JPS63297290A - Slaked lime fertilizer and manufacture - Google Patents
Slaked lime fertilizer and manufactureInfo
- Publication number
- JPS63297290A JPS63297290A JP13709687A JP13709687A JPS63297290A JP S63297290 A JPS63297290 A JP S63297290A JP 13709687 A JP13709687 A JP 13709687A JP 13709687 A JP13709687 A JP 13709687A JP S63297290 A JPS63297290 A JP S63297290A
- Authority
- JP
- Japan
- Prior art keywords
- slaked lime
- powder
- fertilizer
- weight
- mixture
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000920 calcium hydroxide Substances 0.000 title claims description 84
- 235000011116 calcium hydroxide Nutrition 0.000 title claims description 84
- 229910001861 calcium hydroxide Inorganic materials 0.000 title claims description 84
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 title claims description 83
- 239000003337 fertilizer Substances 0.000 title claims description 49
- 238000004519 manufacturing process Methods 0.000 title claims description 7
- 239000000843 powder Substances 0.000 claims description 83
- 239000007788 liquid Substances 0.000 claims description 28
- 239000000203 mixture Substances 0.000 claims description 26
- IVJISJACKSSFGE-UHFFFAOYSA-N formaldehyde;1,3,5-triazine-2,4,6-triamine Chemical class O=C.NC1=NC(N)=NC(N)=N1 IVJISJACKSSFGE-UHFFFAOYSA-N 0.000 claims description 11
- 238000003756 stirring Methods 0.000 claims description 6
- 229920000877 Melamine resin Polymers 0.000 description 33
- 239000004640 Melamine resin Substances 0.000 description 31
- 239000002245 particle Substances 0.000 description 16
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 13
- 239000002689 soil Substances 0.000 description 10
- 238000000034 method Methods 0.000 description 9
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 7
- 230000000694 effects Effects 0.000 description 7
- 239000000835 fiber Substances 0.000 description 7
- ODINCKMPIJJUCX-UHFFFAOYSA-N Calcium oxide Chemical compound [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 6
- 230000005484 gravity Effects 0.000 description 6
- 238000005507 spraying Methods 0.000 description 5
- 230000002378 acidificating effect Effects 0.000 description 4
- 239000007864 aqueous solution Substances 0.000 description 4
- 230000007423 decrease Effects 0.000 description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 239000000292 calcium oxide Substances 0.000 description 3
- 235000012255 calcium oxide Nutrition 0.000 description 3
- 230000000704 physical effect Effects 0.000 description 3
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- 235000019738 Limestone Nutrition 0.000 description 2
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 2
- 235000011941 Tilia x europaea Nutrition 0.000 description 2
- 230000002776 aggregation Effects 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- GPRLSGONYQIRFK-UHFFFAOYSA-N hydron Chemical compound [H+] GPRLSGONYQIRFK-UHFFFAOYSA-N 0.000 description 2
- 239000004571 lime Substances 0.000 description 2
- 239000006028 limestone Substances 0.000 description 2
- 238000011160 research Methods 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 235000013311 vegetables Nutrition 0.000 description 2
- 206010061218 Inflammation Diseases 0.000 description 1
- 206010040880 Skin irritation Diseases 0.000 description 1
- 238000005054 agglomeration Methods 0.000 description 1
- 238000004220 aggregation Methods 0.000 description 1
- 239000003905 agrochemical Substances 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 238000013098 chemical test method Methods 0.000 description 1
- 238000012937 correction Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000004889 fertilizer analysis Methods 0.000 description 1
- 235000013312 flour Nutrition 0.000 description 1
- 235000011389 fruit/vegetable juice Nutrition 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 230000004054 inflammatory process Effects 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 238000000691 measurement method Methods 0.000 description 1
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 description 1
- 150000007974 melamines Chemical class 0.000 description 1
- 210000004400 mucous membrane Anatomy 0.000 description 1
- 230000003472 neutralizing effect Effects 0.000 description 1
- 239000010893 paper waste Substances 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- -1 propatool Chemical compound 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 230000036556 skin irritation Effects 0.000 description 1
- 231100000475 skin irritation Toxicity 0.000 description 1
- 230000000391 smoking effect Effects 0.000 description 1
- 239000008399 tap water Substances 0.000 description 1
- 235000020679 tap water Nutrition 0.000 description 1
- 235000020681 well water Nutrition 0.000 description 1
- 239000002349 well water Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05D—INORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C; FERTILISERS PRODUCING CARBON DIOXIDE
- C05D3/00—Calcareous fertilisers
- C05D3/02—Calcareous fertilisers from limestone, calcium carbonate, calcium hydrate, slaked lime, calcium oxide, waste calcium products
Abstract
(57)【要約】本公報は電子出願前の出願データであるた
め要約のデータは記録されません。(57) [Summary] This bulletin contains application data before electronic filing, so abstract data is not recorded.
Description
【発明の詳細な説明】
［産業上の利用分野］
本発明は消石灰肥料およびその製造方法に関する。さら
に詳しくは、本発明は飛散性を改善した消石灰肥料およ
びその製造方法に関する。DETAILED DESCRIPTION OF THE INVENTION [Industrial Field of Application] The present invention relates to slaked lime fertilizer and a method for producing the same. More specifically, the present invention relates to a slaked lime fertilizer with improved scattering properties and a method for producing the same.
［従来の技術］
作物の生育に適する土壌のｐＨは作物の種類によって異
なるため、該土壌のｐＨの範囲を設定するのは困難であ
るが、一般に大部分の作物に対する適切な土壌のｐＨは
５．５〜６．５であるとさ糺ている。土壌のｐＨがかか
る範囲外にあるばあい、土壌のｐＨが６，０〜８．５程
度であるのなら順調に生育する酸性土壌を好む植物であ
っても、ｐＨが５以下の酸性土壌においては生育しない
。[Prior Art] Since the pH of soil suitable for growing crops varies depending on the type of crop, it is difficult to set the pH range of the soil, but in general, the pH of soil suitable for most crops is 5. It is estimated that it is between .5 and 6.5. If the pH of the soil is outside this range, even plants that prefer acidic soil will grow well if the soil pH is between 6.0 and 8.5, but will grow in acidic soil with a pH of 5 or less. does not grow.
そこでこのような極端な酸性土壌のｐＨを作物に適した
ｐＨに調整するために、従来より中和剤として石灰質肥
料が用いられている。この石灰質肥料としては、一般に
石灰石を機械的に粉砕することにより粉末化されたｐＨ
が１０以下である炭酸カルシウム肥料（ＣＢＣＯ３）
ｓ石灰石を高温で燻焼することによりえられる塊状また
は粒状の生石灰肥料（Ｃａｂ）および生石灰と水とを反
応させることによりえられるｐｌが１２．５程度である
強アルカリ性の粉状の消石灰肥料（Ｃａ（０１１）２）
があり、これらの肥料は対象土壌の酸度の状態に応じて
適宜選択して用いられるが、とくに消石灰肥料は粉状で
あり、しかもアルカリ度が大きいため強酸性土壌の速効
性酸度矯正剤として広く用いられている。Therefore, in order to adjust the pH of such extremely acidic soil to a pH suitable for crops, calcareous fertilizers have conventionally been used as a neutralizing agent. This calcareous fertilizer is generally made into powder by mechanically crushing limestone.
Calcium carbonate fertilizer (CBCO3) with a value of 10 or less
sLumpy or granular quicklime fertilizer (Cab) obtained by smoking limestone at high temperature, and strong alkaline powder slaked lime fertilizer with a pl of about 12.5 obtained by reacting quicklime with water ( Ca(011)2)
These fertilizers are selected and used as appropriate depending on the acidity state of the target soil, but slaked lime fertilizer in particular is in powder form and has a high alkalinity, so it is widely used as a quick-acting acidity correction agent for strongly acidic soil. It is used.
ところが該消石灰肥料の粒子はきわめて小さく、しかも
比重が小さいため散布の際には飛散による亡失が多いの
で、目的とする投肥効果をうるためにかかる亡失分をあ
らかじめ補給して散布する必要があるという経済上の不
利益があるのみならず、所望の場所以外にも飛散するの
で公害が発生することがあり、さらに作業者の皮膚に付
着して肌荒れが生じたり、目や口などに入り、粘膜など
で炎症などの障害を生じることがあるため、従来より消
石灰肥料の飛散防止に対する使用者側のニーズには根強
いものがあった。However, since the particles of slaked lime fertilizer are extremely small and have a low specific gravity, they are often lost due to scattering during spraying, so it is necessary to replenish the lost amount before spraying in order to achieve the desired fertilizer effect. Not only is this an economic disadvantage, but it can also cause pollution because it is scattered in areas other than the desired location, and it can also adhere to the skin of workers and cause skin irritation, get into the eyes and mouth, etc. Users have long had a deep-rooted need to prevent slaked lime fertilizer from scattering because it can cause problems such as inflammation in mucous membranes.
［発明が解決しようとする問題点］
そこで本発明者は消石灰肥料が有する特性を保持し、飛
散性が小さい消石灰肥料をうるべく鋭意研究を重ねた結
果、パルプ粉単独またはそれとアルコール変性メラミン
−ホルムアルデヒド初期縮合物水性液との混合物を消石
灰粉末に添加して該消石灰粒子を処理したばあい、えら
れた消石灰肥料は優れた防散効果を呈するというまった
く新しい事実を見出し、本発明を完成するに至った。[Problems to be Solved by the Invention] Therefore, the inventor of the present invention conducted intensive research to create a slaked lime fertilizer that maintains the characteristics of slaked lime fertilizer and has low scattering properties, and found that pulp powder alone or in combination with alcohol-denatured melamine-formaldehyde. The inventors have discovered a completely new fact that when a mixture with an aqueous initial condensate liquid is added to slaked lime powder to treat the slaked lime particles, the resulting slaked lime fertilizer exhibits an excellent dispersion prevention effect, and in order to complete the present invention. It's arrived.
［問題点を解決するための手段］
本発明はパルプ粉単独またはそれとアルコール変性メラ
ミン−ホルムアルデヒド初期縮合物水性液との混合物と
、消石灰粉末とからなる消石灰肥料およびパルプ粉単独
またはそれとアルコール変性メラミン−ホルムアルデヒ
ド初期縮合物水性液との混合物を消石灰粉末１００重量
部、に対して０．１〜５重量部添加し、混合撹拌するこ
とにより前記パルプ粉単独またはそれとアルコール変性
メラミン−ホルムアルデヒド初期縮合物との混合物を消
石灰粒子に付着させることを特徴とする消石灰肥料の製
造方法に関する。[Means for Solving the Problems] The present invention provides a slaked lime fertilizer consisting of pulp powder alone or a mixture of it and an alcohol-modified melamine-formaldehyde initial condensate aqueous liquid, and slaked lime powder, and pulp flour alone or a mixture of it and alcohol-modified melamine-formaldehyde initial condensate. By adding 0.1 to 5 parts by weight of a mixture with an aqueous formaldehyde initial condensate to 100 parts by weight of slaked lime powder and stirring, the pulp powder alone or a combination of it and an alcohol-modified melamine-formaldehyde initial condensate can be prepared. The present invention relates to a method for producing slaked lime fertilizer, which comprises adhering a mixture to slaked lime particles.
［作用および実施例］
本発明の消石灰肥料は、パルプ粉単独またはそれとアル
コール変性メラミン−ホルムアルデヒド初期縮合物との
混合物を消石灰粉末に添加し、混合撹拌して前記バ！レ
ブ粉単独ままたはそれとアルコール変性メラミン−ホル
ムアルデヒド初期縮合物水性液との混合惣をｔＱ石灰粉
末に付着させることによりえられる。[Function and Examples] The slaked lime fertilizer of the present invention is produced by adding pulp powder alone or a mixture of pulp powder and an alcohol-modified melamine-formaldehyde initial condensate to slaked lime powder, mixing and stirring to produce the slaked lime fertilizer described above. It can be obtained by attaching Rebu powder alone or a mixture of it and an aqueous alcohol-modified melamine-formaldehyde initial condensate to tQ lime powder.
本発明に用いられるアルコール変性メラミン−ホルムア
ルデヒド初期縮合物水性液（以下、メラミン樹脂水性液
という）はホルムアルデヒドとメラミンとをモル比７１
＝２〜３で反応させることによりえられるメ？ミンーホ
ルムアルデヒド初期縮合物を低級アルコール、なかんづ
くメタノール、エタノール、プロパツールやブタノール
などで変性することによりえられるものである。The alcohol-modified melamine-formaldehyde initial condensate aqueous liquid (hereinafter referred to as melamine resin aqueous liquid) used in the present invention contains formaldehyde and melamine in a molar ratio of 71.
=Mean obtained by reacting with 2~3? It is obtained by denaturing the min-formaldehyde initial condensate with lower alcohols, particularly methanol, ethanol, propatool, butanol, etc.
前記パルプ粉としては、たとえば古紙再生繊維や製紙用
バルブなどのバルブや植物性短繊維などがあげられる。Examples of the pulp powder include recycled waste paper fibers, valves such as paper-making valves, and short vegetable fibers.
前記植物短繊維としては、繊維長が１〜３０１１１％繊
度が０．１〜２デニールに破砕されたものを用いるのが
好ましい。As the short plant fibers, it is preferable to use those crushed to have a fiber length of 1 to 30111% and a fineness of 0.1 to 2 deniers.
前記パルプ粉のみを用いて消石灰肥料を調製するばあい
、添加する水の量は、パルプ粉１００重量部に対して５
００〜７００重量部となるように調整するのが好ましい
。水の添加量は５００重量部未満であるばあい、パルプ
粉の濃度が高くなって分散しにくくなり、また７００ｆ
ｆｉ量部をこえるばあい、パルプ粉の濃度が低くなって
処理効果が低下する。When preparing slaked lime fertilizer using only the pulp powder, the amount of water added is 5 parts by weight per 100 parts by weight of pulp powder.
It is preferable to adjust the amount to 00 to 700 parts by weight. If the amount of water added is less than 500 parts by weight, the concentration of pulp powder will become high and it will be difficult to disperse, and if the amount of water added is less than 500 parts by weight,
If the amount exceeds fi parts, the concentration of pulp powder becomes low and the treatment effect decreases.
前記パルプ粉とメラミン樹脂水溶液との混合物を用いて
消石灰肥料を調製するばあい、パルプ粉とメラミン樹脂
水性液との混合割合は、メラミン樹脂水性液中のメラミ
ン樹脂含有量によって異なるので一概には決定すること
はできないが、通常パルプ粉１００重量部に対してメラ
ミン樹脂水性液２０〜５００重量部、なかんづ＜２０〜
３００重量部とするのが好ましい。該メラミン樹脂水性
液の使用量は、２０重量部よりもすくないばあい、パル
プ粉に対する相対量が小さくなってうまく分散混合でき
なくなり、パルプ粉を消石灰粉末の粒子またはパルプ粉
に付着させるための媒体としての効果が減少する。また
５００重量部をこえるばあい、分散性においては満足さ
れてもその増量による効果は認められず、過余剰のメラ
ミン樹脂水性液が容器の器壁などへ付着し、経済的にマ
イナスとなる。When preparing slaked lime fertilizer using a mixture of the pulp powder and the melamine resin aqueous solution, the mixing ratio of the pulp powder and the melamine resin aqueous solution varies depending on the melamine resin content in the melamine resin aqueous solution, so it cannot be generalized. Although it cannot be determined, usually 20 to 500 parts by weight of the melamine resin aqueous liquid per 100 parts by weight of pulp powder, and <20 to 500 parts by weight of the melamine resin aqueous liquid.
The amount is preferably 300 parts by weight. If the amount of the melamine resin aqueous liquid used is less than 20 parts by weight, the relative amount to the pulp powder will be small and it will not be possible to disperse and mix it well, and it will become a medium for adhering the pulp powder to the slaked lime powder particles or pulp powder. The effectiveness of this decreases. Moreover, if the amount exceeds 500 parts by weight, even if the dispersibility is satisfied, the effect of increasing the amount will not be recognized, and an excess of the melamine resin aqueous liquid will adhere to the walls of the container, resulting in an economic disadvantage.
前記パルプ粉とメラミン樹脂水性液との混合物に添加す
る水の量は、メラミン樹脂水性液１００重量部に対して
５００〜７００重量部となるように調整するのが好まし
い。水の添加量は、５００重量部未満であるばあい、メ
ラミン樹脂の濃度が高く、液の粘性が大きくなり、消石
灰中にうまく滲透しにくく、また経済的に高価になる。The amount of water added to the mixture of pulp powder and aqueous melamine resin liquid is preferably adjusted to 500 to 700 parts by weight per 100 parts by weight of the aqueous melamine resin liquid. If the amount of water added is less than 500 parts by weight, the concentration of the melamine resin will be high, the viscosity of the liquid will be high, it will be difficult to penetrate into the slaked lime, and it will be economically expensive.
また７００重量部をこえるばあい、消石灰に対するメラ
ミン樹脂量が相対的に小さくなり、処理効果が低下する
。Moreover, if it exceeds 700 parts by weight, the amount of melamine resin relative to slaked lime becomes relatively small, and the treatment effect decreases.
なお、用いる水については本発明においてはとくに限定
はなく、たとえば水道水や井戸水などを用いることがで
きる。水を添加する方法の一例としては、前記パルプ粉
単独またはそれとメラミン樹脂水性液との混合物を撹拌
しながらそれに水を噴霧する方法があげられる。Note that the water used is not particularly limited in the present invention, and for example, tap water, well water, etc. can be used. An example of a method for adding water is a method of spraying water onto the pulp powder alone or a mixture of the pulp powder and an aqueous melamine resin liquid while stirring the pulp powder.
前記消石灰粉末としては、生石灰に水を注いで消化する
ことによりえられる主として水酸化カルシウムからなる
一般に用いられているものをそのまま用いることができ
る。該消石灰粉末の粒径については、本発明においては
とくに限定はないが、小さければ小さいものほど好まし
い。As the slaked lime powder, a commonly used powder mainly composed of calcium hydroxide obtained by pouring water into quicklime and digesting it can be used as is. The particle size of the slaked lime powder is not particularly limited in the present invention, but the smaller it is, the more preferable it is.
また、前記水が添加された、パルプ粉単独またはそれと
メラミン樹脂水性液の混合物を消石灰粒子に添加するこ
とにより、本発明の消石灰肥料かえられるが、該水が添
加されたパルプ粉単独またはそれとメラミン樹脂水性液
との混合物の添加量は石灰粒子１００重量部に対して希
釈前のパルプ粉またはそれとメラミン樹脂水性液の混合
物量に換算して０，１〜５重量部、なかんづ＜０．５〜
１゜０重量部であるのが好ましい。該添加量は０．１重
量部未満であるばあい、えられる消石灰肥料が飛散しや
すくなり、また５重量部をこえると高価になるとともに
該消石灰肥料の主成分である消石灰粉末の占める割合が
小さくなり、肥料としての効果が小さくなる。Furthermore, the slaked lime fertilizer of the present invention can be changed by adding the water-added pulp powder alone or a mixture thereof and a melamine resin aqueous liquid to the slaked lime particles. The amount of the mixture with the resin aqueous liquid added is 0.1 to 5 parts by weight in terms of the amount of pulp powder before dilution or the mixture of it and the melamine resin aqueous liquid per 100 parts by weight of lime particles, where <0. 5~
Preferably it is 1.0 parts by weight. If the amount added is less than 0.1 parts by weight, the resulting slaked lime fertilizer will easily scatter, and if it exceeds 5 parts by weight, it will become expensive and the proportion of slaked lime powder, which is the main component of the slaked lime fertilizer, will decrease. It becomes smaller and less effective as a fertilizer.
前記水が添加されたパルプ粉単独またはそれとメラミン
樹脂水性液との混合物と、消石灰粉末との混合は、たと
えばロール、バンバリーミキサ−やニーダなどの混線手
段によって行なわれ、パルプ粉単独またはそれとメラミ
ン樹脂水性液との混合物が消石灰粉末に付着される。The mixing of the water-added pulp powder alone or a mixture thereof with the melamine resin aqueous liquid and the slaked lime powder is carried out by, for example, a mixing means such as a roll, a Banbury mixer, or a kneader. A mixture with an aqueous liquid is applied to the slaked lime powder.
なお、本発明の方法を実施するにあたっては、消石灰粉
末を攪拌しながら該消石灰粉末にパルプ粉単独またはそ
れとメラミン樹脂水性液の混合物が添加されるが、その
際、前記メラミン樹脂水性液をたとえば噴霧などの手段
によって添加すると共にパルプ粉を添加することによっ
て、その場でコンパウンドをつくるようにして、コンパ
ウンドの混合攪拌を行なうのも好ましい一実施態様であ
る。In carrying out the method of the present invention, pulp powder alone or a mixture of pulp powder and a melamine resin aqueous liquid is added to the slaked lime powder while stirring the slaked lime powder. At this time, the melamine resin aqueous liquid is, for example, sprayed. It is also a preferred embodiment to mix and stir the compound by adding pulp powder and making the compound on the spot.
かくして消石灰粉末とパルプ粉単独またはそれとメラミ
ン樹脂水性液の混合物からなる本発明の消石灰肥料は、
つぎのような過程により防散効果を発揮する。Thus, the slaked lime fertilizer of the present invention, which is composed of slaked lime powder and pulp powder alone or a mixture of them and an aqueous melamine resin liquid,
The anti-scattering effect is achieved through the following process.
消石灰粉末の粒子は負に帯電しており、この消石灰粉末
のなかに正に帯電しているメラミン樹脂水性液を添加処
理すると、このメラミン樹脂水性液種消石灰の粒子表面
に付着する。同時にパルプ粉を添加したばあいは、パル
プ粉は負に帯電しており、消石灰粉末の粒子は、その表
面に付着したメラミン樹脂水性液を媒体として他の消石
灰粉末の粒子および／またはパルプ粉に付着する。なお
、メラミン樹脂水性液には、消石灰粉末に添加するまえ
に水が添加されるのが好ましい。かかる処理によりメラ
ミン樹脂水性液が消石灰粉末の粒子に付着する。The particles of slaked lime powder are negatively charged, and when a positively charged aqueous melamine resin liquid is added to the slaked lime powder, the melamine resin aqueous liquid adheres to the surface of the slaked lime particles. If pulp powder is added at the same time, the pulp powder is negatively charged, and the slaked lime powder particles are mixed with other slaked lime powder particles and/or pulp powder using the melamine resin aqueous liquid attached to the surface as a medium. adhere to. Note that water is preferably added to the melamine resin aqueous liquid before adding it to the slaked lime powder. This treatment causes the melamine resin aqueous liquid to adhere to the particles of slaked lime powder.
上記の結果、パルプ粉単独またはそれとメラミン樹脂水
性液との混合物が付着した消石灰粉末の粒子の重量は、
消石灰粉末のみの粒子の重量よりも大きくなり、さらに
消石灰粉末のからみあったパルプ粉への付着により生じ
る軽い凝集により、散布時の飛散が抑制される。なお、
消石灰肥料の粒子単体の重量は増加してもパルプ粉のか
らみあいにより生じる空隙のため、消石灰肥料の嵩比重
は軽くなる。As a result of the above, the weight of slaked lime powder particles to which pulp powder alone or a mixture of pulp powder and melamine resin aqueous liquid is attached is:
The weight of the particles is larger than that of the slaked lime powder alone, and the light aggregation caused by adhesion of the slaked lime powder to the entangled pulp powder suppresses scattering during spraying. In addition,
Even if the weight of individual particles of slaked lime fertilizer increases, the bulk specific gravity of slaked lime fertilizer becomes lighter due to the voids created by the entanglement of pulp powder.
本発明の消石灰肥料の製造法によれば、パルプ粉単独ま
たはそれとメラミン樹脂水性液との混合物を消石灰粉末
に添加し、混合撹拌した際には数分以内にパルプ粉単独
またはそれとメラミン樹脂水溶液との混合物と、消石灰
粉末とが付着し、軽い凝集を生じる。According to the method for producing slaked lime fertilizer of the present invention, when pulp powder alone or a mixture of it and an aqueous melamine resin solution is added to slaked lime powder and mixed and stirred, pulp powder alone or a mixture of it and an aqueous melamine resin solution are added within a few minutes. The mixture of slaked lime and slaked lime powder adhere to each other, resulting in slight agglomeration.
つぎに本発明の消石灰肥料を実施例に基づいてさらに詳
細に説明するが、本発明はかかる実施例のみに限定され
るものではない。Next, the slaked lime fertilizer of the present invention will be explained in more detail based on Examples, but the present invention is not limited to these Examples.
実施例１
・消石灰粉末（平均粒径ニア通、みかけ比重：０．４９
ｇ ／ ｍｌ ）２００ ｇに水６ｇおよびブタノー
ル変性メラミン樹脂水性液（メラミン樹脂含有ｍ：８０
％）Ｉｇを添加したのち、パルプ粉１ｇを添加し、ジュ
ース用電気ミキサー（松下電器産業■製、品番： ＭＸ
−８４０Ｇ ）を用いて１分間撹拌し、消石灰肥料を作
製した。Example 1 - Slaked lime powder (average particle size near average, apparent specific gravity: 0.49
g/ml) 200 g with 6 g of water and a butanol-modified melamine resin aqueous solution (melamine resin content m: 80
%) After adding Ig, 1 g of pulp powder was added, and an electric mixer for juice (manufactured by Matsushita Electric Industrial ■, product number: MX) was added.
-840G) for 1 minute to prepare slaked lime fertilizer.
つぎにえられた消石灰肥料の物性として比表面積、みか
け比重、水素イオン濃度およびアルカリ分ならびに飛散
率および減少率を下記の方法に基づいて測定した。その
結果を第１表に示す。Next, the physical properties of the obtained slaked lime fertilizer, such as specific surface area, apparent specific gravity, hydrogen ion concentration, alkaline content, scattering rate, and reduction rate, were measured based on the following methods. The results are shown in Table 1.
（比表面積）
粉体比表面積測定装置（■島津製作所製、型式： ８３
−１００形）を用いて測定した。(Specific surface area) Powder specific surface area measurement device (manufactured by Shimadzu Corporation, model: 83
-100 type).
（みかけ比重）
農薬公定検査法に規定する見掛比重測定法に基づいて測
定した。(Appearance specific gravity) Measured based on the apparent specific gravity measurement method stipulated in the official agricultural chemical testing method.
（水素イオン濃度）
ガラス電極ｐＨメーター１Ｍ−５Ｂ形（東亜電波工業■
製）を用いて測定した。(Hydrogen ion concentration) Glass electrode pH meter 1M-5B type (Toa Denpa Kogyo ■
(manufactured by).
（アルカリ分）
農林水産省農業技術研究所発行の肥料分析法のなかの塩
酸法に基づいて測定した。(Alkalinity) Measured based on the hydrochloric acid method among the fertilizer analysis methods published by the Agricultural Technology Research Institute of the Ministry of Agriculture, Forestry and Fisheries.
（飛散率）
高さ Ｉｏｏｃｍ、幅４００１＋１．長さ ２００ ｃ
＋ｎの風洞の一端に送風機を取り付け、風速を１．０ｍ
／秒に設定し、風洞の出口に設置した試料投入口（直径
；１ｃｍ）より消石灰肥料を０．０５ｇ／秒の割合で落
下させ、試料投入口の直下より半径１ｍの領域外に飛散
した消石灰肥料の重量から、飛散率（［領域外に飛散し
た消石灰肥料の重量］×１００／ ［飛散させた消石灰
肥料の重量］）を求めた。(Scatter rate) Height Ioocm, width 4001+1. length 200c
Attach a blower to one end of the +n wind tunnel and increase the wind speed to 1.0 m.
/second, and slaked lime fertilizer was dropped at a rate of 0.05g/second from the sample input port (diameter: 1cm) installed at the exit of the wind tunnel, and the slaked lime scattered outside the area within a 1m radius from directly below the sample input port. From the weight of the fertilizer, the scattering rate ([weight of slaked lime fertilizer scattered outside the area] x 100/[weight of slaked lime fertilizer scattered]) was determined.
（減少率）
前記飛散率の測定方法にしたがって消石灰肥料として実
施例１で用いたのと同じ消石灰粉末を用いて飛散率を測
定しく比較例１）、このときの飛散率に対する消石灰肥
料を飛散させたときの飛散率の減少率を求めた。(Reduction rate) The scattering rate was measured using the same slaked lime powder as used in Example 1 as the slaked lime fertilizer according to the method for measuring the scattering rate. Comparative Example 1) The reduction rate of the scattering rate was calculated when
実施例２〜１３
実施例１で用いたものと同じ消石灰粉末２００ｇに水、
水溶性メラミン樹脂水性液、パルプ粉および植物短繊維
（古紙再生繊維、繊維長：２０關、繊度：１デニール）
を第１表に示すように調製して添加したほかは実施例１
と同様にして消石灰肥料を作製した。えられた消石灰肥
料の物性を実施例１と同様にして測定した。その結果を
第１表に示す。Examples 2 to 13 Water and 200 g of the same slaked lime powder used in Example 1 were added.
Water-soluble melamine resin aqueous liquid, pulp powder and short vegetable fibers (used paper recycled fiber, fiber length: 20 mm, fineness: 1 denier)
Example 1 except that the following was prepared and added as shown in Table 1.
Slaked lime fertilizer was prepared in the same manner as above. The physical properties of the obtained slaked lime fertilizer were measured in the same manner as in Example 1. The results are shown in Table 1.
比較例１
実施例１で用いたものと同じ消石灰粉末２００ｇのみか
らなる従来の消石灰肥料を用いたほかは実施例１と同様
にして消石灰肥料の物性を測定した。その結果を第１表
に示す。Comparative Example 1 The physical properties of a slaked lime fertilizer were measured in the same manner as in Example 1, except that a conventional slaked lime fertilizer consisting of only 200 g of slaked lime powder, which was the same as that used in Example 1, was used. The results are shown in Table 1.
（以下余白］
以上の結果から本発明の消石灰肥料は、消石灰が有する
ｐＨなどの特性を損わずに、使用時における飛散率の減
少率が従来の消石灰肥料と比べて約３５％以上と大幅に
向上されたものであることがわかる。(Left below) From the above results, the slaked lime fertilizer of the present invention has a significant reduction in scattering rate of about 35% or more when used, compared to conventional slaked lime fertilizers, without impairing the pH and other properties of slaked lime. It can be seen that this has been improved.
［発明の効果］
本発明の消石灰肥料の製造方法によってえられた消石灰
肥料は、強アルカリ性でかつ速効性であるという消石灰
が有する特性をなんら失わず、散布時などにおける飛散
による障害やロスなどが小さいので、取扱いやすくしか
も経済的であるという効果を奏する。[Effects of the Invention] The slaked lime fertilizer obtained by the method for producing slaked lime fertilizer of the present invention does not lose any of the characteristics of slaked lime, which are strongly alkaline and fast-acting, and does not cause any damage or loss due to scattering during spraying. Since it is small, it is easy to handle and economical.
Claims (1)
−ホルムアルデヒド初期縮合物水性液との混合物と、消
石灰粉末とからなる消石灰肥料。 ２ パルプ粉単独またはそれとアルコール変性メラミン
−ホルムアルデヒド初期縮合物水性液との混合物の添加
量が消石灰粉末１００重量部に対して０．１〜５重量部
である特許請求の範囲第１項記載の消石灰肥料。 ３ パルプ粉単独またはそれとアルコール変性メラミン
−ホルムアルデヒド初期縮合物水性液との混合物を消石
灰粉末１００重量部に対して０．１〜５重量部添加し、
混合撹拌することにより前記パルプ粉単独またはそれと
アルコール変性メラミン−ホルムアルデヒド初期縮合物
水性液との混合物を消石灰粉末に付着させることを特徴
とする消石灰肥料の製造方法。[Scope of Claims] 1. A slaked lime fertilizer comprising pulp powder alone or a mixture of pulp powder and an aqueous alcohol-modified melamine-formaldehyde initial condensate, and slaked lime powder. 2. Slaked lime according to claim 1, wherein the amount of pulp powder alone or a mixture of pulp powder and an aqueous alcohol-modified melamine-formaldehyde initial condensate is added in an amount of 0.1 to 5 parts by weight per 100 parts by weight of slaked lime powder. fertilizer. 3 Adding 0.1 to 5 parts by weight of pulp powder alone or a mixture of it and an aqueous liquid of alcohol-modified melamine-formaldehyde initial condensate to 100 parts by weight of slaked lime powder,
A method for producing slaked lime fertilizer, which comprises adhering either the pulp powder alone or a mixture of it and an aqueous alcohol-modified melamine-formaldehyde initial condensate to slaked lime powder by mixing and stirring.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP13709687A JPS63297290A (en) | 1987-05-29 | 1987-05-29 | Slaked lime fertilizer and manufacture |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP13709687A JPS63297290A (en) | 1987-05-29 | 1987-05-29 | Slaked lime fertilizer and manufacture |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS63297290A true JPS63297290A (en) | 1988-12-05 |
| JPH0246556B2 JPH0246556B2 (en) | 1990-10-16 |
Family
ID=15190773
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP13709687A Granted JPS63297290A (en) | 1987-05-29 | 1987-05-29 | Slaked lime fertilizer and manufacture |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS63297290A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2020132442A (en) * | 2019-02-14 | 2020-08-31 | 株式会社竹中庭園緑化 | Liquid fertilizer containing silicate and method of growing plant using the same |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP6876184B2 (en) * | 2020-06-23 | 2021-05-26 | 株式会社ユニバーサルエンターテインメント | Pachinko machine |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS63270377A (en) * | 1987-04-27 | 1988-11-08 | 足立石灰工業株式会社 | Slaked lime fertilizer and manufacture |
-
1987
- 1987-05-29 JP JP13709687A patent/JPS63297290A/en active Granted
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS63270377A (en) * | 1987-04-27 | 1988-11-08 | 足立石灰工業株式会社 | Slaked lime fertilizer and manufacture |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2020132442A (en) * | 2019-02-14 | 2020-08-31 | 株式会社竹中庭園緑化 | Liquid fertilizer containing silicate and method of growing plant using the same |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0246556B2 (en) | 1990-10-16 |
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