JPS63284113A - Hair treatment - Google Patents
Hair treatmentInfo
- Publication number
- JPS63284113A JPS63284113A JP11934387A JP11934387A JPS63284113A JP S63284113 A JPS63284113 A JP S63284113A JP 11934387 A JP11934387 A JP 11934387A JP 11934387 A JP11934387 A JP 11934387A JP S63284113 A JPS63284113 A JP S63284113A
- Authority
- JP
- Japan
- Prior art keywords
- hair
- hair treatment
- weight
- alcohol
- stearyl alcohol
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000011282 treatment Methods 0.000 title abstract description 20
- GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 claims abstract description 28
- NOPFSRXAKWQILS-UHFFFAOYSA-N docosan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCCCCCO NOPFSRXAKWQILS-UHFFFAOYSA-N 0.000 claims abstract description 26
- GOQYKNQRPGWPLP-UHFFFAOYSA-N n-heptadecyl alcohol Natural products CCCCCCCCCCCCCCCCCO GOQYKNQRPGWPLP-UHFFFAOYSA-N 0.000 claims abstract description 14
- 229960000735 docosanol Drugs 0.000 claims abstract description 13
- 229920001184 polypeptide Polymers 0.000 claims abstract description 10
- 102000004196 processed proteins & peptides Human genes 0.000 claims abstract description 10
- 108090000765 processed proteins & peptides Proteins 0.000 claims abstract description 10
- 125000000217 alkyl group Chemical group 0.000 claims abstract description 8
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 claims abstract description 4
- 125000005843 halogen group Chemical group 0.000 claims abstract description 4
- 150000003242 quaternary ammonium salts Chemical class 0.000 claims abstract description 3
- 238000002156 mixing Methods 0.000 claims description 8
- 125000004432 carbon atom Chemical group C* 0.000 claims description 5
- 239000000126 substance Substances 0.000 claims description 3
- 239000002932 luster Substances 0.000 abstract description 15
- 230000000694 effects Effects 0.000 abstract description 13
- 125000002091 cationic group Chemical group 0.000 abstract 1
- 239000013078 crystal Substances 0.000 abstract 1
- 229910052736 halogen Inorganic materials 0.000 abstract 1
- 239000004094 surface-active agent Substances 0.000 abstract 1
- 239000003795 chemical substances by application Substances 0.000 description 15
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 12
- 239000000203 mixture Substances 0.000 description 9
- 238000003860 storage Methods 0.000 description 7
- 230000000052 comparative effect Effects 0.000 description 6
- 235000014113 dietary fatty acids Nutrition 0.000 description 6
- 239000000194 fatty acid Substances 0.000 description 6
- 229930195729 fatty acid Natural products 0.000 description 6
- -1 fatty acid esters Chemical class 0.000 description 5
- BXWNKGSJHAJOGX-UHFFFAOYSA-N hexadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCO BXWNKGSJHAJOGX-UHFFFAOYSA-N 0.000 description 4
- 239000004615 ingredient Substances 0.000 description 4
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- 239000003093 cationic surfactant Substances 0.000 description 3
- 239000011521 glass Substances 0.000 description 3
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- 230000002776 aggregation Effects 0.000 description 2
- 239000001913 cellulose Substances 0.000 description 2
- 229920002678 cellulose Polymers 0.000 description 2
- 229960000541 cetyl alcohol Drugs 0.000 description 2
- 230000008034 disappearance Effects 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- 150000004665 fatty acids Chemical class 0.000 description 2
- 238000005191 phase separation Methods 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- PRAKJMSDJKAYCZ-UHFFFAOYSA-N squalane Chemical compound CC(C)CCCC(C)CCCC(C)CCCCC(C)CCCC(C)CCCC(C)C PRAKJMSDJKAYCZ-UHFFFAOYSA-N 0.000 description 2
- HIQIXEFWDLTDED-UHFFFAOYSA-N 4-hydroxy-1-piperidin-4-ylpyrrolidin-2-one Chemical compound O=C1CC(O)CN1C1CCNCC1 HIQIXEFWDLTDED-UHFFFAOYSA-N 0.000 description 1
- 102000008186 Collagen Human genes 0.000 description 1
- 108010035532 Collagen Proteins 0.000 description 1
- 235000017788 Cydonia oblonga Nutrition 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 239000004354 Hydroxyethyl cellulose Substances 0.000 description 1
- 229920001479 Hydroxyethyl methyl cellulose Polymers 0.000 description 1
- 239000004264 Petrolatum Substances 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- 229920001214 Polysorbate 60 Polymers 0.000 description 1
- VBIIFPGSPJYLRR-UHFFFAOYSA-M Stearyltrimethylammonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCC[N+](C)(C)C VBIIFPGSPJYLRR-UHFFFAOYSA-M 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 238000005054 agglomeration Methods 0.000 description 1
- 238000004220 aggregation Methods 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 125000003277 amino group Chemical group 0.000 description 1
- 235000021302 avocado oil Nutrition 0.000 description 1
- 239000008163 avocado oil Substances 0.000 description 1
- 239000003899 bactericide agent Substances 0.000 description 1
- YSJGOMATDFSEED-UHFFFAOYSA-M behentrimonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCCCCCC[N+](C)(C)C YSJGOMATDFSEED-UHFFFAOYSA-M 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 239000002738 chelating agent Substances 0.000 description 1
- 229920001436 collagen Polymers 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 230000003766 combability Effects 0.000 description 1
- 239000002178 crystalline material Substances 0.000 description 1
- REZZEXDLIUJMMS-UHFFFAOYSA-M dimethyldioctadecylammonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCC[N+](C)(C)CCCCCCCCCCCCCCCCCC REZZEXDLIUJMMS-UHFFFAOYSA-M 0.000 description 1
- 239000004664 distearyldimethylammonium chloride (DHTDMAC) Substances 0.000 description 1
- 239000010696 ester oil Substances 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 239000011888 foil Substances 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- QMGPXBPMUADRMC-UHFFFAOYSA-M heptyl(trimethyl)azanium;chloride Chemical compound [Cl-].CCCCCCC[N+](C)(C)C QMGPXBPMUADRMC-UHFFFAOYSA-M 0.000 description 1
- 239000003906 humectant Substances 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 1
- XUGNVMKQXJXZCD-UHFFFAOYSA-N isopropyl palmitate Chemical compound CCCCCCCCCCCCCCCC(=O)OC(C)C XUGNVMKQXJXZCD-UHFFFAOYSA-N 0.000 description 1
- 229940057995 liquid paraffin Drugs 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 229920000609 methyl cellulose Polymers 0.000 description 1
- 239000001923 methylcellulose Substances 0.000 description 1
- 235000010981 methylcellulose Nutrition 0.000 description 1
- 239000010445 mica Substances 0.000 description 1
- 229910052618 mica group Inorganic materials 0.000 description 1
- JXTPJDDICSTXJX-UHFFFAOYSA-N n-Triacontane Natural products CCCCCCCCCCCCCCCCCCCCCCCCCCCCCC JXTPJDDICSTXJX-UHFFFAOYSA-N 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 235000019198 oils Nutrition 0.000 description 1
- 235000008390 olive oil Nutrition 0.000 description 1
- 239000004006 olive oil Substances 0.000 description 1
- 229940066842 petrolatum Drugs 0.000 description 1
- 235000019271 petrolatum Nutrition 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 239000003531 protein hydrolysate Substances 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 239000002453 shampoo Substances 0.000 description 1
- 150000004756 silanes Chemical class 0.000 description 1
- 229940032094 squalane Drugs 0.000 description 1
- SFVFIFLLYFPGHH-UHFFFAOYSA-M stearalkonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCC[N+](C)(C)CC1=CC=CC=C1 SFVFIFLLYFPGHH-UHFFFAOYSA-M 0.000 description 1
- 229940012831 stearyl alcohol Drugs 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 235000015112 vegetable and seed oil Nutrition 0.000 description 1
- 239000008158 vegetable oil Substances 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/64—Proteins; Peptides; Derivatives or degradation products thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/34—Alcohols
- A61K8/342—Alcohols having more than seven atoms in an unbroken chain
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/41—Amines
- A61K8/416—Quaternary ammonium compounds
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/12—Preparations containing hair conditioners
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Emergency Medicine (AREA)
- Dermatology (AREA)
- Cosmetics (AREA)
Abstract
Description
【発明の詳細な説明】
（技術分野）
本発明は、ヘアーリンス、ヘアートリートメントなどの
毛髪処理剤に関し、更に詳細には、カチオン性界面活性
剤、ポリペプチド、ステアリルアルコール、ベヘニルア
ルコールによりパール状結晶を生成させ、外観が美麗で
あり、保存安定性に優れると共に壁仕上効果の優れた毛
髪処理剤に関する。Detailed Description of the Invention (Technical Field) The present invention relates to hair treatment agents such as hair rinses and hair treatments, and more specifically, the present invention relates to hair treatment agents such as hair rinses and hair treatments. This invention relates to a hair treatment agent that has a beautiful appearance, excellent storage stability, and an excellent wall finishing effect.
（従来技術）
シャンプー、リンス、ローシラン等の商品価値を高める
目的で、外観をパール状にすることが行なわれている。(Prior Art) For the purpose of increasing the commercial value of shampoos, conditioners, low silanes, etc., it has been carried out to make the appearance pearl-like.
いわゆるパール光沢剤としては古くから魚鱗箔。Fish scale foil has been used as a so-called pearlescent agent since ancient times.
雲母または高級脂肪酸もしくはその塩、エチレングリコ
ール高級脂肪酸エステル等の結晶物が用いられている。Crystalline materials such as mica, higher fatty acids or salts thereof, and ethylene glycol higher fatty acid esters are used.
これらのうち、近年量も汎用されているパール光沢剤は
、例えば特開昭５７−１５６４０９号等の公報に記載さ
れているごとく、エチレングリコ−ル等の多価アルコー
ルと高級脂肪酸とのエステル類の結晶物である。しかし
、これらはエチレングリコール高級脂肪酸エステル類を
予めパール剤として調製して、組成物中に配合するなど
複雑な工程を必要とし、また美麗なパール光沢を付与す
るために毛髪□用の組成物中に多量に配合すると、後記
の髪仕上効果（髪のしっとり感、髪のなめらかさ、くシ
通り性）が悪化するという欠点を有していた。Among these, pearl luster agents, which have been widely used in recent years, are esters of polyhydric alcohols such as ethylene glycol and higher fatty acids, as described in JP-A-57-156409 and other publications. It is a crystalline substance. However, these require complicated processes such as preparing ethylene glycol higher fatty acid esters as a pearl agent in advance and incorporating it into the composition, and in order to impart a beautiful pearlescent luster to the hair composition. If a large amount is added to the hair, it has the disadvantage that the hair finishing effect (moist feeling of hair, smoothness of hair, combability) described below deteriorates.
（発明の開示）
このような状況において、本発明者は外観が美麗で、保
存安定性に優れたパール光沢を付与すると共に、髪仕上
効果の優れたヘアーリンス、ヘアートリートメント等の
毛髪処理剤を得る目的で鋭意研究を重ねた結果、後記特
定のカチオン性界面活性剤とポリペプチドと、ステアリ
ルアルコール及びベヘニルアルコールを必須成分として
含有してなる毛髪処理剤は、上記目的を達成し得ること
を見出し、本発明を完成した。(Disclosure of the Invention) Under these circumstances, the present inventor has developed a hair treatment agent such as a hair rinse or hair treatment that has a beautiful appearance, has a pearlescent luster with excellent storage stability, and has an excellent hair finishing effect. As a result of intensive research for the purpose of obtaining the above-mentioned results, it was discovered that a hair treatment agent containing a specific cationic surfactant and polypeptide described below, as well as stearyl alcohol and behenyl alcohol as essential components, can achieve the above-mentioned purpose. The invention has been completed.
（発明の目的）
即ち、本発明の目的は、バール光沢性、保存安定性、髪
仕上効果に優れた毛髪処理剤を提供することにある。(Objective of the Invention) That is, an object of the present invention is to provide a hair treatment agent having excellent burl gloss, storage stability, and hair finishing effect.
（発明の構成）
本発明は
囚 一般式
〔式中、Ｒ、Ｒｘ−Ｒｓ及びＲ４の１〜２個は炭素数１
２〜２４の長鎖アルキル基を示し、残余は炭素数１〜３
のアルキル基、ベンジル基を示し、Ｘはハロゲン原子を
示す、〕
で表わされる第４級アンモニウム塩の少なくとも一種０
．１〜１０重量％、８平均分子！２００〜ｓ、ｏｏｏの
ポリペプチド１．０〜１２重量％０ステアリルアルコー
ル０．１〜１０重量％。(Structure of the Invention) The present invention is based on the general formula [wherein 1 to 2 of R, Rx-Rs and R4 have 1 or
Indicates a long chain alkyl group with 2 to 24 carbon atoms, and the remainder has 1 to 3 carbon atoms.
represents an alkyl group or a benzyl group, and X represents a halogen atom.] At least one quaternary ammonium salt represented by 0
．． 1-10% by weight, 8 average molecules! 200-s, ooo polypeptide 1.0-12% by weight 0 stearyl alcohol 0.1-10% by weight.
０ベヘニルアルコール０．１５〜１５重１％を含有して
なり、かつステアリルアルコールとベヘニルアルコール
の配合重量比は１：１．５〜１：４．５である毛髪処理
剤である。The hair treatment agent contains 0.15 to 15% by weight of 0.0 behenyl alcohol, and the weight ratio of stearyl alcohol to behenyl alcohol is 1:1.5 to 1:4.5.
（構成の具体的な説明）
本発明の＾成分であるカチオン性界面活性剤は、次の一
般式
〔式中、Ｒｌ＋ Ｒｓｒ Ｒ３＋及びＲ４の１〜．１個
は炭素数１２〜２４の長鎖アルキル基を示し、残余は炭
素数１〜３のアルキル基、ベンジル基を示し、Ｘはハロ
ゲン原子を示す、〕
で表わされる第４級アンモニウム塩の少なくとも一種が
適用され、通常のへアーリンス荊等に配合され得るすべ
てのものが使用される０例えば、ジステアリルジメチル
アンモニウムクロライド、ステアリルトリメチルアンモ
ニウムクロライド、ステアリルジメチルベンジルアンモ
ニウムクロライド、七チルトリメチルアンモニウムクロ
ライド。(Specific description of structure) The cationic surfactant which is the ^ component of the present invention has the following general formula [wherein Rl+ Rsr R3+ and R4 1 to . One represents a long-chain alkyl group with 12 to 24 carbon atoms, the rest represent an alkyl group with 1 to 3 carbon atoms or a benzyl group, and X represents a halogen atom. One type is applicable, and all those that can be blended into ordinary hair rinses etc. are used. For example, distearyldimethylammonium chloride, stearyltrimethylammonium chloride, stearyldimethylbenzylammonium chloride, heptyltrimethylammonium chloride.
ベヘニルトリメチルアンモニウムクロライドなどが挙げ
られる。Examples include behenyltrimethylammonium chloride.
本発明の毛髪処理剤には、これらの囚成分の少なくとも
一種を総量を基準として０．１〜１０重量％（以下ｗｔ
％と略記する）好ましくは、０．５〜５ｗｔ％配合され
る。また、配合量がＱ、ｌ ｖｒ ｔ％未満では髪仕上
効果に良好な結果が得られず、ｌ Ｑｖｒｔ％を超える
と毛髪にべたつきが生し好ましくない。The hair treatment agent of the present invention contains at least one of these components in an amount of 0.1 to 10% by weight (hereinafter wt.%) based on the total amount.
(abbreviated as %) is preferably blended in an amount of 0.5 to 5 wt%. Further, if the amount is less than Q, lvrt%, good results will not be obtained for the hair finishing effect, and if it exceeds lqvrt%, the hair will become sticky, which is undesirable.
本発明の日成分であるポリペプチドは、公知の物質であ
って、下記一般式で表わされるようにアミノ基とカルボ
キシル基を併せもつ物質で本質的にはその製造の由来を
問うものではないが実用的には、通常のコラーゲン蛋白
質の加水分解物が適用される。The polypeptide that is the ingredient of the present invention is a known substance that has both an amino group and a carboxyl group as represented by the general formula below, and the origin of its production is not essentially questioned. Practically, a conventional collagen protein hydrolyzate is applied.
ＮＨ＊ （ＣＨＣＯＮＨ）−ＣＨＣＯ○■（（ただ
しＲはアルキル基を示す）
また、ポリペプチドの平均分子！（ゲル口過測定）は、
２００〜５０００であり好ましくは、４００〜３０００
である。平均分子量が２００未満あるいは５０００を超
えては良好なパール光沢及び壁仕上効果が得られない、
また、ポリペプチドの含有量は１．０〜ｌ ２ｗｔ％、
好ましくは２．０〜１０ｗｔ％である。また配合量が１
ｗｔ％未満あるいはｌ２ｗｔ％を超えては良好なパール
光沢が得られず、後記の保存安定性が劣る。NH* (CHCONH)-CHCO○■ ((where R represents an alkyl group) Also, the average molecule of a polypeptide! (gel sip measurement) is
200-5000, preferably 400-3000
It is. If the average molecular weight is less than 200 or more than 5000, good pearlescent luster and wall finishing effects cannot be obtained.
In addition, the polypeptide content is 1.0 to 2 wt%,
Preferably it is 2.0 to 10 wt%. Also, the blending amount is 1
If it is less than 12 wt % or more than 12 wt %, good pearlescent luster cannot be obtained and the storage stability described below will be poor.
また、０成分であるステアリルアルコール、ａ成分であ
るベヘニルアルコールの配合量はＯ，１〜１０ｗｔ％、
好ましくは０．５〜６ｗｔ％であり、ステアリルアルコ
ールとベヘニルアルコールの配合重量比はｔ：１．Ｓ〜
ｔｉｔｓ特に好ましくは、ｌ：２〜ｌ：４の範囲である
。In addition, the blending amounts of stearyl alcohol, which is component 0, and behenyl alcohol, which is component a, are O, 1 to 10 wt%,
Preferably it is 0.5 to 6 wt%, and the blending weight ratio of stearyl alcohol and behenyl alcohol is t:1. S~
tits is particularly preferably in the range of 1:2 to 1:4.
ステアリルアルコールとベヘニルアルコールの配合重量
比が上記範囲以外では優れたパール光沢性及び保存安定
性は得られない。If the blending weight ratio of stearyl alcohol and behenyl alcohol is outside the above range, excellent pearl luster and storage stability cannot be obtained.
本発明の毛髪処理剤は、上述した４成分を必須の構成成
分とするが、当該組成物には、本発明の目的を達成する
範囲で他の成分を配合することができる。The hair treatment agent of the present invention has the above-mentioned four components as essential components, but other components may be blended into the composition within the range that achieves the object of the present invention.
即ち、流動パラフィン、ワセリン、スクワラン。namely, liquid paraffin, petrolatum, and squalane.
等の炭化水素、イソプロピルミリステート、イ゛ノプロ
ピルパルミテート１等のエステル油、゛ンノイキ油、オ
リーブ油、アボカド油等の植物油、ポリグリセリン脂肪
酸エステル、ポリオキシエチレン脂肪酸エステル、ポリ
オキシエチレンソルビタンモノラウレート等の非イオン
界面活性剤、メチルセルロース、ヒドロキシエチルセル
ロース、カチオン化セルロース等のセルロース誘導体、
エチレングリコール、プロピレングリコール、グリセリ
ン等の保湿剤、その他殺菌剤、キレート剤、紫外線吸収
剤１着色剤、香料などが挙げられ、これらの一種または
二種以上を配合することができる。hydrocarbons such as isopropyl myristate, ester oils such as isopropyl palmitate 1, vegetable oils such as quince oil, olive oil, avocado oil, polyglycerin fatty acid esters, polyoxyethylene fatty acid esters, polyoxyethylene sorbitan monolau Nonionic surfactants such as esters, cellulose derivatives such as methyl cellulose, hydroxyethyl cellulose, and cationized cellulose,
Examples include humectants such as ethylene glycol, propylene glycol, and glycerin, other bactericidal agents, chelating agents, ultraviolet absorbers 1 colorants, and fragrances, and one or more of these may be blended.
本発明の毛髪処理剤にパール状光沢が付与される理由は
明確ではないが、本発明に用いるカチオン性界面活性剤
と特定の配合比率のステアリルアルコール及びベヘニル
アルコールとポリペプチドの複合塩が析出するためであ
ると推考される。The reason why the hair treatment agent of the present invention has pearl-like luster is not clear, but it is because the complex salt of the cationic surfactant used in the present invention, stearyl alcohol and behenyl alcohol, and polypeptide in a specific blending ratio precipitates. It is assumed that
（実施例）
次に実施例を挙げ本発明を説明するが、本発明はこれら
実施例に限定されるものではない。(Examples) Next, the present invention will be described with reference to Examples, but the present invention is not limited to these Examples.
なお、本実施例中で用いた試験方法は、下記の通りであ
る。The test method used in this example is as follows.
（１１パール光沢性
試料を１００ｍｊの透明ガラス容器に入れ、肉眼判定に
より下記基準で評価を行なった。 ゛Ｑ：美麗なパ
ール光沢が認められる。(No. 11 Pearl luster sample was placed in a 100 mJ transparent glass container and evaluated with the naked eye according to the following criteria.゛Q: Beautiful pearl luster is observed.
Δ：わずかにパール光沢が認められる。Δ: Slight pearlescent luster is observed.
×：パール光沢が認められない。×: No pearlescent luster observed.
＋２１ 保存安定性
（イ） 高温安定性
試料を１００ｍ＆の透明ガラス容器に入れ、密閉し、４
５℃の恒温室中にｌケ月保存した後、肉眼判定により、
下記基準で評価を行なった。+21 Storage stability (a) Place the high temperature stability sample in a 100 m transparent glass container, seal it,
After being stored in a constant temperature room at 5°C for one month, visually determined:
Evaluation was performed based on the following criteria.
Ｏ：相分離、パール光沢の凝集、消失等を認めない。O: No phase separation, aggregation or disappearance of pearlescent luster, etc. were observed.
×；相分離、パール光沢の凝集、消失等を認める。×: Phase separation, agglomeration and disappearance of pearlescent luster, etc. were observed.
（ロ）低温安定性
試料を１００ｍｊの透明ガラス容器に入れ、密閉し、０
℃の恒温室中に１ケ月保存した後、（■ 壁仕上げ効果
各側における「髪のしっとり感」、「髪のなめらかさ」
、「（し通り性」を市販のヘアーリンス剤と比べ、女性
２０名のパネラ−により官能的に比較し、下記基準で評
価を行なった。(b) Place the low-temperature stability sample in a 100 mJ transparent glass container, seal it, and
After being stored in a constant temperature room at ℃ for one month,
A panel of 20 women sensually compared the ``passability'' with commercially available hair rinses and evaluated them according to the following criteria.
◎：良いと答えた人が１８Å以上の場合ｏ： ＃
が１４〜１７人の場合Δ： ｌ が８〜１
３人の場合×： ｌ が７Å以下の場合
実施例１〜２、比較例１〜３
第１表に示す配合組成のヘアーリンス組成物を通常の方
法で調製し、各必須成分の効果を調べ第１表にその結果
を示す。◎: If the person who answered good is 18Å or more o: #
If there are 14 to 17 people, Δ: l is 8 to 1
In the case of 3 people ×: When l is 7 Å or less Examples 1 to 2, Comparative Examples 1 to 3 Hair rinse compositions having the composition shown in Table 1 were prepared in a conventional manner, and the effects of each essential ingredient were investigated. Table 1 shows the results.
第 １ 表
注） ＊ｌ・・・平均分子量２００． 傘２・・・
１． ＯＯ０実施例３〜４、比較例４〜７
第２表に示す配合組成のへアートリートメント組成物を
通常の方法でｉｌｌ製し、各必須成分の効果第 ２
表
由 傘３・・・平均分子！１３１０００ 傘４・
・・５．０００実施例５〜６、比較例８〜ｌＯ
第３表に示す配合組成のへアーリンス組成物を通常の方
法で調製し、各必須成分の効果を調べ第第 ３ 表
（特性）
実施例１〜６より明らかなように、本発明の毛髪処理剤
は、いずれも優れた性能を示している。Table 1 Note) *l...Average molecular weight 200. Umbrella 2...
1. OO0 Examples 3 to 4, Comparative Examples 4 to 7 A hair treatment composition having the composition shown in Table 2 was prepared in a conventional manner, and the effects of each essential ingredient were evaluated.
Umbrella 3...average molecule! 131000 Umbrella 4・
...5.000 Examples 5 to 6, Comparative Examples 8 to 1O A hair rinse composition having the composition shown in Table 3 was prepared in a conventional manner, and the effects of each essential ingredient were examined in Table 3 (Characteristics) As is clear from Examples 1 to 6, the hair treatment agents of the present invention all exhibit excellent performance.
これに対し、必須成分である高級アルコールが、セチ７
Ｌ／ ７７Ｌ／ ：Ｉ−ル、ステアリルアルコール及ヒ
ベヘニルアルコールの単独、またはセチルアルコールと
ステアリルアルコールあるいはセチルアルコールとベヘ
ニルアルコールのごとく二種の併用ノ場合（比較例１〜
５）、ステアリルアルコールとベヘニルアルコールの配
合重量比が本発明の範囲外の場合（比較例６〜７）、ま
た必須成分であるポリペプチドの配合量が本発明の範囲
外の場合（比較例８〜１０）等々は、いずれも劣った性
能を示し、本発明の目的を達成できない。On the other hand, higher alcohols, which are essential components,
L/77L/: I-ru, stearyl alcohol and hbehenyl alcohol alone or in combination of two such as cetyl alcohol and stearyl alcohol or cetyl alcohol and behenyl alcohol (Comparative Examples 1 to
5) When the blending weight ratio of stearyl alcohol and behenyl alcohol is outside the range of the present invention (Comparative Examples 6 to 7), and when the blending amount of the essential component polypeptide is outside the range of the present invention (Comparative Examples 8 to 7) 10) etc., all exhibit inferior performance and cannot achieve the purpose of the present invention.
（発明の効果） 以上記載のとと（、本発明は、パール光沢性。(Effect of the invention) In addition to the above description, the present invention also relates to pearlescent luster.
保存安定性、髪仕上効果に優れた有用なる毛髪処理剤を
提供することは明らかである。It is clear that a useful hair treatment agent with excellent storage stability and hair finishing effects can be provided.
Claims (1)
は炭素数１２〜２４の長鎖アルキル基を示し、残余は炭
素数１〜３のアルキル基、ベンジル基を示し、Ｘはハロ
ゲン原子を示す。〕 で表わされる第４級アンモニウム塩の少なくとも一種０
．１〜１０重量％、（Ｂ）平均分子量２００〜５，００
０のポリペプチド１．０〜１２重量％（Ｃ）ステアリル
アルコール０．１〜１０重量％、（Ｄ）ベヘニルアルコ
ール０．１５〜１５重量％を含有してなり、かつステア
リルアルコールとベヘニルアルコールの配合重量比は１
：１．５〜１：４．５である毛髪処理剤。[Claims] (A) General formula ▲ Numerical formulas, chemical formulas, tables, etc. , the remainder represents an alkyl group having 1 to 3 carbon atoms or a benzyl group, and X represents a halogen atom. ] At least one quaternary ammonium salt represented by 0
．． 1 to 10% by weight, (B) average molecular weight 200 to 5,00
0 polypeptide containing 1.0 to 12% by weight (C) 0.1 to 10% by weight of stearyl alcohol, and (D) 0.15 to 15% by weight of behenyl alcohol, and the blending weight ratio of stearyl alcohol and behenyl alcohol. is 1
:1.5 to 1:4.5.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP11934387A JPH0617296B2 (en) | 1987-05-15 | 1987-05-15 | Hair treatment agent |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP11934387A JPH0617296B2 (en) | 1987-05-15 | 1987-05-15 | Hair treatment agent |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS63284113A true JPS63284113A (en) | 1988-11-21 |
| JPH0617296B2 JPH0617296B2 (en) | 1994-03-09 |
Family
ID=14759136
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP11934387A Expired - Lifetime JPH0617296B2 (en) | 1987-05-15 | 1987-05-15 | Hair treatment agent |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0617296B2 (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1997047274A3 (en) * | 1996-06-07 | 1998-02-26 | Henkel Kgaa | Aqueous nacreous lustre concentrates |
| FR2781368A1 (en) * | 1998-07-27 | 2000-01-28 | Oreal | COMPOSITION CONTAINING AN OPACIFYING OR NACRANT AGENT AND AT LEAST ONE FATTY ALCOHOL |
| JP2000511914A (en) * | 1996-06-07 | 2000-09-12 | ヘンケル・コマンディットゲゼルシャフト・アウフ・アクチエン | Aqueous pearlescent concentrate |
-
1987
- 1987-05-15 JP JP11934387A patent/JPH0617296B2/en not_active Expired - Lifetime
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1997047274A3 (en) * | 1996-06-07 | 1998-02-26 | Henkel Kgaa | Aqueous nacreous lustre concentrates |
| JP2000511914A (en) * | 1996-06-07 | 2000-09-12 | ヘンケル・コマンディットゲゼルシャフト・アウフ・アクチエン | Aqueous pearlescent concentrate |
| JP2000511913A (en) * | 1996-06-07 | 2000-09-12 | ヘンケル・コマンディットゲゼルシャフト・アウフ・アクチエン | Aqueous pearlescent concentrate |
| US6228831B1 (en) | 1996-06-07 | 2001-05-08 | Henkel Kommanditgesellschaft Auf Aktien | Aqueous nacreous lustre concentrates |
| JP2006117695A (en) * | 1996-06-07 | 2006-05-11 | Cognis Deutschland Gmbh & Co Kg | Aqueous nacreous luster concentrates |
| FR2781368A1 (en) * | 1998-07-27 | 2000-01-28 | Oreal | COMPOSITION CONTAINING AN OPACIFYING OR NACRANT AGENT AND AT LEAST ONE FATTY ALCOHOL |
| EP0976393A1 (en) * | 1998-07-27 | 2000-02-02 | L'oreal | Composition containing an opacifying or pearlescent agent and at least one fatty alcohol |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0617296B2 (en) | 1994-03-09 |
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