JPS63293322A - Surface treatment method for bearing - Google Patents
Surface treatment method for bearingInfo
- Publication number
- JPS63293322A JPS63293322A JP12640687A JP12640687A JPS63293322A JP S63293322 A JPS63293322 A JP S63293322A JP 12640687 A JP12640687 A JP 12640687A JP 12640687 A JP12640687 A JP 12640687A JP S63293322 A JPS63293322 A JP S63293322A
- Authority
- JP
- Japan
- Prior art keywords
- organic
- compound
- oil
- surface treatment
- molybdenum
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000004381 surface treatment Methods 0.000 title claims abstract description 8
- 238000000034 method Methods 0.000 title claims description 11
- 239000005078 molybdenum compound Substances 0.000 claims abstract description 10
- 150000002752 molybdenum compounds Chemical class 0.000 claims abstract description 10
- 239000003921 oil Substances 0.000 claims abstract description 10
- 239000002480 mineral oil Substances 0.000 claims abstract description 9
- 235000010446 mineral oil Nutrition 0.000 claims abstract description 9
- 150000003752 zinc compounds Chemical class 0.000 claims abstract description 8
- 239000004215 Carbon black (E152) Substances 0.000 claims abstract description 7
- 229930195733 hydrocarbon Natural products 0.000 claims abstract description 7
- 150000002430 hydrocarbons Chemical class 0.000 claims abstract description 7
- 239000003963 antioxidant agent Substances 0.000 claims description 9
- 150000001412 amines Chemical class 0.000 claims description 7
- 239000011259 mixed solution Substances 0.000 claims description 6
- 230000003078 antioxidant effect Effects 0.000 claims description 4
- 238000007654 immersion Methods 0.000 claims description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 abstract description 7
- 239000011701 zinc Substances 0.000 abstract description 7
- 229910052725 zinc Inorganic materials 0.000 abstract description 7
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 abstract description 4
- 229910052750 molybdenum Inorganic materials 0.000 abstract description 4
- 239000011733 molybdenum Substances 0.000 abstract description 4
- 239000000203 mixture Substances 0.000 abstract description 3
- 238000002791 soaking Methods 0.000 abstract 2
- 239000003795 chemical substances by application Substances 0.000 abstract 1
- 239000012528 membrane Substances 0.000 abstract 1
- 238000004544 sputter deposition Methods 0.000 description 6
- 239000007788 liquid Substances 0.000 description 5
- 230000000052 comparative effect Effects 0.000 description 4
- 150000001875 compounds Chemical class 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 229920002545 silicone oil Polymers 0.000 description 4
- 125000000217 alkyl group Chemical group 0.000 description 3
- 238000000576 coating method Methods 0.000 description 3
- 230000001050 lubricating effect Effects 0.000 description 3
- 238000005259 measurement Methods 0.000 description 3
- CWQXQMHSOZUFJS-UHFFFAOYSA-N molybdenum disulfide Chemical compound S=[Mo]=S CWQXQMHSOZUFJS-UHFFFAOYSA-N 0.000 description 3
- 229910052982 molybdenum disulfide Inorganic materials 0.000 description 3
- 238000005096 rolling process Methods 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- 150000004982 aromatic amines Chemical class 0.000 description 2
- 125000003118 aryl group Chemical group 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000000314 lubricant Substances 0.000 description 2
- 239000010723 turbine oil Substances 0.000 description 2
- 238000007740 vapor deposition Methods 0.000 description 2
- ZRMMVODKVLXCBB-UHFFFAOYSA-N 1-n-cyclohexyl-4-n-phenylbenzene-1,4-diamine Chemical compound C1CCCCC1NC(C=C1)=CC=C1NC1=CC=CC=C1 ZRMMVODKVLXCBB-UHFFFAOYSA-N 0.000 description 1
- RUFPHBVGCFYCNW-UHFFFAOYSA-N 1-naphthylamine Chemical compound C1=CC=C2C(N)=CC=CC2=C1 RUFPHBVGCFYCNW-UHFFFAOYSA-N 0.000 description 1
- UXKQNCDDHDBAPD-UHFFFAOYSA-N 4-n,4-n-diphenylbenzene-1,4-diamine Chemical compound C1=CC(N)=CC=C1N(C=1C=CC=CC=1)C1=CC=CC=C1 UXKQNCDDHDBAPD-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 239000005069 Extreme pressure additive Substances 0.000 description 1
- XQVWYOYUZDUNRW-UHFFFAOYSA-N N-Phenyl-1-naphthylamine Chemical compound C=1C=CC2=CC=CC=C2C=1NC1=CC=CC=C1 XQVWYOYUZDUNRW-UHFFFAOYSA-N 0.000 description 1
- QAPVYZRWKDXNDK-UHFFFAOYSA-N P,P-Dioctyldiphenylamine Chemical compound C1=CC(CCCCCCCC)=CC=C1NC1=CC=C(CCCCCCCC)C=C1 QAPVYZRWKDXNDK-UHFFFAOYSA-N 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 235000010290 biphenyl Nutrition 0.000 description 1
- 239000004305 biphenyl Substances 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- DMBHHRLKUKUOEG-UHFFFAOYSA-N diphenylamine Chemical class C=1C=CC=CC=1NC1=CC=CC=C1 DMBHHRLKUKUOEG-UHFFFAOYSA-N 0.000 description 1
- 238000002845 discoloration Methods 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 239000004519 grease Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000010687 lubricating oil Substances 0.000 description 1
- 238000005461 lubrication Methods 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- ZUOUZKKEUPVFJK-UHFFFAOYSA-N phenylbenzene Natural products C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 description 1
- 229920013639 polyalphaolefin Polymers 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
Landscapes
- Lubricants (AREA)
- Rolling Contact Bearings (AREA)
Abstract
Description
【発明の詳細な説明】 〔産業上の利用分野〕 この発明は軸受の表面処理方法に関するものである。[Detailed description of the invention] [Industrial application field] This invention relates to a bearing surface treatment method.
高温または裔真空度の条件下で使用されるすべり軸受、
転がり軸受および軌道輪、転動体（ボール）、保持器等
の軸受部品（以下これを一括して軸受と略記する）の潤
滑性付与のための表面処理には、液体もしくは半固体状
の潤滑油もしくはグリースなどは使用できないので、二
硫化モリブデン、グラファイトなどの固体潤滑剤が用い
られている。そしてこれら固体潤滑剤は塗布もしくは蒸
着（イオンブレーティング、スパッタリング）などの方
法によって皮膜に加工されるが、近年は薄くて均質な膜
が得られ、また付着力が大きいという理由から塗布法よ
りもスパッタリング法の方が特に愛用されている。しか
し、このようなスパッタリング法にも、球状物の処理が
困難であったり、高価な真空設備を必要とするなどの欠
点がある。Plain bearings used under high temperature or low vacuum conditions,
Liquid or semi-solid lubricating oil is used for surface treatment to impart lubricity to rolling bearings and bearing parts such as bearing rings, rolling elements (balls), and cages (hereinafter referred to collectively as bearings). Alternatively, since grease cannot be used, solid lubricants such as molybdenum disulfide and graphite are used. These solid lubricants are processed into a film by methods such as coating or vapor deposition (ion blating, sputtering), but in recent years, coating methods have become more effective because they produce thin, homogeneous films and have greater adhesion. The sputtering method is particularly popular. However, such sputtering methods also have drawbacks, such as difficulty in processing spherical objects and the need for expensive vacuum equipment.
このように、従来の技術においては、軸受特に球状のも
のに対しても、薄くて均質で付着力も大きい潤滑性皮膜
を、しかも安価に形成することは容易でないという問題
点があった。As described above, the conventional technology has a problem in that it is not easy to form a thin, homogeneous, and highly adhesive lubricating film on bearings, especially on spherical bearings, and at a low cost.
上記の問題点を解決するために、この発明は有機モリブ
デン化合物０．３〜３．０重量％、有機亜鉛化合物０．
１〜１．０重量％さらにアミン系酸化防止剤を加えるか
または加えずして、鉱油もしくは合成炭化水素油残部か
らなりかつ１７０″Ｃ〜２２０℃に加熱された混合溶液
に浸漬して軸受の表面処理を行なうという手段を採用し
たものである。以下その詳細を述べる。In order to solve the above problems, this invention contains 0.3 to 3.0% by weight of an organic molybdenum compound and 0.3 to 3.0% by weight of an organic zinc compound.
1 to 1.0% by weight, with or without the addition of further amine antioxidants, by immersing the bearing in a mixed solution consisting of mineral oil or the balance of synthetic hydrocarbon oil and heated to 170"C to 220C. This method employs a method of surface treatment.The details will be described below.
まず、この発明における有機モリブデン化合物としては
、１式で示されるモリブデンジアルキルジチオカーバメ
イトまたはモリブデンジアリールジチオカーバメイトの
ほか、■式で示されるモリブデンジアルキルジチオフォ
スフェートまたはモリブデンジアリールジチオフオスフ
ヱート、すなわち
〔式中Ｘは０またはＳ〕
〔式中Ｒは一級または二級のアルキル基またはアリール
基〕
で示される化合物を挙げることができる。このような有
機モリブデン化合物はそれぞれ単独または２種類以上を
混合したものであってもよい、そして、これら有機モリ
ブデン化合物の添加量を０．３〜３．０重量％とする理
由は０．３重量％未満の少量では期待する効果が現れに
くく、また３、０重量％を越える多量では皮膜が必要以
上に厚くなって剥離しやすくなったり経済的な不利を招
いたりして好ましくないからである。[ In the formula, X is 0 or S] [In the formula, R is a primary or secondary alkyl group or an aryl group] Compounds represented by the following can be mentioned. These organic molybdenum compounds may be used alone or in combination of two or more types, and the reason why the amount of these organic molybdenum compounds added is 0.3 to 3.0% by weight is 0.3% by weight. This is because if the amount is less than 3.0% by weight, it is difficult to achieve the desired effect, and if the amount is more than 3.0% by weight, the film becomes thicker than necessary, making it easy to peel off or causing economic disadvantage, which is undesirable.
つぎに、この発明における有機亜鉛化合物としては、ジ
ンクジアルキルジチオフォスフェートまたはジンクジア
リールジチオフォスフェート、すなわち、
〔式中Ｒ′は一級または二級のアルキル基またはアリー
ル基〕
で示される化合物を挙げることができる。そしてこのよ
うな有機亜鉛化合物はそれぞれ単独または２種類以上の
混合物であってもよく、いずれにしても前記の有機モリ
ブデン化合物とともにきわめて有効な極圧添加剤である
が、添加量は多過ぎても効果は同じかまたは悪くなるた
め、０．１〜１．０重量％であることが好ましい。Next, examples of the organozinc compound in the present invention include zinc dialkyldithiophosphate or zinc diaryldithiophosphate, that is, a compound represented by [wherein R' is a primary or secondary alkyl group or aryl group] Can be done. These organozinc compounds may be used alone or in a mixture of two or more, and in any case, together with the organomolybdenum compounds mentioned above, they are extremely effective extreme pressure additives, but if the amount added is too large, Since the effect is the same or worse, it is preferably 0.1 to 1.0% by weight.
さらに、この発明におけるアミン系酸化防止剤は、たと
えばフェニルαナフチルアミン、４．４′−ジオクチル
ジフェニルアミン、アルキル化ジフェニルアミン、Ｎ、
Ｎ’−ジフェニル−ｐ−フェニレンジアミン、Ｎ−フェ
ニル−Ｎ′−シクロヘキシル−Ｐ−フェニレンジアミン
などの芳香族系アミンが望ましい、なぜならば、芳香族
アミン系酸化防止剤はほかの酸化防止剤たとえばアルキ
ルアミンなどに比べて、熱的に安定性がある点で好まし
いからである。そしてこのようなアミン系酸化防止剤の
添加量は１．０重量％以下であることが望ましい、なぜ
ならば１．０重量％を越える多量では添加剤の析出など
が起こる場合もあって好ましくないからである。Furthermore, the amine antioxidants in this invention include, for example, phenyl α-naphthylamine, 4,4'-dioctyl diphenylamine, alkylated diphenylamine, N,
Aromatic amines such as N'-diphenyl-p-phenylenediamine and N-phenyl-N'-cyclohexyl-P-phenylenediamine are preferred, since aromatic amine antioxidants may be used in combination with other antioxidants such as alkyl This is because it is preferable in terms of thermal stability compared to amines and the like. It is desirable that the amount of such amine antioxidants added is 1.0% by weight or less, because if the amount exceeds 1.0% by weight, precipitation of the additive may occur, which is not desirable. It is.
また、この発明における鉱油もしくは合成炭化水素油は
後述する混合溶液の加熱温度１７０〜２２０℃よりも高
い沸点のものであることが望ましく、たとえばポリαオ
レフィン油などを例示することができる。なお、ジメチ
ルシリコーン油、ジメチルジフェニルシリコーン油など
のシリコーン油は均一な皮膜の形成が困難であるから好
ましくない。Further, the mineral oil or synthetic hydrocarbon oil in this invention preferably has a boiling point higher than the heating temperature of the mixed solution (170 to 220°C, which will be described later), and examples include poly-α-olefin oil. Note that silicone oils such as dimethyl silicone oil and dimethyl diphenyl silicone oil are not preferred because it is difficult to form a uniform film.
以上の有機モリブデン化合物、有機亜鉛化合物、さらに
必要に応じてアミン系酸化防止剤、を鉱油もしくは合成
炭化水素油に溶解する方法は特に限定するものではない
が、得られた混合溶液に被処理物の軸受を浸漬する。好
ましい浸漬温度を１７０〜２２０℃とする理由は第１回
に示したように、１７０℃未満の低温では皮膜の形成が
悪く、１７０℃付近で急激に良くなり、また２２０℃を
越える高温では次第に低下して、温度を上昇させてもそ
の効果がないからである。また、浸漬時間は特に限定さ
れるものではないが、−Ｓに潤滑性皮膜の場合、０．５
〜０．８μ厚の皮膜が広く採用されることから、第２図
に示す結果からすれば２時間以上を一つの目安とすれば
よい、なお、この発明の方法を行なうには、たとえば被
処理物を入れた編製の回転ドラムを混合液内で回転させ
れぽよく、このようにすれば被処理物の表面を満遍なく
処理することが出来て、皮膜の厚さは均一になる。The method of dissolving the above-mentioned organic molybdenum compound, organic zinc compound, and optionally an amine antioxidant in mineral oil or synthetic hydrocarbon oil is not particularly limited, but the method of dissolving the above-mentioned organic molybdenum compound, organic zinc compound, and optionally an amine antioxidant in mineral oil or synthetic hydrocarbon oil is not particularly limited. Immerse the bearings in the The reason why the preferred immersion temperature is 170 to 220°C is as shown in Part 1. At low temperatures below 170°C, film formation is poor, and at temperatures around 170°C, it rapidly improves, and at high temperatures above 220°C, it gradually deteriorates. This is because even if the temperature is lowered and the temperature is raised, there is no effect. In addition, the immersion time is not particularly limited, but in the case of a lubricating film on -S, 0.5
Since films with a thickness of ~0.8 μm are widely adopted, from the results shown in Figure 2, it is sufficient to use a time period of 2 hours or more as a guide. A knitted rotary drum filled with objects may be rotated within the mixed solution, and in this way the surface of the object to be treated can be evenly treated, resulting in a uniform coating thickness.
ここで、この発明で形成される皮膜はモリブデン、硫黄
、亜鉛などを含む複雑な組成、構造のものと推定される
。なお、鉱油、合成油などが支障を来たすときは皮膜を
溶剤で洗浄して使用すればよい。Here, the film formed by the present invention is presumed to have a complex composition and structure containing molybdenum, sulfur, zinc, etc. If mineral oil, synthetic oil, etc. cause trouble, the film can be cleaned with a solvent before use.
実施例１：
タービン油＃１４０にモリブデンジアルキルジチオフォ
スフェート〔旭電化工業社製：商品名すクラループ３０
０） ３重量％とジンクジアルキルジチオフォスフェー
ト〔日本ループリシール社製：商品名Ｌｕｂｒｉｚｏｌ
１０９５ ） １重量％とを混合して処理液を作製し
た。そしてこの溶液を２００±１℃に加熱して、これに
５ＵＪ２製の１／４”ボールを浸漬し３．５時間静置し
た。このような処理を施したボールの表面には膜厚０．
３−の均一な黒色皮膜が形成されていた。そしてこの皮
膜の潤滑性を調べるために、つぎのような回転摩擦トル
クを測定した。Example 1: Molybdenum dialkyl dithiophosphate was added to turbine oil #140 [manufactured by Asahi Denka Kogyo Co., Ltd., trade name: Kuralup 30]
0) 3% by weight and zinc dialkyldithiophosphate [manufactured by Nippon Lubrizil Co., Ltd.: trade name Lubrizol]
1095) and 1% by weight to prepare a treatment liquid. Then, this solution was heated to 200±1°C, and a 1/4" ball made of 5UJ2 was immersed in it and left to stand for 3.5 hours. The surface of the ball treated in this way had a film thickness of 0.
A uniform black film of 3- was formed. In order to examine the lubricity of this film, the following rotational friction torque was measured.
測定に使用した装置は第３図に示すように回転するレー
ス１に１６個の試験ボール２を乗せ、荷重３を塔載し、
２個の軸受４および４′で支えられた軸５に取り付けら
れた平板６で前記試験ボール２を押え、この状態でレー
ス１を一定の回転速度で回転させ、そのときの回転摩擦
トルクをトルクメータ７で読み取るようになっている。As shown in Fig. 3, the equipment used for the measurement was as follows: 16 test balls 2 were placed on a rotating race 1, and a load 3 was placed on the rotating race 1.
The test ball 2 is held down by a flat plate 6 attached to a shaft 5 supported by two bearings 4 and 4', and in this state, the race 1 is rotated at a constant rotational speed, and the rotational friction torque at that time is expressed as the torque. It is designed to be read by meter 7.
このような装置を用いて得た測定結果を第４図および第
５図に示した。なお第４図は真空度２ Ｘ １０− ”
ｔｏｒｒの比較的低真空下、荷重１．５ｋｇ ｆ 、
１６００ ｒｐｍの条件のもとのトルクの経時変化を
、また第５図は真空度６Ｘ１０−’と比較的高真空下で
荷重１．０ｋｇ ｒ 、５０００ｒｐ−としたときの回
転数とトルクとの関係を示したものであり、いずれも摩
擦トルク値は第３図の二つの軸受４および４′の分をも
含む合計値である。また、第４図には対照品として実施
例１の処理を施さない５ＩＩＪ２製の１／４″ボールを
用い、この結果をも記載したが、短時間でトルクは急上
昇し、本発明品は良好な潤滑性を示した。Measurement results obtained using such an apparatus are shown in FIGS. 4 and 5. In addition, Fig. 4 shows the degree of vacuum 2 x 10-''
Under relatively low vacuum of torr, load 1.5 kg f,
Figure 5 shows the change in torque over time under the condition of 1600 rpm, and Figure 5 shows the relationship between rotational speed and torque when the load is 1.0 kg r and 5000 rpm under a relatively high vacuum of 6 x 10-'. In both cases, the friction torque value is a total value including that of the two bearings 4 and 4' shown in FIG. In addition, Fig. 4 also shows the results using a 1/4'' ball made of 5IIJ2 which was not subjected to the treatment of Example 1 as a control product, but the torque increased rapidly in a short time, and the product of the present invention was good. It showed excellent lubricity.
実施例２：
実施例１における処理液に酸化防止剤としてフェニルα
ナフチルアミン１重量％を添加した以外は実施例１と全
く同様の操作をして、５ＵＪ２ボールの表面に皮膜を形
成した。得られた皮膜は、厚さ０．７５−の均一な黒色
皮膜で、実施例１における皮膜よりもかなり厚いものが
得られた。またこのボールに対する回転摩擦トルクはＱ
、５ｇ−ｃｍ以下であった。Example 2: Phenyl α was added as an antioxidant to the treatment liquid in Example 1.
A film was formed on the surface of a 5UJ2 ball by carrying out the same operation as in Example 1 except that 1% by weight of naphthylamine was added. The resulting film was a uniform black film with a thickness of 0.75 mm, which was considerably thicker than the film in Example 1. Also, the rotational friction torque for this ball is Q
, 5 g-cm or less.
比較例１：
実施例１における＃１４０タービン油の代りにジメチル
シリコーン油（信越化学工業社製： ＫＰ９６）を用い
た以外は実施例１と全く同一の操作を行なった。しかし
、ボール表面には皮膜が形成されず黒変しなかった。Comparative Example 1: The same operation as in Example 1 was performed except that dimethyl silicone oil (manufactured by Shin-Etsu Chemical Co., Ltd.: KP96) was used instead of the #140 turbine oil in Example 1. However, no film was formed on the ball surface and it did not turn black.
比較例２：
実施例１におけるジンクジアルキルジチオフォスフェー
トを用いないこと以外は実施例１と全く同様の操作を行
なった。しかし得られたボールの表面に部分的な変色は
認められたものの全表面に均一な皮膜は形成されなかっ
た。Comparative Example 2: The same operation as in Example 1 was performed except that the zinc dialkyl dithiophosphate in Example 1 was not used. However, although some discoloration was observed on the surface of the resulting ball, a uniform film was not formed over the entire surface.
比較例３： 。Comparative example 3:
従来用いられて来たスパッタリング法によって、実施例
１において用いたと同じ５ＩＩＪ２の１／４″ボ一ル表
面に、平均膜厚０．４−の二硫化モリブデンの黒色皮膜
を形成した。なお、スパッタリングの条件は４ Ｗ ／
ｃｄ、２時間（日型アネルバ社製：高周波スパッタリ
ング装置５ＴＦ−２１０使用）であって、得られたボー
ルについて、実施例１の場合と同様回転摩擦トルクを測
定した。測定結果を第４図に併記したが、第４図の低真
空度下においては本発明よりはやや劣る結果を示した。By a conventional sputtering method, a black film of molybdenum disulfide with an average thickness of 0.4 mm was formed on the surface of the same 5IIJ2 1/4'' bowl used in Example 1. The condition is 4 W/
cd for 2 hours (using high frequency sputtering device 5TF-210 manufactured by Nikkei Anelva Co., Ltd.), and the rotational friction torque of the obtained ball was measured in the same manner as in Example 1. The measurement results are also shown in FIG. 4, and under the low degree of vacuum shown in FIG. 4, the results were slightly inferior to those of the present invention.
また第５図に相当する高真空下においては、本発明品（
実施例１）の耐久寿命が５．１Ｘ１０’回転（１０２分
）であったのに対して、このスパッタリング法によるも
の（比較例３）の耐久寿命は９．３５ ＸＩＯ’回転（
１８７分）であった。In addition, under high vacuum corresponding to Fig. 5, the product of the present invention (
The durability life of Example 1) was 5.1X10' rotations (102 minutes), while the durability life of the sputtering method (Comparative Example 3) was 9.35 XIO' rotations (102 minutes).
187 minutes).
以上述べたように、この発明の軸受（すべり軸受、転が
り軸受およびこれら軸受の部品）の潤滑処理方法によれ
ば、たとえば蒸着装置のような特殊装置を必要とせず、
大量の処理が可能であり、潤滑処理費が安価であり、摩
擦係数が小さくて従来の二硫化モリブデンの蒸着皮膜と
少なくとも同程度のものを得ることが出来た。As described above, according to the method for lubricating bearings (sliding bearings, rolling bearings, and parts of these bearings) of the present invention, there is no need for special equipment such as a vapor deposition equipment,
It is possible to process a large amount, the lubrication treatment cost is low, and the coefficient of friction is small, making it possible to obtain a film that is at least comparable to the conventional vapor-deposited film of molybdenum disulfide.
第１図は混合溶液の液温と膜厚との関係を、また第２図
は液温１７５℃、２００℃における浸漬時間と膜厚との
関係を示す図、また第３図は回転摩擦トルク測定装置を
模式的に示す図、第４図は回転摩擦トルクの経時変化、
第５図は回転摩擦トルクの寿命（総回転数）を示す図で
ある。。
１・・・・・・レース、２・・・・・・試験ボール、３
・・・・・・荷重、４．４′・・・・・・軸受、５・・
・・・・軸、６・・・・・・平板、７・・・・・・トル
クメータ。Figure 1 shows the relationship between the liquid temperature of the mixed solution and film thickness, Figure 2 shows the relationship between immersion time and film thickness at liquid temperatures of 175°C and 200°C, and Figure 3 shows the rotational friction torque. A diagram schematically showing the measuring device, Figure 4 shows the change in rotational friction torque over time,
FIG. 5 is a diagram showing the life of rotational friction torque (total number of rotations). . 1... Race, 2... Test ball, 3
...Load, 4.4'...Bearing, 5...
... shaft, 6 ... flat plate, 7 ... torque meter.
Claims (2)
機亜鉛化合物０．１〜１．０重量％および鉱油もしくは
合成炭化水素油残部からなり、かつ１７０〜２２０℃に
加熱された混合溶液に浸漬することを特徴とする軸受の
表面処理方法。(1) A mixed solution consisting of 0.3 to 3.0% by weight of an organic molybdenum compound, 0.1 to 1.0% by weight of an organic zinc compound, and the balance of mineral oil or synthetic hydrocarbon oil, and heated to 170 to 220°C. A method for surface treatment of bearings, characterized by immersing them in water.
機亜鉛化合物０．１〜１．０重量％、アミン系酸化防止
剤および鉱油もしくは合成炭化水素油残部からなり、か
つ１７０〜２２０℃に加熱された混合溶液に浸漬するこ
とを特徴とする軸受の表面処理方法。(2) Consisting of 0.3 to 3.0% by weight of an organic molybdenum compound, 0.1 to 1.0% by weight of an organic zinc compound, an amine antioxidant, and the balance of mineral oil or synthetic hydrocarbon oil, and at a temperature of 170 to 220°C. A method for surface treatment of bearings, characterized by immersion in a mixed solution heated to .
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP12640687A JPH0823371B2 (en) | 1987-05-23 | 1987-05-23 | Bearing surface treatment method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP12640687A JPH0823371B2 (en) | 1987-05-23 | 1987-05-23 | Bearing surface treatment method |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS63293322A true JPS63293322A (en) | 1988-11-30 |
| JPH0823371B2 JPH0823371B2 (en) | 1996-03-06 |
Family
ID=14934367
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP12640687A Expired - Lifetime JPH0823371B2 (en) | 1987-05-23 | 1987-05-23 | Bearing surface treatment method |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0823371B2 (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2227031A (en) * | 1988-12-01 | 1990-07-18 | Nippon Seiko Kk | Surface treated sliding or rolling contact element and rolling bearing |
| JPH02256920A (en) * | 1988-12-01 | 1990-10-17 | Nippon Seiko Kk | Sliding or rolling members whereto surface treatment is performed and rolling bearing |
| US5252391A (en) * | 1988-12-01 | 1993-10-12 | Nippon Seiko Kabushiki Kaisha | Surface treated sliding or rolling contact element and rolling bearing |
| US6612746B2 (en) | 1996-07-30 | 2003-09-02 | Nsk Ltd. | Rolling apparatus having surface-treated rolling member |
-
1987
- 1987-05-23 JP JP12640687A patent/JPH0823371B2/en not_active Expired - Lifetime
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2227031A (en) * | 1988-12-01 | 1990-07-18 | Nippon Seiko Kk | Surface treated sliding or rolling contact element and rolling bearing |
| JPH02256920A (en) * | 1988-12-01 | 1990-10-17 | Nippon Seiko Kk | Sliding or rolling members whereto surface treatment is performed and rolling bearing |
| GB2227031B (en) * | 1988-12-01 | 1993-07-21 | Nippon Seiko Kk | Surface treated sliding or rolling contact element and rolling bearing |
| US5252391A (en) * | 1988-12-01 | 1993-10-12 | Nippon Seiko Kabushiki Kaisha | Surface treated sliding or rolling contact element and rolling bearing |
| US6612746B2 (en) | 1996-07-30 | 2003-09-02 | Nsk Ltd. | Rolling apparatus having surface-treated rolling member |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0823371B2 (en) | 1996-03-06 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN107312600A (en) | Graphene composite lube additive and preparation method thereof | |
| EP0322916B1 (en) | New lubricant greases | |
| CN103732729B (en) | EV, HEV drive bearing of motor lubricant composition and EV, HEV to drive bearing of motor | |
| TWI443188B (en) | Lubricant composition and lubricating system using the same | |
| JP2017036385A (en) | Grease composition and grease encapsulated rolling shaft bearing | |
| JP3512183B2 (en) | Grease for high-temperature, high-speed, high-load rolling bearings and grease-filled rolling bearing for high-temperature, high-speed, high-load rolling | |
| JP7434953B2 (en) | Grease compositions and rolling bearings | |
| JP2019060499A (en) | Friction piece operating in lubricated medium | |
| JP3727683B2 (en) | Extreme pressure grease lubricant composition for rolling bearing and preparation method thereof | |
| JPS63293322A (en) | Surface treatment method for bearing | |
| JP5756587B2 (en) | Grease composition for angular ball bearing and angular ball bearing using the same | |
| US10508249B2 (en) | Grease composition for rolling bearings and rolling bearing | |
| JPH0480079B2 (en) | ||
| CN111876218B (en) | Conductive bearing lubricating grease composition and preparation method thereof | |
| CN102748396B (en) | Rolling bearing | |
| EP1498472B1 (en) | Use of a Grease Composition in a Rolling Bearing | |
| JP4162326B2 (en) | Lubricant composition and rolling bearing using the same | |
| US3082170A (en) | Polyorgano siloxane thickened to a grease consistency with a diazo compound and an arylurea | |
| JPH02248496A (en) | Lubricating grease | |
| CN115867632A (en) | Grease composition and rolling bearing | |
| CN112143544A (en) | Grease composition and rolling bearing | |
| JP3997756B2 (en) | Rust-proof lubricating coating composition | |
| JP3763572B2 (en) | Grease for rolling bearings for high temperature, high speed rotation and high load and grease filled rolling bearings for high temperature, high speed rotation and high load | |
| JP5351557B2 (en) | Rolling bearing | |
| CN106221878B (en) | Chemical material and preparation method thereof for chain greasisng antirust |