JPS6332421B2 - - Google Patents
Info
- Publication number
- JPS6332421B2 JPS6332421B2 JP53106860A JP10686078A JPS6332421B2 JP S6332421 B2 JPS6332421 B2 JP S6332421B2 JP 53106860 A JP53106860 A JP 53106860A JP 10686078 A JP10686078 A JP 10686078A JP S6332421 B2 JPS6332421 B2 JP S6332421B2
- Authority
- JP
- Japan
- Prior art keywords
- oil
- weight
- fatty acid
- acid ester
- fat
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000003921 oil Substances 0.000 claims description 71
- 239000000203 mixture Substances 0.000 claims description 70
- -1 glycerin fatty acid ester Chemical class 0.000 claims description 51
- 239000003925 fat Substances 0.000 claims description 48
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 39
- 239000000194 fatty acid Substances 0.000 claims description 39
- 229930195729 fatty acid Natural products 0.000 claims description 39
- 239000006071 cream Substances 0.000 claims description 37
- 229930006000 Sucrose Natural products 0.000 claims description 36
- 239000003995 emulsifying agent Substances 0.000 claims description 35
- 239000005720 sucrose Substances 0.000 claims description 33
- 238000005187 foaming Methods 0.000 claims description 29
- 239000007787 solid Substances 0.000 claims description 22
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerol Natural products OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 19
- 235000021122 unsaturated fatty acids Nutrition 0.000 claims description 18
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 17
- 235000013336 milk Nutrition 0.000 claims description 16
- 239000008267 milk Substances 0.000 claims description 16
- 210000004080 milk Anatomy 0.000 claims description 16
- 239000008346 aqueous phase Substances 0.000 claims description 14
- 235000013861 fat-free Nutrition 0.000 claims description 14
- 235000011187 glycerol Nutrition 0.000 claims description 13
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 claims description 9
- 229910052740 iodine Inorganic materials 0.000 claims description 9
- 239000011630 iodine Substances 0.000 claims description 9
- 150000003904 phospholipids Chemical class 0.000 claims description 9
- 235000000346 sugar Nutrition 0.000 claims description 9
- 150000001720 carbohydrates Chemical class 0.000 claims description 6
- 150000008163 sugars Chemical class 0.000 claims description 6
- 235000019198 oils Nutrition 0.000 description 58
- 235000019197 fats Nutrition 0.000 description 39
- 239000006260 foam Substances 0.000 description 16
- 239000003240 coconut oil Substances 0.000 description 14
- 235000019864 coconut oil Nutrition 0.000 description 14
- 230000014759 maintenance of location Effects 0.000 description 13
- 238000002844 melting Methods 0.000 description 10
- 230000008018 melting Effects 0.000 description 10
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- 239000000843 powder Substances 0.000 description 8
- 238000004519 manufacturing process Methods 0.000 description 7
- 239000012071 phase Substances 0.000 description 7
- JLPULHDHAOZNQI-ZTIMHPMXSA-N 1-hexadecanoyl-2-(9Z,12Z-octadecadienoyl)-sn-glycero-3-phosphocholine Chemical compound CCCCCCCCCCCCCCCC(=O)OC[C@H](COP([O-])(=O)OCC[N+](C)(C)C)OC(=O)CCCCCCC\C=C/C\C=C/CCCCC JLPULHDHAOZNQI-ZTIMHPMXSA-N 0.000 description 6
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 description 6
- 239000002253 acid Substances 0.000 description 6
- 150000002148 esters Chemical class 0.000 description 6
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- 229940083466 soybean lecithin Drugs 0.000 description 6
- 239000001577 tetrasodium phosphonato phosphate Substances 0.000 description 6
- 239000000796 flavoring agent Substances 0.000 description 5
- 235000019634 flavors Nutrition 0.000 description 5
- 235000019982 sodium hexametaphosphate Nutrition 0.000 description 5
- GCLGEJMYGQKIIW-UHFFFAOYSA-H sodium hexametaphosphate Chemical compound [Na]OP1(=O)OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])O1 GCLGEJMYGQKIIW-UHFFFAOYSA-H 0.000 description 5
- 239000003381 stabilizer Substances 0.000 description 5
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- 150000004670 unsaturated fatty acids Chemical class 0.000 description 5
- 239000007762 w/o emulsion Substances 0.000 description 5
- OWEGMIWEEQEYGQ-UHFFFAOYSA-N 100676-05-9 Natural products OC1C(O)C(O)C(CO)OC1OCC1C(O)C(O)C(O)C(OC2C(OC(O)C(O)C2O)CO)O1 OWEGMIWEEQEYGQ-UHFFFAOYSA-N 0.000 description 4
- 108010010803 Gelatin Proteins 0.000 description 4
- GUBGYTABKSRVRQ-PICCSMPSSA-N Maltose Natural products O[C@@H]1[C@@H](O)[C@H](O)[C@@H](CO)O[C@@H]1O[C@@H]1[C@@H](CO)OC(O)[C@H](O)[C@H]1O GUBGYTABKSRVRQ-PICCSMPSSA-N 0.000 description 4
- 125000004432 carbon atom Chemical group C* 0.000 description 4
- 235000009508 confectionery Nutrition 0.000 description 4
- 238000005034 decoration Methods 0.000 description 4
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- 235000019322 gelatine Nutrition 0.000 description 4
- 235000011852 gelatine desserts Nutrition 0.000 description 4
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- 238000002156 mixing Methods 0.000 description 4
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- 150000004671 saturated fatty acids Chemical class 0.000 description 4
- 102000011632 Caseins Human genes 0.000 description 3
- 108010076119 Caseins Proteins 0.000 description 3
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 3
- 229910019142 PO4 Inorganic materials 0.000 description 3
- 239000005862 Whey Substances 0.000 description 3
- 102000007544 Whey Proteins Human genes 0.000 description 3
- 108010046377 Whey Proteins Proteins 0.000 description 3
- 240000008042 Zea mays Species 0.000 description 3
- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 description 3
- 235000002017 Zea mays subsp mays Nutrition 0.000 description 3
- 235000015155 buttermilk Nutrition 0.000 description 3
- 235000010418 carrageenan Nutrition 0.000 description 3
- 239000000679 carrageenan Substances 0.000 description 3
- 229920001525 carrageenan Polymers 0.000 description 3
- 229940113118 carrageenan Drugs 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
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- 235000005822 corn Nutrition 0.000 description 3
- 238000002845 discoloration Methods 0.000 description 3
- ZQPPMHVWECSIRJ-MDZDMXLPSA-N elaidic acid Chemical compound CCCCCCCC\C=C\CCCCCCCC(O)=O ZQPPMHVWECSIRJ-MDZDMXLPSA-N 0.000 description 3
- 238000004945 emulsification Methods 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 3
- 239000003346 palm kernel oil Substances 0.000 description 3
- 235000019865 palm kernel oil Nutrition 0.000 description 3
- 235000021317 phosphate Nutrition 0.000 description 3
- 235000003441 saturated fatty acids Nutrition 0.000 description 3
- 230000001954 sterilising effect Effects 0.000 description 3
- 238000010257 thawing Methods 0.000 description 3
- UHVMMEOXYDMDKI-JKYCWFKZSA-L zinc;1-(5-cyanopyridin-2-yl)-3-[(1s,2s)-2-(6-fluoro-2-hydroxy-3-propanoylphenyl)cyclopropyl]urea;diacetate Chemical compound [Zn+2].CC([O-])=O.CC([O-])=O.CCC(=O)C1=CC=C(F)C([C@H]2[C@H](C2)NC(=O)NC=2N=CC(=CC=2)C#N)=C1O UHVMMEOXYDMDKI-JKYCWFKZSA-L 0.000 description 3
- JNYAEWCLZODPBN-JGWLITMVSA-N (2r,3r,4s)-2-[(1r)-1,2-dihydroxyethyl]oxolane-3,4-diol Chemical compound OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O JNYAEWCLZODPBN-JGWLITMVSA-N 0.000 description 2
- OYHQOLUKZRVURQ-NTGFUMLPSA-N (9Z,12Z)-9,10,12,13-tetratritiooctadeca-9,12-dienoic acid Chemical compound C(CCCCCCC\C(=C(/C\C(=C(/CCCCC)\[3H])\[3H])\[3H])\[3H])(=O)O OYHQOLUKZRVURQ-NTGFUMLPSA-N 0.000 description 2
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 2
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 2
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 2
- 235000003301 Ceiba pentandra Nutrition 0.000 description 2
- 244000146553 Ceiba pentandra Species 0.000 description 2
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 2
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 description 2
- 102000002322 Egg Proteins Human genes 0.000 description 2
- 108010000912 Egg Proteins Proteins 0.000 description 2
- 241001465754 Metazoa Species 0.000 description 2
- 239000005642 Oleic acid Substances 0.000 description 2
- 240000007594 Oryza sativa Species 0.000 description 2
- 235000007164 Oryza sativa Nutrition 0.000 description 2
- 235000021314 Palmitic acid Nutrition 0.000 description 2
- 235000019484 Rapeseed oil Nutrition 0.000 description 2
- 235000019485 Safflower oil Nutrition 0.000 description 2
- 235000021355 Stearic acid Nutrition 0.000 description 2
- 235000019486 Sunflower oil Nutrition 0.000 description 2
- 230000032683 aging Effects 0.000 description 2
- 239000010775 animal oil Substances 0.000 description 2
- 235000020186 condensed milk Nutrition 0.000 description 2
- 235000005687 corn oil Nutrition 0.000 description 2
- 239000002285 corn oil Substances 0.000 description 2
- 235000012343 cottonseed oil Nutrition 0.000 description 2
- 239000002385 cottonseed oil Substances 0.000 description 2
- 238000009826 distribution Methods 0.000 description 2
- UKMSUNONTOPOIO-UHFFFAOYSA-N docosanoic acid Chemical compound CCCCCCCCCCCCCCCCCCCCCC(O)=O UKMSUNONTOPOIO-UHFFFAOYSA-N 0.000 description 2
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 235000013345 egg yolk Nutrition 0.000 description 2
- 210000002969 egg yolk Anatomy 0.000 description 2
- 235000021323 fish oil Nutrition 0.000 description 2
- 235000019866 hydrogenated palm kernel oil Nutrition 0.000 description 2
- VKOBVWXKNCXXDE-UHFFFAOYSA-N icosanoic acid Chemical compound CCCCCCCCCCCCCCCCCCCC(O)=O VKOBVWXKNCXXDE-UHFFFAOYSA-N 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 239000000155 melt Substances 0.000 description 2
- 244000005700 microbiome Species 0.000 description 2
- WQEPLUUGTLDZJY-UHFFFAOYSA-N n-Pentadecanoic acid Natural products CCCCCCCCCCCCCCC(O)=O WQEPLUUGTLDZJY-UHFFFAOYSA-N 0.000 description 2
- 239000007764 o/w emulsion Substances 0.000 description 2
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 2
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 2
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 2
- 229920000728 polyester Polymers 0.000 description 2
- 235000008476 powdered milk Nutrition 0.000 description 2
- 238000010791 quenching Methods 0.000 description 2
- 230000000171 quenching effect Effects 0.000 description 2
- 235000009566 rice Nutrition 0.000 description 2
- 235000005713 safflower oil Nutrition 0.000 description 2
- 239000003813 safflower oil Substances 0.000 description 2
- 229920006395 saturated elastomer Polymers 0.000 description 2
- 229940080237 sodium caseinate Drugs 0.000 description 2
- 239000000600 sorbitol Substances 0.000 description 2
- 239000003549 soybean oil Substances 0.000 description 2
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- 239000008117 stearic acid Substances 0.000 description 2
- 238000004659 sterilization and disinfection Methods 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 239000002600 sunflower oil Substances 0.000 description 2
- 229940082892 tamarind seed extract Drugs 0.000 description 2
- 235000015112 vegetable and seed oil Nutrition 0.000 description 2
- 239000008158 vegetable oil Substances 0.000 description 2
- 239000010698 whale oil Substances 0.000 description 2
- TZCPCKNHXULUIY-RGULYWFUSA-N 1,2-distearoyl-sn-glycero-3-phosphoserine Chemical compound CCCCCCCCCCCCCCCCCC(=O)OC[C@H](COP(O)(=O)OC[C@H](N)C(O)=O)OC(=O)CCCCCCCCCCCCCCCCC TZCPCKNHXULUIY-RGULYWFUSA-N 0.000 description 1
- IXPNQXFRVYWDDI-UHFFFAOYSA-N 1-methyl-2,4-dioxo-1,3-diazinane-5-carboximidamide Chemical compound CN1CC(C(N)=N)C(=O)NC1=O IXPNQXFRVYWDDI-UHFFFAOYSA-N 0.000 description 1
- IIZPXYDJLKNOIY-JXPKJXOSSA-N 1-palmitoyl-2-arachidonoyl-sn-glycero-3-phosphocholine Chemical compound CCCCCCCCCCCCCCCC(=O)OC[C@H](COP([O-])(=O)OCC[N+](C)(C)C)OC(=O)CCC\C=C/C\C=C/C\C=C/C\C=C/CCCCC IIZPXYDJLKNOIY-JXPKJXOSSA-N 0.000 description 1
- MOMKYJPSVWEWPM-UHFFFAOYSA-N 4-(chloromethyl)-2-(4-methylphenyl)-1,3-thiazole Chemical compound C1=CC(C)=CC=C1C1=NC(CCl)=CS1 MOMKYJPSVWEWPM-UHFFFAOYSA-N 0.000 description 1
- GUBGYTABKSRVRQ-XLOQQCSPSA-N Alpha-Lactose Chemical compound O[C@@H]1[C@@H](O)[C@@H](O)[C@@H](CO)O[C@H]1O[C@@H]1[C@@H](CO)O[C@H](O)[C@H](O)[C@H]1O GUBGYTABKSRVRQ-XLOQQCSPSA-N 0.000 description 1
- 235000021357 Behenic acid Nutrition 0.000 description 1
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- KRKNYBCHXYNGOX-UHFFFAOYSA-K Citrate Chemical compound [O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O KRKNYBCHXYNGOX-UHFFFAOYSA-K 0.000 description 1
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- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 1
- JZNWSCPGTDBMEW-UHFFFAOYSA-N Glycerophosphorylethanolamin Natural products NCCOP(O)(=O)OCC(O)CO JZNWSCPGTDBMEW-UHFFFAOYSA-N 0.000 description 1
- ZWZWYGMENQVNFU-UHFFFAOYSA-N Glycerophosphorylserin Natural products OC(=O)C(N)COP(O)(=O)OCC(O)CO ZWZWYGMENQVNFU-UHFFFAOYSA-N 0.000 description 1
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- SQUHHTBVTRBESD-UHFFFAOYSA-N Hexa-Ac-myo-Inositol Natural products CC(=O)OC1C(OC(C)=O)C(OC(C)=O)C(OC(C)=O)C(OC(C)=O)C1OC(C)=O SQUHHTBVTRBESD-UHFFFAOYSA-N 0.000 description 1
- GUBGYTABKSRVRQ-QKKXKWKRSA-N Lactose Natural products OC[C@H]1O[C@@H](O[C@H]2[C@H](O)[C@@H](O)C(O)O[C@@H]2CO)[C@H](O)[C@@H](O)[C@H]1O GUBGYTABKSRVRQ-QKKXKWKRSA-N 0.000 description 1
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- GUBGYTABKSRVRQ-QUYVBRFLSA-N beta-maltose Chemical compound OC[C@H]1O[C@H](O[C@H]2[C@H](O)[C@@H](O)[C@H](O)O[C@@H]2CO)[C@H](O)[C@@H](O)[C@@H]1O GUBGYTABKSRVRQ-QUYVBRFLSA-N 0.000 description 1
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- BECPQYXYKAMYBN-UHFFFAOYSA-N casein, tech. Chemical compound NCCCCC(C(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(CC(C)C)N=C(O)C(CCC(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(C(C)O)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(COP(O)(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(N)CC1=CC=CC=C1 BECPQYXYKAMYBN-UHFFFAOYSA-N 0.000 description 1
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- GPRLSGONYQIRFK-UHFFFAOYSA-N hydron Chemical compound [H+] GPRLSGONYQIRFK-UHFFFAOYSA-N 0.000 description 1
- CDAISMWEOUEBRE-GPIVLXJGSA-N inositol Chemical compound O[C@H]1[C@H](O)[C@@H](O)[C@H](O)[C@H](O)[C@@H]1O CDAISMWEOUEBRE-GPIVLXJGSA-N 0.000 description 1
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- MOYKHGMNXAOIAT-JGWLITMVSA-N isosorbide dinitrate Chemical compound [O-][N+](=O)O[C@H]1CO[C@@H]2[C@H](O[N+](=O)[O-])CO[C@@H]21 MOYKHGMNXAOIAT-JGWLITMVSA-N 0.000 description 1
- 239000008101 lactose Substances 0.000 description 1
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- 229940045641 monobasic sodium phosphate Drugs 0.000 description 1
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- 229920001206 natural gum Polymers 0.000 description 1
- 229920001542 oligosaccharide Polymers 0.000 description 1
- 150000002482 oligosaccharides Chemical class 0.000 description 1
- 239000002540 palm oil Substances 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- WTJKGGKOPKCXLL-RRHRGVEJSA-N phosphatidylcholine Chemical compound CCCCCCCCCCCCCCCC(=O)OC[C@H](COP([O-])(=O)OCC[N+](C)(C)C)OC(=O)CCCCCCCC=CCCCCCCCC WTJKGGKOPKCXLL-RRHRGVEJSA-N 0.000 description 1
- 150000008104 phosphatidylethanolamines Chemical class 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- CDAISMWEOUEBRE-UHFFFAOYSA-N scyllo-inosotol Natural products OC1C(O)C(O)C(O)C(O)C1O CDAISMWEOUEBRE-UHFFFAOYSA-N 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 230000021148 sequestering of metal ion Effects 0.000 description 1
- 238000004904 shortening Methods 0.000 description 1
- 235000010413 sodium alginate Nutrition 0.000 description 1
- 239000000661 sodium alginate Substances 0.000 description 1
- 229940005550 sodium alginate Drugs 0.000 description 1
- AJPJDKMHJJGVTQ-UHFFFAOYSA-M sodium dihydrogen phosphate Chemical compound [Na+].OP(O)([O-])=O AJPJDKMHJJGVTQ-UHFFFAOYSA-M 0.000 description 1
- FQENQNTWSFEDLI-UHFFFAOYSA-J sodium diphosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])([O-])=O FQENQNTWSFEDLI-UHFFFAOYSA-J 0.000 description 1
- 235000019983 sodium metaphosphate Nutrition 0.000 description 1
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- 229940048086 sodium pyrophosphate Drugs 0.000 description 1
- 235000019710 soybean protein Nutrition 0.000 description 1
- 230000000087 stabilizing effect Effects 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000003760 tallow Substances 0.000 description 1
- TUNFSRHWOTWDNC-HKGQFRNVSA-N tetradecanoic acid Chemical compound CCCCCCCCCCCCC[14C](O)=O TUNFSRHWOTWDNC-HKGQFRNVSA-N 0.000 description 1
- 235000019818 tetrasodium diphosphate Nutrition 0.000 description 1
- 150000005691 triesters Chemical class 0.000 description 1
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 description 1
Landscapes
- Grain Derivatives (AREA)
- Edible Oils And Fats (AREA)
Description
【発明の詳細な説明】
本発明はクリーム状の起泡性水中油型乳化脂お
よびその製法ならびに該乳化脂製造用油脂組成物
およびその製法に関するもので、詳しくは流通保
管中の粘度増加が少なく、機械的な起泡において
作業性がよく、高い起泡性を有し、しかも起泡後
の保形性、口どけ性にすぐれ、また起泡後の凍結
処理においてほとんど品質の劣化がないクリーム
状の起泡性乳化脂および該乳化脂製造用油脂組成
物および、それらの製法に関するものである。DETAILED DESCRIPTION OF THE INVENTION The present invention relates to a creamy foamable oil-in-water emulsified fat and a method for producing the same, as well as an oil and fat composition for producing the emulsified fat and a method for producing the same. A cream that has good workability in mechanical foaming, high foaming properties, excellent shape retention and melting properties after foaming, and almost no quality deterioration during freezing treatment after foaming. The present invention relates to foamable emulsified fats, oil and fat compositions for producing the emulsified fats, and methods for producing them.
近年、洋生菓子類の伸長に伴ない、洋生菓子類
のトツピング、フイリング材料として使用される
生クリーム類の使用量も著しく伸長している。 In recent years, along with the growth in Western fresh confectionery, the amount of fresh cream used as a topping and filling material for Western fresh confectionery has also increased significantly.
トツピングフイリング材料としては、当初は生
クリームが用いられていたが、国内の乳資源の不
足、これに伴う価格の高騰、また生クリームは風
味においては優秀であるが、起泡する場合、機械
的適性が十分でなく、起泡の終点の幅が狭いため
にしばしば失敗し、起泡に熟練を要するうえ、起
泡後のクリームは保形性に乏しく、温度の変化や
輸送の際の振動により型崩れを起こし商品価値を
減じたり、消泡して気泡を失い黄変化するなどの
欠点を有していることなどから、近年生クリーム
と動植物油脂、無脂乳固形分、乳化剤、安定剤等
から製造されるフイルドクリームを混合して用い
たり、また上記のごときフイルドクリームそのも
ののみで生クリームを代替したり、さらに、生ク
リームと上記のごとき原料とからコンパウンドク
リームを製造して生クリームと代替することが行
われている。 Initially, fresh cream was used as the filling material for toppings, but due to the lack of domestic milk resources and the resulting rise in prices, fresh cream has an excellent flavor, but when foaming, The foaming process often fails due to insufficient mechanical suitability and the narrow width of the foaming end point. In addition, foaming requires skill, and the cream after foaming has poor shape retention and is susceptible to temperature changes and transportation. In recent years, fresh cream, animal and vegetable oils, non-fat milk solids, emulsifiers, and stabilizers have been developed due to drawbacks such as losing its shape due to vibration, reducing product value, and losing air bubbles and turning yellow. It is possible to use a mixture of filled cream produced from such ingredients, to replace fresh cream with the above-mentioned filled cream itself, or to make compound cream from fresh cream and the above-mentioned raw materials. It is being replaced with
しかしながら、これらのフイルドクリームまた
はコンパウンドクリームは現在のところ大部分が
油分45重量%前後を含有し、オーバーランが80〜
130%の範囲のものであり低油分高起泡性のクリ
ーム類としてはほとんど見るべきものがない。低
油分高起泡性クリームは経済性に優れているほ
か、低油分に伴うローカロリー、耐凍結性、高起
泡性に伴う口あたりの軽さという点およびホイツ
プ時の終点幅の広さが特長となりうるものであ
る。 However, most of these filled creams or compound creams currently contain around 45% oil by weight and have an overrun of 80~80% by weight.
It is in the range of 130%, which is almost nothing to see as a low oil content high foaming cream. Low-oil, high-foaming creams are not only economical, but also low in calories due to their low oil content, freeze-resistant, light in the mouth due to their high-foaming properties, and have a wide finishing point when whipped. This can be a feature.
低油分クリームといえば、本邦ではコーヒーホ
ワイトナーが大部分であり、このコーヒーホワイ
トは起泡性は全くないかまたは起泡性はあつても
その保形性において全く不良であつた。また一部
トツピング用低油分クリームも上市されてはいる
が、気泡の安定性および、低油分のゆえに高融点
の油脂を使わざるを得なかつたという技術的欠陥
からくる口どけの悪さという点とから不十分なも
のでしかなかつた。 When it comes to low-oil creams, most in Japan are coffee whiteners, and this coffee white either has no foaming properties, or even if it does have foaming properties, its shape retention is completely poor. In addition, some low-oil creams for toppings have been put on the market, but they suffer from poor texture due to the stability of the air bubbles and technical flaws such as having to use high-melting-point oils due to the low oil content. It was simply inadequate.
本発明は上記のごとき従来のクリーム状組成物
に改良を加え、オーバーラン150〜200%という高
い起泡性を保有し、かつその気泡が安定でありし
かも良好な口どけ性および広い起泡終点幅を有す
るようなものを提供することを目的とするもので
ある。 The present invention has improved the conventional cream composition as described above, and has a high foaming property with an overrun of 150 to 200%, stable bubbles, good meltability in the mouth, and a wide foaming end point. The purpose is to provide something with a wide range of width.
すなわち本発明はクリーム状組成物およびその
製造に適した油脂組成物に関するもので、本発明
の油脂組成物は、5℃における固体脂指数
(SFI)が55〜65、かつ20℃におけるSFIが30〜
45、かつ30℃におけるSFIが7以下である油脂
と、(A)ヨウ素価20以下のグリセリン脂肪酸エステ
ルと(B)ソルビタン不飽和脂肪酸エステルおよび/
または燐脂質と(C)蔗糖脂肪酸エステル〔但し、蔗
糖脂肪酸エステルの量については、式y=a/5x
(但し、aは使用される蔗糖脂肪酸エステルの
HLB、xは使用される蔗糖脂肪酸エステルの重
量、yは換算した量)で換算した量で算出、以下
同じ〕からなる乳化剤とを含有し、乳化剤の合計
量が油脂に対して1.5〜4重量%であつて、(A)が
乳化剤合計量に対して5〜50重量%かつ(B)が乳化
剤合計量に対して10〜50重量%かつ(C)が乳化剤合
計量に対して25〜80重量%であることを特徴と
し、また本発明のクリーム状組成物は、5℃にお
けるSFIが55〜65、かつ20℃におけるSFIが30〜
45、かつ30℃におけるSFIが7以下である油脂
と、(A)ヨウ素価20以下のグリセリン脂肪酸エステ
ルと(B)ソルビタン不飽和脂肪酸エステルおよび/
または燐脂質と(C)蔗糖脂肪酸エステル〔但し、蔗
糖脂肪酸エステルの量については、式y=a/5x
(但し、aは使用される蔗糖脂肪酸エステルの
HLB、xは使用される蔗糖脂肪酸エステルの重
量、yは換算した量)で換算した量で算出、以下
同じ〕からなる乳化剤と、水と、糖類と、無脂乳
固形分とを含有する水中油型乳化脂で、油脂が全
体に対して20〜30重量%、水が全体に対して45〜
65重量%、糖類が全体に対して10〜30重量%、無
脂乳固形分が全体に対して0.5〜7重量%、乳化
剤の合計量が油脂に対して1.5〜4重量%、(A)が
乳化剤合計量に対して5〜50重量%かつ(B)が乳化
剤合計量に対して10〜50重量%かつ(C)が乳化剤合
計量に対して25〜80重量%であることを特徴とす
る。 That is, the present invention relates to a cream composition and an oil or fat composition suitable for producing the same. ~
45 and an SFI of 7 or less at 30°C, (A) glycerin fatty acid ester with an iodine value of 20 or less, (B) sorbitan unsaturated fatty acid ester and/or
or phospholipid and (C) sucrose fatty acid ester [However, regarding the amount of sucrose fatty acid ester, the formula y = a / 5x (where a is the amount of sucrose fatty acid ester used)
HLB, x is the weight of the sucrose fatty acid ester used, y is the converted amount); %, where (A) is 5 to 50% by weight based on the total amount of emulsifier, (B) is 10 to 50% by weight based on the total amount of emulsifier, and (C) is 25 to 80% by weight based on the total amount of emulsifier. % by weight, and the cream composition of the present invention has an SFI of 55 to 65 at 5°C and an SFI of 30 to 65 at 20°C.
45 and an SFI of 7 or less at 30°C, (A) glycerin fatty acid ester with an iodine value of 20 or less, (B) sorbitan unsaturated fatty acid ester and/or
or phospholipid and (C) sucrose fatty acid ester [However, regarding the amount of sucrose fatty acid ester, the formula y = a / 5x (where a is the amount of sucrose fatty acid ester used)
HLB, x is the weight of the sucrose fatty acid ester used, y is the converted amount), the same applies hereinafter], water, sugar, and non-fat milk solids. It is an oil-type emulsified fat, with fats and oils being 20-30% by weight and water being 45-45% by weight.
65% by weight, saccharides 10-30% by weight, non-fat milk solids 0.5-7% by weight, total amount of emulsifiers 1.5-4% by weight based on fats and oils, (A) is 5 to 50% by weight based on the total amount of emulsifier, (B) is 10 to 50% by weight based on the total amount of emulsifier, and (C) is 25 to 80% by weight based on the total amount of emulsifier. do.
本発明に使用される油脂としては、動、植物油
脂およびそれらの硬化油脂の単独または2種以上
の混合物あるいはこれらのものに種々の化学的処
理および/または物理的処理を施したものであつ
て、5℃におけるSFIが55〜65、かつ20℃におけ
るSFIが30〜45、かつ30℃におけるSFIが7以下
であるものである。 The fats and oils used in the present invention include animal and vegetable oils, hydrogenated fats and oils, singly or a mixture of two or more thereof, or those that have been subjected to various chemical and/or physical treatments. , SFI at 5°C is 55 to 65, SFI at 20°C is 30 to 45, and SFI at 30°C is 7 or less.
かかる油脂としては、そのままで使用できる油
脂としては例えばヤシ油、パーム核油等があり、
硬化油として使用できる油脂としては例えばヤシ
硬化油、パーム核硬化油等があり、分別油として
使用できる油脂としては例えばヤシ油、ヤシ硬化
油、パーム核油、パーム核硬化油の分別油や、米
油、大豆油、ナタネ油、ひまわり油、サフラワー
油、コーン油、綿実油、カポツク油、鯨油、魚油
等の液体油脂の硬化油の分別油等があり、エステ
ル交換油として使用できる油脂としては、例え
ば、ヤシ油、ヤシ硬化油、パーム核油、パーム核
硬化油のエステル交換油や、米油、大豆油、ナタ
ネ油、ひまわり油、サフラワー油、コーン油、綿
実油、カポツク油、鯨油、魚油等の液体油脂の硬
化油のエステル交換油等をあげることができる。 Examples of such oils and fats that can be used as they are include coconut oil, palm kernel oil, etc.
Examples of oils and fats that can be used as hydrogenated oils include hydrogenated coconut oil and hydrogenated palm kernel oil. Examples of oils and fats that can be used as fractionated oils include coconut oil, hydrogenated coconut oil, palm kernel oil, and fractionated oil of palm kernel hydrogenated oil. Oils and fats that can be used as transesterified oils include fractionated hydrogenated oils of liquid oils such as rice oil, soybean oil, rapeseed oil, sunflower oil, safflower oil, corn oil, cottonseed oil, kapok oil, whale oil, and fish oil. For example, coconut oil, hydrogenated palm oil, palm kernel oil, transesterified oil of hydrogenated palm kernel oil, rice oil, soybean oil, rapeseed oil, sunflower oil, safflower oil, corn oil, cottonseed oil, kapok oil, whale oil, Examples include transesterified oils of hydrogenated oils and liquid fats and oils such as fish oils.
又、前記液体油脂の硬化油を分別後、エステル
交換した油脂や、前記液体油脂の硬化油をエステ
ル交換後、分別した油脂或いはこれらの2種以上
を混合した油脂を使用することができ、更にこれ
らの油脂に前記液体油脂や液体油脂の硬化油、牛
脂、ラード、乳脂等を混合してSFIを調節したも
のも使用することができる。 In addition, it is possible to use an oil or fat obtained by transesterifying the hydrogenated oil of the liquid oil or fat, an oil or fat obtained by transesterifying the hydrogenated oil of the liquid oil or fat, or a mixture of two or more of these, and further It is also possible to use these oils and fats mixed with the above-mentioned liquid oils, hydrogenated liquid oils, beef tallow, lard, milk fat, etc. to adjust the SFI.
本発明で使用される油脂の量は、クリーム状組
成物においては20〜30%(重量基準、以下同じ)
で好ましくは23〜30%である。20%未満では十分
な保形性をもつクリーム状組成物は得られず、30
%を越える場合はクリームの組織がかたいものに
なり、十分なオーバーランも得られなくなる。ま
た、かかる低油分条件下でも、常温で高いオーバ
ーランを保持し、十分な保形性を保たせかつ低温
での起泡の戻り現象を押えるため、また更には、
良好な口どけ性をもつクリーム状組成物を得るた
め、ある特定の固体脂指数(SFI)特性値を保有
することが必要である。 The amount of fats and oils used in the present invention is 20 to 30% (by weight, the same applies hereinafter) in cream compositions.
It is preferably 23 to 30%. If it is less than 20%, a cream composition with sufficient shape retention cannot be obtained;
If it exceeds %, the cream structure will become hard and sufficient overrun will not be obtained. In addition, even under such low oil content conditions, in order to maintain a high overrun at room temperature, maintain sufficient shape retention, and suppress the foaming return phenomenon at low temperatures,
In order to obtain a cream composition with good melting properties in the mouth, it is necessary to have a certain solid fat index (SFI) characteristic value.
すなわち5℃という低温では55〜65と非常に高
いSFIを、常温の20℃では30〜45という比較的高
めのSFIをかつ体温に近づく30℃では以下という
低いSFIを示し、口腔内で体温によつてすみやか
に溶解するため、良好な口どけ性を示すものであ
る。従来のフイルドクリーム、コンパウンドクリ
ーム類に使用される油脂のSFI特性値は、5℃で
40〜54、20℃で15〜20、30℃で3〜7というよう
になかなり傾斜のゆるい温度〜SFI曲線を示すも
のであつたが、これらのSFI特性では、良好な低
油分高起泡性のクリーム状組成物を得ることはで
きないのである。 In other words, it shows a very high SFI of 55 to 65 at a low temperature of 5℃, a relatively high SFI of 30 to 45 at room temperature of 20℃, and a low SFI of less than 30℃ at a temperature close to body temperature. Since it dissolves quickly, it exhibits good melt-in-the-mouth properties. The SFI characteristics of oils and fats used in conventional filled creams and compound creams are
40-54, 15-20 at 20℃, and 3-7 at 30℃, showing a fairly sloped temperature-SFI curve. Therefore, it is not possible to obtain a cream-like composition with a creamy texture.
本発明においては乳化剤としてグリセリン脂肪
酸エステル、燐脂質、ソルビタン不飽和脂肪酸エ
ステル、および蔗糖脂肪酸エステルを使用する。 In the present invention, glycerol fatty acid esters, phospholipids, sorbitan unsaturated fatty acid esters, and sucrose fatty acid esters are used as emulsifiers.
使用しうるグリセリン脂肪酸エステルとは、グ
リセリンと炭素原子数12〜22個の飽和および/ま
たは不飽和の脂肪酸エステル、好ましくは炭素原
子数16〜18個の脂肪酸との部分エステルで、モノ
エステルを主成分としそのヨウ素価が20以下のも
のである。 The glycerin fatty acid ester that can be used is a partial ester of glycerin and a saturated and/or unsaturated fatty acid ester having 12 to 22 carbon atoms, preferably a fatty acid having 16 to 18 carbon atoms, and mainly monoesters. The ingredients have an iodine value of 20 or less.
また本発明で使用される燐脂質とは、例えばフ
オスフアチジルコリン、フオスフアチジルエタノ
ールアミン、イノシトールフオスフアチド、フオ
スフアチジールセリン等をいいこれらは通常市販
されている大豆レシチン、卵黄レシチン、卵黄、
バターミルク等に含有されており、これらを燐脂
質の給源として使用すればよい。また本発明で使
用される蔗糖脂肪酸エステルとは蔗糖と炭素原子
数14〜22の飽和および/または不飽和の脂肪酸と
のモノ、ジ−およびポリエステルの混合物であ
る。またソルビタン不飽和脂肪酸エステルとは炭
素原子数16〜22個の不飽和脂肪酸あるいはそれと
飽和脂肪酸の混合物(不飽和脂肪酸を50重量%以
上、好ましくは70重量%以上含有するもの)とソ
ルビタン、あるいはソルビタンを主成分とし、ソ
ルビトール、ソルバイドを含有する混合物との部
分エステルでモノエステルを主成分とし、ジ−ま
たはトリエステル等のポリエステルを含有するも
のである。上記の各種の乳化剤を構成する飽和脂
肪酸としては例えばミリスチン酸、パルミチン
酸、ステアリン酸、ラウリン酸、アラキン酸、ベ
ヘン酸等があり、その中でも特にパルミチン酸、
ステアリン酸が好ましく、また不飽和脂肪酸とし
ては例えばオレイン酸、ゾーマリン酸、リノール
酸、エライジン酸、リノレイン酸等であり、その
中でも特に好ましいものはオレイン酸、ゾーマリ
ン酸である。また乳化剤の合計量は油脂に対して
1.5〜4重量%であることが必要であり、さらに
グリセリン脂肪酸エステルの量が乳化剤の合計量
に対して5〜50重量%で、ソルビタン不飽和脂肪
酸エステルおよび/または燐脂質の量が乳化剤の
合計量に対して10〜50重量%かつ蔗糖脂肪酸エス
テルの量が乳化剤の合計量に対して25〜80重量%
であることが必要である。 The phospholipids used in the present invention include, for example, phosphatidylcholine, phosphatidylethanolamine, inositol phosphatide, phosphatidylserine, etc. These include soybean lecithin, egg yolk, etc. lecithin, egg yolk,
It is contained in buttermilk and the like, and these can be used as a source of phospholipids. The sucrose fatty acid ester used in the present invention is a mixture of mono-, di- and polyesters of sucrose and saturated and/or unsaturated fatty acids having 14 to 22 carbon atoms. In addition, sorbitan unsaturated fatty acid ester refers to unsaturated fatty acids having 16 to 22 carbon atoms or a mixture of unsaturated fatty acids and saturated fatty acids (containing 50% by weight or more, preferably 70% by weight or more of unsaturated fatty acids), sorbitan, or sorbitan. The main component is a partial ester with a mixture containing sorbitol and sorbide, and the main component is a monoester, and it contains a polyester such as a di- or triester. Examples of saturated fatty acids constituting the various emulsifiers mentioned above include myristic acid, palmitic acid, stearic acid, lauric acid, arachidic acid, and behenic acid, among which palmitic acid,
Stearic acid is preferred, and unsaturated fatty acids include, for example, oleic acid, zomarinic acid, linoleic acid, elaidic acid, and linoleic acid, among which oleic acid and zomarinic acid are particularly preferred. Also, the total amount of emulsifier is
It is necessary that the amount of glycerin fatty acid ester is 5 to 50% by weight based on the total amount of emulsifier, and the amount of sorbitan unsaturated fatty acid ester and/or phospholipid is 1.5 to 4% by weight based on the total amount of emulsifier. The amount of sucrose fatty acid ester is 25-80% by weight based on the total amount of emulsifier.
It is necessary that
乳化剤の合計量に対するグリセリン脂肪酸エス
テルの量が50%を越えると起泡した際、高いオー
バーランは得られるが保形性の弱いものとなり、
5%を下回ると十分なオーバーランが得られな
い。また乳化剤の合計量に対するソルビタン不飽
和脂肪酸エステルおよび/または燐脂質の量が50
%を越えると、クリーム状組成物の粘度が著しく
高くなつたり、起泡後のクリームの組織がしまつ
た堅いものになりオーバーランも低いものになつ
たりする。また10%を下回ると高めのオーバーラ
ンは得られるが起泡体の保形性が弱く、造花した
ものが経時的にダレてきて好ましくない。また乳
化剤合計量に対する蔗糖脂肪酸エステルの量が80
重量%を越えると高いオーバーランは得られる
が、起泡時間が長くなりすぎ、起泡体の保形性が
悪く、特に冷蔵保存時の起泡の戻り現象が起つて
実用に供せない。逆に25重量%より少なくなる
と、高いオーバーランが得られず、起泡体も堅く
しまつたものとなつてしまう。さらに乳化剤の合
計量が油脂に対して1.5重量%より少なくなると
乳化が不安定で分離しやすくなりりかつ起泡性が
著しく悪くなる。また4重量%より多くなるとク
リーム状組成物の粘度が高くなり、固化しやす
く、起泡性も悪化し、また乳化剤がクリーム状組
成物の風味に悪影響をおよぼすことになり好まし
くない。 If the amount of glycerin fatty acid ester relative to the total amount of emulsifier exceeds 50%, a high overrun can be obtained when foaming occurs, but the shape retention will be weak.
If it is less than 5%, sufficient overrun cannot be obtained. In addition, the amount of sorbitan unsaturated fatty acid ester and/or phospholipid relative to the total amount of emulsifier is 50%.
If it exceeds %, the viscosity of the cream composition becomes extremely high, the structure of the cream after foaming becomes tight and hard, and the overrun becomes low. On the other hand, if it is less than 10%, a high overrun can be obtained, but the shape retention of the foam is weak and the artificial flowers will sag over time, which is not preferable. In addition, the amount of sucrose fatty acid ester relative to the total amount of emulsifier is 80%.
If it exceeds % by weight, a high overrun can be obtained, but the foaming time becomes too long, the shape retention of the foam is poor, and the foaming returns, especially during refrigerated storage, so that it cannot be put to practical use. On the other hand, if it is less than 25% by weight, a high overrun cannot be obtained and the foam will become hard and compact. Furthermore, if the total amount of emulsifier is less than 1.5% by weight based on the fat or oil, the emulsification becomes unstable and tends to separate, and the foaming properties deteriorate significantly. Moreover, if the amount exceeds 4% by weight, the viscosity of the cream composition becomes high, it is easy to solidify, the foamability deteriorates, and the emulsifier adversely affects the flavor of the cream composition, which is not preferable.
本発明のクリーム状組成物は無脂乳固形分を含
有する。かかる無脂乳固形分とは脂肪分を除いた
乳固形分のことで乳蛋白質を主成分とするもので
ある。かかる無脂乳固形分の給源としては、例え
ば牛乳等の獣乳、脱脂乳、練乳、脱脂練乳、粉
乳、脱脂粉乳、凍結濃縮脱脂乳、加糖濃縮バター
ミルク、粉末バターミルク、粉末ホエー、クリー
ムカゼイン、ナトリウムカゼイネート等があり、
無脂乳固形分の一部を大豆蛋白質等の植物性蛋白
質に置き換えることも可能である。また無脂乳固
形分の給源として脱脂粉乳、粉乳等を使用する場
合は種々のリン酸塩を添加することが好ましい。
リン酸塩には主としてその水素イオン濃度緩衝作
用、金属イオン封鎖作用、増粘防止作用等があり
乳化脂の品質安定に寄与し、必要に応じて適宜添
加する。かかるリン酸塩としては第1リン酸ナト
リウム、第2リン酸ナトリウム、第3リン酸ナト
リウム、メタリン酸ナトリウム、ポリリン酸ナト
リウム、ピロリン酸ナトリウム等が使用でき、ク
エン酸塩等の他の塩と併用することによつてより
一層効果を発揮する場合もある。 The creamy composition of the present invention contains non-fat milk solids. The non-fat milk solid content refers to milk solid content excluding fat content, and is mainly composed of milk protein. Sources of such non-fat milk solids include, for example, animal milk such as cow's milk, skim milk, condensed milk, skim condensed milk, powdered milk, skim milk powder, frozen concentrated skim milk, sweetened concentrated buttermilk, powdered buttermilk, powdered whey, cream casein. , sodium caseinate, etc.
It is also possible to replace part of the non-fat milk solids with vegetable protein such as soybean protein. Furthermore, when skim milk powder, powdered milk, etc. are used as a source of non-fat milk solids, it is preferable to add various phosphates.
Phosphate mainly has a hydrogen ion concentration buffering effect, a metal ion sequestering effect, an anti-thickening effect, etc., and contributes to stabilizing the quality of the emulsified fat, and is added as necessary. As such phosphates, monobasic sodium phosphate, dibasic sodium phosphate, tertiary sodium phosphate, sodium metaphosphate, sodium polyphosphate, sodium pyrophosphate, etc. can be used, and they can be used in combination with other salts such as citrate. In some cases, it may be even more effective.
発本明のクリーム状組成物中の無脂乳固形分の
量は風味上また乳化脂の粘度の点から全体に対し
て0.5〜7重量%特に3〜6%が好ましく、水の
量は全体に対して45〜65%が好ましい。 The amount of non-fat milk solids in the creamy composition of the present invention is preferably 0.5 to 7% by weight, particularly 3 to 6%, based on the whole from the viewpoint of flavor and viscosity of emulsified fat, and the amount of water is preferably 3 to 6%. 45 to 65% is preferable.
また本発明のクリーム状組成物に使用される糖
類としては、例えば蔗糖、果糖、ぶどう糖、乳
糖、麦芽糖、ソルビトール、転化糖、コーンシロ
ツプ、オリゴ糖等があり、これらの糖類の量とし
ては甘味の点からみて、例えば蔗糖のみの場合10
〜15%とするのが好ましいが、凍結用クリームと
して使用する際凍結時に生成する氷結晶の大きさ
をできるだけ小さくするため水相中の固形分量を
多くすることが好ましく、甘味度の低いコーンシ
ロツプ等を併用して糖類の量を15〜30重量%とす
ることが好ましい。また本発明の組成物は必要に
応じて安定剤を含ませることができる。安定剤は
クリーム状組成物の粘性を適度なものにして起泡
を助けたり、凍結処理時の安定性がさらに良好な
ものとなる。安定剤としては、例えばゼラチン、
カラギナン、タマリンド種子抽出物、グアーガム
等の天然ガム質、および例えばカルボキシメチル
セルロース、メチルセルロース、アルギン酸ソー
ダ等の合成ガム質等があり、安定剤の量はその種
類によつて若干異なるが0.05〜0.4重量%が好ま
しい。 Examples of sugars used in the creamy composition of the present invention include sucrose, fructose, glucose, lactose, maltose, sorbitol, invert sugar, corn syrup, and oligosaccharides, and the amount of these sugars depends on the sweetness. For example, in the case of only sucrose, it is 10
It is preferably ~15%, but when used as a freezing cream, it is preferable to increase the solid content in the aqueous phase in order to minimize the size of ice crystals generated during freezing. It is preferable to use saccharides in combination to make the amount of saccharides 15 to 30% by weight. Furthermore, the composition of the present invention may contain a stabilizer if necessary. The stabilizer moderates the viscosity of the cream composition, aids in foaming, and provides better stability during freezing treatment. Examples of stabilizers include gelatin,
There are natural gums such as carrageenan, tamarind seed extract, guar gum, and synthetic gums such as carboxymethylcellulose, methylcellulose, and sodium alginate.The amount of stabilizer varies slightly depending on the type, but is 0.05 to 0.4% by weight. is preferred.
本発明の組成物の製造法は以下の通りである。
まず、本発明の油脂組成物は原料油脂を溶融し、
それに乳化剤を溶解分散せしめるか、又は好まし
い方法として溶融された原料油脂に油溶性乳化剤
を添加して混合撹拌して乳化剤を溶解ないしは分
散せしめ、一方水溶性乳化剤および必要に応じて
糖類(その量はその濃度が70重量%以上、特に80
重量%以上となる量が好ましい。)を加え混合撹
拌して溶解せしめ、これらの油相75重量%以上と
水相25重量%以下好ましくは10〜20重量%を合わ
せ混合撹拌し油中水型乳化脂にするかして、その
後、例えばマーガリン、シヨートニング製造に使
用される急冷可塑化装置を通過せしめて急冷可塑
化することによつて製造できる。 The method for producing the composition of the present invention is as follows.
First, the oil and fat composition of the present invention is prepared by melting raw material oil and fat,
An emulsifier is dissolved or dispersed therein, or as a preferred method, an oil-soluble emulsifier is added to the melted raw material oil and fat, and mixed and stirred to dissolve or disperse the emulsifier, while a water-soluble emulsifier and sugars (the amount thereof is Its concentration is 70% by weight or more, especially 80%
The amount is preferably at least % by weight. ), mix and stir to dissolve, combine 75% by weight or more of the oil phase and 25% by weight or less, preferably 10 to 20% by weight of the aqueous phase, mix and stir to make a water-in-oil emulsified fat, and then For example, it can be produced by passing through a quenching and plasticizing apparatus used in the production of margarine and shortening to quenching and plasticizing it.
また本発明のクリーム状組成物は上記のように
して製造された油脂組成物を溶解した後、無脂乳
固形分を含有する水相と混合するか、あるいは原
料油脂を加温溶融したものに乳化剤の一部または
全部を加えるかまたは全く乳化剤を加えずに調製
された油相と、無脂乳固形分を含有する水相に乳
化剤の一部または全部を加えるかまたは全く乳化
剤を加えないものとを混合するかして水中油型の
エマルジヨンを形成し、これを例えば50〜70℃に
保持しながら、例えば高圧均質機を通して均質化
して製造することができる。 The creamy composition of the present invention can be prepared by dissolving the fat composition produced as described above and then mixing it with an aqueous phase containing non-fat milk solids, or by heating and melting the raw material fat. Oil phases prepared with some or all emulsifiers or no emulsifiers and aqueous phases containing non-fat milk solids with some or all emulsifiers or no emulsifiers added. An oil-in-water emulsion is formed by mixing the above-mentioned components, and this can be homogenized, for example, through a high-pressure homogenizer while maintaining the emulsion at a temperature of, for example, 50 to 70°C.
このようにして製造されたクリーム状組成物は
さらに例えば間接加熱式、直接加熱式の殺菌手段
で、バツチ的にあるいは連続的に殺菌して無菌的
に包装し、流通、保存に適した製品とすることも
もちろん可能である。 The creamy composition produced in this way is then sterilized in batches or continuously using sterilization methods such as indirect heating or direct heating, and packaged aseptically to make it a product suitable for distribution and storage. Of course, it is also possible to do so.
本発明のクリーム状組成物は製造工程中の諸条
件の振れにかかわらず、安定した品質のものが得
られ、流通保管中の室内外の温度変化や輸送によ
る振動等によつて増粘固化することなく、高い起
泡性を有し、起泡したときの起泡体の物性が常に
安定し、最適起泡状態に到達するまでの時間が一
定で起泡の終点に適当な幅があり、オーバーラン
は高く、しかも一定しており、その起泡体は十分
なコシ、ネバリがあり脱泡しにくく、経時的にバ
サつくことがなく、スムーズに一様に造花でき、
また保形性にすぐれ、乳漿分離を引き起さず、外
観もなめらかで光沢があり、それが経時的に変化
することがなく風味、口どけも良好であるもので
ある。また本発明のクリーム状組成物は製菓業者
がそれを購入し、解凍するだけで、常に新鮮な起
泡体をトツピング用、フイリング用、アイシング
用として使用できるような凍結された起泡クリー
ム状物の製造に適しており、また本発明のクリー
ム状組成物を起泡した起泡体で造花、ナツペ、サ
ンドされた菓子類を凍結保存した場合も該起泡体
に全く品質の劣化が起らず、洋菓子類の長期保
存、ひいてはその計画生産を可能にするものであ
る。 The creamy composition of the present invention can be obtained with stable quality regardless of fluctuations in various conditions during the manufacturing process, and will thicken and solidify due to indoor and outdoor temperature changes during distribution and storage, vibrations caused by transportation, etc. It has high foaming properties without foaming, the physical properties of the foamed product are always stable, the time to reach the optimal foaming state is constant, and the end point of foaming has an appropriate width. The overrun is high and constant, and the foam has sufficient firmness and stickiness, making it difficult to defoam, and it does not get loose over time, allowing you to create artificial flowers smoothly and uniformly.
In addition, it has excellent shape retention, does not cause whey separation, has a smooth and glossy appearance, does not change over time, and has a good flavor and melts in the mouth. The creamy composition of the present invention is a frozen foamed cream that can be used as a fresh foam for toppings, fillings, and icings by simply purchasing and thawing the creamy composition of the present invention. It is suitable for the production of foamed products made from the creamy composition of the present invention, and even when artificial flowers, natuppe, and sandwiched confectionery are frozen and preserved using the foamed material, there is no deterioration in the quality of the foamed material. First, it enables long-term storage of Western confectionery and, by extension, planned production thereof.
また本発明の油脂組成物は加熱溶融し無脂乳固
形分及び必要に応じて糖類を含有させた水相と合
わせ均質化するだけで良好なクリーム状の起泡性
水中油型乳化脂を得ることが可能なものである。
この油脂組成物は蔗糖脂肪酸エステルを含有する
ため常温ではカビ等の微生物による変質が避けら
れず冷蔵好ましくは冷凍保存が必要である。この
ような微生物による変質は糖類の濃度70重量%以
上、好ましくは80重量%以上の糖類水溶液からな
る水相を含有せしめることによつて防止され、常
温での保存が可能になる。 Further, the oil and fat composition of the present invention can be heated and melted, and a good creamy foamable oil-in-water emulsion can be obtained by simply homogenizing the mixture with non-fat milk solids and an aqueous phase containing sugars as necessary. It is possible.
Since this oil and fat composition contains a sucrose fatty acid ester, deterioration by microorganisms such as mold cannot be avoided at room temperature, so it must be stored refrigerated, preferably frozen. Such deterioration by microorganisms can be prevented by containing an aqueous phase consisting of an aqueous saccharide solution with a saccharide concentration of 70% by weight or more, preferably 80% by weight or more, and storage at room temperature becomes possible.
以下に本発明の実施例をあげ、さらに本発明を
詳細に説明する。例中の部は重量部である。 Examples of the present invention will be given below to further explain the present invention in detail. Parts in the examples are parts by weight.
実施例 1
上昇融点34℃のヤシ硬化油(SFIは5℃で63.5、
20℃で42.1、30℃で5.7)100部を加熱溶融しその
中にヨウ素価2のグリセリンモノ脂肪酸エステル
0.38部、ソルビタン不飽和脂肪酸エステル0.2部、
大豆レシチン0.3部、HLB2の蔗糖脂肪酸エステ
ル1.75部を添加し、これらを溶解ないし分散せし
めた油相と、20部の水にHLB7の蔗糖脂肪酸エス
テル0.75部を添加溶解せしめて水相となしたもの
を混合乳化し油中水型エマルジヨンとなした後ボ
テーターを通して急冷可塑化し油脂組成物を得
た。Example 1 Hydrogenated coconut oil with an elevated melting point of 34°C (SFI 63.5 at 5°C,
42.1 at 20℃, 5.7 at 30℃) 100 parts are heated and melted, and glycerin monofatty acid ester with an iodine value of 2 is contained in it.
0.38 parts, sorbitan unsaturated fatty acid ester 0.2 parts,
An oil phase prepared by adding 0.3 parts of soybean lecithin and 1.75 parts of HLB2 sucrose fatty acid ester and dissolving or dispersing them, and an aqueous phase obtained by adding and dissolving 0.75 parts of HLB7 sucrose fatty acid ester in 20 parts of water. The mixture was mixed and emulsified to form a water-in-oil emulsion, which was then rapidly cooled and plasticized through a votator to obtain an oil and fat composition.
実施例 2
実施例1で得た油脂組成物30部を溶融したもの
と、50部の水に4部の脱脂粉乳、10部のコーンシ
ロツプ固形分、5部の上白糖、0.1部のヘキサメ
タリン酸ソーダ、0.1部のゼラチンを溶解したも
のとを混合撹拌したのち均質圧力120Kg/cm2で均
質化し、プレート式殺菌装置で80℃で5分間殺菌
したのち、10℃まで冷却し、さらに5℃前後の冷
蔵庫中で15時間エージングしてクリーム状組成物
を得た。このクリーム状組成物は乳化時の温度の
ふれ、均質圧力のふれ、および殺菌条件のふれに
関係なくほぼ一定の品質のものが得られ、良好な
結果、耐振動性、および高起泡性を保有し、その
起泡体は保形性、外観ともに優れたもので風味、
口溶けも良好であつた。また起泡体を丸型デコレ
ーシヨンケーキにナツペ、トツピングして凍結解
凍処理したものは、ひびわれ、変色、しまりとも
なく良好であつた。Example 2 Melted 30 parts of the oil and fat composition obtained in Example 1, 50 parts of water, 4 parts of skim milk powder, 10 parts of corn syrup solids, 5 parts of white sugar, and 0.1 part of sodium hexametaphosphate. , 0.1 part of gelatin dissolved therein was mixed and stirred, homogenized at a homogenizing pressure of 120 kg/cm 2 , sterilized at 80°C for 5 minutes using a plate-type sterilizer, cooled to 10°C, and further heated to around 5°C. A creamy composition was obtained by aging in the refrigerator for 15 hours. This cream composition has almost constant quality regardless of temperature fluctuations during emulsification, homogeneous pressure fluctuations, and sterilization conditions fluctuations, and has good results, vibration resistance, and high foaming properties. The foam has excellent shape retention and appearance, and has great flavor and
It also melted well in the mouth. Furthermore, when the foam was added to a round decoration cake and subjected to freezing and thawing treatment, the cake was in good condition with no cracks, discoloration, or clumps.
実施例 3
上昇融点34℃のヤシ硬化油70部とヤシ油30部の
混合物(混合物のSFIは5℃で61.9、20℃で38.1、
30℃で4.0)を加熱溶融しその中にヨウ素価10の
グリセリンモノ脂肪酸エステル0.75部、ソルビタ
ン不飽和脂肪酸エステル0.2部、大豆レシチン0.8
部、HLB2の蔗糖脂肪酸エステル1.2部を添加し、
これらを溶解ないし分散せしめた油相と20部の水
にHLB11の蔗糖脂肪酸エステル0.5部を溶解せし
めて水相となしたものを混合乳化し油中水型エマ
ルジヨンとなした後ボテーターを通して急冷可塑
化し油脂組成物を得た。Example 3 A mixture of 70 parts of hydrogenated coconut oil and 30 parts of coconut oil with an elevated melting point of 34°C (SFI of the mixture is 61.9 at 5°C, 38.1 at 20°C,
4.0) at 30°C and contains 0.75 part of glycerin monofatty acid ester with an iodine value of 10, 0.2 part of sorbitan unsaturated fatty acid ester, and 0.8 part of soybean lecithin.
1.2 parts of HLB2 sucrose fatty acid ester,
An oil phase in which these were dissolved or dispersed and an aqueous phase obtained by dissolving 0.5 parts of sucrose fatty acid ester of HLB11 in 20 parts of water were mixed and emulsified to form a water-in-oil emulsion, and then passed through a votator to rapidly cool and plasticize. An oil and fat composition was obtained.
実施例 4
実施例3で得た油脂組成物30部を溶融したもの
と、50部の水に7.0部の脱脂粉乳、1.5部のホエイ
パウダー、0.5部のナトリウムカゼイネート、
0.05部のヘキサメタリン酸ソーダ、15部のハイマ
ルトースシロツプ固型分、0.05部のカラギナンを
溶解したものとを混合撹拌したのち40℃前後で均
質圧力30Kg/cm2で均質化したのち、VTIS殺菌機
(アルフアラバル社製UHT殺菌機)で140℃で3
秒間殺菌したのち70℃前後まで冷却、さらに再度
均質圧50Kg/cm2で均質化した。均質化後プレート
クーラーで10℃前後まで急冷しこのものを5℃の
冷蔵庫で18時間以上エージングした。これを30コ
ートケーキミキサーにて起泡したところオーバー
ラン185%のコシ、キメのよい起泡体が得られた。
またこの起泡体は保形性、外観ともすぐれたもの
で口どけは非常に良好であつた。また起泡体をそ
のままポリ袋に充填し−20℃前後の凍結庫で24時
間以上凍結し5℃内外の冷蔵庫で解凍したものも
良好なコシ、キメで造花が可能であつた。Example 4 A melt of 30 parts of the oil and fat composition obtained in Example 3, 7.0 parts of skim milk powder, 1.5 parts of whey powder, 0.5 parts of sodium caseinate in 50 parts of water,
A solution of 0.05 parts of sodium hexametaphosphate, 15 parts of high maltose syrup solids, and 0.05 parts of carrageenan was mixed and stirred, then homogenized at around 40°C with a homogenizing pressure of 30 kg/ cm2 , and then VTIS 3 at 140℃ with a sterilizer (UHT sterilizer manufactured by Alfa Arrabal)
After sterilizing for seconds, the mixture was cooled to around 70°C and homogenized again at a homogenizing pressure of 50 kg/cm 2 . After homogenization, the mixture was rapidly cooled to around 10°C in a plate cooler and aged in a refrigerator at 5°C for 18 hours or more. When this was foamed using a 30-coat cake mixer, a foam with a 185% overrun and good texture was obtained.
Moreover, this foam had excellent shape retention and appearance, and melted in the mouth very well. In addition, artificial flowers with good stiffness and texture were also possible by filling the foam into a plastic bag, freezing it in a freezer at around -20°C for 24 hours or more, and thawing it in a refrigerator at around 5°C.
実施例 5
上昇融点34℃のヤシ硬化油40部と同じく42℃の
ヤシ硬化油15部とヤシ油45部の混合物(混合物の
SFIは5℃で61.3、20℃で36.9、30℃で4.3)を加
熱溶融し、その中にヨウ素価2のグリセリンモノ
脂肪酸エステル0.5部、ソルビタン不飽和脂肪酸
エステル1.2部、HLB2の蔗糖脂肪酸エステル0.85
部を添加しこれらを溶解ないし分散せしめた油相
とし、これに水20部にハイマルトース固形分40
部、上白糖18部、タマリンド種子抽出物0.5部を
混合溶解したものを水相としたものを混合乳化し
油中水型エマルジヨンとなした後ボテーターを通
して急冷可塑化油脂組成物を得た。Example 5 A mixture of 40 parts of hydrogenated coconut oil with an elevated melting point of 34°C, 15 parts of hydrogenated coconut oil and 45 parts of coconut oil, also at 42°C (mixture of
SFI is 61.3 at 5°C, 36.9 at 20°C, and 4.3 at 30°C.
20 parts of water and 40 parts of high maltose solids are added to form an oil phase in which these are dissolved or dispersed.
A water-in-oil emulsion was prepared by mixing and dissolving 18 parts of white sugar, 18 parts of caster sugar, and 0.5 parts of tamarind seed extract into an aqueous phase, which was mixed and emulsified to form a water-in-oil emulsion, and then passed through a votator to obtain a quenched plasticized oil and fat composition.
実施例 6
実施例5で得た油脂組成物50部を溶融したもの
と45部の水に5部の脱脂粉乳、0.2部のHLB11の
蔗糖脂肪酸エステル、0.1部のゼラチン、0.1部の
ヘキサメタリン酸ソーダを溶解したものとを混合
撹拌したのち40℃前後で均質圧力30Kg/cm2で均質
化したのち、V.T.I.S殺菌機(アルフアラバル社
製UHT殺菌機)で140℃3秒間殺菌したのち70
℃前後まで冷却、さらに再度均質圧50Kg/cm2で均
質化した。均質化後プレートクーラーで10℃前後
まで急冷し、このものを5℃の冷蔵庫で18時間以
上エージングした。これを30コートケーキミキサ
ーにて起泡したところオーバーラン170%のコシ、
キメのよい起泡体が得られた。またこの起泡体は
保形性外観ともすぐれたもので口どけも良好であ
つた。またこの起泡体をデコレーシヨンケーキの
ナツペ、トツピング用として用い、凍結解凍処理
したものはひび割れ、変色、しまりともなく良好
であつた。Example 6 Melted 50 parts of the oil and fat composition obtained in Example 5, 45 parts of water, 5 parts of skim milk powder, 0.2 parts of HLB11 sucrose fatty acid ester, 0.1 part of gelatin, and 0.1 part of sodium hexametaphosphate. The mixture was mixed and stirred, then homogenized at around 40℃ with a homogenization pressure of 30Kg/cm 2 , and then sterilized at 140℃ for 3 seconds using a VTIS sterilizer (UHT sterilizer manufactured by Alfa Arabal).
The mixture was cooled to around ℃ and homogenized again at a homogenizing pressure of 50 kg/cm 2 . After homogenization, the mixture was rapidly cooled to around 10°C in a plate cooler, and then aged in a refrigerator at 5°C for 18 hours or more. When this was whipped with a 30 coat cake mixer, the overrun was 170%.
A foam with good texture was obtained. This foam also had excellent shape retention and appearance, and melted well in the mouth. Further, this foam was used as a topping for a decoration cake, and when it was frozen and thawed, it was in good condition with no cracks, discoloration, or clumps.
実施例 7
上昇融点34℃のヤシ硬化油20部とヤシ油5部の
混合物(混合物のSFIは5℃で62.3、20℃で39.3、
30℃で4.6)を加熱溶融しヨウ素価3のグリセリ
ンモノ脂肪酸エステル0.2部、大豆レシチン0.1
部、ソルビタン不飽和脂肪酸エステル0.1部、
HLB2の蔗糖脂肪酸エステル0.2部を加え分散溶
解せしめて油相となし、一方水49部に上白糖5
部、ハイマルトースシロツプ(水分25%を含有)
15部、カラギナン0.1部、脱脂粉乳5部、ヘキサ
メタリン酸ナトリウム0.1部、HLB11の蔗糖脂肪
酸エステル0.2部を分散溶解せしめたものを水相
となす。水相と油脂とを乳化温度45℃前後で混合
乳化し均質圧力40Kg/cm2で均質化したのちVTIS
殺菌機(アルフアラバル社UHT殺菌機)で140
℃3秒間殺菌した。これを70℃前後まで冷却、さ
らに再度均質圧力50Kg/cm2で均質化した。均質化
後プレートクーラーで10℃前後まで急冷し、この
ものを5℃の冷蔵庫で18時間以上エージングし
た。このものを30コートケーキミキサーにて起泡
したところオーバーラン165%のコシキメのよい
起泡体が得られた。この起泡体は保形性、外観と
もすぐれたもので口どけも良好であつた。またこ
の起泡体をデコレーシヨンケーキのナツペ、トツ
ピング用として用い、凍結解凍処理したものは、
ひび割れ変色しまりともなく良好であつた。Example 7 A mixture of 20 parts hydrogenated coconut oil and 5 parts coconut oil with an elevated melting point of 34°C (SFI of the mixture is 62.3 at 5°C, 39.3 at 20°C,
Heat and melt 4.6) at 30℃ to obtain 0.2 parts of glycerin monofatty acid ester with an iodine value of 3, and 0.1 part of soybean lecithin.
part, sorbitan unsaturated fatty acid ester 0.1 part,
Add 0.2 parts of sucrose fatty acid ester of HLB2 and disperse and dissolve it to form an oil phase.Meanwhile, add 5 parts of caster sugar to 49 parts of water.
Part, high maltose syrup (contains 25% water)
15 parts of carrageenan, 0.1 part of skim milk powder, 0.1 part of sodium hexametaphosphate, and 0.2 part of sucrose fatty acid ester of HLB11 were dispersed and dissolved to form an aqueous phase. After mixing and emulsifying the aqueous phase and fat and oil at an emulsification temperature of around 45℃, homogenizing at a homogenization pressure of 40Kg/ cm2 , VTIS
140 with a sterilizer (Alfa Arrabal UHT sterilizer)
Sterilized at ℃ for 3 seconds. This was cooled to around 70°C and further homogenized again at a homogenization pressure of 50 kg/cm 2 . After homogenization, the mixture was rapidly cooled to around 10°C in a plate cooler, and then aged in a refrigerator at 5°C for 18 hours or more. When this product was foamed using a 30-coat cake mixer, a foamed product with good stiffness and an overrun of 165% was obtained. This foam had excellent shape retention and appearance, and melted well in the mouth. In addition, this foam is used as a topping for decoration cakes and is frozen and thawed.
It was in good condition with no cracks or discoloration.
比較例 1
上昇融点28℃の魚硬化油60部と上昇融点34℃の
ヤシ硬化油40部の混合物(混合物のSFIは、5℃
で42.8、20℃で22.4、30℃で3.5)を加熱溶融し、
その中にヨウ素価2のグリセリンモノ脂肪酸エス
テル0.38部、ソルビタン不飽和脂肪酸エステル
0.2部、大豆レシチン0.3部、HLB2の蔗糖脂肪酸
エステル1.75部を添加し、これらを溶解ないし分
散せしめた油相と、20部の水にHLB7の蔗糖脂肪
酸エステル0.75部を添加溶解せしめて水相となし
たものを混合乳化し油中水型エマルジヨンとなし
た後、ボテーターを通して急冷可塑化し油脂組成
物を得た。Comparative Example 1 A mixture of 60 parts of hydrogenated fish oil with an elevated melting point of 28°C and 40 parts of hydrogenated coconut oil with an elevated melting point of 34°C (SFI of the mixture is 5°C
42.8 at 20℃, 22.4 at 20℃, 3.5 at 30℃),
Contains 0.38 parts of glycerin monofatty acid ester with an iodine value of 2, and sorbitan unsaturated fatty acid ester.
0.2 parts of soybean lecithin, 0.3 parts of soybean lecithin, and 1.75 parts of sucrose fatty acid ester of HLB2 were added and dissolved or dispersed to form an oil phase, and 0.75 parts of sucrose fatty acid ester of HLB7 was added and dissolved in 20 parts of water to form an aqueous phase. The resulting mixture was mixed and emulsified to form a water-in-oil emulsion, which was then rapidly cooled and plasticized through a votator to obtain an oil and fat composition.
比較例 2
比較例1で得た油脂組成物30部を溶融したもの
と、50部の水に4部の脱脂粉乳、10部のコーンシ
ロツプ固形分、5部の上白糖、0.1部のヘキサメ
タリン酸ソーダ、0.1部のゼラチンを溶解したも
のとを混合撹拌したのち均質圧力120Kg/cm2で均
質化し、プレート式殺菌装置で80℃で5分間殺菌
した後、10℃まで冷却し、更に5℃前後の冷蔵庫
中で15時間エージングしてクリーム状組成物を得
た。このクリーム状組成物を30コートケーキミキ
サーにて起泡したところ、オーバーランは120%
と低く、またホイツプ終点幅も狭く、いわゆるシ
マリ、バサツキのひどいクリームになつてしまつ
た。また、この起泡体を丸型デコレーシヨンケー
キにナツペ、トツピングして凍結解凍処理したも
のは、表面のきめは悪く、また、ひび割れを生じ
た。Comparative Example 2 Melted 30 parts of the fat composition obtained in Comparative Example 1, 50 parts of water, 4 parts of skim milk powder, 10 parts of corn syrup solids, 5 parts of white sugar, and 0.1 part of sodium hexametaphosphate. , 0.1 part of gelatin dissolved therein was mixed and stirred, homogenized at a homogenizing pressure of 120 kg/cm 2 , sterilized at 80°C for 5 minutes using a plate sterilizer, cooled to 10°C, and further heated to around 5°C. A creamy composition was obtained by aging in the refrigerator for 15 hours. When this creamy composition was whipped with a 30-coat cake mixer, the overrun was 120%.
It was low, and the width at the end of the whip was narrow, resulting in a cream that was so-called shimmery and dull. In addition, when this foam was topped on a round decoration cake and subjected to freeze-thaw treatment, the surface texture was poor and cracks were formed.
Claims (1)
かつ20℃におけるSFIが30〜45、かつ30℃におけ
るSFIが7以下である油脂と、 (A)ヨウ素価20以下のグリセリン脂肪酸エステル
と、(B)ソルビタン不飽和脂肪酸エステルおよび/
または燐脂質と、(C)蔗糖脂肪酸エステル〔但し、
蔗糖脂肪酸エステルの量については、式y=a/5 x(但し、aは使用される蔗糖脂肪酸エステルの
HLB、xは使用される蔗糖脂肪酸エステルの重
量、yは換算した量)で換算した量で算出、以下
同じ〕からなる乳化剤、 とを含有し、乳化剤の合計量が油脂に対して1.5
〜4重量%であつて、(A)が乳化剤合計量に対して
5〜50重量%かつ(B)が乳化剤合計量に対して10〜
50重量%かつ(C)が乳化剤合計量に対して25〜80重
量%である油脂組成物。 2 全体に対し、25重量%以下の水相を含有する
油中水型乳化脂である特許請求の範囲第1項記載
の油脂組成物。 3 水相が濃度70重量%以上、好ましくは濃度80
重量%以上の糖類水溶液からなる特許請求の範囲
第2項記載の油脂組成物。 4 5℃におけるSFIが55〜65かつ20℃における
SFIが30〜45かつ30℃におけるSFIが7以下であ
る油脂と、(A)ヨウ素価20以下のグリセリン脂肪酸
エステルと(B)ソルビタン不飽和脂肪酸エステルお
よび/または燐脂質と(C)蔗糖脂肪酸エステル〔但
し、蔗糖脂肪酸エステルの量については式y=
a/5x(但し、aは使用される蔗糖脂肪酸エステル のHLB、xは使用される蔗糖脂肪酸エステルの
重量、yは換算した量)で換算した量で算出、以
下同じ〕からなる乳化剤と、水と、糖類と、無脂
乳固形分とを含有する水中油型乳化脂で、油脂が
全体に対して20〜30重量%、水が全体に対して45
〜65重量%、糖類が全体に対して10〜30重量%、
無脂乳固形分が全体に対して0.5〜7重量%、乳
化剤の合計量が油脂に対して1.5〜4重量%、(A)
が乳化剤合計量に対して5〜50重量%かつ(B)が乳
化剤合計量に対して10〜50重量%かつ(C)が乳化剤
合計量に対して25〜80重量%であることを特徴と
するオーバーラン150〜200%の低油分高起泡性ク
リーム状組成物。[Claims] 1 Solid fat index (SFI) at 5°C is 55 to 65,
and an oil or fat with an SFI of 30 to 45 at 20°C and an SFI of 7 or less at 30°C, (A) glycerin fatty acid ester with an iodine value of 20 or less, (B) sorbitan unsaturated fatty acid ester and/or
or phospholipid and (C) sucrose fatty acid ester [however,
For the amount of sucrose fatty acid ester, use the formula y=a/5x (where a is the amount of sucrose fatty acid ester used).
HLB, where x is the weight of the sucrose fatty acid ester used and y is the converted amount); the same applies hereinafter];
-4% by weight, (A) is 5-50% by weight based on the total amount of emulsifier, and (B) is 10-4% by weight based on the total amount of emulsifier.
An oil and fat composition in which 50% by weight and (C) is 25 to 80% by weight based on the total amount of emulsifier. 2. The oil and fat composition according to claim 1, which is a water-in-oil emulsified fat containing 25% by weight or less of an aqueous phase based on the total weight. 3 The aqueous phase has a concentration of 70% by weight or more, preferably a concentration of 80%.
The oil and fat composition according to claim 2, which comprises an aqueous saccharide solution of at least % by weight. 4 SFI at 5℃ is 55-65 and at 20℃
Fats and oils with an SFI of 30 to 45 and an SFI of 7 or less at 30°C, (A) glycerin fatty acid ester with an iodine value of 20 or less, (B) sorbitan unsaturated fatty acid ester and/or phospholipid, and (C) sucrose fatty acid ester [However, regarding the amount of sucrose fatty acid ester, the formula y=
an emulsifier consisting of a/5x (where a is the HLB of the sucrose fatty acid ester used, x is the weight of the sucrose fatty acid ester used, and y is the converted amount; the same applies hereinafter); and water. It is an oil-in-water emulsified fat containing sugars, non-fat milk solids, and the oil content is 20 to 30% by weight based on the total weight, and the water content is 45% by weight based on the total weight.
~65% by weight, sugars 10-30% by weight,
Non-fat milk solids content is 0.5 to 7% by weight based on the total amount, total amount of emulsifier is 1.5 to 4% by weight based on fats and oils, (A)
is 5 to 50% by weight based on the total amount of emulsifier, (B) is 10 to 50% by weight based on the total amount of emulsifier, and (C) is 25 to 80% by weight based on the total amount of emulsifier. A low-oil, high-foaming cream composition with an overrun of 150-200%.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP10686078A JPS5534052A (en) | 1978-08-31 | 1978-08-31 | Creamy composition, and oil and fat composition suitable preparation thereof |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP10686078A JPS5534052A (en) | 1978-08-31 | 1978-08-31 | Creamy composition, and oil and fat composition suitable preparation thereof |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS5534052A JPS5534052A (en) | 1980-03-10 |
JPS6332421B2 true JPS6332421B2 (en) | 1988-06-29 |
Family
ID=14444316
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP10686078A Granted JPS5534052A (en) | 1978-08-31 | 1978-08-31 | Creamy composition, and oil and fat composition suitable preparation thereof |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS5534052A (en) |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS61170338A (en) * | 1985-01-21 | 1986-08-01 | Meiji Milk Prod Co Ltd | Production of whipped cream stable at low temperature for long period |
JPS6359840A (en) * | 1986-09-01 | 1988-03-15 | Fuji Oil Co Ltd | Compounded emulsion and production thereof |
AU645392B2 (en) * | 1991-02-21 | 1994-01-13 | Unilever Plc | Non-lauric filling fats |
JP4444804B2 (en) * | 2004-11-30 | 2010-03-31 | 日清オイリオグループ株式会社 | Oil composition for cream and cream containing the oil composition |
-
1978
- 1978-08-31 JP JP10686078A patent/JPS5534052A/en active Granted
Also Published As
Publication number | Publication date |
---|---|
JPS5534052A (en) | 1980-03-10 |
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