JPS63279750A - Preparation of low-fat spread - Google Patents

Preparation of low-fat spread

Info

Publication number
JPS63279750A
JPS63279750A JP62116300A JP11630087A JPS63279750A JP S63279750 A JPS63279750 A JP S63279750A JP 62116300 A JP62116300 A JP 62116300A JP 11630087 A JP11630087 A JP 11630087A JP S63279750 A JPS63279750 A JP S63279750A
Authority
JP
Japan
Prior art keywords
oil
fat
emulsion
added
phase
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP62116300A
Other languages
Japanese (ja)
Inventor
Tadaaki Hayakawa
早川 忠昭
Tadao Kato
忠夫 加藤
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
NOF Corp
Original Assignee
Nippon Oil and Fats Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nippon Oil and Fats Co Ltd filed Critical Nippon Oil and Fats Co Ltd
Priority to JP62116300A priority Critical patent/JPS63279750A/en
Publication of JPS63279750A publication Critical patent/JPS63279750A/en
Pending legal-status Critical Current

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  • Edible Oils And Fats (AREA)

Abstract

PURPOSE:To obtain the titled spread having excellent emulsion stability, tastiness, etc., by adding a specific innermost phase fat or oil part to a specific intermediate aqueous phase part to prepare an oil-in-water type emulsion and mixing and emulsifying the resultant emulsion in a specific outermost phase fat or oil part. CONSTITUTION:An intermediate aqueous phase part is initially heated and polyglycerol ester of a fatty acid having >=5 polymerization degree is added and dissolved. The innermost fat or oil phase part is then heated and lecithin is added and dissolved. The resultant solution is subsequently added to the above-mentioned intermediate aqueous phase part and preemulsified. The obtained preemulsion is then homogenized in a colloid mill, etc., to form an oil-in-water type emulsion. On the other hand, the outermost fat or oil phase part is heated and polyglycerol condensed ricinoleic acid ester and lecithin are added and dissolved to provide a solution, which is subsequently mixed and emulsified with the afore-mentioned emulsion. The obtained oil-in-water-in oil type preemulsion is passed through a quick-cooling plasticator while being homogeneously stirred and stabilized to afford the aimed spread.

Description

【発明の詳細な説明】 〔産業上の利用分野〕 1一 本発明は、乳化安定性、口どけ、呈味性、展延性の優れ
た低脂肪スプレッドの製造方法に関する。
DETAILED DESCRIPTION OF THE INVENTION [Industrial Application Field] 11 The present invention relates to a method for producing a low-fat spread that has excellent emulsion stability, melt-in-the-mouth texture, taste, and spreadability.

〔従来の技術および発明が解決しようとする問題点〕[Problems to be solved by conventional technology and invention]

従来、低脂肪スプレッドとしては、低脂肪のマーガリン
が用いられ、これらは通常のマーガリンに比較して、分
散相となる水相部の、油相部に対する比率が高いため、
油中水型の乳化状態が壊れやすく、急冷可塑化機を通過
せしめる際に、油中水型から水中油型に転相したり、ま
た製品の保存中に油と水との分離が起こるなどの問題点
があった。そこで、その乳化状態を安定に保つための方
法として、添加する乳化剤の種々の組み合わせが研究さ
れて来たが、未だ十分なものは得られていなかった。
Conventionally, low-fat margarine has been used as a low-fat spread, and compared to regular margarine, these have a higher ratio of the water phase, which is the dispersed phase, to the oil phase.
The water-in-oil emulsion is easily broken, and the phase may change from water-in-oil to oil-in-water when passing through a quenching plasticizer, or separation of oil and water may occur during storage of the product. There was a problem. Therefore, various combinations of emulsifiers to be added have been studied as a method for keeping the emulsified state stable, but a satisfactory one has not yet been obtained.

最近、それらを解決するものとして、第1表に示すよう
な乳化剤および安定剤を油中水中油型エマルションの各
相に用いた二重乳化型の油脂組成物が用いられるように
なった。しかし、この場合でもなおエマルションの最内
相油脂部または中間水相部に添加されたフレーバー、呈
味性物質などの長期安定性が不十分である上に、最外相
油脂部と最内相油脂部とが合一してしまうことがあり、
やはり乳化状態としては不安定であることを免れなかっ
た。
Recently, as a solution to these problems, double emulsion type oil and fat compositions have been used in which emulsifiers and stabilizers as shown in Table 1 are used in each phase of an oil-in-water emulsion. However, even in this case, the long-term stability of flavors and taste-producing substances added to the innermost fat phase or middle aqueous phase of the emulsion is still insufficient, and the outermost fat phase and innermost phase fat Departments may merge,
As expected, the emulsified state was unstable.

さらに、現在は低脂肪スプレッドとしては、これら乳化
安定性問題の解決に加えて、製品そのものの口どけ、呈
味性、展延性の向上が要求されるようになって来ている
Furthermore, in addition to solving these emulsion stability problems, low-fat spreads are now required to improve the melt in the mouth, taste, and spreadability of the product itself.

〔問題点を解決するための手段〕[Means for solving problems]

本発明者らは、これら従来の低脂肪スプレッドの有する
問題点を解決し、さらにそれに対する要求をすべて満足
せしめ得る低脂肪スプレッドを得るべく鋭意研究した結
果、乳化の型式を油中水中油型の二重乳化型とすること
、そのエマルションを得るために特定の乳化剤を使用す
ることにより、その目的を達し得ることを知り本発明を
完成するに至った。
The inventors of the present invention solved the problems of conventional low-fat spreads, and as a result of intensive research to obtain a low-fat spread that satisfies all the requirements, the emulsification type was changed to an oil-in-water-in-oil type. The present invention was completed based on the knowledge that the object can be achieved by creating a double emulsion type and by using a specific emulsifier to obtain the emulsion.

すなわち、本発明は、油脂分20〜50重量%と水分8
0〜50重量%とを乳化させて得られる低脂肪スプレッ
ドにおいて、乳化剤として最外相油脂部にはポリグリセ
リン縮合リシノレイン酸エステルとレシチンとを、中間
水相部には重合度5以上のポリグリセリン脂肪酸エステ
ルを、最内相油脂部にはレシチンをそれぞれ添加して、
油中水中油型エマルションに乳化させたのち急冷可塑化
することを特徴とする低脂肪スプレッドの製造方法に関
する。
That is, the present invention has an oil content of 20 to 50% by weight and a water content of 8% by weight.
In the low-fat spread obtained by emulsifying 0 to 50% by weight, polyglycerin condensed ricinoleic acid ester and lecithin are used as emulsifiers in the outermost oil and fat part, and polyglycerin fatty acid with a degree of polymerization of 5 or more is used in the middle aqueous phase. Add ester and lecithin to the innermost fat and oil part,
This invention relates to a method for producing a low-fat spread, which is characterized by emulsifying it into an oil-in-water-in-oil emulsion and then rapidly cooling and plasticizing it.

本発明に用いることができる油脂としては、従来から公
知の食用天然動植物油脂、例えば、牛脂、豚脂、パーム
油、大豆油、なたね油、コーン油、サフラワー油、ひま
わり油、乳脂、およびこれらの加工脂、配合油、水添油
、エステル交換油などが挙げられるが、油中水中油型エ
マルションとしての最内相油脂部へは、常温で液状もし
くは流動状の油脂を使用するのが好ましい。
The oils and fats that can be used in the present invention include conventionally known edible natural animal and vegetable oils, such as beef tallow, lard, palm oil, soybean oil, rapeseed oil, corn oil, safflower oil, sunflower oil, milk fat, and these. Examples include processed fats, blended oils, hydrogenated oils, transesterified oils, etc., but it is preferable to use fats and oils that are liquid or fluid at room temperature for the innermost phase of the oil-in-water emulsion.

これらの油脂は、製品中に20〜50重景%配合される
ことが必要で、さらに製品の油中水中油型エマルション
における最外相油脂部と最内相油脂部との配合割合は、
重量比で1=1〜5:1であることが好ましい。
These oils and fats need to be blended in the product in an amount of 20 to 50% by weight, and the ratio of the outermost phase oil and fat in the oil-in-water emulsion of the product is as follows:
It is preferable that the weight ratio is 1=1 to 5:1.

最外相油脂部への配合割合が、この比率よりも多いと口
どけ、呈味性は低下し、逆に少ないと製造時に乳化破壊
が生ずる。
If the blending ratio in the outermost fat/oil part is higher than this ratio, melting in the mouth and taste will be deteriorated, while if it is lower than this ratio, demulsification will occur during production.

本発明において、乳化剤として最外相油脂部に添加され
るポリグリセリン縮合リシノレイン酸エステルは、主に
ひまし油を原料とする縮合リシノレイン酸とポリグリセ
リンとのエステル化反応により得られる。
In the present invention, the polyglycerin condensed ricinoleic acid ester added to the outermost fat/oil portion as an emulsifier is obtained by an esterification reaction between condensed ricinoleic acid and polyglycerin mainly using castor oil as a raw material.

このポリグリセリン縮合リシノレイン酸エステルの添加
量は、製品中0.1〜5重量%、好ましくは0.2〜3
重量%である。
The amount of this polyglycerin condensed ricinoleic acid ester added is 0.1 to 5% by weight, preferably 0.2 to 3% by weight in the product.
Weight%.

また、同様に最外相油脂部および最内相油脂部に添加さ
れるレシチンは、大豆、卵黄などから抽出されたリン脂
質であり、精製したものでも、未精製のものでも、ある
いは酵素処理を施したものでも使用できるが、通常は一
般のマーガリン製造に用いられる市販の大豆レシチンを
使用するのが簡便である。
Similarly, lecithin, which is added to the outermost oil and fat parts and the innermost fat part, is a phospholipid extracted from soybeans, egg yolks, etc., and may be purified, unrefined, or subjected to enzyme treatment. However, it is convenient to use commercially available soybean lecithin, which is commonly used in the production of margarine.

このレシチンの添加量は、最外相油脂部に添加する場合
、製品中0.05〜3重量%、好ましくは0.1〜1.
8重量%である。また、最内相油脂部へは、第一段階の
乳化で得られる水中油型エマル23290.05〜1重
量%、好ましくは0.05〜0.5重量%添加するのが
よい。
When added to the outermost fat/oil part, the amount of lecithin added is 0.05 to 3% by weight, preferably 0.1 to 1% by weight in the product.
It is 8% by weight. Further, it is preferable to add 23290.05 to 1% by weight, preferably 0.05 to 0.5% by weight of the oil-in-water emulsion obtained in the first stage of emulsification to the innermost phase fat/oil portion.

本発明において、中間水相部に添加される重合度5以上
のポリグリセリン脂肪酸エステルは、ポリグリセリンと
脂肪酸とのエステルであり、好ましくはポリグリセリン
と炭素数12〜20の脂肪酸とのモノエステルである。
In the present invention, the polyglycerin fatty acid ester with a degree of polymerization of 5 or more added to the intermediate aqueous phase is an ester of polyglycerin and a fatty acid, preferably a monoester of polyglycerin and a fatty acid having 12 to 20 carbon atoms. be.

このポリグリセリン脂肪酸エステルの添加量は。What is the amount of polyglycerin fatty acid ester added?

水中油型エマルション中0.05〜1.5重量%、好ま
しくは0.05〜1重量%である。
It is 0.05 to 1.5% by weight, preferably 0.05 to 1% by weight in the oil-in-water emulsion.

本発明の低脂肪スプレッドにおいては、上記各種の乳化
剤以外に、その中間水相部には、水溶性添加物として、
食塩、アミノ酸系調味料、糖類、香辛料、果汁などの種
々の調味料や、脱脂粉乳、ホエーパウダー、生クリーム
などの乳製品などを目的に応じて添加することができる
。また、最外相油脂部および最内相油脂部には、油溶性
添加物として、油溶性色素、抗酸化剤、油溶性香料など
を同様に添加することができる。
In the low-fat spread of the present invention, in addition to the various emulsifiers mentioned above, the intermediate aqueous phase contains water-soluble additives such as
Various seasonings such as salt, amino acid seasonings, sugars, spices, and fruit juice, and dairy products such as skim milk powder, whey powder, and fresh cream can be added depending on the purpose. Moreover, oil-soluble dyes, antioxidants, oil-soluble fragrances, and the like can be similarly added to the outermost fat and oil portions and the innermost fat and oil portions as oil-soluble additives.

さらに、キサンタンガムなどの乳化安定剤は、最外相油
脂部に分散させても、また中間水相部に溶解させてもよ
い。
Furthermore, an emulsion stabilizer such as xanthan gum may be dispersed in the outermost oil phase or dissolved in the intermediate aqueous phase.

次に、本発明の低脂肪スプレッドの製造方法について説
明する。
Next, the method for producing the low-fat spread of the present invention will be explained.

まず、必要に応じて水溶性添加物を分散せしめた中間水
相部を約60℃に加温し、重合度5以上のポリグリセリ
ン脂肪酸エステルを添加溶解する。
First, an intermediate aqueous phase in which water-soluble additives are dispersed as necessary is heated to about 60° C., and a polyglycerol fatty acid ester having a degree of polymerization of 5 or more is added and dissolved therein.

次いで、必要に応じて油溶性添加物を分散せしめた最内
相油脂部を加温し、レシチンを添加溶解したのち、それ
を中間水相部に添加し予備乳化する。
Next, the innermost fat phase in which oil-soluble additives are dispersed as necessary is heated to add and dissolve lecithin, and then added to the intermediate aqueous phase to pre-emulsify.

さらに、その予備乳化液をコロイドミル、ホモゲナイザ
ーなどで均質化し、水中油型乳化液を調製する。
Further, the preliminary emulsion is homogenized using a colloid mill, a homogenizer, etc. to prepare an oil-in-water emulsion.

次に、必要に応じて油溶性添加物を分散せしめた最外相
油脂部を加温し、ポリグリセリン縮合リシノレイン酸エ
ステルおよびレシチンを添加溶解したのち、これに対し
上記水中油型乳化液を混合乳化する。乳化温度は、最外
相油脂部が十分に溶融する温度であればよく、好ましく
は40〜70℃である。
Next, the outermost fat phase in which oil-soluble additives have been dispersed as necessary is heated, polyglycerin condensed ricinoleic acid ester and lecithin are added and dissolved, and then the above oil-in-water emulsion is mixed and emulsified. do. The emulsification temperature may be any temperature at which the outermost fat/oil portion is sufficiently melted, and is preferably 40 to 70°C.

このようにして得られた油中水中油型予備乳化液は、均
一に撹拌しながら急冷可塑化機を通して安定化し、本発
明の低脂肪スプレッドを得る。
The oil-in-water-in-oil preemulsion thus obtained is stabilized by passing through a quenching plasticizer while stirring uniformly to obtain the low-fat spread of the present invention.

急冷可塑化機としては、公知のパーツエフター、コンビ
ネータ−、ボテーターなどを使用することができる。
As the quenching plasticizer, a known part-effecter, combinator, votator, etc. can be used.

〔発明の効果〕〔Effect of the invention〕

本発明の低脂肪スプレッドの製造方法によれば、得られ
る低脂肪スプレッドを油中水中油型の二重乳化型とし、
さらに最外相油脂部、中間水相部、最内相油脂部にそれ
ぞれ添加する乳化剤を特定することによって、製造工程
中に乳化状態が損なわれることなく、しかも保存中に油
と水とが分離することのない安定な製品を得ることがで
きる。
According to the method for producing a low-fat spread of the present invention, the low-fat spread obtained is made into an oil-in-water-in-oil double emulsion type,
Furthermore, by specifying the emulsifiers to be added to the outermost oil phase, middle aqueous phase, and innermost oil phase, the emulsified state is not impaired during the manufacturing process, and oil and water are separated during storage. You can get a stable product without any problems.

しかも、得られた低脂肪スプレッドは、低脂肪であるこ
とから、口どけが優れているとともに、近年の消費者の
低カロリー指向にも合致した好ましい有用な食品となる
Moreover, since the obtained low-fat spread is low in fat, it has excellent melt-in-the-mouth texture and is a desirable and useful food that meets the low-calorie preference of consumers in recent years.

〔実施例および比較例〕[Examples and comparative examples]

次に、実施例および比較例により、本発明をさらに詳細
に説明する。
Next, the present invention will be explained in more detail with reference to Examples and Comparative Examples.

実施例1〜4.比較例1〜3 第2表に示す配合で低脂肪スプレッドを製造した。Examples 1-4. Comparative examples 1 to 3 A low-fat spread was produced with the formulation shown in Table 2.

すなわち、まず中間水相部を60℃に加温し、同温度の
最内相油脂部を添加したのち、ホモゲナイザーを用いて
圧力 120kg/cm”で処理し、水中油型乳化液を
調製した。次いで、この水中油型乳化液を再び60℃に
加温し、同温度の最外相油脂部中に混合乳化したのち、
急冷可塑化機を通過せしめ、低脂肪スプレッドを得た。
That is, first, the intermediate aqueous phase was heated to 60° C., the innermost fat phase at the same temperature was added, and then treated using a homogenizer at a pressure of 120 kg/cm'' to prepare an oil-in-water emulsion. Next, this oil-in-water emulsion was heated again to 60°C, mixed and emulsified into the outermost fat phase at the same temperature, and then
It was passed through a quenching plasticizer to obtain a low-fat spread.

比較例4,5 第2表において、最内相油脂部を用いずに、中間水相部
を60℃に加温し、同温度に加温した最外相油脂部中に
混合乳化したのち、急冷可塑化機を通過せしめ、低脂肪
スプレッドを製造した。
Comparative Examples 4 and 5 In Table 2, the middle aqueous phase was heated to 60°C without using the innermost fat phase, mixed and emulsified into the outermost fat phase heated to the same temperature, and then rapidly cooled. It was passed through a plasticizer to produce a low fat spread.

以上の実施例1〜4および比較例1〜5により得られた
低脂肪スプレッドについて、乳化安定性と風味の評価を
行なった。
The low-fat spreads obtained in Examples 1 to 4 and Comparative Examples 1 to 5 above were evaluated for emulsion stability and flavor.

まず、低脂肪スプレッドを15℃で1週間保存し、その
ときの乳化安定性を目視により評価した。
First, the low-fat spread was stored at 15° C. for one week, and the emulsion stability at that time was visually evaluated.

結果は第3表に示す。The results are shown in Table 3.

また、低脂肪スプレッドを10名のパネラ−に試食させ
、風味を評価した。評価点は、非常に良い : 5点 良い    = 4点 普通    = 3点 悪い    = 2点 非常に悪い : 1点 の5段階に分け、10名のパネラ−の平均値を第3表に
示す。
Additionally, 10 panelists tasted the low-fat spread and evaluated the flavor. The evaluation scores were divided into five levels: very good: 5 points good = 4 points average = 3 points bad = 2 points very bad: 1 point, and the average values of the 10 panelists are shown in Table 3.

第3表 (注)乳化安定性評価 O:均一な乳化状態Δ:水がわ
ずかに分離 ×:水が完全に分離 第3表に示す結果からも明らかなように、本発明により
得られた低脂肪スプレッドは、乳化安定性、風味ともに
優れたものであった。
Table 3 (Note) Emulsion stability evaluation O: Uniform emulsification state Δ: Water is slightly separated ×: Water is completely separated The fat spread had excellent emulsion stability and flavor.

Claims (2)

【特許請求の範囲】[Claims] (1)油脂分20〜50重量%と水分80〜50重量%
とを乳化させて得られる低脂肪スプレツドにおいて、乳
化剤として最外相油脂部にはポリグリセリン縮合リシノ
レイン酸エステルとレシチンとを、中間水相部には重合
度5以上のポリグリセリン脂肪酸エステルを、最内相油
脂部にはレシチンをそれぞれ添加して、油中水中油型エ
マルシヨンに乳化させたのち急冷可塑化することを特徴
とする低脂肪スプレツドの製造方法。
(1) Oil and fat content 20-50% by weight and moisture 80-50% by weight
In the low-fat spread obtained by emulsifying the above, polyglycerin condensed ricinoleic acid ester and lecithin are used as emulsifiers in the outermost fat phase, polyglycerin fatty acid ester with a degree of polymerization of 5 or more is used in the middle aqueous phase, and 1. A method for producing a low-fat spread, which comprises adding lecithin to each of the fat and oil phases, emulsifying it into an oil-in-water emulsion, and then rapidly cooling and plasticizing it.
(2)油中水中油型エマルシヨンの最外相油脂部と最内
相油脂部との重量比が、1:1〜5:1である特許請求
の範囲第1項記載の低脂肪スプレツドの製造方法。
(2) The method for producing a low-fat spread according to claim 1, wherein the weight ratio of the outermost fat phase to the innermost phase fat portion of the oil-in-water-in-oil emulsion is 1:1 to 5:1. .
JP62116300A 1987-05-13 1987-05-13 Preparation of low-fat spread Pending JPS63279750A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP62116300A JPS63279750A (en) 1987-05-13 1987-05-13 Preparation of low-fat spread

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP62116300A JPS63279750A (en) 1987-05-13 1987-05-13 Preparation of low-fat spread

Publications (1)

Publication Number Publication Date
JPS63279750A true JPS63279750A (en) 1988-11-16

Family

ID=14683603

Family Applications (1)

Application Number Title Priority Date Filing Date
JP62116300A Pending JPS63279750A (en) 1987-05-13 1987-05-13 Preparation of low-fat spread

Country Status (1)

Country Link
JP (1) JPS63279750A (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH04141048A (en) * 1990-10-03 1992-05-14 Meiji Milk Prod Co Ltd Oil and fat composition for food and its production
JPH04234947A (en) * 1991-01-09 1992-08-24 Nagoya Seiraku Kk Cream-like composition
JPH08231981A (en) * 1995-02-23 1996-09-10 Asahi Denka Kogyo Kk Oil and fat composition
JP2003213290A (en) * 2002-01-25 2003-07-30 Snow Brand Milk Prod Co Ltd Double-emulsified oil and fat composition and method for producing the same

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH04141048A (en) * 1990-10-03 1992-05-14 Meiji Milk Prod Co Ltd Oil and fat composition for food and its production
JPH04234947A (en) * 1991-01-09 1992-08-24 Nagoya Seiraku Kk Cream-like composition
JP2601950B2 (en) * 1991-01-09 1997-04-23 名古屋製酪株式会社 Creamy composition
JPH08231981A (en) * 1995-02-23 1996-09-10 Asahi Denka Kogyo Kk Oil and fat composition
JP2003213290A (en) * 2002-01-25 2003-07-30 Snow Brand Milk Prod Co Ltd Double-emulsified oil and fat composition and method for producing the same

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