JPS63296758A - Sterilizing deodorant - Google Patents
Sterilizing deodorantInfo
- Publication number
- JPS63296758A JPS63296758A JP62134008A JP13400887A JPS63296758A JP S63296758 A JPS63296758 A JP S63296758A JP 62134008 A JP62134008 A JP 62134008A JP 13400887 A JP13400887 A JP 13400887A JP S63296758 A JPS63296758 A JP S63296758A
- Authority
- JP
- Japan
- Prior art keywords
- chlorine dioxide
- aqueous solution
- stabilized chlorine
- pref
- microporous beads
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 230000001954 sterilising effect Effects 0.000 title claims abstract description 9
- 239000002781 deodorant agent Substances 0.000 title abstract description 4
- OSVXSBDYLRYLIG-UHFFFAOYSA-N dioxidochlorine(.) Chemical compound O=Cl=O OSVXSBDYLRYLIG-UHFFFAOYSA-N 0.000 claims abstract description 45
- 239000004155 Chlorine dioxide Substances 0.000 claims abstract description 23
- 235000019398 chlorine dioxide Nutrition 0.000 claims abstract description 23
- 239000007864 aqueous solution Substances 0.000 claims abstract description 20
- 239000011324 bead Substances 0.000 claims abstract description 15
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims abstract description 5
- 229910052782 aluminium Inorganic materials 0.000 claims abstract description 5
- 239000004745 nonwoven fabric Substances 0.000 claims abstract description 5
- 230000001877 deodorizing effect Effects 0.000 claims description 9
- 239000003795 chemical substances by application Substances 0.000 claims description 7
- 239000011148 porous material Substances 0.000 abstract description 12
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract description 11
- 239000002245 particle Substances 0.000 abstract description 6
- 229910052681 coesite Inorganic materials 0.000 abstract description 4
- 229910052906 cristobalite Inorganic materials 0.000 abstract description 4
- 239000000377 silicon dioxide Substances 0.000 abstract description 4
- 235000012239 silicon dioxide Nutrition 0.000 abstract description 4
- 239000002002 slurry Substances 0.000 abstract description 4
- 229910052682 stishovite Inorganic materials 0.000 abstract description 4
- 229910052905 tridymite Inorganic materials 0.000 abstract description 4
- 239000000843 powder Substances 0.000 abstract description 3
- 239000011347 resin Substances 0.000 abstract description 3
- 229920005989 resin Polymers 0.000 abstract description 3
- 239000000126 substance Substances 0.000 abstract description 3
- 229920001577 copolymer Polymers 0.000 abstract description 2
- 230000000052 comparative effect Effects 0.000 description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 7
- 244000269722 Thea sinensis Species 0.000 description 5
- 239000000243 solution Substances 0.000 description 5
- 235000006468 Thea sinensis Nutrition 0.000 description 4
- 235000020279 black tea Nutrition 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- 235000019645 odor Nutrition 0.000 description 4
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 3
- 239000000645 desinfectant Substances 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 239000011325 microbead Substances 0.000 description 3
- 239000000741 silica gel Substances 0.000 description 3
- 229910002027 silica gel Inorganic materials 0.000 description 3
- 210000001685 thyroid gland Anatomy 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- 235000005979 Citrus limon Nutrition 0.000 description 2
- 244000131522 Citrus pyriformis Species 0.000 description 2
- 230000002378 acidificating effect Effects 0.000 description 2
- 239000003463 adsorbent Substances 0.000 description 2
- 239000004744 fabric Substances 0.000 description 2
- 239000012943 hotmelt Substances 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- 241001465754 Metazoa Species 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000004480 active ingredient Substances 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 235000011114 ammonium hydroxide Nutrition 0.000 description 1
- 238000007664 blowing Methods 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- -1 chlorine dioxide compound Chemical class 0.000 description 1
- 238000004332 deodorization Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000002360 explosive Substances 0.000 description 1
- 210000003608 fece Anatomy 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 235000011389 fruit/vegetable juice Nutrition 0.000 description 1
- 238000005470 impregnation Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 230000020477 pH reduction Effects 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 235000013616 tea Nutrition 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Landscapes
- Disinfection, Sterilisation Or Deodorisation Of Air (AREA)
Abstract
Description
【発明の詳細な説明】
〔産業上の利用分野〕
本発明は、殺菌・消臭剤に関する。更に詳しくは、安定
化二酸化塩素化合物を有効成分とする殺菌・消臭剤に関
する。DETAILED DESCRIPTION OF THE INVENTION [Field of Industrial Application] The present invention relates to a disinfectant and deodorizer. More specifically, the present invention relates to a disinfectant/deodorant containing a stabilized chlorine dioxide compound as an active ingredient.
二酸化塩素が、強い酸化剤であることは周知である。安
定化二酸化塩素は、安定形態の二酸化塩素錯体を水溶液
にしたもので、二酸化塩素ガスの利点をすべて備え、爆
発性などその欠点を持たない。It is well known that chlorine dioxide is a strong oxidizing agent. Stabilized chlorine dioxide is an aqueous solution of a stable form of chlorine dioxide complex, which has all the advantages of chlorine dioxide gas without its disadvantages, such as its explosive nature.
安定化二酸化塩素には、約６より低いｐｉ（へと酸性化
することによりガス状二酸化塩素を発生するに適した安
定化二酸化塩素水溶液と、これを有効量吸着した塩基性
吸着剤を含む粉状固体の２種形態があり、酸性物質を添
加してｐＨを調節することによりＣＵ Ｏ２ガスの発生
速度を自由に調節出来る。Stabilized chlorine dioxide includes a stabilized chlorine dioxide aqueous solution suitable for generating gaseous chlorine dioxide by acidification to a pi lower than about 6, and a powder containing a basic adsorbent that has adsorbed an effective amount of the stabilized chlorine dioxide solution. There are two types of solid forms, and the rate of generation of CU O2 gas can be freely adjusted by adding an acidic substance to adjust the pH.
従って、安定化二酸化塩素は、殺菌剤、消臭剤等広範な
用途に用いられる。Therefore, stabilized chlorine dioxide is used in a wide range of applications such as disinfectants and deodorants.
しかしながら、この水溶液を用いる場合には、次のよう
な欠点がある。例えば、消臭対象物に散布すると固まっ
たりして堆積した対象物では散布した液が流れてその効
果が減少することが多く、空気中の悪臭を消す為に噴霧
状に散布すると人畜に害を与え、又悪臭を含む空気を水
溶液中に吹き込んだり、水溶液のシャワーをくぐらせる
方法もあるが、大災りな装置を要するなどの欠点がみら
れる。悪臭を自然吸収させるには、接触面積を相当大に
する必要があり、布等に滲み込ませる方法もあるが、布
を保持する方法、人体に触れない様にする為の手段が厄
介である。However, when using this aqueous solution, there are the following drawbacks. For example, when sprayed on an object to be deodorized, it often solidifies and accumulates on the object, causing the sprayed liquid to flow and reduce its effectiveness.If sprayed in the form of a spray to eliminate bad odors in the air, it may cause harm to humans and animals. There are also methods such as blowing foul-smelling air into the aqueous solution or passing through a shower of the aqueous solution, but these methods have drawbacks such as the need for expensive equipment. In order to naturally absorb bad odors, it is necessary to make the contact area considerably large, and there is also a method of letting the odor seep into cloth, etc., but the method of holding the cloth and the means to prevent it from coming into contact with the human body are complicated. .
塩基性吸着剤を含む粉状固体の場合、対象が水分を有す
る酸性廃棄物のときには、その上に散布することが出来
るが、他の場合には使用時に水に溶解する必要がある点
で、溶液の場合より一層厄介である。In the case of powdered solids containing basic adsorbents, when the target is acidic waste with moisture, it can be sprayed onto it, but in other cases it needs to be dissolved in water before use. This is even more troublesome than in the case of solutions.
本発明者等は、安定化二酸化塩素の水溶液における上記
の問題点を解決すべく、安定化二酸化塩素水溶液を水溶
液の特性を残したまま粉状固体化することを鋭意研究の
結果、安定化二酸化塩素水溶液をマイクロポーラスビー
ズに含浸せしめたものが有効であることを見出し、本発
明に至った。In order to solve the above-mentioned problems with an aqueous solution of stabilized chlorine dioxide, the present inventors have conducted extensive research into solidifying a stabilized chlorine dioxide aqueous solution into a powder form while retaining the characteristics of the aqueous solution. It was discovered that microporous beads impregnated with an aqueous chlorine solution was effective, leading to the present invention.
即ち、本発明は殺菌・消臭剤に係り、この殺菌・消臭剤
は、安定化二酸化塩素水溶液をマイクロポーラスビーズ
に含浸せしめてなる。好ましくは、本発明の殺菌・消臭
剤は、殺菌・消臭剤は、安定化二酸化塩素水溶液をマイ
クロポーラスビーズに含浸せしめた殺菌・消臭剤を、最
小孔隙径１００μｍでヒートシール可能な水不溶性の不
織布または不織紙製の袋及び／又は片面を熱溶融性樹脂
フィルムをラミネートしたアルミ製の袋に充填し、装入
口をヒートシールして用いられる。That is, the present invention relates to a sterilizing/deodorizing agent, which is made by impregnating microporous beads with a stabilized chlorine dioxide aqueous solution. Preferably, the sterilizing/deodorizing agent of the present invention is a sterilizing/deodorizing agent in which microporous beads are impregnated with a stabilized chlorine dioxide aqueous solution, and the sterilizing/deodorizing agent is made of water that can be heat-sealed with a minimum pore size of 100 μm. It is used by filling a bag made of insoluble nonwoven fabric or paper and/or an aluminum bag laminated with a hot-melt resin film on one side, and heat-sealing the charging port.
本発明に用いられる安定化二酸化塩素水溶液としては、
市販品１例えば純正化学（株）製品シュンクレーム（安
定化二酸化塩素、５０．ＯＯＯｐｐｍ）などが用いられ
る。The stabilized chlorine dioxide aqueous solution used in the present invention includes:
Commercially available product 1, such as Schunkreme (stabilized chlorine dioxide, 50.00ppm) manufactured by Junsei Kagaku Co., Ltd., is used.
マイクロポーラスビーズとしては、ＳｉＯ２系、スチレ
ン−ジビニルベンゼン共重合体系等を使用出来るが、細
孔容積約０．３〜２．０ｍ Ｑ ／ｇ、好ましくは約０
．５〜１．６ｍ Ｑ ／ｇ、平均細孔径約２５〜３００
人、好ましくは約１００〜２００人、５％水スラリーｐ
Ｈ約６．５〜９、好ましくは約７〜８、平均粒子径約１
．４μｍ〜５ｍｍのＳｉＯ２系マイクロポーラスビーズ
が好んで用いられる。具体的には、富士デヴイソン化学
（株）製マイクロビーズシリカゲル５Ｄ（細孔容積１．
１ｍ Ｑ ／ｇ、平均細孔径１６０人、５％水スラリー
ｐＨ８，０，粒度ｉｏ。As the microporous beads, SiO2 type, styrene-divinylbenzene copolymer type, etc. can be used, but the pore volume is about 0.3 to 2.0 m Q /g, preferably about 0.
．． 5-1.6m Q/g, average pore diameter about 25-300
people, preferably about 100-200 people, 5% water slurry p
H about 6.5-9, preferably about 7-8, average particle size about 1
．． SiO2-based microporous beads of 4 μm to 5 mm are preferably used. Specifically, Microbead Silica Gel 5D manufactured by Fuji Davison Chemical Co., Ltd. (pore volume 1.
1 m Q /g, average pore size 160, 5% water slurry pH 8.0, particle size io.
〜２００メツシュ）あるいは同社製サイロイド８１０（
細孔容積１．６ｍ Ｑ ／ｇ、平均細孔径１２０人、９
水スラリーｐＨ７，０、平均粒子径３．０μｍ）などが
例示される。~200 mesh) or the company's Thyroid 810 (
Pore volume 1.6m Q/g, average pore diameter 120 people, 9
Examples include water slurry pH 7.0, average particle diameter 3.0 μm).
安定化二酸化塩素水溶液を、マイクロポーラスビーズの
細孔容積に対し９９％まで含浸することが可能であり、
含浸済みマイクロポーラスビーズ粒子の流動性は、含浸
前と殆んど変化がないことが分った。It is possible to impregnate up to 99% of the pore volume of microporous beads with a stabilized chlorine dioxide aqueous solution,
It was found that the fluidity of the impregnated microporous bead particles was almost unchanged from before impregnation.
この含浸済みマイクロポーラスビーズは、種々の袋詰形
態１例えばティーバッグの様な取扱いを意図して、最小
孔隙径が１００μｍでヒートシール可能な水不溶性の不
織布・不織紙製の袋に詰めたものあるいは更に水溶液の
乾燥防止効果を意図して、片面を熱溶融性樹脂フィルム
をラミネートしたアルミニウムシート製の袋に充填し、
装入口をヒートシールしたもの（袋を二重に用いる場合
、アルミシート袋が外側となる）として供給され、安定
化二酸化塩素の簡易利用が要請される各種用途に対応さ
せることが出来る。The impregnated microporous beads were packaged in a heat-sealable water-insoluble non-woven fabric/non-woven paper bag with a minimum pore size of 100 μm, with the intention of handling them in various packaging formats, such as tea bags. In order to prevent drying of the product or even the aqueous solution, the bag is filled with an aluminum sheet with one side laminated with a hot-melt resin film.
It is supplied with a heat-sealed charging port (if double bags are used, the aluminum sheet bag is the outside), and can be used for various applications that require simple use of stabilized chlorine dioxide.
安定化二酸化塩素水溶液の化学的特性を失うことなく粉
末化・粒子化が達成出来、取扱性の点で格段に向上した
製品が得られた。The stabilized chlorine dioxide aqueous solution was able to be powdered and granulated without losing its chemical properties, resulting in a product with significantly improved handling properties.
次に、実施例により本発明を更に詳細に説明する。 Next, the present invention will be explained in more detail with reference to Examples.
実施例１
５００ｍ Ｑビーカー中に、前述のマイクロビーズシリ
カゲル５０１００ｇを投入し、次に前述のシュンクレー
ムを１０９ｇ加える。ビーカー内容物を攪拌し、シュン
クレームをマイクロビーズシリカゲル５Ｄ中に完全に含
浸せしめた。これを含浸−５Ｄという。Example 1 Into a 500 m Q beaker, 50,100 g of the above-mentioned microbead silica gel is placed, and then 109 g of the above-mentioned Schunkreme is added. The contents of the beaker were stirred to completely impregnate the Schunkreme into the microbead silica gel 5D. This is called impregnation-5D.
実施例２
５００ｍ Ｑビーカー中に前述のサイロイド８１０１０
０ｇを投入し、次にシュンクレームを水で１０倍稀釈し
たちの１５５ｇを加える。ビーカー内容物を攪拌し、シ
ュンクレーム稀釈液をサイロイド８１０中に完全に含浸
せしめた。これを含浸−８１０という。Example 2 Said thyroid 81010 in a 500m Q beaker
Add 0g, then add 155g of Schunkreme diluted 10 times with water. The contents of the beaker were stirred to completely impregnate the Schunkrem diluted solution into Thyroid 810. This is called impregnation-810.
実施例３〜４、比較例１
飲用の紅茶の葉１ｇをとり、１８０ｍＱの湯（８０℃）
を注ぎ、１分間経過後葉を取り除いた紅茶液に。Examples 3-4, Comparative Example 1 Take 1 g of potable black tea leaves and add 180 mQ of hot water (80°C)
Pour into the black tea liquid and remove the leaves after 1 minute.
生レモン（サンキストレモン）の絞り汁を紅茶がほぼ淡
色になるまで加える。淡色になった紅茶液を３等分し、
その各々に含浸−５Ｄ Ｉｇ（実施例３）、含浸−８１
０１ｇ（実施例４）あるいはシュンクレーム０．５ｇ（
比較例１）をそれぞれ加えると、同様に赤褐色に着色し
た。これは含浸−５Ｄあるいは含浸−８１０が、シュン
クレームと同様の酸化作用を発揮したことを示すもので
ある。Add the juice of fresh lemon (Sunkist lemon) until the black tea becomes almost light in color. Divide the pale black tea liquid into three equal parts,
Impregnation-5D Ig (Example 3), impregnation-81
01g (Example 4) or Schunkreme 0.5g (
When each of Comparative Example 1) was added, the mixture was similarly colored reddish brown. This indicates that Impregnation-5D or Impregnation-810 exhibited the same oxidizing effect as Schuncrem.
実施例５、比較例２〜３
図面の第１〜３図に示される如く市販のシール性ふた付
ポリエチレン容器１．１’ 、１’ （容量約５８）の
底部に、３％アンモニア水溶液０．５ｍＱを入れたシャ
ーレ２．２’ 、２’を置いた容器を３個用意し、その
中の１個の容器１には、含浸−５０ｔｏｇを、長繊維不
織布（旭化成工業製フィールパック）により作られたＩ
ＯＣ！ｌｌＸｌ０■の袋５に入れ、容器の中間の高さの
位置に懸垂した（実施例５）。第２の容器１′には、５
０ｍＱのビーカー６中に５ｇのシュンクレームを加え、
容器中に設けられた支持台７により、容器の中間の高さ
の位置に保持した（比較例２）。第３の容器１′には、
前述のアンモニア水以外には何も入れなかった（比較例
３）。各容器には、ピンチコック付の空気の導入管３．
３’ 。Example 5, Comparative Examples 2 to 3 As shown in Figures 1 to 3 of the drawings, a 3% ammonia aqueous solution 0.0. Prepare three containers in which petri dishes 2.2' and 2' containing 5 mQ were placed, and in one container 1, impregnated -50 tog was prepared using a long fiber nonwoven fabric (Feel Pack manufactured by Asahi Kasei Industries). I was given
OC! It was placed in a bag 5 of 11X10 and suspended at the middle height of the container (Example 5). The second container 1' contains 5
Add 5g of Schunkreme to 0mQ beaker 6,
The container was held at a mid-height position by a support stand 7 provided in the container (Comparative Example 2). In the third container 1',
Nothing was added other than the ammonia water mentioned above (Comparative Example 3). Each container has an air inlet tube 3 with a pinch cock.
3'.
３１及び排気導出管４．４’ 、４’を設け、検討時に
ピンチコックを開いて導入管より少量の空気を導入し、
導出管より排気中のアンモニア臭を検討した。結果を第
１表に対比した。含浸−５Ｄの脱臭効果は、顕著であっ
た。31 and exhaust outlet pipes 4.4' and 4' are provided, and at the time of consideration, a pinch cock is opened to introduce a small amount of air from the inlet pipe,
We investigated the ammonia odor in the exhaust from the outlet pipe. The results are compared in Table 1. The deodorizing effect of Impregnation-5D was remarkable.
第１表
実施例６、比較例４〜５
牛糞（形の崩れにくいもの）約３ｋｇを、平らな面上に
直径約５０■の円になる様に一様に配置したものを３試
料設置し、第１の試料には、含浸−８１０２５５ｇを一
様に散布しく実施例６）、第２にはシュンクレーム１０
倍稀釈液１５５ｇをスプレーで一様に散布しく比較例４
）、第３はそのままに放置しく比較例５）、消臭の経過
を検討した。結果を第２表に対比した。Table 1 Example 6, Comparative Examples 4 to 5 Three samples of approximately 3 kg of cow dung (which does not easily lose its shape) were uniformly arranged in a circle with a diameter of approximately 50 cm on a flat surface. , the first sample was uniformly sprinkled with 255 g of Impregnation-810 (Example 6), and the second sample was coated with Schunkrem 10
Comparative Example 4: Spread 155g of the diluted solution uniformly with a sprayer.
), the third was left as is, and the progress of deodorization was examined. The results are compared in Table 2.
第２表 含浸−８１０の脱臭効果が、顕著であった。Table 2 The deodorizing effect of Impregnation-810 was remarkable.
第１〜３図は、実施例５、比較例２及び比較例３のそれ
ぞれの実施態様を示す概要図である。
（符号の説明）
１・・・・・シール性ふた付ポリエチレン容器２・・・
・・アンモニア水溶液を入れたシャーレ３・・・・・空
気導入管
４・・・・・排気導出管
５・・・・・袋
６・・・・・ビーカー
７・・・・・支持台1 to 3 are schematic diagrams showing respective embodiments of Example 5, Comparative Example 2, and Comparative Example 3. (Explanation of symbols) 1...Polyethylene container with sealable lid 2...
... Petri dish containing ammonia aqueous solution 3 ... Air introduction pipe 4 ... Exhaust outlet pipe 5 ... Bag 6 ... Beaker 7 ... Support stand
Claims (1)
に含浸せしめてなる殺菌・消臭剤。 ２、マイクロポーラスビーズが、ＳｉＯ＿２系マイクロ
ポーラスビーズである特許請求の範囲第１項記載の殺菌
・消臭剤。 ３、不織布または不織紙製の袋及び／又はヒートシール
性フィルムをラミネートしたアルミニウムシート製の袋
に充填して用いられる特許請求の範囲第１項記載の殺菌
・消臭剤。[Claims] 1. A sterilizing/deodorizing agent obtained by impregnating microporous beads with a stabilized chlorine dioxide aqueous solution. 2. The sterilizing/deodorizing agent according to claim 1, wherein the microporous beads are SiO_2-based microporous beads. 3. The sterilizing/deodorizing agent according to claim 1, which is used by filling a bag made of nonwoven fabric or paper and/or a bag made of aluminum sheet laminated with a heat-sealable film.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP62134008A JPH0675589B2 (en) | 1987-05-29 | 1987-05-29 | Sterilizer / deodorant |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP62134008A JPH0675589B2 (en) | 1987-05-29 | 1987-05-29 | Sterilizer / deodorant |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS63296758A true JPS63296758A (en) | 1988-12-02 |
| JPH0675589B2 JPH0675589B2 (en) | 1994-09-28 |
Family
ID=15118223
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP62134008A Expired - Lifetime JPH0675589B2 (en) | 1987-05-29 | 1987-05-29 | Sterilizer / deodorant |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0675589B2 (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2002501872A (en) * | 1998-02-09 | 2002-01-22 | サウスウエスト・リサーチ・インスティチュート | Silicate containing powder |
| JP2006204445A (en) * | 2005-01-26 | 2006-08-10 | Soft99 Corporation | Deodorizing method |
| US8480852B2 (en) | 2009-11-20 | 2013-07-09 | Kimberly-Clark Worldwide, Inc. | Cooling substrates with hydrophilic containment layer and method of making |
| US8795717B2 (en) | 2009-11-20 | 2014-08-05 | Kimberly-Clark Worldwide, Inc. | Tissue products including a temperature change composition containing phase change components within a non-interfering molecular scaffold |
| US9181465B2 (en) | 2009-11-20 | 2015-11-10 | Kimberly-Clark Worldwide, Inc. | Temperature change compositions and tissue products providing a cooling sensation |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS57198775A (en) * | 1981-06-01 | 1982-12-06 | Nasa:Kk | Molding material having deodorizing function, etc. |
| JPS5878518A (en) * | 1981-09-28 | 1983-05-12 | ザ・クロロツクス・コンパニ− | Animal litter material |
-
1987
- 1987-05-29 JP JP62134008A patent/JPH0675589B2/en not_active Expired - Lifetime
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS57198775A (en) * | 1981-06-01 | 1982-12-06 | Nasa:Kk | Molding material having deodorizing function, etc. |
| JPS5878518A (en) * | 1981-09-28 | 1983-05-12 | ザ・クロロツクス・コンパニ− | Animal litter material |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2002501872A (en) * | 1998-02-09 | 2002-01-22 | サウスウエスト・リサーチ・インスティチュート | Silicate containing powder |
| JP2006204445A (en) * | 2005-01-26 | 2006-08-10 | Soft99 Corporation | Deodorizing method |
| US8480852B2 (en) | 2009-11-20 | 2013-07-09 | Kimberly-Clark Worldwide, Inc. | Cooling substrates with hydrophilic containment layer and method of making |
| US8795717B2 (en) | 2009-11-20 | 2014-08-05 | Kimberly-Clark Worldwide, Inc. | Tissue products including a temperature change composition containing phase change components within a non-interfering molecular scaffold |
| US8894814B2 (en) | 2009-11-20 | 2014-11-25 | Kimberly-Clark Worldwide, Inc. | Cooling substrates with hydrophilic containment layer and method of making |
| US9181465B2 (en) | 2009-11-20 | 2015-11-10 | Kimberly-Clark Worldwide, Inc. | Temperature change compositions and tissue products providing a cooling sensation |
| US9545365B2 (en) | 2009-11-20 | 2017-01-17 | Kimberly-Clark Worldwide, Inc. | Temperature change compositions and tissue products providing a cooling sensation |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0675589B2 (en) | 1994-09-28 |
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