JPS6334851A - 亜鉛のデンドライト抑制方法 - Google Patents
亜鉛のデンドライト抑制方法Info
- Publication number
- JPS6334851A JPS6334851A JP61176588A JP17658886A JPS6334851A JP S6334851 A JPS6334851 A JP S6334851A JP 61176588 A JP61176588 A JP 61176588A JP 17658886 A JP17658886 A JP 17658886A JP S6334851 A JPS6334851 A JP S6334851A
- Authority
- JP
- Japan
- Prior art keywords
- electrolyte
- charging
- zinc
- negative electrode
- discharge
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 210000001787 dendrite Anatomy 0.000 title claims abstract description 31
- 239000011701 zinc Substances 0.000 title claims description 64
- 238000000034 method Methods 0.000 title claims description 15
- 229910052725 zinc Inorganic materials 0.000 title claims description 9
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 title claims description 6
- 239000003792 electrolyte Substances 0.000 claims abstract description 45
- 239000007789 gas Substances 0.000 claims abstract description 19
- ZRXYMHTYEQQBLN-UHFFFAOYSA-N [Br].[Zn] Chemical compound [Br].[Zn] ZRXYMHTYEQQBLN-UHFFFAOYSA-N 0.000 claims abstract description 13
- 239000011261 inert gas Substances 0.000 claims abstract description 13
- 238000007599 discharging Methods 0.000 claims description 29
- 239000008151 electrolyte solution Substances 0.000 claims description 8
- 239000003112 inhibitor Substances 0.000 claims description 6
- 239000000203 mixture Substances 0.000 claims description 3
- 239000008139 complexing agent Substances 0.000 claims description 2
- 230000001629 suppression Effects 0.000 claims description 2
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 claims 2
- SODQFLRLAOALCF-UHFFFAOYSA-N 1lambda3-bromacyclohexa-1,3,5-triene Chemical compound Br1=CC=CC=C1 SODQFLRLAOALCF-UHFFFAOYSA-N 0.000 claims 1
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims 1
- 229910000831 Steel Inorganic materials 0.000 claims 1
- 229910052786 argon Inorganic materials 0.000 claims 1
- 229910001873 dinitrogen Inorganic materials 0.000 claims 1
- 239000010959 steel Substances 0.000 claims 1
- 210000004027 cell Anatomy 0.000 abstract description 12
- 238000004070 electrodeposition Methods 0.000 abstract description 10
- 229910052751 metal Inorganic materials 0.000 abstract description 5
- 239000002184 metal Substances 0.000 abstract description 5
- 230000036961 partial effect Effects 0.000 abstract description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 3
- 230000006866 deterioration Effects 0.000 abstract description 2
- 238000009826 distribution Methods 0.000 abstract description 2
- 150000002739 metals Chemical class 0.000 abstract description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 29
- 229910052760 oxygen Inorganic materials 0.000 description 29
- 239000001301 oxygen Substances 0.000 description 29
- 230000008859 change Effects 0.000 description 9
- 238000004090 dissolution Methods 0.000 description 8
- 230000015572 biosynthetic process Effects 0.000 description 7
- 238000006243 chemical reaction Methods 0.000 description 7
- 238000010586 diagram Methods 0.000 description 7
- 238000002474 experimental method Methods 0.000 description 7
- 239000000243 solution Substances 0.000 description 7
- 239000000047 product Substances 0.000 description 6
- 238000004140 cleaning Methods 0.000 description 5
- 230000000694 effects Effects 0.000 description 5
- 150000004679 hydroxides Chemical class 0.000 description 5
- 238000005259 measurement Methods 0.000 description 5
- 230000007423 decrease Effects 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 238000012546 transfer Methods 0.000 description 4
- 150000001875 compounds Chemical class 0.000 description 3
- 238000000151 deposition Methods 0.000 description 3
- 230000008021 deposition Effects 0.000 description 3
- 150000002500 ions Chemical class 0.000 description 3
- 239000002244 precipitate Substances 0.000 description 3
- 238000001556 precipitation Methods 0.000 description 3
- 230000002829 reductive effect Effects 0.000 description 3
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 2
- 229910052794 bromium Inorganic materials 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 229910021645 metal ion Inorganic materials 0.000 description 2
- 229920006395 saturated elastomer Polymers 0.000 description 2
- YXEARCXBPCFTKH-UHFFFAOYSA-M 4-dodecyl-4-methylmorpholin-4-ium;bromide Chemical compound [Br-].CCCCCCCCCCCC[N+]1(C)CCOCC1 YXEARCXBPCFTKH-UHFFFAOYSA-M 0.000 description 1
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- 239000011149 active material Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 238000006392 deoxygenation reaction Methods 0.000 description 1
- 238000003795 desorption Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000005246 galvanizing Methods 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- 239000002563 ionic surfactant Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 230000004660 morphological change Effects 0.000 description 1
- 238000009828 non-uniform distribution Methods 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- 230000000149 penetrating effect Effects 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 125000001453 quaternary ammonium group Chemical group 0.000 description 1
- 235000020079 raki Nutrition 0.000 description 1
- 239000003115 supporting electrolyte Substances 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 229910021511 zinc hydroxide Inorganic materials 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/42—Methods or arrangements for servicing or maintenance of secondary cells or secondary half-cells
- H01M10/44—Methods for charging or discharging
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/70—Arrangements for stirring or circulating the electrolyte
- H01M50/77—Arrangements for stirring or circulating the electrolyte with external circulating path
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Filling, Topping-Up Batteries (AREA)
- Secondary Cells (AREA)
- Hybrid Cells (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP61176588A JPS6334851A (ja) | 1986-07-29 | 1986-07-29 | 亜鉛のデンドライト抑制方法 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP61176588A JPS6334851A (ja) | 1986-07-29 | 1986-07-29 | 亜鉛のデンドライト抑制方法 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS6334851A true JPS6334851A (ja) | 1988-02-15 |
| JPH0413832B2 JPH0413832B2 (enrdf_load_stackoverflow) | 1992-03-10 |
Family
ID=16016187
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP61176588A Granted JPS6334851A (ja) | 1986-07-29 | 1986-07-29 | 亜鉛のデンドライト抑制方法 |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS6334851A (enrdf_load_stackoverflow) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2017506811A (ja) * | 2014-02-27 | 2017-03-09 | ヴィズン エナジー システムズ インコーポレーテッドＶｉｚｎ Ｅｎｅｒｇｙ Ｓｙｓｔｅｍｓ， Ｉｎｃ． | シャント電流カウンター電極を有するフローセル |
| JP2018037275A (ja) * | 2016-08-31 | 2018-03-08 | 京セラ株式会社 | フロー電池 |
| JP2018512719A (ja) * | 2015-03-19 | 2018-05-17 | プリマス パワー コーポレイション | キレート剤および金属めっき促進剤を含むフロー電池電解質組成物 |
| CN109786870A (zh) * | 2018-12-25 | 2019-05-21 | 上海力信能源科技有限责任公司 | 一种减少锂电池析锂的方法 |
| JP2019102245A (ja) * | 2017-11-30 | 2019-06-24 | 京セラ株式会社 | 二次電池およびフロー電池 |
-
1986
- 1986-07-29 JP JP61176588A patent/JPS6334851A/ja active Granted
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2017506811A (ja) * | 2014-02-27 | 2017-03-09 | ヴィズン エナジー システムズ インコーポレーテッドＶｉｚｎ Ｅｎｅｒｇｙ Ｓｙｓｔｅｍｓ， Ｉｎｃ． | シャント電流カウンター電極を有するフローセル |
| JP2018512719A (ja) * | 2015-03-19 | 2018-05-17 | プリマス パワー コーポレイション | キレート剤および金属めっき促進剤を含むフロー電池電解質組成物 |
| JP2018037275A (ja) * | 2016-08-31 | 2018-03-08 | 京セラ株式会社 | フロー電池 |
| JP2019102245A (ja) * | 2017-11-30 | 2019-06-24 | 京セラ株式会社 | 二次電池およびフロー電池 |
| CN109786870A (zh) * | 2018-12-25 | 2019-05-21 | 上海力信能源科技有限责任公司 | 一种减少锂电池析锂的方法 |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0413832B2 (enrdf_load_stackoverflow) | 1992-03-10 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| S111 | Request for change of ownership or part of ownership |
Free format text: JAPANESE INTERMEDIATE CODE: R313111 |
|
| R350 | Written notification of registration of transfer |
Free format text: JAPANESE INTERMEDIATE CODE: R350 |
|
| LAPS | Cancellation because of no payment of annual fees |