JPS63245970A - Magnetic shielding case - Google Patents

Magnetic shielding case

Info

Publication number
JPS63245970A
JPS63245970A JP62080414A JP8041487A JPS63245970A JP S63245970 A JPS63245970 A JP S63245970A JP 62080414 A JP62080414 A JP 62080414A JP 8041487 A JP8041487 A JP 8041487A JP S63245970 A JPS63245970 A JP S63245970A
Authority
JP
Japan
Prior art keywords
case
superconducting material
elements
group
magnetic
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP62080414A
Other languages
Japanese (ja)
Inventor
Kazuo Sawada
澤田 和夫
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Sumitomo Electric Industries Ltd
Original Assignee
Sumitomo Electric Industries Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Sumitomo Electric Industries Ltd filed Critical Sumitomo Electric Industries Ltd
Priority to JP62080414A priority Critical patent/JPS63245970A/en
Publication of JPS63245970A publication Critical patent/JPS63245970A/en
Pending legal-status Critical Current

Links

Classifications

    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E40/00Technologies for an efficient electrical power generation, transmission or distribution
    • Y02E40/60Superconducting electric elements or equipment; Power systems integrating superconducting elements or equipment

Abstract

PURPOSE:To completely protect a container against an external magnetic field by holding laminated superconducting material at a critical temperature or lower. CONSTITUTION:Mixture of oxide, carbonate, sulfide, fluoride, nitride or carbide containing predetermined superconducting material, such as group I, II, III elements and oxygen, nitrogen, fluorine, carbon, sulfur, etc. is mixed at a suitable ratio. The mixture is sintered or crystallized at a temperature directly under a melting point to form a molding or powder, which is covered on the inner or outer surface of a magnetic shielding case. When this is held at critical temperature or lower, the interior of the case is shielded from an external magnetic field to completely protect a content.

Description

【発明の詳細な説明】 〈産業上の利用分野〉 この発明は、収納物を外部磁界からシールドすることが
できる磁気シールドケースに関する。
DETAILED DESCRIPTION OF THE INVENTION <Industrial Application Field> The present invention relates to a magnetic shield case that can shield stored items from external magnetic fields.

〈従来の技術〉 最近、磁気を使って情報を記録した媒体が多く使用され
るようになり、外部磁界による情報破壊の問題がクロー
ズアップされつつある。また、電子レンジ、高周波加熱
機器等、電磁波を使用する機器が多く使用されるように
なり、電子機器、通信機器等が誤動作を受けることがあ
り、電磁環境対策(EM I ”)の必要性が叫ばれて
いる。
<Prior Art> Recently, media in which information is recorded using magnetism have come into widespread use, and the problem of information destruction due to external magnetic fields is drawing attention. In addition, many devices that use electromagnetic waves, such as microwave ovens and high-frequency heating devices, are being used, and electronic devices and communication devices may malfunction, making it necessary to take electromagnetic environment countermeasures (EMI). being shouted at.

このような外部磁界によって損傷を受ける物として、磁
気ディスク、磁気テープ、磁気カード等の磁気記憶媒体
や、磁気記憶媒体を組み込んだ各種の情報機器等が挙げ
られる。また、外部磁界のうち特に電磁界によって妨害
を受ける物として、各種の電子機器、通信機器等が挙げ
られる。
Objects that can be damaged by such external magnetic fields include magnetic storage media such as magnetic disks, magnetic tapes, and magnetic cards, and various information devices incorporating magnetic storage media. In addition, various electronic devices, communication devices, and the like are examples of objects that are particularly disturbed by electromagnetic fields among external magnetic fields.

従来、これらの物を外部磁界から保護するために、透磁
率の大きな材料、例えばNi製の網からなるケースに収
納したり、小さな物であれば、パーマロイ等を電着また
は蒸着して磁気シールド膜を形成したケースに収納して
いた。また、電磁界から保護するためには、上記透磁率
の大きな材料からなるケースのほか、導電率の高いCu
、AJ等の網からなるケースに収納することも行われて
いた。
Conventionally, in order to protect these objects from external magnetic fields, they were housed in a case made of a material with high magnetic permeability, such as a Ni mesh, or, if the object was small, a magnetic shield was created by electrodepositing or vapor depositing permalloy, etc. It was housed in a case with a membrane. In addition, in order to protect from electromagnetic fields, in addition to the case made of the above-mentioned material with high magnetic permeability, it is necessary to use a case made of a material with high conductivity.
, AJ, etc. were also housed in a case made of netting.

〈発明が解決しようとする問題点〉 上記の場合、外部磁界が強かったり、収納物が外部磁界
に対してして敏感なものであればあるほどシールドを徹
底して施す必要があるが、シールドを万全にしようとす
るほど、網の目を密にしたり、何重にも設けたり、また
シールドを厚くしたりしなければならず、構造が複雑化
したり、重量が増加したりするという問題があった。
<Problem to be solved by the invention> In the above case, the stronger the external magnetic field is, or the more sensitive the stored items are to the external magnetic field, the more thorough the shielding is. The more you try to make the shield perfect, the more you have to make the mesh denser, install multiple layers, and thicken the shield, which leads to problems such as the structure becoming more complicated and the weight increasing. there were.

〈発明の目的〉 この発明は上記の問題点に鑑みてなされたものであり、
収納物を簡単な構造でかつ完全に磁気シールドできる磁
気シールドケースを提供することを目的としている。
<Object of the invention> This invention was made in view of the above problems,
To provide a magnetic shielding case which has a simple structure and can completely magnetically shield stored items.

く問題点を解決するための手段〉 上記の目的を達成するためのこの発明の磁気シールドケ
ースは、ケース基材に対して超電導材を積層しているも
のである。
Means for Solving the Problems> A magnetic shielding case of the present invention for achieving the above object has a case base material laminated with a superconducting material.

上記超電導材は、一般式AaBbCc(式中、Aは周期
律表1 a s II aおよびHa族元素から選択さ
れた少なくとも1種の元素であり、Bは周期律表1b、
I[bおよびIIIb族元素から選択された少なくとも
1種の元素であり、Cは酸素、フッ素、硫黄、炭素およ
び窒素から“選択された少なくとも1種の元素である)
で表されるセラミックス超電導材であることが好ましい
The superconducting material has a general formula AaBbCc (where A is at least one element selected from Group 1 of the Periodic Table 1 a s II a and Ha group elements, and B is a group 1 b of the Periodic Table,
I[is at least one element selected from group b and IIIb elements, and C is at least one element selected from oxygen, fluorine, sulfur, carbon and nitrogen.
It is preferable to use a ceramic superconducting material represented by:

上記超電導材は、超電導材用原料を焼結すること等によ
って製造され、その原料としては、超電導材を構成する
元素を含有するものであれば単体、化合物の何れの形態
でも使用し得る。上記元素としては、周期律表I族、■
族および■族元素並びに酸素、窒素、フッ素、炭素およ
び硫黄等が例示される。
The superconducting material described above is manufactured by sintering a raw material for superconducting material, and the raw material can be used in the form of either a single substance or a compound as long as it contains the elements constituting the superconducting material. The above elements include Group I of the periodic table, ■
Examples thereof include Group and Group II elements, oxygen, nitrogen, fluorine, carbon, and sulfur.

より詳細には、上記周期律表I族元素のうち、Ia族元
素としては、L i、Na、に、Rb。
More specifically, among the Group I elements of the periodic table, the Group Ia elements include Li, Na, and Rb.

Cs等が挙げられ、Ib族元素としては、Cu。Examples include Cs, and group Ib elements include Cu.

AgおよびAuが挙げられる。また、周期律表■族元素
のうち、Ila族元素としては、B e s M g 
sCa、Sr、BaおよびRaが挙げられ、nb族元素
としては、Zn、(d等が挙げられる。周期律表■族元
素のうち、III a族元素としては、Sc。
Examples include Ag and Au. In addition, among group I elements of the periodic table, as group Ila elements, B e s M g
Examples of sCa, Sr, Ba and Ra are mentioned, and examples of the nb group elements include Zn, (d, etc.).Among the elements of the group I of the periodic table, examples of the group IIIa elements include Sc.

Yやランタノイド系元素であるLa%Ce、Gd。Y and lanthanoid elements such as La%Ce and Gd.

Lu等、アクチノイド系元素であるAc、Th。Ac, Th, which are actinide elements such as Lu.

Pa5Cf等が挙げられる。また、IIIb族元素とし
ては、AJ%G aN I ns T1等が挙げられる
Examples include Pa5Cf. Further, examples of the IIIb group element include AJ%GaN Ins T1 and the like.

上記元素のうち、Ib族元素から選ばれた元素、Ila
族元素、ma族元素およびランタノイド系元素から選ば
れた元素、並びに酸素およびフッ素から選ばれた元素か
らなるセラミックス超電導材が好ましい。なお、Ib族
元素としてはCuおよびAgが好ましい。
Among the above elements, an element selected from group Ib elements, Ila
A ceramic superconducting material comprising an element selected from Group elements, Ma group elements, and lanthanoid elements, and an element selected from oxygen and fluorine is preferred. Note that Cu and Ag are preferred as the Ib group elements.

く作用〉 以上の構成の磁気シールドケースを、臨界温度以下の温
度に保つと、超電導材の反磁性によって、磁気シールド
ケース内部の磁界は0となり、収納物を外部磁界から完
全に保護することができる。
When the magnetic shield case with the above configuration is kept at a temperature below the critical temperature, the magnetic field inside the magnetic shield case becomes 0 due to the diamagnetic properties of the superconducting material, making it impossible to completely protect the stored items from external magnetic fields. can.

上記超電導体が、上記組成のセラミックス超電導体であ
れば、臨界温度が比較的高いもの(例えば液体窒素温度
以上)が知られているので、このような場合には、臨界
温度以下に保つことが容易にできる。
If the above-mentioned superconductor is a ceramic superconductor with the above-mentioned composition, it is known that the critical temperature is relatively high (for example, higher than the liquid nitrogen temperature), so in such a case, it is necessary to maintain the critical temperature below the critical temperature. It's easy to do.

〈実施例〉 以下、実施例について詳述すると、この発明の磁気シー
ルドケースは、例えば、超電導材を5US1プラスチツ
クケース等のケース基材に被覆し、または基材間に挾み
込んでなるものであればよく、要は収納物を磁気シール
ド可能に包囲できるものであればよい。
<Example> Hereinafter, examples will be described in detail. The magnetic shield case of the present invention is made by, for example, coating a case base material such as a 5US1 plastic case with a superconducting material, or sandwiching it between base materials. In short, it is sufficient as long as it can surround the stored items in a magnetically shielded manner.

上記の磁気シールドケースは、例えば以下のようにして
製作することができる。周期律表1族、■族、■族およ
び酸素、窒素、フッ素、炭素、硫黄等所定の超電導原料
を含有する酸化物、炭酸化物、硫化物、フッ化物、窒化
物または炭化物の混合粉を、所望する超電導材の組成に
応じて適宜の割合で混合し、必要ならば一定圧力でプレ
ス、焼結あるいは融点直下で結晶化して(焼結温度や結
晶化温度、熱処理時間等は、セラミックス超電導体を構
成する元素の種類、組成などにより適宜選択できる。)
、成形体またはこの成形体を粉砕した粉体を得、これを
磁気シールドケースの内面または外面に被覆する。
The above magnetic shield case can be manufactured, for example, as follows. A mixed powder of oxides, carbonates, sulfides, fluorides, nitrides, or carbides containing Groups 1, 2, and 2 of the periodic table and specified superconducting raw materials such as oxygen, nitrogen, fluorine, carbon, and sulfur, Mix in an appropriate ratio depending on the composition of the desired superconducting material, and if necessary, press at a constant pressure, sinter, or crystallize just below the melting point (sintering temperature, crystallization temperature, heat treatment time, etc. (Can be selected as appropriate depending on the type and composition of the elements constituting it.)
A molded body or a powder obtained by pulverizing the molded body is obtained, and this is coated on the inner or outer surface of a magnetic shielding case.

上記被覆は、スパッタリング法、真空蒸着法、プラズマ
8射法等の物理蒸着法、またはプラズマCVD法等の化
学蒸着法等を採用して行うこともでき、また、吹付け、
塗布にて行うこともできる。
The above-mentioned coating can also be performed by employing sputtering method, vacuum evaporation method, physical vapor deposition method such as plasma 8-shot method, or chemical vapor deposition method such as plasma CVD method.
It can also be done by coating.

さらに、磁気シールドケースと一体に焼結してもよい。Furthermore, it may be sintered integrally with the magnetic shield case.

このようにしてできた磁気シールドケースを臨界温度以
下に保てば、磁気シールドケース内部は外部磁界から遮
蔽され、収納物を磁界から完全に保護することができる
ので、磁気ディスク、磁気テープ、磁気カード等の磁気
記憶媒体や、磁気記憶媒体を組み込んだ各種の情報機器
、ならびに電子機器、通信機器等の保護に用いることが
できる。
If the magnetic shield case made in this way is kept below the critical temperature, the inside of the magnetic shield case will be shielded from external magnetic fields, and the stored items can be completely protected from the magnetic field. It can be used to protect magnetic storage media such as cards, various information devices incorporating magnetic storage media, electronic equipment, communication equipment, etc.

なお、超電導膜については前記以外の種々の組成の物を
使用することができ、その他この発明の要旨を変更しな
い範囲内において、種々の設計変更を施すことが可能で
ある。
The superconducting film may have various compositions other than those described above, and various other design changes may be made without departing from the gist of the present invention.

く試験例1〉 SUS板で容器を製作し、一定成分比率からなる微粉末
を焼結して得た超電導材(組成Y。、8Ba   Cu
03)をプラズマ溶射して、磁気シ0.2 −ルドケース内面にシールド膜を形成した。磁気シール
ドケース内部に通信機器を設置して動作させ、磁気シー
ルドケース外部に強い電磁界を発生させたが、通信機器
は何ら妨害を受けなかった。
Test Example 1 A container was made of SUS plate, and a superconducting material (composition Y., 8Ba Cu
0.2) was plasma sprayed to form a shield film on the inner surface of the magnetic shield case. Communication equipment was installed and operated inside the magnetically shielded case, and a strong electromagnetic field was generated outside the magnetically shielded case, but the communication equipment was not disturbed in any way.

く試験例2〉 磁気カードを収納するプラスチック箱の外面に一定成分
比率からなる微粉末を焼結して得た超電導材(組成 Y
   Sr   CaO2)をスバッ0.6 0.4 りしてシールド膜を形成し、さらにその外面を他のやや
大きめのプラスチック箱で覆って磁気シールドケースと
した。その中に磁気カードを入れ、1000ガウスの外
部磁界を印加したが、磁気カードに書き込まれた情報は
損傷を受けず、正常に使用することができた。
Test Example 2> A superconducting material (composition: Y
A shield film was formed by scrubbing SrCaO2), and the outer surface of the film was further covered with another slightly larger plastic box to form a magnetic shield case. A magnetic card was placed in it and an external magnetic field of 1000 Gauss was applied, but the information written on the magnetic card was not damaged and could be used normally.

〈発明の効果〉 以上のように、この発明の磁気シールドケースによれば
、ケース基板に対して積層された超電導材料によって、
外部磁界の影響を受けやすい収納物の損傷、特性劣化、
誤動作等を簡単に防止することができ、収納物を完全に
保護することができるという特有の効果を奏する。
<Effects of the Invention> As described above, according to the magnetically shielded case of the present invention, the superconducting material laminated on the case substrate provides
Damage to stored items that are susceptible to external magnetic fields, deterioration of characteristics,
It has the unique effect of easily preventing malfunctions and completely protecting stored items.

Claims (1)

【特許請求の範囲】 1、収納物を外部磁界より保護する磁気シールドケース
であって、ケース基材に対して超電導材を積層している
ことを特徴とする磁気シールドケース。 2、超電導材が、下記一般式(I)で表される組成のセ
ラミックス超電導材である上記特許請求の範囲第1項記
載の磁気シールドケース。 AaBbCc(I) (式中、Aは周期律表Ia、IIaおよびIIIa族元素か
ら選択された少なくとも1種の元素であり、Bは周期律
表Ib、IIbおよびIIIb族元素から選択された少なく
とも1種の元素であり、Cは酸素、フッ素、硫黄、炭素
および窒素から選択された少なくとも1種の元素である
[Scope of Claims] 1. A magnetic shielding case for protecting stored items from external magnetic fields, characterized in that a superconducting material is laminated on the case base material. 2. The magnetic shield case according to claim 1, wherein the superconducting material is a ceramic superconducting material having a composition represented by the following general formula (I). AaBbCc(I) (wherein A is at least one element selected from elements of groups Ia, IIa and IIIa of the periodic table, and B is at least one element selected from elements of groups Ib, IIb and IIIb of the periodic table) (C is at least one element selected from oxygen, fluorine, sulfur, carbon and nitrogen)
JP62080414A 1987-03-31 1987-03-31 Magnetic shielding case Pending JPS63245970A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP62080414A JPS63245970A (en) 1987-03-31 1987-03-31 Magnetic shielding case

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP62080414A JPS63245970A (en) 1987-03-31 1987-03-31 Magnetic shielding case

Publications (1)

Publication Number Publication Date
JPS63245970A true JPS63245970A (en) 1988-10-13

Family

ID=13717634

Family Applications (1)

Application Number Title Priority Date Filing Date
JP62080414A Pending JPS63245970A (en) 1987-03-31 1987-03-31 Magnetic shielding case

Country Status (1)

Country Link
JP (1) JPS63245970A (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS63250875A (en) * 1987-04-08 1988-10-18 Hitachi Ltd Electronic equipment
JPH02192615A (en) * 1989-01-20 1990-07-30 Ngk Insulators Ltd Metal coated superconductive ceramics compact and manufacture thereof
US5202305A (en) * 1989-04-17 1993-04-13 Ngk Insulators, Ltd. Superconducting structure for magnetic shielding
JP2007333285A (en) * 2006-06-14 2007-12-27 Sumitomo Heavy Ind Ltd Cooling storage type cryogenic device

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6033082U (en) * 1983-08-11 1985-03-06 株式会社吉野工業所 Creamy storage container

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6033082U (en) * 1983-08-11 1985-03-06 株式会社吉野工業所 Creamy storage container

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS63250875A (en) * 1987-04-08 1988-10-18 Hitachi Ltd Electronic equipment
JPH02192615A (en) * 1989-01-20 1990-07-30 Ngk Insulators Ltd Metal coated superconductive ceramics compact and manufacture thereof
US5202305A (en) * 1989-04-17 1993-04-13 Ngk Insulators, Ltd. Superconducting structure for magnetic shielding
JP2007333285A (en) * 2006-06-14 2007-12-27 Sumitomo Heavy Ind Ltd Cooling storage type cryogenic device

Similar Documents

Publication Publication Date Title
EP0194748B1 (en) Magnetic thin film and method of manufacturing the same
Wang et al. Effect of Fe/Sr mole ratios on the formation and magnetic properties of SrFe12O19 microtubules prepared by sol–gel method
Shepard et al. Magnetic and transport properties of Na doped SrRuO3 and CaRuO3
Buschmann et al. Reversed (negative) magnetization for electrochemically deposited high-T c thin films of chromium hexacyanide magnets
Costa et al. Microstructure and magnetic properties of Ni 1− x Zn x Fe 2 O 4 synthesized by combustion reaction
JPS63245970A (en) Magnetic shielding case
US4429052A (en) Magnetic hexagonal ferrite layer on a nonmagnetic hexagonal mixed crystal substrate
Shen et al. Microstructure, magnetic properties of hexagonal barium ferrite powder based on calcination temperature and holding time
Jadhav et al. Basics of ferrites: structures and properties
Donahue et al. The deposition of BaFe12O19 by metalorganic chemical vapor deposition
Pan et al. Tolerance factor control of tetragonality and negative thermal expansion in PbTiO3-based ferroelectrics
You et al. Magnetic properties of Zn-substituted Y-type hexaferrites, Ba2ZnxFe2− xFe12O22
Verdaguer et al. Magnetism: Molecules to Build Solids
Shen et al. Ferromagnetic behavior induced by La-doping in SrCo 2 As 2
US3795541A (en) Ferromagnetic material
Zhigadlo et al. High-Pressure Synthesis and Characterization of a New Series of V-Based Superconductors (Cu0. 5V0. 5) Sr2Ca n-1Cu n O y
US3850706A (en) Mn{11 {118 {11 M{11 {11 Ga Ge FERROMAGNETIC MATERIALS WHERE M COMPRISES TRANSITION METALS
Rivera et al. Effect of Ho3+ on structural and magnetic properties of the Sm3-xHoxFe5O12 ceramic system
Varadinov et al. New solvents for the growth of substituted BaFe12O19 single crystals from high-temperature solutions
KR101022439B1 (en) Layered perovskites having room-temperature ferromagnetism and ferroelectricity and electronics comprising the perovskites
JPS63258098A (en) Superconducting electromagnetic shield
US3991233A (en) Method of manufacturing a magnetizable layer for a magnetic domain device
Xu et al. Metal-semiconductor transition at a comparable resistivity level and positive magnetoresistance in Mn3Mn1− xPdxN thin films
Wolski et al. Barium-strontium ferrite with admixtures of elements of the III-rd group
Giriya et al. Structural analysis and magnetic properties of substituted Ca-Sr Hexaferrites