JPS63277520A - Compound having hexagonal layer structure expressed by lufezn7o10 and production thereof - Google Patents
Compound having hexagonal layer structure expressed by lufezn7o10 and production thereofInfo
- Publication number
- JPS63277520A JPS63277520A JP62111406A JP11140687A JPS63277520A JP S63277520 A JPS63277520 A JP S63277520A JP 62111406 A JP62111406 A JP 62111406A JP 11140687 A JP11140687 A JP 11140687A JP S63277520 A JPS63277520 A JP S63277520A
- Authority
- JP
- Japan
- Prior art keywords
- compound
- heating
- oxide
- lutetium
- metallic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 150000001875 compounds Chemical class 0.000 title claims abstract description 27
- 238000004519 manufacturing process Methods 0.000 title claims description 3
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 claims abstract description 20
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims abstract description 18
- 239000011701 zinc Substances 0.000 claims abstract description 18
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims abstract description 17
- 238000010438 heat treatment Methods 0.000 claims abstract description 16
- 229910052742 iron Inorganic materials 0.000 claims abstract description 8
- 239000000203 mixture Substances 0.000 claims abstract description 8
- 229910052725 zinc Inorganic materials 0.000 claims abstract description 8
- 239000011787 zinc oxide Substances 0.000 claims abstract description 8
- 229910052765 Lutetium Inorganic materials 0.000 claims abstract description 7
- 229910003443 lutetium oxide Inorganic materials 0.000 claims abstract description 7
- MPARYNQUYZOBJM-UHFFFAOYSA-N oxo(oxolutetiooxy)lutetium Chemical compound O=[Lu]O[Lu]=O MPARYNQUYZOBJM-UHFFFAOYSA-N 0.000 claims abstract description 7
- 230000001590 oxidative effect Effects 0.000 claims abstract description 4
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims abstract description 3
- OHSVLFRHMCKCQY-UHFFFAOYSA-N lutetium atom Chemical compound [Lu] OHSVLFRHMCKCQY-UHFFFAOYSA-N 0.000 claims abstract description 3
- 150000002500 ions Chemical class 0.000 claims description 5
- 239000000463 material Substances 0.000 abstract description 8
- 239000004065 semiconductor Substances 0.000 abstract description 6
- 239000003054 catalyst Substances 0.000 abstract description 4
- 229910052751 metal Inorganic materials 0.000 abstract description 2
- 239000002184 metal Substances 0.000 abstract description 2
- 238000002156 mixing Methods 0.000 abstract description 2
- 150000002739 metals Chemical class 0.000 abstract 1
- 239000013078 crystal Substances 0.000 description 5
- 239000000696 magnetic material Substances 0.000 description 5
- 239000000843 powder Substances 0.000 description 5
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 2
- 238000000634 powder X-ray diffraction Methods 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 239000007858 starting material Substances 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 229910052769 Ytterbium Inorganic materials 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 239000004570 mortar (masonry) Substances 0.000 description 1
- 150000002823 nitrates Chemical class 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
Landscapes
- Catalysts (AREA)
- Hard Magnetic Materials (AREA)
- Soft Magnetic Materials (AREA)
- Recrystallisation Techniques (AREA)
- Compounds Of Iron (AREA)
Abstract
Description
【発明の詳細な説明】
産業上の利用分野
本発明は磁性材料、半導体材料、触媒材料等として有用
な新規化合物であるＬｕＦｅＺｎ７０．。で示される六
方晶系の層状構造を有する化合物およびその製造法に関
する。DETAILED DESCRIPTION OF THE INVENTION Field of Industrial Application The present invention relates to LuFeZn70., which is a new compound useful as a magnetic material, a semiconductor material, a catalyst material, etc. . This invention relates to a compound having a hexagonal layered structure represented by and a method for producing the same.
従来技術
従来、（Ｙｂ”Ｆｅ”Ｏ＝）、Ｆｅ”０ （ｎは整数を
示す）で示される六方晶系の層状構造を有する化合物は
本出願人によって合成され知られている。Prior Art Conventionally, compounds having a hexagonal layered structure represented by (Yb"Fe"O=), Fe"0 (n is an integer) have been synthesized by the present applicant and are known.
ＹｂＦｅ０ｉ、 ＹｂＦｅ０ｔ、 Ｙｂ３ＦｅｎＯ＋ｏ
及びＹｂ、Ｆｅ、Ｏｌの六方晶系としての格子定数、Ｙ
ｂＯ＋、ｓ層、 ＦｅＯ＋、ｓ層、 Ｐｅ、０□、２層
の単位格子内における層数を示すと表−１の通りである
。YbFe0i, YbFe0t, Yb3FenO+o
and the lattice constant of Yb, Fe, Ol as a hexagonal system, Y
Table 1 shows the number of layers in the unit cell of bO+, s layer, FeO+, s layer, Pe, 0□, and 2 layers.
これらの化合物は酸化鉄（Ｆｅｄ） １モルに対して、
ＹｂＦｅ０ｉがｎモル（ｎ−１，２，３・・・）の割合
で化合していると考えられる層状構造を持つ化合物であ
る。These compounds are based on 1 mole of iron oxide (Fed).
It is a compound having a layered structure in which YbFeOi is thought to be combined in a ratio of n moles (n-1, 2, 3...).
発明の目的
本発明は（ＹｂＦｅＯｓ） 、ＦｅＯの化学式において
、ｎ−１７７に相当し、ｙｂ３″′の代わりにＬｕ１を
、Ｆｅ”の代わりにＺｎ”を置きかえて得られた新規な
化合物を提供するにある。Object of the invention The present invention provides a novel compound (YbFeOs) corresponding to n-177 in the chemical formula of FeO, obtained by replacing Lu1 in place of yb3'' and Zn'' in place of Fe''. It is in.
発明の構成
本発明のＬｕＦｅＺｎｔＯ＋。で示される化合物は、イ
オン結晶モデルではｌ ｕ ３ ” （ｐ ｅ ！＋
、 ｚｎ Ｉ ＋Ｊ ） Ｚｎ ｂｔ ＋ Ｑ 、 。Constitution of the Invention LuFeZntO+ of the present invention. In the ionic crystal model, the compound represented by
, zn I + J) Zn bt + Q, .
トとして記載され、その構造はＬｕＯ＋、ｓ層、（Ｆｅ
。Its structure consists of LuO+, s layer, (Fe
.
Ｚｎ） Ｏ□、５層およびＺｎＯ層の積層によって形成
されており、著しい構造異方性を持つことがその特徴の
一つである。Ｚｎ”イオンの１／７はＦｅ”と共に（Ｆ
ｅ”、Ｚｎ”）Ｏｘ、 ｓ層を作り、残りの６７７はＺ
ｎＯ層を作っている。六方晶系としての格子定数は次の
通りである。It is formed by stacking five layers of Zn)O□ and a ZnO layer, and one of its characteristics is that it has significant structural anisotropy. 1/7 of Zn” ion is together with Fe” (F
e”, Zn”) Ox, s layer is made, and the remaining 677 are Z
Making the nO layer. The lattice constants as a hexagonal crystal system are as follows.
ａ ＝３．３１０ ±０．００１ （人）ｃ −７２
，２２±ｏ、ｏｉ ｃ人）この化合物の面指数（ｈ
ｋｌ）、面間隔（ｄ（入））（ｄ、は実測値＋ｄｅは計
算値を示す）及びＸ線に対する相対反射強度（１（％）
）を示すと、表−２の通りである。a = 3.310 ±0.001 (person) c -72
, 22±o, oic) The surface index (h
kl), interplanar spacing (d (in)) (d is the measured value + de is the calculated value), and relative reflection intensity for X-rays (1 (%)
) is shown in Table 2.
この化合物は磁性材料、半導体材料および触媒材料とし
て有用なものである。例えば、異方性の強い２次元的性
質を持つ磁性体・半導体および触媒物質としての利用の
可能性が考えられる。This compound is useful as a magnetic material, a semiconductor material, and a catalytic material. For example, it is possible to use them as magnetic materials, semiconductors, and catalyst materials that have two-dimensional properties with strong anisotropy.
この化合物は次の方法によって製造し得られる。This compound can be produced by the following method.
金属ルテチウムあるいは酸化ルテチウムもしくは加熱に
より酸化ルテチウムに分解される化合物と、金属鉄ある
いは酸化鉄もしくは加熱により酸化鉄に分解される化合
物と、金属亜鉛あるいは酸化亜鉛もしくは加熱により酸
化亜鉛に分解される化合物とを、Ｌｕ、 Ｆｅ及びＺｎ
の割合が原子比で１対１対７の割合で混合し、該混合物
を６５０℃以上の温度で、大気中、酸化性雰囲気中ある
いはＬｕおよびＦｅが各々３価イオン状態、Ｚｎが２価
イオン状態より還元されない還元雰囲気中で加熱するこ
とによって製造し得られる。Metallic lutetium or lutetium oxide or a compound that is decomposed into lutetium oxide by heating; Metallic iron or iron oxide or a compound that is decomposed into iron oxide by heating; Metallic zinc or zinc oxide or a compound that is decomposed into zinc oxide by heating. , Lu, Fe and Zn
are mixed in an atomic ratio of 1:1:7, and the mixture is heated at a temperature of 650° C. or higher in the air, an oxidizing atmosphere, or in a state where Lu and Fe are each in a trivalent ion state and Zn is a divalent ion state. It can be produced by heating in a reducing atmosphere that is not reduced by the state.
本発明に用いる出発物質は市販のものをそのまま使用し
てもよいが、化学反応を速やかに進行させるためには粒
径が小さい方がよく、特にｌＯμｌ以下であることが好
ましい。Commercially available starting materials for use in the present invention may be used as they are, but in order to allow the chemical reaction to proceed rapidly, it is better to have a small particle size, particularly preferably 10 μl or less.
また、磁性材料、半導体材料として用いる場合には不純
物の混入をきらうので、純度の高いことが好ましい。出
発物質が加熱により金属酸化物を得る化合物としては、
それぞれの金属の水酸化物。Further, when used as a magnetic material or a semiconductor material, it is preferable to have high purity since contamination with impurities is avoided. Compounds whose starting materials yield metal oxides by heating include:
hydroxide of each metal.
炭酸塩、硝酸塩等が挙げられる。Examples include carbonates and nitrates.
原料はそのまま、あるいはアルコール類、アセトン等と
共に充分に混合する。The raw materials are thoroughly mixed as they are or together with alcohols, acetone, etc.
原料の混合割合はＬｕ、 Ｆｅ、及びＺｎの割合が原子
比で、１対１対７の割合であることが必要である。The mixing ratio of the raw materials must be such that the atomic ratio of Lu, Fe, and Zn is 1:1:7.
これをはずすと目的とする化合物の単−相を得ることが
できない。If this is removed, a single phase of the target compound cannot be obtained.
この混合物を大気中、酸化性雰囲気中あるいはＬｕおよ
びＦｅが各々３価イオン状ａ、Ｚｎが２価イオン状態か
ら還元されない還元雰囲気中で６５０℃以上で加熱する
。加熱時間は数時間もしくはそれ以上である。加熱の際
の昇温速度には制約はない。This mixture is heated at 650° C. or higher in the air, in an oxidizing atmosphere, or in a reducing atmosphere in which Lu and Fe are not reduced from their trivalent ionic states a, and Zn is not reduced from their divalent ionized states. Heating time is several hours or more. There are no restrictions on the rate of temperature increase during heating.
加熱終了後急冷するか、あるいは大気中に急激に引き出
せばよい。After heating, it can be rapidly cooled, or it can be rapidly drawn out into the atmosphere.
得られたＬｕＦｅＺｎｙＯ＋ｅ化合物の粉末は褐色であ
り、粉末Ｘ線回折法によって結晶構造を有することが分
かった。その結晶構造は層状構造であり、ＬｕＯ＋、ｓ
層＋ （Ｆｅ 、 Ｚｎ）０．ｓ層、およびＺｎＯ層の
積み重ねによって形成されていることが分かった。The obtained LuFeZnyO+e compound powder was brown in color and was found to have a crystal structure by powder X-ray diffraction. Its crystal structure is a layered structure, and LuO+, s
Layer + (Fe, Zn)0. It was found that it was formed by stacking an s layer and a ZnO layer.
実施例
純度９９．９９％以上の酸化ルテチウム（ＬｕｚＯ＋）
粉末、純度９９．９％以上の酸化鉄（Ｆｅ！０３）粉末
、および試薬特級の酸化亜鉛（ＺｎＯ）粉末をモル比で
１対１対１４の割合に秤量し、めのう乳鉢内でエタノー
ルを加えて、約３０分間部合し、平均粒径数μｍの微粉
状混合物を得た。該混合物を白金管内に封入し、１４５
０℃に設定された管状シリコニット炉内に入れ５日間加
熱し、その後、試料を炉外にとりだし室温まで急速に冷
却した。Example Lutetium oxide (LuzO+) with a purity of 99.99% or more
Powder, iron oxide (Fe!03) powder with a purity of 99.9% or higher, and reagent grade zinc oxide (ZnO) powder were weighed at a molar ratio of 1:1:14, and ethanol was added in an agate mortar. The mixture was mixed for about 30 minutes to obtain a fine powder mixture with an average particle size of several μm. The mixture was sealed in a platinum tube, and 145
The sample was placed in a tubular siliconite furnace set at 0° C. and heated for 5 days, and then taken out of the furnace and rapidly cooled to room temperature.
得られた試料はＬｕＦｅＺｎ７０１．の単−相であり、
粉末Ｘ線回折法によって、各面指数（ｈｋｌ）、面間隔
（ｄｏ）および相対反射強度を測定した結果は表−２の
通りであった。The obtained sample was LuFeZn701. It is a single phase of
Table 2 shows the results of measuring each plane index (hkl), plane distance (do), and relative reflection intensity by powder X-ray diffraction.
六方晶系としての格子定数は
ａ＝３゜３１０ ±０．００１ （人）ｃ ＝７２
．２２ ±０．０１ （人）であった。The lattice constant as a hexagonal crystal system is a = 3°310 ±0.001 (person) c = 72
．． 22 ±0.01 (persons).
上記の格子定数および表−２の面指数（ｈ ｋ Ｊ）よ
り算出した面間隔（ｄｃ（人））は実測の面間隔（ｄ。The interplanar spacing (dc (people)) calculated from the above lattice constant and the planar index (h k J) in Table 2 is the actually measured interplanar spacing (d).
（人））と極めてよく一致している。(person)).
発明の効果
本発明は磁性材料、半導体材料および触媒として有用な
新規化合物を特徴する
特許出願人 科学技術庁無機材質研究所長瀬 高
信 雄Effects of the Invention The present invention features novel compounds useful as magnetic materials, semiconductor materials, and catalysts.Patent applicant: Takashi Nagase, Institute of Inorganic Materials, Science and Technology Agency
Nobuo
Claims (2)
の層状構造を有する化合物。(1) A compound having a hexagonal layered structure represented by LuFeZn_7O_1_0.
加熱により酸化ルテチウムに分解される化合物と、金属
鉄あるいは酸化鉄もしくは加熱により酸化鉄に分解され
る化合物と、金属亜鉛あるいは酸化亜鉛もしくは加熱に
より酸化亜鉛に分解される化合物とを、Ｌｕ、Ｆｅおよ
びＺｎの割合が原子比で１対１対７の割合で混合し、該
混合物を６５０℃以上の温度で、大気中、酸化性雰囲気
中あるいはＬｕおよびＦｅが各々３価イオン状態、Ｚｎ
が２価イオン状態より還元されない還元雰囲気中で加熱
することを特徴とするＬｕＦｅＺｎ＿７Ｏ＿１＿０で示
される六方晶系の層状構造を有する化合物の製造法。(2) Metallic lutetium or lutetium oxide or a compound that is decomposed into lutetium oxide by heating, metallic iron or iron oxide or a compound that is decomposed into iron oxide by heating, and metallic zinc or zinc oxide or a compound that is decomposed into zinc oxide by heating. Lu, Fe, and Zn are mixed in an atomic ratio of 1:1:7, and the mixture is heated at a temperature of 650° C. or higher in the air, in an oxidizing atmosphere, or when Lu and Fe are present, respectively. Trivalent ion state, Zn
A method for producing a compound having a hexagonal layered structure represented by LuFeZn_7O_1_0, which comprises heating in a reducing atmosphere in which LuFeZn_7O_1_0 is not reduced to a divalent ion state.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP62111406A JPS63277520A (en) | 1987-05-07 | 1987-05-07 | Compound having hexagonal layer structure expressed by lufezn7o10 and production thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP62111406A JPS63277520A (en) | 1987-05-07 | 1987-05-07 | Compound having hexagonal layer structure expressed by lufezn7o10 and production thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS63277520A true JPS63277520A (en) | 1988-11-15 |
| JPH0435417B2 JPH0435417B2 (en) | 1992-06-11 |
Family
ID=14560347
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP62111406A Granted JPS63277520A (en) | 1987-05-07 | 1987-05-07 | Compound having hexagonal layer structure expressed by lufezn7o10 and production thereof |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS63277520A (en) |
-
1987
- 1987-05-07 JP JP62111406A patent/JPS63277520A/en active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0435417B2 (en) | 1992-06-11 |
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