JPS63309150A - Production of instant gelatinous substance - Google Patents

Production of instant gelatinous substance

Info

Publication number
JPS63309150A
JPS63309150A JP62145776A JP14577687A JPS63309150A JP S63309150 A JPS63309150 A JP S63309150A JP 62145776 A JP62145776 A JP 62145776A JP 14577687 A JP14577687 A JP 14577687A JP S63309150 A JPS63309150 A JP S63309150A
Authority
JP
Japan
Prior art keywords
parts
water
aqueous solution
room temperature
acid
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP62145776A
Other languages
Japanese (ja)
Inventor
Kaoru Okuno
薫 奥野
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
San Ei Kagaku Co Ltd
Sanei Kagaku Kogyo KK
Original Assignee
San Ei Kagaku Co Ltd
Sanei Kagaku Kogyo KK
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by San Ei Kagaku Co Ltd, Sanei Kagaku Kogyo KK filed Critical San Ei Kagaku Co Ltd
Priority to JP62145776A priority Critical patent/JPS63309150A/en
Publication of JPS63309150A publication Critical patent/JPS63309150A/en
Pending legal-status Critical Current

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  • Jellies, Jams, And Syrups (AREA)

Abstract

PURPOSE:To industrially and advantageously produce an instant gelatinous substance without denaturing and deteriorating foods, medicines, industrial chemicals, etc., by gelatinizing the medicines, etc., with gelan gum. CONSTITUTION:Gelan gum is dissolved in water by heating or dispersed and suspended in water at ordinary temperature to prepare an about 0.1-2wt.% aqueous solution of the gelan gum. An alkaline earth metal salt and/or alkaline metal salt and/or an acidic substance, such as organic or inorganic acid, and acid salts thereof or foods, medicines, industrial chemicals, etc., containing the above-mentioned alkaline earth metallic salts, etc., are added, blended with the afore-mentioned aqueous solution of the gelan gum and gelatinized at ordinary temperature.

Description

【発明の詳細な説明】 〈産業上の利用分野〉 この発明は、食品、医薬品、工業薬品に係るものであっ
て、ジェランガム水溶液に、ア/L’力!J土類金属塩
類、及び又はアルカリ金属塩類及び又は有機、無機酸な
どの酸性物質、又はこれらを含む食品、医薬品、工業薬
品を常温で添加し、即時にゲル化せしめて、工業的に、
有利に製造することを目的とする。
[Detailed Description of the Invention] <Industrial Field of Application> The present invention relates to foods, pharmaceuticals, and industrial chemicals, and includes applying A/L'power to an aqueous gellan gum solution. J Earth metal salts and/or alkali metal salts and/or acidic substances such as organic and inorganic acids, or foods, pharmaceuticals, and industrial chemicals containing these are added at room temperature and instantly gelled, resulting in industrial use.
The purpose is to manufacture it advantageously.

〈従来の技術とその欠点〉 従来、食品、医薬品、工業薬品をゲル化させるには、ゲ
ル化性の膠質、例えば、寒天、ゼラチン、ペクチン、ア
ルギン酸ナトリウム、カラギーナンなどが利用されてい
る。これらは、食品、医薬品、工業薬品をゲル化させる
ことができるが、次のような問題点を有している。即ち
、■加熱溶解し熱時食品、医薬品、工業薬品などを添加
して冷却する事によりゲルを形成せしめる必要がある。
<Conventional techniques and their disadvantages> Conventionally, gelatinous colloids such as agar, gelatin, pectin, sodium alginate, and carrageenan have been used to gel foods, pharmaceuticals, and industrial chemicals. Although these can gel foods, pharmaceuticals, and industrial chemicals, they have the following problems. That is, (1) it is necessary to form a gel by heating and dissolving, adding food, pharmaceuticals, industrial chemicals, etc. when hot, and cooling.

■熱時食品、医薬品、工業薬品を添加するだめ、これら
が変性、変質する。■室温でゲル強度が低下する。■加
熱する事によりゲル強度が低下したり、融解してゾルに
なる。■従来のゲル化性の膠質は、耐酸、耐塩、耐薬品
性に欠ける。
■Do not add foods, pharmaceuticals, or industrial chemicals when heated, as these will denature and change in quality. ■Gel strength decreases at room temperature. ■Gel strength decreases or melts and becomes a sol by heating. ■Conventional gelatinous colloids lack acid, salt, and chemical resistance.

く問題を解決するための方法〉 以上の問題点を解決するためにジェランガムが採用され
る。即ちまず、ジェランガムの0.1〜2%(重量%、
以下同じ)水溶液(加熱溶解した常温のジェランガム水
溶液、又は常温の水に分散懸濁せしめたジェランガム水
溶液)を用意する。こうして調整したジェランガム水溶
液にアルカリ土類金属塩類、例えば乳酸カルシウム、塩
化マグネシウム、塩化カルシウム、グルコン酸カルシウ
ム1その他、など。アルカリ金属塩類、例えば、リン酸
又は重合燐酸ナトリウム、リン酸又は重合燐酸カリウム
、塩化ナトリウム、塩化カリウム、その他、など。有機
酸類、例えば、クエン酸、リンゴ酸、マレイン酸、フマ
ー〜酸、酒石酸、アジピン酸、その他、など。無機酸類
、例えば、硝酸、ホウ酸、塩酸、硫酸、その他、フマー
ル酸1ナトリウム、酒石酸水素カリウム、リン酸2水素
カリウム、など、又これらを含む食品、例えば牛乳、発
酵乳、コーヒー、紅茶、果汁、果肉、生クリームその他
、など。医薬品、例えば、抗生物質、下剤、胃腸薬、解
熱剤、その他、など。又肥料、農薬、飼料、餌料、研摩
剤、油脂、香料、その他、などにも混合することもでき
る。
Method for solving the above problems> Gellan gum is adopted to solve the above problems. That is, first, 0.1 to 2% (weight%,
(The same applies hereinafter) Prepare an aqueous solution (an aqueous gellan gum solution at room temperature dissolved by heating, or an aqueous gellan gum solution dispersed and suspended in water at room temperature). Alkaline earth metal salts such as calcium lactate, magnesium chloride, calcium chloride, calcium gluconate 1, and others are added to the gellan gum aqueous solution thus prepared. Alkali metal salts, such as phosphoric acid or polymerized sodium phosphate, phosphoric acid or polymerized potassium phosphate, sodium chloride, potassium chloride, etc. Organic acids, such as citric acid, malic acid, maleic acid, fumaric acid, tartaric acid, adipic acid, etc. Inorganic acids such as nitric acid, boric acid, hydrochloric acid, sulfuric acid, monosodium fumarate, potassium hydrogen tartrate, potassium dihydrogen phosphate, etc., and foods containing these, such as milk, fermented milk, coffee, tea, fruit juice , fruit pulp, fresh cream, etc. Pharmaceuticals, such as antibiotics, laxatives, gastrointestinal drugs, antipyretics, etc. It can also be mixed into fertilizers, agricultural chemicals, feeds, feedstuffs, abrasives, oils and fats, fragrances, and others.

混合するジェランガム水溶液と他の物質の混合割合は、
ジェランガム濃度によっても、又他の物質の種類によっ
ても異るので一概には言えないが、ジェランガム水溶液
が0.5%濃度の場合、アルカリ土類金属塩類、アルカ
リ金属塩類、有機、無機酸類で0.01〜0.5部又食
品、その他の場合、重量比1:1前後が適当である。
The mixing ratio of gellan gum aqueous solution and other substances to be mixed is
It is difficult to make a general statement because it varies depending on the gellan gum concentration and the type of other substances, but if the gellan gum aqueous solution has a concentration of 0.5%, it will be 0 for alkaline earth metal salts, alkali metal salts, organic and inorganic acids. In the case of foods and other products, a weight ratio of about 1:1 is appropriate.

ここに本発明はその目的を達成する。The invention here achieves its objective.

発明の効果 以下にこの発明の実験例を記載してその作用及び効果を
説明する。
Effects of the Invention Experimental examples of the invention will be described below to explain its functions and effects.

実験例1 ■水(20°C)99部を攪拌(佐竹式攪拌器、回転数
2000〜2500rpm(以下間じすしながら試料1
部を徐々に加え、10分間攪拌分散懸濁せしめる。又別
に水(20°C) 99.92部、乳酸力ルシウム0.
08部、又は水(20°C)99.5部、塩化ナトリウ
ム0.5部、又は水(20°C)99.7部、クエン酸
0.3部の各々の水溶液を作る。試料溶液50部と乳酸
カルシウム水溶液50部、又は塩化ナトリウム水溶液5
0部、又はクエン酸水溶液50部を混合し、容器につめ
、室温で2時間放置し、ゲルの状態を観察した。
Experimental Example 1 ■ Stir 99 parts of water (20°C) (Satake type stirrer, rotation speed 2000-2500 rpm)
1 part was gradually added, and the mixture was stirred and suspended for 10 minutes. Separately, water (20°C) 99.92 parts, lactic acid lucium 0.
08 parts of water (20°C), 0.5 parts of sodium chloride, 99.7 parts of water (20°C), and 0.3 parts of citric acid. 50 parts of sample solution and 50 parts of calcium lactate aqueous solution or 5 parts of sodium chloride aqueous solution
0 parts or 50 parts of a citric acid aqueous solution were mixed, packed in a container, and left to stand at room temperature for 2 hours, and the state of the gel was observed.

■水(90℃)99部を攪拌しながら試料1部を徐々に
加え、90℃、10分間攪拌溶解し、常温まで冷却した
。又別に水(20°C’) 99.92部、塩化マグネ
シウム0.08部、又は水(20’C) 99.5部リ
ン酸水素2ナトリウム0.5部、又は、水(20℃)9
9.7部、塩酸0.3部の各々の水溶液を作る。
(1) 1 part of the sample was gradually added to 99 parts of water (90°C) with stirring, dissolved with stirring at 90°C for 10 minutes, and cooled to room temperature. Separately, 99.92 parts of water (20°C'), 0.08 part of magnesium chloride, or 99.5 parts of water (20'C), 0.5 part of disodium hydrogen phosphate, or 9 parts of water (20°C).
Prepare aqueous solutions containing 9.7 parts of hydrochloric acid and 0.3 parts of hydrochloric acid.

試料水溶液50部と塩化マグネシウム水溶液50部、又
バリン酸水素2ナトリウム水溶液50部又は塩酸水溶液
50部を混合し、容器につめ室温で2時間放置しゲμの
状態を観察した。
Fifty parts of the sample aqueous solution, 50 parts of a magnesium chloride aqueous solution, 50 parts of a disodium hydrogen valate aqueous solution or 50 parts of a hydrochloric acid aqueous solution were mixed, and the mixture was packed in a container and allowed to stand at room temperature for 2 hours, and the state of the gel μ was observed.

■20’Cの水に試料を分散懸濁した場合■試料を加熱
溶解後、常温まで冷却した場合実験例2 加熱溶解した常温のジェランガム溶液と常温水に分散、
懸濁したジェランガム溶液のゲル強度。
■ When a sample is dispersed and suspended in water at 20'C ■ When a sample is heated and dissolved and then cooled to room temperature Experimental example 2 Dispersed in a heated and dissolved gellan gum solution at room temperature and room temperature water,
Gel strength of suspended gellan gum solution.

■水(90°C’) 99.3部を攪拌(佐竹式攪拌器
、回転数2000〜2500rpm)しながら試料0.
7部を徐々に加え、90’C,10分間攪拌溶解する。
■While stirring 99.3 parts of water (90°C') (Satake type stirrer, rotation speed 2000-2500 rpm), 0.0% of the sample was added.
Gradually add 7 parts and stir and dissolve at 90'C for 10 minutes.

これを常温(25°C)まで冷却する。This is cooled to room temperature (25°C).

■水(25°C)98.8部を攪拌(佐竹式攪拌器、回
転数2000〜250Orpm)Lながら試料1.2部
を徐々に加え、10分間攪拌溶解する。
(2) Gradually add 1.2 parts of the sample to 98.8 parts of water (25°C) while stirring (Satake type stirrer, rotation speed 2000-250 rpm), and stir and dissolve for 10 minutes.

■水99.92部、乳酸カルシウム0.08部の溶液を
作る。
■Make a solution of 99.92 parts of water and 0.08 part of calcium lactate.

■試料溶液50部に乳酸カルシウム溶液50部を混合し
、容器につめ室温で2時間放置し、ゲルの状態を観察し
た。
(2) 50 parts of the calcium lactate solution was mixed with 50 parts of the sample solution, and the mixture was packed in a container and left at room temperature for 2 hours, and the state of the gel was observed.

透明性を要求される場合又は経済的にジェランガムの量
を少なくしたい時は、加熱溶解後、常温まで冷却して使
用する。又加熱などの手間をはふきたい時、又は透明性
があまり必要でない場合は、常温水に分散し使用できる
When transparency is required or when it is desired to economically reduce the amount of gellan gum, the gellan gum is melted by heating and then cooled to room temperature before use. Also, when you want to avoid the hassle of heating, or when transparency is not very necessary, you can use it by dispersing it in room temperature water.

実験例8  アルコール含有ゲル化物 水(90°C’) 79.5部を攪拌(佐竹式攪拌器、
回転数2000〜250Orpm)Lながら試料0.5
部を徐々に加え、90°C110分間攪拌溶解する。
Experimental Example 8 Stirring 79.5 parts of alcohol-containing gelled water (90°C') (Satake type stirrer,
Rotation speed 2000~250Orpm) Sample 0.5
1 part was gradually added and stirred and dissolved at 90°C for 110 minutes.

これを常温(25°C)まで冷却する。乳酸カルシウム
0.05部、水(25°C)9.95部の溶液を加え、
さらにエタノ−/L/10部又はワイン10部を混合す
る。これを容器に詰め冷却後、臭いの変化をみた。
This is cooled to room temperature (25°C). Add a solution of 0.05 parts of calcium lactate and 9.95 parts of water (25°C),
Furthermore, 10 parts of ethanol/L/10 parts of wine are mixed. After this was packed in a container and cooled, the change in odor was observed.

実験例4  耐熱性・ 実験例1■でテストした系を容器のまま電子レンジに入
れ、5分間加熱する。
Experimental Example 4 Heat Resistance - Place the system tested in Experimental Example 1■ in a microwave oven in its container and heat for 5 minutes.

実施例1  肥料のゲル化 水(90°C”) 49.5部を攪拌しながらジェラン
ガム0.5部を加え攪拌溶解後、常温まで冷却した。
Example 1 Gelled fertilizer water (90° C.) 0.5 part of gellan gum was added to 49.5 parts of gelatinous water (90° C.) with stirring, dissolved, and then cooled to room temperature.

これに硫酸アンモニア82部、過リン酸石灰20部、硫
酸カリ☆ム18部を加え混合し、ゲル化させた。これを
植物の根元に置くことにより肥料の流出が防げ、長期間
にわたシ、肥料の効果が得られた。
To this, 82 parts of ammonia sulfate, 20 parts of lime superphosphate, and 18 parts of potassium sulfate were added and mixed to form a gel. By placing this at the base of the plants, it was possible to prevent the fertilizer from flowing out, and the effect of the fertilizer was obtained over a long period of time.

実施例2  オレンジ果汁入りゼリー 20°Cの水81.3部を泡立器で攪拌しながらジェラ
ンガム0.5部、砂糖14部の混合物を徐々に加え3分
間攪拌し溶解させた。この中に115m縮、温州果汁4
部、クエン酸0.2部を均一に混和した。室温放置する
ことにより、口どけの良いゼリーが簡単に得られた。
Example 2 Jelly containing orange juice While stirring 81.3 parts of water at 20°C with a whisk, a mixture of 0.5 parts of gellan gum and 14 parts of sugar was gradually added and stirred for 3 minutes to dissolve. In this, 115m shrinkage, Wenzhou fruit juice 4
1 part and 0.2 part of citric acid were uniformly mixed. By leaving it at room temperature, a jelly with a good melting sensation in the mouth was easily obtained.

又、この物を電子レンジに入れ加熱することにより暖た
かいゼリーが得られた。
In addition, warm jelly was obtained by heating this product in a microwave oven.

実施例3  ヨーグルトゼリー ジェランガム0.8部、砂糖12部の粉体混合物に25
°Cの水40部を加え、泡立器で3分間攪拌し溶解した
。この中にカードを潰した。ヨーグルシト50実施例4
  コーヒーゼリー ジェランガム0.4部、砂糖11部に20’Cの水85
部を加え泡立器で3分間攪拌溶解した。ここへ、コーヒ
ーエキスH(三栄化学工業■の製品コーヒーの抽出液の
濃縮量)を5部添加してよく均一に混和し、プヲヌチッ
ク容器に充填して室内(20°C)に1時間放置した。
Example 3 Yogurt jelly 25% of a powder mixture of 0.8 parts of gellan gum and 12 parts of sugar
40 parts of water at °C was added and stirred with a whisk for 3 minutes to dissolve. I crushed the card in this. Yoglucito 50 Example 4
Coffee jelly 0.4 parts gellan gum, 11 parts sugar, 85% water at 20'C
of the mixture and stirred with a whisk for 3 minutes to dissolve. To this, 5 parts of Coffee Extract H (concentrated amount of coffee extract manufactured by Sanei Chemical Industry ■) was added, mixed well and uniformly, and the mixture was filled into a Puwonchik container and left indoors (20°C) for 1 hour. .

このものを電子レンジで5分間加熱した。。This was heated in the microwave for 5 minutes. .

組織のなめらかな、あたたかいコーヒーゼリーが得られ
た。
A warm coffee jelly with a smooth texture was obtained.

実施例5  胃炎、胃痛剤のゲル化 水(20°C)95.5部を攪拌しながらジェランガム
0,5部を加え攪拌し分散、懸濁水溶液とした。
Example 5 Gelling of a drug for gastritis and stomach pain 0.5 parts of gellan gum was added to 95.5 parts of water (20°C) while stirring, and the mixture was stirred and dispersed to form a suspended aqueous solution.

これにロートエキス散0.5部、合成ケイ酸アルミニウ
ム3部、酸化マグネシウム0.5部を加えよく混合し、
ゲル化させた。
Add 0.5 parts of funnel extract powder, 3 parts of synthetic aluminum silicate, and 0.5 parts of magnesium oxide to this and mix well.
gelatinized.

ゲル化させることによシ酸化マグネシウム、合成ケイ酸
アルミニウムなど飛散性薬品が飛散せず又、飲用時、苦
味が軽減された。
By gelatinizing, flying chemicals such as magnesium silicate and synthetic aluminum silicate were not scattered, and the bitter taste was reduced when drinking.

実施例6  ベットフード 水(25°C)49部を攪拌しながらジェランガム1部
を徐々に加え、分散懸濁した。これに、煮魚の残シをミ
ンチしたもの15部、うす塩のお湯で柔らかく煮たマカ
ロニ10部、水で柔らかく煮た人参2部、人参の煮汁で
やわらかくしたパン粉23部を加え、混合し室温で放置
した。出来上がったものを犬に与えだが皿からこほれる
ことなく犬が食べた。
Example 6 While stirring 49 parts of bed food water (25°C), 1 part of gellan gum was gradually added and dispersed and suspended. To this, add 15 parts of minced leftovers of boiled fish, 10 parts of macaroni boiled in lightly salted hot water, 2 parts of carrots boiled in water to soften them, and 23 parts of bread crumbs softened with carrot broth, and mix together at room temperature. I left it there. I gave the finished food to the dog, but the dog ate it without spilling anything from the plate.

Claims (1)

【特許請求の範囲】[Claims]  加熱溶解した常温のジェランガム水溶液、又は常温の
水にジェランガムを分散懸濁せしめたジェランガム水溶
液にアルカリ土類金属塩類及び又はアルカリ金属塩類及
び又は有機、無機酸などの酸性物質及びその酸性塩類又
は、これらを含む食品、医薬品、工業薬品を常温で添加
、混合することにより即時ゲル状物を形成せしめる方法
Alkaline earth metal salts and/or alkali metal salts and/or acidic substances such as organic and inorganic acids and their acid salts or these A method of immediately forming a gel-like substance by adding and mixing foods, pharmaceuticals, and industrial chemicals containing the ingredients at room temperature.
JP62145776A 1987-06-11 1987-06-11 Production of instant gelatinous substance Pending JPS63309150A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP62145776A JPS63309150A (en) 1987-06-11 1987-06-11 Production of instant gelatinous substance

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP62145776A JPS63309150A (en) 1987-06-11 1987-06-11 Production of instant gelatinous substance

Publications (1)

Publication Number Publication Date
JPS63309150A true JPS63309150A (en) 1988-12-16

Family

ID=15392901

Family Applications (1)

Application Number Title Priority Date Filing Date
JP62145776A Pending JPS63309150A (en) 1987-06-11 1987-06-11 Production of instant gelatinous substance

Country Status (1)

Country Link
JP (1) JPS63309150A (en)

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1998023292A1 (en) * 1996-11-29 1998-06-04 Monsanto Company Lubricious self-standing (intact) gel for oral delivery of biologically-active ingredients
JP2000245362A (en) * 1999-03-03 2000-09-12 House Foods Corp Jelly food and its production
JP2009051855A (en) * 1997-03-28 2009-03-12 Eisai R & D Management Co Ltd Oral pharmaceutical preparation masked to eliminate bitterness or like unpleasant taste
JP2014166968A (en) * 2013-02-28 2014-09-11 Kobayashi Pharmaceutical Co Ltd Composition for internal use
JP2017132818A (en) * 2017-05-12 2017-08-03 小林製薬株式会社 Oral composition
JP2019062830A (en) * 2017-10-02 2019-04-25 三栄源エフ・エフ・アイ株式会社 Bitterness masking composition

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1998023292A1 (en) * 1996-11-29 1998-06-04 Monsanto Company Lubricious self-standing (intact) gel for oral delivery of biologically-active ingredients
JP2009051855A (en) * 1997-03-28 2009-03-12 Eisai R & D Management Co Ltd Oral pharmaceutical preparation masked to eliminate bitterness or like unpleasant taste
JP2000245362A (en) * 1999-03-03 2000-09-12 House Foods Corp Jelly food and its production
JP2014166968A (en) * 2013-02-28 2014-09-11 Kobayashi Pharmaceutical Co Ltd Composition for internal use
JP2017132818A (en) * 2017-05-12 2017-08-03 小林製薬株式会社 Oral composition
JP2019062830A (en) * 2017-10-02 2019-04-25 三栄源エフ・エフ・アイ株式会社 Bitterness masking composition

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