちによる変形が
観察された。一方促謹シートを用いなかったものは、1
2月中旬から外葉が枯れ始め、1月上旬には結球部にま
で枯死した部分が広がり、はとんど商品価値を失ったと
判定された。
A sheet of this porous film was placed over a fully grown Chinese cabbage, the surrounding area was covered with soil, and the cabbage was stored as planted in the field from November 2). Outside air A-7-12'C humidity 20-
I observed 571 and 311 side by side with those that don't cover anything until early 311. Once a week, the coating 3 was removed and the condition of the Chinese cabbage was examined. No particular abnormality was observed in those using protective sheets until early February, and deformation due to damage was observed after mid-February. On the other hand, those who did not use the promotion sheet received 1
The outer leaves began to wither in mid-February, and by early January, the dead parts had spread to the head part, and it was determined that the plant had almost lost its commercial value.

比較例 1 実施PA Iの多孔フィルムのかわりに、厚さ30μn
lのポリエチレン フィルムと用いたところ、被覆して
いない白菜とほとんど同一時期がら外葉が枯死する傾向
が現れた。
Comparative Example 1 Instead of the porous film of Example PA I, a thickness of 30 μn was used.
When using the same polyethylene film, the outer leaves tended to wither at almost the same time as uncoated Chinese cabbage.

実施例 2 実施例 1の多孔フィルムに、ポリエステル系バインダ
ー繊維(未延伸タイプ)t15$含むポリエステル繊維
ウェブ(目イ寸25g/m”)を重す、ウェブ側から熱
風と吹き付けて@着処理な行った。
Example 2 A polyester fiber web (measuring size: 25 g/m) containing 15 t of polyester binder fiber (unstretched type) was placed on the porous film of Example 1, and hot air was blown from the web side for @adhesion treatment. went.

このシートご用いてキャベツ苗の移植後の活着率の改良
を試みた。外気温度 最高31−37°C最低26−3
1’C晴天の 14日間観察を続けた。移植後の苗にこ
のシー+−1直接被躍したものは、4日に1回の潅水に
より 100% 活着した。50に1回の潅水では活着
率は70% に低下した。被覆をしなかった苗は毎日潅
水した場合には 100%活着したが、2目に一回の潅
水では活着率は 45%に低下した。
Using this sheet, we attempted to improve the survival rate of cabbage seedlings after transplanting. Outside temperature Maximum 31-37°C Minimum 26-3
Observations continued for 14 days under clear skies at 1'C. After transplanting, seedlings directly covered with this Sea+-1 were 100% established by watering once every 4 days. When watered once every 50 times, the survival rate decreased to 70%. When uncovered seedlings were watered every day, 100% of them took root, but after the second watering, the survival rate dropped to 45%.

比較例 3 実施例 2のシートのかわりに、目付け34g/m2の
スパンボンド型不織布3用いたところ、潅水の周期は同
様に延長できたが、被覆した不繊布が固く重いため、葉
に潟を生じて成Tγの遅れたものが15%生じた。
Comparative Example 3 When spunbond nonwoven fabric 3 with a basis weight of 34 g/m2 was used instead of the sheet in Example 2, the irrigation cycle could be extended in the same way, but the covered nonwoven fabric was hard and heavy, so it was difficult to cover the leaves with lagoons. 15% of the samples had delayed Tγ growth.

実施例 3 ポリプロピレンのMFR4,5のものを用い、直線状の
グイから押し出して凝固する訂に、表面温度 155°
Cのエンボス ローラーと平坦な表面を有するアンビル
 ローラーとの間に挟んで六角形の隆起部が規則的に残
るように成型した攪、二軸延部を行い多孔フィルム!!
:得た。この多孔フィルムノ目付++ハ8 g/m”、
最11!7 イ所ノJ5ミ0.06−一、孔径の平均 
1,4−鋼、孔密度80個/cl12であった。
Example 3 Polypropylene with an MFR of 4.5 was used, and the surface temperature was 155° when it was extruded from a straight line and solidified.
A porous film is formed by sandwiching it between an embossing roller (C) and an anvil roller with a flat surface so that hexagonal ridges remain regularly, then performing biaxial stretching and agitation! !
:Obtained. The weight of this porous film is ++8 g/m”,
Maximum 11!7 Isokoro J5 Mi 0.06-1, average pore diameter
1,4-steel, pore density 80/cl12.

この多孔フィルムに網目状の横?i物(目]・1け10
 g/−2、長手方向の糸条物の密度220本/lI2
゜幅方向の糸条物の密度800本/−)を約1cm間隔
で点状に熱融着した物3、実施例 1と同様にして寒冷
期のホウレンソウ用の保護カバーとしたところ、同様に
優れた保護能力を示した。
Is this porous film horizontally meshed? i thing (eye)・1 digit 10
g/-2, longitudinal yarn density 220 threads/lI2
3. A protective cover for spinach in the cold season was made in the same manner as in Example 1 by heat-sealing dots of threads (density of 800 yarns/- in the width direction) at approximately 1 cm intervals. It showed excellent protection ability.

実施例 4 分子量的 15,000のナイロン6に低密度ポリエチ
レンのMFRll、0のものを 30重量%混合した物
を用い、直線状のグイから押出して凝固した後、表面温
度205°Cのエンボス ローラーと平坦を表面な有す
るアンビル ローラーの間に挟んでほぼ正方形の隆起部
が残るように成型した後、二輪延伸を行なった。得られ
た多孔フィルムの目付けは5 g/輸2、最も厚い所の
厚み0.05 am、孔密度 12個/C輪2であった
Example 4 A mixture of 30% by weight of nylon 6 with a molecular weight of 15,000 and low density polyethylene with MFRll, 0 was extruded through a linear gouer and solidified, followed by an embossing roller with a surface temperature of 205°C. The material was sandwiched between an anvil roller with a flat surface and formed to leave an approximately square raised portion, and then two-wheel stretching was performed. The basis weight of the obtained porous film was 5 g/2, the thickness at the thickest point was 0.05 am, and the pore density was 12/C ring 2.

この多孔フィルムも直接被覆する植物保護シートとして
、実施例 1と同様に優れた性能を示した。
This porous film also showed excellent performance as in Example 1 as a plant protection sheet for direct coating.

(へ)発明の効果 本発明の直接被覆するFa物保譚シートは農fe物など
を強風、冷気、高温、低湿、水滴、日照などから保護す
る能力に優れており、軽重、安価で作業性が良好である
(F) Effects of the Invention The directly coated ferrous material protection sheet of the present invention has excellent ability to protect agricultural products from strong winds, cold air, high temperatures, low humidity, water droplets, sunlight, etc., and is lightweight, inexpensive, and easy to work with. is good.

Claims (1)

【特許請求の範囲】[Claims] 厚み0.001mmないし0.2mm、孔径0.1mm
ないし5mm、孔密度1ないし5000個/cm^2の
実質的に規則正しく配列する孔を有するフィルムを主な
材料とする直接被覆する植物保護シート
Thickness 0.001mm to 0.2mm, hole diameter 0.1mm
A plant protection sheet for direct coating, the main material of which is a film having substantially regularly arranged pores with a diameter of 1 to 5 mm and a pore density of 1 to 5000/cm^2.
JP18884486A 1986-08-11 1986-08-11 Directly applicable, plant protecting sheet Pending JPS6343933A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP18884486A JPS6343933A (en) 1986-08-11 1986-08-11 Directly applicable, plant protecting sheet

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP18884486A JPS6343933A (en) 1986-08-11 1986-08-11 Directly applicable, plant protecting sheet

Publications (1)

Publication Number Publication Date
JPS6343933A true JPS6343933A (en) 1988-02-25

Family

ID=16230829

Family Applications (1)

Application Number Title Priority Date Filing Date
JP18884486A Pending JPS6343933A (en) 1986-08-11 1986-08-11 Directly applicable, plant protecting sheet

Country Status (1)

Country Link
JP (1) JPS6343933A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2002544310A (en) * 1999-05-07 2002-12-24 スリーエム イノベイティブ プロパティズ カンパニー Film having fibrillated surface and manufacturing method
JP2018080256A (en) * 2016-11-16 2018-05-24 日本カーバイド工業株式会社 Method for producing porous film, and porous film

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2002544310A (en) * 1999-05-07 2002-12-24 スリーエム イノベイティブ プロパティズ カンパニー Film having fibrillated surface and manufacturing method
JP2018080256A (en) * 2016-11-16 2018-05-24 日本カーバイド工業株式会社 Method for producing porous film, and porous film

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