JPS63314233A - メルカプタン末端硬化性液体共重合体 - Google Patents
メルカプタン末端硬化性液体共重合体Info
- Publication number
- JPS63314233A JPS63314233A JP63135360A JP13536088A JPS63314233A JP S63314233 A JPS63314233 A JP S63314233A JP 63135360 A JP63135360 A JP 63135360A JP 13536088 A JP13536088 A JP 13536088A JP S63314233 A JPS63314233 A JP S63314233A
- Authority
- JP
- Japan
- Prior art keywords
- mercaptan
- epoxy
- adduct
- terminated polymer
- viscosity
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000007788 liquid Substances 0.000 title claims description 39
- 229920001577 copolymer Polymers 0.000 title claims description 15
- 229920000642 polymer Polymers 0.000 claims description 67
- LSDPWZHWYPCBBB-UHFFFAOYSA-N Methanethiol Chemical compound SC LSDPWZHWYPCBBB-UHFFFAOYSA-N 0.000 claims description 56
- 239000004593 Epoxy Substances 0.000 claims description 35
- 239000003795 chemical substances by application Substances 0.000 claims description 22
- 239000007787 solid Substances 0.000 claims description 22
- 238000000034 method Methods 0.000 claims description 19
- 238000006243 chemical reaction Methods 0.000 claims description 17
- 239000000126 substance Substances 0.000 claims description 13
- 125000003700 epoxy group Chemical group 0.000 claims description 10
- 238000004519 manufacturing process Methods 0.000 claims description 10
- 239000003054 catalyst Substances 0.000 claims description 8
- 229920001400 block copolymer Polymers 0.000 claims description 3
- 239000012265 solid product Substances 0.000 claims description 3
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims 2
- 239000000203 mixture Substances 0.000 description 45
- 229920001021 polysulfide Polymers 0.000 description 39
- 229920000647 polyepoxide Polymers 0.000 description 32
- 150000008117 polysulfides Polymers 0.000 description 27
- 239000005077 polysulfide Substances 0.000 description 26
- 238000009472 formulation Methods 0.000 description 20
- 239000000047 product Substances 0.000 description 20
- 239000003973 paint Substances 0.000 description 16
- 238000003860 storage Methods 0.000 description 16
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 15
- 125000000466 oxiranyl group Chemical group 0.000 description 15
- 239000003822 epoxy resin Substances 0.000 description 14
- 238000012360 testing method Methods 0.000 description 12
- 239000011248 coating agent Substances 0.000 description 11
- 238000000576 coating method Methods 0.000 description 11
- 150000002118 epoxides Chemical class 0.000 description 11
- 229920005989 resin Polymers 0.000 description 11
- 239000011347 resin Substances 0.000 description 11
- 239000010408 film Substances 0.000 description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 9
- LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical compound C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 description 8
- 238000002156 mixing Methods 0.000 description 8
- 239000007921 spray Substances 0.000 description 8
- 238000005299 abrasion Methods 0.000 description 7
- 150000001412 amines Chemical class 0.000 description 7
- 230000015572 biosynthetic process Effects 0.000 description 7
- 239000003085 diluting agent Substances 0.000 description 7
- VILCJCGEZXAXTO-UHFFFAOYSA-N 2,2,2-tetramine Chemical compound NCCNCCNCCN VILCJCGEZXAXTO-UHFFFAOYSA-N 0.000 description 6
- 238000005260 corrosion Methods 0.000 description 6
- 230000007797 corrosion Effects 0.000 description 6
- 150000003839 salts Chemical class 0.000 description 6
- 239000000523 sample Substances 0.000 description 6
- 229960001124 trientine Drugs 0.000 description 6
- KUAUJXBLDYVELT-UHFFFAOYSA-N 2-[[2,2-dimethyl-3-(oxiran-2-ylmethoxy)propoxy]methyl]oxirane Chemical compound C1OC1COCC(C)(C)COCC1CO1 KUAUJXBLDYVELT-UHFFFAOYSA-N 0.000 description 5
- 238000005516 engineering process Methods 0.000 description 5
- 229940032007 methylethyl ketone Drugs 0.000 description 5
- 229910000831 Steel Inorganic materials 0.000 description 4
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 4
- 230000032683 aging Effects 0.000 description 4
- 239000004567 concrete Substances 0.000 description 4
- 238000004132 cross linking Methods 0.000 description 4
- 230000020169 heat generation Effects 0.000 description 4
- 238000007654 immersion Methods 0.000 description 4
- NUJOXMJBOLGQSY-UHFFFAOYSA-N manganese dioxide Chemical compound O=[Mn]=O NUJOXMJBOLGQSY-UHFFFAOYSA-N 0.000 description 4
- 239000004848 polyfunctional curative Substances 0.000 description 4
- 239000004587 polysulfide sealant Substances 0.000 description 4
- 239000000565 sealant Substances 0.000 description 4
- 239000010959 steel Substances 0.000 description 4
- 229920003319 Araldite® Polymers 0.000 description 3
- 241000238557 Decapoda Species 0.000 description 3
- 229910001209 Low-carbon steel Inorganic materials 0.000 description 3
- 239000000853 adhesive Substances 0.000 description 3
- 230000001070 adhesive effect Effects 0.000 description 3
- 230000003247 decreasing effect Effects 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 238000005538 encapsulation Methods 0.000 description 3
- 239000000499 gel Substances 0.000 description 3
- 239000012263 liquid product Substances 0.000 description 3
- 238000005259 measurement Methods 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- 230000035882 stress Effects 0.000 description 3
- 230000003442 weekly effect Effects 0.000 description 3
- 241000254173 Coleoptera Species 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 2
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 2
- 125000001931 aliphatic group Chemical group 0.000 description 2
- 238000004458 analytical method Methods 0.000 description 2
- 238000013329 compounding Methods 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 230000003750 conditioning effect Effects 0.000 description 2
- 230000032798 delamination Effects 0.000 description 2
- 238000011156 evaluation Methods 0.000 description 2
- 239000012467 final product Substances 0.000 description 2
- 238000001879 gelation Methods 0.000 description 2
- 125000003055 glycidyl group Chemical group C(C1CO1)* 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- JYGXADMDTFJGBT-VWUMJDOOSA-N hydrocortisone Chemical compound O=C1CC[C@]2(C)[C@H]3[C@@H](O)C[C@](C)([C@@](CC4)(O)C(=O)CO)[C@@H]4[C@@H]3CCC2=C1 JYGXADMDTFJGBT-VWUMJDOOSA-N 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 238000000465 moulding Methods 0.000 description 2
- 230000000704 physical effect Effects 0.000 description 2
- 239000004014 plasticizer Substances 0.000 description 2
- 239000011541 reaction mixture Substances 0.000 description 2
- 150000003512 tertiary amines Chemical class 0.000 description 2
- 238000010998 test method Methods 0.000 description 2
- 239000004408 titanium dioxide Substances 0.000 description 2
- 239000008096 xylene Substances 0.000 description 2
- DMYOHQBLOZMDLP-UHFFFAOYSA-N 1-[2-(2-hydroxy-3-piperidin-1-ylpropoxy)phenyl]-3-phenylpropan-1-one Chemical compound C1CCCCN1CC(O)COC1=CC=CC=C1C(=O)CCC1=CC=CC=C1 DMYOHQBLOZMDLP-UHFFFAOYSA-N 0.000 description 1
- XXZCIYUJYUESMD-UHFFFAOYSA-N 2-[4-[2-(2,3-dihydro-1H-inden-2-ylamino)pyrimidin-5-yl]-3-(morpholin-4-ylmethyl)pyrazol-1-yl]-1-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)ethanone Chemical compound C1C(CC2=CC=CC=C12)NC1=NC=C(C=N1)C=1C(=NN(C=1)CC(=O)N1CC2=C(CC1)NN=N2)CN1CCOCC1 XXZCIYUJYUESMD-UHFFFAOYSA-N 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- 206010053567 Coagulopathies Diseases 0.000 description 1
- BWGNESOTFCXPMA-UHFFFAOYSA-N Dihydrogen disulfide Chemical compound SS BWGNESOTFCXPMA-UHFFFAOYSA-N 0.000 description 1
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical group S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 1
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 description 1
- 239000005062 Polybutadiene Substances 0.000 description 1
- 206010037660 Pyrexia Diseases 0.000 description 1
- 206010042135 Stomatitis necrotising Diseases 0.000 description 1
- AWMVMTVKBNGEAK-UHFFFAOYSA-N Styrene oxide Chemical compound C1OC1C1=CC=CC=C1 AWMVMTVKBNGEAK-UHFFFAOYSA-N 0.000 description 1
- 102100033213 Teneurin-1 Human genes 0.000 description 1
- 229920001079 Thiokol (polymer) Polymers 0.000 description 1
- 230000006750 UV protection Effects 0.000 description 1
- GOPYZMJAIPBUGX-UHFFFAOYSA-N [O-2].[O-2].[Mn+4] Chemical class [O-2].[O-2].[Mn+4] GOPYZMJAIPBUGX-UHFFFAOYSA-N 0.000 description 1
- 238000007259 addition reaction Methods 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 239000002318 adhesion promoter Substances 0.000 description 1
- 125000002947 alkylene group Chemical group 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- 230000001588 bifunctional effect Effects 0.000 description 1
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 125000002843 carboxylic acid group Chemical group 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- XENVCRGQTABGKY-ZHACJKMWSA-N chlorohydrin Chemical compound CC#CC#CC#CC#C\C=C\C(Cl)CO XENVCRGQTABGKY-ZHACJKMWSA-N 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 230000035602 clotting Effects 0.000 description 1
- 239000008199 coating composition Substances 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 1
- GYZLOYUZLJXAJU-UHFFFAOYSA-N diglycidyl ether Chemical compound C1OC1COCC1CO1 GYZLOYUZLJXAJU-UHFFFAOYSA-N 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 230000001747 exhibiting effect Effects 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 125000000524 functional group Chemical group 0.000 description 1
- 150000002432 hydroperoxides Chemical class 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 238000005286 illumination Methods 0.000 description 1
- 238000011065 in-situ storage Methods 0.000 description 1
- 239000004850 liquid epoxy resins (LERs) Substances 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000004570 mortar (masonry) Substances 0.000 description 1
- 201000008585 noma Diseases 0.000 description 1
- 239000013307 optical fiber Substances 0.000 description 1
- 125000000962 organic group Chemical group 0.000 description 1
- 150000008116 organic polysulfides Chemical class 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 150000002978 peroxides Chemical class 0.000 description 1
- 235000021110 pickles Nutrition 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920002857 polybutadiene Polymers 0.000 description 1
- 229920006295 polythiol Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 230000004224 protection Effects 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 230000008961 swelling Effects 0.000 description 1
- 108010063973 teneurin-1 Proteins 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- KUAZQDVKQLNFPE-UHFFFAOYSA-N thiram Chemical compound CN(C)C(=S)SSC(=S)N(C)C KUAZQDVKQLNFPE-UHFFFAOYSA-N 0.000 description 1
- 229960002447 thiram Drugs 0.000 description 1
- 239000013008 thixotropic agent Substances 0.000 description 1
- 238000004627 transmission electron microscopy Methods 0.000 description 1
Landscapes
- Epoxy Resins (AREA)
- Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)
- Heterocyclic Carbon Compounds Containing A Hetero Ring Having Nitrogen And Oxygen As The Only Ring Hetero Atoms (AREA)
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB8419036 | 1984-07-26 | ||
| GB848419036A GB8419036D0 (en) | 1984-07-26 | 1984-07-26 | Liquid copolymers |
| GB8517361 | 1985-07-09 | ||
| GB08517361A GB2162189B (en) | 1984-07-26 | 1985-07-09 | Curable liquid compositions of epoxy-and mercaptan-terminated polymers |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS63314233A true JPS63314233A (ja) | 1988-12-22 |
| JPH0432087B2 JPH0432087B2 (enrdf_load_stackoverflow) | 1992-05-28 |
Family
ID=26288027
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP63135360A Granted JPS63314233A (ja) | 1984-07-26 | 1988-06-01 | メルカプタン末端硬化性液体共重合体 |
Country Status (8)
| Country | Link |
|---|---|
| JP (1) | JPS63314233A (enrdf_load_stackoverflow) |
| AU (1) | AU577398B2 (enrdf_load_stackoverflow) |
| CA (1) | CA1255040A (enrdf_load_stackoverflow) |
| DK (1) | DK339785A (enrdf_load_stackoverflow) |
| IN (1) | IN164412B (enrdf_load_stackoverflow) |
| NO (1) | NO164779C (enrdf_load_stackoverflow) |
| NZ (1) | NZ212727A (enrdf_load_stackoverflow) |
| PT (1) | PT80850B (enrdf_load_stackoverflow) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2006525390A (ja) * | 2003-05-07 | 2006-11-09 | シオプラスト ケミカル ゲーエムベーハー アンド シーオー． ケージー | ポリスルフィドとポリエポキシドとからプレポリマーを製造する方法 |
| US7196763B2 (en) | 2002-03-19 | 2007-03-27 | Lg. Philips Lcd Co., Ltd. | Liquid crystal display panel and method for fabricating the same |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2789958A (en) * | 1951-10-30 | 1957-04-23 | Thiokol Chemical Corp | Resinous reaction products of polyepoxides and polysulfide polymers and methods of making the same |
| GB787022A (en) * | 1952-12-20 | 1957-11-27 | Minnesota Mining & Mfg | Improvements in or relating to self-hardening, liquid resinous compositions and articles having the resinous composition bonded thereto |
| US3914288A (en) * | 1969-01-02 | 1975-10-21 | Ciba Geigy Ag | Reaction products of polyepoxides, mercaptoalkanoic acid esters and amines |
-
1985
- 1985-07-12 NZ NZ212727A patent/NZ212727A/xx unknown
- 1985-07-17 IN IN564/DEL/85A patent/IN164412B/en unknown
- 1985-07-17 CA CA000486937A patent/CA1255040A/en not_active Expired
- 1985-07-19 AU AU45180/85A patent/AU577398B2/en not_active Ceased
- 1985-07-23 PT PT80850A patent/PT80850B/pt not_active IP Right Cessation
- 1985-07-24 NO NO852951A patent/NO164779C/no unknown
- 1985-07-25 DK DK339785A patent/DK339785A/da not_active Application Discontinuation
-
1988
- 1988-06-01 JP JP63135360A patent/JPS63314233A/ja active Granted
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7196763B2 (en) | 2002-03-19 | 2007-03-27 | Lg. Philips Lcd Co., Ltd. | Liquid crystal display panel and method for fabricating the same |
| JP2006525390A (ja) * | 2003-05-07 | 2006-11-09 | シオプラスト ケミカル ゲーエムベーハー アンド シーオー． ケージー | ポリスルフィドとポリエポキシドとからプレポリマーを製造する方法 |
Also Published As
| Publication number | Publication date |
|---|---|
| PT80850A (en) | 1985-08-01 |
| DK339785D0 (da) | 1985-07-25 |
| NO164779B (no) | 1990-08-06 |
| AU577398B2 (en) | 1988-09-22 |
| JPH0432087B2 (enrdf_load_stackoverflow) | 1992-05-28 |
| IN164412B (enrdf_load_stackoverflow) | 1989-03-18 |
| PT80850B (pt) | 1987-09-30 |
| NO852951L (no) | 1986-01-27 |
| DK339785A (da) | 1986-01-27 |
| NO164779C (no) | 1990-11-14 |
| AU4518085A (en) | 1986-01-30 |
| NZ212727A (en) | 1988-09-29 |
| CA1255040A (en) | 1989-05-30 |
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