JPS6343638B2 - - Google Patents
Info
- Publication number
- JPS6343638B2 JPS6343638B2 JP59131460A JP13146084A JPS6343638B2 JP S6343638 B2 JPS6343638 B2 JP S6343638B2 JP 59131460 A JP59131460 A JP 59131460A JP 13146084 A JP13146084 A JP 13146084A JP S6343638 B2 JPS6343638 B2 JP S6343638B2
- Authority
- JP
- Japan
- Prior art keywords
- oxygen
- gas
- activated carbon
- pressure
- present
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 47
- 229910052760 oxygen Inorganic materials 0.000 claims description 30
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 28
- 239000001301 oxygen Substances 0.000 claims description 28
- 239000007789 gas Substances 0.000 description 25
- 239000000443 aerosol Substances 0.000 description 6
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 4
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 4
- 230000029058 respiratory gaseous exchange Effects 0.000 description 4
- 229910001882 dioxygen Inorganic materials 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
- 206010039897 Sedation Diseases 0.000 description 2
- 239000003610 charcoal Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000003205 fragrance Substances 0.000 description 2
- 238000002347 injection Methods 0.000 description 2
- 239000007924 injection Substances 0.000 description 2
- NNPPMTNAJDCUHE-UHFFFAOYSA-N isobutane Chemical compound CC(C)C NNPPMTNAJDCUHE-UHFFFAOYSA-N 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 230000001590 oxidative effect Effects 0.000 description 2
- 230000002265 prevention Effects 0.000 description 2
- 238000011084 recovery Methods 0.000 description 2
- 230000036280 sedation Effects 0.000 description 2
- 229920000742 Cotton Polymers 0.000 description 1
- 206010013975 Dyspnoeas Diseases 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 241001465754 Metazoa Species 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- 238000000222 aromatherapy Methods 0.000 description 1
- 238000003287 bathing Methods 0.000 description 1
- 230000033228 biological regulation Effects 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000011491 glass wool Substances 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 230000000147 hypnotic effect Effects 0.000 description 1
- 239000001282 iso-butane Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 230000036651 mood Effects 0.000 description 1
- 239000003345 natural gas Substances 0.000 description 1
- 210000005036 nerve Anatomy 0.000 description 1
- 239000005416 organic matter Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 230000001766 physiological effect Effects 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 230000035945 sensitivity Effects 0.000 description 1
- 239000002341 toxic gas Substances 0.000 description 1
- 239000000341 volatile oil Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K3/00—Materials not provided for elsewhere
- C09K3/30—Materials not provided for elsewhere for aerosols
Landscapes
- Chemical & Material Sciences (AREA)
- Dispersion Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Respiratory Apparatuses And Protective Means (AREA)
- Filling Or Discharging Of Gas Storage Vessels (AREA)
Description
【発明の詳細な説明】
産業上の利用分野
人類を始め動物類は空気を呼吸して生存してい
るが、酸素の欠乏する状態におかれた場合、また
呼吸困難な場合、酸素また酸素濃度の高い空気を
呼吸させて回復させることは周知のとおりであ
り、本発明はその目的に用いられる酸素を収納し
てなる酸素ボンベに関するものである。[Detailed Description of the Invention] Industrial Application Fields Humans and other animals survive by breathing air, but when they are placed in an oxygen-deficient state or have difficulty breathing, oxygen or oxygen concentration decreases. It is well known that breathing air with high levels of oxygen can be used for recovery, and the present invention relates to an oxygen cylinder containing oxygen used for this purpose.
従来の技術
従来は、高圧に圧縮された酸素を耐圧容器に入
れたいわゆる酸素ボンベが供給されている。普通
150Kg/cm2Gの圧縮ガスを充填するため、圧力に
よつて破壊しないような計算肉厚によつて保証さ
れ従つて重量が極めて重い。例えば6容器で50
Kg、1容器で5Kg程度もあり、また取扱い上減
圧弁を付すので金額も高価なものとなる。簡便に
酸素を得るために、KClO3−MnO2;Na2CO3・
2H2O2;H2O2−(NH4)2SO5系の薬剤の化学反応
によつて、緊急的に発生させるものがあるが、必
然的に高価となりまた径時的劣化の欠点がある。BACKGROUND ART Conventionally, so-called oxygen cylinders, in which highly compressed oxygen is placed in a pressure-resistant container, have been supplied. usually
Since it is filled with 150 Kg/cm 2 G of compressed gas, it is guaranteed by the calculated wall thickness that it will not break under pressure and is therefore extremely heavy. For example, 50 for 6 containers
One container weighs about 5 kg, and a pressure reducing valve is required for handling, making it expensive. In order to easily obtain oxygen, KClO 3 −MnO 2 ;Na 2 CO 3・
2H 2 O 2 ; H 2 O 2 −(NH 4 ) 2 SO 5 can be generated in an emergency manner through a chemical reaction, but it is inevitably expensive and has the drawback of deterioration over time. be.
発明が解決しようとする問題点
上記の如く従来品は緊急的に酸素が必要になつ
た場合手軽に提供し、かつ簡便な取扱を考え、ま
たコスト的に問題がある。例えば火災の発生有毒
ガスによる事故が報道されるが、この時短時間で
あつても酸素また空気を呼吸しながら逃避すれば
免れ得るものであるが、前記のボンベでは重過ぎ
るし、化学反応酸素品は取扱上緊急に作動しない
のである。Problems to be Solved by the Invention As mentioned above, the conventional products have problems in terms of easy provision when oxygen is urgently needed, easy handling, and cost. For example, there have been reports of fires caused by toxic gases, which can be avoided by escaping while breathing oxygen or air even for a short time, but the cylinders mentioned above are too heavy, and chemically reactive oxygen products are does not operate in an emergency due to handling reasons.
問題を解決するための手段
酸素ガス等を圧縮充填する場合、この圧力によ
つて充填容量が決定される。例えば150Kg/cm2G
圧力で充填された1容器から放出するガスは
150である。こゝにおいて10Kg/cm2G以上の圧
縮ガスは高圧ガス取締法の対象となるため、その
容器の規格、耐圧検査、保管等が煩雑で、重量的
に重くなり自ら高価なものとなる。この法規の適
用外となり、現在一般に大量生産されているエア
ゾール用耐圧缶を流用すれば、大巾なコストダウ
ンが期待できるものゝ、現在日本では500ml(米
国等では1000mlで日本でも之等拡大する気運はあ
る)が最大で、之に10Kg/cm2Gで圧入したとき放
出され得るガスは5であり、量的には少い。因
みに市販エアゾール缶は耐圧強度13Kg/cm2G保証
で、之に缶封する放出バルブ機構マウテンカツプ
も大量生産されており割安である。Means for Solving the Problem When compressing and filling oxygen gas, etc., the filling capacity is determined by this pressure. For example, 150Kg/cm 2 G
The gas released from a container filled with pressure is
It is 150. Compressed gas of 10 kg/cm 2 G or more is subject to the High Pressure Gas Control Law, so the specifications, pressure testing, storage, etc. of the container are complicated, and the gas becomes heavy and expensive. If we use pressure-resistant aerosol cans, which are not covered by this law and are currently mass-produced, we can expect a significant cost reduction.Currently in Japan, the canister size is 500ml (in the United States, it is 1000ml, and it is expected to expand in Japan as well). The maximum amount of gas is 10 kg/cm 2 G, and the amount of gas that can be released is 5, which is small in quantity. Incidentally, commercially available aerosol cans are guaranteed to have a pressure resistance of 13 kg/cm 2 G, and the release valve mechanism that seals the cans, the Mauten Cup, is also mass-produced and inexpensive.
一般に人間一人が呼吸する空気量は約2〜3
/分で持続時間4分程度が消防用防災機器の標
準になつていることから、10程度以上の収納能
力が望ましいところである。単なる新鮮空気の吸
入といつた気分転換の目的、例えば香料を入れた
アロマテラピイ的に用いる場合必ずしもその量に
限定される必要はないとしても、上記エアゾール
缶を使用した場合の単なる10Kg/cm2以下のガス充
填では不充分である。 Generally, the amount of air that a person breathes is approximately 2 to 3
As the standard for firefighting disaster prevention equipment is approximately 4 minutes per minute, it is desirable to have a storage capacity of approximately 10 minutes or more. When used for the purpose of refreshing the mood, such as simply inhaling fresh air, for example, aromatherapy containing fragrances, the amount may not necessarily be limited to 10 kg/cm 2 when using the above aerosol can. The following gas filling is insufficient.
本発明では上記の一般流通缶を用い、法規規制
以下で出来得る限り大量の酸素を収納し得る手段
を発明した。即ち本発明では、活性炭が酸素を吸
蔵することに着目し、上記エアゾール缶に活性炭
を収納し、それに酸素ガスまた酸素富化空気を圧
充する方法を採用した。 In the present invention, we have invented a means to store as much oxygen as possible within the legal regulations using the above-mentioned general distribution can. That is, the present invention focuses on the fact that activated carbon stores oxygen, and adopts a method of storing activated carbon in the aerosol can and pressurizing it with oxygen gas or oxygen-enriched air.
例えばAE420缶(内容積420ml)に粒状活性炭
を収納し、20℃で酸素を10Kg/cm2Gまで圧入させ
る。これを弁を開いて放出したとき10.5の酸素
が得られた。即ちスペースボリユーム当り2.5倍
の酸素が収納されたことになる。圧縮ガスの容積
はボイル・シヤールの法則できめられる筈である
が、活性炭が存在するとこの関係は成立たなくな
る。図面第1図は480ml容積缶において、O2:N2
=65:35(V%)のガスを圧入したとき、放出し
得るガス量は缶内圧力との関係を示したもので点
線は乾燥活性炭、鎖線は湿潤活性炭を90%の容積
に充填した場合実線は活性炭なしの場合を示す。 For example, granular activated carbon is stored in an AE420 can (inner volume: 420 ml), and oxygen is pressurized at 20°C up to 10 kg/cm 2 G. When this was released by opening the valve, 10.5% of oxygen was obtained. In other words, 2.5 times more oxygen was stored per space volume. The volume of compressed gas is supposed to be determined by Boyle-Schard's law, but this relationship no longer holds if activated carbon is present. Figure 1 shows O 2 :N 2 in a 480ml volume can.
The amount of gas that can be released when pressurizing gas at =65:35 (V%) shows the relationship with the internal pressure of the tank.The dotted line is dry activated carbon, and the chain line is when wet activated carbon is filled to 90% volume. The solid line shows the case without activated carbon.
活性炭を充填した容器に、ガスを圧入したとき
圧縮ガスの貯蔵量が増大することは例えば特許公
報 昭和50−27604号(出願日 昭和45年7月1
日)に記載されている。この報文によればメタ
ン、天然ガス(プロパン、プロピレン、イソブタ
ン、イソズチレン等)エチレン、窒素、水素につ
いて可能であるとしている。酸素についての記載
がないのは、従来圧縮酸素ガスは有機物、カーボ
ン等の混在は極めて危険であり、タブーとされて
いたためであろうと推察される。事実本発明者の
実験でも活性炭が存在した場合40℃において逐次
加圧充填したとき57Kg/cm2において爆発した。し
かし、本発明の範囲上限即ち10Kg/cm2では100℃
においても安全であつた。 For example, it is known that when gas is pressurized into a container filled with activated carbon, the amount of compressed gas stored increases.
day). According to this report, it is possible to use methane, natural gas (propane, propylene, isobutane, isoztyrene, etc.), ethylene, nitrogen, and hydrogen. The reason why there is no mention of oxygen is presumed to be because in the past, compressed oxygen gas mixed with organic matter, carbon, etc. was considered extremely dangerous and taboo. In fact, in the inventor's experiments, when activated carbon was present, it exploded at 57 kg/cm 2 when it was sequentially pressurized and filled at 40°C. However, at the upper limit of the range of the present invention, that is, 10Kg/ cm2, the temperature is 100℃.
It was also safe.
次に問題になると考える点は、圧力下において
酸素が活性炭と反応しCOまたはCO2を生成する
ことである。これらのガスは人間の呼吸に望まし
くない生理作用があるので、注意すべきことであ
る。実験的に求めると、図面第2図に示す様に、
圧力が10Kg/cm2を超えると急速に活性炭の酸化に
よるCO+CO2ガスが増えることが判る。従つて
10Kg/cm2G以下の圧入とする条件が重要である。 The next point that we think is problematic is that under pressure oxygen reacts with activated carbon to produce CO or CO 2 . Caution should be taken as these gases have undesirable physiological effects on human respiration. When experimentally determined, as shown in Figure 2 of the drawing,
It can be seen that when the pressure exceeds 10Kg/cm 2 , the amount of CO + CO 2 gas increases rapidly due to the oxidation of activated carbon. accordingly
It is important to maintain a press fit of 10 kg/cm 2 G or less.
高圧ガス取締法によれば、容器が30ml以下の場
合圧力は限定されてないし、また逆に10Kg/cm2以
下であれば容器の大きさは制限されることはな
い。本発明は、法的規定による経済性の制約を避
けるために請求の範囲の設定を行つたと同時に、
偶然上述の活性炭の酸化性を避ける条件でもあ
る。活性炭の有効表面積が高い程充填酸素量が多
いが、酸化ガスも多くなるのでその兼合が重要
で、チヤコール、木炭も代用し得る資源である。 According to the High Pressure Gas Control Law, there are no restrictions on the pressure if the container is 30ml or less, and conversely, there are no restrictions on the size of the container if it is 10Kg/cm 2 or less. The scope of the present invention has been defined in order to avoid economical constraints due to legal provisions, and at the same time,
This also happens to be a condition that avoids the oxidizing properties of activated carbon mentioned above. The higher the effective surface area of activated carbon, the greater the amount of oxygen it can fill, but since the amount of oxidizing gas also increases, it is important to balance these two aspects, and charcoal and charcoal are also resources that can be substituted.
次に問題になると考えられる第三の検討事項
は、富化空気においてN2が混在したとき活性炭
に対する吸蔵はO2の方が活性なため、初期放出
ガスはN2リツチになるのではないかと考えられ
るが、N2:O2=50:50V%のガスを圧入し、初
期噴出のガスを分析したときO2=48.0V%で実用
上問題にならないことが判つた。 The third consideration that is considered to be a problem is that when N 2 is mixed in enriched air, O 2 is more active in occluding O 2 in activated carbon, so the initial released gas may be rich in N 2 . However, when gas was injected at a ratio of N 2 :O 2 =50:50V% and the initial ejected gas was analyzed, it was found that O2 = 48.0V%, which was not a practical problem.
従つて本発明において適用する酸素富化空気と
は、空気の21V%以上のO2濃度のガスである。 Therefore, the oxygen-enriched air applied in the present invention is a gas with an O 2 concentration of 21 V% or more of air.
実施例
実施例 1
エアゾール用AE480缶に粒状活性炭350gを詰
め、その上面をガラスウールを以て固定し、噴出
機構を有するマウテインキヤツプをかしめ、ステ
ムよりO290%、N210%の混合ガスを8Kg/cm2G
になる迄圧入し、本発明品を得た。Examples Example 1 Fill an aerosol AE480 can with 350 g of granular activated carbon, fix the top surface with glass wool, caulk a mountain cap with a blowout mechanism, and inject a mixed gas of 90% O 2 and 10% N 2 from the stem. 8Kg/ cm2G
The product of the present invention was obtained by press-fitting the product until it became .
本発明品は、酸素富化空気を11.5放出するこ
とが出来た。なお噴射機構のキヤピラリーを細く
して2.8/minの噴出速度をとり、4分以上の
保持が可能である。 The product of the present invention was able to release 11.5 hours of oxygen-enriched air. Note that by making the capillary of the injection mechanism thinner, a jetting speed of 2.8/min can be achieved, which can be maintained for more than 4 minutes.
実施例 2
エアゾール980ml缶(φ64×H300mm)に粉状活
性炭600gを詰め、その上面を綿布で固定し、噴
射機構を有するマウテインキヤツプをかしめ、ス
テムよりO260%富化空気を8Kg/cm2になる迄圧
入し、本発明品を得た。Example 2 A 980ml aerosol can (φ64 x H300mm) was filled with 600g of powdered activated carbon, the top of the can was fixed with cotton cloth, a mount cap with an injection mechanism was caulked, and 8Kg/cm of 60% O 2 enriched air was pumped through the stem. The product of the present invention was obtained by press-fitting until it reached 2 .
本品は約20の酸素富化空気を放出させること
が出来た。 This product was able to release approximately 20 oxygen-enriched air.
発明の効果
本発明品は重量的に軽く、取扱操作は極めて簡
単であり、緊急医療用、防災用に最適のみなら
ず、疲労回復、神経鎮静等応倫範囲の広いもので
ある。Effects of the Invention The product of the present invention is light in weight, extremely easy to handle, and is not only ideal for emergency medical care and disaster prevention, but also has a wide range of applications, including fatigue recovery and nerve sedation.
なお、活性炭を詰めた後、香料等を添加し、特
殊な効果即ち、最近の話題となつている森林浴の
様に、植物精油により覚醒・催眠・鎮静・賦活等
の効能、更に心理的感応が期待出来る。 After filling the activated charcoal, fragrances, etc. are added to create special effects, such as awakening, hypnosis, sedation, and activation using plant essential oils, as well as psychological sensitivity, similar to forest bathing, which has recently become a hot topic. I can expect it.
第1図は480ml容積缶において、酸素富化空気
を圧入したとき、充填する缶内圧力と放出し得る
ガス量の関係を示すもので、実線は活性炭を入れ
ない空缶、点線は乾燥活性炭、鎖線は湿潤活性炭
を430ml詰めた缶について求めたものである。第
2図は、活性炭を充填した容器に、酸素富化空気
を充填したものを40℃で1ケ月後に放出し、その
放出ガス中に含まれる(CO+CO2)ガス濃度を
充填圧力との関係において求めたものである。
Figure 1 shows the relationship between the pressure inside the can and the amount of gas that can be released when oxygen-enriched air is injected into a 480ml can.The solid line shows the empty can without activated carbon, the dotted line shows the dry activated carbon, and the dotted line shows the empty can without activated carbon. The dashed line is determined for a can filled with 430 ml of wet activated carbon. Figure 2 shows a container filled with activated carbon filled with oxygen-enriched air that is released after one month at 40°C, and the concentration of (CO + CO 2 ) gas contained in the released gas in relation to the filling pressure. It's what I asked for.
Claims (1)
が10Kg/cm2G以下で酸素または酸素富化空気を圧
入した簡易酸素ボンベ。1 A simple oxygen cylinder in which oxygen or oxygen-enriched air is pressurized into a container containing activated carbon at a pressure of 10 kg/cm 2 G or less at 20°C.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP13146084A JPS6113097A (en) | 1984-06-26 | 1984-06-26 | Simple oxygen cylinder |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP13146084A JPS6113097A (en) | 1984-06-26 | 1984-06-26 | Simple oxygen cylinder |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS6113097A JPS6113097A (en) | 1986-01-21 |
JPS6343638B2 true JPS6343638B2 (en) | 1988-08-31 |
Family
ID=15058475
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP13146084A Granted JPS6113097A (en) | 1984-06-26 | 1984-06-26 | Simple oxygen cylinder |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS6113097A (en) |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS62183850U (en) * | 1986-05-16 | 1987-11-21 | ||
JPS63167198A (en) * | 1986-12-27 | 1988-07-11 | Kyushu Refract Co Ltd | Conveying method for carbon monoxide |
GB2561148B (en) * | 2017-03-01 | 2019-10-23 | Simply Breathe Ltd | Oxygen dispenser with activated carbon and carbon monoxide preventing catalyst |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5027604A (en) * | 1973-06-05 | 1975-03-20 |
-
1984
- 1984-06-26 JP JP13146084A patent/JPS6113097A/en active Granted
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5027604A (en) * | 1973-06-05 | 1975-03-20 |
Also Published As
Publication number | Publication date |
---|---|
JPS6113097A (en) | 1986-01-21 |
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