JPS6343204A - Flame resisting electrically insulating composition - Google Patents
Flame resisting electrically insulating compositionInfo
- Publication number
- JPS6343204A JPS6343204A JP61187053A JP18705386A JPS6343204A JP S6343204 A JPS6343204 A JP S6343204A JP 61187053 A JP61187053 A JP 61187053A JP 18705386 A JP18705386 A JP 18705386A JP S6343204 A JPS6343204 A JP S6343204A
- Authority
- JP
- Japan
- Prior art keywords
- flame
- electrically insulating
- insulating composition
- parts
- aluminum hydroxide
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000203 mixture Substances 0.000 title claims description 8
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 claims description 10
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 claims description 8
- 239000003063 flame retardant Substances 0.000 claims description 8
- 229920000098 polyolefin Polymers 0.000 claims description 6
- 238000010292 electrical insulation Methods 0.000 claims description 5
- TXDNPSYEJHXKMK-UHFFFAOYSA-N sulfanylsilane Chemical compound S[SiH3] TXDNPSYEJHXKMK-UHFFFAOYSA-N 0.000 claims description 5
- 230000000052 comparative effect Effects 0.000 description 5
- 229910052736 halogen Inorganic materials 0.000 description 5
- 150000002367 halogens Chemical class 0.000 description 5
- 239000007789 gas Substances 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- 238000010521 absorption reaction Methods 0.000 description 3
- 239000003963 antioxidant agent Substances 0.000 description 3
- 238000004132 cross linking Methods 0.000 description 3
- 239000003431 cross linking reagent Substances 0.000 description 3
- 231100000331 toxic Toxicity 0.000 description 3
- 230000002588 toxic effect Effects 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 2
- 229920001577 copolymer Polymers 0.000 description 2
- 238000011156 evaluation Methods 0.000 description 2
- 239000012796 inorganic flame retardant Substances 0.000 description 2
- 238000009413 insulation Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- -1 polyethylene, ethylene vinyl acetate Polymers 0.000 description 2
- 239000000779 smoke Substances 0.000 description 2
- 231100000419 toxicity Toxicity 0.000 description 2
- 230000001988 toxicity Effects 0.000 description 2
- KOMNUTZXSVSERR-UHFFFAOYSA-N 1,3,5-tris(prop-2-enyl)-1,3,5-triazinane-2,4,6-trione Chemical compound C=CCN1C(=O)N(CC=C)C(=O)N(CC=C)C1=O KOMNUTZXSVSERR-UHFFFAOYSA-N 0.000 description 1
- RUFPHBVGCFYCNW-UHFFFAOYSA-N 1-naphthylamine Chemical compound C1=CC=C2C(N)=CC=CC2=C1 RUFPHBVGCFYCNW-UHFFFAOYSA-N 0.000 description 1
- XMNIXWIUMCBBBL-UHFFFAOYSA-N 2-(2-phenylpropan-2-ylperoxy)propan-2-ylbenzene Chemical compound C=1C=CC=CC=1C(C)(C)OOC(C)(C)C1=CC=CC=C1 XMNIXWIUMCBBBL-UHFFFAOYSA-N 0.000 description 1
- NLZUEZXRPGMBCV-UHFFFAOYSA-N Butylhydroxytoluene Chemical compound CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 NLZUEZXRPGMBCV-UHFFFAOYSA-N 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 239000004641 Diallyl-phthalate Substances 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 239000006087 Silane Coupling Agent Substances 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- QUDWYFHPNIMBFC-UHFFFAOYSA-N bis(prop-2-enyl) benzene-1,2-dicarboxylate Chemical compound C=CCOC(=O)C1=CC=CC=C1C(=O)OCC=C QUDWYFHPNIMBFC-UHFFFAOYSA-N 0.000 description 1
- WXCZUWHSJWOTRV-UHFFFAOYSA-N but-1-ene;ethene Chemical compound C=C.CCC=C WXCZUWHSJWOTRV-UHFFFAOYSA-N 0.000 description 1
- 239000000306 component Substances 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000010894 electron beam technology Methods 0.000 description 1
- HQQADJVZYDDRJT-UHFFFAOYSA-N ethene;prop-1-ene Chemical group C=C.CC=C HQQADJVZYDDRJT-UHFFFAOYSA-N 0.000 description 1
- STVZJERGLQHEKB-UHFFFAOYSA-N ethylene glycol dimethacrylate Chemical compound CC(=C)C(=O)OCCOC(=O)C(C)=C STVZJERGLQHEKB-UHFFFAOYSA-N 0.000 description 1
- 239000005038 ethylene vinyl acetate Substances 0.000 description 1
- 229920006244 ethylene-ethyl acrylate Polymers 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 238000007765 extrusion coating Methods 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 239000011810 insulating material Substances 0.000 description 1
- 239000012774 insulation material Substances 0.000 description 1
- 230000005865 ionizing radiation Effects 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- DZCCLNYLUGNUKQ-UHFFFAOYSA-N n-(4-nitrosophenyl)hydroxylamine Chemical compound ONC1=CC=C(N=O)C=C1 DZCCLNYLUGNUKQ-UHFFFAOYSA-N 0.000 description 1
- 239000000615 nonconductor Substances 0.000 description 1
- 239000002530 phenolic antioxidant Substances 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- DOIRQSBPFJWKBE-UHFFFAOYSA-N phthalic acid di-n-butyl ester Natural products CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 238000004381 surface treatment Methods 0.000 description 1
- 239000008399 tap water Substances 0.000 description 1
- 235000020679 tap water Nutrition 0.000 description 1
- 229920001897 terpolymer Polymers 0.000 description 1
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
- Organic Insulating Materials (AREA)
- Insulated Conductors (AREA)
Abstract
(57)【要約】本公報は電子出願前の出願データであるた
め要約のデータは記録されません。(57) [Abstract] This bulletin contains application data before electronic filing, so abstract data is not recorded.
Description
【発明の詳細な説明】
［産業上の利用分野］
本発明は、燃焼時に有毒なハロゲン系ガスを発生しない
難燃性電気絶縁組成物、特に、電線・ケーブルの絶縁材
料やシース材料への適用に好適な難燃性電気絶縁組成物
に関するものである。[Detailed Description of the Invention] [Industrial Application Field] The present invention is a flame-retardant electrical insulation composition that does not generate toxic halogen gas when burned, and is particularly applicable to insulation materials and sheath materials for electric wires and cables. The present invention relates to a flame-retardant electrical insulation composition suitable for.
［従来の技術］
電線・ケーブルの絶縁材料やシース材料としては電気絶
縁性に優れたポリオレフィンが多く用いられてきている
。最近の趨勢として車両用、船舶用電線・ケーブルおよ
び盤内、機内配線用電線等に難燃性を付与することが強
く要望されるようになってきた。[Prior Art] Polyolefins, which have excellent electrical insulation properties, have been widely used as insulating materials and sheath materials for electric wires and cables. As a recent trend, there has been a strong demand for flame retardancy to be imparted to electric wires and cables for vehicles and ships, and electric wires for wiring inside panels and aircraft.
ポリオレフィンを難燃化する方法としてはハロゲン含有
化合物、りん含有化合物等を混和する方法が一般に採用
されてきている。しかし、これらは燃焼時多量の煙を発
生し、機器への腐食性、人体への有害性等が問題になっ
ている。特に、最近は安全面からこの様なハロゲン系ガ
スを発生しないことが要望されるようになってき、てい
る。As a method of making polyolefin flame retardant, a method of mixing a halogen-containing compound, a phosphorus-containing compound, etc. has generally been adopted. However, these produce a large amount of smoke when burned, causing problems such as corrosivity to equipment and toxicity to the human body. In particular, recently there has been a demand for not generating such halogen-based gas from a safety standpoint.
この様な情勢を踏まえ、発煙性、有毒性の非常に少ない
無機系難燃剤が注目されるようになってきた。なかでも
、水酸化アルミニウムは最も代表的な無機系難燃剤であ
る。In light of this situation, inorganic flame retardants with extremely low smoke generation and toxicity are attracting attention. Among them, aluminum hydroxide is the most typical inorganic flame retardant.
［発明が解決しようとする問題点］
しかし、高度の難燃性を付与するためには水酸化アルミ
ニウムを多量加える必要があるが、通常の水酸化アルミ
ニラミラを用いると吸水、吸湿により電気的特性を大幅
に低下させるという問題を生ずる。[Problems to be solved by the invention] However, in order to impart a high degree of flame retardancy, it is necessary to add a large amount of aluminum hydroxide, but when ordinary aluminum hydroxide lamira is used, the electrical properties deteriorate due to water absorption. This results in the problem of significantly lowering the amount of water.
本発明は上記に基いてなされたものであり、高度の難燃
性を付与できると共に優れた電気的特性を有し、しかも
有毒なハロゲン系ガスを発生しない難燃性電気絶縁組成
物の提供を目的とするものである。The present invention has been made based on the above, and an object of the present invention is to provide a flame-retardant electrical insulating composition that can impart a high degree of flame retardancy, has excellent electrical properties, and does not generate toxic halogen gases. This is the purpose.
［問題点を解決するための手段］
本発明の難燃性電気絶縁組成物は、ポリオレフィン１０
０重量部に対してメルカプトシランで表面処理した水酸
化アルミニウムを５０〜５００重量部含有することを特
徴とするものである。[Means for solving the problems] The flame-retardant electrical insulation composition of the present invention comprises polyolefin 10
It is characterized by containing 50 to 500 parts by weight of aluminum hydroxide surface-treated with mercaptosilane relative to 0 parts by weight.
本発明において、ポリオレフィンとしては、エチレンプ
ロピレンコポリマ、エチレンプロピレンジェンターポリ
マ、ポリエチレン、エチレン酢酸ビニルコポリマ、エチ
レンエチルアクリレートコポリマ、エチレンブテンコポ
リマ、エチレンブテンジェンターポリマといったものが
あげられ、これらは単独使用または２種以上の併用が可
能である。In the present invention, examples of the polyolefin include ethylene propylene copolymer, ethylene propylene genter polymer, polyethylene, ethylene vinyl acetate copolymer, ethylene ethyl acrylate copolymer, ethylene butene copolymer, and ethylene butene terpolymer, which may be used alone or in combination. A combination of the above is possible.
水酸化アルミニウムは、Ｈ８（ＣＨ２）ｎ５ｉ（ＯＲ）
３ ［ｎ ：自然数、Ｒ：アルキル基］で表されるメ
ルカプトシランで表面処理をしたものを使用することに
より吸水、吸湿を抑制して電気的特性の向上をはかれる
。メルカプトシランで表面処理した水酸化アルミニウム
の含有量は、ポリオレフィン１００重量部に対して５０
〜５００重量部の範囲とする必要があり、５０重量部未
満では目的とする難燃性を付与できず、５００重量部を
越えると加工性が著しく低下して押出成形が困難になる
。Aluminum hydroxide is H8(CH2)n5i(OR)
By using a surface treated with mercaptosilane represented by 3 [n: natural number, R: alkyl group], water absorption and moisture absorption can be suppressed and electrical characteristics can be improved. The content of aluminum hydroxide surface-treated with mercaptosilane is 50 parts by weight per 100 parts by weight of polyolefin.
The content should be in the range of ~500 parts by weight; if it is less than 50 parts by weight, the desired flame retardance cannot be imparted, and if it exceeds 500 parts by weight, the processability will be significantly reduced and extrusion molding will become difficult.
本発明においては、上記成分に加えて架橋剤、酸化防止
剤、滑剤、軟化剤、分散剤等を適宜添加してもよい。架
橋剤としては、ジクミルパーオキサイド、３−ビス（ｔ
−ブチルパーオキシイソプロピル）ベンゼンに代表され
る有機過酸化物が適切であり、これに架橋助剤として、
硫黄、エチレンジメタアクリレート、ジアリルフタレー
ト、ｐ−キノンジオキシム等を併用してもよい。また、
電子線等の電離性放射線による架橋の場合は、架橋助剤
としてトリメチロールプロパントリメリテート、トリア
リルイソシアヌレート等の反応性のモノマを添加するの
が一般的である。酸化防止剤としては、フェニル−α−
ナフチルアミン、Ｎ＋Ｎ′−ジ−β−ナフチル−ｐ−フ
ェニレンジアミン等のアミン系酸化防止剤、２，６−ジ
ーｔ−ブチル−４−メチルフェノール、ヒンダードフェ
ノール等のフェノール系酸化防止剤があげられる。In the present invention, in addition to the above components, crosslinking agents, antioxidants, lubricants, softeners, dispersants, etc. may be added as appropriate. As a crosslinking agent, dicumyl peroxide, 3-bis(t
-butylperoxyisopropyl)benzene is suitable, and as a crosslinking agent,
Sulfur, ethylene dimethacrylate, diallyl phthalate, p-quinone dioxime, etc. may be used in combination. Also,
In the case of crosslinking using ionizing radiation such as an electron beam, a reactive monomer such as trimethylolpropane trimellitate or triallyl isocyanurate is generally added as a crosslinking aid. As an antioxidant, phenyl-α-
Examples include amine antioxidants such as naphthylamine, N+N'-di-β-naphthyl-p-phenylenediamine, and phenolic antioxidants such as 2,6-di-t-butyl-4-methylphenol and hindered phenol. .
［実施例］
第１表に示すような配合にしたがって各種成分を１００
℃に保持された６インチロールに投入してロール混線を
行い、混線後１２０℃に保持された４０ｍ／ｍ押出機（
Ｉ、／Ｄ−２５）を用い、外径２．０ｎｏｎの銅線上に
厚さ１．０ｍｍに押出被覆して絶縁電線を作製した（実
施例４〜６）。実施例１〜３および比較例１〜４につい
ては押出被覆に続いて１３ ｋｇ／ ａｎの水蒸気雰囲
気中に３分間保持して架橋することにより架橋絶縁電線
を作製した。[Example] 100% of various ingredients were mixed according to the formulation shown in Table 1.
The mixture was placed in a 6-inch roll kept at 120°C, and the rolls were mixed.
I, /D-25) was used to extrude and coat a copper wire with an outer diameter of 2.0 mm to a thickness of 1.0 mm to produce insulated wires (Examples 4 to 6). For Examples 1 to 3 and Comparative Examples 1 to 4, crosslinked insulated wires were produced by extrusion coating and then holding in a steam atmosphere of 13 kg/an for 3 minutes for crosslinking.
各側で作製した絶縁電線についての評価結果は第１表の
下欄に示した通りである。The evaluation results for the insulated wires produced on each side are shown in the lower column of Table 1.
評価は次に基いて行った。The evaluation was based on the following.
難燃性：ＪＩＳＣ３００４に基き水平に保った電線をバ
ーナーで燃焼後１分以内に消えれば合格であり、１分以
上燃えるものは不合格である。Flame retardancy: Based on JISC3004, if a wire held horizontally is burned in a burner and disappears within 1 minute, it is passed; if it burns for more than 1 minute, it is rejected.
絶縁抵抗：電線を７５℃の水道水に３０日間浸漬後、温
度２０℃、電圧５００Ｖで測定した。Insulation resistance: The wire was immersed in tap water at 75°C for 30 days, and then measured at a temperature of 20°C and a voltage of 500V.
第１表からも明らかな通り、本発明に係わる実施例１〜
６ではいずれも難燃性に合格し、電気的特性に優れてい
る。これに対し水酸化アルミニウムの含有量が規定値以
下の比較例１では難燃性が不合格であり、規定値以上の
比較例２では押出性が悪く成形不可能であった。また、
規定以外のシランカップリング剤を用いた比較例３およ
び表面処理なしの比較例４では浸水後の絶縁抵抗が低い
。As is clear from Table 1, Examples 1 to 1 according to the present invention
6, all passed the flame retardant test and had excellent electrical properties. On the other hand, in Comparative Example 1, in which the content of aluminum hydroxide was below the specified value, the flame retardance was rejected, and in Comparative Example 2, in which the content of aluminum hydroxide was above the specified value, extrudability was poor and molding was impossible. Also,
In Comparative Example 3 using a silane coupling agent other than the specified one and Comparative Example 4 without surface treatment, the insulation resistance after immersion in water was low.
［発明の効果］
以上説明してきた通り、本発明は難燃剤としてメルカプ
トシランで表面処理した水酸化アルミニウムを用いたも
のであり、良好な電気的特性を維持しながら高度の難燃
性を付与でき、しかも燃焼時に有毒なハロゲン系ガスを
発生しない電気絶縁物を得られるようになる。[Effects of the Invention] As explained above, the present invention uses aluminum hydroxide surface-treated with mercaptosilane as a flame retardant, and can provide a high degree of flame retardancy while maintaining good electrical properties. Moreover, it becomes possible to obtain an electrical insulator that does not generate toxic halogen gas when burned.
Claims (1)
シランで表面処理した水酸化アルミニウムを５０〜５０
０重量部含有することを特徴とする難燃性電気絶縁組成
物。(1) 50 to 50 parts of aluminum hydroxide surface-treated with mercaptosilane to 100 parts by weight of polyolefin.
A flame-retardant electrical insulation composition containing 0 parts by weight.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP61187053A JPS6343204A (en) | 1986-08-08 | 1986-08-08 | Flame resisting electrically insulating composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP61187053A JPS6343204A (en) | 1986-08-08 | 1986-08-08 | Flame resisting electrically insulating composition |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPS6343204A true JPS6343204A (en) | 1988-02-24 |
Family
ID=16199348
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP61187053A Pending JPS6343204A (en) | 1986-08-08 | 1986-08-08 | Flame resisting electrically insulating composition |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS6343204A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH06283030A (en) * | 1993-03-25 | 1994-10-07 | Hitachi Cable Ltd | Nonflammable electric insulating composite and insulated wire |
| JP2017160286A (en) * | 2016-03-07 | 2017-09-14 | 株式会社戸出Ｏ−Ｆｉｔ | Method for producing flame retardant composite resin material and flame retardant composite resin material |
-
1986
- 1986-08-08 JP JP61187053A patent/JPS6343204A/en active Pending
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH06283030A (en) * | 1993-03-25 | 1994-10-07 | Hitachi Cable Ltd | Nonflammable electric insulating composite and insulated wire |
| JP2017160286A (en) * | 2016-03-07 | 2017-09-14 | 株式会社戸出Ｏ−Ｆｉｔ | Method for producing flame retardant composite resin material and flame retardant composite resin material |
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