JPS63311A - Liquid epoxy resin composition - Google Patents
Liquid epoxy resin compositionInfo
- Publication number
- JPS63311A JPS63311A JP14127986A JP14127986A JPS63311A JP S63311 A JPS63311 A JP S63311A JP 14127986 A JP14127986 A JP 14127986A JP 14127986 A JP14127986 A JP 14127986A JP S63311 A JPS63311 A JP S63311A
- Authority
- JP
- Japan
- Prior art keywords
- epoxy resin
- resin composition
- parts
- dicyandiamide
- bisphenol
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 13
- 239000004850 liquid epoxy resins (LERs) Substances 0.000 title description 4
- 239000003822 epoxy resin Substances 0.000 claims abstract description 21
- 229920000647 polyepoxide Polymers 0.000 claims abstract description 21
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 20
- 239000002253 acid Substances 0.000 claims abstract description 9
- QGBSISYHAICWAH-UHFFFAOYSA-N dicyandiamide Chemical group NC(N)=NC#N QGBSISYHAICWAH-UHFFFAOYSA-N 0.000 claims abstract description 9
- 239000007788 liquid Substances 0.000 claims abstract description 7
- 239000011256 inorganic filler Substances 0.000 claims abstract description 6
- 229910003475 inorganic filler Inorganic materials 0.000 claims abstract description 6
- 241000287828 Gallus gallus Species 0.000 claims description 11
- 239000000945 filler Substances 0.000 claims description 7
- 239000011342 resin composition Substances 0.000 abstract description 9
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 abstract description 4
- 229930185605 Bisphenol Natural products 0.000 abstract description 2
- 239000004841 bisphenol A epoxy resin Substances 0.000 abstract description 2
- 239000004842 bisphenol F epoxy resin Substances 0.000 abstract description 2
- 239000013008 thixotropic agent Substances 0.000 abstract 2
- 238000001723 curing Methods 0.000 description 17
- 229920005989 resin Polymers 0.000 description 10
- 239000011347 resin Substances 0.000 description 10
- 239000000440 bentonite Substances 0.000 description 7
- 229910000278 bentonite Inorganic materials 0.000 description 7
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 7
- 238000010998 test method Methods 0.000 description 6
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 5
- 150000001875 compounds Chemical class 0.000 description 4
- 238000012937 correction Methods 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- -1 imide compound Chemical class 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 230000004580 weight loss Effects 0.000 description 3
- 239000004952 Polyamide Substances 0.000 description 2
- YKTSYUJCYHOUJP-UHFFFAOYSA-N [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] Chemical compound [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] YKTSYUJCYHOUJP-UHFFFAOYSA-N 0.000 description 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 2
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 2
- 239000002131 composite material Substances 0.000 description 2
- 230000006866 deterioration Effects 0.000 description 2
- 150000002460 imidazoles Chemical class 0.000 description 2
- 150000002894 organic compounds Chemical class 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 229920002647 polyamide Polymers 0.000 description 2
- 238000007665 sagging Methods 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- 230000008719 thickening Effects 0.000 description 2
- GQHTUMJGOHRCHB-UHFFFAOYSA-N 2,3,4,6,7,8,9,10-octahydropyrimido[1,2-a]azepine Chemical compound C1CCCCN2CCCN=C21 GQHTUMJGOHRCHB-UHFFFAOYSA-N 0.000 description 1
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 1
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 150000008065 acid anhydrides Chemical class 0.000 description 1
- IBVAQQYNSHJXBV-UHFFFAOYSA-N adipic acid dihydrazide Chemical compound NNC(=O)CCCCC(=O)NN IBVAQQYNSHJXBV-UHFFFAOYSA-N 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 229910052796 boron Inorganic materials 0.000 description 1
- 239000008119 colloidal silica Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical compound C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 description 1
- 238000013007 heat curing Methods 0.000 description 1
- 239000011346 highly viscous material Substances 0.000 description 1
- 150000002484 inorganic compounds Chemical class 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 239000004849 latent hardener Substances 0.000 description 1
- 239000002075 main ingredient Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 229910052901 montmorillonite Inorganic materials 0.000 description 1
- 238000013021 overheating Methods 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000000600 sorbitol Substances 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
- Epoxy Resins (AREA)
- Manufacture Of Motors, Generators (AREA)
Abstract
Description
【発明の詳細な説明】
〔産業上の利用分野〕
本発明は、回転電機用回転子の回転体における回転時の
アンバランスを是正する、いわゆるバランス取シするた
めは用いられる液状エイキシ樹脂組成物に関するもので
ある。[Detailed Description of the Invention] [Industrial Application Field] The present invention relates to a liquid eixylene resin composition used for correcting unbalance during rotation of a rotor of a rotor for a rotating electric machine, so-called balancing. It is related to.
回転電機用回転子の回転体は大きい直径を有するため、
バランスが完全にとれていないと回転時に振動が発生す
る。従来ではバランスをとるために回転体外径を切削す
る方法が多くの場合とられていた。しかし、仁の方法で
は回転時騒音を発生するため、ノζテ、鉛を貼り付けた
シビスを埋込むこと等にてバランスを取る方法も取られ
ている。Since the rotating body of the rotor for rotating electric machines has a large diameter,
If it is not perfectly balanced, vibration will occur during rotation. Conventionally, in many cases, the outer diameter of the rotating body was cut in order to maintain balance. However, since Jin's method generates noise during rotation, other methods have been used to balance the rotation by embedding lead-covered lead.
従来用いられてきた。Ｆテ状の樹脂では非常に高粘度で
あるため、手作業でバランス修正が行なわれてきた。It has been used conventionally. Because the viscosity of F-type resin is extremely high, balance correction has been performed manually.
本発明は、回転ＴＩＬ機用画用回転子転体に液状樹脂を
付着硬化させ、バランスを取る方法に用いる液状エポキ
シ樹脂に関するものであ）、自励混合吐出機を用いて自
動化できる樹脂組成物を提供するものである。The present invention relates to a liquid epoxy resin used in a method of adhering and curing a liquid resin to a drawing rotor rolling element for a rotary TIL machine to maintain balance), and a resin composition that can be automated using a self-excited mixing and discharging machine. It provides:
即ち、本発明者らは、従来高粘度・ぐテ状で自動機によ
る吐出ができなかったバランス用樹脂に代わる速硬化、
低粘度でかつタレ落ちが生じず、保存安定性の優れた樹
脂組成物を得んとして研究した結果、エポキシ樹脂、潜
在性硬化剤、無機充填材を成分とする系にて潜在性硬化
剤、チキン付与剤等の検討を行ない、保存性がよく室温
で６ケ月以上のピットライフを有しておシ、シかも低粘
度、高チキソ性かつ速硬化でおるため、硬化時にタレ落
ちがなく自動機による吐出が可能な一液性の液状エポキ
シ樹脂組成物を提供するに至ったものである。That is, the present inventors have developed a fast-curing resin that can replace the conventional balance resin, which has a high viscosity and a sticky texture and cannot be discharged by automatic machines.
As a result of research to obtain a resin composition with low viscosity, no sagging, and excellent storage stability, we developed a system containing an epoxy resin, a latent hardener, and an inorganic filler. We have investigated the use of chicken-adding agents, etc., which have good storage stability, a pit life of over 6 months at room temperature, low viscosity, high thixotropy, and quick curing. The present invention has led to the provision of a one-component liquid epoxy resin composition that can be discharged by a machine.
本発明は、回転電機用回転子の回転体における回転時の
アンバランスを是正するために用いられるエポキシ樹脂
組成物において、エポキシ樹脂、硬化剤、硬化促進剤、
無機充填材及びチキン付与剤を主成分とし、硬化剤はジ
シアンジアミド又は有機二塩基酸ジヒドラジドであって
、ニーキシ樹脂１００重量部に対しジンアンジアミド１
〜１０重量部または有機二塩基酸ジヒドラジド１〜４０
重量部を含有することを特徴とする一液性液状エポキシ
樹脂組成物である。The present invention provides an epoxy resin composition used for correcting unbalance during rotation in a rotating body of a rotor for a rotating electric machine, including an epoxy resin, a curing agent, a curing accelerator,
The main components are an inorganic filler and a chicken-adding agent, and the curing agent is dicyandiamide or organic dibasic acid dihydrazide, and 1 part of dicyandiamide is used per 100 parts by weight of Nixy resin.
~10 parts by weight or 1 to 40 parts by weight of organic dibasic acid dihydrazide
It is a one-component liquid epoxy resin composition characterized in that it contains parts by weight.
本組成物に用いられるエポキシ樹脂は室温で液状である
ことが必須の条件であシ、一般に用いられるビスフェノ
ールＡ型エポキシ樹脂等が挙げられるが、本発明の目的
とする低粘度の樹脂組成物を得るためには、ビスフェノ
ールＡ型エポキシ樹脂よυ耐熱性、耐衝撃性等の物性を
低下させない低粘度のエポキシ樹脂が好ましく、ビスフ
ェノールＦ型エポキシ樹脂もしくはビスフェノール却型
エゴキシ樹脂等が望ましい。It is essential that the epoxy resin used in this composition be liquid at room temperature, and commonly used bisphenol A type epoxy resins may be used. For this purpose, a low viscosity epoxy resin that does not reduce physical properties such as heat resistance and impact resistance is preferable than a bisphenol A epoxy resin, and a bisphenol F epoxy resin or a bisphenol oxidation resin is preferable.
硬化剤は潜在性を有するものであシ、硬化前後の重量差
が大きいとバランス取シが難しいため高温（１２０〜２
００℃）での硬化重電減少率が低いことが好ましい。The curing agent has latent properties, and if there is a large difference in weight before and after curing, it is difficult to balance the curing agent, so high temperatures (120 to 2
It is preferable that the curing heavy electric charge reduction rate at 00° C.) is low.
潜在性硬化剤として、三フフ化ホウ素−アミンアダクト
、ジシアンジアミド、二塩基酸ジヒドラジド、酸無水物
、アミン・イミド化合物、トリアジン化合物等が挙げら
れる。Examples of the latent curing agent include boron trifluoride-amine adduct, dicyandiamide, dibasic acid dihydrazide, acid anhydride, amine/imide compound, triazine compound, and the like.
これらの化合物中で、硬化時の重量減少率が低く、１２
０℃〜２００℃の条件下で３０分以内に硬化し得て、室
温で保存性の優れたものは、ジシアンジアミド及び二塩
基酸ジヒドラジドに限定される。Among these compounds, the weight loss rate during curing is low, and 12
Those that can be cured within 30 minutes under conditions of 0° C. to 200° C. and have excellent storage stability at room temperature are limited to dicyandiamide and dibasic acid dihydrazide.
ジシアンジアミドの添加量はエイキシ樹脂１００部（重
量部、以下同じ）に対して１部〜１０部である。添加量
が１部よシ少ない場合硬化が遅くなυ硬化しにくく、１
０部よシ多い場合硬化物は脆挙げられる。The amount of dicyandiamide added is 1 part to 10 parts with respect to 100 parts (parts by weight, same hereinafter) of Eixy resin. If the amount added is less than 1 part, curing will be slow υ hard to cure;
If the amount is more than 0 parts, the cured product may be brittle.
これらの化合物の中で、供給安定性及び硬化性を考える
と、アジピン酸ジヒドラジドが好ましい。Among these compounds, adipic acid dihydrazide is preferred in view of supply stability and curability.
二塩基酸ジヒドラジドの添加量はエポキシ樹脂１００部
に対して１部〜４０部である。添加量が１部より少ない
場合硬化し難く、４０部よシ多い場合硬化物が脆くなる
。The amount of dibasic acid dihydrazide added is 1 part to 40 parts per 100 parts of epoxy resin. If the amount added is less than 1 part, it will be difficult to cure, and if it is more than 40 parts, the cured product will become brittle.
動機にて混合吐出可能な粘度（４０００ｐｏｉｓｅ ７
２５℃以下）を満たすものであればよい。無機充填材の
高比重、吸油量の関係を考慮すると、シリカ系充填材、
硫酸バリウム系充填材、アルミナ系充填材、水酸化アル
ミニウム系充填材等が挙げられるが、特に好ましくは、
シリカ系充填材及びアルミナ系充填材である。Viscosity that can be mixed and discharged with a motor (4000poise 7
25°C or lower). Considering the relationship between high specific gravity and oil absorption of inorganic fillers, silica fillers,
Examples include barium sulfate-based fillers, alumina-based fillers, aluminum hydroxide-based fillers, and particularly preferably,
These are silica-based fillers and alumina-based fillers.
硬化促進剤は硬化時の重量減少率が低く耐熱性が向上す
るものが望ましく、かつ保存安定性が優れ、熱ｉｔ性の
高いものが望ましい。一般的には、アルキル尿素系化合
物、イミダゾール系化合物、ＤＢＵ（１，８−ジアゾ−
ビシクロ（５，４，０） ウンデセン−７）系化合物等
が挙げられる。本発明においてはイミダゾール系化合物
が好ましい。The curing accelerator is desirably one that exhibits a low weight loss rate during curing and improves heat resistance, and is desirably one that has excellent storage stability and high heat resistance. Generally, alkyl urea compounds, imidazole compounds, DBU (1,8-diazo-
Examples include bicyclo(5,4,0) undecene-7) compounds. In the present invention, imidazole compounds are preferred.
チキン付与剤は有機系化合物と無機系化合物を含めて非
常に多岐にわたっているが、本発明の目的とする組成物
を得るためＫは、チキン性付与効果が高く、増粘作用が
低く、高温時の重量減少率が低いものが望ましい。There are a wide variety of chicken imparting agents, including organic compounds and inorganic compounds, but in order to obtain the composition targeted by the present invention, K has a high chicken characteristic imparting effect, a low thickening effect, and a high temperature resistance. It is desirable that the weight loss rate is low.
従って、溶剤等を使用しているチキン付与剤は使えない
。無機系のチキン付与剤ではコロイダルシリカが最も良
いが、高温でのチキン性が不足しておシ、組成物でのチ
キン性の経時変化が大きく本発明には不適である。Therefore, chicken imparting agents that use solvents etc. cannot be used. Colloidal silica is the best inorganic chicken-imparting agent, but it is unsuitable for the present invention because it lacks chicken properties at high temperatures and the chicken properties of the composition change significantly over time.
有機系のチキン付与剤としては、酸化ポリエチレン、ポ
リアマイド、ペンジニリデンソルビトール、コロイド性
含水ケイ酸アルミニウムの有機複合体（オルマン）等が
考えられる。酸化、ｆ ＩＪエチレン、ポリアマイド等
では、高温（１２０〜２００℃）での熱劣化があるため
本発明の用途には不適である。本発明のチキン付与剤と
しては、高温時のチキン性が失なわれず、耐熱性を有し
、チキン性の経時変化の少ないコロイド性含水ケイ酸ア
ルミニウムの有機複合体及び有機ベントナイトが適して
いる。低粘度の組成物を得るべく検討を重ねた結果、有
機ベントナイトが最適であることを確認した。本発明に
おいて有機ベントナイトとは有機化合物で表面変性した
モンモリロナイトをいう。Possible organic chicken-imparting agents include polyethylene oxide, polyamide, pendinylidene sorbitol, and an organic composite of colloidal hydrous aluminum silicate (Olman). Oxidation, f IJ ethylene, polyamide, etc. are unsuitable for use in the present invention because they undergo thermal deterioration at high temperatures (120 to 200°C). As the chicken imparting agent of the present invention, organic composites of colloidal hydrous aluminum silicate and organic bentonite that do not lose their chicken properties at high temperatures, are heat resistant, and have little change in chicken properties over time are suitable. . As a result of repeated studies to obtain a composition with low viscosity, it was confirmed that organic bentonite is optimal. In the present invention, organic bentonite refers to montmorillonite surface-modified with an organic compound.
以上の結果よシ、チキン付与剤として有機ベントナイト
を用いた系にて添加量の検討を行なった。Based on the above results, we investigated the amount of addition in a system using organic bentonite as a chicken imparting agent.
その結果、エポキシ樹脂１００部に対し有機ベントナイ
トが８部よ）少ない場合、硬化時でのタレ落ちが生じる
ため、８部以上の添加量が必要である。また添加量を１
２部以上にすると非常に高粘度表組放物（４，０００ｐ
ｏｉｓｅ ／ ２５℃以上）になシ作業性、特に自動機
への適用が困難になる。As a result, if the amount of organic bentonite is less than 8 parts per 100 parts of epoxy resin, sagging occurs during curing, so it is necessary to add 8 parts or more. Also, the amount added is 1
If the amount is 2 parts or more, it becomes extremely viscous (4,000p).
oise / 25°C or higher), workability becomes difficult, especially application to automatic machines.
このため有機ベントナイトの添加量としては、エポキシ
樹脂１００部に対して８部から１２部が最適である。Therefore, the optimum amount of organic bentonite to be added is 8 to 12 parts per 100 parts of the epoxy resin.
回転？積用回転子の回転体における回転時のアンバラン
スを是正するために、従来は、Ｆテ状の看ざヒ
高粘度物を用いて手作業で付囃七ていたが、本発明の一
液性液状エイキシ樹脂組成物を用いれば、保存安定性が
優れているため二液性の場合のように使用時主剤・硬化
剤の配合ミスをする恐れがなく、自動吐出機によシ計量
吐出可能となシ、かつ速硬化であるためバランス是正の
自動化が可能になり、生産性が向上する。rotate? Conventionally, in order to correct the unbalance during rotation of the rotating body of the loading rotor, a highly viscous material in the shape of an F-shaped material was used to manually apply the sound. If a liquid Eixy resin composition is used, it has excellent storage stability, so there is no risk of mixing the main ingredient or curing agent when using it, unlike in the case of two-component products, and it can be dispensed metered using an automatic dispensing machine. Because it is thin and hardens quickly, it is possible to automate balance correction, improving productivity.
なお、本発明の一液性液状エデキシ樹脂組成物のチキン
付与剤として有機ベントナイトを使用すれば、室温付近
の増粘作用が小さいので、自動吐出機使用時の作業性が
優れておシ、高温時においてもチキン性が失われず加熱
硬化時にタレ落ちが生じない。In addition, if organic bentonite is used as the chicken-imparting agent in the one-component liquid edexy resin composition of the present invention, the thickening effect at around room temperature is small, so the workability when using an automatic dispensing machine is excellent. It does not lose its chicken properties even when heated and does not drip off during heat curing.
実施例及び比較例を以下に示す。 Examples and comparative examples are shown below.
第１表に示すような配合の樹脂組成物を混合し、特性比
較を行なった。その結果を第２表に示す。Resin compositions having the formulations shown in Table 1 were mixed and properties were compared. The results are shown in Table 2.
その結果、実施例１及び２のエポキシ樹脂組成物は、ポ
ットライフ、タレ落ち性、バランス１−ｆｆ Ｉ！、熱
時強度、過熱劣化、自動吐出機適用性をすべて満足する
もので、自動機によシ吐出可能で速硬化であるため自動
化が可能となる。As a result, the epoxy resin compositions of Examples 1 and 2 had pot life, dripping properties, and balance of 1-ff I! It satisfies all the requirements of strength under heat, overheating deterioration, and applicability to automatic dispensing machines, and can be dispensed by automatic machines and cures quickly, making automation possible.
試験方法（１）
エポキシ樹脂配合物的２０Ｏｆを紙コツプにとシ、２５
℃恒温槽中に放置し、初期粘度から粘度が２倍に到達し
た時間をポットライフとする。Test method (1) Put 20 of the epoxy resin compound into a paper cup, 25
The pot life is defined as the time it takes for the viscosity to double from the initial viscosity when the pot is left in a constant temperature bath.
試験方法（２）
エポキシ樹脂混合物を約１？、アルミカップにと）１５
０℃１０分加熱し、重量変化率を測定する。Test method (2) Approximately 1? , in an aluminum cup) 15
Heat at 0°C for 10 minutes and measure the rate of weight change.
試験方法（３）
回転体に樹脂を所定の位置次所定量滴下し、回転体のバ
ランスがうまくとれるかどうか判定する。Test method (3) A predetermined amount of resin is dropped onto a rotating body at a predetermined position, and it is determined whether the rotating body can be well balanced.
試験方法（４）
回転体を１５０〜２００℃に１時間放置し、１５０〜２
００℃雰朋気内において高速回転例えば６０００〜１０
０００ ｒｐｍにて１分間回転させ、バランス修正用樹
脂がヒビ割れ浮き等の外観変化の有無を観察する。Test method (4) The rotating body was left at 150-200°C for 1 hour, and the
High speed rotation in an atmosphere of 00℃, e.g. 6000~10
The balance correction resin was rotated for 1 minute at 000 rpm and observed for changes in appearance such as cracks and floating.
○外観変化がない
×外観変化がある
試験方法（５）
回転体に電圧１２〜１４Ｖにて常温で１分間印加後高速
回転６０００〜１００００ ｒｐｍにて１分間回転させ
、バランス修正用樹脂チヒビ割れ、浮き等の外観変化の
有無を観察する。○ Test method with no change in appearance x change in appearance (5) After applying a voltage of 12 to 14 V to the rotating body for 1 minute at room temperature, it was rotated at a high speed of 6000 to 10000 rpm for 1 minute, and the resin for balance correction was cracked, Observe for changes in appearance such as floating.
○外観変化がない
×外観変化がある
試験方法（６）
Ｍ自動哄暗吐出機にて樹脂組成物を吐出し、０、０ Ｉ
Ｐから１ｆ位の吐出精度が得られるかどうかを確認す
る。○ No change in appearance × Test method with change in appearance (6) Dispense the resin composition with an M automatic dark dispensing machine and test 0,0 I
Check whether a discharge accuracy of about 1f can be obtained from P.
○吐出精度良好 ×吐出精度不良○Good discharge accuracy ×Poor discharge accuracy
Claims (1)
スを是正するために用いられるエポキシ樹脂組成物にお
いて、エポキシ樹脂、硬化剤、硬化促進剤、無機充填材
及びチキン付与剤を主成分とし、硬化剤はジシアンジア
ミド又は有機二塩基酸ジヒドラジドであって、エポキシ
樹脂１００重量部に対し、ジシアンジアミド１〜１０重
量部または有機二塩基酸ジヒドラジド１〜４０重量部を
含有することを特徴とする一液性液状エポキシ樹脂組成
物。An epoxy resin composition used to correct unbalance during rotation in the rotating body of a rotor for a rotating electric machine, which contains an epoxy resin, a curing agent, a curing accelerator, an inorganic filler, and a chicken filler as the main components, and cures. The agent is dicyandiamide or organic dibasic acid dihydrazide, and is a one-component liquid characterized by containing 1 to 10 parts by weight of dicyandiamide or 1 to 40 parts by weight of organic dibasic acid dihydrazide per 100 parts by weight of the epoxy resin. Epoxy resin composition.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP14127986A JPS63311A (en) | 1986-06-19 | 1986-06-19 | Liquid epoxy resin composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP14127986A JPS63311A (en) | 1986-06-19 | 1986-06-19 | Liquid epoxy resin composition |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS63311A true JPS63311A (en) | 1988-01-05 |
| JPH0341089B2 JPH0341089B2 (en) | 1991-06-21 |
Family
ID=15288196
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP14127986A Granted JPS63311A (en) | 1986-06-19 | 1986-06-19 | Liquid epoxy resin composition |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS63311A (en) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH02124931A (en) * | 1988-07-04 | 1990-05-14 | Somar Corp | Penetrative epoxy resin composition, adhesion of ferrite magnet to motor yoke and motor |
| JPH04503854A (en) * | 1989-03-01 | 1992-07-09 | ポウラー・テクノロジーズ・インターナシヨナル・プロプライエタリー・リミテツド | Lightweight portable snow making equipment |
| US5201248A (en) * | 1989-09-19 | 1993-04-13 | Sumitomo Bakelite Company Limited | Materials for balancing rotators and method for balancing rotators |
| US5267140A (en) * | 1990-12-27 | 1993-11-30 | Asmo Co. Ltd. | Method of apparatus for correcting dynamic balance of rotatable member |
| JPH0996901A (en) * | 1995-09-30 | 1997-04-08 | Toppan Printing Co Ltd | Photosensitive resin composition and printed circuit board using same |
| WO2012168414A1 (en) * | 2011-06-10 | 2012-12-13 | Carnehammar, Prof. Dr. Lars Bertil | Method, apparatus and system for reducing vibration in a rotary system of a tool |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5996857A (en) * | 1982-11-24 | 1984-06-04 | Nippon Radiator Co Ltd | Imbalance correcting method for armature in flat motor |
-
1986
- 1986-06-19 JP JP14127986A patent/JPS63311A/en active Granted
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5996857A (en) * | 1982-11-24 | 1984-06-04 | Nippon Radiator Co Ltd | Imbalance correcting method for armature in flat motor |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH02124931A (en) * | 1988-07-04 | 1990-05-14 | Somar Corp | Penetrative epoxy resin composition, adhesion of ferrite magnet to motor yoke and motor |
| JPH04503854A (en) * | 1989-03-01 | 1992-07-09 | ポウラー・テクノロジーズ・インターナシヨナル・プロプライエタリー・リミテツド | Lightweight portable snow making equipment |
| US5201248A (en) * | 1989-09-19 | 1993-04-13 | Sumitomo Bakelite Company Limited | Materials for balancing rotators and method for balancing rotators |
| US5267140A (en) * | 1990-12-27 | 1993-11-30 | Asmo Co. Ltd. | Method of apparatus for correcting dynamic balance of rotatable member |
| JPH0996901A (en) * | 1995-09-30 | 1997-04-08 | Toppan Printing Co Ltd | Photosensitive resin composition and printed circuit board using same |
| WO2012168414A1 (en) * | 2011-06-10 | 2012-12-13 | Carnehammar, Prof. Dr. Lars Bertil | Method, apparatus and system for reducing vibration in a rotary system of a tool |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0341089B2 (en) | 1991-06-21 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US5201248A (en) | Materials for balancing rotators and method for balancing rotators | |
| JPH03244626A (en) | Epoxy resin powder composition | |
| US20050126286A1 (en) | Method for balancing a movable member and member formed thereby | |
| JP5175509B2 (en) | Powder coating composition | |
| JPS63311A (en) | Liquid epoxy resin composition | |
| KR100444409B1 (en) | Epoxy resin composition | |
| JP5383642B2 (en) | Powder coating method and gas insulated switchgear | |
| JPS62112620A (en) | Liquid epoxy resin composition | |
| JP3007026B2 (en) | Heat-curable epoxy resin composition | |
| JP3195187B2 (en) | Epoxy resin composition for dispenser application | |
| JPS6392639A (en) | One-pack, heat-curable epoxy resin composition for use in correcting balance of rotor of motor | |
| US5008309A (en) | Balancing putty | |
| JPH02286738A (en) | Epoxy resin composition prevented from generating curing strain and method of bonding therewith | |
| JP2575998B2 (en) | Thixotropic epoxy resin composition | |
| JP2000212504A (en) | Coating film for coil | |
| JPH07258384A (en) | Epoxy resin composition | |
| JP5258205B2 (en) | Two-component curable resin composition | |
| JPS60181122A (en) | Powder suitable for applying electric insulating coating on electric wire | |
| JPH03107646A (en) | Balancing material for rotary electric element | |
| JPH09316171A (en) | One-component epoxy resin composition | |
| KR20100132863A (en) | Latent hardener composite particleswith improved storage stability using mechanochemical bonding system and fabrication method thereof, and one component epoxy resin formulation using the same | |
| JPH0348416A (en) | Primary coating impregnant for film capacitor | |
| JP2731879B2 (en) | Epoxy resin curing method | |
| US20030139506A1 (en) | Powdered epoxy composition | |
| JPS61151231A (en) | Liquid epoxy resin composition |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| EXPY | Cancellation because of completion of term |