JPS63266403A - Solid-state image pickup device and its production - Google Patents

Solid-state image pickup device and its production

Info

Publication number
JPS63266403A
JPS63266403A JP62102412A JP10241287A JPS63266403A JP S63266403 A JPS63266403 A JP S63266403A JP 62102412 A JP62102412 A JP 62102412A JP 10241287 A JP10241287 A JP 10241287A JP S63266403 A JPS63266403 A JP S63266403A
Authority
JP
Japan
Prior art keywords
layer
solid
magenta
filter layer
layers
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP62102412A
Other languages
Japanese (ja)
Other versions
JPH0734042B2 (en
Inventor
Toshiyuki Ota
敏行 太田
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
NEC Corp
Original Assignee
NEC Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by NEC Corp filed Critical NEC Corp
Priority to JP10241287A priority Critical patent/JPH0734042B2/en
Publication of JPS63266403A publication Critical patent/JPS63266403A/en
Publication of JPH0734042B2 publication Critical patent/JPH0734042B2/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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  • Optical Filters (AREA)
  • Solid State Image Pick-Up Elements (AREA)

Abstract

PURPOSE:To uniformize the thickness of a magenta filter layer and the eliminate fluctuations in sensitivity by using a magenta film layer to form the lowermost layer of plural color filter layers. CONSTITUTION:The magenta filter layer 3a is formed in a prescribed position via a flattening layer 2a on a semiconductor substrate 1 on which a photodetecting part 1a and a CCD part 1b are provided. An intermediate layer 2b, a cyan filter layer 3b, an intermediate layer 2c and a yellow filter layer 3c are successively laminated on the layers 3a and the surface thereof is coated with a top coating layer 2d. The layers 2a, 2b and 2c can be formed of a radiation sensitive resin such as polymethyl methacrylate and dyeing base materials for the layers 3a, 3b and 3c can be formed by mixing ammonium dichromate with gelatin, casein, albumin and PVA.

Description

【発明の詳細な説明】 〔産業上の利用分野〕 本発明は固体撮像装置およびその製造方法に関し、時に
カラーフィルタ層を積層したモノリシックの固体撮像装
置およびその製造方法に関する。
DETAILED DESCRIPTION OF THE INVENTION [Field of Industrial Application] The present invention relates to a solid-state imaging device and a manufacturing method thereof, and more particularly to a monolithic solid-state imaging device in which color filter layers are laminated and a manufacturing method thereof.

〔従来の技術〕[Conventional technology]

従来のカシ−フィルタ層を核層したモノリンツクの固体
撮像装置およびその製造方法としては、例えば、第3ニ に示されている文献がある。
Regarding a conventional monolink solid-state imaging device having a core layer of a Cassie filter layer and a method for manufacturing the same, there is, for example, the document shown in No. 3 (D).

第3図tag. (b)及び(C)はそれぞれ従来の固
体#L像装置の一例を説明する平面図、A−A’i及び
B−B’崖の模式的町四図である。この例は、第3図F
a)に示すよう罠、下の行(第1行目)がシアン画素部
C.マゼンタ画素部M,、 71ン画素部C及びグリー
ンIII+1素部Gという順序にくり返し配列され、上
の行(第2行目)はイエロー画素部Y。
Figure 3 tag. (b) and (C) are a plan view and a schematic diagram of A-A'i and B-B' cliffs, respectively, illustrating an example of a conventional solid-state #L image device. This example is shown in Figure 3F.
As shown in a), the bottom row (first row) is the cyan pixel portion C. The magenta pixel section M, 71 pixel section C and the green III+1 pixel section G are arranged repeatedly in this order, and the upper row (second row) is the yellow pixel section Y.

グリーン画素部G,イエロー画素部Y及びマゼンタ画素
部M2という順序にくり返し配列され、さらにこの第1
及び第2行が列方向にくり返し配置されている。
The green pixel section G, the yellow pixel section Y, and the magenta pixel section M2 are arranged repeatedly in this order.
and the second row are arranged repeatedly in the column direction.

この例の第1行目の構造では、第3図(b) K示すよ
うに、表面に受光部1aとCCD部1− bとを備えた
半導体基板1上に表面の平担化層2aを設け、平坦化N
1Za上のシアン及びグリーン画素部C及びGの位置に
シアンフィルタ層3b’を設け、この上を中間層2bで
覆った後にグリーン画素部Gの位置にイエローフィルタ
層3c’を設け、更に中間層2Cを介してマゼンタ画素
部Mlの位置にマゼンタフィルタrfi3a’を設けて
いる。
In the structure in the first row of this example, as shown in FIG. 3(b)K, a flattening layer 2a is formed on the semiconductor substrate 1, which has a light receiving section 1a and a CCD section 1-b on its surface. Setting, flattening N
A cyan filter layer 3b' is provided at the positions of the cyan and green pixel parts C and G on 1Za, and after this is covered with an intermediate layer 2b, a yellow filter layer 3c' is provided at the position of the green pixel part G. A magenta filter rfi3a' is provided at the position of the magenta pixel portion Ml via 2C.

父、この実施例の第2行目の構造では、第3図tc)に
示すように、半導体基板1上の平坦化層2a上のグリー
ン画素部Gの位置にシアンフィルタ層3b’を設け、こ
の上に中間層2bを介し℃イエロー及びグリーン画素部
Y及びGの位置にイエローフィルタ層3 c/を設け、
更に中間層2Cを介してマゼンタ画素部M2の位置廻マ
ゼンタフィルタ層3a’を設けている。
In the structure of the second row of this embodiment, as shown in FIG. A yellow filter layer 3c/ is provided on this at the positions of the yellow and green pixel portions Y and G via the intermediate layer 2b,
Further, a positional magenta filter layer 3a' of the magenta pixel portion M2 is provided via the intermediate layer 2C.

従って、第1行目のマゼンダ画素部M1のマゼンタフィ
ルタ層3 a /は、これに隣接するシアン画素Cのシ
アンフィルタ層3 b’ Kよる段差が中間層2b及び
2Cによって比較的平坦疋なった部分に形成されている
ので、所定の厚さに形成されているが、しかし第2行目
のマゼンタ+jluX部へ12のマゼンタフィルタ層3
8′は、これに隣接するイエロー画素Yのイエローフィ
ルタ層3 C’ Kより層の厚さがP;ir9’+によ
り不均一に形成されることになる。
Therefore, in the magenta filter layer 3a/ of the magenta pixel portion M1 in the first row, the step caused by the cyan filter layer 3b'K of the adjacent cyan pixel C is made relatively flat by the intermediate layers 2b and 2C. However, 12 magenta filter layers 3 are formed in the magenta+jluX part of the second row.
8' is formed non-uniformly because the layer thickness P;ir9'+ is greater than that of the yellow filter layer 3C'K of the yellow pixel Y adjacent thereto.

〔発明が解決しようとする問題点〕[Problem that the invention seeks to solve]

上述した従来の固体撮像装置では、モノリンツクに形成
したカシ−フィルタ、qの形成Ha序が下からイエロー
フィルり層、/アンフィルタへ吻及びマゼンタフィルタ
層の順となっているので、シアンフィルタ層に挾まれた
マゼンタ画素部のマゼンタフィルタ層の増厚とイエロー
フィルタ層に挾まれたマゼンタ画素部のマゼンタフィル
タ層の増厚とが異なシ光の透過率が違ってくるためそれ
ぞれのフィルタ層を通して受光部に入射した元による出
力信号に差が生じて感度がはらつくという欠点がある。
In the conventional solid-state imaging device described above, the formation order of the Cassie filter and q is from the bottom to the yellow filter layer, then to the unfilter, and then the magenta filter layer. The increase in the thickness of the magenta filter layer in the magenta pixel area sandwiched by the yellow filter layer is different from the increase in the thickness of the magenta filter layer in the magenta pixel area sandwiched by the yellow filter layer. The drawback is that the output signal varies depending on the source incident on the light receiving section, resulting in fluctuations in sensitivity.

〔問題点を解決するための手段〕[Means for solving problems]

本発明の固体m像装置は、固体撮像素子を表面に形成し
た半導体基板の上に層間膜を介して積層した所定のパタ
ーンの複数のカシ−フィルタ層を備えた固体系は装置に
おいて、前記複数のカラーフィルタ層の最下層がマゼン
タフィルタ層からなるO 本発明の固体撮像装置の製造方法は、固体撮像素子を表
面に形成した半導体基板の上に層間膜を介して積層した
ffr定のパターンの複数のカニ)−フィルタ層を備え
た固体rf&像装置の製造方法において、マゼンタフィ
ルタ層を最下層として前記層間膜を介して積層した前記
複数のカラーフィルタ層を順次形成する工程を含んで成
る。
The solid-state m-image device of the present invention is a solid-state m-image device comprising a plurality of Cassie filter layers in a predetermined pattern laminated on a semiconductor substrate on which a solid-state image sensor is formed via an interlayer film. The lowermost layer of the color filter layer is a magenta filter layer. The method for manufacturing a solid-state imaging device according to the present invention includes a method for manufacturing a solid-state imaging device in which a pattern with a constant ffr is laminated via an interlayer film on a semiconductor substrate on which a solid-state imaging element is formed. A method for manufacturing a solid-state RF & imaging device having a plurality of crab-filter layers, comprising the step of sequentially forming the plurality of color filter layers laminated with the interlayer film interposed therebetween, with a magenta filter layer as the bottom layer.

〔実施ビシす〕[Implementation]

次に、本発明の実施例について図面を参照して説明する
Next, embodiments of the present invention will be described with reference to the drawings.

第1図は本発明の固体撮像装置の一実施例の模式的断面
図である。
FIG. 1 is a schematic cross-sectional view of an embodiment of the solid-state imaging device of the present invention.

この夾M回では、表面に少くとも受光部1aとCCD部
1bとを備えた半導体基板1上にポリメチルメタクリレ
ート(PMMA)やポリグリンジルメタクリレート(P
GMA)、ポリメチルイソグロペニルケトン(PMIP
K) 等の放射線感光樹脂からなる表面の平坦化層2a
を設け、平坦化@2a上のマゼンダ画素部の位置にゼラ
チン、カゼイン。
In these M times, polymethyl methacrylate (PMMA) or polygrindyl methacrylate (P
GMA), polymethyl isogropenyl ketone (PMIP)
K) A surface flattening layer 2a made of a radiation-sensitive resin such as
gelatin and casein were placed at the magenta pixel area on flattened @2a.

アルブミン及びポリビニルアルコールに重クロム酸アン
モニウム(AT)C)を混合したものを染色母材とする
マゼンタフィルタ層3aを設け、平坦1ヒ/#2aと同
僚の材料からなる中間N2bで堕った後にマゼンタフィ
ルタ19113 aと同様の染色母材を用いた/アノフ
ィルタノー31)をシアン及びグリーン画素部の位置に
設け、中間/fi2bと同様の材料の中間層2Cで覆っ
た後イエロー及びグリーン画素部の位置に他のフィルタ
層と同様の染色母材を使ったイエローフィルタ層3Cを
設げ、更に中間層と同様の材料を使ったト、グコート層
2dで覆っている。
A magenta filter layer 3a is provided using a mixture of albumin and polyvinyl alcohol with ammonium dichromate (AT) C) as the dyeing matrix, and after filtering with flat 1/#2a and intermediate N2b made of the material of colleagues. Magenta filter 19113a using the same dyeing base material /anofilter no 31) is provided at the positions of the cyan and green pixel parts, and after covering with the intermediate layer 2C of the same material as intermediate /fi2b, the yellow and green pixel parts A yellow filter layer 3C using the same dyed matrix material as the other filter layers is provided at the position, and is further covered with a gray coat layer 2d using the same material as the intermediate layer.

第2図(a)、 (b)は本発明の同体撮像装置の製造
方法の一実施例を説明するための模式的断面図である0 この実施例では、先ず、第2図(a)に示すように、表
面に受光部1a及びCCD部1bを形成した半害体基板
1上にポリメチルメタクリレート(PMMA)やポリグ
リンジルメタクリレート(PGMA)、ポリメチルイソ
グロペニルケトン(PMIPK)等の放射線感光樹脂か
らなる表面の平坦化層2aを塗布することによ多形成し
、ゼラチン、カゼイン、アルブミン及びポリビニルアル
コールに重クロム酸アンモニウムADCを混合してなる
染色母材を塗布し、これを露光・現像して所定のパター
ンにした後、例えば下記に示すようなマゼンタ染色液中
に浸してマゼンダ画素部の位置にヌゼンタフィルタ層3
aを形成する。
FIGS. 2(a) and 2(b) are schematic cross-sectional views for explaining an embodiment of the method for manufacturing the same-body imaging device of the present invention. In this embodiment, first, FIG. As shown, polymethyl methacrylate (PMMA), polygrindyl methacrylate (PGMA), polymethyl isogropenyl ketone (PMIPK), etc. A surface flattening layer 2a made of a radiation-sensitive resin is applied to form a layer, and a dyeing base material made of a mixture of gelatin, casein, albumin, and polyvinyl alcohol with ammonium dichromate ADC is applied, and this is exposed.・After developing into a predetermined pattern, for example, soak it in a magenta dye solution as shown below and apply a Nugenta filter layer 3 at the position of the magenta pixel area.
form a.

次に、第2図(b)に示すように、平坦化層2aと同様
のPMMA−?PGMA、PMIPK等の放射線感光樹
脂からなる中間層2bを塗布することによ多形成し、さ
らに、その上にゼラチン、カゼイン、アルブミン及びポ
リビニルアルコール等Klクロム酸アンモニウムを混合
してなる染色母材を塗布し、これを露光、視像して所定
のパターンtcシタ=、下記に示す7アン染色液中に浸
して7アン及びグリーン画素部の位置にシアンフィルタ
層3bを形成する。
Next, as shown in FIG. 2(b), PMMA-? A multilayer layer 2b is formed by applying an intermediate layer 2b made of a radiation-sensitive resin such as PGMA or PMIPK, and then a dyeing base material made of a mixture of gelatin, casein, albumin, and Kl ammonium chromate such as polyvinyl alcohol is further applied thereto. The cyan filter layer 3b is formed at the positions of the 7mm and green pixel portions by applying the coating, exposing and visualizing it to a predetermined pattern, and immersing it in the 7mm dyeing solution shown below.

j?llc、ポリメチルメタクリレート(PklMA 
)やポリグリンジルメタクリレート(PGMA)、ポリ
メチルイソグロベニルクトン(PMIPK )等の放射
線感光樹脂からなる中間層2cを塗布することにより形
成し、さらKその上にゼラチンやカゼイン、アルブミン
及びポリビニルアルコール等に重クロム酸アンモニウム
を混合してなる染色母材を塗布し、これを露光、現像し
て所定のパターンにした後下記に示すイエロー染色液中
で染色しイエロー及びグリーン画素部の位置にイエロー
フィルタ層3Cを形成し、更に、 PMMA−?PGMA、PMIPK等の放射線感光樹脂
層からなるドッグコート層2dを塗布することにより形
成し、ポンディングパッド部やスクライプ綾部等の遠紫
外線の照射及び現像欣申でのfA像工程を柱で、スクラ
イプ婦やポンディングパッド部の放射線感光樹脂層から
なる平坦化層2a、中間層2b及び2C並びにドッグコ
ート層2dを除去すれば、第1図に示す固体撮像装置が
できる。
j? llc, polymethyl methacrylate (PklMA
), polygrindyl methacrylate (PGMA), polymethyl isoglobenyl lactone (PMIPK), etc. is formed by applying an intermediate layer 2c consisting of a radiation-sensitive resin, and then gelatin, casein, albumin, and polyvinyl alcohol are further applied on top of the intermediate layer 2c. A dyeing base material made by mixing ammonium dichromate is applied to the surface, exposed and developed to form a predetermined pattern, and then dyed in the yellow dyeing solution shown below to add yellow to the yellow and green pixel areas. A filter layer 3C is formed, and PMMA-? It is formed by applying a dog coat layer 2d made of a radiation-sensitive resin layer such as PGMA, PMIPK, etc., and the fA image process in the irradiation of far ultraviolet rays and development of the bonding pad part and the scrip twill part is the pillar, and the scrip is applied. By removing the flattening layer 2a, the intermediate layers 2b and 2C, and the dog coat layer 2d, which are made of a radiation-sensitive resin layer at the front and padding pad portions, the solid-state imaging device shown in FIG. 1 can be obtained.

〔発明の効果〕〔Effect of the invention〕

以上説明したように本発明では、52間層を介して設け
られた複数のカラーフィルタ層の最下層をマゼンタフィ
ルタ層とすることによシ、隣接フィルタ層の眩差の影響
を受け!S %、%%マゼンタフィルタ層の層厚を均一
にして、出力信号の場所により生じ3差を防止して感度
のばらつきのない特性の艮好な固体撮像装置を実現でき
るという効果がある。
As explained above, in the present invention, by using the magenta filter layer as the lowest layer of the plurality of color filter layers provided with 52 interlayers in between, it is possible to avoid the effects of glare between adjacent filter layers! S%, %% By making the layer thickness of the magenta filter layer uniform, it is possible to prevent three-dimensional differences that occur depending on the location of the output signal, thereby realizing a solid-state imaging device with excellent characteristics without variations in sensitivity.

【図面の簡単な説明】[Brief explanation of the drawing]

第1図は本発明の固体撮像装置の一実施例の模式的断面
図、第2図fan、 lb)は本発明の固体撮像装置の
製造方法の一夾農列を説明するための模式的断面図、第
3図(a)、 lb)及びtc)はそれぞれ従来の固体
撮像装置の一例を説明する平面図、A−A’i及びB−
8’線の模式的断面図である。 1・・・・・・半導体基板、1a・・・・・・受光部、
1b・・・・・・CCD部、2a・・・・・・平坦化層
、2b、2c・・・・・・中間層、2d・・・・・・ド
ッグコート層、3a、3a’。 3a′・・・・・・マゼンタフィルタ層、3b、3b’
・・・・・・シアンフィルタ層、3C,3c/ ・・・
・・・イエローフィルタ層、C・・・・・・シアン画素
部、G・・・・・・グリーン画素部、Ml、M、・・・
・・・マゼンダ画素部、Y・・・・・・イエローIl!
jI素部。 2丁ミド 代理人 弁理士  内 原   晋(′・・W、、”1
.:”+。 牛I図 (α) l呼529  代理人弁理士
FIG. 1 is a schematic cross-sectional view of an embodiment of the solid-state imaging device of the present invention, and FIG. 3(a), lb) and tc) are plan views illustrating an example of a conventional solid-state imaging device, A-A'i and B-, respectively.
FIG. 8 is a schematic cross-sectional view taken along line 8'. 1... Semiconductor substrate, 1a... Light receiving section,
1b... CCD section, 2a... Flattening layer, 2b, 2c... Intermediate layer, 2d... Dog coat layer, 3a, 3a'. 3a'...Magenta filter layer, 3b, 3b'
...Cyan filter layer, 3C, 3c/ ...
...Yellow filter layer, C...Cyan pixel section, G...Green pixel section, Ml, M,...
...Magenta pixel part, Y...Yellow Il!
jI elementary section. 2 Cho Mido Patent Attorney Susumu Uchihara ('...W,,”1
.. :”+. Cow I diagram (α) l call 529 agent patent attorney

Claims (2)

【特許請求の範囲】[Claims] (1)固体撮像素子を表面に形成した半導体基板の上に
層間膜を介して積層した所定のパターンの複数のカラー
フィルタ層を備えた固体撮像装置において、前記複数の
カラーフィルタ層の最下層がマゼンタフィルタ層からな
ることを特徴とする固体撮像装置。
(1) In a solid-state imaging device comprising a plurality of color filter layers in a predetermined pattern laminated via an interlayer film on a semiconductor substrate on which a solid-state imaging device is formed, the bottom layer of the plurality of color filter layers is A solid-state imaging device comprising a magenta filter layer.
(2)固体撮像素子を表面に形成した半導体基板の上に
層間膜を介して積層した所定のパターンの複数のカラー
フィルタ層を備えた固体撮像装置の製造方法において、
マゼンタフィルタ層を最下層として前記層間膜を介して
積層した前記複数のカラーフィルタ層を順次形成する工
程を含むことを特徴とする固体撮像装置の製造方法。
(2) A method for manufacturing a solid-state imaging device comprising a plurality of color filter layers in a predetermined pattern laminated via an interlayer film on a semiconductor substrate on which a solid-state imaging device is formed,
A method for manufacturing a solid-state imaging device, comprising the step of sequentially forming the plurality of color filter layers stacked with the interlayer film interposed therebetween, with a magenta filter layer as the bottom layer.
JP10241287A 1987-04-24 1987-04-24 Solid-state imaging device Expired - Lifetime JPH0734042B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP10241287A JPH0734042B2 (en) 1987-04-24 1987-04-24 Solid-state imaging device

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP10241287A JPH0734042B2 (en) 1987-04-24 1987-04-24 Solid-state imaging device

Publications (2)

Publication Number Publication Date
JPS63266403A true JPS63266403A (en) 1988-11-02
JPH0734042B2 JPH0734042B2 (en) 1995-04-12

Family

ID=14326727

Family Applications (1)

Application Number Title Priority Date Filing Date
JP10241287A Expired - Lifetime JPH0734042B2 (en) 1987-04-24 1987-04-24 Solid-state imaging device

Country Status (1)

Country Link
JP (1) JPH0734042B2 (en)

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5525025A (en) * 1978-08-09 1980-02-22 Akai Electric Co Ltd Color filter for single tube color image pickup tube and production thereof
JPS61286804A (en) * 1985-06-14 1986-12-17 Nec Corp Solid stage image sensing element

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5525025A (en) * 1978-08-09 1980-02-22 Akai Electric Co Ltd Color filter for single tube color image pickup tube and production thereof
JPS61286804A (en) * 1985-06-14 1986-12-17 Nec Corp Solid stage image sensing element

Also Published As

Publication number Publication date
JPH0734042B2 (en) 1995-04-12

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