JPS6342676A - Preservation of food - Google Patents

Preservation of food

Info

Publication number
JPS6342676A
JPS6342676A JP18650086A JP18650086A JPS6342676A JP S6342676 A JPS6342676 A JP S6342676A JP 18650086 A JP18650086 A JP 18650086A JP 18650086 A JP18650086 A JP 18650086A JP S6342676 A JPS6342676 A JP S6342676A
Authority
JP
Japan
Prior art keywords
food
agent
hypochlorous acid
chlorine
proliferation
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP18650086A
Other languages
Japanese (ja)
Other versions
JPH088852B2 (en
Inventor
Daishiro Fujishima
藤島 大四郎
藤島 信一郎
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Individual
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Priority to JP61186500A priority Critical patent/JPH088852B2/en
Publication of JPS6342676A publication Critical patent/JPS6342676A/en
Publication of JPH088852B2 publication Critical patent/JPH088852B2/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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  • Food Preservation Except Freezing, Refrigeration, And Drying (AREA)

Abstract

PURPOSE:To prevent the proliferation of decaying fungi and mildew, etc., prevent the emission of chlorine smell and enable the long-term preservation of a food in fresh state, by treating a food with hypochlorous acid (salt) and hermetically sealing the treated food together with a dechlorination agent. CONSTITUTION:A food (e.g. rice cake, dried fish, etc.) is treated with hypochlorous acid (salt) (e.g. bleaching powder, sodium hypochlorite, etc.) and hermetically sealed together with a dechlorination agent (e.g. activated carbon, activated clay, etc.). Since the food is sterilized with hypochlorous acid (salt), the proliferation of decaying fungi and mildew in the package can be prevented. The chlorine smell is eliminated or highly suppressed by the sealed dechlorination agent to prevent the lowering of the commercial value caused by chlorine smell. When a disoxidation agent (e.g. iron powder, ascorbic acid, etc.) is sealed together with the dechlorination agent, the oxidative deterioration of the food can be prevented and the proliferation of aerobic bacteria can be suppressed.

Description

【発明の詳細な説明】 〔技術分野〕 本発明は食品の保存方法に関するものである。[Detailed description of the invention] 〔Technical field〕 The present invention relates to a method for preserving food.

〔従来技術〕[Prior art]

従来、食品を脱酸素剤の存在下で密封性の袋又は容器し
こ密封包装する方法は行われている。そして、このよう
にして形成された包装体は、封入した脱酸素剤の作用に
より、その内部は無酸素状態に保持され、その結果、そ
の被包装体である食品は、酸素から保護され、酸化劣化
や変色を受けず、また好気性菌の繁殖が抑制され、カビ
の発生がないという利点が得られる。
BACKGROUND ART Conventionally, a method has been used in which food products are tightly packaged in airtight bags or containers in the presence of an oxygen absorber. The interior of the package formed in this way is maintained in an oxygen-free state due to the action of the enclosed oxygen absorber, and as a result, the packaged food is protected from oxygen and oxidized. It has the advantage of not being subject to deterioration or discoloration, inhibiting the growth of aerobic bacteria, and preventing the growth of mold.

しかしながら、このような無酸素包装食品のうち、水分
の多い、カマボコ、チクワ、生干し魚、惣菜、野菜、煮
物、蒸し物等の食品は、カビの発生はないものの、嫌気
性菌の作用により、ネトが発生したり、発酵が生じたり
する等の問題があった。
However, among these oxygen-free packaged foods, foods with a high moisture content, such as kamaboko, chikuwa, dried fish, side dishes, vegetables, boiled foods, and steamed foods, do not develop mold, but due to the action of anaerobic bacteria, they can become moldy. There were problems such as the occurrence of water and fermentation.

一方、食品殺菌剤として、次亜塩素酸や、サラシ粉、次
亜塩素酸ナトリウム等の次亜塩素酸系処理剤が知られて
いる。このような次亜塩素酸系処理剤は強い殺菌力を示
すものの、塩素臭を生じるという欠点があり、包装食品
等の殺菌剤としての使用は困難であった。
On the other hand, hypochlorous acid, and hypochlorous acid-based processing agents such as white powder and sodium hypochlorite are known as food disinfectants. Although such hypochlorous acid-based treatment agents exhibit strong sterilizing power, they have the drawback of producing a chlorine odor, making it difficult to use them as sterilizing agents for packaged foods and the like.

〔目  的〕〔the purpose〕

本発明は、従来の食品保存技術に見られる前記問題を解
決することを目的とする。
The present invention aims to solve the above-mentioned problems found in conventional food preservation techniques.

〔構  成〕〔composition〕

本発明によれば、第1の発明として、次亜塩素酸処理又
は次亜塩素酸塩処理された食品を、脱塩素剤と共に密封
包装することを特徴とする食品の保存方法が提供され、
第2の発明として、次亜塩素酸処理又は次亜塩素酸塩処
理された食品を、脱塩素剤及び脱酸素剤と共に密封包装
することを特徴とする食品の保存方法が提供される。
According to the present invention, as a first invention, there is provided a method for preserving food, characterized in that food treated with hypochlorous acid or hypochlorite is hermetically packaged together with a dechlorination agent,
As a second invention, there is provided a method for preserving food, characterized in that food treated with hypochlorous acid or hypochlorite is hermetically packaged together with a dechlorinator and an oxygen absorber.

本明細書で言う食品は広く解釈され、各種菓子類の他、
煮物、蒸し物、干物、惣菜、野菜、果実、生鮮魚介類等
が包含される。本発明で使用し得る食品は、一般に、好
気性菌や嫌気性菌の作用により品質劣化の生じるもので
ある。
The term food referred to herein is broadly interpreted and includes various sweets,
This includes boiled foods, steamed foods, dried foods, side dishes, vegetables, fruits, fresh seafood, etc. Foods that can be used in the present invention generally suffer from quality deterioration due to the action of aerobic bacteria or anaerobic bacteria.

本発明では、前記食品を密封包装する前に、あらかじめ
次亜塩素酸処理又は次亜塩素酸塩処理する。この場合、
次亜塩素酸塩としては、従来公知のもの、例えば、高度
サラシ粉、サラシ粉、次亜塩素酸す1〜リウム等を挙げ
ることができる。このような次亜塩素酸塩は、通常、水
溶液の形で用いられ、その濃度は、有効塩素量換算で、
10ppm〜1重量%程度、好ましくは50〜1100
0ppの範囲である。
In the present invention, the food is treated with hypochlorous acid or hypochlorite in advance before being sealed and packaged. in this case,
Examples of the hypochlorite include conventionally known ones, such as highly refined white powder, white raw powder, sodium to lithium hypochlorite, and the like. Such hypochlorite is usually used in the form of an aqueous solution, and its concentration is equivalent to the amount of available chlorine.
About 10 ppm to 1% by weight, preferably 50 to 1100
It is in the range of 0pp.

また、この水溶液には、次亜塩素酸塩の作用促進剤とし
て、クエン酸やリンゴ酸、マレイン酸等の有機酸を添加
することができる。
Moreover, an organic acid such as citric acid, malic acid, or maleic acid can be added to this aqueous solution as an action promoter of hypochlorite.

本発明では、次亜塩素酸水溶液も使用し得るが、この次
亜塩素酸水溶液は、水に塩素を溶解させることによって
得ることができる。食品の次亜塩素酸又は次亜塩素酸塩
(以下、単に塩素剤という)による処理は、浸漬法の他
、スプレー法等を採用することができる。スプレー法に
より処理する場合、食品を包装用容器又は袋に入れた後
、その内部へスプレー処理することもできる。
In the present invention, an aqueous hypochlorous acid solution may also be used, and this aqueous hypochlorous acid solution can be obtained by dissolving chlorine in water. For the treatment of foods with hypochlorous acid or hypochlorite (hereinafter simply referred to as a chlorine agent), in addition to the immersion method, a spray method or the like can be employed. When processing by a spray method, the food can be placed in a packaging container or bag and then the inside thereof can be sprayed.

次に、塩素剤処理された食品は、これを脱塩素剤と共に
、密封性の袋又は容器を用いて密封包装する。この場合
、脱塩素剤としては、塩素系ガスに対して吸着性又は反
応性を示すものであれば任意のものが用いられる。この
ような脱塩素剤としては、例えば、活性炭の他、活性白
土、ケイソウ士、シリカ、アルミナ、マグネシア、シリ
カ−アルミナ、シリカ−マグネシア、酸化カルシウム、
水酸化カルシウム、水酸化マグネシウム、酸化鉄、水酸
化鉄(n)等の金属酸化物又は金属水酸化物、炭酸水素
塩、炭酸塩、亜硫酸水素塩、亜硫酸塩、ピロ亜硫酸塩、
チオ硫酸塩、硫酸鉄(n)等が挙げられる。前記炭酸水
素塩や炭酸塩、亜硫酸塩、亜硫酸水素塩、ピロ亜硫酸塩
、チオ硫酸塩、硫酸鉄等を脱塩素剤として用いる場合、
適量の水分、例えば、10〜50重量2を加えることが
望ましく、また、水分を10〜50重量%程度含む吸着
剤との混合物の形で用いるのも好ましい。さらに、炭酸
塩や、炭酸水素塩、亜硫酸塩、亜硫酸水素塩、ピロ亜硫
酸塩、チオ硫酸塩、硫酸鉄等の水溶液を吸着剤に10〜
50重斌%程度含浸させて用いることも好ましい。
Next, the chlorinated food is sealed and packaged together with a dechlorinator in a sealable bag or container. In this case, any dechlorination agent can be used as long as it exhibits adsorption or reactivity to chlorine gas. Examples of such dechlorinating agents include, in addition to activated carbon, activated clay, diatomite, silica, alumina, magnesia, silica-alumina, silica-magnesia, calcium oxide,
Metal oxides or metal hydroxides such as calcium hydroxide, magnesium hydroxide, iron oxide, iron hydroxide (n), hydrogen carbonates, carbonates, hydrogen sulfites, sulfites, pyrosulfites,
Examples include thiosulfate, iron sulfate (n), and the like. When using the above-mentioned bicarbonate, carbonate, sulfite, bisulfite, pyrosulfite, thiosulfate, iron sulfate, etc. as a dechlorination agent,
It is desirable to add an appropriate amount of moisture, for example 10 to 50% by weight, and it is also preferable to use it in the form of a mixture with an adsorbent containing about 10 to 50% by weight of moisture. Furthermore, an aqueous solution of carbonate, hydrogen carbonate, sulfite, hydrogen sulfite, pyrosulfite, thiosulfate, iron sulfate, etc. is used as an adsorbent for 10 to 30 minutes.
It is also preferable to use it by impregnating it with a concentration of about 50% by weight.

本発明で用いる脱塩素剤は、通常、紙や合成紙、紙と有
孔ポリフィルムとの積層フィルム等の通気性フィル11
の小袋に充填密封して適用される。脱塩素剤の使用量は
、食品に施した塩素剤処理の程度に応じて異なるが、一
般には、包装後、1週間以内、好ましくは1〜3日間以
内に包装体内の塩素臭が実質−1−感じられなくなる程
度の割合にするのがよい。包装後、1日程度で消費者に
わたる食品の場合には、12時間以内で包装体内の塩素
臭を実買上完全に除去するようにするのが好ましい。
The dechlorinator used in the present invention is usually made of a breathable film such as paper, synthetic paper, or a laminated film of paper and perforated polyethylene film.
It is applied by filling and sealing into sachets. The amount of dechlorinator used varies depending on the degree of chlorine treatment applied to the food, but in general, the odor of chlorine in the package is reduced to 1 to 1 within one week, preferably within 1 to 3 days after packaging. - It is best to set the proportion to such a level that you can no longer feel it. In the case of food products that are delivered to consumers within about one day after packaging, it is preferable that the chlorine odor in the packaging is completely removed within 12 hours after purchase.

食品包装用材料としては、プラスチック製の容器や袋、
あるいはガラス製ビン等が一般的に用いられる。
Food packaging materials include plastic containers and bags,
Alternatively, a glass bottle or the like is generally used.

本発明においては、塩素剤処理した食品を脱塩素剤と共
に密封包装する場合、その包装体内にはさらに脱酸素剤
を同封させることができる。この場合、脱酸素剤として
は従来公知の各種のもの、例えば、脱酸素活性成分とし
て、鉄粉、ハイドロサルファイド、アスコルビン酸、カ
テコール又はピロガロールを含むもの用いることができ
る。この脱酸素剤は、通常、通気性フィルムに充填密封
されて市販されている。この脱酸素剤を塩素剤処理され
た食品及び脱塩素剤と共に密封包装する場合、その包装
体は完全気密性のものにすることが必要である。その包
装用容器や袋に、ピンホールが存在すると、包装体内の
酸素濃度は1%以下にならず、脱酸素効果が得られない
。一方、塩素剤処理した食品を塩素剤のみと密封包装す
る場合、その包装体は必ずしも完全気密性のものにする
必要はなく、ピンホールがあっても、その塩素剤処理効
果は特に阻害されない。
In the present invention, when chlorinated food is sealed and packaged together with a dechlorinator, an oxygen absorber can be further enclosed within the package. In this case, various conventionally known oxygen scavengers can be used, such as those containing iron powder, hydrosulfide, ascorbic acid, catechol, or pyrogallol as oxygen scavenging active ingredients. This oxygen scavenger is usually commercially available sealed in a breathable film. When this oxygen absorber is sealed together with chlorinated food and the dechlorinator, the package must be completely airtight. If a pinhole exists in the packaging container or bag, the oxygen concentration within the package will not fall below 1%, making it impossible to obtain an oxygen removal effect. On the other hand, when chlorinated food is sealed and packaged with only the chlorine agent, the package does not necessarily have to be completely airtight, and even if there are pinholes, the effect of the chlorine treatment is not particularly impaired.

また、塩素剤処理された食品と脱塩素剤と脱酸素剤とを
密封包装する場合、脱塩素剤と脱酸素剤とはそれぞれ別
個に包装用容器又は袋内に封入する必要はなく、脱塩素
剤と脱酸素剤を同一の通気性袋内に充填密封することが
できる。
In addition, when chlorinating food, dechlorinating agent, and oxygen absorbing agent are sealed and packaged, it is not necessary to seal the dechlorinating agent and oxygen absorbing agent separately in packaging containers or bags; The agent and the oxygen scavenger can be filled and sealed in the same breathable bag.

〔効  果〕〔effect〕

本発明によれは、食品は、塩素剤処理、即ち、殺菌処理
されていることから、その包装体内における腐改菌やカ
ビ菌等の菌の繁殖はなく、長期にわたって食品の鮮度は
保持される。しかも、本発明の場合、脱塩素剤を同封し
たことから、塩素臭は除去ないし著しく抑制され、塩素
臭による商品価値の低1・の問題はない。さらに、包装
体内に脱M素剤を存在させた場合には、包装体内を無酸
素状態に保持させることができるので、食品の酸素劣化
を防114することができる]−1好気性菌の繁殖抑制
効果をも1:)ろことかできる。
According to the present invention, since the food is treated with chlorine, that is, sterilized, there is no spoilage or growth of bacteria such as mold inside the package, and the freshness of the food is maintained over a long period of time. . Moreover, in the case of the present invention, since a dechlorination agent is enclosed, the chlorine odor is removed or significantly suppressed, and there is no problem of low commercial value due to the chlorine odor. Furthermore, when a de-M agent is present inside the package, the inside of the package can be maintained in an anoxic state, thereby preventing oxygen deterioration of the food]-1 Propagation of aerobic bacteria It can also have a suppressive effect of 1:).

〔実施例〕〔Example〕

次に、本発明を実施例によりさらに詳細に説明する。 Next, the present invention will be explained in more detail with reference to Examples.

実施例1 (A)脱塩素剤の調製 水分斌約45%の砂状活性炭10重量部に粉末状チオ硫
酸ナトリウム5重量部を均一に混合し、この混合物6g
を紙袋に封入して脱塩素剤充填袋口)を調製した。
Example 1 (A) Preparation of dechlorination agent 5 parts by weight of powdered sodium thiosulfate was uniformly mixed with 10 parts by weight of sandy activated carbon having a moisture content of about 45%, and 6 g of this mixture was prepared.
was sealed in a paper bag to prepare a dechlorinator-filled bag opening).

(B)食品の保存試験 食品としての切餅約20gを有効塩素量0.1重量%の
次亜塩素酸ソーダ水溶液200cc中に5分間浸漬した
後、表面の水分を濾紙でふきとり、これを内容積約50
0ccのプラスチック袋に入れ、次いで前記脱塩素剤充
填袋(1)を入れて密封し、食品包装体(A)を作った
(B) Food preservation test Approximately 20 g of cut rice cakes as a food were immersed in 200 cc of sodium hypochlorite aqueous solution containing 0.1% by weight of available chlorine for 5 minutes, the surface water was wiped off with a filter paper, and the internal volume was Approximately 50
The product was placed in a 0 cc plastic bag, and then the dechlorinator filling bag (1) was placed therein and sealed to produce a food package (A).

比較のために、脱塩素剤充填袋(1)を封入しない以外
は同様にして食品包装体(B)を作った。
For comparison, a food package (B) was made in the same manner except that the dechlorination agent filling bag (1) was not enclosed.

さらに、比較のために、切餅を塩素剤処理せずに、かつ
脱塩素剤充填袋(1)を封入しない以外は同様にして5
食品包装体(C)を作った。
Furthermore, for comparison, 5 pieces were prepared in the same manner except that the cut rice cakes were not treated with chlorine and the dechlorination agent filling bag (1) was not sealed.
A food package (C) was made.

−7= 次に、前記で得た食品包装体を、10日間常温に保存し
た結果、食品包装体(C)中の切餅表面には許しいカビ
の発生が見られたが、食品包装体(A)及び(11)に
はカビの発生は見られなかった。これらの包装体を開封
して、包装体内部の塩素臭を調へたところ、脱塩素剤袋
(1)を封入した本発明による食品包装体(A)内には
塩素臭は殆んど感じられなかったが、比較のための食品
包装体(B)内には塩素臭が感じられ、商品としては価
値のないものであった・
-7= Next, the food package obtained above was stored at room temperature for 10 days, and as a result, mild mold was observed on the surface of the cut mochi in the food package (C). No mold growth was observed in A) and (11). When these packages were opened and the chlorine odor inside the packages was checked, it was found that there was almost no chlorine odor inside the food package (A) according to the present invention in which the dechlorinator bag (1) was enclosed. However, a chlorine odor was felt inside the food package (B) for comparison, and it was worthless as a product.

Claims (2)

【特許請求の範囲】[Claims] (1)次亜塩素酸処理又は次亜塩素酸塩処理を施された
食品を、脱塩素剤と共に密封包装することを特徴とする
食品の保存方法。
(1) A method for preserving food, which comprises sealing and packaging food that has been treated with hypochlorous acid or hypochlorite together with a dechlorination agent.
(2)次亜塩素酸処理又は次亜塩素酸塩処理を施された
食品を、脱塩素剤及び脱酸素剤と共に密封包装すること
を特徴とする食品の保存方法。
(2) A method for preserving food, which comprises sealing and packaging food treated with hypochlorous acid or hypochlorite together with a dechlorinator and an oxygen absorber.
JP61186500A 1986-08-08 1986-08-08 How to store food Expired - Fee Related JPH088852B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP61186500A JPH088852B2 (en) 1986-08-08 1986-08-08 How to store food

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP61186500A JPH088852B2 (en) 1986-08-08 1986-08-08 How to store food

Publications (2)

Publication Number Publication Date
JPS6342676A true JPS6342676A (en) 1988-02-23
JPH088852B2 JPH088852B2 (en) 1996-01-31

Family

ID=16189578

Family Applications (1)

Application Number Title Priority Date Filing Date
JP61186500A Expired - Fee Related JPH088852B2 (en) 1986-08-08 1986-08-08 How to store food

Country Status (1)

Country Link
JP (1) JPH088852B2 (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH02163069A (en) * 1988-12-13 1990-06-22 Ueno Seiyaku Oyo Kenkyusho:Kk Preservation of food
JP2002210474A (en) * 2001-01-15 2002-07-30 Hirosuke Sato Method for sterilizing preserved drinking water for emergency and hermetically sealed container of sterilizer
JP2013053287A (en) * 2011-09-01 2013-03-21 Amtec Co Ltd Chlorine gas reducing agent constituting composite with base material

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS60259170A (en) * 1984-06-06 1985-12-21 Daishiro Fujishima Manufacture of bag for holding disoxidation agent having sterilizing effect
JPS61104773A (en) * 1984-10-24 1986-05-23 Ueno Seiyaku Kk Treatment for food

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS60259170A (en) * 1984-06-06 1985-12-21 Daishiro Fujishima Manufacture of bag for holding disoxidation agent having sterilizing effect
JPS61104773A (en) * 1984-10-24 1986-05-23 Ueno Seiyaku Kk Treatment for food

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH02163069A (en) * 1988-12-13 1990-06-22 Ueno Seiyaku Oyo Kenkyusho:Kk Preservation of food
JP2002210474A (en) * 2001-01-15 2002-07-30 Hirosuke Sato Method for sterilizing preserved drinking water for emergency and hermetically sealed container of sterilizer
JP2013053287A (en) * 2011-09-01 2013-03-21 Amtec Co Ltd Chlorine gas reducing agent constituting composite with base material

Also Published As

Publication number Publication date
JPH088852B2 (en) 1996-01-31

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