JPS6332096B2 - - Google Patents
Info
- Publication number
- JPS6332096B2 JPS6332096B2 JP56196723A JP19672381A JPS6332096B2 JP S6332096 B2 JPS6332096 B2 JP S6332096B2 JP 56196723 A JP56196723 A JP 56196723A JP 19672381 A JP19672381 A JP 19672381A JP S6332096 B2 JPS6332096 B2 JP S6332096B2
- Authority
- JP
- Japan
- Prior art keywords
- smoke
- weight
- molybdenum
- smoke suppressant
- composition
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000000779 smoke Substances 0.000 claims description 90
- 239000000203 mixture Substances 0.000 claims description 85
- 239000004800 polyvinyl chloride Substances 0.000 claims description 40
- 229920000915 polyvinyl chloride Polymers 0.000 claims description 39
- 229920000642 polymer Polymers 0.000 claims description 36
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims description 25
- 229910052750 molybdenum Inorganic materials 0.000 claims description 25
- 239000011733 molybdenum Substances 0.000 claims description 25
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims description 19
- 229910052698 phosphorus Inorganic materials 0.000 claims description 19
- 239000011574 phosphorus Substances 0.000 claims description 19
- 229920012485 Plasticized Polyvinyl chloride Polymers 0.000 claims description 9
- 230000001629 suppression Effects 0.000 claims description 7
- 239000003517 fume Substances 0.000 claims 1
- 239000011701 zinc Substances 0.000 description 39
- 239000000654 additive Substances 0.000 description 36
- 239000000454 talc Substances 0.000 description 29
- 229910052623 talc Inorganic materials 0.000 description 29
- JKQOBWVOAYFWKG-UHFFFAOYSA-N molybdenum trioxide Chemical compound O=[Mo](=O)=O JKQOBWVOAYFWKG-UHFFFAOYSA-N 0.000 description 22
- 229910052725 zinc Inorganic materials 0.000 description 18
- 238000009472 formulation Methods 0.000 description 17
- 239000000047 product Substances 0.000 description 17
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 16
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 16
- 230000000996 additive effect Effects 0.000 description 16
- 239000004014 plasticizer Substances 0.000 description 16
- 239000002002 slurry Substances 0.000 description 14
- -1 ethylene, propylene, 1-butene Chemical class 0.000 description 13
- 229920005989 resin Polymers 0.000 description 12
- 239000011347 resin Substances 0.000 description 12
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 11
- 239000000463 material Substances 0.000 description 11
- UOURRHZRLGCVDA-UHFFFAOYSA-D pentazinc;dicarbonate;hexahydroxide Chemical compound [OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[Zn+2].[Zn+2].[Zn+2].[Zn+2].[Zn+2].[O-]C([O-])=O.[O-]C([O-])=O UOURRHZRLGCVDA-UHFFFAOYSA-D 0.000 description 10
- ISIJQEHRDSCQIU-UHFFFAOYSA-N tert-butyl 2,7-diazaspiro[4.5]decane-7-carboxylate Chemical compound C1N(C(=O)OC(C)(C)C)CCCC11CNCC1 ISIJQEHRDSCQIU-UHFFFAOYSA-N 0.000 description 9
- 150000001875 compounds Chemical class 0.000 description 8
- 239000000314 lubricant Substances 0.000 description 8
- 229920002554 vinyl polymer Polymers 0.000 description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 8
- 239000011787 zinc oxide Substances 0.000 description 8
- 239000003795 chemical substances by application Substances 0.000 description 7
- 239000002245 particle Substances 0.000 description 7
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 7
- 230000000694 effects Effects 0.000 description 6
- 238000002485 combustion reaction Methods 0.000 description 5
- 239000008367 deionised water Substances 0.000 description 5
- 229910021641 deionized water Inorganic materials 0.000 description 5
- 238000000034 method Methods 0.000 description 5
- 239000000178 monomer Substances 0.000 description 5
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 4
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 4
- 238000000354 decomposition reaction Methods 0.000 description 4
- 150000002148 esters Chemical class 0.000 description 4
- 239000012065 filter cake Substances 0.000 description 4
- 239000004615 ingredient Substances 0.000 description 4
- 238000003892 spreading Methods 0.000 description 4
- 230000007480 spreading Effects 0.000 description 4
- 238000003756 stirring Methods 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 238000010998 test method Methods 0.000 description 4
- 239000002253 acid Substances 0.000 description 3
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 3
- 125000004432 carbon atom Chemical group C* 0.000 description 3
- 239000003153 chemical reaction reagent Substances 0.000 description 3
- 229920001577 copolymer Polymers 0.000 description 3
- 239000000945 filler Substances 0.000 description 3
- 239000003063 flame retardant Substances 0.000 description 3
- 239000012760 heat stabilizer Substances 0.000 description 3
- 229920001519 homopolymer Polymers 0.000 description 3
- OCWMFVJKFWXKNZ-UHFFFAOYSA-L lead(2+);oxygen(2-);sulfate Chemical compound [O-2].[O-2].[O-2].[Pb+2].[Pb+2].[Pb+2].[Pb+2].[O-]S([O-])(=O)=O OCWMFVJKFWXKNZ-UHFFFAOYSA-L 0.000 description 3
- 230000009467 reduction Effects 0.000 description 3
- 229910001868 water Inorganic materials 0.000 description 3
- 150000003752 zinc compounds Chemical class 0.000 description 3
- MYRTYDVEIRVNKP-UHFFFAOYSA-N 1,2-Divinylbenzene Chemical compound C=CC1=CC=CC=C1C=C MYRTYDVEIRVNKP-UHFFFAOYSA-N 0.000 description 2
- LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 description 2
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 2
- LEJBBGNFPAFPKQ-UHFFFAOYSA-N 2-(2-prop-2-enoyloxyethoxy)ethyl prop-2-enoate Chemical compound C=CC(=O)OCCOCCOC(=O)C=C LEJBBGNFPAFPKQ-UHFFFAOYSA-N 0.000 description 2
- WSSSPWUEQFSQQG-UHFFFAOYSA-N 4-methyl-1-pentene Chemical compound CC(C)CC=C WSSSPWUEQFSQQG-UHFFFAOYSA-N 0.000 description 2
- IRIAEXORFWYRCZ-UHFFFAOYSA-N Butylbenzyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCC1=CC=CC=C1 IRIAEXORFWYRCZ-UHFFFAOYSA-N 0.000 description 2
- SOGAXMICEFXMKE-UHFFFAOYSA-N Butylmethacrylate Chemical compound CCCCOC(=O)C(C)=C SOGAXMICEFXMKE-UHFFFAOYSA-N 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- ZVFDTKUVRCTHQE-UHFFFAOYSA-N Diisodecyl phthalate Chemical compound CC(C)CCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC(C)C ZVFDTKUVRCTHQE-UHFFFAOYSA-N 0.000 description 2
- 239000004606 Fillers/Extenders Substances 0.000 description 2
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 2
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 2
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 2
- ARCGXLSVLAOJQL-UHFFFAOYSA-N anhydrous trimellitic acid Natural products OC(=O)C1=CC=C(C(O)=O)C(C(O)=O)=C1 ARCGXLSVLAOJQL-UHFFFAOYSA-N 0.000 description 2
- FUSUHKVFWTUUBE-UHFFFAOYSA-N buten-2-one Chemical compound CC(=O)C=C FUSUHKVFWTUUBE-UHFFFAOYSA-N 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 150000001735 carboxylic acids Chemical class 0.000 description 2
- UQLDLKMNUJERMK-UHFFFAOYSA-L di(octadecanoyloxy)lead Chemical compound [Pb+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O UQLDLKMNUJERMK-UHFFFAOYSA-L 0.000 description 2
- 150000001993 dienes Chemical class 0.000 description 2
- QQVHEQUEHCEAKS-UHFFFAOYSA-N diundecyl benzene-1,2-dicarboxylate Chemical compound CCCCCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCCCCC QQVHEQUEHCEAKS-UHFFFAOYSA-N 0.000 description 2
- 230000031700 light absorption Effects 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000004570 mortar (masonry) Substances 0.000 description 2
- 230000003287 optical effect Effects 0.000 description 2
- 230000002195 synergetic effect Effects 0.000 description 2
- 239000003017 thermal stabilizer Substances 0.000 description 2
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 2
- 150000004684 trihydrates Chemical class 0.000 description 2
- LENZDBCJOHFCAS-UHFFFAOYSA-N tris Chemical compound OCC(N)(CO)CO LENZDBCJOHFCAS-UHFFFAOYSA-N 0.000 description 2
- 239000001993 wax Substances 0.000 description 2
- OJOWICOBYCXEKR-KRXBUXKQSA-N (5e)-5-ethylidenebicyclo[2.2.1]hept-2-ene Chemical compound C1C2C(=C/C)/CC1C=C2 OJOWICOBYCXEKR-KRXBUXKQSA-N 0.000 description 1
- PMJHHCWVYXUKFD-SNAWJCMRSA-N (E)-1,3-pentadiene Chemical group C\C=C\C=C PMJHHCWVYXUKFD-SNAWJCMRSA-N 0.000 description 1
- DURPTKYDGMDSBL-UHFFFAOYSA-N 1-butoxybutane Chemical compound CCCCOCCCC DURPTKYDGMDSBL-UHFFFAOYSA-N 0.000 description 1
- LHHMNJZNWUJFOC-UHFFFAOYSA-N 1-chloro-2-[2-chloroethoxy(ethenyl)phosphoryl]oxyethane Chemical compound ClCCOP(=O)(C=C)OCCCl LHHMNJZNWUJFOC-UHFFFAOYSA-N 0.000 description 1
- OZCMOJQQLBXBKI-UHFFFAOYSA-N 1-ethenoxy-2-methylpropane Chemical compound CC(C)COC=C OZCMOJQQLBXBKI-UHFFFAOYSA-N 0.000 description 1
- IGGDKDTUCAWDAN-UHFFFAOYSA-N 1-vinylnaphthalene Chemical compound C1=CC=C2C(C=C)=CC=CC2=C1 IGGDKDTUCAWDAN-UHFFFAOYSA-N 0.000 description 1
- HECLRDQVFMWTQS-RGOKHQFPSA-N 1755-01-7 Chemical compound C1[C@H]2[C@@H]3CC=C[C@@H]3[C@@H]1C=C2 HECLRDQVFMWTQS-RGOKHQFPSA-N 0.000 description 1
- OEPOKWHJYJXUGD-UHFFFAOYSA-N 2-(3-phenylmethoxyphenyl)-1,3-thiazole-4-carbaldehyde Chemical compound O=CC1=CSC(C=2C=C(OCC=3C=CC=CC=3)C=CC=2)=N1 OEPOKWHJYJXUGD-UHFFFAOYSA-N 0.000 description 1
- RFIMISVNSAUMBU-UHFFFAOYSA-N 2-(hydroxymethyl)-2-(prop-2-enoxymethyl)propane-1,3-diol Chemical compound OCC(CO)(CO)COCC=C RFIMISVNSAUMBU-UHFFFAOYSA-N 0.000 description 1
- GOXQRTZXKQZDDN-UHFFFAOYSA-N 2-Ethylhexyl acrylate Chemical compound CCCCC(CC)COC(=O)C=C GOXQRTZXKQZDDN-UHFFFAOYSA-N 0.000 description 1
- SBYMUDUGTIKLCR-UHFFFAOYSA-N 2-chloroethenylbenzene Chemical compound ClC=CC1=CC=CC=C1 SBYMUDUGTIKLCR-UHFFFAOYSA-N 0.000 description 1
- FWWXYLGCHHIKNY-UHFFFAOYSA-N 2-ethoxyethyl prop-2-enoate Chemical compound CCOCCOC(=O)C=C FWWXYLGCHHIKNY-UHFFFAOYSA-N 0.000 description 1
- HKFPXINKVCOLOD-UHFFFAOYSA-N 2-hexylsulfanylethyl prop-2-enoate Chemical compound CCCCCCSCCOC(=O)C=C HKFPXINKVCOLOD-UHFFFAOYSA-N 0.000 description 1
- HFCUBKYHMMPGBY-UHFFFAOYSA-N 2-methoxyethyl prop-2-enoate Chemical compound COCCOC(=O)C=C HFCUBKYHMMPGBY-UHFFFAOYSA-N 0.000 description 1
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 description 1
- ALKCLFLTXBBMMP-UHFFFAOYSA-N 3,7-dimethylocta-1,6-dien-3-yl hexanoate Chemical compound CCCCCC(=O)OC(C)(C=C)CCC=C(C)C ALKCLFLTXBBMMP-UHFFFAOYSA-N 0.000 description 1
- UHBAWOXYQROEIH-UHFFFAOYSA-N 3-chloro-4-(2-chlorobut-3-enoxy)but-1-ene Chemical compound C=CC(Cl)COCC(Cl)C=C UHBAWOXYQROEIH-UHFFFAOYSA-N 0.000 description 1
- KWCPPCKBBRBYEE-UHFFFAOYSA-N 3-chloropropyl prop-2-enoate Chemical compound ClCCCOC(=O)C=C KWCPPCKBBRBYEE-UHFFFAOYSA-N 0.000 description 1
- JVUAYVUZADWJBK-UHFFFAOYSA-N 3-cyanopropyl prop-2-enoate Chemical compound C=CC(=O)OCCCC#N JVUAYVUZADWJBK-UHFFFAOYSA-N 0.000 description 1
- FASUFOTUSHAIHG-UHFFFAOYSA-N 3-methoxyprop-1-ene Chemical compound COCC=C FASUFOTUSHAIHG-UHFFFAOYSA-N 0.000 description 1
- LEUWBMAQQQENOO-UHFFFAOYSA-N 4-(4-chlorophenyl)-6-methyl-2-oxo-3,4-dihydro-1h-pyridine-5-carboxylic acid Chemical compound C1C(=O)NC(C)=C(C(O)=O)C1C1=CC=C(Cl)C=C1 LEUWBMAQQQENOO-UHFFFAOYSA-N 0.000 description 1
- DBCAQXHNJOFNGC-UHFFFAOYSA-N 4-bromo-1,1,1-trifluorobutane Chemical compound FC(F)(F)CCCBr DBCAQXHNJOFNGC-UHFFFAOYSA-N 0.000 description 1
- VNPRJHMMOKDEDZ-UHFFFAOYSA-L 6-methylheptyl 2-[dibutyl-[2-(6-methylheptoxy)-2-oxoethyl]sulfanylstannyl]sulfanylacetate Chemical compound CC(C)CCCCCOC(=O)CS[Sn](CCCC)(CCCC)SCC(=O)OCCCCCC(C)C VNPRJHMMOKDEDZ-UHFFFAOYSA-L 0.000 description 1
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 1
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 1
- 239000004803 Di-2ethylhexylphthalate Substances 0.000 description 1
- VOWAEIGWURALJQ-UHFFFAOYSA-N Dicyclohexyl phthalate Chemical compound C=1C=CC=C(C(=O)OC2CCCCC2)C=1C(=O)OC1CCCCC1 VOWAEIGWURALJQ-UHFFFAOYSA-N 0.000 description 1
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 1
- VQTUBCCKSQIDNK-UHFFFAOYSA-N Isobutene Chemical group CC(C)=C VQTUBCCKSQIDNK-UHFFFAOYSA-N 0.000 description 1
- 241000276489 Merlangius merlangus Species 0.000 description 1
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 1
- GYCMBHHDWRMZGG-UHFFFAOYSA-N Methylacrylonitrile Chemical compound CC(=C)C#N GYCMBHHDWRMZGG-UHFFFAOYSA-N 0.000 description 1
- 239000006057 Non-nutritive feed additive Substances 0.000 description 1
- MXRIRQGCELJRSN-UHFFFAOYSA-N O.O.O.[Al] Chemical compound O.O.O.[Al] MXRIRQGCELJRSN-UHFFFAOYSA-N 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
- 235000021355 Stearic acid Nutrition 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
- QYKIQEUNHZKYBP-UHFFFAOYSA-N Vinyl ether Chemical compound C=COC=C QYKIQEUNHZKYBP-UHFFFAOYSA-N 0.000 description 1
- FMRLDPWIRHBCCC-UHFFFAOYSA-L Zinc carbonate Chemical compound [Zn+2].[O-]C([O-])=O FMRLDPWIRHBCCC-UHFFFAOYSA-L 0.000 description 1
- SLETZFVTVXVPLS-UHFFFAOYSA-N [Zn].[Cd].[Ba] Chemical compound [Zn].[Cd].[Ba] SLETZFVTVXVPLS-UHFFFAOYSA-N 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 239000004480 active ingredient Substances 0.000 description 1
- 239000001361 adipic acid Substances 0.000 description 1
- 235000011037 adipic acid Nutrition 0.000 description 1
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 229910000410 antimony oxide Inorganic materials 0.000 description 1
- 239000012736 aqueous medium Substances 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- 239000010425 asbestos Substances 0.000 description 1
- 150000001536 azelaic acids Chemical class 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- ZDWGXBPVPXVXMQ-UHFFFAOYSA-N bis(2-ethylhexyl) nonanedioate Chemical compound CCCCC(CC)COC(=O)CCCCCCCC(=O)OCC(CC)CCCC ZDWGXBPVPXVXMQ-UHFFFAOYSA-N 0.000 description 1
- BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 description 1
- ZFMQKOWCDKKBIF-UHFFFAOYSA-N bis(3,5-difluorophenyl)phosphane Chemical compound FC1=CC(F)=CC(PC=2C=C(F)C=C(F)C=2)=C1 ZFMQKOWCDKKBIF-UHFFFAOYSA-N 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 description 1
- 239000008116 calcium stearate Substances 0.000 description 1
- 235000013539 calcium stearate Nutrition 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 239000000969 carrier Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- KBLWLMPSVYBVDK-UHFFFAOYSA-N cyclohexyl prop-2-enoate Chemical compound C=CC(=O)OC1CCCCC1 KBLWLMPSVYBVDK-UHFFFAOYSA-N 0.000 description 1
- 230000000368 destabilizing effect Effects 0.000 description 1
- 125000004386 diacrylate group Chemical group 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- YCZJVRCZIPDYHH-UHFFFAOYSA-N ditridecyl benzene-1,2-dicarboxylate Chemical compound CCCCCCCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCCCCCCC YCZJVRCZIPDYHH-UHFFFAOYSA-N 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 238000009429 electrical wiring Methods 0.000 description 1
- XJELOQYISYPGDX-UHFFFAOYSA-N ethenyl 2-chloroacetate Chemical compound ClCC(=O)OC=C XJELOQYISYPGDX-UHFFFAOYSA-N 0.000 description 1
- GLVVKKSPKXTQRB-UHFFFAOYSA-N ethenyl dodecanoate Chemical compound CCCCCCCCCCCC(=O)OC=C GLVVKKSPKXTQRB-UHFFFAOYSA-N 0.000 description 1
- UIWXSTHGICQLQT-UHFFFAOYSA-N ethenyl propanoate Chemical compound CCC(=O)OC=C UIWXSTHGICQLQT-UHFFFAOYSA-N 0.000 description 1
- 229940052303 ethers for general anesthesia Drugs 0.000 description 1
- SUPCQIBBMFXVTL-UHFFFAOYSA-N ethyl 2-methylprop-2-enoate Chemical compound CCOC(=O)C(C)=C SUPCQIBBMFXVTL-UHFFFAOYSA-N 0.000 description 1
- STVZJERGLQHEKB-UHFFFAOYSA-N ethylene glycol dimethacrylate Substances CC(=C)C(=O)OCCOC(=O)C(C)=C STVZJERGLQHEKB-UHFFFAOYSA-N 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 238000009408 flooring Methods 0.000 description 1
- 230000009969 flowable effect Effects 0.000 description 1
- 230000004907 flux Effects 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 239000001530 fumaric acid Substances 0.000 description 1
- 239000003365 glass fiber Substances 0.000 description 1
- VOZRXNHHFUQHIL-UHFFFAOYSA-N glycidyl methacrylate Chemical compound CC(=C)C(=O)OCC1CO1 VOZRXNHHFUQHIL-UHFFFAOYSA-N 0.000 description 1
- 125000001188 haloalkyl group Chemical group 0.000 description 1
- LNMQRPPRQDGUDR-UHFFFAOYSA-N hexyl prop-2-enoate Chemical compound CCCCCCOC(=O)C=C LNMQRPPRQDGUDR-UHFFFAOYSA-N 0.000 description 1
- 239000007970 homogeneous dispersion Substances 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 150000002484 inorganic compounds Chemical class 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- PBOSTUDLECTMNL-UHFFFAOYSA-N lauryl acrylate Chemical compound CCCCCCCCCCCCOC(=O)C=C PBOSTUDLECTMNL-UHFFFAOYSA-N 0.000 description 1
- 231100000053 low toxicity Toxicity 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
- 239000011976 maleic acid Substances 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- XJRBAMWJDBPFIM-UHFFFAOYSA-N methyl vinyl ether Chemical compound COC=C XJRBAMWJDBPFIM-UHFFFAOYSA-N 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000005078 molybdenum compound Substances 0.000 description 1
- 150000002752 molybdenum compounds Chemical class 0.000 description 1
- ZIUHHBKFKCYYJD-UHFFFAOYSA-N n,n'-methylenebisacrylamide Chemical compound C=CC(=O)NCNC(=O)C=C ZIUHHBKFKCYYJD-UHFFFAOYSA-N 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- FSAJWMJJORKPKS-UHFFFAOYSA-N octadecyl prop-2-enoate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)C=C FSAJWMJJORKPKS-UHFFFAOYSA-N 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- RPQRDASANLAFCM-UHFFFAOYSA-N oxiran-2-ylmethyl prop-2-enoate Chemical compound C=CC(=O)OCC1CO1 RPQRDASANLAFCM-UHFFFAOYSA-N 0.000 description 1
- VTRUBDSFZJNXHI-UHFFFAOYSA-N oxoantimony Chemical compound [Sb]=O VTRUBDSFZJNXHI-UHFFFAOYSA-N 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 235000019809 paraffin wax Nutrition 0.000 description 1
- HVAMZGADVCBITI-UHFFFAOYSA-M pent-4-enoate Chemical compound [O-]C(=O)CCC=C HVAMZGADVCBITI-UHFFFAOYSA-M 0.000 description 1
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pentâ4âenâ2âone Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 1
- 235000019271 petrolatum Nutrition 0.000 description 1
- WRAQQYDMVSCOTE-UHFFFAOYSA-N phenyl prop-2-enoate Chemical compound C=CC(=O)OC1=CC=CC=C1 WRAQQYDMVSCOTE-UHFFFAOYSA-N 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 239000006069 physical mixture Substances 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 230000000485 pigmenting effect Effects 0.000 description 1
- PMJHHCWVYXUKFD-UHFFFAOYSA-N piperylene Natural products CC=CC=C PMJHHCWVYXUKFD-UHFFFAOYSA-N 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- HJWLCRVIBGQPNF-UHFFFAOYSA-N prop-2-enylbenzene Chemical compound C=CCC1=CC=CC=C1 HJWLCRVIBGQPNF-UHFFFAOYSA-N 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- 238000000197 pyrolysis Methods 0.000 description 1
- 238000009877 rendering Methods 0.000 description 1
- 239000011342 resin composition Substances 0.000 description 1
- 229910052895 riebeckite Inorganic materials 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 235000012424 soybean oil Nutrition 0.000 description 1
- 239000003549 soybean oil Substances 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 238000002834 transmittance Methods 0.000 description 1
- JNXDCMUUZNIWPQ-UHFFFAOYSA-N trioctyl benzene-1,2,4-tricarboxylate Chemical compound CCCCCCCCOC(=O)C1=CC=C(C(=O)OCCCCCCCC)C(C(=O)OCCCCCCCC)=C1 JNXDCMUUZNIWPQ-UHFFFAOYSA-N 0.000 description 1
- WDRCVXGINNJWPH-UHFFFAOYSA-N tris(6-methylheptyl) benzene-1,2,4-tricarboxylate Chemical compound CC(C)CCCCCOC(=O)C1=CC=C(C(=O)OCCCCCC(C)C)C(C(=O)OCCCCCC(C)C)=C1 WDRCVXGINNJWPH-UHFFFAOYSA-N 0.000 description 1
- NSBGJRFJIJFMGW-UHFFFAOYSA-N trisodium;stiborate Chemical compound [Na+].[Na+].[Na+].[O-][Sb]([O-])([O-])=O NSBGJRFJIJFMGW-UHFFFAOYSA-N 0.000 description 1
- 229920001567 vinyl ester resin Polymers 0.000 description 1
- 229960000834 vinyl ether Drugs 0.000 description 1
- 239000011667 zinc carbonate Substances 0.000 description 1
- 229910000010 zinc carbonate Inorganic materials 0.000 description 1
- 235000004416 zinc carbonate Nutrition 0.000 description 1
- XAEWLETZEZXLHR-UHFFFAOYSA-N zinc;dioxido(dioxo)molybdenum Chemical compound [Zn+2].[O-][Mo]([O-])(=O)=O XAEWLETZEZXLHR-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/32—Phosphorus-containing compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Description
æ¬çºæã¯å¡©åããã«ããªããŒã«é¢ãããã®ã§ã
ããç¹ã«å¯å¡åããªå¡©åããã«ïŒå¡©ãïŒããªããŒ
åã³ç¡¬è³ªå¡©ãããªããŒã«å¯ŸããŠçºç æå¶ãããã
ãæ·»å å€ã§ãã€ãŠãå å·¥äžã«ãã®ãããªããªããŒ
ãææã«äžå®å®åããããšã®ãªãæ·»å å€ã«é¢ãã
ãã®ã§ãããçºç æå¶ãããå¡©ãããªããŒçµæç©
ã¯çºç æå¶ã瀺ããå³ã¡ãçºç æå¶ãããŠãªãçµ
æç©ã«æ¯èŒããŠãççŒã«éãçºç åŸåãæžå°ãã
ããã å¡©åããã«ãã¢ããªããŒåã³ã³ããªããŒã¯ãã®
åªããæ©æ¢°çåã³ååŠçæ§è³ªãåã³é åå€åã«å¯Ÿ
ããå€çšæ§ã®ããã«ãäºæ¬¡å å·¥ã®çš®ã ã®æ§é éš
æãå粧åžãå粧ç®èãé»æ°é ç·ãåã³åºæçã«
察ããŠåºãåæ¥çã«äœ¿çšãããŠããã å€æ°ã®åæ¥çå¿çšã«ãããŠã¯ãæçµçšéã«åã€
ãææã®æè»æ§ãåŸãããã«ãå¡©ãçµçç©äžã«ãš
ã¹ãã«åå¯å¡å€ãçžåœéãäŸãã°çŽ20phrããçŽ
100phrïŒå¡©ãæš¹è100éšã«å¯ŸããéšïŒãå«æãã
ããšãå¿ èŠãšãããå¡©ãçµæç©ã®ä»ã®åæ¥çå¿çš
ã«ãããŠã¯ã硬質å³ã¡éå¯å¡ååã§çšããå¡©ãæš¹
èãå¿ èŠãšããã å¡©ãããªããŒçµæç©ã®ççŒã¯ãå¡©ããå解ãã
åªç ãæµ®éç²åãçºæ£ããäžè¬ã«ç ãšç§°ãããã®
ãçæãããå解çæç©ã¯ãŸãè³éŠæåã³èèªæ
çåæ°ŽçŽ ãççŽ ã®é žåç©ãåã³å¡©é žãå å«ããã
å¯å¡åå¡©ãã®å Žåã«ã¯ãç ãçæããååç©ã¯å¡©
ãããã®çåæ°ŽçŽ ãççŽ ã®é žåç©ãåã³å¡©é žã°ã
ãã§ãªããå¯å¡å€ååç©åã³ãã®å解çæç©ãã
å å«ãããå¡©ãçµæç©ã¯çã䌎ãé«æž©ã«ãããã
ããšãçºç ããããããã¯çèªäœããããã倧ã
ãªå±éºã人éã«åãŒãåå ãšãªãã ããæ ãå¡©ãããªããŒçµæç©ã«çºç æå¶å€ãå³
ã¡çµæç©ãççŒãããšãã«ç ã®çºçãæå¶ããå
åç©ããæ·»å æ··åããããšãæãŸããããããã
ãªææ©åã³ç¡æ©ååç©åã³å¡©é¡ããããŸã§ç¡¬è³ªãŸ
ãã¯å¯å¡åå¡©ãããªããŒçµæç©ã®çºç ç¹æ§ãæžå°
ããããããã«ææ¡ãããŸãã¯äœ¿çšãããŠããã
ããããã®ãããªè¬å€ã¯ã硬質åã³å¯å¡åå¡©ãçµ
æç©ã®åæ¹ã«å¯Ÿããæé©ãªçºç æå¶ã®æ¹åããã
ãããããŸãããªããŒçµæç©ã®å®å®æ§ãŸãã¯å å·¥
æ§ãé床ã«æžå°ãããããšãããããªæ¬ ç¹ãæã
ãŠããã å¡©ãçµæç©ãé åãåã³å å·¥ããéã«ãããé«
æž©ãå¡©ãã«å¯ŸããŠæãŸãããªã圱é¿ãäžããã®ã§
éåžžã¯äžçš®ãŸãã¯ãã以äžã®ç±å®å®å€ãå¡©ãçµæ
ç©äžã«æ·»å ããŠãããç±å®å®å€ã¯å¡©ãã®å解ãæ
ããæžå°ããããäžã€ããªããŒæ§é ãç²æ§åã³å¯
床ã®å€åã®ãããªä»ã®ç±çã«èªçºãããæãŸãã
ãªã圱é¿ã«å¯ŸããŠå¡©ããå®å®åãããããããã
ãªå¡©åããã«çµæç©ã«çºç æå¶ãä»äžããããã«
䜿çšãããŠããè¬å€ã¯ãããæ·»å ãããŠããããª
ããŒçµæç©ã®ç±å®å®æ§ãé床ã«æžå°ãããããç¹
ã«åžè²©ã®äºéååç©ãŸãã¯äºéååç©ãšä»ã®åå
ç©ã®çµåããããŒã¹ã«ããããçš®ã®çºç æå¶æ·»å
ç©ã¯éé¢ã®é žåäºéãå«æããããã¯çŽ100â以
äžã®æž©åºŠã§ããªå¡©åããã«æš¹èã®å解ãä¿é²ãã
ããšã«ãªããããããããã§ãé åç©ãäžå®å®å
ããããšãªããå³ã¡ãããªå¡©åããã«çµæç©ã®ç±
å®å®æ§ãææã«æããããšãªããç±å®å®åããã
ãªå¡©åããã«é åç©ã«æ·»å æ··åããããšãã§ãã
çºç æå¶å€æ·»å ç©ãå¿ èŠãšãªãã å¡©ãããªããŒã«å¯Ÿããçºç æå¶å€ãšããŠæçšãª
äžã€è¿å¹Žå ¥æå¯èœãšãªã€ãææã¯Zn3Mo2O9ã»
H2OãããŒã¹ã«ããã¿ã«ã¯ã§å¢éãããçµæç©
ãå å«ããŠããããã®ææã®è£œæ³åã³ç¹æ§ã¯æ¬é¡
ã®å®æœäŸäžã«ãã詳ããé瀺ããŠãããä»ã®çºç
æå¶å€ãšããŠç±³åœç¹èš±ç¬¬4098748å·åã³ç¬¬4098753
å·äžã«ãMoO2ïŒMoO3ïŒïŒNH4ïŒ2Mo2O7ïŒ
ïŒNH4ïŒ6Mo7O24ã»4H2OïŒïŒNH4ïŒ4Mo8O26ïŒ
ïŒNH4ïŒ2Mo10O31ïŒNa2MoO4ïŒCaMoO4ïŒåã¯
ZnMoO4ãå¯å¡å€å¡©ãçµæç©ã«å¯ŸããŠçŽïŒãçŽ
8phræ·»å ããŠçºç æå¶åã³é£çæ§ãä»äžããã
ãšãé瀺ãããŠãããç±³åœç¹èš±ç¬¬3900441å·ã«ã¯ã
ååæ§é ãç¹å®ããªãã¢ãªããã³é žäºéãåã¯äº
éååç©ãšã¢ãªããã³ååç©ã®ç©ççæ··åç©ãã
ãªå¡©åããã«å«æçµæç©ã«å¯Ÿããçºç æå¶å€ãšã
ãŠäœ¿çšã§ãããšããããšãé瀺ãããŠããããã
ççºç æå¶å€ã¯å€ãã®äœ¿çšã«ãããŠæçšã§ã¯ãã
ããæ¬çºæã®å¡©ãé åç©ã«æ·»åã§ããç¹ã«çžä¹ç
ã«æå¹ãªçºç æå¶å€æ·»å ç©ãå å«ãããã®ã§ããª
ãããã瀺åãããã®ã§ããªãã å¡©åããã«ããªããŒã®å€æ°ã®åé¡ç¹ãæ¬ ç¹ãå
æããããšãã§ããæ¬çºæã®æš¹èé åç©ã«æå¹é
å«æãããçºç æå¶å€ã¯ãããªããŒã®ç±å®å®æ§å
ã³å å·¥æ§ãæãããšã®ãªãçºç æå¶å€ãšããŠäœçš
ããæ¯èŒçäœæ¯æ§ã§ãããç±å解枩床ã«å ç±ãã
ãŠãããèªäœã¯æ®çºããããšããªãççŒçåæ®ç©
äžã«æ®ããäŸ¡æ Œçã«åŸæ¥ã®å€æ°ã®è¬å€ããçµæžç
ã§ãããè¯å¥œãªäŸçµŠç¶æ ã§åœå ã§å ¥æã§ããäžã€
å¡©åããã«ããªããŒçµæç©ã®é åã«ãããŠå€æ¹é¢
ã®çšéããããã奜ãŸããã¯ããªããŒçµæç©ãçœ
è²ã«ããŠã¯ã€ã€ãŒãã±ãŒãã«çã®ã³ãŒãã€ã³ã°ã
çè²ã§ããããã«ãããã®ã§ããã æ¬çºæã®å©ç¹ã¯ãããªå¡©åããã«ããªããŒã®äž»
æååã³ããªããŒçµæç©ãçºç æå¶ããããäž»ãš
ããŠZn3Mo2O9ã»H2OãšZnHPO3ã®æ··åç©ããæ
ãã¢ãªããã³å¯Ÿãªã³ã®ååæ¯ãçŽ0.5ïŒïŒããçŽ
2.0ïŒïŒã§ããçºç æå¶å€ã®å°éã§ãããããã
æå¹éããæããçºç æå¶ããã硬質ãŸãã¯å¯å¡
åããªå¡©åããã«ããªããŒçµæç©ã«ãã€ãŠéæã
ããã æ¬çºæã®å¥œãŸããå ·äœäŸã¯ãçºç æå¶å€ãããª
ããŒçµæç©äžã«ã¿ã«ã¯æ äœäžã«å±éãããŠååšã
ããã®ã§ããã æš¹èé åç©ã®çµæç©ã䜿çšæåã¯æ¬æ现æžåã³
è«æ±ç¯å²äžã«ãç¹ã«å€ããªãéãééããŒã¹ã§èš
èŒããŠãããphrã¯æš¹è100éééšã«å¯Ÿããéé
éšã瀺ãã æ¬æ现æžäžã§äœ¿çšããŠããå¡©åããã«ããªããŒ
ãšããå称ã¯åºãæå³ã§çšããŠãããå¡©åããã«
åã³å¡©åãããªãã³ã®ããªããŒãå å«ãããã®ã
ã¢ããªããŒãã³ããªããŒãåã³ãã¢ããªããŒå
ã³ïŒåã¯ã³ããªããŒã®ãã¬ã³ããå å«ãããå¡©å
ããã«ããªããŒã¯å ±éåãããä»ã®ããã«ã¢ãã
ãŒã50ééïŒ ãŸã§å«æããããšãã§ããéåžžãã
ãã«ã¢ãããŒã®éã¯çŽ20ïŒ ãŸã§ã§ããããã®ãã
ãªããã«ã¢ãããŒã¯ïŒåãã12åã®ççŽ ååãã
ããéäŸçã«ã¯ïŒåããïŒåã®ççŽ ååãå«æã
ãïŒâãªã¬ãã€ã³ãå å«ãã代衚çãªãã®ãšã
ãŠããšãã¬ã³ããããã¬ã³ãïŒâããã³ãã€ãœã
ãã¬ã³ãïŒâããã»ã³ãïŒâã¡ãã«âïŒâãã³ã
ã³çãããããŸãããã«ã¢ãããŒã¯ããã¿ãžãš
ã³ãã€ãœãã¬ã³ããããªã¬ã³çã®å ±åœ¹ãžãšã³ãå
å«ããïŒåãã10åã®ççŽ ååãæãããžãšã³ïŒ
ãšããªãã³ãã«ãã«ãã³åã³ãžã·ã¯ããã³ã¿ãžãš
ã³ïŒé ¢é žããã«ãã¯ãã«é ¢é žããã«ãããããªã³
é žããã«ãã©ãŠãªã«é žããã«ãé ¢é žã¢ãªã«çãå
å«ããããã«ãšã¹ãã«åã³ã¢ãªã«ãšã¹ãã«ïŒã¹ã
ã¬ã³ãαâã¡ãã«ã¹ãã¬ã³ãã¯ãã«ã¹ãã¬ã³ãã
ãã«ãã«ãšã³ãããã«ããã¿ã¬ã³çã®ãããªãã
ã«è³éŠæïŒããã«ã¡ãã«ãšãŒãã«ãã¢ãªã«ã¡ãã«
ãšãŒãã«ãããã«ã€ãœããã«ãšãŒãã«ãããã«ïœ
âããã«ãšãŒãã«ãããã«ã¯ãã«ãšãã«ãšãŒã
ã«ãã¡ãã«ããã«ã±ãã³çã®ãããªããã«åã³ã¢
ãªã«ã®ãšãŒãã«åã³ã±ãã³ïŒã¢ã¯ãªããããªã«ã
ã¡ã¿ã¯ãªããããªã«çã®ãããªããã«ãããªã«ïŒ
αâã·ã¢ãã¡ãã«ã¢ã¯ãªã¬ãŒããαâïŒÎ²âãå
ã³Î³âã·ã¢ããããã«ã¢ã¯ãªã¬ãŒãçã®ãããªã·
ã¢ãã¢ã«ãã«ã¢ã¯ãªã¬ãŒãïŒã¡ãã«ã¢ã¯ãªã¬ãŒ
ãããšãã«ã¢ã¯ãªã¬ãŒããã¯ãã«ãããã«ã¢ã¯ãª
ã¬ãŒããããã«ã¢ã¯ãªã¬ãŒããããã·ã«ã¢ã¯ãªã¬
ãŒããïŒâãšãã«ããã·ã«ã¢ã¯ãªã¬ãŒããããã·
ã«ã¢ã¯ãªã¬ãŒãããªã¯ã¿ãã·ã«ã¢ã¯ãªã¬ãŒããã·
ã¯ãããã·ã«ã¢ã¯ãªã¬ãŒããããšãã«ã¢ã¯ãªã¬ãŒ
ããã°ãªã·ãžã«ã¢ã¯ãªã¬ãŒããã¡ããã·ãšãã«ã¢
ã¯ãªã¬ãŒãããšããã·ãšãã«ã¢ã¯ãªã¬ãŒãããã
ã·ã«ããªãšãã«ã¢ã¯ãªã¬ãŒããã¡ãã«ã¡ã¿ã¯ãªã¬
ãŒãããšãã«ã¡ã¿ã¯ãªã¬ãŒããããã«ã¡ã¿ã¯ãªã¬
ãŒããã°ãªã·ãžã«ã¡ã¿ã¯ãªã¬ãŒãçã®ãããªãå
ã³ãã¬ã€ã³é žãããã«é žçã®ãšã¹ãã«ãå å«ãã
ãªã¬ãã€ã³äžé£œåã«ã«ãã³é žåã³ãã®ãšã¹ãã«ã
ãªã¬ãã€ã³äžé£œåé žåã³ãã®ãšã¹ãã«ïŒã¢ã¯ãªã«
ã¢ããçã®ãããªÎ±âãŸãã¯Î²âãªã¬ãã€ã³äžé£œ
åã«ã«ãã³é žã®ã¢ããïŒãžããã«ãã³ãŒã³ããžã
ãã«ãšãŒãã«ããžãšãã¬ã³ã°ãªã³ãŒã«ãžã¢ã¯ãªã¬
ãŒãããšãã¬ã³ã°ãªã³ãŒã«ãžã¡ã¿ã¯ãªã¬ãŒããã¡
ãã¬ã³ãã¹ã¢ã¯ãªã«ã¢ãããã¢ãªã«ãã³ã¿ãšãªã
ãªããŒã«çã®ãããªãžããã«ããžã¢ã¯ãªã¬ãŒãå
ã³ãã®ä»ã®å€å®èœã¢ãããŒïŒãã¹ïŒÎ²âã¯ãã«ãš
ãã«ïŒããã«ãã¹ãããŒãçã®ãããªãã¹ïŒÎ²â
ããã¢ã«ãã«ïŒã¢ã«ã±ãã«ãã¹ãããŒãïŒçãå
å«ããã æ¬çºæã®ããªå¡©åããã«çµæç©ã¯ãããªãŠã â
ã«ãããŠã âäºéç³ããïŒå¯å¡åå¡©ãé åç©ã«åº
ã䜿çšãããŠããïŒãææ©é«ååç©ïŒç¡¬è³ªå¡©ãé
åç©ã«åºã䜿çšãããŠããïŒããšããã·å倧è±æ²¹ã
äžå¡©åºæ§ç¡«é žéçã®ãããªç±å®å®å€ãéåžžçŽ
8phrãŸã§ã®æå¹éã§å«æããããšãã§ããã æŽã«ãæ¬çºæã®ããªããŒçµæç©ã¯é£çå€ãçŽïŒ
ããçŽ8phrã®éã§å«æããããšãã§ãããé©åœ
ãªé£çå€ã¯é žåã¢ã³ãã¢ã³ãã¢ã³ãã¢ã³é žãããª
ãŠã ãã¢ã³ãã¢ã³é žã«ãªãŠã ãåã³ããçã®æ··å
ç©ãå å«ãããæ¬çºæã®ããªããŒçµæç©ã¯æŽã«åŸ
æ¥ã®å ãŠãå€ãŸãã¯çé žã«ã«ã·ãŠã ãã¿ã«ã¯ãã·
ãªã«ãã¢ã«ããäžæ°Žåç©ã®ãããªç²ç¶å¢éå€ãçŽ
50phrãŸã§ã®éã§ïŒã¹ãã¢ãªã³é žãããªãšãã¬
ã³ããã©ãã€ã³ã¯ãã¯ã¹çã®ãããªæš¹èé åç©ã®
å å·¥ãä¿é²ããããã®æ»å€ãçŽ5phrãŸã§ã®é
ã§ïŒæš¹èçµæç©ãææã®è²ã«çè²åã³ïŒãŸãã¯äž
éæåããããã®çš®ã ã®ææåã³ïŒãŸãã¯é¡æã
å«æããããšãã§ããã æ¬çºæã®ç¯å²å ã®å¯å¡åå¡©ãããªããŒçµæç©
ã¯ããŸããäžçš®ä»¥äžã®å¯å¡å€ã代衚çãªãã®ãšã
ãŠã¯ãšã¹ãã«åå¯å¡å€ãå«æãããå¯å¡å€ã®é
ã¯ãéåžžãçŽ20phrããçŽ100phrã®ç¯å²ã«ããã
äœå¯å¡å€éã«ããå硬質ããé«å¯å¡å€éã«ããé
åžžãªæè»æ§ãŸã§æè»æ§ã«å¿ããŠéžæããããå¯å¡
å€ã¯ãã¿ã«é žãšã¹ãã«ç³»å¯å¡å€ãã¢ãŒã©ã€ã³é žãš
ã¹ãã«ç³»å¯å¡å€ãã¢ãžãã³é žãšã¹ãã«ç³»å¯å¡å€ã
ããªã¡ãªããé žãšã¹ãã«ç³»å¯å¡å€ãåã³ããçã®
æ··åç©ããæã矀ããéžæããããå¯å¡åå¡©ãæš¹
èã®é åã«ãããŠåºãåæ¥çã«äœ¿çšãããŠããäž
èšã®ãšã¹ãã«åå¯å¡å€ã®ä»£è¡šçãªãã®ã¯ãã¿ã«é ž
ãžâïŒâãšãã«ããã·ã«ããã¿ã«é žãžã€ãœãã·
ã«ããã¿ã«é žãžããªãã·ã«ããã¿ã«é žæ··åçŽéã¢
ã«ãã«ããã¿ã«é žãžã·ã¯ãããã·ã«ããã¿ã«é žãž
ãŠã³ãã·ã«ããã¿ã«é žããã«ãã³ãžã«çïŒã¢ãŒã©
ã€ã³é žãžâïŒâãšãã«ããã·ã«ãã¢ãŒã©ã€ã³é žãž
âïœâããã·ã«çãå å«ããã¢ãŒã©ã€ã³é žãšã¹ã
ã«ïŒã¢ãžãã³é žãžã€ãœãã·ã«ãã¢ãžãã³é žãžãªã¯
ãã«çãå å«ããã¢ãžãã³é žãšã¹ãã«ïŒåã³ããª
ã¡ãªããé žããªã€ãœãªã¯ãã«ãããªã¡ãªããé žã
ãªãªã¯ãã«çãå å«ããããªã¡ãªããé žãšã¹ãã«
ã§ããã äžèšæåã«å ããŠãæ¬çºæã®ããªå¡©åããã«ã
ãªããŒçµæç©ã¯ããªããŒçµæç©ã«çºç æå¶ãä»äž
ããããã«æå¹éã®æ°èŠãªçºç æå¶å€ãå«æãã
ãã®ã§ãããçºç æå¶å€ã¯äž»ãšããŠZn3Mo2O9ã»
H2OãšZnHPO3ã®æ··åç©ããæããã¢ãªããã³å¯Ÿ
ãªã³ã®ååæ¯ã¯çŽ0.5ïŒïŒããçŽ2.0ïŒïŒã§ããã
奜ãŸããã¯çŽ0.75ïŒïŒããçŽ1.5ïŒïŒã§ãããå¹
æçãªçºç æå¶ã¯æå¹ãªã¢ãªããã³äœ¿çšãšé¢é£ã
ãŠãããã¢ãªããã³å¯Ÿãªã³ã®æ¯ãçŽ0.75ïŒïŒãã
çŽ1.25ïŒïŒã®ç¯å²ã§ãããæå¹ã§ããããã«ã¯çŽ
ïŒïŒïŒã§ãå¹æçãªæå¶ãããããããã å¡©ãããªããŒçµæç©äžã®çºç æå¶å€ã®éã¯çŽ
0.1phrããçŽ20phrã§ããã奜ãŸããã¯çŽ0.2phr
ããçŽ10phrã§ãããçºç æå¶å€ã¯ååç©ããèª
äœãšããŠæ·»å ããããšãã§ããããã¿ã«ã¯ã®ãã
ãªææäžã«å±éãã圢ã§æ·»å ãããšæçã§ããã æ¬çºæã«äŸãã°ãçºç æå¶å€ã¯å¡©åºæ§çé žäºé
ã®æ°Žæ§ã¹ã©ãªãŒã§ãã€ãŠåšå²æž©åºŠããã¹ã©ãªãŒã®
沞ç¹ãŸã§ã®æž©åºŠã«ãããã®ããåºçºããŠèª¿è£œãã
ããšãã§ãããå¡©åºæ§çé žäºéã¯åœæ¥è ã«ããç¥
ãããç·ç§°ã§ãã€ãŠããããã2ZnCO3ã»3Zn
ïŒOHïŒ2ã®çµæãæããç©è³ªãæå³ããã次ãã§
ã¹ã©ãªãŒã«äžé žåã¢ãªããã³ïŒMoO3ïŒãšäºãªã³
é žããã¢ãªããã³å¯Ÿãªã³ã®ååæ¯ãçæç©äžã§çŽ
0.5ïŒïŒããçŽ2.0ïŒïŒãšãªãããã«æ·»å ãããäž
é žåã¢ãªããã³ãšããŠã¯ã奜ãŸããã¯å°ãªããšã
çŽ90ïŒ ã®äžé žåã¢ãªããã³ãå«æããççŽã®åå
ãçšããããšãã§ãããå¡©åºæ§çé žäºéãäžé žå
ã¢ãªããã³ãåã³äºãªã³é žãåå¿ããŠå®è³ªçã«å®
å šã«ææã®çæç©ãçãããäŸãã°ãå¡©åºæ§çé ž
äºéãšããŠäºéïŒã¢ã«ãäžé žåã¢ãªããã³ïŒã¢
ã«ãäºãªã³é žïŒã¢ã«ãäžç·ã«ãªã€ãŠåå¿ãããš
Zn3Mo2O9ã»H2O1ã¢ã«ãšZnHPO32ã¢ã«ã®æ··åç©
ïŒã¢ãªããã³å¯Ÿãªã³ã®æ¯ã¯ïŒïŒïŒã§ããïŒãçæ
ãããåå¿çæç©ãæ°Žæ§åªäœãããéãã也ç¥
ãããããŠããªå¡©åããã«ããªããŒçµæç©äžã«ã
ã¬ã³ãããææãšããŠé©ãããããªææã®ç²åŸã«
çŽç²ããã æ¬çºæã®çºç æå¶å€ã¯ã¿ã«ã¯ãä»ã®çŽ°ãåå²ã
ãæ äœäžã«å±éããŠèª¿åããããšãã§ãã次ãã§
å±éææãããªããŒçµæç©ã®ä»ã®æåã«æ·»å ã
ããã¿ã«ã¯å±éææäžã®Zn3Mo2O9ã»H2Oãš
ZnHPO3ã®éã¯ãããªããŒçµæç©äžãžã®çºç æå¶
å€ã®æ·»å éãåºæ¥ãã ãå¶éã§ãäžã€å質ãªåæ£
ãå¯èœãšãªãããã«éžæãããäžè¬ã«ã¯å±éææ
ã®çŽ10ééïŒ ããçŽ35ééïŒ ã§ãããå±éæ äœã¯
çºç æå¶å€åã³å±éææã«å¯ŸããŠäžæŽ»æ§ã§ãªãã
ã°ãªãããé žåäºéãæããŠããããäžã€åæ±ã
åé¡ãå®å šæ§ã®åé¡ãååšããªããã®ã§ãªããã°
ãªããªããäŸãã°ã¿ã«ã¯ãå±éæ äœãšããå Žå
ã¯ãã¢ã¹ãã¹ããå«æããŠããŠã¯ãªããªããçºç
æå¶å€ã¯å±éããŠäœ¿çšãããã©ããã«ããããã
åœæ¥è ã«å ¬ç¥ã®ãããããªæ¹æ³ã§å¡©ãããªããŒã«
çµã¿åããŠãæ¬çºæã®çºç æå¶ãããçµæç©ã補
é ããããšãã§ããã æ¬çºæã®å¥œãŸããå ·äœäŸã§ãããæ¬çºæã®çºç
æå¶å€æ·»å ç©ã調補ããæãè¯ãæ¹æ³ãæ§æãã
ãã®ã§ãããäŸã«ãããŠã¯ã现ãåå²ããã¿ã«
ã¯ã»ãšãã¹ãã³ããŒãæ°Žäžã«æžæ¿ãã該ã¹ã©ãªãŒ
ã«å¡©åºæ§çé žäºéãäžé žåã¢ãªããã³ãåã³äºãª
ã³é žãã ãããåè¿°ãããããªæ¯çã§æ·»å ãåå¿
ããã次ãã§ã¹ã©ãªãŒããéããŠçœè²ã®æµåæ§ã®
ç²åãååããçš®ã ã®å ¬ç¥ã®æ¹æ³ã«ãããã®ç²å
ãæ¬çºææžã«äŸç€ºããä»ã®ä»»æã®è¬å€ãšäžç·ã«ã
ãªå¡©åããã«ããªããŒã«é åããããšãã§ããã å±éããåã¯å±éããªãçºç æå¶å€ã®ç²ååŸã¯
ç¹ã«èšççã§ã¯ãªãããäžè¬ã«åå¿ã«å©çšã§ãã
ããã«ããããåã³ããªå¡©åããã«æš¹èãããªã
ã¯ã¹å šäœãžã®åäžãªåæ£æ§ãä¿é²ããããã«æé©
ãªå šè¡šé¢ç©ãæãããããªç²åŸåã³åœ¢ç¶ã®ç²åã
çšããããšãæãŸããã çŽ0.5ããçŽ2.0ã®ã¢ãªããã³ïŒãªã³ã®æ¯ã§äœ¿çš
ãããZn3Mo2O9ã»H2OãšZnHPO3ã®æ··åç©ãã
Zn3Mo2O9ã»H2Oåç¬ãŸãã¯ZnHPO3åç¬ãåçš
床ã®é䜿çšããå Žåã«æ¯ã¹ãŠãå¡©ãããªããŒçµæ
ç©ã«å¯ŸããŠçžä¹çã«æå¹ãªçºç æå¶å€ã§ãããšã
ãããšã¯æ³šç®ãã¹ãããšã§ãããåŸã€ãŠæ¬çºæã¯
æå®ã®ã¢ãªããã³æ¶è²»éããã€ãŠçºç æå¶å¹æã
å¢å ããæ¹æ³ãæäŸãããã®ã§ãããç¹ã«ãã
ã¯ãZnHPO3ããèªäœãç¹ã«æå¹ãªçºç æå¶å€ã§
ã¯ãªãã®ã§ãäºæ³å€ã®ããšã§ãããZnHPO3ã¯æ¬
çºæã®çµæç©ã«ãããŠæããã«åªããŠããã®ã§ã
ZnHPO3æåã¯Zn3ïŒPO4ïŒ2ã®ãããªãªã³é žå¡©åå
ç©ãšåºå¥ãããã¹ããã®ã§ããã æ¬çºæã«ãã補é ããããªå¡©åããã«ããªããŒ
çµæç©ã®çºç æå¶å€ã®ç¹åŸŽãã次ã®å®æœäŸããã€
ãŠæŽã«èª¬æãããå®æœäŸã¯èª¬æã®ããã«ããã®ã§
ãã€ãŠãæ¬çºæã®ç¯å²ãéå®ããç¹èš±è«æ±ã®ç¯å²
ãç¹å®ããããšãæå³ãããã®ã§ã¯ãªãã äŸ ïŒ ã¿ã«ã¯äžã«å±éããäž»ãšããŠZn3Mo2O9ã»H2O
ãšZnHPO3ã®æ··åç©ããæãæ¬çºæã®çºç æå¶å€
ã®ïŒãããã次ã®ããã«èª¿è£œããã çºç æå¶å€æ·»å ç© ïŒ¡ ã¿ã«ã¯äžã®Zn3Mo2O9ã»H2OãšZnHPO3ã®æ··å
ç© ã¿ã«ã¯ããã€ã¶ãŒãã¯ãã¿ã«ã¯ïŒPfizer
MicrotalcïŒMP10â52ã253.0ïœãè±ã€ãªã³æ°Ž
1180mlã«æ¹æããªããæ·»å ããåŸãããã¹ã©ãªãŒ
ã90âã«å ç±ãããããããå¡©åºæ§çé žäºéïŒé ž
åäºéå«é73.46ïŒ ã«çžåœïŒ54.1ïœãå ãã次ã
ã§30ïŒ ã®äºãªã³é ž53.3ïœã15å以äžã®æéããã
ãŠæ·»å ãããé žæ·»å çµäºåŸ10åããŠããäžé žåã¢
ãªããã³28.1ïœããã€ããæ·»å ãããããããŠè©Š
è¬ã¯äºé察ã¢ãªããã³å¯Ÿãªã³ã®ååæ¯ãçŽïŒïŒ
ïŒïŒïŒã§æ·»å ãããããšã«ãªããã¹ã©ãªãŒã90â
ã«3.5æéä¿ã€ãåŸãå·åŽãããããŠãéããã
ãéã±ãŒã¯ã110âã§äžæ©ä¹Ÿç¥ãã次ãã§200âã§
çŽïŒæé也ç¥ããã也ç¥çæç©ã¯330ïœãããã
ããä¹³é¢ãšä¹³æ£ã§ç²ç ãããçæç©äžã«äºéã
9.22ééïŒ ãã¢ãªããã³ã5.37ééïŒ ããªã³ã
1.80ééïŒ å«æãããŠãããäºé察ã¢ãªããã³å¯Ÿ
ãªã³ã®ååæ¯ã«çŽããšçŽ5.02ïŒ2.00ïŒ2.08ã§ãã€
ããåŸã€ãŠãã¿ã«ã¯äžã«å±éããçºç æå¶å€æ·»å
ç©ã¯Zn3Mo2O9ã»H2OãšZnHPO3ã®æ··åç©ãçŽ
23.8ééïŒ å«æããŠããã çºç æå¶å€æ·»å ç© ïŒ¢ ã¿ã«ã¯äžã®Zn3Mo2O9ã»H2OãšZnHPO3ã®æ··å
ç© ã¿ã«ã¯ïŒãã€ã¶ãŒãã¯ãã¿ã«ã¯MP10â52ïŒ
1518ïœãå¡©åºæ§çé žäºéïŒé žåäºéå«é73.65ïŒ
ã«çžåœïŒ323.4ïœã30ïŒ äºãªã³é ž319.8ïœãåã³äž
é žåã¢ãªããã³168.6ïœããæ·»å ç©ïŒ¡ã補é ãã
ããã«çšããæé ã«åŸã€ãŠãè±ã€ãªã³æ°Ž8.0äž
ã§çµã¿åããã也ç¥çæç©ã¯2.0Kgãããäºéã
8.93ééïŒ ãã¢ãªããã³ã5.14ééïŒ ãåã³ãªã³
ã1.67ééïŒ å«æããŠãããäºé察ã¢ãªããã³å¯Ÿ
ãªã³ã®ååæ¯ã¯5.10ïŒ2.00ïŒ2.02ã§ãã€ããåŸã€
ãŠãã¿ã«ã¯äžã«å±éããçºç æå¶å€æ·»å ç©ã¯
Zn3Mo2O9ã»H2OãšZnHPO3ã®æ··åç©çŽ22.7éé
ïŒ ãå«æããŠããã çºç æå¶å€æ·»å ç© ïŒ£ ã¿ã«ã¯äžã®Zn3Mo2O9ã»H2OãšZnHPO3ã®æ··å
ç© ã¿ã«ã¯ïŒãã€ã¶ãŒãã¯ãã¿ã«ã¯MP10â52ïŒ
34.5Kgãè±ã€ãªã³æ°Ž182ã«æ¹æããªããæ·»å ãã
åŸãããã¹ã©ãªãŒã90âã«å ç±ãããããããå¡©
åºæ§çé žäºéïŒé žåäºéå«é73.65ïŒ ã«çžåœïŒ7.3
Kgãæ·»å ãã次ãã§30ïŒ äºãªã³é ž7.3KgãïŒæé
以äžãããŠæ·»å ãããé žæ·»å çµäºåŸ10åããŠãã
äžé žåã¢ãªããã³3.8Kgã20å以äžãããŠæ·»å ã
ããããããŠè©Šè¬ã¯äºé察ã¢ãªããã³å¯Ÿãªã³ã®å
åæ¯ãïŒïŒïŒïŒïŒã§æ·»å ããããã¹ã©ãªãŒã90â
ã«3.5æéä¿ã€ãåŸãå·åŽãããéããããéã±
ãŒã¯ã110âã§16æé也ç¥ãã次ãã§200âã§ïŒæ
é也ç¥ããã也ç¥çæç©ã¯43.8Kgããã次ãã§ã
ãããã³ããŒã§ç²ç ãããçæç©ã¯äºéã8.55é
éïŒ ãã¢ãªããã³ã5.07ééïŒ ãåã³ãªã³ã1.80
ééïŒ å«æããŠãããäºé察ã¢ãªããã³å¯Ÿãªã³ã®
ååæ¯ã¯4.95ïŒ2.00ïŒ2.21ã§ãã€ããåŸã€ãŠãã¿
ã«ã¯äžã«å±éããçºç æå¶å€æ·»å ç©ã¯
Zn3Mo2O9ã»H2OãšZnHPO3ã®æ··åç©çŽ23.0éé
ïŒ ãå«æããŠããã äŸ ïŒ æ¯èŒã®ãããä»ã®ããã€ãã®çºç æå¶å€æ·»å ç©
ã次ã®æ¹æ³ã§èª¿è£œããã çºç æå¶å€æ·»å ç© ïŒ€ ã¿ã«ã¯äžã®Zn3Mo2O9ã»H2O ã¿ã«ã¯ïŒãã€ã¶ãŒãã¯ãã¿ã«ã¯MP10â52ïŒ
42.0Kgãæ°Ž208äžã«æžæ¿ãã該ã¹ã©ãªãŒã90â
ã«å ç±ãããã¹ã©ãªãŒã«å¡©åºæ§çé žäºéïŒ68.78
ïŒ é žåäºéçžåœïŒ6.5Kgãå ããããããäºé žå
ççŽ ã®çºçãèæ ®ããŠäžé žåã¢ãªããã³5.3Kgã
åŸã ã«æ·»å ãããè©Šè¬ã®äºé察ã¢ãªããã³ã®åå
æ¯ã¯çŽïŒïŒïŒã§ãã€ãã90âã§ïŒæéä¿ã€ãåŸã
åŸãããæ··åç©ãå·åŽãããéããŠååããåºäœ
ãçŽ115âã§äžæ©ä¹Ÿç¥ãããããã200âã§ïŒæé
也ç¥ããã也ç¥çæç©ããã³ããŒã§ç²ç ãã
Zn3Mo2O9ã»H2OçŽ18.5ééïŒ å«æããçœè²ã®ã
ãããããç²å50.9Kgãçæãããçæç©ã¯äºé
6.74ééïŒ ãåã³ã¢ãªããã³6.30ééïŒ ãå«æã
ãŠããã çºç æå¶å€æ·»å ç© ïŒ¥ ã¿ã«ã¯äžã®ZnHPO3 ã¿ã«ã¯ïŒãã€ã¶ãŒãã¯ãã¿ã«ã¯MP10â52ïŒ
253.0ïœãè±ã€ãªã³æ°Ž1180mlã«æ¹æããªããæ·»å
ããåŸãããã¹ã©ãªãŒã90âã«å ç±ãããããã
ãå¡©åºæ§çé žäºéïŒé žåäºéå«æé73.65ïŒ ã«çž
åœïŒ54.0ïœãæ·»å ãã次ãã§30ïŒ äºãªã³é ž133.6
ïœã25å以äžã®æéããããŠæ·»å ãããã¹ã©ãªãŒ
ã90âã«3.5æéä¿ã€ãåŸãå·åŽãããéããã
ãéã±ãŒã¯ãçŽ110âã§äžæ©ä¹Ÿç¥ãããããã200
âã§2.5æé也ç¥ããã也ç¥çæç©ã¯319ïœããã
ãããä¹³é¢ãšä¹³æ£ã§ç²ç ãããã¿ã«ã¯äžã«å±éã
ãçæç©ã¯äºé9.17ééïŒ åã³ãªã³4.60ééïŒ ã
å«æããŠãããåŸã€ãŠZnHPO3çŽ20ééïŒ ãå«æ
ããŠããã çºç æå¶å€æ·»å ç© ïŒŠ ã¿ã«ã¯äžã®Zn3Mo2O9ã»H2OãšZn3ïŒPO4ïŒ2ã»
2H2Oã®æ··åç© ãã®çæç©ã¯ãæ·»å ç©ïŒ¡ã補é ããããã«çšã
ãæ¹æ³ã«åŸã€ãŠãäºãªã³é žïŒH3PO3ïŒã«ä»£ããŠ
ãªã³é žïŒH3PO4ïŒã䜿çšããç¹ã ããéããŠã
補é ããã也ç¥çæç©ã¯328ïœãããäºé10.4é
éïŒ ãã¢ãªããã³5.4ééïŒ ãåã³ãªã³1.75éé
ïŒ ãå«æããŠãããåŸã€ãŠZn3Mo2O9ã»H2Oãš
Zn3ïŒPO4ïŒ2ã»2H2Oã®æ··åç©ãçŽ26ééïŒ å«æã
ãŠããã çºç æå¶å€æ·»å ç© ïŒ§ ã¿ã«ã¯äžã®ZnMoO4ã»0.8H2O ã¿ã«ã¯ïŒãã€ã¶ãŒãã¯ãã¿ã«ã¯MP10â52ïŒ1.8
Kgãè±ã€ãªã³æ°Ž7.0ã«æ¹æããªããæ·»å ããåŸ
ãããã¹ã©ãªãŒã90âã«å ç±ãããããããå¡©åº
æ§çé žäºéïŒé žåäºéå«é73.1ïŒ ã«çžåœïŒ0.21Kg
ãæ·»å ãã次ãã§äžé žåã¢ãªããã³0.27KgãåŸã
ã«å ããŠãäºé察ã¢ãªããã³ã®ååæ¯ãçŽïŒïŒïŒ
ãšããã該ã¹ã©ãªãŒã90âã«ïŒæéä¿ã€ãåŸãå·
åŽãããéããããéã±ãŒã¯ã110âã§äžæ©ä¹Ÿç¥
ãããããã200âã§ïŒæé也ç¥ããã也ç¥çæ
ç©ã¯2.11Kgãããããããã³ããŒã§ç²ç ãããç
æç©ã¯äºé5.3ééïŒ åã³ã¢ãªããã³7.4ééïŒ ã
å«æããŠãããäºé察ã¢ãªããã³ã®ååæ¯ã¯
1.05ïŒïŒã§ãã€ããåŸã€ãŠããã®ã¿ã«ã¯äžã«å±é
ããçºç æå¶å€æ·»å ç©ã¯ZnMoO4ã»0.8H2OãçŽ
18.5ééïŒ å«æããŠããã æ¬çºæã®çºç æå¶å€ã®æ¹åãããç¹æ§ãæãã
ã«ããããã«ãäžè¬ã«èªããããããã€ãã®ç°ãª
ã€ãçºç è©Šéšãè¡ã€ããè©Šéšæ¹æ³ã®æŠèŠã¯æ¬¡ã®é
ãã§ããã ã¢ã©ãããŒïŒArapahoeïŒãã¹ãïŒ å°ããªè©ŠæïŒ1.5Ã0.5Ã0.125ã€ã³ãå³ã¡3.8Ã
1.3Ã0.3cmïŒãå¯é宀å ã§ãããã³çãçšããŠ30
ç§éççŒãããççŒçæç©ãã¬ã©ã¹ç¹ç¶ã®ãçŽã
éããŠé£ç¶çã«ç空åžåŒããããçŽã®ééå¢å ã«
ãã€ãŠç ã®ééã枬å®ãããè©Šæã®ãã¹ãååŸã®
ééå·®ã«ãã€ãŠè©Šæã®æ¶è²»éãå®ãŸãããã¹ãçµ
æã¯è©Šæã®æ¶è²»éã«å¯Ÿããç ã®ééæ¯ããã€ãŠã
çºç ããŒã»ã³ããšããŠè¡šããã NBSã»ã¹ã¢ãŒã¯ã»ãã€ã³ããŒã»ãã¹ã ïŒASTM â662â79ïŒïŒ ïŒã€ã³ãå¹³æ¹ã®è©Šçãå®å šã«å¯éããç®±ïŒäŸã
ã°36Ã24Ã36ã€ã³ãïŒå ã®ãã¬ãŒã ã«åçŽã«æ¯æ
ããããŠãè©Šçå ã®6.57å¹³æ¹ã€ã³ãé åã«ç±ãã
ãŠããç±æºã¯ããçã®ãã¹ãã§ã¯é»æ°çã§ãã€ã
ããè©Šæçè¡šé¢ã«å¯ŸããŠçºçççŒã®æ¡ä»¶äžã§å¹³æ¹
ã»ã³ãã¡ãŒãã«åœã2.5ã¯ããã®ç±ç·æãããã
ããã«èª¿æŽãããè©Šçäžã®äžèšé åã®å åžåãæš
æºå 床èšã䜿çšããŠæž¬å®ãããç çºçãå¢å ãã
ãšå åžåã倧ãããªãããã¹ãçµæã¯å¹ŸäœåŠçå
åãšæž¬å®ããå åŠæ¿åºŠããå°ããæ倧æ¯å åŠå¯åºŠ
ãšããŠè¡šããã ãªãã€ãªã»ã¹ããŒãã»ã¬ãªãŒãºã»ã¬ã€ãã»ãã¹
ãïŒOSRRãã¹ãïŒïŒ ïŒã€ã³ãå¹³æ¹ã§åãã3.2mmïŒ1/8ã€ã³ãïŒã®è©Š
çãäžå®ã®ç©ºæ°æµéãæãã宀å ã«åçŽã«æ¯æã
ããããè©Šçã«æå®ã®ç±ç·æãããŠãè©Šçã®åºèŸº
ã®äžå€®ã«å°ããªç¹ç«çãã¶ã€ãããçºçããç ã®
éãã»ãå ã®ããã»ã«ã«ãã€ãŠæž¬å®ããæéã®åœ
æ°ãšããŠãããããããçºç ããŒã¿ã¯ãã¹ã¢ãŒ
ã¯ãåäœã§è¡šãããããã¹ã¢ãŒã¯ãåäœã¯ãç«æ¹
ç±³åœãïŒã¹ã¢ãŒã¯ã®æ¿åºŠãæãã空æ°ã¯çåç®ç
ã§å ééçã10ïŒ æžãããããªïŒå³ã¡å ééç80
ïŒ ãã70ïŒ ãžããŸãã¯45ïŒ ãã35ïŒ ãžïŒãã®ãšã
ãŠå®çŸ©ããããå€ã¯äžå®æéå ã«çºçããåã¯ç±
ç·ãããŠãŠããæéã«çºçããããŒã¿ã«ã¹ã¢ãŒã¯
ãšããŠãšãããã 次ã®å®æœäŸã«ãããŠãçºç æå¶å€æ·»å ç©ã®æ·»å
ã¯ã¿ã«ã¯ãããŒã¹ã«ããææã®phrã§è¡šç€ºãããŠ
ããã掻æ§æåã®phrã¯ã¿ã«ã¯ãããŒã¹ã«ããæ
æã®æ·»å ç©å«æéããå°ãããšãã§ããã äŸ ïŒ æ¬¡ã®æåãæãã硬質塩ãå°ç®¡é åç©ã«ãããŠ
ãããããªæ·»å ç©ã®çºç æå¶å¹æã枬å®ããã ããªå¡©åããã«æš¹èïŒgeon103EP F76ïŒã°ã
ããªããç€Ÿè£œïŒ 100éééš ã³ãŒããããã¯ã€ãã³ã°ïŒå å¡«å€ïŒ 25éééš ïŒOmyalite90TïŒOmya補ïŒå å·¥å©å€
ïŒAcryloid K120NïŒããŒã ïŒãã¹ç€Ÿè£œïŒ
ïŒéééš é«å®å®å€ïŒThermolite31ïŒïŒïŒïŒŽã±ãã«ã«ãº
ç€Ÿè£œïŒ ïŒéééš æ»å€ïŒPlastiflow POPïŒNLã€ã³ãã¹ããªãŒç€Ÿ
è£œïŒ 0.6éééš æ»å€ïŒã¹ãã¢ãªã³é žã«ã«ã·ãŠã ïŒ 0.8éééš æ»å€ïŒLubricin25ïŒNLã€ã³ãã¹ããªãŒç€Ÿè£œïŒ
0.5éééš ãã®é åç©ã«ãããããªæ·»å ç©ãæ·»å ãããã®
åã³æ·»å ããªããã®ã«ã€ããŠã®ç çºçããåè¿°ã®
äžçš®ã®ãã¹ãæ¹æ³ã§æž¬å®ããã®ã§ããã®çµæãè¡š
ïŒã«ç€ºãã è¡šïŒã®ããŒã¿ããæ¬çºæã®Zn3Mo2O9ã»H2Oå
ã³ZnHPO3ãå«æããå¡©ãçµæç©ã¯ä»ã®æ·»å ç©ã
å«æããå¡©ãçµæç©ããææã«åªããçºç æå¶å¹
æãæããŠãããšããããšãå€ããå®éãæ·»å ç©
ïŒïŒ¢åã³ïŒ£ã®å¹æãæ·»å ç©ïŒ€åã³ïŒ¥ãšæ¯èŒãã
ãšãæ¬çºæã¯ãZn3Mo2O9ã»H2Oåç¬åã³
ZnHPO3åç¬ã«ãã€ãŠãããããã以äžã®äžã€ã
ãçäºã€ã®åç¬ååç©ãããããçºç æžå°å¹æã
å ç®ããããšããæåŸ ããã以äžã®ãåªããçºç
æå¶ãä»äžãããã®ã§ãããšäºãããšãæãããš
ãªããäŸãã°è¡šïŒãåç §ã«ãããšãæ·»å ç©ïŒ¡ïŒæ¬
çºæã®çºç æå¶å€ïŒã¯38ïŒ ã®çºç æžå°å¹æãã
ããäžæ¹åãçšåºŠã®çºç æžå°ãéæããããã«ã¯
æ·»å ç©ïŒ€åã³æ·»å ç©ïŒ¥ããããã10phrãã€äžç·
ã«æ·»å ããããã«äºåã®æ·»å ç©ã䜿çšããªããã°
ãªããªããã®ãšäºæ³ãããã¯ãã§ããããããã
ååç©ã®åã ã«èããããç¹æ§ãå ç®ããŠã®äºæ³
ã¯ã¯ãããæ¬çºæã¯æåŸ ä»¥äžã®å¹æãæãããåŸ
ã€ãŠæ¬çºæã¯çžä¹çå¹æãæãäžã€åŸæ¥æè¡ãã
ã¯äºæ³ã§ããªãçºæãšäºããããåŸãªãã
ããç¹ã«å¯å¡åããªå¡©åããã«ïŒå¡©ãïŒããªããŒ
åã³ç¡¬è³ªå¡©ãããªããŒã«å¯ŸããŠçºç æå¶ãããã
ãæ·»å å€ã§ãã€ãŠãå å·¥äžã«ãã®ãããªããªããŒ
ãææã«äžå®å®åããããšã®ãªãæ·»å å€ã«é¢ãã
ãã®ã§ãããçºç æå¶ãããå¡©ãããªããŒçµæç©
ã¯çºç æå¶ã瀺ããå³ã¡ãçºç æå¶ãããŠãªãçµ
æç©ã«æ¯èŒããŠãççŒã«éãçºç åŸåãæžå°ãã
ããã å¡©åããã«ãã¢ããªããŒåã³ã³ããªããŒã¯ãã®
åªããæ©æ¢°çåã³ååŠçæ§è³ªãåã³é åå€åã«å¯Ÿ
ããå€çšæ§ã®ããã«ãäºæ¬¡å å·¥ã®çš®ã ã®æ§é éš
æãå粧åžãå粧ç®èãé»æ°é ç·ãåã³åºæçã«
察ããŠåºãåæ¥çã«äœ¿çšãããŠããã å€æ°ã®åæ¥çå¿çšã«ãããŠã¯ãæçµçšéã«åã€
ãææã®æè»æ§ãåŸãããã«ãå¡©ãçµçç©äžã«ãš
ã¹ãã«åå¯å¡å€ãçžåœéãäŸãã°çŽ20phrããçŽ
100phrïŒå¡©ãæš¹è100éšã«å¯ŸããéšïŒãå«æãã
ããšãå¿ èŠãšãããå¡©ãçµæç©ã®ä»ã®åæ¥çå¿çš
ã«ãããŠã¯ã硬質å³ã¡éå¯å¡ååã§çšããå¡©ãæš¹
èãå¿ èŠãšããã å¡©ãããªããŒçµæç©ã®ççŒã¯ãå¡©ããå解ãã
åªç ãæµ®éç²åãçºæ£ããäžè¬ã«ç ãšç§°ãããã®
ãçæãããå解çæç©ã¯ãŸãè³éŠæåã³èèªæ
çåæ°ŽçŽ ãççŽ ã®é žåç©ãåã³å¡©é žãå å«ããã
å¯å¡åå¡©ãã®å Žåã«ã¯ãç ãçæããååç©ã¯å¡©
ãããã®çåæ°ŽçŽ ãççŽ ã®é žåç©ãåã³å¡©é žã°ã
ãã§ãªããå¯å¡å€ååç©åã³ãã®å解çæç©ãã
å å«ãããå¡©ãçµæç©ã¯çã䌎ãé«æž©ã«ãããã
ããšãçºç ããããããã¯çèªäœããããã倧ã
ãªå±éºã人éã«åãŒãåå ãšãªãã ããæ ãå¡©ãããªããŒçµæç©ã«çºç æå¶å€ãå³
ã¡çµæç©ãççŒãããšãã«ç ã®çºçãæå¶ããå
åç©ããæ·»å æ··åããããšãæãŸããããããã
ãªææ©åã³ç¡æ©ååç©åã³å¡©é¡ããããŸã§ç¡¬è³ªãŸ
ãã¯å¯å¡åå¡©ãããªããŒçµæç©ã®çºç ç¹æ§ãæžå°
ããããããã«ææ¡ãããŸãã¯äœ¿çšãããŠããã
ããããã®ãããªè¬å€ã¯ã硬質åã³å¯å¡åå¡©ãçµ
æç©ã®åæ¹ã«å¯Ÿããæé©ãªçºç æå¶ã®æ¹åããã
ãããããŸãããªããŒçµæç©ã®å®å®æ§ãŸãã¯å å·¥
æ§ãé床ã«æžå°ãããããšãããããªæ¬ ç¹ãæã
ãŠããã å¡©ãçµæç©ãé åãåã³å å·¥ããéã«ãããé«
æž©ãå¡©ãã«å¯ŸããŠæãŸãããªã圱é¿ãäžããã®ã§
éåžžã¯äžçš®ãŸãã¯ãã以äžã®ç±å®å®å€ãå¡©ãçµæ
ç©äžã«æ·»å ããŠãããç±å®å®å€ã¯å¡©ãã®å解ãæ
ããæžå°ããããäžã€ããªããŒæ§é ãç²æ§åã³å¯
床ã®å€åã®ãããªä»ã®ç±çã«èªçºãããæãŸãã
ãªã圱é¿ã«å¯ŸããŠå¡©ããå®å®åãããããããã
ãªå¡©åããã«çµæç©ã«çºç æå¶ãä»äžããããã«
䜿çšãããŠããè¬å€ã¯ãããæ·»å ãããŠããããª
ããŒçµæç©ã®ç±å®å®æ§ãé床ã«æžå°ãããããç¹
ã«åžè²©ã®äºéååç©ãŸãã¯äºéååç©ãšä»ã®åå
ç©ã®çµåããããŒã¹ã«ããããçš®ã®çºç æå¶æ·»å
ç©ã¯éé¢ã®é žåäºéãå«æããããã¯çŽ100â以
äžã®æž©åºŠã§ããªå¡©åããã«æš¹èã®å解ãä¿é²ãã
ããšã«ãªããããããããã§ãé åç©ãäžå®å®å
ããããšãªããå³ã¡ãããªå¡©åããã«çµæç©ã®ç±
å®å®æ§ãææã«æããããšãªããç±å®å®åããã
ãªå¡©åããã«é åç©ã«æ·»å æ··åããããšãã§ãã
çºç æå¶å€æ·»å ç©ãå¿ èŠãšãªãã å¡©ãããªããŒã«å¯Ÿããçºç æå¶å€ãšããŠæçšãª
äžã€è¿å¹Žå ¥æå¯èœãšãªã€ãææã¯Zn3Mo2O9ã»
H2OãããŒã¹ã«ããã¿ã«ã¯ã§å¢éãããçµæç©
ãå å«ããŠããããã®ææã®è£œæ³åã³ç¹æ§ã¯æ¬é¡
ã®å®æœäŸäžã«ãã詳ããé瀺ããŠãããä»ã®çºç
æå¶å€ãšããŠç±³åœç¹èš±ç¬¬4098748å·åã³ç¬¬4098753
å·äžã«ãMoO2ïŒMoO3ïŒïŒNH4ïŒ2Mo2O7ïŒ
ïŒNH4ïŒ6Mo7O24ã»4H2OïŒïŒNH4ïŒ4Mo8O26ïŒ
ïŒNH4ïŒ2Mo10O31ïŒNa2MoO4ïŒCaMoO4ïŒåã¯
ZnMoO4ãå¯å¡å€å¡©ãçµæç©ã«å¯ŸããŠçŽïŒãçŽ
8phræ·»å ããŠçºç æå¶åã³é£çæ§ãä»äžããã
ãšãé瀺ãããŠãããç±³åœç¹èš±ç¬¬3900441å·ã«ã¯ã
ååæ§é ãç¹å®ããªãã¢ãªããã³é žäºéãåã¯äº
éååç©ãšã¢ãªããã³ååç©ã®ç©ççæ··åç©ãã
ãªå¡©åããã«å«æçµæç©ã«å¯Ÿããçºç æå¶å€ãšã
ãŠäœ¿çšã§ãããšããããšãé瀺ãããŠããããã
ççºç æå¶å€ã¯å€ãã®äœ¿çšã«ãããŠæçšã§ã¯ãã
ããæ¬çºæã®å¡©ãé åç©ã«æ·»åã§ããç¹ã«çžä¹ç
ã«æå¹ãªçºç æå¶å€æ·»å ç©ãå å«ãããã®ã§ããª
ãããã瀺åãããã®ã§ããªãã å¡©åããã«ããªããŒã®å€æ°ã®åé¡ç¹ãæ¬ ç¹ãå
æããããšãã§ããæ¬çºæã®æš¹èé åç©ã«æå¹é
å«æãããçºç æå¶å€ã¯ãããªããŒã®ç±å®å®æ§å
ã³å å·¥æ§ãæãããšã®ãªãçºç æå¶å€ãšããŠäœçš
ããæ¯èŒçäœæ¯æ§ã§ãããç±å解枩床ã«å ç±ãã
ãŠãããèªäœã¯æ®çºããããšããªãççŒçåæ®ç©
äžã«æ®ããäŸ¡æ Œçã«åŸæ¥ã®å€æ°ã®è¬å€ããçµæžç
ã§ãããè¯å¥œãªäŸçµŠç¶æ ã§åœå ã§å ¥æã§ããäžã€
å¡©åããã«ããªããŒçµæç©ã®é åã«ãããŠå€æ¹é¢
ã®çšéããããã奜ãŸããã¯ããªããŒçµæç©ãçœ
è²ã«ããŠã¯ã€ã€ãŒãã±ãŒãã«çã®ã³ãŒãã€ã³ã°ã
çè²ã§ããããã«ãããã®ã§ããã æ¬çºæã®å©ç¹ã¯ãããªå¡©åããã«ããªããŒã®äž»
æååã³ããªããŒçµæç©ãçºç æå¶ããããäž»ãš
ããŠZn3Mo2O9ã»H2OãšZnHPO3ã®æ··åç©ããæ
ãã¢ãªããã³å¯Ÿãªã³ã®ååæ¯ãçŽ0.5ïŒïŒããçŽ
2.0ïŒïŒã§ããçºç æå¶å€ã®å°éã§ãããããã
æå¹éããæããçºç æå¶ããã硬質ãŸãã¯å¯å¡
åããªå¡©åããã«ããªããŒçµæç©ã«ãã€ãŠéæã
ããã æ¬çºæã®å¥œãŸããå ·äœäŸã¯ãçºç æå¶å€ãããª
ããŒçµæç©äžã«ã¿ã«ã¯æ äœäžã«å±éãããŠååšã
ããã®ã§ããã æš¹èé åç©ã®çµæç©ã䜿çšæåã¯æ¬æ现æžåã³
è«æ±ç¯å²äžã«ãç¹ã«å€ããªãéãééããŒã¹ã§èš
èŒããŠãããphrã¯æš¹è100éééšã«å¯Ÿããéé
éšã瀺ãã æ¬æ现æžäžã§äœ¿çšããŠããå¡©åããã«ããªããŒ
ãšããå称ã¯åºãæå³ã§çšããŠãããå¡©åããã«
åã³å¡©åãããªãã³ã®ããªããŒãå å«ãããã®ã
ã¢ããªããŒãã³ããªããŒãåã³ãã¢ããªããŒå
ã³ïŒåã¯ã³ããªããŒã®ãã¬ã³ããå å«ãããå¡©å
ããã«ããªããŒã¯å ±éåãããä»ã®ããã«ã¢ãã
ãŒã50ééïŒ ãŸã§å«æããããšãã§ããéåžžãã
ãã«ã¢ãããŒã®éã¯çŽ20ïŒ ãŸã§ã§ããããã®ãã
ãªããã«ã¢ãããŒã¯ïŒåãã12åã®ççŽ ååãã
ããéäŸçã«ã¯ïŒåããïŒåã®ççŽ ååãå«æã
ãïŒâãªã¬ãã€ã³ãå å«ãã代衚çãªãã®ãšã
ãŠããšãã¬ã³ããããã¬ã³ãïŒâããã³ãã€ãœã
ãã¬ã³ãïŒâããã»ã³ãïŒâã¡ãã«âïŒâãã³ã
ã³çãããããŸãããã«ã¢ãããŒã¯ããã¿ãžãš
ã³ãã€ãœãã¬ã³ããããªã¬ã³çã®å ±åœ¹ãžãšã³ãå
å«ããïŒåãã10åã®ççŽ ååãæãããžãšã³ïŒ
ãšããªãã³ãã«ãã«ãã³åã³ãžã·ã¯ããã³ã¿ãžãš
ã³ïŒé ¢é žããã«ãã¯ãã«é ¢é žããã«ãããããªã³
é žããã«ãã©ãŠãªã«é žããã«ãé ¢é žã¢ãªã«çãå
å«ããããã«ãšã¹ãã«åã³ã¢ãªã«ãšã¹ãã«ïŒã¹ã
ã¬ã³ãαâã¡ãã«ã¹ãã¬ã³ãã¯ãã«ã¹ãã¬ã³ãã
ãã«ãã«ãšã³ãããã«ããã¿ã¬ã³çã®ãããªãã
ã«è³éŠæïŒããã«ã¡ãã«ãšãŒãã«ãã¢ãªã«ã¡ãã«
ãšãŒãã«ãããã«ã€ãœããã«ãšãŒãã«ãããã«ïœ
âããã«ãšãŒãã«ãããã«ã¯ãã«ãšãã«ãšãŒã
ã«ãã¡ãã«ããã«ã±ãã³çã®ãããªããã«åã³ã¢
ãªã«ã®ãšãŒãã«åã³ã±ãã³ïŒã¢ã¯ãªããããªã«ã
ã¡ã¿ã¯ãªããããªã«çã®ãããªããã«ãããªã«ïŒ
αâã·ã¢ãã¡ãã«ã¢ã¯ãªã¬ãŒããαâïŒÎ²âãå
ã³Î³âã·ã¢ããããã«ã¢ã¯ãªã¬ãŒãçã®ãããªã·
ã¢ãã¢ã«ãã«ã¢ã¯ãªã¬ãŒãïŒã¡ãã«ã¢ã¯ãªã¬ãŒ
ãããšãã«ã¢ã¯ãªã¬ãŒããã¯ãã«ãããã«ã¢ã¯ãª
ã¬ãŒããããã«ã¢ã¯ãªã¬ãŒããããã·ã«ã¢ã¯ãªã¬
ãŒããïŒâãšãã«ããã·ã«ã¢ã¯ãªã¬ãŒããããã·
ã«ã¢ã¯ãªã¬ãŒãããªã¯ã¿ãã·ã«ã¢ã¯ãªã¬ãŒããã·
ã¯ãããã·ã«ã¢ã¯ãªã¬ãŒããããšãã«ã¢ã¯ãªã¬ãŒ
ããã°ãªã·ãžã«ã¢ã¯ãªã¬ãŒããã¡ããã·ãšãã«ã¢
ã¯ãªã¬ãŒãããšããã·ãšãã«ã¢ã¯ãªã¬ãŒãããã
ã·ã«ããªãšãã«ã¢ã¯ãªã¬ãŒããã¡ãã«ã¡ã¿ã¯ãªã¬
ãŒãããšãã«ã¡ã¿ã¯ãªã¬ãŒããããã«ã¡ã¿ã¯ãªã¬
ãŒããã°ãªã·ãžã«ã¡ã¿ã¯ãªã¬ãŒãçã®ãããªãå
ã³ãã¬ã€ã³é žãããã«é žçã®ãšã¹ãã«ãå å«ãã
ãªã¬ãã€ã³äžé£œåã«ã«ãã³é žåã³ãã®ãšã¹ãã«ã
ãªã¬ãã€ã³äžé£œåé žåã³ãã®ãšã¹ãã«ïŒã¢ã¯ãªã«
ã¢ããçã®ãããªÎ±âãŸãã¯Î²âãªã¬ãã€ã³äžé£œ
åã«ã«ãã³é žã®ã¢ããïŒãžããã«ãã³ãŒã³ããžã
ãã«ãšãŒãã«ããžãšãã¬ã³ã°ãªã³ãŒã«ãžã¢ã¯ãªã¬
ãŒãããšãã¬ã³ã°ãªã³ãŒã«ãžã¡ã¿ã¯ãªã¬ãŒããã¡
ãã¬ã³ãã¹ã¢ã¯ãªã«ã¢ãããã¢ãªã«ãã³ã¿ãšãªã
ãªããŒã«çã®ãããªãžããã«ããžã¢ã¯ãªã¬ãŒãå
ã³ãã®ä»ã®å€å®èœã¢ãããŒïŒãã¹ïŒÎ²âã¯ãã«ãš
ãã«ïŒããã«ãã¹ãããŒãçã®ãããªãã¹ïŒÎ²â
ããã¢ã«ãã«ïŒã¢ã«ã±ãã«ãã¹ãããŒãïŒçãå
å«ããã æ¬çºæã®ããªå¡©åããã«çµæç©ã¯ãããªãŠã â
ã«ãããŠã âäºéç³ããïŒå¯å¡åå¡©ãé åç©ã«åº
ã䜿çšãããŠããïŒãææ©é«ååç©ïŒç¡¬è³ªå¡©ãé
åç©ã«åºã䜿çšãããŠããïŒããšããã·å倧è±æ²¹ã
äžå¡©åºæ§ç¡«é žéçã®ãããªç±å®å®å€ãéåžžçŽ
8phrãŸã§ã®æå¹éã§å«æããããšãã§ããã æŽã«ãæ¬çºæã®ããªããŒçµæç©ã¯é£çå€ãçŽïŒ
ããçŽ8phrã®éã§å«æããããšãã§ãããé©åœ
ãªé£çå€ã¯é žåã¢ã³ãã¢ã³ãã¢ã³ãã¢ã³é žãããª
ãŠã ãã¢ã³ãã¢ã³é žã«ãªãŠã ãåã³ããçã®æ··å
ç©ãå å«ãããæ¬çºæã®ããªããŒçµæç©ã¯æŽã«åŸ
æ¥ã®å ãŠãå€ãŸãã¯çé žã«ã«ã·ãŠã ãã¿ã«ã¯ãã·
ãªã«ãã¢ã«ããäžæ°Žåç©ã®ãããªç²ç¶å¢éå€ãçŽ
50phrãŸã§ã®éã§ïŒã¹ãã¢ãªã³é žãããªãšãã¬
ã³ããã©ãã€ã³ã¯ãã¯ã¹çã®ãããªæš¹èé åç©ã®
å å·¥ãä¿é²ããããã®æ»å€ãçŽ5phrãŸã§ã®é
ã§ïŒæš¹èçµæç©ãææã®è²ã«çè²åã³ïŒãŸãã¯äž
éæåããããã®çš®ã ã®ææåã³ïŒãŸãã¯é¡æã
å«æããããšãã§ããã æ¬çºæã®ç¯å²å ã®å¯å¡åå¡©ãããªããŒçµæç©
ã¯ããŸããäžçš®ä»¥äžã®å¯å¡å€ã代衚çãªãã®ãšã
ãŠã¯ãšã¹ãã«åå¯å¡å€ãå«æãããå¯å¡å€ã®é
ã¯ãéåžžãçŽ20phrããçŽ100phrã®ç¯å²ã«ããã
äœå¯å¡å€éã«ããå硬質ããé«å¯å¡å€éã«ããé
åžžãªæè»æ§ãŸã§æè»æ§ã«å¿ããŠéžæããããå¯å¡
å€ã¯ãã¿ã«é žãšã¹ãã«ç³»å¯å¡å€ãã¢ãŒã©ã€ã³é žãš
ã¹ãã«ç³»å¯å¡å€ãã¢ãžãã³é žãšã¹ãã«ç³»å¯å¡å€ã
ããªã¡ãªããé žãšã¹ãã«ç³»å¯å¡å€ãåã³ããçã®
æ··åç©ããæã矀ããéžæããããå¯å¡åå¡©ãæš¹
èã®é åã«ãããŠåºãåæ¥çã«äœ¿çšãããŠããäž
èšã®ãšã¹ãã«åå¯å¡å€ã®ä»£è¡šçãªãã®ã¯ãã¿ã«é ž
ãžâïŒâãšãã«ããã·ã«ããã¿ã«é žãžã€ãœãã·
ã«ããã¿ã«é žãžããªãã·ã«ããã¿ã«é žæ··åçŽéã¢
ã«ãã«ããã¿ã«é žãžã·ã¯ãããã·ã«ããã¿ã«é žãž
ãŠã³ãã·ã«ããã¿ã«é žããã«ãã³ãžã«çïŒã¢ãŒã©
ã€ã³é žãžâïŒâãšãã«ããã·ã«ãã¢ãŒã©ã€ã³é žãž
âïœâããã·ã«çãå å«ããã¢ãŒã©ã€ã³é žãšã¹ã
ã«ïŒã¢ãžãã³é žãžã€ãœãã·ã«ãã¢ãžãã³é žãžãªã¯
ãã«çãå å«ããã¢ãžãã³é žãšã¹ãã«ïŒåã³ããª
ã¡ãªããé žããªã€ãœãªã¯ãã«ãããªã¡ãªããé žã
ãªãªã¯ãã«çãå å«ããããªã¡ãªããé žãšã¹ãã«
ã§ããã äžèšæåã«å ããŠãæ¬çºæã®ããªå¡©åããã«ã
ãªããŒçµæç©ã¯ããªããŒçµæç©ã«çºç æå¶ãä»äž
ããããã«æå¹éã®æ°èŠãªçºç æå¶å€ãå«æãã
ãã®ã§ãããçºç æå¶å€ã¯äž»ãšããŠZn3Mo2O9ã»
H2OãšZnHPO3ã®æ··åç©ããæããã¢ãªããã³å¯Ÿ
ãªã³ã®ååæ¯ã¯çŽ0.5ïŒïŒããçŽ2.0ïŒïŒã§ããã
奜ãŸããã¯çŽ0.75ïŒïŒããçŽ1.5ïŒïŒã§ãããå¹
æçãªçºç æå¶ã¯æå¹ãªã¢ãªããã³äœ¿çšãšé¢é£ã
ãŠãããã¢ãªããã³å¯Ÿãªã³ã®æ¯ãçŽ0.75ïŒïŒãã
çŽ1.25ïŒïŒã®ç¯å²ã§ãããæå¹ã§ããããã«ã¯çŽ
ïŒïŒïŒã§ãå¹æçãªæå¶ãããããããã å¡©ãããªããŒçµæç©äžã®çºç æå¶å€ã®éã¯çŽ
0.1phrããçŽ20phrã§ããã奜ãŸããã¯çŽ0.2phr
ããçŽ10phrã§ãããçºç æå¶å€ã¯ååç©ããèª
äœãšããŠæ·»å ããããšãã§ããããã¿ã«ã¯ã®ãã
ãªææäžã«å±éãã圢ã§æ·»å ãããšæçã§ããã æ¬çºæã«äŸãã°ãçºç æå¶å€ã¯å¡©åºæ§çé žäºé
ã®æ°Žæ§ã¹ã©ãªãŒã§ãã€ãŠåšå²æž©åºŠããã¹ã©ãªãŒã®
沞ç¹ãŸã§ã®æž©åºŠã«ãããã®ããåºçºããŠèª¿è£œãã
ããšãã§ãããå¡©åºæ§çé žäºéã¯åœæ¥è ã«ããç¥
ãããç·ç§°ã§ãã€ãŠããããã2ZnCO3ã»3Zn
ïŒOHïŒ2ã®çµæãæããç©è³ªãæå³ããã次ãã§
ã¹ã©ãªãŒã«äžé žåã¢ãªããã³ïŒMoO3ïŒãšäºãªã³
é žããã¢ãªããã³å¯Ÿãªã³ã®ååæ¯ãçæç©äžã§çŽ
0.5ïŒïŒããçŽ2.0ïŒïŒãšãªãããã«æ·»å ãããäž
é žåã¢ãªããã³ãšããŠã¯ã奜ãŸããã¯å°ãªããšã
çŽ90ïŒ ã®äžé žåã¢ãªããã³ãå«æããççŽã®åå
ãçšããããšãã§ãããå¡©åºæ§çé žäºéãäžé žå
ã¢ãªããã³ãåã³äºãªã³é žãåå¿ããŠå®è³ªçã«å®
å šã«ææã®çæç©ãçãããäŸãã°ãå¡©åºæ§çé ž
äºéãšããŠäºéïŒã¢ã«ãäžé žåã¢ãªããã³ïŒã¢
ã«ãäºãªã³é žïŒã¢ã«ãäžç·ã«ãªã€ãŠåå¿ãããš
Zn3Mo2O9ã»H2O1ã¢ã«ãšZnHPO32ã¢ã«ã®æ··åç©
ïŒã¢ãªããã³å¯Ÿãªã³ã®æ¯ã¯ïŒïŒïŒã§ããïŒãçæ
ãããåå¿çæç©ãæ°Žæ§åªäœãããéãã也ç¥
ãããããŠããªå¡©åããã«ããªããŒçµæç©äžã«ã
ã¬ã³ãããææãšããŠé©ãããããªææã®ç²åŸã«
çŽç²ããã æ¬çºæã®çºç æå¶å€ã¯ã¿ã«ã¯ãä»ã®çŽ°ãåå²ã
ãæ äœäžã«å±éããŠèª¿åããããšãã§ãã次ãã§
å±éææãããªããŒçµæç©ã®ä»ã®æåã«æ·»å ã
ããã¿ã«ã¯å±éææäžã®Zn3Mo2O9ã»H2Oãš
ZnHPO3ã®éã¯ãããªããŒçµæç©äžãžã®çºç æå¶
å€ã®æ·»å éãåºæ¥ãã ãå¶éã§ãäžã€å質ãªåæ£
ãå¯èœãšãªãããã«éžæãããäžè¬ã«ã¯å±éææ
ã®çŽ10ééïŒ ããçŽ35ééïŒ ã§ãããå±éæ äœã¯
çºç æå¶å€åã³å±éææã«å¯ŸããŠäžæŽ»æ§ã§ãªãã
ã°ãªãããé žåäºéãæããŠããããäžã€åæ±ã
åé¡ãå®å šæ§ã®åé¡ãååšããªããã®ã§ãªããã°
ãªããªããäŸãã°ã¿ã«ã¯ãå±éæ äœãšããå Žå
ã¯ãã¢ã¹ãã¹ããå«æããŠããŠã¯ãªããªããçºç
æå¶å€ã¯å±éããŠäœ¿çšãããã©ããã«ããããã
åœæ¥è ã«å ¬ç¥ã®ãããããªæ¹æ³ã§å¡©ãããªããŒã«
çµã¿åããŠãæ¬çºæã®çºç æå¶ãããçµæç©ã補
é ããããšãã§ããã æ¬çºæã®å¥œãŸããå ·äœäŸã§ãããæ¬çºæã®çºç
æå¶å€æ·»å ç©ã調補ããæãè¯ãæ¹æ³ãæ§æãã
ãã®ã§ãããäŸã«ãããŠã¯ã现ãåå²ããã¿ã«
ã¯ã»ãšãã¹ãã³ããŒãæ°Žäžã«æžæ¿ãã該ã¹ã©ãªãŒ
ã«å¡©åºæ§çé žäºéãäžé žåã¢ãªããã³ãåã³äºãª
ã³é žãã ãããåè¿°ãããããªæ¯çã§æ·»å ãåå¿
ããã次ãã§ã¹ã©ãªãŒããéããŠçœè²ã®æµåæ§ã®
ç²åãååããçš®ã ã®å ¬ç¥ã®æ¹æ³ã«ãããã®ç²å
ãæ¬çºææžã«äŸç€ºããä»ã®ä»»æã®è¬å€ãšäžç·ã«ã
ãªå¡©åããã«ããªããŒã«é åããããšãã§ããã å±éããåã¯å±éããªãçºç æå¶å€ã®ç²ååŸã¯
ç¹ã«èšççã§ã¯ãªãããäžè¬ã«åå¿ã«å©çšã§ãã
ããã«ããããåã³ããªå¡©åããã«æš¹èãããªã
ã¯ã¹å šäœãžã®åäžãªåæ£æ§ãä¿é²ããããã«æé©
ãªå šè¡šé¢ç©ãæãããããªç²åŸåã³åœ¢ç¶ã®ç²åã
çšããããšãæãŸããã çŽ0.5ããçŽ2.0ã®ã¢ãªããã³ïŒãªã³ã®æ¯ã§äœ¿çš
ãããZn3Mo2O9ã»H2OãšZnHPO3ã®æ··åç©ãã
Zn3Mo2O9ã»H2Oåç¬ãŸãã¯ZnHPO3åç¬ãåçš
床ã®é䜿çšããå Žåã«æ¯ã¹ãŠãå¡©ãããªããŒçµæ
ç©ã«å¯ŸããŠçžä¹çã«æå¹ãªçºç æå¶å€ã§ãããšã
ãããšã¯æ³šç®ãã¹ãããšã§ãããåŸã€ãŠæ¬çºæã¯
æå®ã®ã¢ãªããã³æ¶è²»éããã€ãŠçºç æå¶å¹æã
å¢å ããæ¹æ³ãæäŸãããã®ã§ãããç¹ã«ãã
ã¯ãZnHPO3ããèªäœãç¹ã«æå¹ãªçºç æå¶å€ã§
ã¯ãªãã®ã§ãäºæ³å€ã®ããšã§ãããZnHPO3ã¯æ¬
çºæã®çµæç©ã«ãããŠæããã«åªããŠããã®ã§ã
ZnHPO3æåã¯Zn3ïŒPO4ïŒ2ã®ãããªãªã³é žå¡©åå
ç©ãšåºå¥ãããã¹ããã®ã§ããã æ¬çºæã«ãã補é ããããªå¡©åããã«ããªããŒ
çµæç©ã®çºç æå¶å€ã®ç¹åŸŽãã次ã®å®æœäŸããã€
ãŠæŽã«èª¬æãããå®æœäŸã¯èª¬æã®ããã«ããã®ã§
ãã€ãŠãæ¬çºæã®ç¯å²ãéå®ããç¹èš±è«æ±ã®ç¯å²
ãç¹å®ããããšãæå³ãããã®ã§ã¯ãªãã äŸ ïŒ ã¿ã«ã¯äžã«å±éããäž»ãšããŠZn3Mo2O9ã»H2O
ãšZnHPO3ã®æ··åç©ããæãæ¬çºæã®çºç æå¶å€
ã®ïŒãããã次ã®ããã«èª¿è£œããã çºç æå¶å€æ·»å ç© ïŒ¡ ã¿ã«ã¯äžã®Zn3Mo2O9ã»H2OãšZnHPO3ã®æ··å
ç© ã¿ã«ã¯ããã€ã¶ãŒãã¯ãã¿ã«ã¯ïŒPfizer
MicrotalcïŒMP10â52ã253.0ïœãè±ã€ãªã³æ°Ž
1180mlã«æ¹æããªããæ·»å ããåŸãããã¹ã©ãªãŒ
ã90âã«å ç±ãããããããå¡©åºæ§çé žäºéïŒé ž
åäºéå«é73.46ïŒ ã«çžåœïŒ54.1ïœãå ãã次ã
ã§30ïŒ ã®äºãªã³é ž53.3ïœã15å以äžã®æéããã
ãŠæ·»å ãããé žæ·»å çµäºåŸ10åããŠããäžé žåã¢
ãªããã³28.1ïœããã€ããæ·»å ãããããããŠè©Š
è¬ã¯äºé察ã¢ãªããã³å¯Ÿãªã³ã®ååæ¯ãçŽïŒïŒ
ïŒïŒïŒã§æ·»å ãããããšã«ãªããã¹ã©ãªãŒã90â
ã«3.5æéä¿ã€ãåŸãå·åŽãããããŠãéããã
ãéã±ãŒã¯ã110âã§äžæ©ä¹Ÿç¥ãã次ãã§200âã§
çŽïŒæé也ç¥ããã也ç¥çæç©ã¯330ïœãããã
ããä¹³é¢ãšä¹³æ£ã§ç²ç ãããçæç©äžã«äºéã
9.22ééïŒ ãã¢ãªããã³ã5.37ééïŒ ããªã³ã
1.80ééïŒ å«æãããŠãããäºé察ã¢ãªããã³å¯Ÿ
ãªã³ã®ååæ¯ã«çŽããšçŽ5.02ïŒ2.00ïŒ2.08ã§ãã€
ããåŸã€ãŠãã¿ã«ã¯äžã«å±éããçºç æå¶å€æ·»å
ç©ã¯Zn3Mo2O9ã»H2OãšZnHPO3ã®æ··åç©ãçŽ
23.8ééïŒ å«æããŠããã çºç æå¶å€æ·»å ç© ïŒ¢ ã¿ã«ã¯äžã®Zn3Mo2O9ã»H2OãšZnHPO3ã®æ··å
ç© ã¿ã«ã¯ïŒãã€ã¶ãŒãã¯ãã¿ã«ã¯MP10â52ïŒ
1518ïœãå¡©åºæ§çé žäºéïŒé žåäºéå«é73.65ïŒ
ã«çžåœïŒ323.4ïœã30ïŒ äºãªã³é ž319.8ïœãåã³äž
é žåã¢ãªããã³168.6ïœããæ·»å ç©ïŒ¡ã補é ãã
ããã«çšããæé ã«åŸã€ãŠãè±ã€ãªã³æ°Ž8.0äž
ã§çµã¿åããã也ç¥çæç©ã¯2.0Kgãããäºéã
8.93ééïŒ ãã¢ãªããã³ã5.14ééïŒ ãåã³ãªã³
ã1.67ééïŒ å«æããŠãããäºé察ã¢ãªããã³å¯Ÿ
ãªã³ã®ååæ¯ã¯5.10ïŒ2.00ïŒ2.02ã§ãã€ããåŸã€
ãŠãã¿ã«ã¯äžã«å±éããçºç æå¶å€æ·»å ç©ã¯
Zn3Mo2O9ã»H2OãšZnHPO3ã®æ··åç©çŽ22.7éé
ïŒ ãå«æããŠããã çºç æå¶å€æ·»å ç© ïŒ£ ã¿ã«ã¯äžã®Zn3Mo2O9ã»H2OãšZnHPO3ã®æ··å
ç© ã¿ã«ã¯ïŒãã€ã¶ãŒãã¯ãã¿ã«ã¯MP10â52ïŒ
34.5Kgãè±ã€ãªã³æ°Ž182ã«æ¹æããªããæ·»å ãã
åŸãããã¹ã©ãªãŒã90âã«å ç±ãããããããå¡©
åºæ§çé žäºéïŒé žåäºéå«é73.65ïŒ ã«çžåœïŒ7.3
Kgãæ·»å ãã次ãã§30ïŒ äºãªã³é ž7.3KgãïŒæé
以äžãããŠæ·»å ãããé žæ·»å çµäºåŸ10åããŠãã
äžé žåã¢ãªããã³3.8Kgã20å以äžãããŠæ·»å ã
ããããããŠè©Šè¬ã¯äºé察ã¢ãªããã³å¯Ÿãªã³ã®å
åæ¯ãïŒïŒïŒïŒïŒã§æ·»å ããããã¹ã©ãªãŒã90â
ã«3.5æéä¿ã€ãåŸãå·åŽãããéããããéã±
ãŒã¯ã110âã§16æé也ç¥ãã次ãã§200âã§ïŒæ
é也ç¥ããã也ç¥çæç©ã¯43.8Kgããã次ãã§ã
ãããã³ããŒã§ç²ç ãããçæç©ã¯äºéã8.55é
éïŒ ãã¢ãªããã³ã5.07ééïŒ ãåã³ãªã³ã1.80
ééïŒ å«æããŠãããäºé察ã¢ãªããã³å¯Ÿãªã³ã®
ååæ¯ã¯4.95ïŒ2.00ïŒ2.21ã§ãã€ããåŸã€ãŠãã¿
ã«ã¯äžã«å±éããçºç æå¶å€æ·»å ç©ã¯
Zn3Mo2O9ã»H2OãšZnHPO3ã®æ··åç©çŽ23.0éé
ïŒ ãå«æããŠããã äŸ ïŒ æ¯èŒã®ãããä»ã®ããã€ãã®çºç æå¶å€æ·»å ç©
ã次ã®æ¹æ³ã§èª¿è£œããã çºç æå¶å€æ·»å ç© ïŒ€ ã¿ã«ã¯äžã®Zn3Mo2O9ã»H2O ã¿ã«ã¯ïŒãã€ã¶ãŒãã¯ãã¿ã«ã¯MP10â52ïŒ
42.0Kgãæ°Ž208äžã«æžæ¿ãã該ã¹ã©ãªãŒã90â
ã«å ç±ãããã¹ã©ãªãŒã«å¡©åºæ§çé žäºéïŒ68.78
ïŒ é žåäºéçžåœïŒ6.5Kgãå ããããããäºé žå
ççŽ ã®çºçãèæ ®ããŠäžé žåã¢ãªããã³5.3Kgã
åŸã ã«æ·»å ãããè©Šè¬ã®äºé察ã¢ãªããã³ã®åå
æ¯ã¯çŽïŒïŒïŒã§ãã€ãã90âã§ïŒæéä¿ã€ãåŸã
åŸãããæ··åç©ãå·åŽãããéããŠååããåºäœ
ãçŽ115âã§äžæ©ä¹Ÿç¥ãããããã200âã§ïŒæé
也ç¥ããã也ç¥çæç©ããã³ããŒã§ç²ç ãã
Zn3Mo2O9ã»H2OçŽ18.5ééïŒ å«æããçœè²ã®ã
ãããããç²å50.9Kgãçæãããçæç©ã¯äºé
6.74ééïŒ ãåã³ã¢ãªããã³6.30ééïŒ ãå«æã
ãŠããã çºç æå¶å€æ·»å ç© ïŒ¥ ã¿ã«ã¯äžã®ZnHPO3 ã¿ã«ã¯ïŒãã€ã¶ãŒãã¯ãã¿ã«ã¯MP10â52ïŒ
253.0ïœãè±ã€ãªã³æ°Ž1180mlã«æ¹æããªããæ·»å
ããåŸãããã¹ã©ãªãŒã90âã«å ç±ãããããã
ãå¡©åºæ§çé žäºéïŒé žåäºéå«æé73.65ïŒ ã«çž
åœïŒ54.0ïœãæ·»å ãã次ãã§30ïŒ äºãªã³é ž133.6
ïœã25å以äžã®æéããããŠæ·»å ãããã¹ã©ãªãŒ
ã90âã«3.5æéä¿ã€ãåŸãå·åŽãããéããã
ãéã±ãŒã¯ãçŽ110âã§äžæ©ä¹Ÿç¥ãããããã200
âã§2.5æé也ç¥ããã也ç¥çæç©ã¯319ïœããã
ãããä¹³é¢ãšä¹³æ£ã§ç²ç ãããã¿ã«ã¯äžã«å±éã
ãçæç©ã¯äºé9.17ééïŒ åã³ãªã³4.60ééïŒ ã
å«æããŠãããåŸã€ãŠZnHPO3çŽ20ééïŒ ãå«æ
ããŠããã çºç æå¶å€æ·»å ç© ïŒŠ ã¿ã«ã¯äžã®Zn3Mo2O9ã»H2OãšZn3ïŒPO4ïŒ2ã»
2H2Oã®æ··åç© ãã®çæç©ã¯ãæ·»å ç©ïŒ¡ã補é ããããã«çšã
ãæ¹æ³ã«åŸã€ãŠãäºãªã³é žïŒH3PO3ïŒã«ä»£ããŠ
ãªã³é žïŒH3PO4ïŒã䜿çšããç¹ã ããéããŠã
補é ããã也ç¥çæç©ã¯328ïœãããäºé10.4é
éïŒ ãã¢ãªããã³5.4ééïŒ ãåã³ãªã³1.75éé
ïŒ ãå«æããŠãããåŸã€ãŠZn3Mo2O9ã»H2Oãš
Zn3ïŒPO4ïŒ2ã»2H2Oã®æ··åç©ãçŽ26ééïŒ å«æã
ãŠããã çºç æå¶å€æ·»å ç© ïŒ§ ã¿ã«ã¯äžã®ZnMoO4ã»0.8H2O ã¿ã«ã¯ïŒãã€ã¶ãŒãã¯ãã¿ã«ã¯MP10â52ïŒ1.8
Kgãè±ã€ãªã³æ°Ž7.0ã«æ¹æããªããæ·»å ããåŸ
ãããã¹ã©ãªãŒã90âã«å ç±ãããããããå¡©åº
æ§çé žäºéïŒé žåäºéå«é73.1ïŒ ã«çžåœïŒ0.21Kg
ãæ·»å ãã次ãã§äžé žåã¢ãªããã³0.27KgãåŸã
ã«å ããŠãäºé察ã¢ãªããã³ã®ååæ¯ãçŽïŒïŒïŒ
ãšããã該ã¹ã©ãªãŒã90âã«ïŒæéä¿ã€ãåŸãå·
åŽãããéããããéã±ãŒã¯ã110âã§äžæ©ä¹Ÿç¥
ãããããã200âã§ïŒæé也ç¥ããã也ç¥çæ
ç©ã¯2.11Kgãããããããã³ããŒã§ç²ç ãããç
æç©ã¯äºé5.3ééïŒ åã³ã¢ãªããã³7.4ééïŒ ã
å«æããŠãããäºé察ã¢ãªããã³ã®ååæ¯ã¯
1.05ïŒïŒã§ãã€ããåŸã€ãŠããã®ã¿ã«ã¯äžã«å±é
ããçºç æå¶å€æ·»å ç©ã¯ZnMoO4ã»0.8H2OãçŽ
18.5ééïŒ å«æããŠããã æ¬çºæã®çºç æå¶å€ã®æ¹åãããç¹æ§ãæãã
ã«ããããã«ãäžè¬ã«èªããããããã€ãã®ç°ãª
ã€ãçºç è©Šéšãè¡ã€ããè©Šéšæ¹æ³ã®æŠèŠã¯æ¬¡ã®é
ãã§ããã ã¢ã©ãããŒïŒArapahoeïŒãã¹ãïŒ å°ããªè©ŠæïŒ1.5Ã0.5Ã0.125ã€ã³ãå³ã¡3.8Ã
1.3Ã0.3cmïŒãå¯é宀å ã§ãããã³çãçšããŠ30
ç§éççŒãããççŒçæç©ãã¬ã©ã¹ç¹ç¶ã®ãçŽã
éããŠé£ç¶çã«ç空åžåŒããããçŽã®ééå¢å ã«
ãã€ãŠç ã®ééã枬å®ãããè©Šæã®ãã¹ãååŸã®
ééå·®ã«ãã€ãŠè©Šæã®æ¶è²»éãå®ãŸãããã¹ãçµ
æã¯è©Šæã®æ¶è²»éã«å¯Ÿããç ã®ééæ¯ããã€ãŠã
çºç ããŒã»ã³ããšããŠè¡šããã NBSã»ã¹ã¢ãŒã¯ã»ãã€ã³ããŒã»ãã¹ã ïŒASTM â662â79ïŒïŒ ïŒã€ã³ãå¹³æ¹ã®è©Šçãå®å šã«å¯éããç®±ïŒäŸã
ã°36Ã24Ã36ã€ã³ãïŒå ã®ãã¬ãŒã ã«åçŽã«æ¯æ
ããããŠãè©Šçå ã®6.57å¹³æ¹ã€ã³ãé åã«ç±ãã
ãŠããç±æºã¯ããçã®ãã¹ãã§ã¯é»æ°çã§ãã€ã
ããè©Šæçè¡šé¢ã«å¯ŸããŠçºçççŒã®æ¡ä»¶äžã§å¹³æ¹
ã»ã³ãã¡ãŒãã«åœã2.5ã¯ããã®ç±ç·æãããã
ããã«èª¿æŽãããè©Šçäžã®äžèšé åã®å åžåãæš
æºå 床èšã䜿çšããŠæž¬å®ãããç çºçãå¢å ãã
ãšå åžåã倧ãããªãããã¹ãçµæã¯å¹ŸäœåŠçå
åãšæž¬å®ããå åŠæ¿åºŠããå°ããæ倧æ¯å åŠå¯åºŠ
ãšããŠè¡šããã ãªãã€ãªã»ã¹ããŒãã»ã¬ãªãŒãºã»ã¬ã€ãã»ãã¹
ãïŒOSRRãã¹ãïŒïŒ ïŒã€ã³ãå¹³æ¹ã§åãã3.2mmïŒ1/8ã€ã³ãïŒã®è©Š
çãäžå®ã®ç©ºæ°æµéãæãã宀å ã«åçŽã«æ¯æã
ããããè©Šçã«æå®ã®ç±ç·æãããŠãè©Šçã®åºèŸº
ã®äžå€®ã«å°ããªç¹ç«çãã¶ã€ãããçºçããç ã®
éãã»ãå ã®ããã»ã«ã«ãã€ãŠæž¬å®ããæéã®åœ
æ°ãšããŠãããããããçºç ããŒã¿ã¯ãã¹ã¢ãŒ
ã¯ãåäœã§è¡šãããããã¹ã¢ãŒã¯ãåäœã¯ãç«æ¹
ç±³åœãïŒã¹ã¢ãŒã¯ã®æ¿åºŠãæãã空æ°ã¯çåç®ç
ã§å ééçã10ïŒ æžãããããªïŒå³ã¡å ééç80
ïŒ ãã70ïŒ ãžããŸãã¯45ïŒ ãã35ïŒ ãžïŒãã®ãšã
ãŠå®çŸ©ããããå€ã¯äžå®æéå ã«çºçããåã¯ç±
ç·ãããŠãŠããæéã«çºçããããŒã¿ã«ã¹ã¢ãŒã¯
ãšããŠãšãããã 次ã®å®æœäŸã«ãããŠãçºç æå¶å€æ·»å ç©ã®æ·»å
ã¯ã¿ã«ã¯ãããŒã¹ã«ããææã®phrã§è¡šç€ºãããŠ
ããã掻æ§æåã®phrã¯ã¿ã«ã¯ãããŒã¹ã«ããæ
æã®æ·»å ç©å«æéããå°ãããšãã§ããã äŸ ïŒ æ¬¡ã®æåãæãã硬質塩ãå°ç®¡é åç©ã«ãããŠ
ãããããªæ·»å ç©ã®çºç æå¶å¹æã枬å®ããã ããªå¡©åããã«æš¹èïŒgeon103EP F76ïŒã°ã
ããªããç€Ÿè£œïŒ 100éééš ã³ãŒããããã¯ã€ãã³ã°ïŒå å¡«å€ïŒ 25éééš ïŒOmyalite90TïŒOmya補ïŒå å·¥å©å€
ïŒAcryloid K120NïŒããŒã ïŒãã¹ç€Ÿè£œïŒ
ïŒéééš é«å®å®å€ïŒThermolite31ïŒïŒïŒïŒŽã±ãã«ã«ãº
ç€Ÿè£œïŒ ïŒéééš æ»å€ïŒPlastiflow POPïŒNLã€ã³ãã¹ããªãŒç€Ÿ
è£œïŒ 0.6éééš æ»å€ïŒã¹ãã¢ãªã³é žã«ã«ã·ãŠã ïŒ 0.8éééš æ»å€ïŒLubricin25ïŒNLã€ã³ãã¹ããªãŒç€Ÿè£œïŒ
0.5éééš ãã®é åç©ã«ãããããªæ·»å ç©ãæ·»å ãããã®
åã³æ·»å ããªããã®ã«ã€ããŠã®ç çºçããåè¿°ã®
äžçš®ã®ãã¹ãæ¹æ³ã§æž¬å®ããã®ã§ããã®çµæãè¡š
ïŒã«ç€ºãã è¡šïŒã®ããŒã¿ããæ¬çºæã®Zn3Mo2O9ã»H2Oå
ã³ZnHPO3ãå«æããå¡©ãçµæç©ã¯ä»ã®æ·»å ç©ã
å«æããå¡©ãçµæç©ããææã«åªããçºç æå¶å¹
æãæããŠãããšããããšãå€ããå®éãæ·»å ç©
ïŒïŒ¢åã³ïŒ£ã®å¹æãæ·»å ç©ïŒ€åã³ïŒ¥ãšæ¯èŒãã
ãšãæ¬çºæã¯ãZn3Mo2O9ã»H2Oåç¬åã³
ZnHPO3åç¬ã«ãã€ãŠãããããã以äžã®äžã€ã
ãçäºã€ã®åç¬ååç©ãããããçºç æžå°å¹æã
å ç®ããããšããæåŸ ããã以äžã®ãåªããçºç
æå¶ãä»äžãããã®ã§ãããšäºãããšãæãããš
ãªããäŸãã°è¡šïŒãåç §ã«ãããšãæ·»å ç©ïŒ¡ïŒæ¬
çºæã®çºç æå¶å€ïŒã¯38ïŒ ã®çºç æžå°å¹æãã
ããäžæ¹åãçšåºŠã®çºç æžå°ãéæããããã«ã¯
æ·»å ç©ïŒ€åã³æ·»å ç©ïŒ¥ããããã10phrãã€äžç·
ã«æ·»å ããããã«äºåã®æ·»å ç©ã䜿çšããªããã°
ãªããªããã®ãšäºæ³ãããã¯ãã§ããããããã
ååç©ã®åã ã«èããããç¹æ§ãå ç®ããŠã®äºæ³
ã¯ã¯ãããæ¬çºæã¯æåŸ ä»¥äžã®å¹æãæãããåŸ
ã€ãŠæ¬çºæã¯çžä¹çå¹æãæãäžã€åŸæ¥æè¡ãã
ã¯äºæ³ã§ããªãçºæãšäºããããåŸãªãã
ãè¡šã
ãè¡šã
äŸ ïŒ
次ã®æåãæããå¯å¡åå¡©ãå€è¢«é
åç©ã«ã€ã
ãŠæ¬çºæã®çºç æå¶å€ã®ç¹æ§ããã¹ãããã ããªå¡©åããã«æš¹èïŒgeon103EP F76ïŒã°ã
ããªããç€Ÿè£œïŒ 100éééš ãã¿ã«é žæ··åã¢ã«ãã«ïŒå¯å¡å€ïŒ
ïŒSanticizer711ïŒã¢ã³ãµã³ãç€Ÿè£œïŒ 40éééš ã¢ã«ããäžæ°Žåç©ïŒå å¡«å€ïŒïŒHydral710ïŒã¢
ã«ããã»ã«ã³ãããŒã»ãªãã»ã¢ã¡ãªã«ç€Ÿè£œïŒ
15éééš äžå¡©åºæ§ç¡«é žéïŒç±å®å®å€ïŒïŒTribase XLïŒ
NLã€ã³ãã¹ããªãŒç€Ÿè£œïŒ ïŒéééš ã¯ãã¯ã¹ 0.5éééš ã¹ãã¢ãªã³é žéïŒå å·¥æ»å€ïŒïŒDSâ207ïŒNLã€
ã³ãã¹ããªãŒç€Ÿè£œïŒ 0.2éééš æ»å€ïŒPlastiflow POPïŒNLã€ã³ãã¹ããªãŒç€Ÿ
è£œïŒ 0.2éééš Sb2O3ïŒé£çå€ïŒ ïŒéééš ãã®é åç©ã«ããããã®æ·»å ç©ãæ·»å ãããã®
åã³æ·»å ããªããã®ã«ã€ããŠã®ç çºçããåè¿°ã®
äžçš®ã®ãã¹ãæ¹æ³ã§æž¬å®ããã®ã§ããã®çµæãè¡š
ïŒã«ç€ºãã å床ãæ¬çºæã®æ°èŠãªçºç æå¶å€ã®åªããçžä¹
çå¹æã¯ãZn3Mo2O9ã»H2Oåã³ZnHPO3ããæ
ãæ·»å ç©ïŒ¡ïŒïŒ¢åã³ïŒ£ããããããã«åé¢ããå
ç¬æåããæãæ·»å ç©ïŒ€åã³ïŒ¥ãšæ¯èŒããããšã«
ããæããã§ããã
ãŠæ¬çºæã®çºç æå¶å€ã®ç¹æ§ããã¹ãããã ããªå¡©åããã«æš¹èïŒgeon103EP F76ïŒã°ã
ããªããç€Ÿè£œïŒ 100éééš ãã¿ã«é žæ··åã¢ã«ãã«ïŒå¯å¡å€ïŒ
ïŒSanticizer711ïŒã¢ã³ãµã³ãç€Ÿè£œïŒ 40éééš ã¢ã«ããäžæ°Žåç©ïŒå å¡«å€ïŒïŒHydral710ïŒã¢
ã«ããã»ã«ã³ãããŒã»ãªãã»ã¢ã¡ãªã«ç€Ÿè£œïŒ
15éééš äžå¡©åºæ§ç¡«é žéïŒç±å®å®å€ïŒïŒTribase XLïŒ
NLã€ã³ãã¹ããªãŒç€Ÿè£œïŒ ïŒéééš ã¯ãã¯ã¹ 0.5éééš ã¹ãã¢ãªã³é žéïŒå å·¥æ»å€ïŒïŒDSâ207ïŒNLã€
ã³ãã¹ããªãŒç€Ÿè£œïŒ 0.2éééš æ»å€ïŒPlastiflow POPïŒNLã€ã³ãã¹ããªãŒç€Ÿ
è£œïŒ 0.2éééš Sb2O3ïŒé£çå€ïŒ ïŒéééš ãã®é åç©ã«ããããã®æ·»å ç©ãæ·»å ãããã®
åã³æ·»å ããªããã®ã«ã€ããŠã®ç çºçããåè¿°ã®
äžçš®ã®ãã¹ãæ¹æ³ã§æž¬å®ããã®ã§ããã®çµæãè¡š
ïŒã«ç€ºãã å床ãæ¬çºæã®æ°èŠãªçºç æå¶å€ã®åªããçžä¹
çå¹æã¯ãZn3Mo2O9ã»H2Oåã³ZnHPO3ããæ
ãæ·»å ç©ïŒ¡ïŒïŒ¢åã³ïŒ£ããããããã«åé¢ããå
ç¬æåããæãæ·»å ç©ïŒ€åã³ïŒ¥ãšæ¯èŒããããšã«
ããæããã§ããã
ãè¡šã
äŸ ïŒ
次ã®æåãæããå¯å¡åå¡©ãç·æé
åç©ã«ã€ã
ãŠãããããªæ·»å ç©ã®çºç æå¶å¹æã枬å®ããã ããªå¡©åããã«æš¹èïŒgeon103EP F76ïŒã°ã
ããªããç€Ÿè£œïŒ 100éééš ãã¿ã«é žãžã€ãœãã·ã«ïŒå¯å¡å€ïŒ 30éééš äžå¡©åºæ§ç¡«é žéïŒç±å®å®å€ïŒïŒTribase XLïŒ
NLã€ã³ãã¹ããªãŒç€Ÿè£œïŒ ïŒéééš ã¯ãã¯ã¹ïŒæ»å€ïŒïŒAcrowax ïŒã°ãªã³ã»ã±
ãã«ã«ãºç€Ÿè£œïŒ 0.4éééš ã¹ãã¢ãªã³é žéïŒæ»å€ïŒïŒDSâ207ïŒNLã€ã³ã
ã¹ããªãŒç€Ÿè£œïŒ 0.4éééš Sb2O3ïŒé£çå€ïŒ ïŒéééš ãã®é åç©ã«ããããã®æ·»å ç©ãæ·»å ãããã®
åã³æ·»å ããªããã®ã«ã€ããŠã®ç çºçããåè¿°ã®
äžçš®ã®ãã¹ãæ¹æ³ã§æž¬å®ããã®ã§ããã®çµæãè¡š
ïŒã«ç€ºããè¡šïŒããæ¬çºæã«ãã€ãŠçºç æå¶ã«ã
ããææãªãããŠäºæ³ã§ããªãæ¹åããªããããš
ããããšãå€ãã
ãŠãããããªæ·»å ç©ã®çºç æå¶å¹æã枬å®ããã ããªå¡©åããã«æš¹èïŒgeon103EP F76ïŒã°ã
ããªããç€Ÿè£œïŒ 100éééš ãã¿ã«é žãžã€ãœãã·ã«ïŒå¯å¡å€ïŒ 30éééš äžå¡©åºæ§ç¡«é žéïŒç±å®å®å€ïŒïŒTribase XLïŒ
NLã€ã³ãã¹ããªãŒç€Ÿè£œïŒ ïŒéééš ã¯ãã¯ã¹ïŒæ»å€ïŒïŒAcrowax ïŒã°ãªã³ã»ã±
ãã«ã«ãºç€Ÿè£œïŒ 0.4éééš ã¹ãã¢ãªã³é žéïŒæ»å€ïŒïŒDSâ207ïŒNLã€ã³ã
ã¹ããªãŒç€Ÿè£œïŒ 0.4éééš Sb2O3ïŒé£çå€ïŒ ïŒéééš ãã®é åç©ã«ããããã®æ·»å ç©ãæ·»å ãããã®
åã³æ·»å ããªããã®ã«ã€ããŠã®ç çºçããåè¿°ã®
äžçš®ã®ãã¹ãæ¹æ³ã§æž¬å®ããã®ã§ããã®çµæãè¡š
ïŒã«ç€ºããè¡šïŒããæ¬çºæã«ãã€ãŠçºç æå¶ã«ã
ããææãªãããŠäºæ³ã§ããªãæ¹åããªããããš
ããããšãå€ãã
ãè¡šã
Claims (1)
- ãç¹èš±è«æ±ã®ç¯å²ã ïŒ ããªããŒçµæç©ã«çºç æå¶ãä»äžããããã®
çºç æå¶å€ãæ¬è³ªçã«Zn3Mo2O9ã»H2Oãš
ZnHPO3ã®æ··åç©ããæãã¢ãªããã³å¯Ÿãªã³ã®å
åæ¯ãçŽ0.5ïŒïŒããçŽ2.0ïŒïŒã§ããããšãç¹åŸŽ
ãšãããæ¬è³ªçã«ããªå¡©åããã«ããªããŒåã³å°
éã®ãããæå¹éã®çºç æå¶å€ããæãçºç æå¶
ããã硬質ãŸãã¯å¯å¡åããªå¡©åããã«ããªããŒ
çµæç©ã ïŒ ã¢ãªããã³å¯Ÿãªã³ã®ååæ¯ãçŽ0.75ïŒïŒãã
çŽ1.5ïŒïŒã§ããããšãç¹åŸŽãšãããç¹èš±è«æ±ã®
ç¯å²ç¬¬ïŒé èšèŒã®çµæç©ã ïŒ ã¢ãªããã³å¯Ÿãªã³ã®ååæ¯ãçŽ0.75ïŒïŒãã
çŽ1.25ïŒïŒã§ããããšãç¹åŸŽãšãããç¹èš±è«æ±ã®
ç¯å²ç¬¬ïŒé èšèŒã®çµæç©ã ïŒ ã¢ãªããã³å¯Ÿãªã³ã®ååæ¯ãçŽïŒïŒïŒã§ãã
ããšãç¹åŸŽãšãããç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒé èšèŒã®
çµæç©ã ïŒ çºç æå¶å€ãçµæç©äžã«çŽ0.1phrããçŽ
20phrã®éã§ååšããããšãç¹åŸŽãšãããç¹èš±è«
æ±ã®ç¯å²ç¬¬ïŒé ãã第ïŒé èšèŒã®ããããã®çµæ
ç©ã ïŒ çºç æå¶å€ãçŽ0.2phrããçŽ10phrã®éã§å
åšããããšãç¹åŸŽãšãããç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒé
èšèŒã®çµæç©ã ïŒ çºç æå¶å€ãç²ç¶æ äœäžã«å±éãããŠããã
ãšãç¹åŸŽãšããç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒé ãã第ïŒé
èšèŒã®ããããã®çµæç©ã
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US06/216,894 US4328152A (en) | 1980-12-16 | 1980-12-16 | Polyvinyl chloride polymer compositions containing trizinc dimolybdate monohydrate and zinc phosphite for smoke suppression |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS57121044A JPS57121044A (en) | 1982-07-28 |
| JPS6332096B2 true JPS6332096B2 (ja) | 1988-06-28 |
Family
ID=22808902
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP56196723A Granted JPS57121044A (en) | 1980-12-16 | 1981-12-07 | Polyvinyl chloride polymer composition containing smoke suppressant |
Country Status (4)
| Country | Link |
|---|---|
| US (1) | US4328152A (ja) |
| EP (1) | EP0054742B1 (ja) |
| JP (1) | JPS57121044A (ja) |
| DE (1) | DE3171728D1 (ja) |
Families Citing this family (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA1275528C (en) * | 1984-05-14 | 1990-10-23 | Allied Corporation | Flame retardant polyamide fiber and carpet |
| US4965309A (en) * | 1987-11-04 | 1990-10-23 | H. B. Fuller Company | Smoke suppressant compositions for halogen-containing plastics and methods of using |
| US4892683A (en) * | 1988-05-20 | 1990-01-09 | Gary Chemical Corporation | Flame retardant low smoke poly(vinyl chloride) thermoplastic compositions |
| CA2028191C (en) * | 1989-10-23 | 2001-04-24 | Ahmed Sharaby | Non-toxic corrosion inhibitive compositions and methods therefor |
| US5686055A (en) * | 1993-12-27 | 1997-11-11 | Mazda Motor Corporation | Process for recovering phthalic anhydride and hydrogen chloride from plastic materials |
| WO1999001507A1 (en) * | 1997-07-02 | 1999-01-14 | Sumitomo Bakelite Company, Ltd. | Epoxy resin compositions for encapsulating semiconductors, and semiconductor devices |
| US7763345B2 (en) | 1999-12-14 | 2010-07-27 | Mannington Mills, Inc. | Thermoplastic planks and methods for making the same |
| US8028486B2 (en) | 2001-07-27 | 2011-10-04 | Valinge Innovation Ab | Floor panel with sealing means |
| SE530653C2 (sv) | 2006-01-12 | 2008-07-29 | Vaelinge Innovation Ab | FuktsÀker golvskiva samt golv med ett elastiskt ytskikt omfattande ett dekorativt spår |
| US8277703B2 (en) * | 2010-04-23 | 2012-10-02 | J. M. Huber Corporation | Smoke suppressants |
| DE102021202508A1 (de) | 2021-03-15 | 2022-09-15 | Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung eingetragener Verein | Verwendung einer Stabilisatorzusammensetzung zur Stabilisierung von Polyolefin-Recyclaten, Stabilisatorzusammensetzung, Masterbatchkonzentrat, Kunststoffzusammensetzung, Formmasse oder Formteil, Verfahren zur Stabilisierung eines Polyolefin-Recyclats sowie Verwendung einer Kunststoffzusammensetzung |
| WO2022251063A1 (en) * | 2021-05-25 | 2022-12-01 | J.M. Huber Corporation | Supported zinc dimolybdate hydroxide / silica complexes and uses thereof in polymer formulations |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3741893A (en) * | 1971-10-08 | 1973-06-26 | Air Prod & Chem | Flame retardant comprising supported antimony tetroxide |
| US3900441A (en) * | 1973-03-12 | 1975-08-19 | Armstrong Cork Co | Zinc and molybdenum-containing compounds as smoke depressants for poly(vinyl chloride) resin compositions |
| US3945974A (en) * | 1973-12-20 | 1976-03-23 | N L Industries, Inc. | Smoke suppressants for halogen-containing plastic compositions |
| US4098748A (en) * | 1976-08-16 | 1978-07-04 | Amax Inc. | Plasticized polyvinyl chloride resin composition containing molybdenum flame retardant and antimony compound smoke suppressant agent |
| US4098753A (en) * | 1976-08-16 | 1978-07-04 | Amax Inc. | Ester-plasticized polyvinyl chloride resin composition containing molybdenum flame retardant and smoke suppressant agent |
-
1980
- 1980-12-16 US US06/216,894 patent/US4328152A/en not_active Expired - Fee Related
-
1981
- 1981-11-05 DE DE8181109532T patent/DE3171728D1/de not_active Expired
- 1981-11-05 EP EP81109532A patent/EP0054742B1/en not_active Expired
- 1981-12-07 JP JP56196723A patent/JPS57121044A/ja active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| EP0054742A2 (en) | 1982-06-30 |
| EP0054742A3 (en) | 1982-10-20 |
| US4328152A (en) | 1982-05-04 |
| EP0054742B1 (en) | 1985-08-07 |
| JPS57121044A (en) | 1982-07-28 |
| DE3171728D1 (en) | 1985-09-12 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| EP2875069B1 (en) | Pvc flame retardant compositions | |
| US4098748A (en) | Plasticized polyvinyl chloride resin composition containing molybdenum flame retardant and antimony compound smoke suppressant agent | |
| JP2015522691A5 (ja) | ||
| JPS6332096B2 (ja) | ||
| GB2075989A (en) | Stabilized thermoplastic resin compositions | |
| JPS601241A (ja) | é£çæ§æš¹èçµæç© | |
| US3996142A (en) | Smoke and fire retardants for halogen-containing plastic compositions comprising the reaction product of magnesium oxide and a zinc salt of an acid | |
| US3870679A (en) | Smoke retardant vinyl halide polymers | |
| JPH062843B2 (ja) | é£çå€ããã³é£çæ§æš¹èçµæç© | |
| GB1561016A (en) | Fire-retardant thermoplastic resin composition | |
| US3965068A (en) | Smoke retardant vinyl chloride and vinylidene chloride polymer compositions | |
| EP0427173B1 (en) | Self-extinguishing polymeric compositions | |
| US4098753A (en) | Ester-plasticized polyvinyl chloride resin composition containing molybdenum flame retardant and smoke suppressant agent | |
| US5190700A (en) | Flame retardant for halogen-containing vinyl resins | |
| US3956231A (en) | Flame and smoke retardant styrene polymer composition | |
| US3741893A (en) | Flame retardant comprising supported antimony tetroxide | |
| US4464502A (en) | Low smoke plasticized polyvinyl chloride | |
| US4507414A (en) | Smoke retardant vinyl halide polymer compositions | |
| US4965309A (en) | Smoke suppressant compositions for halogen-containing plastics and methods of using | |
| JPS6049219B2 (ja) | èçæ§ããã³èçºç æ§ãæ¹è¯ããå¡©åããã«ããªãâçµæç© | |
| US3546160A (en) | Self-extinguishing styrene/acrylonitrile-copolymers | |
| US4053451A (en) | Smoke retardant vinyl chloride and vinylidene chloride polymer compositions | |
| JPH0341132A (ja) | é£çå€ããã³é£çæ§æš¹èçµæç© | |
| US3644589A (en) | Method of imparting self-extinguishing flame properties to impact-modified polyvinyl chloride | |
| EP0596020A1 (en) | Stabilizer composition and polymer compositions stabilized therewith |